MXPA99003721A - Concentrated fabric softening composition - Google Patents
Concentrated fabric softening compositionInfo
- Publication number
- MXPA99003721A MXPA99003721A MXPA/A/1999/003721A MX9903721A MXPA99003721A MX PA99003721 A MXPA99003721 A MX PA99003721A MX 9903721 A MX9903721 A MX 9903721A MX PA99003721 A MXPA99003721 A MX PA99003721A
- Authority
- MX
- Mexico
- Prior art keywords
- methyl
- dimethyl
- pentanediol
- hexanediol
- butanediol
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 306
- 239000004744 fabric Substances 0.000 title claims abstract description 73
- 239000002904 solvent Substances 0.000 claims abstract description 237
- 239000000194 fatty acid Substances 0.000 claims abstract description 50
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 49
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 49
- 150000002009 diols Chemical class 0.000 claims abstract description 48
- 239000002738 chelating agent Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 31
- 239000002979 fabric softener Substances 0.000 claims abstract description 27
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 25
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000000875 corresponding Effects 0.000 claims abstract description 7
- 125000001165 hydrophobic group Chemical group 0.000 claims abstract description 7
- 230000000670 limiting Effects 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 230000003078 antioxidant Effects 0.000 claims abstract description 6
- 230000036935 ClogP Effects 0.000 claims abstract 8
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- -1 group Chemical group 0.000 claims description 380
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 146
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 72
- 239000004480 active ingredient Substances 0.000 claims description 67
- 150000001875 compounds Chemical class 0.000 claims description 58
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 claims description 58
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-Propanediol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 57
- ALQSHHUCVQOPAS-UHFFFAOYSA-N 1,5-Pentanediol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 48
- JCYHHICXJAGYEL-UHFFFAOYSA-N 3-butoxypropane-1,2-diol Chemical compound CCCCOCC(O)CO JCYHHICXJAGYEL-UHFFFAOYSA-N 0.000 claims description 41
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 38
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 38
- WERYXYBDKMZEQL-UHFFFAOYSA-N 1,4-butanediol Substances OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 35
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 34
- 239000002304 perfume Substances 0.000 claims description 29
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000004615 ingredient Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- OGRCRHSHBFQRKO-UHFFFAOYSA-N heptane-1,4-diol Chemical compound CCCC(O)CCCO OGRCRHSHBFQRKO-UHFFFAOYSA-N 0.000 claims description 23
- XTVHTJKQKUOEQA-UHFFFAOYSA-N heptane-2,5-diol Chemical compound CCC(O)CCC(C)O XTVHTJKQKUOEQA-UHFFFAOYSA-N 0.000 claims description 23
- 229960004063 Propylene glycol Drugs 0.000 claims description 22
- NNYOSLMHXUVJJH-UHFFFAOYSA-N heptane-1,5-diol Chemical compound CCC(O)CCCCO NNYOSLMHXUVJJH-UHFFFAOYSA-N 0.000 claims description 22
- 235000013772 propylene glycol Nutrition 0.000 claims description 22
- IOMHEFJNPZANMF-UHFFFAOYSA-N 2-methylheptane-2,6-diol Chemical compound CC(O)CCCC(C)(C)O IOMHEFJNPZANMF-UHFFFAOYSA-N 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 229940035437 1,3-propanediol Drugs 0.000 claims description 20
- BKKAVOLVYULZEM-UHFFFAOYSA-N 2-(2-methylpropyl)propane-1,3-diol Chemical compound CC(C)CC(CO)CO BKKAVOLVYULZEM-UHFFFAOYSA-N 0.000 claims description 20
- GSQFUEPQVUSAPE-UHFFFAOYSA-N 2-methylpentane-2,3-diol Chemical compound CCC(O)C(C)(C)O GSQFUEPQVUSAPE-UHFFFAOYSA-N 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 20
- UQGLNXPQGUMNRU-UHFFFAOYSA-N heptane-1,6-diol Chemical compound CC(O)CCCCCO UQGLNXPQGUMNRU-UHFFFAOYSA-N 0.000 claims description 20
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 20
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 20
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 19
- AUGLSFONVIKZLA-UHFFFAOYSA-N 2-methylheptane-3,5-diol Chemical compound CCC(O)CC(O)C(C)C AUGLSFONVIKZLA-UHFFFAOYSA-N 0.000 claims description 19
- MFBMFHMAWZBOEZ-UHFFFAOYSA-N 6-methylheptane-2,5-diol Chemical compound CC(C)C(O)CCC(C)O MFBMFHMAWZBOEZ-UHFFFAOYSA-N 0.000 claims description 19
- HTXVEEVTGGCUNC-UHFFFAOYSA-N heptane-1,3-diol Chemical compound CCCCC(O)CCO HTXVEEVTGGCUNC-UHFFFAOYSA-N 0.000 claims description 19
- 150000001450 anions Chemical class 0.000 claims description 18
- TXGJTWACJNYNOJ-UHFFFAOYSA-N hexane-2,4-diol Chemical compound CCC(O)CC(C)O TXGJTWACJNYNOJ-UHFFFAOYSA-N 0.000 claims description 18
- OWBTYPJTUOEWEK-UHFFFAOYSA-N 2,3-Butanediol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 17
- IDEOPBXRUBNYBN-UHFFFAOYSA-N 2-methylbutane-2,3-diol Chemical compound CC(O)C(C)(C)O IDEOPBXRUBNYBN-UHFFFAOYSA-N 0.000 claims description 17
- LFWYBPFYLUEUIJ-UHFFFAOYSA-N 4-methylheptane-2,6-diol Chemical compound CC(O)CC(C)CC(C)O LFWYBPFYLUEUIJ-UHFFFAOYSA-N 0.000 claims description 17
- XVEOUOTUJBYHNL-UHFFFAOYSA-N heptane-2,4-diol Chemical compound CCCC(O)CC(C)O XVEOUOTUJBYHNL-UHFFFAOYSA-N 0.000 claims description 17
- POFSNPPXJUQANW-UHFFFAOYSA-N hexane-3,4-diol Chemical compound CCC(O)C(O)CC POFSNPPXJUQANW-UHFFFAOYSA-N 0.000 claims description 17
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (-)-propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 16
- UNVGBIALRHLALK-UHFFFAOYSA-N (±)-1,5-Hexanediol Chemical compound CC(O)CCCCO UNVGBIALRHLALK-UHFFFAOYSA-N 0.000 claims description 16
- XXMIOPMDWAUFGU-UHFFFAOYSA-N 1,6-Hexanediol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 16
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical class CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 claims description 16
- RLWWHEFTJSHFRN-UHFFFAOYSA-N 3-methylpentane-2,3-diol Chemical compound CCC(C)(O)C(C)O RLWWHEFTJSHFRN-UHFFFAOYSA-N 0.000 claims description 16
- FNWJZNQLNMUDGE-UHFFFAOYSA-N 5-methylheptane-2,4-diol Chemical compound CCC(C)C(O)CC(C)O FNWJZNQLNMUDGE-UHFFFAOYSA-N 0.000 claims description 16
- POWFRZFDXPVABI-UHFFFAOYSA-N 6-methylheptane-2,4-diol Chemical compound CC(C)CC(O)CC(C)O POWFRZFDXPVABI-UHFFFAOYSA-N 0.000 claims description 16
- 125000002947 alkylene group Chemical group 0.000 claims description 16
- BQWORYKVVNTRAW-UHFFFAOYSA-N heptane-3,5-diol Chemical compound CCC(O)CC(O)CC BQWORYKVVNTRAW-UHFFFAOYSA-N 0.000 claims description 16
- AVIYEYCFMVPYST-UHFFFAOYSA-N hexane-1,3-diol Chemical compound CCCC(O)CCO AVIYEYCFMVPYST-UHFFFAOYSA-N 0.000 claims description 16
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 16
- 229940083957 1,2-BUTANEDIOL Drugs 0.000 claims description 15
- BMRWNKZVCUKKSR-UHFFFAOYSA-N 1,2-Butanediol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 15
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 15
- ZWNMRZQYWRLGMM-UHFFFAOYSA-N 2,5-dimethylhexane-2,5-diol Chemical compound CC(C)(O)CCC(C)(C)O ZWNMRZQYWRLGMM-UHFFFAOYSA-N 0.000 claims description 15
- ZSCKAEOFRPCEES-UHFFFAOYSA-N 2-(3-methylbutan-2-yl)propane-1,3-diol Chemical compound CC(C)C(C)C(CO)CO ZSCKAEOFRPCEES-UHFFFAOYSA-N 0.000 claims description 15
- YTCRRFFBEJJVLV-UHFFFAOYSA-N 2-butan-2-ylpropane-1,3-diol Chemical compound CCC(C)C(CO)CO YTCRRFFBEJJVLV-UHFFFAOYSA-N 0.000 claims description 15
- DXWLGCKTCQEDOO-UHFFFAOYSA-N 2-methylheptane-2,4-diol Chemical compound CCCC(O)CC(C)(C)O DXWLGCKTCQEDOO-UHFFFAOYSA-N 0.000 claims description 15
- WPIMUZQTFDJTFU-UHFFFAOYSA-N 2-methylheptane-2,5-diol Chemical compound CCC(O)CCC(C)(C)O WPIMUZQTFDJTFU-UHFFFAOYSA-N 0.000 claims description 15
- DKAPFPUUXKLAJO-UHFFFAOYSA-N 3,4-dimethylpentane-2,3-diol Chemical compound CC(C)C(C)(O)C(C)O DKAPFPUUXKLAJO-UHFFFAOYSA-N 0.000 claims description 15
- ZMWAURRHTDCQCX-UHFFFAOYSA-N 3-methylheptane-2,4-diol Chemical compound CCCC(O)C(C)C(C)O ZMWAURRHTDCQCX-UHFFFAOYSA-N 0.000 claims description 15
- RNKURRDNOYXATR-UHFFFAOYSA-N 4-methylpentane-2,3-diol Chemical compound CC(C)C(O)C(C)O RNKURRDNOYXATR-UHFFFAOYSA-N 0.000 claims description 15
- IVDFJHOHABJVEH-UHFFFAOYSA-N Pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 claims description 15
- OZIMXLFSRSPFAS-UHFFFAOYSA-N heptane-2,6-diol Chemical compound CC(O)CCCC(C)O OZIMXLFSRSPFAS-UHFFFAOYSA-N 0.000 claims description 15
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 15
- QCIYAEYRVFUFAP-UHFFFAOYSA-N hexane-2,3-diol Chemical compound CCCC(O)C(C)O QCIYAEYRVFUFAP-UHFFFAOYSA-N 0.000 claims description 15
- VWRMHWAYIOHUNG-UHFFFAOYSA-N 3-methylheptane-2,6-diol Chemical compound CC(O)CCC(C)C(C)O VWRMHWAYIOHUNG-UHFFFAOYSA-N 0.000 claims description 14
- INVGCXXCVPGTOA-UHFFFAOYSA-N 4-methylheptane-2,5-diol Chemical compound CCC(O)C(C)CC(C)O INVGCXXCVPGTOA-UHFFFAOYSA-N 0.000 claims description 14
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 14
- PKJRYBRCZGCXPB-UHFFFAOYSA-N 2,3,4-trimethylpentane-1,4-diol Chemical compound OCC(C)C(C)C(C)(C)O PKJRYBRCZGCXPB-UHFFFAOYSA-N 0.000 claims description 13
- GVIOYVUZPOGQQP-UHFFFAOYSA-N 2-methyl-3-propan-2-ylbutane-1,4-diol Chemical compound CC(C)C(CO)C(C)CO GVIOYVUZPOGQQP-UHFFFAOYSA-N 0.000 claims description 13
- AREOBENUACTGHH-UHFFFAOYSA-N 3-methylheptane-3,5-diol Chemical compound CCC(O)CC(C)(O)CC AREOBENUACTGHH-UHFFFAOYSA-N 0.000 claims description 13
- NKWKZLRCUPYPSO-UHFFFAOYSA-N 5-methylheptane-2,5-diol Chemical compound CCC(C)(O)CCC(C)O NKWKZLRCUPYPSO-UHFFFAOYSA-N 0.000 claims description 13
- 238000006065 biodegradation reaction Methods 0.000 claims description 13
- 239000006260 foam Substances 0.000 claims description 13
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 claims description 13
- MVHBECGZHRZJKG-UHFFFAOYSA-N 2,3,4-trimethylpentane-2,4-diol Chemical compound CC(O)(C)C(C)C(C)(C)O MVHBECGZHRZJKG-UHFFFAOYSA-N 0.000 claims description 12
- JANSZBDMCKVQEK-UHFFFAOYSA-N 2,5-dimethylhexane-2,4-diol Chemical compound CC(C)C(O)CC(C)(C)O JANSZBDMCKVQEK-UHFFFAOYSA-N 0.000 claims description 12
- LNCZPZFNQQFXPT-UHFFFAOYSA-N 2-phenylpropane-1,2-diol Chemical compound OCC(O)(C)C1=CC=CC=C1 LNCZPZFNQQFXPT-UHFFFAOYSA-N 0.000 claims description 12
- VVOISBSEMFDYNE-UHFFFAOYSA-N 2-propan-2-ylpropane-1,3-diol Chemical compound CC(C)C(CO)CO VVOISBSEMFDYNE-UHFFFAOYSA-N 0.000 claims description 12
- CFEPFAMBMGCTQM-UHFFFAOYSA-N 3,3-dimethylpentane-1,5-diol Chemical compound OCCC(C)(C)CCO CFEPFAMBMGCTQM-UHFFFAOYSA-N 0.000 claims description 12
- YRDZJWZHGKDMBL-UHFFFAOYSA-N 5-methylhexane-2,4-diol Chemical compound CC(C)C(O)CC(C)O YRDZJWZHGKDMBL-UHFFFAOYSA-N 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 12
- QVTWBMUAJHVAIJ-UHFFFAOYSA-N hexane-1,4-diol Chemical compound CCC(O)CCCO QVTWBMUAJHVAIJ-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- XLMFDCKSFJWJTP-UHFFFAOYSA-N pentane-2,3-diol Chemical compound CCC(O)C(C)O XLMFDCKSFJWJTP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 12
- YHSJEDVJYGRFHX-UHFFFAOYSA-N 1-(2-hydroxyethyl)cyclohexan-1-ol Chemical compound OCCC1(O)CCCCC1 YHSJEDVJYGRFHX-UHFFFAOYSA-N 0.000 claims description 11
- PTXIOWUPCBAQBY-UHFFFAOYSA-N 1-(4-methylphenyl)propane-1,3-diol Chemical compound CC1=CC=C(C(O)CCO)C=C1 PTXIOWUPCBAQBY-UHFFFAOYSA-N 0.000 claims description 11
- OQGDYHLGWMRXBL-UHFFFAOYSA-N 2,3-dimethylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)(C)O OQGDYHLGWMRXBL-UHFFFAOYSA-N 0.000 claims description 11
- GCQIRPJZONARRR-UHFFFAOYSA-N 2,4-dimethylpentane-2,3-diol Chemical compound CC(C)C(O)C(C)(C)O GCQIRPJZONARRR-UHFFFAOYSA-N 0.000 claims description 11
