NL2003136C2

NL2003136C2 - Antenna filter, sensor system and method for measuring a fluid.

Info

Publication number: NL2003136C2
Application number: NL2003136A
Authority: NL
Inventors: Mateo Jozef Jacques Mayer
Original assignee: Stichting Wetsus Ct Excellence Sustainable Water Technology
Priority date: 2009-07-06
Filing date: 2009-07-06
Publication date: 2011-01-10
Also published as: EP2452182A1; WO2011005084A1

Description

ANTENNA FILTER, SENSOR SYSTEM AND METHOD FOR MEASURING A

FLUID

The present invention relates to an antenna filter 5 for measuring a fluid. More specifically, the filter is used for measuring properties of a fluid, like drinking water.

In present practice, for measuring a fluid, samples are often taken and analyzed in laboratories. Such analysis is performed off-line. This results in a time delay 10 before measurement information is available. Furthermore, this practice is relatively labour intensive.

Existing prior art sensors to measure properties of a solution are based on either capacitive or microwave measurements. These techniques suffer from relatively large 15 parasitic capacities thereby limiting the sensitivity of the measurement and/or require a relatively complex measurement set up involving relatively high investment costs.

The object of the present invention is to improve the measuring of a fluid to enable an effective and 20 efficient measurement thereof.

This object is achieved with the antenna filter for measuring a fluid according to the invention, the antenna filter comprising: - a first conductor; and 25 - a second conductor placed at a distance from the first conductor, wherein the distance between the first and second conductors defines a volume that in use holds the fluid to achieve a fluid containing transmission line.

30 By providing a first and second conductor at a distance from each other the volume between the at least two conductors can be filled with a fluid. When in use, the fluid defines a fluid containing transmission line, 2 preferably transmitting a radio frequency signal. The filter comprises a fluid, like water, as dielectricum between the conductors. The characteristics of such filter depend, amongst other things, on the dielectric constant of the 5 fluid. This constant is influenced by the presence of small solid particles, bacteria and also dissolved compounds. This influence can be determined by comparing the supplied broad radio frequency spectrum to the filter with the outgoing signal, for example, preferably as function of time.

10 The antenna filter according to the invention can be used to characterize properties of this fluid, or fluid sample, by measuring the response by a receiver on an input signal from a transmitter. In a presently preferred embodiment of the invention, the dielectric permittivity of 15 the fluid can be deduced from the measured response. The determined dielectric permittivity of the fluid between the first and second conductor is correlated to specific contents, like contaminations and other items mentioned above, in the fluid. This enables on-line measurement of a 20 fluid to determine its contents. In fact, this enables the so-called on-line "fingerprinting" of a fluid. This can be applied in applications including monitoring of water quality, physical separation processes and chemical reactions in process industry. Also, the sensor will be able 25 to detect aggreqates of molecules, such as primary crystals and can be useful to monitor and control crystallization and scaling processes, for example. This results in an effective and efficient manner to measure such fluid.

Depending on the applied input signal for the 30 antenna filter according to the invention, and the measured response thereof, it is shown in experiments that the presence of a broad range of components in the fluid can be detected. Furthermore, also the concentrations of the 3 detected components in the fluid can be determined with the antenna filter according to the present invention as function of the characteristics of the input signal, like amplitude and frequency. This even further improves the 5 possibilities for on-line "fingerprinting" of a fluid in an efficient and effective manner.

In a presently preferred embodiment, the first conductor is provided as a co-axial cable with a solid metal or tubing. This first conductor is surrounded by the second 10 conductor comprising a metal tubing. This results in a relatively compact antenna filter of a co-axial type. As an illustrative explanation for this specific embodiment, below the characteristic impudent of the transmission line is calculated from the diameters of the first inner conductor 15 and second outer conductor with a dielectric permittivity of insulating material 138.2 D Zo — 7 1-9 “7

Vsr ct

Zq - Characteristic impedance [Ohm].

D - Diameter of outer conductor [m].

^ - Diameter of inner conductor [m].

, , , , efluid 20 sr - Relative dielectric permittivity i.e., sr = -, eo where is e fluid = absolute dielectric permittivity of the solution applied as dielectric and £0 = absolute dielectric permittivity of vacuum = 8,85 10 ( —) 25 For a first diameter of 4 mm and second diameter of 32 mm this would result, in case of the fluid being drinking water with a relative dialectic permittivity of 70, in a characteristic impedance of 15 Ohm.

