NL2029493B1 - Electrochemical process for producing chemicals - Google Patents

Electrochemical process for producing chemicals Download PDF

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Publication number
NL2029493B1
NL2029493B1 NL2029493A NL2029493A NL2029493B1 NL 2029493 B1 NL2029493 B1 NL 2029493B1 NL 2029493 A NL2029493 A NL 2029493A NL 2029493 A NL2029493 A NL 2029493A NL 2029493 B1 NL2029493 B1 NL 2029493B1
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NL
Netherlands
Prior art keywords
hydrogen peroxide
water
intermediate compound
contacting
produced
Prior art date
Application number
NL2029493A
Other languages
English (en)
Inventor
Nijenhuis John
Kortlever Ruud
Luc Yvon Brasselet Hugo
Hollmann Frank
Original Assignee
Univ Delft Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Delft Tech filed Critical Univ Delft Tech
Priority to NL2029493A priority Critical patent/NL2029493B1/en
Priority to PCT/NL2022/050600 priority patent/WO2023068933A1/en
Application granted granted Critical
Publication of NL2029493B1 publication Critical patent/NL2029493B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C07D301/16—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof formed in situ, e.g. from carboxylic acids and hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/28—Per-compounds
    • C25B1/30—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/03—Acyclic or carbocyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Claims (9)

Conclusies
1. Werkwijze voor het produceren van organische verbindingen met ten minste een zuurstofatoom in de structuur hiervan, welke werkwijze de stappen omvat van: - het toevoeren van een eerste stroom omvattende CO2 naar een elektrochemische cel; - het in aanraking brengen van ten minste een deel van voornoemd CO2 met een kathode, waardoor ten minste een deel van voornoemd CO2 wordt omgezet in een intermediaire verbinding; - het toevoeren van een tweede stroom omvattende water naar voornoemde elektrochemische cel; - het verschaffen in waterstofperoxide (H202); - het oxideren van ten minste een deel van voornoemde intermediaire verbinding door deze in aanraking te brengen met ten minste een deel van voornoemd waterstofperoxide in aanwezigheid van een enzym, waardoor genoemde organische verbinding wordt geproduceerd.
2. Werkwijze volgens conclusie 1, waarbij voornoemd H202 in situ wordt geproduceerd middels ten minste een van de volgende: - elektrochemische reactie; - enzymatische reactie; - fotochemische reactie; en - uit nucleair afval.
3. Werkwijze volgens conclusie 2, waarbij voornoemd waterstofperoxide wordt verschaft door het in aanraking brengen van ten minste een deel van genoemd water met een anode, waardoor ten minste een deel van voornoemd water wordt omgezet in waterstofperoxide.
4. Werkwijze volgens een der voorgaande conclusies, waarbij H202 wordt geproduceerd in dezelfde cel als waarin het CO2 wordt omgezet in de intermediaire verbinding.
5. Werkwijze volgens conclusie 4, waarbij H202 wordt vervaardigd via anodische wateroxidatie.
6. Werkwijze volgens conclusie 5, waarbij de H202 wordt vervaardigd door het combineren van de kathodische reductie van CO2 en de kathodische reductie van O2.
7. Werkwijze volgens een der voorgaande conclusies, waarbij voornoemde tussenliggende verbinding wordt gekozen uit de groep bestaande uit alkenen, alkanen, alcoholen, aldehyden en combinaties daarvan.
8. Werkwijze volgens een der voorgaande conclusies, waarbij de stap van het oxideren van ten minste een deel van voornoemde tussenliggende verbinding een oxidatiereactie omvat die wordt gekozen uit: - epoxidatie (productie van epoxiden), zoals ethyleenoxide; - hydroxylatie; - Baeyer-Villiger oxidatie (vorming van een ester uit een keton of een aldehyde); en - combinaties hiervan.
9. Werkwijze volgens een der voorgaande conclusies, die een continu proces IS.
NL2029493A 2021-10-22 2021-10-22 Electrochemical process for producing chemicals NL2029493B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NL2029493A NL2029493B1 (en) 2021-10-22 2021-10-22 Electrochemical process for producing chemicals
PCT/NL2022/050600 WO2023068933A1 (en) 2021-10-22 2022-10-24 Electrochemical process for producing chemicals

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL2029493A NL2029493B1 (en) 2021-10-22 2021-10-22 Electrochemical process for producing chemicals

Publications (1)

Publication Number Publication Date
NL2029493B1 true NL2029493B1 (en) 2023-05-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
NL2029493A NL2029493B1 (en) 2021-10-22 2021-10-22 Electrochemical process for producing chemicals

Country Status (2)

Country Link
NL (1) NL2029493B1 (nl)
WO (1) WO2023068933A1 (nl)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3885469A1 (en) * 2020-03-23 2021-09-29 Kabushiki Kaisha Toshiba Carbon dioxide reaction apparatus

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3885469A1 (en) * 2020-03-23 2021-09-29 Kabushiki Kaisha Toshiba Carbon dioxide reaction apparatus

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
BUREK ET AL., GREEN CHEM., vol. 21, 2019, pages 3232 - 3249
CAMPOS-MARTIN, ANGEW. CHEM. INT. ED., vol. 45, 2006, pages 6962 - 6984
HOU, ED., vol. 59, 2020, pages 17356 - 17376
JIN KYOUNGSUK ET AL: "Epoxidation of Cyclooctene Using Water as the Oxygen Atom Source at Manganese Oxide Electrocatalysts", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 141, no. 15, 17 April 2019 (2019-04-17), pages 6413 - 6418, XP055925912, ISSN: 0002-7863, DOI: 10.1021/jacs.9b02345 *
NISHIMI ET AL., EUR. J. ORG. CHEM., 2011, pages 4113 - 4120
RAUCH ET AL., GREEN CHEMISTRY, vol. 19, no. 2, 2017, pages 376 - 379
ZHANG ET AL., ACS CATALYSIS, vol. 10, no. 23, 2020, pages 14195 - 14200, Retrieved from the Internet <URL:https://doi.org/10.1021/acscatal.0c03059>

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Publication number Publication date
WO2023068933A1 (en) 2023-04-27

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