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-Methyl-2,4-pentanediol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 11
- SXWAHMJCEARPFM-UHFFFAOYSA-N 2-butan-2-ylbutane-1,3-diol Chemical compound CCC(C)C(CO)C(C)O SXWAHMJCEARPFM-UHFFFAOYSA-N 0.000 claims description 11
- IFPWAVCXUHSXDW-UHFFFAOYSA-N 2-ethyl-3-methylbutane-1,4-diol Chemical compound CCC(CO)C(C)CO IFPWAVCXUHSXDW-UHFFFAOYSA-N 0.000 claims description 11
- XCTVTCALBXLITL-UHFFFAOYSA-N 2-methylhexane-2,4-diol Chemical compound CCC(O)CC(C)(C)O XCTVTCALBXLITL-UHFFFAOYSA-N 0.000 claims description 11
- ULJJXDAGVBDQBJ-UHFFFAOYSA-N 3,3-dimethylhexane-2,4-diol Chemical compound CCC(O)C(C)(C)C(C)O ULJJXDAGVBDQBJ-UHFFFAOYSA-N 0.000 claims description 11
- PXNAPGDENOWLRW-UHFFFAOYSA-N 3,4-dimethylhexane-2,5-diol Chemical compound CC(O)C(C)C(C)C(C)O PXNAPGDENOWLRW-UHFFFAOYSA-N 0.000 claims description 11
- OORRBWLVIVLEFE-UHFFFAOYSA-N 3-methylheptane-2,5-diol Chemical compound CCC(O)CC(C)C(C)O OORRBWLVIVLEFE-UHFFFAOYSA-N 0.000 claims description 11
- LRBAFUJEQQGGBH-UHFFFAOYSA-N 4-ethylhexane-2,4-diol Chemical compound CCC(O)(CC)CC(C)O LRBAFUJEQQGGBH-UHFFFAOYSA-N 0.000 claims description 11
- FWDSFJJVDRVTJZ-UHFFFAOYSA-N 4-methylheptane-2,4-diol Chemical compound CCCC(C)(O)CC(C)O FWDSFJJVDRVTJZ-UHFFFAOYSA-N 0.000 claims description 11
- 150000002170 ethers Chemical class 0.000 claims description 11
- RUOPINZRYMFPBF-UHFFFAOYSA-N pentane-1,3-diol Chemical compound CCC(O)CCO RUOPINZRYMFPBF-UHFFFAOYSA-N 0.000 claims description 11
- GLOBUAZSRIOKLN-UHFFFAOYSA-N pentane-1,4-diol Chemical compound CC(O)CCCO GLOBUAZSRIOKLN-UHFFFAOYSA-N 0.000 claims description 11
- IPUNFZAUNSJGPB-UHFFFAOYSA-N 2,2,3-trimethylbutane-1,4-diol Chemical compound OCC(C)C(C)(C)CO IPUNFZAUNSJGPB-UHFFFAOYSA-N 0.000 claims description 10
- UGRRTZQNTWNFSI-UHFFFAOYSA-N 2,2,3-trimethylpentane-1,3-diol Chemical compound CCC(C)(O)C(C)(C)CO UGRRTZQNTWNFSI-UHFFFAOYSA-N 0.000 claims description 10
- UPQBAPMBTTWGMM-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,4-diol Chemical compound CC(C)(O)CC(C)(C)CO UPQBAPMBTTWGMM-UHFFFAOYSA-N 0.000 claims description 10
- SKQUTIPQJKQFRA-UHFFFAOYSA-N 2,3-dimethylbutane-1,4-diol Chemical compound OCC(C)C(C)CO SKQUTIPQJKQFRA-UHFFFAOYSA-N 0.000 claims description 10
- QBCWFJLMSMULOG-UHFFFAOYSA-N 2,3-dimethylhexane-2,5-diol Chemical compound CC(O)CC(C)C(C)(C)O QBCWFJLMSMULOG-UHFFFAOYSA-N 0.000 claims description 10
- MHNYUMPVQKTSLK-UHFFFAOYSA-N 2,4-dimethylhexane-2,4-diol Chemical compound CCC(C)(O)CC(C)(C)O MHNYUMPVQKTSLK-UHFFFAOYSA-N 0.000 claims description 10
- BBOMJCSSXWZKGW-UHFFFAOYSA-N 2,4-dimethylhexane-2,5-diol Chemical compound CC(O)C(C)CC(C)(C)O BBOMJCSSXWZKGW-UHFFFAOYSA-N 0.000 claims description 10
- PMYMNKGSHYYMNT-UHFFFAOYSA-N 2-pentan-3-ylpropane-1,3-diol Chemical compound CCC(CC)C(CO)CO PMYMNKGSHYYMNT-UHFFFAOYSA-N 0.000 claims description 10
- XWFCJSXTVSOIDN-UHFFFAOYSA-N 2-propan-2-ylbutane-1,4-diol Chemical compound CC(C)C(CO)CCO XWFCJSXTVSOIDN-UHFFFAOYSA-N 0.000 claims description 10
- DQCNVHDYCALYIF-UHFFFAOYSA-N 3,3-dimethylhexane-2,5-diol Chemical compound CC(O)CC(C)(C)C(C)O DQCNVHDYCALYIF-UHFFFAOYSA-N 0.000 claims description 10
- MXBAXTVFBBFNGU-UHFFFAOYSA-N 3,5-dimethylhexane-2,4-diol Chemical compound CC(C)C(O)C(C)C(C)O MXBAXTVFBBFNGU-UHFFFAOYSA-N 0.000 claims description 10
- PMORVUNYTOZCSE-UHFFFAOYSA-N 3-methylhexane-2,5-diol Chemical compound CC(O)CC(C)C(C)O PMORVUNYTOZCSE-UHFFFAOYSA-N 0.000 claims description 10
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 claims description 10
- UPZJPQJUBMOPKQ-UHFFFAOYSA-N 4,5-dimethylhexane-2,4-diol Chemical compound CC(O)CC(C)(O)C(C)C UPZJPQJUBMOPKQ-UHFFFAOYSA-N 0.000 claims description 10
- MTPUFPIZVDRORX-UHFFFAOYSA-N 5,5-dimethylhexane-2,4-diol Chemical compound CC(O)CC(O)C(C)(C)C MTPUFPIZVDRORX-UHFFFAOYSA-N 0.000 claims description 10
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 10
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N butylene glycol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 10
- 239000003021 water soluble solvent Substances 0.000 claims description 10
- UZOYKBBAMVVEMJ-UHFFFAOYSA-N 1-(3-methylphenyl)propane-1,3-diol Chemical compound CC1=CC=CC(C(O)CCO)=C1 UZOYKBBAMVVEMJ-UHFFFAOYSA-N 0.000 claims description 9
- BGZGQDDKQNYZID-UHFFFAOYSA-N 1-(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1(O)CCCCC1 BGZGQDDKQNYZID-UHFFFAOYSA-N 0.000 claims description 9
- BBWBGVJEDBJKEO-UHFFFAOYSA-N 2,2,3-trimethylpentane-1,4-diol Chemical compound CC(O)C(C)C(C)(C)CO BBWBGVJEDBJKEO-UHFFFAOYSA-N 0.000 claims description 9
- GPLLBLPMTRGQIX-UHFFFAOYSA-N 2,3,3-trimethylpentane-1,4-diol Chemical compound CC(O)C(C)(C)C(C)CO GPLLBLPMTRGQIX-UHFFFAOYSA-N 0.000 claims description 9
- KOHSZBUMEHKSDK-UHFFFAOYSA-N 2,3-dimethylhexane-2,4-diol Chemical compound CCC(O)C(C)C(C)(C)O KOHSZBUMEHKSDK-UHFFFAOYSA-N 0.000 claims description 9
- HNIDTKCNPXBSLD-UHFFFAOYSA-N 2,3-dimethylpentane-2,3-diol Chemical compound CCC(C)(O)C(C)(C)O HNIDTKCNPXBSLD-UHFFFAOYSA-N 0.000 claims description 9
- TWWHGHSCTCMSRB-UHFFFAOYSA-N 2-(2-methylbutan-2-yl)propane-1,3-diol Chemical compound CCC(C)(C)C(CO)CO TWWHGHSCTCMSRB-UHFFFAOYSA-N 0.000 claims description 9
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- MSRXHJALEMAKGB-UHFFFAOYSA-N 2-butan-2-yl-2-methylpropane-1,3-diol Chemical compound CCC(C)C(C)(CO)CO MSRXHJALEMAKGB-UHFFFAOYSA-N 0.000 claims description 9
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- 229930003799 tocopherols Natural products 0.000 description 1
- IMRYETFJNLKUHK-UHFFFAOYSA-N traseolide Chemical compound CC1=C(C(C)=O)C=C2C(C(C)C)C(C)C(C)(C)C2=C1 IMRYETFJNLKUHK-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- QYWVQMLYIXYLRE-SEYXRHQNSA-N trimethyl-[(Z)-octadec-9-enyl]azanium Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C QYWVQMLYIXYLRE-SEYXRHQNSA-N 0.000 description 1
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-O trimethylammonium Chemical compound C[NH+](C)C GETQZCLCWQTVFV-UHFFFAOYSA-O 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- OFHHDSQXFXLTKC-UHFFFAOYSA-N undec-10-enal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 description 1
- 235000021081 unsaturated fats Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 235000021307 wheat Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- LUZDYPLAQQGJEA-UHFFFAOYSA-N Β-Naphthol methyl ether Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 1
- UZFLPKAIBPNNCA-BQYQJAHWSA-N α-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 description 1
Abstract
Principal solvents, especially mono-ol and diol principal solvents, having a ClogP of from about 0. 15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, are disclosed that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of fabric softener actives having highly unsaturated hydrocarbon moieties or branched chains in two long-chain hydrophobic groups with specific cis/trans ratios and having long chain hydrocarbon groups with an IV of from about 70 to about 140 for the unsaturated groups corresponding to fatty acids with the same number of carbons and the same configuration, and the said principal solvents are used at levels of less than about 40%. The fabric softener actives are preferably prepared in the presence of chelating agent and/or antioxidant, as disclosed herein. Such materials are new. Other solvents can be present. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating.
Description
COMPOSITION CONCENTRATED FABRIC SOFTENER
TECHNICAL FIELD
The present invention relates to liquid softening compositions preferably translucent, or, more preferably, transparent, aqueous, concentrated, useful for softening clothes. This refers in particular to fabric softening compositions for use in the cycle
^? rinsing of a textile washing operation to provide excellent fabric softening / static control benefits, the compositions being characterized by, for example, fabric stain reduction, excellent water dispersibility,
soaking, and / or storage stability and viscosity a
^ Sub-normal temperatures, that is, temperatures below normal room temperature, for example, 25 ° C.
BACKGROUND OF THE INVENTION 20 Concentrated transparent compositions containing fabric softening active ingredients, bound with ester and / or amide are discussed in the pending application serial number 08 / 679,694, filed on 11
July 1996 on behalf of B.H. Wahl, T. Trinh, E.P. Gosselink, J.C. Letton, and MR Sivik, referring to Composition / Softening Compound "of Fabrics, wherein said application is incorporated herein by reference 5 The active fabric softening ingredients in said applications are all biodegradable materials bonded to ester containing, as groups long hydrophobes ^ unsaturated and branched chains.
BRIEF DESCRIPTION OF THE INVENTION
The compositions herein comprise: A. From about 2% to 80% of fabric softening active ingredient containing at least two groups
hydrocarbyl of 6 to 22 carbon atoms, but not more than one ^ has less than 12 carbon atoms and the other has at least 16 carbon atoms, the groups have a VY of about 70 to 140, or branched; and B. Less than 40% by weight of the main solvent composition has a ClogP from about 0.15 to 0.64, and at least some degree of asymmetry, said main solvent contains insufficient amounts of solvents selected from the group consisting of 2, 2 , 4-trimethyl-l, 3-pentanediol; loa derivatives ethoxylate, diethoxylate or
2, 2,4-trimethyl-1,3-pentanediol triethoxylate; and / or 2-ethylhexyl-l, 3-diol, to provide a stable aqueous composition by itself, being sufficient. said principal solvent to make the compositions transparent. Preferably, the compositions are stable, transparent, aqueous fabric softening compositions containing: A. About 2% to 80%, preferably near
13% to 75%, more preferable about 17% to 70%, and even more
^ P preferable about 19% to 65%, by weight of the composition, of cationic fabric softener active ingredient, which is selected from: (1) Softener with the formula:
• where each m is 2 or 3, each R1 is from 6 to 22 carbon atoms, preferably from 14 to 20 carbon atoms, but no more than one has less than about 12
carbon atoms and then the other is at least about 16, hydrocarbyl, or substituted hydrocarbyl substituent, preferably alkyl or alkenyl of 10 to 20 carbon atoms (unsaturated alkyl, including polyunsaturated alkyl, also sometimes referred to as "alkylene") ,
much more preferable alkyl or alkenyl of 12 to 18 carbonates, and where the Iodine Value (hereinafter referred to as "VY") of a fatty acid containing this group Rl
"about" is from 70 to 140, more preferable about 80 ~ to 5 130, and much preferable about 90 to 115 (as used herein, the term "Iodine Value" means the Iodine Value of a fatty acid "predecessor" ", or corresponding" fatty acid "which is used to define a level of unsaturation for a group R1 which is the same as the level of unsaturation that
^ would be present in a fatty acid containing the same group R1) with, preferably, a cis / trans ratio of from about 4: 1 to 50: 1, the minimum being 1: 1, preferably from about 2: 1 to 40 : 1, more preferably from about 3: 1 to 30: 1, and even more preferable from about 4: 1 to 15 20: 1; each R1 may also preferably be a group
^ P branched chain alkyl of 14 to 22 carbon atoms; preferably a branched group of 16 to 18 carbon atoms; each R is H or a short chain alkyl or hydroxyalkyl group of 1 to 6 carbon atoms, preferably 20 to 3 carbon atoms, for example, methyl (most preferred), ethyl, propyl, hydroxyethyl, and the like, benzyl or (R20) 2 ~ IH wherein each R2 is an alkylene group of 1 to 6 carbon atoms; and A "is a softening anion compatible, preferably, chloride, bromide, methylsulfate.