4

With the antenna filter according to the present invention, it is possible to measure a fluid on-line with a relatively high sensitivity, such that specific information on components present in the fluid is available in an 5 effective and efficient manner. This would enable to determine the presence of dissolved components in the fluid, like particles and bacteria, for example. By relating the dielectric permittivity of the fluid and the frequency of the input signal, preferably taking into account the 10 temperature and viscosity of the fluid, information on the presence of different types of particles and/or molecules is provided. Particles and/or molecules each have a specific response to changes in the electric field. This enables measurement of a fluid in an effective and efficient manner. 15 In a preferred embodiment according to the present invention, the antenna filter is an open line quarter wave length co-axial antenna filter.

By providing the filter as a quarter wave length open line co-axial filter, changes in fluid composition can 20 be detected. This is achieved as the resonant frequency of the filter depends on the length of this filter and the dielectric between the first and second conductor, i.e., on the dielectric properties of the fluid between the conductors .

25 In a presently preferred embodiment of the present invention, the quarter wave length antenna filter is provided with a first inner conductor of a co-axial cable with a solid metal or tubing and a second outer conductor provided with metal tubing surrounding the first conductor. 30 This results in a compact filter design.

Preferably, the filter comprises an open end. Such open line filter, that in use is filled with fluid, behaves like a series resonant circuit. Therefore, at resonance, 5 this filter has minimum impedance resulting in "short-circuit" of the signal supplied by the function generator.

As this generator has an internal resistance that is often not negligible, the short-circuit at resonance will result 5 in a potential drop over the system. This drop can be measured by a spectrum analyzer. This results in an effective filter that can be used for measuring a fluid efficiently.

In a preferred embodiment according to the present 10 invention, the inner and/or outer conductors are insulated.

By insulating the inner and/or outer conductors, and most preferably both, the sensitivity of the filter for the measurement of the fluid is improved significantly. In fact, the detection levels of components in the fluid can be 15 relatively low.

In a further preferred embodiment according to the present invention, the filter further comprises a dielectric for adsorbing components in a fluid.

By providing a dielectric in the filter, the 20 sensitivity of the filter can be increased significantly.

These dielectrics adsorb components that are present in the fluid, like water. In one of the presently preferred embodiments of the invention, the dielectric comprises an ion exchange resin. Preferably, this ion exchange resin is 25 provided as spherical particles with a diameter in the range of about 0.1 mm tot 2.5 mm. Such particles can be provided as a dielectric between the first and second conductor of the filter. The particles will adsorb components that are present in the water. Periodically, the fluid feed to the 30 filter is stopped and a detailed analysis of the complex dielectric permittivity as function of frequency can be performed. Next, the observed dielectric behaviour is correlated to the type and concentration of adsorbed 6 components to the particles. This means that the detection levels for the filter for detecting the presence of a specific component in the fluid is lowered. Also, other dielectrics with specific adsorption properties can be 5 applied as alternative to the ion exchange resin.

In a further preferred embodiment according to the present invention, the antenna filter is a flow-through filter .

Providing the filter as a flow-through filter 10 enables on-line measurement of a fluid, thereby preventing the taking of samples of such fluids.

Especially in combination with the use of a dielectric, like the added particles of an ion exchanging resin, between the first and second conductor, such flow-15 through filter is used in an advantageous manner. As the fluid flows through the dielectric the particles will gradually adsorb components that are present in the fluid. This not only prevents the taking of samples, it also further minimizes the detection levels of components in the 20 fluid.

The present invention also relates to a sensor system for measuring a fluid, the system comprising: - an antenna filter as described above; and - a transmitter connected to a receiver through a 25 transmission line.

Such device provides the same effects and advantages as those stated with reference to the antenna filter. In the sensor system, the transmitter provides an input signal, preferably as a broad radio frequency 30 spectrum, to the filter, with the response measured by a receiver and/or spectrum analyser. The transmitter and receiver are connected through a transmission line. The response is a measure of properties of the fluid, like the 7 dielectric permittivity thereof. The measurement can be correlated to the presence of components, and possibly also the concentrations thereof, in the fluid. This provides an effective and efficient sensor system. Experiments have 5 shown that applying an input signal by a transmitter comprising a frequency in the range of 20 MHz to 2 GHz provides optimal results on the detection of components and the concentrations thereof in a fluid.

