MY170240A - Hydrogenation catalyst and hydrogenation process - Google Patents

Hydrogenation catalyst and hydrogenation process

Info

Publication number
MY170240A
MY170240A MYPI20056263A MYPI20056263A MY170240A MY 170240 A MY170240 A MY 170240A MY PI20056263 A MYPI20056263 A MY PI20056263A MY PI20056263 A MYPI20056263 A MY PI20056263A MY 170240 A MY170240 A MY 170240A
Authority
MY
Malaysia
Prior art keywords
catalyst
hydrogenation
oxygenates
disclosed
plant
Prior art date
Application number
MYPI20056263A
Inventor
Hoek Arend
Elisabeth Maria Oud Anna
Lodewijk Maria Dierickx Jan
Kornelis Bijlsma Focco
Joris Antonius Kellendonk Frans
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MY170240A publication Critical patent/MY170240A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A hydrogenation catalyst particularly suitable for hydrogenating oxygenates in a hydrogenation unit of a Fischer-Tropsch plant is disclosed. A preferred embodiment comprises more than 5% and less than 20% nickel based on a wide pore alumina support. The catalyst successfully hydrogenates oxygenates which otherwise tend to poison a catalyst in a hydroconversion unit downstream. Moreover, the temperature at which the unwanted hydrogenolysis of long chain paraffins to methane occurs is higher for one catalyst disclosed herein than a comparable known catalyst. This allows the hydrogenation plant to operate at a higher temperature.
MYPI20056263A 2004-12-31 2005-12-29 Hydrogenation catalyst and hydrogenation process MY170240A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP04107077 2004-12-31

Publications (1)

Publication Number Publication Date
MY170240A true MY170240A (en) 2019-07-11

Family

ID=34930204

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI20056263A MY170240A (en) 2004-12-31 2005-12-29 Hydrogenation catalyst and hydrogenation process

Country Status (2)

Country Link
MY (1) MY170240A (en)
WO (1) WO2006070007A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2203250B1 (en) 2007-10-19 2015-04-08 Shell Internationale Research Maatschappij B.V. Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation
CN112007646A (en) * 2019-05-31 2020-12-01 中国石油化工股份有限公司 Carbon-tetrahydrocarbon full-hydrogenation catalyst, preparation method thereof and carbon-tetrahydrocarbon hydrogenation method

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4212729A (en) * 1978-07-26 1980-07-15 Standard Oil Company (Indiana) Process for demetallation and desulfurization of heavy hydrocarbons
JPS594182B2 (en) * 1979-11-27 1984-01-28 千代田化工建設株式会社 Catalyst for hydrotreating heavy hydrocarbon oil and method for producing the same
US4572778A (en) * 1984-01-19 1986-02-25 Union Oil Company Of California Hydroprocessing with a large pore catalyst
GB8527549D0 (en) * 1985-11-08 1985-12-11 Shell Int Research Supported metal catalysts
EP0584879B1 (en) * 1992-08-25 1997-10-29 Shell Internationale Researchmaatschappij B.V. Process for the preparation of lower olefins
ZA98586B (en) * 1997-02-20 1999-07-23 Sasol Tech Pty Ltd "Hydrogenation of hydrocarbons".
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
GB0126643D0 (en) * 2001-11-06 2002-01-02 Bp Exploration Operating Composition and process
US20040267070A1 (en) * 2003-06-30 2004-12-30 Chevron U.S.A. Inc. Hydrotreating of Fischer-Tropsch derived feeds prior to oligomerization using an ionic liquid catalyst

Also Published As

Publication number Publication date
WO2006070007A1 (en) 2006-07-06

Similar Documents

Publication Publication Date Title
GB0222240D0 (en) Cobalt catalysts
TW200700152A (en) Hydrogenation catalyst and hydrogenation method
FR2895415B1 (en) SELECTIVE HYDROGENATION PROCESS USING A CATALYST HAVING A SPECIFIC SUPPORT
ATE311425T1 (en) CATALYST STRUCTURE AND FISCHER TROPICAL SYNTHESIS PROCESS
ATE278750T1 (en) CATALYST STRUCTURE AND FISCHER TROPICAL SYNTHESIS PROCESS
ATE454213T1 (en) CATALYST AND PRODUCTION PROCESS THEREOF
FR2895416B1 (en) SELECTIVE HYDROGENATION PROCESS USING A SULFIDE CATALYST
GB2418673A (en) Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including fischer-tropsch wax
SG155919A1 (en) An improved process to hydrogenate aromatics present in lube oil boiling range feedstreams
WO2003040263A3 (en) Modified zirconia support for catalyst for fischer-tropsch process
SG164387A1 (en) A selective hydrogenation catalyst and methods of making and using same
EP1142980A3 (en) Process for synthesis of lower isoparaffins from synthesis gas
EP2264128A3 (en) Catalyst structure and method of fischer-tropsch synthesis
EA200800170A1 (en) METHOD OF CONVERSION OF SYNTHESIS GAS IN OXYGENATES CONTAINING C + ALCOHOLS
EA200901636A1 (en) SYSTEM AND METHOD OF HYDROGENIZATION OF ALDEHYDES, KETONES OR THEIR MIXTURES
BR0208328A (en) Method for producing liquid fuels from a hydrocarbon stream
MY146894A (en) Process for hydrorefining fuel base material
TW200712043A (en) Hydrogenation of acetone
MY137042A (en) Hydrogenation palladium-silver catalyst and methods
WO2002051779A3 (en) Method for producing alcohols by hydrogenating carbonyl compounds
MY165564A (en) Hydrocracking catalyst and process for production liquid hydrocarbon
ATE388217T1 (en) HYDROGENATION OF SUSPENDED FUELS WITH BULK CATALYSTS COMPRISING MULTIPLE METALS
FI961532A0 (en) Hydro cracking and hydrodewaxing process
MY145545A (en) Method of treatment of a gas
MY147006A (en) Process for the preparation of linear olefins and use thereof to prepare linear alcohols