etiisulfate, sulfate and nitrate, more preferably chloride and methylisulfate; (2) Softener with the formula:
wherein each R, R1 and A "has the definitions given above, each R2 is an alkylene group of 1 to 6 carbon atoms, preferably an ethylene group, and G is an oxygen atom or a group -NR-, - ( 3) Softener with the formula:
wherein R1, R2 and G are defined as above;
(4) Reaction products of substantially unsaturated and / or branched higher fatty acids with dialkylenetriamines in, for example, an approximate molecular ratio of 2: 1, said reaction products contain compounds of the formula:
R1-C (0) -NH-R -NH-R3-NH-C (0) -R1
wherein R1, R2 are defined as above, and each R3 is an alkylene group of 1 to 6 carbon atoms, preferably an ethylene group; (5) Softener with the formula:
[R ^ CtO) -NR-R2-N (R) 2 -R3-NR-C (0) -R1] + A "
previously; (6) the reaction product of unsaturated and / or branched top fatty acid with hydroxyalkylethylenediamines in a molecular ratio of about 2: 1, said reaction products contain compounds of the formula:
R1-C (0) -NH-R2-N (R3OH) -C (0) -R1
wherein R1, R and R3 are defined as above; (7) Softener with the formula:
2AC
wherein R, R, R and A "are defined as above, and (8) mixtures thereof; ^ B. Less than about 40%, preferably near
10% to 35%, more preferably from about 12% to 25%, and even more preferably from about 14% to 20% by weight of the main solvent composition having a ClogP of about 0.15 to 0.64, preferably near 0.25 a
0. 62, and more preferable about 0.40 to 0.60, said solvent
Main contains insufficient amounts of solvents selected from the group consisting of: 2,4-trimethyl-l, 3-pentanediol; and / or 2-ethyl-l, 3-hexanediol, and / or mixtures thereof, when used alone, to provide a transparent product, preferably insufficient for
provide a stable product, more preferable
^ P insufficient to provide a detectable change in the physical characteristics of the composition, and especially completely free thereof, and the main solvent being preferably selected from the group consisting of
in: I. Mono-oles that include: a. n-propanol and / or b. 2-butanol and / or 2-methyl-2-propanol;
II. Isomers of hexadiiol including: 2,3-dimethyl-2,3-butanediol; 2, 3-dimet l-l, 2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2, 3-pentanediol; 3-methyl-2,3
^ pentanediol; 4-methyl -2,3-pentanediol; 2, 3-hexanediol; 3,4- 5-hexanediol, 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol, 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and / or 1,2-hexanediol III. Isomers of heptanediol including: 2-butyl-1,3-propanediol; 2, 2-diethyl-l, 3-propanediol; 2- (1- ^ P methylpropyl) -1,3-propanediol; 2- (2-met? Lpropyl) -1,3-propanediol; 2- (2-methylpropyl) -1,3-propanediol; 2-methyl-2-propyl-1, 3-propanediol; 2, 3, 3-trimethyl-1,2-butanediol, -2- et? L-2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-l, 4-butanediol; 2-isopropyl -1,4-butanediol; 2,2- 15 dimethyl-1,5-pentanediol; 2, 3-dimethyl-l, 5-pentanediol; 2,4- ^ P dimethyl-1,5-pentanediol; 3, 3-dimet? L-l, 5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4, 4-dimethyl-2,3-pentanediol; 2,3-dimethyl3,4-pentanediol, 2-ethyl-l, 5-pentanodol; 2-methyl-1-6-20 hexanediol; 3-methyl-l, 6-hexanediol; 2-methyl-2,3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2, 3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3, 4-hexanediol; 3-methyl-3, 4-hexanediol; 1,3-heptane diol; 1, 4-heptanod ol; 1,5-heptanediol, - and / or 1,6-heptanediol;
IV. Octane diol isomers, including: 2- (2-methylbutyl) -1,3-propanediol; 2- (1,1-dimethylpropyl) -1,3-propanediol; 2- (1,2-dimethylpropyl) -1,3-propanediol; 2- (1- ethylpropyl) -1,3-propanediol; 2- (1-methylbutyl) -1,3-propanediol; 2- (2, 2-dimethylpropyl) -1,3-propanediol; 2- (3-methylbutyl) -1,3-propanediol; 2-butyl-2-methyl-l, 3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-methylpropyl) -1,3-propanediol; 2- ^ 1 butyl-tertiary-2-methyl-1,3-propanediol; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) -1,3-butanediol; 2-butyl-l, 3-butanediol; 2-ethyl-2, 3-dimethyl-l, 3-butanediol; 2- (1,1-dimethyl-ethyl) -1,3-butane-diol; 2- (2-methylpropyl) -1,3-butanediol; 2-methyl-2-isopropyl-l, 3-butanediol; 2-methyl-2-15 propyl -1, 3 -butanediol; 3-methyl-2-isopropyl-l, 3-butanediol;
^ 2-methyl-2-propyl-l, 3-butanediol; 3-methyl-2-isopropyl-l, 3-butanediol; 3-methyl-2-propyl-l, 3-butanediol; 2, 2-diethyl-l, 4-butanediol; 2-methyl-2-propyl-l, 4-butanediol; 2 (1-methylpropyl) -1,4-butanediol; 2-ethyl-2, 3-dimethyl-1,4-20-butanediol; 2-ethyl-3, 3-dimethyl-1,4-butanediol; 2- (1, 1-dimethylethyl) -1,4-butanediol; 2- (2-methylpropyl) -1,4-butanediol; 2- (1,1,1-dimethylethyl) -1,4-butanediol; 2- (2-methylpropyl) -1,4-butanediol; 2-methyl-3-propyl-l, 4-butanediol; 3-methyl-2-isopropyl-1,4-butanediol; 2,2,3-
trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2, 3, 4 -trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3, 4, 4-trimethyl-1,3-pentanediol; 2, 2, 3-trimethyl-β-1,4-pentanediol; 2, 2, 4-trlmethyl-l, 4-pentanediol; 2,3,3- 5 trimethyl-1,4-pentanediol; 2, 3, 4-trimethyl-1,4-pentanediol; 3,3, 4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2, 2, 4 -trimethyl-1,5-pentanediol; 2, 3, 3-trimethyl-1,5-pentanediol; 2, 3, 4-trimethyl-l, 5-pentanediol; 2,3,3-trimethyl-2,4-pentanediol; 2, 3, 4 -trimethyl-2,4-pentanediol; 2-fl ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-3-methyl-l, 3-pentanediol; 2-ethyl-4-methyl-l, 3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-l-methyl-l, 4-pentanediol; 3- ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,4-15 pentanediol; 2-ethyl-2-methyl-l, 5-pentanediol; 2-ethyl-3-methyl- ^ P 1, 5-pentanediol; 2-ethyl-4-methyl-l, 5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2- isopropy1-1, 3-pentanediol; 2-propyl-1, 3-pentanediol; 2- isopropyl-1,4-pentanediol; 2-propyl -1,4-pentanediol; 3- 20 isopropyl-1,4-pentanediol; 2-isopropyl-l, 5-pentanediol; 3- propyl-2,4-pentanediol; 2, 2-dimethyl-l, 3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-l, 3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3, 4-dimethyl-l, 3-hexanodisl; 3,5-dimethyl-l, 3-hexanediol; 4, 5-dimethyl-l, 3-hexanediol; 2,2-
dimethyl 1, 4-he? anodol; 2, 3-dimethyl-1,4-hexanediol 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanedione; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol 5-dimethyl-1,4-hexanediol; 4, 4-dimet? L-l, 3-hexanediol 5-d? Met? L-1,4-hexanod? Ol; 5, 5-dimethyl-1,4-hexanediol 2-dimethyl-1,5-hexanedione; 2, 3-dimethyl-l, 5-hexanediol 4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol 3-dimethyl-1,1-hexanediol; 3,4-dimethyl-1, 5-hexanediol 5-dimethyl-1,5-hexanediol; 4,5-dimethyl? -1-, 5-hexanediol 2-dimethyl-1,6-hexanediol; 2, 3-dimethyl-l, 6-hexanediol 4-dimethyl-1,6-hexanediol; 2,5-dimethyl-1,6-hexanediol 3-dimethyl-1,6-hexanediol; 3,4,4-dimethyl-1,6-hexanediol 3-dimethyl-2,4-hexanedione; 2,4-dimethyl-2,4-hexanediol 5-d? Met? L-2,4-hexanod? Ol; 3, 3-dimethyl -2,4-hexanediol 4-dimethyl-2,4-hexanediol; 3, 5-dimethyl-2,4-hexanediol 5-dimethyl-2,4-hexanediol; 5, 5-dimethyl-2,4-hexanediol 3-dimethyl-2,5-hexanediol, -2,4-dimethyl-2,5-hexanediol 5-d? Met? L-2,5-hexanediol; 3, 3-dimethyl-2, 5-hexanediol 4-dimethyl-2,5-hexanediol; 3, 3-dimethyl-2,6-hexanediol; 2-ethyl 1,3-hexanediol; 4-ethyl-1, 3-hexanediol; 2-ethyl-1,4-hexanediol; 4-ethyl-l, 4-hexanediol; 2-ethyl-l, 5-hexanediol; 3 et? L-2,4-hexanod? Ol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-l, 3-heptanediol; 3-met? L-l, 3 heptanediol; 4-met? L-l, 3-heptanediol; 5-methyl-l, 3
heptanediol; 6-methyl-1, 3-heptane diol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptane diol; 4-methyl-l, 4-heptanediol; 5-methyl-l, 4-heptane diol; "6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1, 5-heptanediol, 2-methyl-1,6-heptanediol, 3-methyl-1,6-heptanediol, 4-methyl-1,6-heptanediol, 5-methyl-1,6-heptanediol 6-methyl-l, 6-heptanediol; 2-methyl-2,4-heptane-diol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-ethyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2, 5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol;; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; , 7-octanediol, 3,5-octanediol and / or 3,6-octanediol V. Nonanodiol isomers, including: 2,3,3,4-tetramethyl-2,4-pentanediol, 3-butyl-2,4-2,4-phenyl -pentanediol; 2, 5, 5-trimethyl-2, 4- hexanediol; 3, 3, 4-trimethyl-2,4-hexanediol; 3, 3, 5-trimethyl-2,4-hexanediol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol;
3, 3, 4-trimethyl-2, 5-hexanediol and / or 3, 3, 5-trimethyl-2,5-hexanediol. VY Glyceryl ethers and / or ethers
^ P di (hydroxyalkyls), including: 3- (n-pentyloxy) -1,2- 5-propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3-pentyloxy) -1,2-propanediol; 3- (2-methyl-1-butyloxy) -1,2-propanediol; 3- (iso-amyloxy) -1,2-propanediol; 3- (3-methyl-2-butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1,2-propanediol; 3- (1-cyclohex-l-enyloxy) -1,2-propanediol; 2- ^ P (pentyloxy) -1,3-propanediol; 2- (2-pentyloxy) -1,3-propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-methyl-l-butoxy) -1,3-propanediol; 2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) -1,3-propanediol; 2- (2-1-cyclohex-l-enyloxy) -1,3-propanediol; 3- 15 (butyloxy) -1,2-propanediol, triethoxylated; 3- (butyloxy) -1, 2- ^ P propanediol, tetraethoxylated; 3- (butyloxy) -1,2-propanediol, pentaethoxylated; 3- (Butyloxy) -1,2-propanediol, hexaethoxylated;
3- (butyloxy) -1,2-propanediol, heptaethoxylated; 3- (butyloxy) -1,2-propanediol, octaethoxylated, -3- (butyloxy) -1,2-20 propanediol, nonaethoxylated; 3- (Butyloxy) -1,2-propanediol, monopropoxylated; 3- (Butyloxy) -1,2-propanediol, dibutylexylated; 3- (butyloxy) -1,2-propanediol, tributyleneoxylated; 3-phenyloxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3- (2-phenylethyloxy) -1,2-propanediol; 3- (l-
phenyl-2-propanyloxy) -1,2-propanediol, -2-phenyloxy-l, 3-propanediol; 2- (m-cresyloxy) -1,3-propanediol; 2- (p-cresyloxy) -1,3-propanediol; benz? lox? -1, 3-propanediol; 2- (2- ^ phenylethyloxy) -1,3-propanediol; 2- (1-phenylethyloxy) -1,3-propanediol; Bis (2-hydroxybutyl? co) ether, - and / or bis (2-hydroxycyclopentyl) ether, - VII. Saturated and unsaturated alicyclic diols, including: 1-isopropyl-1, 2-cyclobutanediol; 3-ethyl-4-methyl- ^ P '1,2-cyclobutanediol; 3-propyl-l, 2-cyclobutanedione; 3- isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-l, 2-cyclopentanediol; 1,4-dimethyl-l, 2-cyclopentanediol; 2, 4, 5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3, 4-dimethyl-l, 2- 15 cyclopentanediol; 3, 5-dimethyl-1,4-cyclopentanediol; 3-ethyl- ^ P 1, 2-cyclopentanediol; 4, 4-dimethyl-1,2-cyclopentanediol; 4- ethyl-1, 2-c-clopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-l, 3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3- 20 d? Methyl-1,3-cyclohexanediol; 1, 6-dimethyl-l, 3-cyclohexanediol; 1-hydroxy-cyclohexaneethanol; 1-hydroxycyclohexanomethanol; 1-ethyl-l, 3-cyclohexanediol; 1-methyl-l, 2-cyclohexanediol; 2, 2-dimethyl-l, 3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanedione; 2, 4-dimethyl-1, 3-
cyclohexanediol; 2,6-dimethyl-l, 4-cyclohexanediol; 2-ethyl-1,3-cydohexanediol; 2-hydroxycyclohexaneethanol; 2- hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol, -3- • Wr hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-5 hydroxymethylcyclohexanol; 3-methyl-1,2-cydohexanediol; 4,4-dimethyl-1,3-cydohexanediol; 4,5-dimethyl-1, 3-cyclohexanediol; 4, 6-dimethyl-l, 3-cyclohexapodiol; 4-ethyl-1,3-cydohexanediol; 4-hydroxyethyl-l-cyclohexanol; 4- hydroxymethylcyclohexanol; 4-methyl-1,2-cydohexanediol; 5.5- ^ P dimethyl-1,3-cydohexanediol; 5-ethyl-l, 3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-l, 3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-l, 3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-l, 4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4- 15 cyclooctanediol; 1,5-cyclooctanediol; 1,2- ^ P-cyclohexanediol dietoxylate; 1, 2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1, 2-cyclohexanediol heptaethoxylate; 1,2- 20-cyclohexanediol octaethoxylate; 1, 2-cyclohexanediol nonaethoxylate; 1, 2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutylenoxylate; 1,2-cyclohexanediol dibutyleneoxylate and / or 1,2-cyclohexanediol tributylexylate; and (b) the unsaturated alicyclic diols