The present invention further also relates to a 10 method for measuring a fluid, the method comprising the steps of : - providing a sensor system as described above; - supplying the fluid to the filter; - applying a frequency signal from the transmitter 15 to the receiver; and - measuring a response of the applied signal.

Such method provides the same effects and advantages as those stated with reference to the sensor system and filter. By measuring the response of the supplied 20 signal, an indication of at least some of the properties of the fluid is achieved. Preferably, the properties of the fluid comprise the dielectric constant of this fluid. This dielectric constant of the fluid, or more specifically, the dielectric permittivity in preferably different frequency 25 ranges, indicates the presence of a specific component, and preferably also the concentrations thereof, in the fluid. Therefore, the method preferably comprises the step of correlating the measure properties to specific components or contents, and optionally the concentrations thereof, that 30 are present in the fluid. After this correlating of properties to specific contents, the presence of such contents in the fluid can be determined.

8

Further advantages, features and details of the invention are elucidated on basis of preferred embodiments thereof, wherein reference is made to the accompanying drawings, wherein: 5 - Figure 1 illustrates a schematic overview of the filter according to the present invention; - Figure 2 illustrates a schematic overview of a sensor system according to the present invention; - Figure 3 illustrates the electric equivalent of 10 the system of Figure 2; and - Figures 4 to 12 show experimental results with the filter and sensor system according to the present invention .

A filter 2 (Figure 1) comprises a co-axial cable 15 4. Cable 4 comprises a solid metal or tubing 6 that is insulated. Metal or tubing 6 acts a conductor. Around cable 4 is provided a metal tubing 8 that acts as another conductor. Tubing 8 is provided at a distance of cable 4. This distance defines a volume 10 between conductors 6, 8 20 that in use is at least partially filled by a fluid to be measured.

A sensor system 12 (Figure 2) comprises a transmitter 14 that is connected to a receiver 16 through a transmission line 18. Transmission line 18 is connected to 25 the earth 20. Transmission line 18 is further connected to a filter 22. Filter 22 comprises a first conductor 24 that is insulated with insulation material 26 and a second conductor 28. The volume 30 between the conductors 24, 28 is filled with fluid 32.

30 Sensor system 22 can be represented with electrical equivalent 34 (Figure 3). Circuit 34 comprises a function generator 36 and a resistance (Rl) 40. Circuit 34 further comprises filter 42 with a capacitor (C3) 44, 9 inductor (L3) 46 and a resistance (R2) 48. Measurements are performed with a spectrum analyzer 50 comprising a resistance (R3) 52 and analyzer (VM1) 54. It will be understood that this is a simplified representation of the 5 spectrum analyzer 50. Capacitors (Cl) 56 and (C2) 58 represent, together with inductors (LI) 60 and (L2) 62 the 50 Ohm co-axial line from the function generator to the open line filter. Capacitors (C4) 64 and (C5) 66 represent, together with inductors (L4) 68 and (L5) 70, the 50 Ohm co-10 axial line from the filter to the analyzer.

From the electrical equivalent 34 it will be understood that the open line co-axial cable that can be filled with a fluid behaves like a series resonant circuit. This means that this open line co-axial cable has minimum 15 impedance and resonance, resulting in short-circuit of the signals supplied by the function generator. As the function generator has a significant internal resistance, such short-circuit and resonance will result in a potential drop over resistor (R3) that can be measured by the spectrum analyzer 20 50. As the resonant frequency of the filter 42 depends also on the dielectric between inner and outer conductors 24, 32 changes in the water composition will result in changes of the resonant frequency.

By supplying a frequency input signal by the 25 transmitter 14, 36 receiver 16, 50 picks up the response. This response depends, amongst other things, on the characteristics of the filter 12, 42 that is filled with the fluid to be measured. From the response, the dielectric permittivity of the fluid can be determined. This dielectric 30 permittivity is correlated to one or more specific components, and preferably also the concentrations thereof can be detected.

10

Optionally, in volume 30 between the conductors 24, 28 dielectric, preferably shaped as spherical ion exchange resin particles with a diameter in the range of 0.1 - 2.5 mm, is provided to increase the sensitivity of the 5 sensor system 34.

