NL2016484A - Prevention of Sb leaching from bottom ash. - Google Patents
Prevention of Sb leaching from bottom ash. Download PDFInfo
- Publication number
- NL2016484A NL2016484A NL2016484A NL2016484A NL2016484A NL 2016484 A NL2016484 A NL 2016484A NL 2016484 A NL2016484 A NL 2016484A NL 2016484 A NL2016484 A NL 2016484A NL 2016484 A NL2016484 A NL 2016484A
- Authority
- NL
- Netherlands
- Prior art keywords
- bottom ash
- suspension
- iii
- green rust
- leaching
- Prior art date
Links
- 239000010882 bottom ash Substances 0.000 title claims abstract description 267
- 238000002386 leaching Methods 0.000 title claims abstract description 81
- 230000002265 prevention Effects 0.000 title description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 98
- 238000000034 method Methods 0.000 claims abstract description 82
- 239000000725 suspension Substances 0.000 claims abstract description 81
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 229910052787 antimony Inorganic materials 0.000 claims description 23
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- 238000004056 waste incineration Methods 0.000 claims description 10
- -1 Fe (III) cations Chemical class 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 8
- 244000005700 microbiome Species 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 5
- 235000015097 nutrients Nutrition 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 67
- 230000002829 reductive effect Effects 0.000 abstract description 21
- 238000011282 treatment Methods 0.000 abstract description 17
- 239000007900 aqueous suspension Substances 0.000 abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 27
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 19
- 230000009467 reduction Effects 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000004411 aluminium Substances 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- 238000007254 oxidation reaction Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 9
- 239000010813 municipal solid waste Substances 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 9
- 230000001681 protective effect Effects 0.000 description 9
- 239000002699 waste material Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000002956 ash Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000005325 percolation Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 235000013980 iron oxide Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000002730 additional effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 2
- 230000003100 immobilizing effect Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 239000012633 leachable Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001507939 Cormus domestica Species 0.000 description 1
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000002479 acid--base titration Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- GLQMDRJYEQDASO-UHFFFAOYSA-N antimony;trihydrate Chemical compound O.O.O.[Sb] GLQMDRJYEQDASO-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- ZYXYTGQFPZEUFX-UHFFFAOYSA-N benzpyrimoxan Chemical compound O1C(OCCC1)C=1C(=NC=NC=1)OCC1=CC=C(C=C1)C(F)(F)F ZYXYTGQFPZEUFX-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000002509 fulvic acid Substances 0.000 description 1
- 229940095100 fulvic acid Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229910052598 goethite Inorganic materials 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003041 laboratory chemical Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/24—Organic substances containing heavy metals
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/43—Inorganic substances containing heavy metals, in the bonded or free state
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/02—Combined processes involving two or more distinct steps covered by groups A62D3/10 - A62D3/40
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Processing Of Solid Wastes (AREA)
Claims (15)
1. Werkwijze voor het verlagen van antimoonuitloging uit bodemas, omvattende: (a) het verschaffen van een waterige suspensie van de bodemas; (b) het mengen van de bodemassuspensie afkomstig uit stap (a) met groene roest en het laten reduceren van Sb(V) tot Sb(III); (c) het introduceren van O2 in het mengsel afkomstig uit stap (b).
2. Werkwijze volgens conclusie 1, waarbij de bodemas afkomstig is uit een afvalverbrandingsinstallatie.
3. Werkwijze volgens conclusie 1 or 2, waarbij de hoeveelheid groene roest zodanig is dat in stap (b) 0.1 - 15 wt% Fe, gebaseerd op drooggewicht van de bodemas, wordt toegevoegd.
4. Werkwijze volgens één der conclusies 1 tot 3, waarbij de groene roest Fe(II) en Fe(III) kationen in een atoomverhouding in het traject 1.5 - 2.5, bij voorkeur 1.9 -2, omvat.
5. Werkwijze volgens één der conclusies 1 tot 4, waarbij het laten reduceren van Sb(V) tot Sb(III) het nemen van stappen om contact van de bodemassuspensie afkomstig uit stap (a) met O2 uit de omgeving te vermijden, bij voorkeur het plaatsen van de suspensie in een luchtdichte omgeving waarbij voorkomen wordt dat gasvorming componenten de omgeving binnentreden, omvat.
6. Werkwijze volgens één der conclusies 1 tot 5, welke verder een Ck-verwijderstap voorafgaand aan stap (b) omvat, waarbij de bodemassuspensie onderworpen wordt aan Ck-verwijdering door middel van (i) het toevoegen van een agens dat O2 vervangt, bij voorkeur een inert gas, (ii) het verschaffen een agens dat met O2 reageert, bij voorkeur A1(0) en/of een Fe(II) zout, of (iii) het toevoegen van een voedingsstof voor aerobe micro-organismen welke suiker omvat, of de bodemassuspensie in zuurstof verarmde vorm verschaft wordt.
7. Werkwijze volgens conclusie 6, waarbij A1(0) uit de bodems zelf verschaft wordt.
8. Werkwijze volgens één der conclusies 1 tot 7, waarbij stap (b) uitgevoerd wordt door het mengen van de bodemassuspensie met een suspensie van groene rust.
9. Werkwijze volgens één der conclusies 1 tot 8, waarbij stap (c) uitgevoerd wordt draineren van een suspensie van bodemas en groene roest en lucht in contact laten komen me de gedraineerde suspensie.
10. Samenstelling omvattende bodemas en groene roest.
11. Samenstelling volgens conclusie 10, waarbij de hoeveelheid groene roest zodanig is dat het 0.1 - 15 wt% Fe, gebaseerd op drooggewicht van de bodemas, verschaft.