including: l-ethenyl-2-ethyl-l, 2-cyclobutanediol; 1,2,3,4-tetramethyl-3-cyclobutene-1,2-diol; 3, 4-diethyl-3-cyclobutene-1,2-diol; 3- (1,1-dimethylethyl) -3-cyclobutene-1,2-diol; 3- ^ butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene-1,2-cyclopentanediol; l-ethyl-3-methylene-l, 2-cyclopentanediol; 4- (1-propenyl) -1,2-cyclopentanediol; l-ethyl-3-methyl-3 ~ -cyclopentene-1,2-diol; 1-ethenyl-l, 2-cyclohexanediol; 1- methyl-3-methylene- 1,2-cydohexanediol; 1-methyl-4-methylene-1,2-cydohexanediol; 3-ethenyl-l, 2-cyclohexanediol, -4-ethenyl- P 1, 2-cydohexanediol; 2,6-dimethyl-3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene-1,2-diol; 3, 6-dimethyl-4-cyclohexene-1,2-diol; 4, 5-dimethyl-4-cyclohexene-1,2-diol; 3- cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol and / or 5-cyclooctene-1,2-diol; 15 VIII. Alkoxylated derivatives of diols from 3 to 8
^ P carbon atoms (in the following description, "EO" means polyethoxylates, ie, - (CHjCHjOnH; Me-En means methyl-capped polyethoxylates - (CH2CH20) "CH3, -" 2 (Me-En) "means the Groups 2-Me-In necessary; "PO"
means polypropoxylates, - (CH (CH3) CH20) aH; "BO" means polybutyleneoxy groups, (CH (CH2CH3) CH2?) NH; and "BO-n" means poly (n-butyleneoxy) or poly (tetramethylene) oxy (CHCH2CH2CH2?) nH groups. The use of the term "(Cx)" in this
refers to the number of carbon atoms in the base material which is alkoxylated, including: 1. 1, 2-propanediol (C3) 2 (Me-E? -4); 1,2-propanediol (C3) P04; 2-methyl-l, 2-propanediol (C4) (Me-E4.10); 2-methyl-5,1, 2-propanediol (C4) 2 (Me-Ex.); 2-methyl-l, 2-propanediol (C4) P03; 2-methyl-l, 2-propanediol (C4) BOi; 1,3-propanediol (C3) 2 (Me-Es-a); 1,3-propanediol (C3) P05.S; 2, 2-diethyl-l, 3-propanediol (C7) E? _7; 2, 2-diethyl-l, 3-propanediol (C7) POi; 2, 2-diethyl-l, 3-propanediol (C7) n-BO? _2; 2, 2-dimethyl-l, 3- ^ > propanediol (C5) 2 (Me-E? _2); 2, 2-dimethyl-1,3-propanediol (C5) P03.4; 2- (1-methylpropyl) -1,3-propanediol (C7) E1.7, -2- (1-methylpropyl) -1,3-propanediol (C7) POi; 2- (1-methylpropyl) -1,3-propanediol (C7) n -BO? -2; 2- (2-methylpropyl) -1,3-propanediol (C7) Ex.7; 2- (2-methylpropyl) -1,3-propanediol (C7) 15 POi; 2- (2-methylpropyl) -1,3-propanediol (C7) -BOi.2,2-ethyl-9,1, 3-propanediol (C5) (Me-E6-? 0); 2-ethyl-l, 3-propanediol (C5) 2 (Me-Ei); 2-ethyl-l, 3-propahodiol (C5) P03; 2-ethyl-2-methyl-1,3-propanediol (C6) (Me-E? _d); 2-ethyl-2-methyl-1,3-propanediol (C6) P02; 2-ethyl-2-methyl-l, 3-propanediol (C6)
BOi; 2-isopropyl-1,3-propanediol (C6) (Me-Ei-6); 2-isopropyl-1,3-propanediol (C6) P02; 2- isopropyl -1, 3-propanediol (C6) BOj .; 2-methyl-l, 3-propanediol (C4) 2 (Me-E2-5); 2-methyl-l, 3-propanediol (C4) P04-5; 2-methyl-l, 3-propanediol (C4) B02; 2- methyl-2-isopropyl-1,3-propanediol (C7) E2-9; 2-methyl-2-
isopropyl-1,3-propanediol (C7) POi; 2-methyl-2-lsopropyl-l, 3-propanediol (C7) n -BO? _3; 2-methyl-2-propyl-l, 3-propanediol (C7) Ex.,; 2-methyl-2-propyl-l, 3-propanediol (C7) POi; 2- ^ methyl-2-propyl-l, 3-propanediol (C7) n -BO? .2, - 2-propyl-l, 3- 5 propanediol (C6) (Me-E? _4); 2-propyl-1, 3-propanediol (C6) P02; 2-propyl-1,3-propanediol (C6) BOj .; 2. 1, 2 -butanediol (C4) (Me-E2-8); 1,2-butanediol
(C4) P02-3; 1,2-butanediol (C4) BOi; 2, 3-dimethyl-l, 2-butanediol (C6) E? .c; 2, 3-dimethyl-l, 2-butanediol (C6) n-BOt-2, -f 2-ethyl-l, 2-butanediol (C6) E? _3; 2-ethyl-l, 2-butanediol (C6) n-BOj .; 2-methyl-1,2-butanediol (C5) (M-eE? _2); 2-methyl-l, 2-butanediol (C5) POi; 3, 3-dimethyl-l, 2-butanediol (C6) E1.s;
3, 3-dimethyl-l, 2-butanediol (C6) n-BOi-2, -3-methyl-l, 2-butanediol (C5) (Me-E? -2); 3-methyl-l, 2-butanediol (C5) POj .;
1,3 -butanediol (C4) 2 (Me-E3-6); 1,3-butanediol (C4) POs; 1,3-f butanediol (C4) B02; 2,2,3-trimethyl-1,3-butanediol (C7) (Me- E3.6); 2, 2, 3-trimethyl-l, 3-butanediol (C7) PO1-2; 2,2-dimethyl-1,3-butanediol (C6) (Me-E3.8); 2, 2-dimethyl-1,3-butanediol
(C6) P03; 2,3-dimethyl-1,3-butanediol (C6) (Me-E3_8); 2,3- 20 dimethyl-1,3-butanediol (C6) P03; 2-ethyl-l, 3-butanediol (C6)
(Me-E? .6); 2-ethyl-l, 3-butanediol (C6) PO2-3; 2-ethyl-l, 3- butanediol (C6) B0?, - 2-ethyl-2-methyl-l, 3-butanediol (C7) (Me-Ex); 2-ethyl-2-methyl-l, 3-butanediol (C7) P0 ?; 2-ethyl-2-methyl-1,3-butanediol (C7) n-BOa.4; 2-ethyl-3-methyl-l, 3-butanediol
(C7) (Me-Ex); 2-ethyl-2-methyl-l, 3-butanediol (C7) POj .; 2-ethyl-2-methyl-1,3-butanediol (C7) n-B02_4; 2-isopropyl -1, 3-butaned ol (C7) (Me-Ei); 2-isopropyl-1, 3-butanediol (CT) POi; 2-isopropyl-l, 3-butanediol (C7) n-B02-; 2-methyl-l, 3-butanediol (C5) 2 (Me-E? -3); 2-methyl-l, 3-butanediol (C5) P04; 2-propyl-l, 3-butanediol (C7) E2-9; 2-propyl-1, 3-butanediol (C7) P0 ?; 2-propy1-1, 3-butanediol (C7) n-B?! -3; 3-methyl-l, 3-butanediol (C5) 2 (Me-E? _3); 3-methyl-l, 3-butanediol (C5) P04; 1,4-butanediol (C4) 2 (Me-E2-4); 1,4-butanediol (C4) P04-5; 1,4-butanediol (C4) B02; 2, 2, 3-trimethyl-1,4-butanediol (C7) E2-s; 2,2,3-Trimethyl-l, 4-butanediol (C7) POi; 2, 2, 3-trimethyl-1,4-butanediol (C7) n-BO? -3; 2, 2-dimethyl-1,4-butanediol (C6) (Me-Ex-s); 2, 2-dimethyl-1,4-butanediol (C6) P03; 2,2-dimethyl-1,4-butanediol (C6) BOi; 2,3-dimethyl-1,4-butanediol (C6) (Me-E6.6); 2, 3-dimethyl-1,4-butanediol (C6) PO2 -, - 2,3-dimethyl-1,4-butanediol (C6) BOi; 2-ethyl-l, 4-butanediol (C6) (Me-Ei-4); 2-et? L-l, 4-butanediol (C6) P02; 2-ethyl-l, 4-butanediol (C6) BOi; 2-ethyl-2-methyl-1,4-butanediol (C7) E? -7; 2-Ethyl-2-methyl-1,4-butanediol (C7) POi, - 2-ethyl-2-methyl-1,4-butanediol (C7) n-BO? .2; 2-ethyl-3-methyl-l, 4-butanediol (C7) E? -7; 2-ethyl-3-methyl-1,4-butanediol (C7) POi; 2-ethyl-3-methyl-1,4-butanediol (C7) n-BO? -2; 2-isopropyl-l, 4-butanediol (C7) E? -7; 2-isopropyl -1,4-butanediol (C7) POi; 2- isopropy1-1, 4-butanediol (C7) n -B0? _2; 2-methyl-1,4-butanediol- (C5) (MeE6.10);
2-methyl-l, 4-butanediol- (C5) 2 (Me-Ex); 2-methyl-l, 4- butanediol- (C5) P03; 2-methyl-l, 4-butanediol- (C5) BOi; 2- propyl-1,4-butanediol- (C7) E? _5; 2-propyl-l, 4-butanediol- (C7) n-BOi-j; 3-ethyl-l-methyl-l, 4-butanediol- (C7) E2.9; 3-ethyl-l- 5-methyl-1,4-butanediol- (C7) P03; 3-ethyl-l-methyl-l, 4- butanediol- (C7) n-BO? _3; 2, 3-butanediol (C4) (Me-E6.?0); 2,3- butanediol (C4) 2 (Me-Ei); 2, 3-butanediol (C4) P03-4; 2,3- butanediol (C4) BOx; 2,3-dimethyl-2,3-butanediol (C6) E3_g; 2,3-dimethyl-2,3-butanediol (C6) n-BO? _3; "2-methyl-2,3-f-butanediol (C5) (Me-E ^ s); 2-methyl-2, 3-butanediol (C5) P02; 2-methyl-2,3-butanediol (C5) BOx, - 3. 1,2-pentanediol (C5) E3-? 0; 1,2-pentanediol (C5)
POi; 1,2-pentanediol (C5) n-B02-3; 2-methyl-l, 2-pentanediol
(C6) Ei-3, -2-methyl-l, 2-pentanediol (C6) n-BOi; 2-methyl-l, 2- 15 pentanediol (CS) BOi; 3-methyl-l, 2-pentanediol (C6) E? _3; 3- ^ P-methyl-1,2-pentanediol (C6) n-BOi; 4-methyl-l, 2-pentanediol (C6) E? -3; 4-methyl-l, 2-pentanediol (C6) n-BO ?; 1,3-pentanediol (C5) 2 (Me-E? _2); 1,3-pentanediol (C5) P03.4; 2,2-dimethyl-l, 3-pentanediol (C7) (Me-Ex); 2, 2-dimethyl-l, 3-20 pentanediol (C7) POi; 2, 2-dimethyl-1,3-pentanediol (C7) n-B02_ 4; 2,3-dimethyl-1,3-pentanediol (C7) (MeEi); 2, 3-dimethyl-l, 3- pentanediol (C7) POi, -2,3-dimethyl-l, 3-pentanediol (C7) n-B02_ 4; 2,4-dimethyl-l, 3-pentanediol (C7) (Me-Ei); 2,4-dimethyl-1,3-pentanediol (C7) POi; 2,4-dimethyl-1,3-pentanediol (C7)
n-B02.4; 2-ethyl-l, 3-pentanediol (C7) E2-9; 2-ethyl-l, 3- pentanediol (C7) POi; 2-ethyl-1,3-pentanediol (C7) n-BO? _3; 2- methyl-1,3-pentanediol (C6) 2 (Me-E? -6); 2-methyl-l, 3- ^ r pentanediol (C6) P02-3; 2-methyl-1,3-pentanediol (C6) B0X; 5 3, 4-dimethyl-l, 3-pentanediol (C7) (Me-Ex.); 3, 4-dimethyl-l, 3-pentanediol (C7) POi; 3, 4-dimethyl-l, 3-pentanediol (C7) n-B02-4; 3-methyl-l, 3-pentanediol (C6) (MeE? _5); 3-methyl-l, 3- pentanediol (C6) PO2-3; 3-methyl-l, 3-pentanediol (C6) BOi; 4, 4-dimethyl-l, 3-pentanediol (C7) (Me-Ex); 4, 4-dimethyl-l, 3-p pentanediol (C7) POi; 4, 4-dimethyl-l, 3-pentanediol (C7) n-B02_ 4; 4-methyl-l, 3-pentanediol (C6) (MeE? _6); 4-methyl-l, 3- pentanediol (C6) PO2-3; 4-methyl-l, 3-pentanediol (C6) B0 ?; 1,4-pentanediol (C5) 2 (MeE? _2); 1,4-pentanediol (C5) P03-4; 2, 2-dimethyl-1,4-pentanediol (C7) (Me-Ei); 2, 2-dimethyl-l, 4-15 pentanediol (C7) POi, -2,2-dimethyl-l, 4-pentanediol (C7) nB02. f 4; 2,3-dimethyl-1,4-pentanediol (C7) (Me-Ex); 2,3-dimethyl-1,4-pentanediol (C7) POi; 2, 3-dimethyl-l, 4-pentanediol (C7) n-B02.4; 2,4-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2,4-dimethyl-1,4-pentanediol (C7) P0X; 2,4-dimethyl-l, 4- 20 pentanediol (C7) n-B02-4; 2-phenyl-1,4-pentanediol (C6) (Me-Ex-s); 2-methyl-1,4-pentanediol (C6) P? 2-3; 2-methyl-l, 4- pentanediol (C6) BO ?; 3, 3-dimethyl-1,4-pentanediol (C7) (MeEx); 3, 3-dimethyl-l, 4-pentanediol (C7) PO ?; 3,3-dimethyl-1,4-pentanediol (C7) n-B02-4; 3, 4-dimethyl-l, 4-pentanediol
(C7) (Me-E_); 3, 4-dimethyl-l, 4-pentanediol (C7) PO ?; 3,4-dimethyl-l, 4-pentanediol (C7) n-B02_4; 3-methyl-l, 4-pentanediol
(C6) 2 (Me-E? -d); 3-methyl-1,4-pentanediol (C6) P02-3; 3-methyl- • s 1,4-pentanediol (C6) B0, -4-methyl-l, 4-pentanediol (C6) 2 (Me-5 E-6); 4-methyl-l, 4-pentanediol (C6) P? 2-3; 4-methyl-l, 4-pentanediol (C6) B0?, -1,5-pentanediol (C5) (Me-E4_10); 1,5- pentanediol (C5) 2 (Me-E); 1,5-pentanediol (C5) P03; 2,2-dimethyl-1,5-pentanediol (C7) E? -7; 2, 2-dimethyl-l, 5-pentanediol
(C7) P0 ?; 2, 2-dimethyl-l, 5-pentanediol (C7) n-BO? -2; 2,3-f) dimethyl-1,5-pentanediol (C7) E-7; 2, 3-dimethyl-l, 5-pentanediol
(C7) P0?, - 2, 3-dimethyl-l, 5-pentanediol (C7) n-BO? -2; 2,4-dimethyl-1,5-pentanediol (C7) E? _7; 2,4-dimethyl-l, 5-pentanediol
(C7) P0 ?; 2,4-dimethyl-l, 5-pentanediol (C7) n-BO? -2; 2-ethyl-l, 5- pentanediol (C7) E1.5; 2-ethyl-l, 5-pentanediol (C7) n-BO? _2; 2- 15 methyl-1, 5-pentanediol (C6) (Me-E? .4), - 2-methyl-l, 5-pentanediol
9jl (C6) P02; 3, 3-dimethyl-l, 5-pentanediol (C7) E-7; 3,3-dimethyl-1,5-pentanediol (C7) P0 ?; 3, 3-dimethyl-l, 5-pentanediol (C7) n-BO? -2, "3-methyl-l, 5-pentanediol (C6) (Me-E?); 3-methyl-l, 5- pentanediol (C6) P02; 2, 3-pentanediol (C5) (Me-E_3); 2,3- 20 pentanediol (C5) P02; 2-methyl-2,3-pentanediol (C6) E? _7; 2-methyl -2, 3 -pentanediol (C6) PO ?; 2-methyl-2, 3-pentanediol
(C6) n-BO-2, -3-methyl-2,3-pentanediol (C6) E? -7; 3-methyl-2,3-pentanediol (C6) PO ?; 3-methyl-2, 3-pentanediol (C6) n-BO? -2; 4- methyl-2, 3-pentanediol (C6) E-7; 4-methyl-2, 3-pentanediol
(C6) P0; 4-methyl-2, 3-penta? Odiol (C6) n-BO? -2; 2, 4 -pentanediol
(C5) 2 (Me-E? _4); 2,4-pentanediol (C5) P04; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E? .4); 2, 3-dimethyl-2,4-pentanediol f (C7) P02; 2,4-dimethyl-2,4-pentanediol (C7) (Me-E.4); 2,4,5-dimethyl-2,4-pentanediol (C7) P02; 2-methyl-2, 4-pentanediol
(C7) (Me-E5.?0); 2-methyl-2,4-pentanediol (C7) P03; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E? _4); 3, 3-dimethyl-2, 4-pentanediol (C7) P02; 3-methyl-2,4-pentanediol (C6) (Me-Es_ xo); 3-methyl-2,4-pentanediol (C6) P03; fl 4. 1, 3-hexanediol (C6) (Me-E? _5); 1, 3-hexanediol
(C6) P02; 1, 3 -hexanediol (C6) BO ?; 2-methyl-l, 3-hexanediol
(C7) E2-9; 2-methyl-l, 3-hexanediol (C7) P0 ?; "2-methyl-1, 3-hexanediol (C7) n-B0? 3; 2-methyl-l, 3-hexanediol (C7) BO ?; 3-methyl-1,3-hexanediol (C7) E2_9; 3 -methyl-l, 3-hexanediol
(C7) P0 ?; 3-methyl-l, 3-hexanediol (C7) n -BO? .3; 4-methyl-l, 3- ^ P-hexanediol (C7) E2-s; 4-methyl-l, 3-hexanediol (C7) P0 ?; 4- methyl-1,3-hexanediol (C7) n-BO? -3; 5-methyl-l, 3-hexanodisl
(C7) E2-9; 5-methyl-l, 3-hexanediol (C7) P0 ?; 5-methyl-l, 3-hexanediol (C7) n-B0? .3; 1, -hexanediol (C6) (Me-E? .5); 1,4- 20 hexanediol (C6) P02; 1, 4-hexanediol (C6) BO ?; 2-methyl-l, 4-hexanediol (C7) E2_9; 2-methyl-l, 4-hexanediol (C7) P0, -2-methyl-1,4-hexanediol (C7) n-B0? _3; 2-methyl-l, 4-hexanediol
(C7) E2.9; 3-methyl-l, 4-hexanediol (C7) P0 ?; 3-methyl-l, 4-hexanediol (C7) n-B0? _3; 4-methyl-l, 4-hexanediol (C7) E2-9; 4-