Experiments

Experiments have been performed with the sensor system 12 as illustrated in Figure 2 with the electrical 10 equivalent thereof illustrated in Figure 3. The set-up was such, that in the electrical equivalent thereof R1 = 50 Ohm, R3 = 50 Ohm. Signal generator 36 was HP8657B, analyzer 50 a HP8594E spectrum analyzer. Filter 22, 42 comprises a PVC tube with an internal diameter of 25 mm wherein an insulated 15 conductor 24 was provided with a diameter of 4 mm. The total length of the tube was 130 mm. Also, tubes with a total length of 100 mm and a diameter of 32 mm were used, also containing insulated inner conductor 24 with a diameter of 4 mm. The measurements were performed in a laboratory at a 20 temperature of about 21°C using for the input signal a frequency range of 20 MHz to 2 GHz. In the experiments, the amplitude of the input signal was set to a fixed value. Subsequently, the amplitude of the measured signal by the spectrum analyzer was measured as function of frequency.

25 Figure 4 shows the amplitude versus frequency plot with air and sunflower oil as dielectric in the filter, with the frequency in MHz and the amplitude in mV with measured results for air being indicated with triangles, and for sunflower oil indicated with squares. From the results, it 30 can be seen that the difference between air and sunflower oil, although the relative dielectric permittivities of both substances are relatively close to each other, can be 11 detected. Measured base resonant frequency for air is 590 MHz and for sunflower oil 400 MHz.

Figure 5 shows results of a similar experiment with tap water (indicated with squares) and ethanol 5 (indicated with triangles). From the measurements, it can be concluded that the measured base resonant frequencies for tap water is 210 MHz and for ethanol 220 MHz with the peaks of the next harmonic considerably different for both fluids, i.e. for tap water 620 MHz and for ethanol 720 MHz.

10 The results shown in Figures 4 and 5 clearly indicate that the filter according to the present invention is technically feasible to discriminate between different dielectrics .

Figures 6-9 show results of an amplitude versus 15 frequency plot for tap water (indicated with squares) and tap water with different concentrations of dissolved sodium chlorite (diamonds indicating 0.0427 mol/L NaCl solution, triangles pointing downwards 0.855 mol/L NaCl, triangles pointing upwards 5.128 mol/L NaCl. In the figures the 20 frequencies are shown in MHz and the amplitude in mV.

Figure 6 illustrates an overview of the measured responses, while Figure 7 zooms in on the frequency range of 100 - 300 MHz, Figure 8 to 500 - 800 MHz, and Figure 9 to 850 - 1150 MHz. From the results can be concluded that 25 differences between tap water and water containing different amounts of sodium chlorite can be detected with the filter according to the present invention. Figure 7 shows that in the frequency range of 100 - 300 MHz the resonant frequency of the filter decreases with increasing salt concentration 30 in the water. It is also shown that a minimum of the amplitude of the resonant frequency increases with increasing salt concentrations. This indicates that the quality factor of the quarter wave length open line co-axial 12 filter decreases when salt is added to the tap water used as dielectric. A higher salt concentration results in a higher loss factor due to higher conductivity of the solution.

With a filter having a length of 130 mm, a 5 diameter of 25 mm, a fluid level of 100 mm and an inner conductor that is about 10 mm higher than the fluid level in the filter, another experiment is performed. Results of this experiment are shown in Figure 10 with the freguency in MHz and the amplitude in mV, showing results for tap water 10 (indicated with sguares) and de-ionized water (indicated with diamonds). The experiment was performed at about 20°C with the filter being filled with 40 ml of fluid. This fluid was injected into the antenna filter using an injection syringe, so that the level of the fluid in the filter was 15 the same in all experiments. Figure 10 shows that the difference between both the fluids is detected by a shift of the resonance frequency of the filter.

Figure 11 shows results of another amplitude versus frequency plot with the 25 mm diameter filter for 20 both ethanol (indicated with diamonds) and tap water (indicated with squares). Also, this experiment was performed at about 20°C in the 25 mm diameter filter at a fluid level of 88 mm, which means that the filter contained 35 ml of fluid. The inner conductor was about 22 mm higher 25 than the fluid level in the filter.