12. Samenstelling volgens conclusie 10 of 11, waarbij de bodemas afkomstig is uit een afvalverbrandingsinstallatie.
13. Bodemas verkrijgbaar door de werkwijze volgens één der conclusies 1-9.
14. Bodemas volgens conclusie 13, waarbij de atoomratio Sb(III)/Sb(V) ten minste 9, bij voorkeur ten minste 100 is.
15. Toepassing van een bodemas volgens conclusie 13 of 14 voor open toepassing.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2016484A NL2016484B1 (en) | 2016-03-24 | 2016-03-24 | Prevention of Sb leaching from bottom ash. |
| PCT/EP2017/057066 WO2017162854A1 (en) | 2016-03-24 | 2017-03-24 | Prevention of sb leaching from bottom ash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2016484A NL2016484B1 (en) | 2016-03-24 | 2016-03-24 | Prevention of Sb leaching from bottom ash. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NL2016484A true NL2016484A (en) | 2017-10-02 |
| NL2016484B1 NL2016484B1 (en) | 2017-10-05 |
Family
ID=56027134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL2016484A NL2016484B1 (en) | 2016-03-24 | 2016-03-24 | Prevention of Sb leaching from bottom ash. |
Country Status (2)
| Country | Link |
|---|---|
| NL (1) | NL2016484B1 (nl) |
| WO (1) | WO2017162854A1 (nl) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1026346C2 (nl) * | 2004-01-21 | 2005-07-25 | Insulinde Recycling & Milieu B | Werkwijze voor het binden van zware metalen en/of zware metaalverbindingen in bodemas. |
| WO2005102942A1 (en) * | 2004-04-26 | 2005-11-03 | Mitsubishi Materials Corporation | Reducing water purification material, method for producing reducing water purification material, method for treating wastewater, and wastewater treatment apparatus |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1002461C2 (nl) | 1995-03-10 | 1996-09-24 | Iwaco B V | Werkwijze voor de behandeling van verbrandingsresiduen. |
| EP1948368A2 (en) | 2005-09-26 | 2008-07-30 | Stichting Energieonderzoek Centrum Nederland | Composition comprising active charcoal, steel, slag and contaminated material and use thereof |
| EP1769856A3 (en) | 2005-09-30 | 2013-01-30 | Insulinde Recycling & Milieu B.V. | A process for fixing heavy metals in inorganic materials, particularly MSWI - bottom ash and soil |
| NL2006813C2 (nl) | 2011-05-19 | 2012-11-20 | Bos & Kalis Baggermaatsch | Werkwijze voor het reinigen van verontreinigde bodemas. |
-
2016
- 2016-03-24 NL NL2016484A patent/NL2016484B1/en active
-
2017
- 2017-03-24 WO PCT/EP2017/057066 patent/WO2017162854A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1026346C2 (nl) * | 2004-01-21 | 2005-07-25 | Insulinde Recycling & Milieu B | Werkwijze voor het binden van zware metalen en/of zware metaalverbindingen in bodemas. |
| WO2005102942A1 (en) * | 2004-04-26 | 2005-11-03 | Mitsubishi Materials Corporation | Reducing water purification material, method for producing reducing water purification material, method for treating wastewater, and wastewater treatment apparatus |
Non-Patent Citations (6)
| Title |
|---|
| LEUZ AK ET AL: "Sorption of Sb(III) and Sb(V) to goethite: Influence", ENVIRONMENTAL SCIENCE & TECHNOLOGY, AMERICAN CHEMICAL SOCIETY, US, vol. 40, no. 23, 1 January 2006 (2006-01-01), pages 7277 - 7282, XP008182432, ISSN: 0013-936X * |
| MITSUNOBU ET AL: "Abiotic reduction of antimony(V) by green rust (Fe4(II)Fe2(III)(OH)12SO4.3H2O)", CHEMOSPHERE, PERGAMON PRESS, OXFORD, GB, vol. 70, no. 5, 24 November 2007 (2007-11-24), pages 942 - 947, XP022360846, ISSN: 0045-6535 * |
| SATOSHI MITSUNOBU ET AL: "[mu]-XANES Evidence for the Reduction of Sb(V) to Sb(III) in Soil from Sb Mine Tailing", ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 44, no. 4, 15 February 2010 (2010-02-15), US, pages 1281 - 1287, XP055324593, ISSN: 0013-936X, DOI: 10.1021/es902942z * |
| SATOSHI MITSUNOBU ET AL: "Antimony (V) Incorporation into Synthetic Ferrihydrite, Goethite, and Natural Iron Oxyhydroxides", ENVIRONMENTAL SCIENCE & TECHNOLOGY, AMERICAN CHEMICAL SOCIETY, US, vol. 44, no. 10, 1 January 2010 (2010-01-01), pages 3712 - 3718, XP008182398, ISSN: 0013-936X, [retrieved on 20100428], DOI: 10.1021/ES903901E * |
| SATOSHI MITSUNOBU ET AL: "Behavior of Antimony(V) during the Transformation of Ferrihydrite and Its Environmental Implications", ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 47, no. 17, 5 August 2013 (2013-08-05), US, pages 9660 - 9667, XP055324305, ISSN: 0013-936X, DOI: 10.1021/es4010398 * |
| SATOSHI MITSUNOBU ET AL: "Interaction of Synthetic Sulfate Green Rust with Antimony(V)", ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 43, no. 2, 15 January 2009 (2009-01-15), US, pages 318 - 323, XP055324595, ISSN: 0013-936X, DOI: 10.1021/es8026067 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017162854A1 (en) | 2017-09-28 |
| NL2016484B1 (en) | 2017-10-05 |
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