MY179898A - Method for manufacturing ethylene vinyl acetate copolymer for solar cell encapsulant and resin obtained by the same - Google Patents
Method for manufacturing ethylene vinyl acetate copolymer for solar cell encapsulant and resin obtained by the sameInfo
- Publication number
- MY179898A MY179898A MYPI2015703332A MYPI2015703332A MY179898A MY 179898 A MY179898 A MY 179898A MY PI2015703332 A MYPI2015703332 A MY PI2015703332A MY PI2015703332 A MYPI2015703332 A MY PI2015703332A MY 179898 A MY179898 A MY 179898A
- Authority
- MY
- Malaysia
- Prior art keywords
- peroxide
- copolymer resin
- vinyl acetate
- based compound
- weight
- Prior art date
Links
- 239000005038 ethylene vinyl acetate Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000008393 encapsulating agent Substances 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 229920006026 co-polymeric resin Polymers 0.000 abstract 4
- 150000002978 peroxides Chemical class 0.000 abstract 4
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 3
- 239000003999 initiator Substances 0.000 abstract 3
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229950010765 pivalate Drugs 0.000 abstract 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/01—High molecular weight, e.g. >800,000 Da.
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
Provided are a method for manufacturing an ethylene vinyl acetate (EVA) copolymer resin used for a sheet of a solar cell encapsulant, which has a low thermal shrinkage rate and high transparency, by specifically defining a method of feeding monomers to a tubular reactor, and an EVA copolymer resin obtained by the manufacturing method. The method includes feeding 67 to 76 % by weight of an ethylene monomer and 24 to 33 % by weight of a vinyl acetate monomer to only a feed entry part of a tubular reactor, adding a peroxide-based initiator at a content of 50 to 3,000 ppm, the peroxide-based initiator being a peroxide-based initiator mixture of one or more compounds selected from the group consisting of (A) dialkylperoxy dicarbonate-based compound, (B) alkylperoxy pivalate-based compound, (C) alkylperoxy ethylhexanoate-based compound and (D) dialkyl peroxide-based compound, the one or more compounds (A):(B):(C):(D) being in a mixing ratio of e:f:g:h by weight, where e, f, g, and hare in the range of 0 to 8.0, and polymerizing at a temperature of 200 to 300 ?c under a pressure of 2500 to 3000 kg/cm2 for 2 to 20 minutes. The EVA copolymer resin has a Z-average molecular weight (Mz) of 220,000 g/mole or less, a molecular weight distribution (Mw/Mn) of 4.3 or less, and a melt flow index in the range of 6 to 35 g/10 min at 190 ?c under a load of 2.16 kg. Accordingly, the EVA copolymer resin having a low thermal shrinkage rate and high transparency can be provided.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140192285A KR20160080453A (en) | 2014-12-29 | 2014-12-29 | Method for manufacturing ethylene vinyl acetate copolymer for solar cell encapsulant and the resin obtained by the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY179898A true MY179898A (en) | 2020-11-18 |
Family
ID=56132498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI2015703332A MY179898A (en) | 2014-12-29 | 2015-09-22 | Method for manufacturing ethylene vinyl acetate copolymer for solar cell encapsulant and resin obtained by the same |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6173400B2 (en) |
| KR (1) | KR20160080453A (en) |
| CN (1) | CN105732871B (en) |
| ES (1) | ES2575124B1 (en) |
| MY (1) | MY179898A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6933755B2 (en) * | 2019-07-19 | 2021-09-08 | 旭化成株式会社 | Ethylene-vinyl acetate copolymer resin and film |
| CN115991812A (en) * | 2021-10-20 | 2023-04-21 | 中国石油化工股份有限公司 | High molecular weight ethylene-vinyl acetate copolymer emulsion |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4919710B1 (en) * | 1970-06-20 | 1974-05-20 | ||
| DE4227905A1 (en) * | 1992-08-22 | 1994-02-24 | Hoechst Ag | Copolymers of ethylene |
| JP3677131B2 (en) * | 1996-10-30 | 2005-07-27 | 日本ユニカー株式会社 | Process for producing ethylene-vinyl acetate copolymer having excellent heat resistance and mechanical properties |
| DE19754039A1 (en) * | 1997-12-05 | 1999-06-24 | Basf Ag | Process for the production of ethylene copolymers in segmented tubular reactors and use of the copolymers as flow improvers |
| KR100456392B1 (en) * | 2001-02-01 | 2004-11-10 | 미쓰이 가가쿠 가부시키가이샤 | Elastomeric composition for preparing olefinic elastomer crosslinked foam and use thereof |
| KR101187466B1 (en) * | 2010-08-12 | 2012-10-02 | 삼성토탈 주식회사 | Method for manufacturing ethylene vinyl acetate copolymer for solar cell encapsulant and the resin obtained by the same |
| JP5995838B2 (en) * | 2011-04-14 | 2016-09-21 | 三井化学東セロ株式会社 | Solar cell sealing resin sheet, solar cell module using the same, and method for producing the same |
| JP2013159777A (en) * | 2012-02-09 | 2013-08-19 | Asahi Kasei Chemicals Corp | Resin for use in sealing material of solar cell |
| CN102965039A (en) * | 2012-12-17 | 2013-03-13 | 无锡量紫谷新材料科技发展有限公司 | Light-conversion EVA (Ethylene Vinyl-Acetate Copolymer) adhesive film for solar battery and preparation method thereof |
| FR3001832B1 (en) * | 2013-02-06 | 2015-02-20 | Arkema France | USE OF A POLYMERIC FLUID COMPOSITION FOR ENCAPSULATION OF PHOTOVOLTAIC MODULES |
| JP2014192280A (en) * | 2013-03-27 | 2014-10-06 | Toray Ind Inc | Ethylene vinyl acetate copolymer composition for solar cell sealing material sheet, method for manufacturing solar cell sealing material sheet by use thereof, and solar cell sealing material sheet |
-
2014
- 2014-12-29 KR KR1020140192285A patent/KR20160080453A/en active Search and Examination
-
2015
- 2015-09-22 MY MYPI2015703332A patent/MY179898A/en unknown
- 2015-09-24 ES ES201531365A patent/ES2575124B1/en active Active
- 2015-09-25 JP JP2015188765A patent/JP6173400B2/en active Active
- 2015-10-15 CN CN201510667122.0A patent/CN105732871B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160080453A (en) | 2016-07-08 |
| CN105732871A (en) | 2016-07-06 |
| JP6173400B2 (en) | 2017-08-02 |
| JP2016125053A (en) | 2016-07-11 |
| ES2575124A1 (en) | 2016-06-24 |
| CN105732871B (en) | 2018-04-17 |
| ES2575124B1 (en) | 2016-11-24 |
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