methyl-1,4-hexanediol (C7) P0? - 4-methyl-1,4-hexanediol (C7) n- BO? -3; 5-methyl-1,4-hexanediol (C7) E2-9; 5-methyl-l, 4-hexanediol (C7) P0 ?; 5-methyl-l, 4-hexanediol (C7) n-BO_3; 1,5-f-hexanediol (C6) (Me-E? -5); 1, 5-hexanediol (C6) P02; 1,5- 5 hexanediol (C6) BO ?; 2-methyl-l, 5-hexanediol (C7) E2_9; 2- methyl-1,5-hexanediol (C7) P0 ?; 2-methyl-l, 5-hexanediol (C7) n- BO? _3; 3-methyl-l, 5-hexanediol (C7) E2.9; 3-methyl-l, 5-hexanediol (C7) P0; 3-methyl-l, 5-hexanediol (C7) n-BO_3; 4- methyl-1,5-hexanediol (C7) E2_9; 4-methyl-l, 5-hexanediol f (C7) P0 ?; 4-methyl-l, 5-hexanediol (C7) n-BO? -3; 5-methyl-l, 5-hexanediol (C7) E2_9; 5-methyl-l, 5-hexanediol (C7) P0 ?; 5- methyl-1, 5-hexanediol (C7) n-BO? _3; 1, 6-hexanediol (C6) (Me-E? -2); 1, 6-hexanediol (C6) PO? .2; 1, 6-hexanediol (C6) n-B04; 2-methyl-l, 6-hexanediol (C7) E_5; 2-methyl-l, 6-hexanediol 15 (C7) n-B0? .2; 3-methyl-l, 6-hexanediol (C7) E? .5; 3-methyl-l, 6- ^ P-hexanediol (C7) n-BO? -2; , 3-hexanediol (C6) E? .5; 2,3- hexanediol (C6) n-BO ?; 2, 3-hexanediol (C6) BO ?; 2,4-hexanediol (C6) (Me-E3.3); 2,4-hexanediol (C6) P03; 2-methyl-2,4-hexanediol (C7) (Me-E? _2); 2-methyl-2,4-hexanediol (C7)
PO? 2, - 3-methyl-2,4-hexanediol (C7) (Me-E? .2); 3-methyl-2,4-hexanediol (C7) PO? .2; 4-methyl -2,4-hexanediol (C7) (Me-E? _2); 4-methyl-2,4-hexanediol (C7) PO? .2; 5-methyl-2,4-hexanediol (C7) (Me-E? .2); 5-methyl-2,4-hexanediol (C7) PO? .2; 2,5-hexanediol (C6) (Me-E3.8); 2,5-hexanediol (C6) P03; 2-raetil-
2,5-hexanediol (C7) (Me-E? .2); 2-methyl-2, 5-hexanediol (C7) PO? .2; 3-methyl-2,5-hexanediol (C7) (Me-E? .2); 3-methyl-2,5-hexanediol (C7) PO? -2; 3,4 hexanediol (C6) EO? -5; 3,4-ß * hexanediol (C6) n-BO; 3, 4-hexanediol (C6) B0 ?; 5-1,3-heptanediol (C7) E? -7; 1,3-heptanediol (C7)
P0?; 1,3-heptanediol (C7) n-B0? -2; 1,4-heptanediol (C7) E _7;
1,4-heptanediol (C7) PO ?; 1,4-heptanediol (C7) n -BO? .2; 1,5-heptanediol (C7) E? .7; 1,5-heptanediol (C7) PO ?; 1,5-heptanediol (C7) n-BO? -2; 1, 6-heptanediol (C7) E? .7; 1,6-fl-heptanediol (C7) PO ?; 1, 6-heptanediol (C7) n-BO? -2, - 1,7-heptanediol (C7) E? _2, - 1, 7-heptanediol (C7) n-B0?, - 2,4-heptanediol (C7) ) E3_? 0; 2,4-heptanediol (C7) (Me-E?); 2,4-heptanediol (C7) PO ?; 2,4-heptanediol (C7) n-B03; 2,5-heptanediol (C7) E3.10; 2, 5-heptanediol (C7) (Me-E?), - 2,5- 15 heptanediol (C7) PO ?; 2,5-heptanediol (C7) n-B03; 2,6-f1 heptanediol (C7) E3-xo; 2,6-heptanediol (C7) (Me-E?); 2,6-heptanediol (C7) P01; -2,6-heptane diol (C7) n-B03; 3,5- heptanediol (C7) E3-10; 3, 5-heptanediol (C7) (Me-E?); 3,5-heptanediol (C7) PO?, -3,5-heptanediol (C7) n-B03; 20 6. 3-methyl-2-isopropyl-1,3-butanediol (C8) P0?, -2,3,3-trimethyl-2,4-pentanediol (C8) P0a; 2, 2-diethyl-l, 3- butanediol (C8) E-5; 2,3-dimethyl -2,4-hexanediol (C8) E2-5; 2,4-dimethyl -2,4-hexanediol (C8) E2_5; 2,5-dimethyl-2,4-hexanediol (C8) E2.5; 3, 3-dimethyl-2,4-hexanediol (C8) E2-5;
3,4-dimethyl-2,4-hexanediol (C8) E2.5; 3, 5-dimethyl-2, 4-hexanediol (C8) E2_5; 4, 5-dimethyl-2,4-hexanediol (C8) E2-5;
, 5-dimethyl-2,4-hexanediol (C8) E2_s; 2,3-dimethyl-2, 5-ß * hexanediol (C8) E2-5; 2,4-dimethyl-2, 5-hexanediol (C8) E2_5;
2, 5-dimethyl-2, 5-hexanediol (C8) E2_s; 3, 3-dimethyl-2, 5-hexanediol (C8) E2-5; 3, 4-dimethyl-2, 5-hexanediol (C8) E2-5; 3- methyl-3,5-heptanediol (C8) E2_5; 2, 2-diethyl-l, 3-butanediol
(C8) n-B0? .2; 2, 3-dimethyl-2,4-hexanediol (C8) n-BO? -2; 2,4-dimethyl-2,4-hexanediol (C8) n-BO_2; 2, 5-dimethyl-2,4-fl-hexanediol (C8) n-BO? -2; 3, 3-dimethyl-2,4-hexanediol (C8) n- BO? _2; 3,4-dimethyl-2,4-hexanediol (C8) n-BO? _2; 3,5-dimethyl-2,4-hexanediol (C8) n-BO? -2,4,5-dimethyl-2,4-hexanediol (C8) n-BO? -2; 5, 5-dimethyl -2,4-hexanediol (C8) n -BO? _2; 2,3-dimethyl-2, 5-hexanediol (C8) n-BO? -2; 2,4-dimethyl-2,5-hexanediol (C8)
n-B0? -2; 2,5-dimethyl-2, 5-hexanediol (C8) n-BO? _2; 3,3-dimethyl-f 2,5-hexanediol (C8) n-BO? -2; 3, 4-dimethyl-2, 5-hexanediol (C8) n-B0? -2; 3-methyl-3, 5-heptanediol (C8) n-BO? -2; 2-. { 1, 2-dimethylpropyl) -1,3-propanediol (C8) n -BO?, - 2-ethyl-2,3-dimethyl-1,3-butanediol (C8) n-BO ?; 2-methyl-2-isopropyl-l, 3- 20 -butanediol (C8) n -B0 ?; 3-methyl-2-isopropyl-l, 4-butanediol
(C8) n-B0 ?; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BOf;
2,2,4-trimethyl-l, 3-pentanediol (C8) n-B0?, -2,4,4-trimethyl-1,3-pentanediol (C8) n -BO ?; 3, 4, 4-trimethyl-l, 3-pentanediol
(C8) n-BO ?; 2, 2, 3-trimethyl-1,4-pentanediol (C8) n-BO ?;
2,2,4-trimethyl-l, 4-pentanediol (C8) n-BO ?; 2, 3, 3-trimethyl-1,4-pentanediol (C8) n-BO ?; 2, 3, 4-trimethyl-lV4-pentanediol (C8) n-BO ?; 3, 3, 4-trimethyl-l, 4-pentanediol (C8) n-BO?, - f 2,3,4-trimethyl-_2,4-pentanediol (C8) n-BO?, - 4-ethyl-2 , 4-5-hexanediol (C8) n-B0?, - 2-methyl-2,4-heptanediol (C8) n-BO, -3-methyl-2,4-heptanediol (C8) n-BO ?; 4-methyl-2,4-heptanediol (C8) n-BO ?; 5-methyl-2, 4-heptanediol (C8) n-BO ?; 5-methyl-2,4-heptanediol (C8) n-BO ?; 6-methyl-2,4-heptanediol (C8) n-B01 (- 2-methyl-2, 5-heptanediol (C8) n-BO ?; 3-methyl-2, 5-heptanediol f (C8) n-BO 4-Methyl-2, 5-heptanediol (C8) n-BO ?; 5-methyl-2,5-heptanediol (C8) n-BO ?; 6-methyl-2, 5-heptanediol (C8) n- BO?, - 6-methyl-2, 5-heptanediol (C8) n-BO ?; 2 -methyl-2,6-heptanediol (C8) n-BO ?; 3-methyl-2,6-heptanediol (C8) n-BO?, - 4-methyl-2,6-heptanediol (C8) n-B0?, - 2-methyl-3,5-heptanodjol (C8) n-BO?, - 15 2- (1, 2-dimethylpropyl) -1,3-propanediol (C8) E? _3; 2-ethyl-2,3-f1-dimethyl-1,3-butanediol (C8) E_3; 2-methyl-2-isopropyl-1, 3- butanediol (C8) E? .3; 3-methyl-2-isopropyl-1,4-butanediol (C8) E? _3; 2,2,3-trimethyl-l, 3-pentanediol (C8) E.3; 2 , 2,4-trimethyl-1,3-pentanediol (C8) E? -3; 2,4, 4-trimethyl-l, 3- 20 pentanediol (C8) E? .3; 3, 4, 4-trimethyl -l, 3-pentanediol (C8) E? .3; 2,2,3-trimethyl-l, 4-pentanediol (C8) E? .3; 2, 2,4-trimethyl-1,4-pentanediol (C8) E .3; 2,3,3-trimethyl-l, 4-pentanediol (C8) E? _3; 2, 3, 4-trimethyl-l, 4-pentanediol (C8) E? .3; 3, 3 , 4-trimethyl -1,4 -pentanediol (C8) E? _3; 2,3,4-
trimethyl-2, 4-pentanediol (C8) E.3; 4-ethyl-2,4-hexanediol
(C8) E? .3; 2-methyl-2,4-heptanediol (C8) E? .3, - 3-methyl-2,4-heptanediol (C8) E? .3 / - 4-methyl-2,4-heptanediol (C8) E? -3; 5-) methyl -2, -heptanediol (C8) E? .3; 6-methyl-2,4-heptanediol (C8)
E? -3; 2-methyl-2, 5-heptanediol (C8) E? .3; 3-methyl-2,5-heptanediol (C8) E? .3; 4-methyl -2,5-heptane diol (C8) E? _3; 5- methyl-2, 5-heptanediol (C8) E? .3; 6-methyl-2, 5-heptanediol (C8 ~)
E? .3; 2-methyl-2,6-heptanediol (C8) E? _3; 3-methyl-2,6-heptanediol (C8) E? _3; 4-methyl-2,6-heptanediol (C8) E? .3; and / or | 2-methyl-3, 5-heptanediol (C8) E? _3; and 7. mixtures thereof; IX. Aromatic diols, including: l-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol, -1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1, 3- ^ P propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1- phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; and / or 1-phenyl-2,3-butanediol, -X. Main solvents that are homologous, or analogues, of the above structures wherein one or more CH2 groups are added, while for each added CH2 group, 2 is removed. hydrogen atoms of adjacent carbon atoms in the molecule to form a carbon-carbon double bond, thus keeping the number of carbon atoms constant
hydrogen atoms in the molecule, including the following: 2, 2-di-2-propenyl-1,3-propanediol, -2- (1-pentenyl) - ^ P 1, 3-propanediol; 2- (2-methyl-2-propenyl) -2- (2-propenyl) -1, 3-propanediol; 2- (3-methyl-1-butenyl) -1,3-propanediol; 2- (4- pentenyl) -1,3-propanediol; 2-ethyl-2- (2-methyl-2-propenyl) -2- (2 -propenyl) -1,3-propanediol; 2-ethyl-2- (2-propenyl) -1,3-propanediol; 2-methyl-2- (3-methyl-3-butenyl) -1,3-propanediol; 2, 2-diallyl-1,3-butanediol; 2- (1-ethyl-1-propenyl) -1,3- ^ P-butanediol; 2- (2-butenyl) -2-methyl-1,3-butanediol; 2- (3-methyl-2-butenyl) -1, 3 -butanediol; 2-and il-2- (2-propenyl) -1,3-butanediol; 2-methyl-2- (1-methyl-2-propenyl) -1,3-butanediol, -2,3-bis (1-methylethylidene) -1,4-butanediol; 2- (3-methyl-2-butenyl) -3-methylene-1,4-butanediol; 2- (1,1-dimethylpropyl) -2,5-butene-1,4-diol; 2- (1-methylpropyl) -2-butene-1,4-diol; 2- ^ P butyl-2-butene-1,4-diol; 2-ethenyl-3-ethyl-l, 3-pentanediol; 2- ethenyl-4,4-dimethyl-l, 3-pentanediol; (3-methyl-2- (2-propenyl) -1,4-pentanediol; 2- (1-propenyl) -1,5-pentanediol; 2- (2-propenyl) -1,5-pentanediol; 2-ethylidene -3-methyl-1, 5- 20 pentanediol; 2-propylidene-1,5-pentanediol; 3-ethylidene-2,4-dimethyl-2,4-pentanediol; 2- (1,1-dimethylethyl) -4- pentene-l, 3- diol, 2-ethyl-2,3-dimethyl-4-pentene-l, 3-diol, 4-ethyl-2-methylene-1,4-hexanediol, 2,3,5-trimethyl- l, 5-hexadiene-3, 4-diol; 5-ethyl-3-methyl-l, 5-hexadiene-3, 4-diol; 2- (1-
methylethhenyl) -1,5-hexanediol; 2-ethenyl-l, 6-hexanediol; 5,5-dimethyl-l-hexene-3,4-diol; 4-ethenyl-2,5-dimethyl-2-hexene-1,5-diol; 2-ethenyl-2,5-dimethyl-3-hexene-1,6-diol; 2-ethyl-3- ^ P hexene- 1,6-diol; 3,4-dimethyl-3-hexene-1,6-diol; 2,5-dimethyl-5-hexene-2,3-diol; 3, 4-dimethyl-4-hexene-2,3-diol; 3- (2-propenyl) -5-hexene-1,3-diol; 2,3-dimethyl-5-hexene-2,3-diol; 3, 4-dimethyl-5-hexene-2,3-diol; 3, 5-dimethyl-5-hexene-2,3-diol; 3-ethenyl-2, 5-dimethyl-5-hexene-2,4-diol; 6-methyl-5-methylene-1,4-heptane diol; 2,3-dimethyl-l, 5-heptadiene-3, 4- ^ diol; 2,5-dimethyl-l, 5-heptadiene-3,4-diol; 3, 5-dimethyl-l, 5-heptadiene-3,4-diol; 2,6-bis (methylene) -1,7-heptanediol; 4- methylene-1,7-heptanediol; 2,4-dimethyl-1-heptene-3,5-diol, -2,6-dimethyl-1-heptane-3,5-diol; 3-ethenyl-5-methyl-1-heptene-3,5-diol; 6, 6-dimethyl-l-heptene-3,5-diol; 4, 6-dimethyl-2, 4-15-heptadiene-2,6-diol; 4, 4-dimethyl-2,5-heptadiene-1,7-diol;
^ P 2, 5, 5-trimethyl-2,6-heptadien-1,4-diol; 5,6-dimethyl-2-heptene-2,6-diol; 5-ethyl-2-heptene-1,5-diol; 2-methyl-2-heptene-1,7-diol; 4,6-dimethyl-3-heptene-1,5-diol; 3-methyl-6-methylene-3-heptene-1,7-diol; 2,4-dimethyl-3-heptene-2,5-diol, -20,5-dimethyl-3-heptene-2,5-diol; 2,6-dimethyl-3-heptene-2,6-diol; 4,6-dimethyl-3-heptene-2,6-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3, 6-dimethyl-5-heptene-1,4-diol; 2,3-dimethyl-5-heptane-2,4-diol; 2, 2-dimethyl-6-heptene-1,3-diol; 4- (2-propenyl) -6-heptene-1,4-diol; 5, 6-dimethyl-6-heptene- 1,4-
diol; 2,4-dimethyl-6-heptene-1, 5-diol; 2-ethylidene-6-methyl-6-heptene-1,5-diol; 4- (2-propenyl) -6-heptene-2,4-diol; 5,5-dimethyl-6-heptene-2,4-diol; 4,6-dimethyl-6-heptene-2,5-diol;
^ P 5-ethenyl-4-methyl-6-heptene-2,5-diol; 2-methylene- 1,3- 5-octanediol; 2,6-dimethyl-l, 6-octadiene-3,5-diol; 3,7-dimethyl-1,6-octadiene-3,5-diol; 2,6-dimethyl-l, 7-octadiene-3,6-diol; 2,7-dimethyl-l, 7-octadiene-3,6-diol; , 6-dimethyl-l, 7- octadiene-3,6-diol; 3-ethenyl-l-octene-3,6-diol; 2,7-dimethyl-2,4,6-octariene-1,8-diol; 3,7-dimethyl-2,4-octadiene-l, 7-f-diol; 2,6-dimethyl-2,5-octadiene-l, 7-diol; 3, 7-dimethyl-2, 5-octadiene-1,7-diol; 3, 7-dimethyl-1-6-octadiene-l, 4-diol (Rosiridol); 2-methyl-2,6-octadiene-l, 8-diol; 3,7-dimethyl-2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-1,5-diol; 2,6-dimethyl-2,7-octadiene-l, 6-diol (8-hydroxylinalool); 2,7-15 dimethyl-2,7,7-octadiene-l, 6-diol; 2-ketene-1,4-diol; 2-octene- ^ P 1,7-diol; 2-methyl-6-methylene-2-octene-l, 7-diol; 3,7-dimethyl-3,5-octadiene-l, 7-diol; 2,7-dimethyl-3,5-octadiene-1,7-diol; 4-methylene-3,5-octanediol; 2,6-dimethyl-3,7-octadiene-l, 6-diol; 2,7-dimethyl-3,7-octadiene-2,5-diol; 2,6-dimethyl-3,7-octadiene-2,6-diol; 4-methyl-3-octene-1, 5-diol; 5-methyl-3-octene-1,5-diol; 2, 2-dimethyl-4,6-octadiene-1,3-diol; 2,6-dimethyl-4,7-octadiene-2,3-diol; 2,6-dimethyl-4,7-octadiene-2,6-diol; 7-methyl-4-ketene-1,6-diol; 2, 7-bis (methylene); 2,7- dimethyl-5,7-octadiene-1,4-diol; 7-methyl-5, 7-octadiene-l, 4-
diol; 5-octene-l, 3-diol; 7-methyl-6-octene-l, 3-diol; 7-methyl-6-octene-1,4-diol; 6-octene-1, 5-diol; 7-methyl-6-octene-l, 5-diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol;
^ P 2 -methyl-7-octene-l, 3-diol; 4-metll-7-octene-1, 3-d-ol; 7- 5-methyl-7-octene-l, 3-diol; 7-octene-1, 5-diol; 7-octene-l, 6-diol; 5-methyl-7-octene-1,6-diol; 2-methyl-6-methylene-7-ketene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3, 5-diol; l-nonene-3, 5-diol; l-nonene-3, 7-diol; 3-nonene-2, 5-diol; 8-methyl-4,6-nonadiene-1,3-diol; 4-nonene-2, 8-d-ol; 6- ^ < nonadiene-1, 5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-noneno-2,5-diol; 1, 9-decadiene-3,8-diol; and / or 1, 9-decadiene-4,6-diol; and XI. Mixtures thereof; C. Optional, but preferably, an effective amount, sufficient to improve transparency, of
^ P Water-soluble solvents of low molecular weight, such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate, etc., said water-soluble solvents are at a level where they will not form compositions
