NL157328B - METHOD OF SEPARATING ACIDS BY DIFFUSION DIALYSIS. - Google Patents

METHOD OF SEPARATING ACIDS BY DIFFUSION DIALYSIS.

Info

Publication number
NL157328B
NL157328B NL7118022A NL7118022A NL157328B NL 157328 B NL157328 B NL 157328B NL 7118022 A NL7118022 A NL 7118022A NL 7118022 A NL7118022 A NL 7118022A NL 157328 B NL157328 B NL 157328B
Authority
NL
Netherlands
Prior art keywords
monomer
film
polymer iii
monomer mixture
vinyl
Prior art date
Application number
NL7118022A
Other languages
Dutch (nl)
Other versions
NL7118022A (en
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Publication of NL7118022A publication Critical patent/NL7118022A/xx
Publication of NL157328B publication Critical patent/NL157328B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

1340970 Production of diffusion dialysis membranes ASAHI GLASS CO Ltd 29 Dec 1971 [29 Dec 1970] 60568/71 Heading C3P [Also in Divisions C2 and B1] An acid diffusion dialysis membrane is prepared by polymerizing a monomer mixture including a monomer I, selected from vinyl benzenes and vinyl pyridines, and a monomer II being a non-conjugated divinyl compound, in the presence of at least one thermoplastic or elastomeric polymer III being swellable in the monomer mixture, to form a film having a thickness of 4-100 microns, and then introducing anion exchange groups into the resulting film. The weight ratio of monomer II to monomer I is preferably 1-25 to 100. The ratio of the polymer III to the monomer mixture is preferably 100-600 to 100. Polymer III may be in the form of a film, which is dipped in the monomer mixture such that it is swelled, and the monomer mixture absorbed therein is then polymerized. Alternatively polymer III may be in the form of a powder or granules, which is admixed with the monomers, formed into a film and polymerized. Polymerization may be brought about by heat/initiator, or by photopolymerization or high energy radiation. Monomer I may be styrene, in which case the ion exchange groups are introduced by halo methylation and then amination. It may also be an ar-halo styrene, in which case amination is only necessary. If monomer I is a vinyl pyridine, quaternization is used. Examples of the divinyl compound II are divinyl benzene, and ethylene glycol diacrylate or -methacrylate. Examples of polymer III are homo- and copolymers of vinyl chloride, vinylidene chloride, ethylene and propylene, and styrene/butadiene rubber, butyl rubber, chlorinated polyethylene rubber, acrylonitrile/butadiene rubber, and chlorosulphonated polyethylene rubber. Polyphenylene oxide is also mentioned. Polymerization may also be in solution, in which case the film is cast.
NL7118022A 1970-12-29 1971-12-29 METHOD OF SEPARATING ACIDS BY DIFFUSION DIALYSIS. NL157328B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12078370A JPS564281B1 (en) 1970-12-29 1970-12-29

Publications (2)

Publication Number Publication Date
NL7118022A NL7118022A (en) 1972-07-03
NL157328B true NL157328B (en) 1978-07-17

Family

ID=14794877

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7118022A NL157328B (en) 1970-12-29 1971-12-29 METHOD OF SEPARATING ACIDS BY DIFFUSION DIALYSIS.

Country Status (5)

Country Link
JP (1) JPS564281B1 (en)
BE (1) BE777489A (en)
FR (1) FR2121077A5 (en)
GB (1) GB1340970A (en)
NL (1) NL157328B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2485395B1 (en) * 1980-06-24 1986-04-11 Commissariat Energie Atomique CATION EXCHANGE MEMBRANE, MANUFACTURING METHOD THEREOF AND APPLICATION AS A SOLID ELECTROLYTE
JPS59182963U (en) * 1983-05-25 1984-12-06 富士通株式会社 printed wiring board
JPS6359377U (en) * 1986-10-07 1988-04-20
JPS6359372U (en) * 1986-10-07 1988-04-20

Also Published As

Publication number Publication date
NL7118022A (en) 1972-07-03
GB1340970A (en) 1973-12-19
BE777489A (en) 1972-06-29
JPS564281B1 (en) 1981-01-29
FR2121077A5 (en) 1972-08-18

Similar Documents

Publication Publication Date Title
US2681320A (en) Permselective films of cationexchange resins
US2681319A (en) Permselective films of anionexchange resins
US3961379A (en) Bioimplantable device from crosslinked, swollen, hydrophilic polymers
GB1091449A (en) A process for the production of thermoplastic moulding compositions
US4137137A (en) Radiation process for the production of graft copolymer to be used for ion-exchange membrane
US3450630A (en) Method of separating metal ions
NL162096B (en) PROCESS FOR PREPARING HOMO OR COPOLYMERS OF VINYL CHLORIDE.
GB1430782A (en) Process for manufacutring amphoteric ion exchange resins
US3392096A (en) Soluble sulfonated vinyl aryl polymers crosslinked with an allyl amine
Chapiro et al. Synthesis of permselective membranes by radiation induced grafting of hydrophilic monomers into poly (tetrafluoroethylene) films
US3674711A (en) Electrically conductive transparent plastic material
NL157328B (en) METHOD OF SEPARATING ACIDS BY DIFFUSION DIALYSIS.
GB1132645A (en) Improving the dyeability of polymers
US3759738A (en) Graft polymeric substrate
ES433865A1 (en) Polycarbonate-polyvinyl chloride moulding compounds
US3081242A (en) Graft co-polymers
Jiang et al. Structures and Properties of Hydrocarbon Ionomer Membranes. 2. Polystyrene-Based Cation Exchangers
CA1132094A (en) Process for improving film of poly (p-methyl-styrene) and copolymers
GB1389115A (en) Graft copolymer and composition thereof
Choi et al. A new preparation method for cation-exchange membrane using monomer sorption into reinforcing materials
ES450268A1 (en) Thermoplastic moulding compositions
GB872217A (en) Improvements in or relating to ion exchange membranes
US2728739A (en) Polymers of n-acrylylpyrrolidine
ES415545A1 (en) Emulsion polymerization of vinyl chloride, and a copolymer of {60 -methyl styrene and acrylic acid ester
JPS5541804A (en) Amphoteric ion exchanger and preparation thereof

Legal Events

Date Code Title Description
V1 Lapsed because of non-payment of the annual fee
NL80 Abbreviated name of patent owner mentioned of already nullified patent

Owner name: ASAHI GLASS