Figure 12 shows an additional amplitude versus frequency plot for tap water (indicated with squares) and non-mixed tap water and ethanol (indicated with diamonds) and mixed tap water and ethanol (indicated with triangles), 30 under similar conditions as previous experiments. As shown in this case, the differences between the different fluids can be detected. This indicates the influence of different 13 process conditions under filter performance for measuring a fluid.

The experiments indicate that so-called "fingerprinting" of a fluid can be done by supplying a broad 5 array of frequencies spectrum to the filter and studying the outgoing signal, preferably as a function of time. From the dynamic response of the filter to changing water quality, it is possible to discriminate between solid particles, bacteria and dissolved components.

10 The present invention is by no means limited to the above described embodiments thereof. The protection sought is defined by the following claims, within the scope of which many modifications can be envisaged.

14

Clauses 1. Antenna filter for measuring a fluid, the filter comprising: 5 a first conductor; and a second conductor placed at a distance from the first conductor, wherein the distance between the first and second conductors defines a volume that in use holds the fluid to achieve a fluid containing 10 transmission line.

2. Antenna filter according to clause 1, wherein the filter is an open line quarter wave length coaxial antenna filter.

15 3. Antenna filter according to clause 1 or 2, wherein the filter comprises an open end.

4. Antenna filter according to clause 1, 2 or 3, wherein 20 the first and/or second conductors are insulated.

5. Antenna filter according to any of clauses 1-4, the filter further comprising a dielectric for adsorbing components in the fluid.

25 6. Antenna filter according to clause 5, wherein the dielectric comprises ion exchange resin.

7. Antenna filter according to clause 5 or 6, wherein the 30 dielectric comprises spherical particles with a diameter in the range of 0.1 mm to 2.5 mm.

15 8. Antenna filter according to any of clauses 1-7, wherein the filter is a flow-through filter.

9. Sensor system for measuring a fluid, comprising: 5 an antenna filter according to any of clauses 1-8; and a transmitter connected to a receiver through a transmission line.

10 10.Sensor system according to clause 9, wherein the transmitter applies an input signal comprising a frequency in the range of 20 MHz - 2 GHz.

11. Method for measuring a fluid, comprising the steps of: 15 - providing a sensor system according to clause 9 or 10; supplying the fluid to the filter; applying a frequency signal from the transmitter to the receiver; and 20 - measuring a response of the applied signal.

12. Method according to clause 11, wherein the measured response is a measure for properties of the fluid comprising a dielectric constant of the fluid.

25 13. Method according to clause 11 or 12, further comprising the step of correlating the measured properties to specific components of the fluid.

30 14. Method according to clause 13, further comprising the step of determining the specific components of the fluid.

Claims

An antenna filter for measuring a fluid, the filter comprising: 5. a first conductor; and - a second conductor disposed at a distance from the first conductor, wherein the distance between the first and second conductor defines a volume that in use contains the fluid for realizing a transmission line containing fluid.

Antenna filter according to claim 1, wherein the filter is an open line quartz wavelength coaxial antenna filter. 15

Antenna filter according to claim 1 or 2, wherein the filter comprises an open end.

4. Antenna filter according to claim 1, 2 or 3, wherein the first and / or second conductors are insulated.

Antenna filter according to one or more of claims 1-4, the filter further comprising a dielectric for adsorbing components in the fluid. 25

The antenna filter of claim 5, wherein the dielectric comprising ion exchange resin.

7. An antenna filter according to claim 5 or 6, wherein the dielectric comprising spherical particles with a diameter in the range of 0.1 to 2.5 mm.

Antenna filter according to one or more of claims 1-7, wherein the filter is a flow-through filter.

A sensor system for measuring a fluid, comprising: - an antenna filter according to one or more of claims 1-8; and - a transmitter connected to a receiver by a transmission line. 10

The sensor system of claim 9, wherein the transmitter uses an input signal comprising a frequency in the range of 20 MHz - 2 GHz.

A method for measuring a fluid, comprising the steps of: - providing a sensor system according to claim 9 or 10; - supplying the fluid to the filter; - applying a frequency signal from the transmitter 20 to the receiver; and - measuring a response to the applied signal.

12. Method according to claim 11, wherein the measured response is a measure of properties of fluid comprising a dielectric constant of the fluid.

A method according to claim 11 or 12, further comprising the step of correlating measured properties to specific components of the fluid.

The method of claim 13, further comprising the step of determining the specific components of the fluid.