transparent by themselves; D. Optional, but preferably, from 0% to about 15%, preferably about 0.1% to 8%, and more preferably about 0.2% to 5% perfume;
E. Optionally, from 0% to about 2%, preferably from about 0.01% to 0.2%, and most preferable from about 0.035% to 0.1% stabilizer; ^ P F. Optional, but preferably, an amount
effective to improve the transparency, of calcium salt and / or magnesium soluble in water, preferably chloride; and G. The rest of water. Preferably the compositions herein are aqueous, translucent or transparent, preferably
Transparent, the compositions contain about 3% to 95%, preferably about 5% to 80%, more preferably about 15% to 70%, and even more preferably about 40% to 60% water and about from 3% to 40%, preferably from 10% to 35%, more preferably from 12% to
25%, and even more preferable around 14% to 20%, of the
^ P solvent ^ main alcoholic B above. - These preferred products (compositions) are not translucent or transparent without the main solvent B. The amount of the main solvent B required to make the compositions
Translucent or transparent is preferably more than 50%, more preferably about 60%, and even more preferably about 75% of the total organic solvent present.The main solvents are desirably kept at the lowest levels they provide.
acceptable stability / transparency in the present compositions. The presence of water exerts an important effect on the need of the main solvents
^ P to achieve the transparency of these compositions. 5 The higher the water content, the higher the level of the main solvent (in relation to the level of softener) necessary to achieve product transparency. Conversely, the lower the water content, the lower the need for the main solvent (in
^ relationship with the softener). Accordingly, at low water levels of about 5% to 15%, the proportion of active softening ingredient to principal solvent is preferably about 55:45 to 85:15, more preferable about 60:40 to 80:20. In water levels
approximately from 15% to 70%, the proportion by weight of
Main active solvent softener preferably is around 45:55 to 70:30, more preferable about 55:45 to 70:30. But at water levels greater than about 70% to 80%, the weight ratio of softening active ingredient
The main solvent is preferably from about 30:70 to 55:45, more preferable about 35:65 to 45:55. At higher water levels, the proportions of softener to principal solvent must be even higher.
The pH of the compositions should be about 1 to 7, preferably about 1.5 to 5, more preferably about 2 to 3.5.
DETAILED DESCRIPTION OF THE INVENTION
1. ACTIVE INGREDIENT OF FABRIC SOFTENER
The compositions of the present invention
They contain as an essential component about 2% to 80%, preferably about 13% to 75%, more preferably about 17% to 70% and even more preferably 19% to 65% by weight of the composition, of a active ingredient softener selected from the compounds identified below, and
mixtures thereof. ^ P Fabric softeners that can be used herein are discussed, at least generically in their basic structures, in US Pat. No. 3,861,870, Edwards and Diehl; 4,308,151, Cambre; 3,886,075, Bernardino; 4,233,164,
Davis; 4,401,578, Verbruggen; 3,974,076, Wierseraa and Rieke; and 4,237,016, Rudkin, Clint and Young, all of these patents incorporated herein by reference. Preferred fabric softening agents are discussed in US Pat. No. 4,661,269, issued on 28
April 1987, in the name of Toan Trinh, Errol H. Wahl, Donald M. Swartley and Ronald L. Hemingway, said patent is incorporated herein by reference. ^ P The primary softening active ingredients of
The present are those which constitute highly unsaturated versions of the traditional softening active ingredients, ie nitrogenous derivatives of long double-chain alkyl, normally catidnic materials, such as dioleyl dimethyl ammonium chloride and
^ m imidazolinium as described hereafter. As discussed in more detail below, most biodegradable fabric softening compounds may be present. Examples of these fabric softeners can be found in US patents 3,408,361, Mannheimer, 15 issued October 29, 1968, 4,709,045, Kubo and
^ P coinventores, issued on November 24, 1987; 4,233,451, Pracht and co-inventors, issued November 11, 1980; 4,127,489, Pracht and co-inventors, issued November 28, 1979; 3,689,424, Berg and
coinventores, issued on September 5, 1972; 4,128,485, Baumann and co-inventors, issued December 5, 1978; 4,161,604, Elster and co-inventors, issued July 17, 1979; 4,189,593, Wechsler and co-inventors, issued February 19, 1980; Y
4,339,391, Hoffman and co-inventors, issued July 13, 1982, said patents are incorporated herein by reference. ^ P The preferred fabric softeners of the
The invention comprises a majority of compounds such as the following: (1) softener with the formula:
R4-m- < ',', -R1 ™ A "
wherein each m is 2 or 3, each R1 is a hydrocarbyl, or substituted hydrocarbyl substituent of 6 to 22 carbon atoms, preferably 14 to 20 carbon atoms, but no more than one has less than about 12 carbon atoms.
carbon atoms and then the other is at least close to
(? 16, hydrocarbyl or substituted hydrocarbyl substituent, preferably alkyl or alkenyl of 10 to 20 carbon atoms (unsaturated alkyl, including poly-saturated alkyl, also sometimes referred to as
"Alkylene"), more preferably alkyl or alkenyl of 12 to 18 carbon atoms, and wherein the Iodine Value of a fatty acid containing this group R1 is approximately from 70 to 140, more preferably from about 80 to 130; and much more preferable around 90 to 115 with a proportion
cis / trans of about 1: 1 to 50: 1, the minimum being 1: 1, preferably about 2: 1 to 40: 1, more preferable about 3: 1 to 30: 1, and even more preferable about 4: 1 to 20: 1, and
^ P the total level of active ingredient containing polyunsaturated acyl fatty acid groups (TPU) is typically from about 3% to 30%; each R1 may also preferably be a branched chain alkyl group of 14 to 22 carbon atoms, preferably a branched chain group of 16 to 18 carbon atoms; each R is H or a short chain alkyl or hydroxyalkyl group of 1 to 6 carbon atoms, preferably 1 to 3 carbon atoms, for example, methyl (most preferred), ethyl, propyl, hydroxyethyl, and the like, benzyl , or (R20) 2-4H; and A "is an anion compatible with softener, preferably chloride, bromide, methylisulfate, etiisulfate, sulfate and
^ P nitrate, more preferable chloride and methylsulfate, - (2) softener with the formula:
wherein each R, R1 and A "have the definitions given above, each R2 is an alkylene group of 1 to 6
carbon atoms, preferably an ethylene group; and G is an oxygen atom or a group -NR-; (3) Softener with the formula:
wherein R1, R2 and G are defined as above;
(4) reaction products of branched chain and / or substantially unsaturated higher fatty acids with dialkylenetriamines in, for example, a molecular ratio of about 2: 1, said reaction products contain compounds of the formula:
R1-C (0) -NH-R2-NH-R3-NH-C (0) -R1
wherein R1, R2 are defined as above, and each R3 is an alkylene group of 1 to 6 carbon atoms, preferably an ethylene group; (5) Formula softener:
[R1-C (O) -NR-R2-N (R) 2 -R3-NR-C (O) -R1] + A "
wherein R, R1, R2, R3 and A "are defined as above; (7) softener with the formula:
where R, R1, R2 and A "are defined as
^ above; and (8) mixtures thereof. Examples of the compound (1) are the dialkylenedimethylammonium salts such as dicanoladimethylammonium chloride, methylisulfate
Dicanedimethylammonium chloride, dimethylammonium chloride di (partially hydrogenated fl iesilic acid, cis / trans ratio of about 4: 1), dioleyldimethylammonium chloride. Dioleldimethylammonium chloride and di (canola) dimethylammonium chloride are preferred. An example of salts
commercially available dialkylenedimethylammonium which can be used in the present invention is the dioleyldimethylammonium chloride available from Witco Corporation under the trade name Adogen® 472.
An example of compound (2) is 1-methyl-1-oleylamidoethyl-2-oleylimidazolinium methylisulfate wherein R 1 is an aliphatic acyclic hydrocarbon group of 15 to 17 carbon atoms, R 2 is an ethylene group, G is an NH group , R5 is a methyl group and A "is a methyl sulfate anion, commercially available from Witco Corporation under the tradename Varisoft® 3690. An example of the compound (3) is 1-oleylamidoethyl-2-oleylimidazoline, wherein R1 is an aliphatic acyclic hydrocarbon group of 15 to 17 carbon atoms, R 2 is an ethylene group and G is an NH group. An example of the compound (4) are the reaction products of oleic acids with diethylenetriamine in a molecular ratio of about 2: 1, said mixture of
reaction product contains N, N '-dioleldiethylenetriamine
^ > with the formula:
Rx-C (0) -NH-CH2-CH2-NH-CH2-CH2-NH-C (0) -R1
Wherein Ra-C (0) is an oleyl group of a commercially available oleic acid derived from an animal or vegetable source, such as Emersol® 223LL or Emersol® 7021, available from Henkel Corporation, and R2 and R3 are divalent ethylene groups.
An example of the compound (5) is a softener based on amidoamine digrasa with the formula:
f [R ^ C (O) -NH-CH2CH2-N (CH3) (CH2CH20H) -CH2CH2-NH-C (O) -R1) + CH3S04 ~ 5 wherein R1-C (0) is an oleyl group, available commercially at Witco Corporation under the trade name Vapsoft® 222LT. An example of the compound (6) are the products of the reaction of oleic acids with N-2-hydroxyethyl ether amine at a molecular ratio of about 2: 1, said fraction of products in reaction contains a compound of the formula:
R1-C (0) -NH-CH2CH2-N (CH2CH2OH) -C (0) -R1 15? K wherein R1-C (0) is an oleyl group of an oleic acid available commercially, derived from a source animal or plant, such as Emersol® 223LL or Emersol® 7021, available from Henkel Corporation. An example of the compound (7) is the diquaternary compound having the formula:
wherein R1 is derived from oleic acid, and the compound is available from the Witco Company. The above individual compounds (active) can be used individually or as mixtures. One type of optional but highly desirable cationic compound that can be used in combination with the above active softening ingredients are the compounds containing a long chain acyclic hydrocarbon group of 8 to 22 carbon atoms, selected from the group consisting of: wherein R7 is a hydrogen or a saturated alkyl or hydroxyalkyl group of 1 to 4 carbon atoms, and R1 and A- are defined as above; (9) acyclic quaternary ammonium salts having the formula:
[R1-N (R5) 2 -R6] + A "
wherein R and R are alkyl or hydroxyalkyl groups of 1 to 4 carbon atoms
(10) substituted imidazolinium salts having the formula:
wherein R7 is hydrogen or a saturated alkyl or hydroxyalkyl group of 1 to 4 carbon atoms, and R1 and A "are defined as above; (11) substituted imidazolinium salts having the formula:
wherein R is an alkyl or hydroxyalkyl group of 1 to 4 carbon atoms, and R1, R2 and A "are as defined above, - (12) alkylpyridinium salts having the formula:
Wherein R 4 is an aliphatic acyclic hydrocarbon group of 8 to 23 carbon atoms - and A "is an anion, and (13) alkylene prunidium alkanamide salts having the formula:
wherein R1, R2 and A "are defined as above, and mixtures thereof Examples of the compound (9) are the monoalkenyltrimethylammonium salts such as" monooleyltrimethylammonium chloride, monocanetrimethylammonium chloride, and soyatrimethylammonium chloride. Monooleyltrimethylammonium chloride and monocanelatrimethylammonium chloride are preferred. Other examples of the compound (9) are soyatrimethylammonium chloride available from Witco Corporation under the tradename Adogen® 415, erucyltrimethylammonium chloride wherein R1 is a group
hydrocarbon of 22 carbon atoms derived from a natural source; Soyadimethylethylammonium ethiisulfate wherein R1 is a hydrocarbon group of 16 to 18 carbon atoms, R5 is a
^ P methyl group, Rd is an ethyl group, and A "is an anion of
etiisulfate; and bis (2-hydroxyethyl) oleyl ammonium methyl chloride wherein R1 is a hydrocarbon group of 18 carbon atoms, R5 is a 2-hydroxyethyl group and Rd is a methyl group. An example of the compound (11) is an ethiisulfate of
^ fe | 1-ethyl-1- (2-hydroxyethyl) -2-isoheptadecylimidazolinium wherein R1 is a hydrocarbon group of 17 carbon atoms, R2 is an ethylene group, Rs is an ethyl group, and A "is an anionisulfate anion.
ANION A
In the cationic nitrogenous salts herein, the anion A ", which is any anion compatible with softener, provides electrical neutrality.Most frequently, the anion used to provide electrical neutrality in these salts, is a strong acid, especially a hale such as chloride, bromide or iodide, however, other anions can be used, such as methylisulfate, etiisulfate, acetate, formate, sulfate, carbonate and the like.
Chloride and methylisulfate are preferred herein as anion A. As mentioned above, the active ingredient softener can also contain a small amount of active ingredient fabric softener more biodegradable, especially: (A) Denser fabric softener active compound quaternary ammonium (DEQA) (I) The first type of DEQA comprises ^ | preferably, as the main active ingredient, compounds of the formula
[(R) 4-m-N + - [(CHaJn-Y-R1].,] A "15 where: each R and A" are as defined above, each m is 2 or 3, each n is 1 to about 4,
^ preferably 2; each Y is -0- (0) C-, - (R) N- (0) C-, -C (0) - N (R) -, or -C (0) -0-; preferably -0 (0) C-, but not -0C (0) 0-; the sum of carbons in each R1, plus one when Y is -0- 20 (O) C- or - (R) N- (0) C- is from 6 to 22 carbon atoms, preferably from 14 to 20 carbon atoms. carbon, but not more than one sum YR1 is less than about 12 and then the other sum YR1 is at least about 16, each R1 being a long chain hydrocarbyl of 8 to 22 carbon atoms (or
from 7 to 21 carbon atoms), substituted hydrocarbyl substituent, preferably alkyl or alkenyl of 10 to 20 carbon atoms (or 9 to 19 carbon atoms), much more
Preferably alkyl or alkenyl of 12 to 18 carbon atoms 5 (or of 11 to 17 carbon atoms), and where, when said carbon sum is 16 to 18 carbon atoms and R 1 is a chain alkyl or alkenyl group Straight, the Iodine Value (hereinafter referred to as VY) of the original fatty acid of this group R1 is preferably from about 20 to 140, more
^ P preferable from about 50 to 130, and much preferable from about 70 to 115. As above, the opposite ion A "above, can be any softener-compatible anid, preferably the anion of a strong acid, for example,
chloride, bromide, methylisulfate, etiisulfate, sulfate,
^ nitrate and the like, more preferably chloride. The anion can also, although less preferable, carry a double charge, in which case A "represents half of a group.
Preferred ammonium, preferably biodegradable quaternary, can contain the - (O) CR1 group which is derived from animal, unsaturated and polyunsaturated fats, fatty acids, for example, oleic acid and / or partially hydrogenated fatty acids, vegetable oil derivatives
and / or partially hydrogenated vegetable oils, such as canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, oil derived from first distillation, rice bran oil, etc. Non-limiting examples of fatty acids (AG) have the following approximate distributions:
Fatty Acrylic Group AGÍ AG2 AG3 AG4 AG5
C12 vestiges vestiges 0 0 0
C14 3 3 0 0 0
C16 4 4 5 5 5
C18 0 0 5 6 6
C14: l 3 3 0 0 0
C16: l 11 7 0 0 3
C18: l 74 73 71 68 67
C18: 2 4 8 8 11 n
C18: 3 0 1 1 2 2
C20: l 0 0 2 2 2
C20 and more 0 0 2 0 0
Unknown 0 0 6 6"7
Total 100 100 102
VY 86-90 38-95 99 100 95
cis / trans (C18: l) 20-30 20-30 4 5 5
TPU 4 9 10 13 13
TPU is the percentage of polyunsaturates present. The mixtures of fatty acids, and mixtures of AG which are derived from different fatty acids can be used, and are preferred.Non-limiting examples of AG that can be mixed, to form the AGs of this invention are as follows: Fatty Acrylic Group AGS AG7 C14 0 1 C16 11 25 C18 4 20 C14: 1 0 C16: 1 1 C18: 1 27 45 C18: 2 50 6 C18: 3 7 0 Unknown 0 3 Total 100 100 VY 125-138 56 cis / trans (C18:: 1) Not available 7 PU 57 6
The AG is prepared from soybean fatty acid, and AG7 is prepared from slightly hydrogenated tallow fatty acid. ^ P Also, optionally, fatty acids can
to be replaced, when appropriate, by the corresponding alkylene groups. The R1 groups may also contain branched chains, for example, from isostearic acid, for at least part of the R1 groups. The total active ingredient represented by the groups
(?) Branched chain, when present, is typically from about 1% to 100%, preferably about 10% to 70%, more preferably from about 20% to 50%.
Fatty Acrylic Group AG8 AG5 AG10 Isomiristic acid - 1-2 - Myristic acid 7-11 0.5-1 - Isopalmitic acid 6-7 6-7 1-3 Palmitic acid 4-5 6-7 - Isostearic acid 70-76 80-82 60-66
Stearic acid - 2-3 8-10 Isoleic acid - - 13-17
Oleic acid - - 6-12 VY 3 2 7-12
AG8-AG10 are prepared from different isostearic acids commercially available. The softening active ingredients more
Preferred, especially DEQA, are those prepared as a single DEQA from mixtures of all the different fatty acids that are represented (total fatty acid mixture), preferably over the mixtures of separated DEQA compounds that are prepared. from different portions of the mixture of
^ P total fatty acid. It is preferred that at least a majority of the fatty acid, or alkyl, groups be unsaturated, for example, from about 50% to 100%, preferably from about 55% to 95%, more preferably from -about 60% to 90%, and that the level
total active ingredient containing fatty acyl groups
^ Polyunsaturated P (TPU) is preferably from about 3% to 30%. The cis / trans ratio is from 1: 1 to about 50: 1, the minimum being 1: 1, preferably at least 3: 1, and more preferably from about 4: 1 to 20: 1. (As used in the
Present, the "percentage of active softening ingredient" containing a given Rl group is the same as the percentage of that same group Rl to the total of Rl groups used to form all softening active ingredients).
The unsaturated fatty acyl and / or alkylene groups, including the preferred polyunsaturates discussed above and hereinafter, surprisingly
^ P provide effective softness, but also provide better soaking characteristics, good antistatic characteristics, and especially, superior recovery after freezing and thawing. Highly unsaturated materials are also easier to formulate in concentrated premixes than
^ P maintain their low viscosity and consequently are easier to process, for example, pump, mix, etc. These highly unsaturated materials (total level of active ingredient containing polyunsaturated fatty acyl groups (TPU) being typically about 3% a
30%, with only the low amount of solvent that is associated
^ P normally with these materials, ie, from about 5% to 20%, preferably from about 8% to 25%, more preferably from about 10% to 20%, by weight of the total softener / solvent mixture , they are also easier to formulate
in the stable, concentrated compositions of the present invention, even at ambient temperatures. This ability to process active ingredients at low temperatures is especially important for polyunsaturated groups, since it minimizes degradation. Protection can be provided
additional against degradation when the softening compounds and compositions contain antioxidants, chelating agents and / or effective reducing agents, as discussed below. The present invention may contain a medium-chain ammonium cationic fabric softening compound, including DEQA having the above formula (1) and / or formula 2, below, wherein: Each Y is -0- (0) C -, - (R) N- (0) C-, -C (0) -N (R) -, or -f C (0) -0-, preferably -0- (0) C -, - M is 2 or 3, preferably; each n is 1 or 4, preferably 2; each R is as defined above in the present; 15 each hydrophobic group R1, or YR1 is a hydrocarbyl
^ saturated, from 8 to 14 carbon atoms, preferably from 12 to 14 carbon atoms, or substituted hydrocarbyl substituent (the VY is preferably about 10 or less, more preferably less than about 5). [The sum of the
carbons in the hydrophobic group is the number of carbon atoms in the group R1, or in the group YR1 when Y is -0- (O) C- or - (R) N- (0) C-] and the ion A "is the same as above, preferably A" does not include phosphate salts.
Saturated fatty acyl groups of 8 to 14 carbon atoms can be pure derivatives or can be of mixed chain lengths. ^ P 'The sources of fatty acids suitable for
said fatty acyl groups are coconut, lauric, caprylic, and capric acids. For hydrocarbyl groups of 12 to 14 carbon atoms (or 11 to 13 carbon atoms), the groups are preferably saturated, for example, VY is
^ preferably less than about 10, preferably less than about 5. It will be understood that the substituents R and R1 may be optionally substituted with various groups such as alkoxy or hydroxyl groups, and may be straight or branched at
the extent to which the R1 groups maintain their character
^ hydrophobic basically. A preferred long chain DEQA is DEQA prepared from sources containing high levels of polyunsaturation, ie, N, -di (acyl-oxyethyl) -20 N, N-dimethyl ammonium chloride, wherein the acyl is derived of fatty acids that contain sufficient polyunsaturation, for example, mixtures of tallow fatty acids and soy fatty acids. Another preferred DEQA of long chain is the dioleyl (nominally) DEQA, ie DEQA in which the chloride of
N, -di (oleyl-oxyethyl) -N, -dimethyl ammonium is the main ingredient. Preferred fatty acid sources for these DEQAS are vegetable oils and / or partially hydrogenated vegetable oils, with high contents of 5 unsaturates, for example, oleyl groups. As used herein, when the DEQA diester is specified, it may include the monoester that is present. Preferably, at least about 80% of the DEQA is in the diester form, and from 0% to about 20% it can be
^ P monoester DEQA, for example, a group YR1 is OH, or -C (0) OH, and, for the formula 1, m is 2. The diamide and / or the corresponding mixed amide ester may also include the ingredient active with a long chain hydrophobic group, for example, a group YR1 is -N (R) H, or -C (0) OH. In the following, any finding, for example, levels, for the
^ P active ingredients monoesters is also applicable to the active ingredients monoamides. For the softener, under non-existent or low conditions of detergent carry, the percentage of monoester must be as low as possible
possible, preferably no more than about 5%. However, under high conditions of anionic detergent carryover or anionic detergent builder, some monoester may be preferred. The overall proportions of diester to monoester are approximately 100: 1 to 2: 1,
preferably from 50: 1 to about 5: 1, more preferable about 13: 1 to 8: 1. Under high detergent carryover conditions, the di / monoester ratio is preferably close to 11: 1. The level of monoester present can be controlled in the preparation of the DEQA. The above compounds, used as the quaternized amine ester softener material in the practice of this invention, can be prepared using standard reactive chemistry. In a synthesis of a diester variation of DTDMAC, an amine of the formula RN (CH2CH20H) 2 wherein R for example is alkyl, is esterified in both hydroxyl groups with an acid chloride of the formula R1C (0) C1, to form a amine which can be made cationic by acidification (an R is H) to be a kind of softener, or quaternized then with an alkyl halide, RX, to obtain the desired reaction product (where R and R1 are as defined above). However, it will be appreciated by those skilled in the chemical arts that this reaction sequence allows the preparation of a wide selection of agents. Notwithstanding another DEQA softening active ingredient which is suitable for the formulation of the concentrated clear liquid fabric softener compositions of the present invention has the formula
above (1) wherein a group R is a hydroxyalkyl group of 1 to 4 carbon atoms, preferably one wherein a group R is a hydroxyethyl group. An example of this hydroxyethyl ester active ingredient is di (acyloxyethyl) (2-hydroxyethyl) methylammonium methylisulfate, wherein the acyl group is derived from AG1 described hereinabove. (2) The second type of active ingredient DEQA has the general formula:
R3-N + -CH2-CH (YR1) -CHj-YR1 A "
where each y, R, R1 and A "have the same meanings as above These compounds include those with the formula:
[CH3] 3N (+1 [CH2CH (CH20 (O) CR1) O (O) CRJ Cl '"'
wherein each R is a methyl or ethyl group and preferably each R1 is in the range of 15 to 19 carbon atoms. Branching and substitution grades may be present in the alkyl or alkenyl chains. The nest X < _ > in the molecule it is the same as in the DEQA (1) above. An example of preferred DEQAs of formula (2) is
"propyl" quaternary ester fabric softener active ingredient having the formula 1,2-di (acyloxy) -3-trimethylammoniumpropane chloride, wherein the acyl group is the same
^ P than in AG5. These types of agents and general methods for making them are described in US Pat. No. 4,137,180, Naik et co-Inventors, issued January 30, 1979, which is incorporated herein by reference. In the DEQA softening active ingredients (1)
^ p, and (2) preferred, each R1 is a hydrocarbyl group, or substituted hydrocarbyl, preferably alkyl, monounsaturated alkenyl, and polyunsaturated alkenyl groups, with the active softening ingredient containing polyunsaturated alkenyl groups preferably at least about 3%, more 15 preferable at least about 5%, more preferable at least
^ P about 10%, and even more preferably at least about 15%, by weight of the total active softening ingredient present; the active ingredients preferably contain mixtures of R1 groups, especially in the individual molecules, and also, optionally, but preferably, the saturated groups R1 containing branched chains, for example, of isostearic acid, for at least part of the saturated R1 groups , the total active ingredient represented by the branched chain groups is preferably from
about 1% to 90%, preferably about 10% to 70%, more preferably about 20% to 50%. [In the ammonium fabric softening compounds
Q preferred quaternary, and especially in the DEQA, - (O) CR1 5 is unsaturated fatty acid derivative, for example, oleic acid, and / or fatty acids and / or partially hydrogenated fatty acids, animal fat derivatives, vegetable oils and / or partially hydrogenated vegetable oils, such as canola oil, sesame oil, oil,
^ peanut, sunflower oil, soybean oil, corn oil, oil derived from first distillation; rice bran oil, etc.] [As used herein, similar biodegradable fabric softening active ingredients, which contain ester linkages are referred to as 15"DEQA" which include diester, triester and
^ monoester containing one to three, preferably two, long chain hydrophobic groups. The corresponding amide softening active ingredients and the mixed amide ester softening active ingredients
may also contain one to three, preferably two, long chain hydrophobic groups. These fabric softening active ingredients have the characteristic that they can be processed by conventional means of mixing at room temperature, at least in the presence of
about 15% solvent C. as previously described herein]. The DEQAs of the present may also contain a
^ P1 low level of fatty acid, which may be of non-material
Reacted used to form the DEQA and / or as a by-product of any partial degradation (hydrolysis) of the softening active in the finished composition.
It is preferred that the level of free fatty acid be low, preferably below about 10%, and more preferably below about 5%, by weight of the softening active.
PREFERRED PROCEDURE FOR PREPARING ACTIVE INGREDIENTS
SOFTENERS 15 ^ P The softening active ingredients of the present invention are preferably prepared by a process wherein a chelating agent, preferably diethylenetriaminpentaacetate, is added to the process.
(DTPA) and / or an ethylenediamine-N, N'-disuccinate (EDDS). The resulting softening active ingredient has reduced discoloration and malodor associated with it. The typical procedure comprises the steps of:
a) providing a source of triglyceride and reacting the triglyceride source to form a mixture of fatty acids and / or esters of fatty acids; fl b) use the mixture formed from step (a)
to react: (1) under amidation conditions or conditions to form an imidazoline, with one or more amines of the formula R2-N-R2-NR-R2-NR2 wherein R is hydrogen or an alkyl or hydroxyalkyl group of chain
short of 1 to 6 carbon atoms, benzyl or mixtures thereof, more preferably an alkyl of 1 to 3 carbon atoms, much more preferably a methyl, ethyl, propyl or hydroxyethyl, with at least one R which is hydrogen in each terminal nitrogen, and wherein R2 is an alkylene group that
contains one to four carbon atoms, to form one
^ > mixture of fatty acid amides; or (2) with ammonium at high temperature to form a fatty amide followed by a subsequent reaction to produce a nitrilp and evolution of water, the nitrile is
reduced with hydrogen to a primary amine under heat, pressure and catalyst, and the subsequent reaction converts the primary amine to the desired digrase secondary amine; c) quaternizing, if desired, the mixture of fatty acid amides, or imidazolines, formed from step
(b) (1) by reacting the mixture under quaternizing conditions with a quaternizing agent of the formula RX wherein R is defined as in step (b) and X is an anion
Suitable for softener, preferably selected from the group consisting of chloride, bromide, methylisulfate, etiisulfate, sulfate, and nitrate, thus forming a quaternary fabric softening active ingredient, wherein at least step (c) is carried out in the presence of a chelating agent selected from the group consisting of j? diethylenetriaminepentaacetic acid, ethylenediamine-N, N'-disuccinic acid and mixtures thereof, or for (b) (2), if desired, quaternary chloride, secondary amine is methylated with methyl chloride in the presence of a caustic to form the chloride
dialkyldimethyl ammonium as described below, or
Alternatively, if quaternary methyl sulfate is desired, then the secondary amine is converted to a methyl tertiary amine by reaction with formalin and hydrogen in the presence of a catalyst and methyl amine
The resulting mixture is then quaternized with methyl chloride or dimethyl sulfate. The step of reacting the triglyceride source can additionally include the reaction in
presence of the chelating agent. Step (b) may additionally include the presence of the chelating agent. The total amount of chelating agent added
^ P is preferably within the range of about 10 ppm 5 to 5,000 ppm, more preferably within the range of about 100 ppm to 2500 ppm by weight of the active softening ingredient formed. The triglyceride source is preferably selected from the group consisting of animal fats, vegetable oils, partially vegetable oils.
Hydrogenated, and mixtures thereof. More preferably, the vegetable oil or partially hydrogenated vegetable oils are selected from the group consisting of canola oil, partially hydrogenated canola oil, sesame oil, partially hydrogenated sesame oil,
peanut, partially hydrogenated peanut oil,
^ P sunflower oil, partially hydrogenated sunflower oil, corn oil, partially hydrogenated corn oil, soybean oil, partially hydrogenated soybean oil, oil derived from first distillation, oil
partially hydrogenated first distillate derivative, rice bran oil, partially hydrogenated rice bran oil, and mixtures thereof. More preferably, the source of triglyceride is canola oil, partially hydrogenated canola oil, and mixtures
thereof. The method can also include the step of adding about 0.01% to 2% by weight of the composition of an antioxidant compound for any of steps (a), (b) or (c). The products of the previous procedure are new materials. The present invention also includes a process for the preparation of a premixed fabric softening composition. This method comprises preparing a fabric softening active as described above and mixing the fabric softening active ingredient, optionally containing a low molecular weight solvent with a main solvent having a ClogP of from about 0.15 to 0.64 thus forming a softening premix of fabrics. The premix may contain about 55% to 85% by weight of fabric softener active ingredient and about 10% to 30% by weight of principal solvent. The process may further comprise the step of adding a low molecular weight water soluble solvent from the group consisting of: ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate, hexylene glycol and mixtures thereof for the premix. Again, the method may also include the step of adding from about 0.01% to 2% by weight of the composition of an antioxidant compound to any of
Steps (a), (b) or (c). The products of the above process are also new compositions. The above procedures produce an active softening ingredient with reduced coloration and poor odor.
II. MAIN SOLVENT SYSTEM
The compositions of the present invention
They comprise less than about 40%, preferably about 10% to 35%, more preferably about 12% to 25%, and even more preferably about 14% to 20%, of principal solvent, by weight of the composition. Said main solvent is selected to minimize the impact of solvent odor
in the composition and to provide a low viscosity to
^ the final composition. For example, isopropyl alcohol is not very effective and has a strong odor. N-propyl alcohol is more effective, but it also has a distinctive odor. Several butyl alcohols also have
odors but can be used for effective transparency / stability, especially when used as part of a main solvent system to minimize odor. The alcohols are also selected to obtain optimum stability at low temperature, that is, they are capable
of forming liquid compositions with acceptable and translucent low viscosities, preferably transparent, below about 4.4 ° C and are capable of
^ P reset after being stored approximately 5 under 6.7 ° C. The desirability of any major solvent for the formulation of the liquid, concentrated, preferably transparent, fabric softener compositions of the present with the required stability is
^ surprisingly selective. Suitable solvents can be selected based on their partition coefficient (P) octanol / water. The octanol / water partition coefficient is the ratio between its equilibrium concentration in octanol and in water. The coefficients of
partition of the main solvent ingredients of this
The invention is conveniently given in the form of its base 10 logarithm, logP. The logP of many ingredients has been reported, - for example, the Pomona92 database, available in
Daylight Chemical Information Systems, Inc. (Daylight CIS), Irvine, California, contains many, along with citations to the original literature. However, the logP values are calculated much more conveniently by the "CLOGP" program, also available in Daylight CIS. This program
it also lists experimental logP values when they are available in the Pomona92 database. The calculated logP (ClogP) is determined by the fragmented method of Hansch fl and Leo (cf., A. Leo, in Comprehensive Medicinal Chemestry, 5 Vol 4, C. Hansch, PG Sammens, JB Taylor and CA Ramdsen, Eds., P. 295, Pergamon Press, 1990, incorporated herein by reference). The fragmented method is based on the chemical structure of each ingredient, and takes into account the numbers and types of atoms, the atomic connectivity and the
^ Chemical links. The ClogP values, which are the most reliable and widely used estimates for this psychemic property, are preferably used in place of the experimental logP values in the selection of the main solvent-ingredients which are useful in the present invention. Other methods that can be used ß? for the calculation of ClogP include, for example, the Crippen fragmentation method as described in J.Chem. Inf. Comput.Sci, 27.21 (1987); the method of Viswanadhan fragmentation as described in J. Chem. Inf. Comput. Sci.,
29, 163 (1989); and Broto method as described in Eur. J. Med. Chem. -Chim. Theor. , 19.71 (1984). The main solvents herein are selected from those having an approximate ClogP of 0.15 to 0.64, preferably from about 0.25 to 0.62, and more
preferable from about 0.40 to 0.60, said main solvent is preferably asymmetric, and preferably has a melting or solidification point that allows it to be liquid
9j) at or near room temperature. Solvents that have a low molecular weight and are biodegradable are also desirable for some purposes. -While solvents are more asymmetric they seem to be more desirable, while highly symmetrical solvents, which have a center of symmetry, such as 1,7-heptanediol, or 1,4- ^) bis (hydroxymethyl) cyclohexane, appear to be incapable of providing essentially transparent compositions when used alone, even if their ClogP values fall within the preferred range. The most appropriate principal solvent can be selected by determining whether a composition containing about 16-20% main solvent, and about 4-6% fl) of ethanol remains clear during storage at about 4.4 ° C and is recovered after being frozen at about -18 ° c. The most preferred main solvents can
to be identified by the appearance of the freeze-dried diluted treatment compositions used to treat fabrics. These diluted compositions appear to have fabric softener dispersions that exhibit a more unilamellar appearance than the softener compositions
of conventional cloth. The closer to unilaminar is the appearance, the compositions seem to behave better. These compositions provide surprisingly good fabric fleece when compared to similar compositions prepared in the conventional manner, especially when perfume is added to the compositions at, or near, room temperature. The main operable solvents are listed below in several listings, for example, diols fl | aliphatic or alicyclic with a given number of carbon atoms; monooles; glycerin derivatives; alkoxylates of diols; and mixtures of all the above. The preferred major solvents are in italics and the most preferred are in bold. The reference numbers are 15 the registration numbers of the Chemical Synopsis Service f) (CAS No.) for those compounds that have this number. The novel compounds have an identified method, described hereinafter, which can be used to prepare the compounds. Some inoperable main solvents are also listed below for comparison purposes. However, the main inoperable solvents can be used in mixtures with operable main solvents. The main operable solvents can be used to make fabric softening compositions that comply with
the stability / transparency requirements defined herein. Many diol main solvents that can have the same chemical formula can exist as many stereoisomers and / or optical isomers. Each isomer is normally assigned to a different CAS number. For example, different isomers of 4-methyl-1,2, 3-hexanediol are assigned to at least the following CAS numbers: 146452-51-9; 146452-50-8; 146452-49-5; 146452-48-4; 123807-f 34-1; 123807-33-0; 123807-32-9; and 123807-31-8. In the following listings, for simplicity, each chemical formula is listed as a single CAS number. This description is for exemplification only and is sufficient to allow the practice of the invention. The description
is not limiting. Consequently, it is understood that other fl) isomers with other CAS numbers and their mixtures are also included. In the same way, when a CAS number represents a molecule that contains some particular isotopes, for example, deuterium, tritium, carbon-13,
etc., it is understood that materials containing naturally distributed isotopes are also included, and vice versa. The methods discussed to prepare the solvents are amply described in the pending application, serial number 08 / 679,694, filed on 11
July 1996 on behalf of E.H. Wahl, T. Trinh, E.P. Gosselink, J.C. Letton and M.R. Sivik, by Fabric Softening Compound / Composition, said application is incorporated herein by reference.
TABLE I MONO-OLES
CAS No. n -propanol 71-23-8 CAS No. 2 -butanol 15892-23-6
2 - . 2-methyl-propanol 75-65-0
TABLE II
DIOLES C6
Operable isomers CAS No. 2, 3-dimethyl-2, 3-butanediol 76-09-5
2,3-dimethyl-1,2-butanediol 66553-15-9 3, 3-dimethyl-1,2-butanediol 59562-82-2 2-methyl-2,3-pentanediol 7795-80-4
3 - . 3-methyl-2, 3-pentanediol 63521-37-9 4-methyl -2, 3 -pe tanodi ol 7795-79-1 2, 3-hexanodi ol 617-30-1 fl,) 3, 4-hexanediol 922-17-8
2-ethyl-l, 2-butanediol 66553-16-0 2-methyl-1,2-pentanediol 20667-05-4 3-methyl-l, 2-pentanediol 159623-53-7 4-methyl-l, 2- pentanediol 72110-08-8 1, 2-hexanediol 6920-22-5
TABLE III
DIOLES C7 Operable isomers CAS No.
2-butyl-l, 3-propanediol 2612_-26-2 2, 2-diethyl -1,3-propanediol 115-76-4 2- (1-methylpropyl) -1, 3-propanediol 33673-01-7 2- (2-methylpropyl) -1,3-propanediol 26462-20-8 2-methyl-2-propyl-1,3-propanediol 78-26-2 2,3, 3-trimethyl-1,2-butanediol Method B 2 -ethyl -2-methyl-1,4-butanediol 7665Í-98-4 2-ethyl-3-methyl-1,4-butanediol 66225-34-1 2-propyl-1,4-butanediol 62946-68-3 2 -isopropyl -1, 4 -butanediol 39497-66-0
2, 2-dimethyl-l, 5-pentanediol 3121-82-2 2, 3-dimethyl-l, 5-pentanediol 81554-20-3, 4-dimethyl-1, 5-pentanediol 21-21-69-9 3 , 3-dimethyl-l, 5-pentanediol 53120-74-4 2, 3-dimethyl-2, 3-pentanediol 6931-70-0 2,4-dimethyl-2,3-pentanediol 66225-53-4 3, 4 -dimethyl -2,3-pentanediol 37164-04-8 4, 4-dimethyl-2,3-pentanediol 89851-45-6 2,3-dimethyl-3,4-pentanediol Method B 2-ethyl-1, 5- pentanediol 14189-13-0 2-methyl-l, 6-hexanediol 25258-92-8 3-methyl-1,6-hexanediol 4089-71-8 2-methyl -2,3-hexanediol 59215-55-3 3 - methyl -2, 3-hexanediol 139093-40-6 4 -methyl-2,3-hexanediol *** 5-methyl -2, 3-hexanediol Method B 2-methyl-3,4-hexanediol Method B 3 -methyl- 3, 4-hexanediol 18938-47-1 1, 3-heptanediol 23433-04-7 1, 4-heptanediol 40646-07-9 1, 5-heptanediol 60096-09-5 1, 6-heptanediol 13175-27-4 Preferred isomers
2 - . 2 - . 2 - . 2 - . 2-butyl-1, 3-propanediol 2612-26-2 2 -propi 1-1, -bu tanodi ol 62946-68-3 2-ethyl-l, 5-pentanediol 14189-13-0
2,3-dimethyl-2,3-pentanediol 6931-70-0 2,4-dimethyl-2,3-pentanediol 66225-53-4
3, 4-dimethyl-2,3-pentanediol 37164-04-8
4, 4-dimethyl-2, 3-pentanediol 89851-45-6 2, 3-dimethyl-3,4-pentanediol Method B 2-methyl-1,6-hexanediol 25258-92-8 3-methyl-1, 6 -hexanodiol 4089-71-8
1,3 -hep tanodi ol 23433-04-7
1, 4-heptanediol 40646-07-9
1, 5-heptanediol 60096-09-5
1, 6-heptanediol 13175-27-4
More preferred isomers 2,3-dimethyl-2,3-pentanediol 6931-70-0
2, -dimethyl-2, 3-pentanediol 66225-53-4
3,4-dimethyl-2,3-pentanediol 37164-04-8
4,4-dimethyl-2,3-pentanediol 89851-45-6
2, 3-dimethyl-3, 4-pentanediol Method B
and mixtures thereof.
TABLE IV
ISOTHERS OF OCTANODIOL
DERIVATIVES OF PROPANODIOL fl ^ Chemical name CAS No. Operable isomers 2- (2-methylbutyl) -1, 3-propanediol 87194-40-9
2- (1, 1-dimethylpropyl) -1, 3-propanediol Method D
2- (1,2-diraethylpropyl) -1,3-propanediol Method D
2- (1-ethylpropyl) -1,3-propanediol 25462-28-6 f 2- (1-methylbutyl) -1,3-propanediol 22131-29-9
2- (2,2-dimethylpropyl) -1, 3-propanediol Method D
2- (3-methylbutyl) -1,3-propanediol 25462-27-5
2-Butyl-2-methyl-1,3-propanediol 3121-83-3
2-ethyl-2-isopropyl-l, 3-propanediol 24765-55-7
2-Ethyl-2-propyl -1,3-propanediol 25450-88-8 fl) 2-methyl-2- (1-methylpropyl) -1, 3-propanediol 813-60-5
2-methyl-2- (2-methylpropyl) -1,3-propanediol 25462-42-4 2-butyl-tertiary-2-methyl-1,3-propanediol 25462-45-7 More preferred isomers 2- (1, 1-dimethylpropyl) -1,3-propanediol Method D
2- (1,2-Dimethylpropyl) -1,3-propanediol Method D
2- (1-ethylpropyl) -1,3-propanediol 25462-28-6
2- (2, 2-dimethylpropyl) -1,3-propanediol Method D
2-ethyl-2-isopropyl-l, 3-propanediol 24765-55-7
2-methyl-2- (1-methylpropyl) -1,3-propanediol 813-60-5
2-methyl-2- (2-methylpropyl) -1,3-propanediol 25462-42-4
2-butyl-tertiary-2-methyl-1,3-propanediol 25462-45-7
BUTANODIOL DERIVATIVES Operable Isomers 2, 2-diethyl-l, 3-butanediol 9g799-77-6
2- (1-methylpropyl) -1,3-butanediol Method C flk 2 -butyl-1,3-butanediol 83988-22-1
2-Ethyl-2,3-dimethyl-1,3-butanediol Method D 2- (1,1-dimethylethyl) -1,3-butanediol 67271-58-3 2- (2-methylpropyl) -1,3-butanediol Method C 2 -methyl-2-isopropyl-1,3-butanediol Method C 2-methyl-2-propyl-1,3-butanediol 99799-79-8 fl) 3-methyl-2-isopropyl-1,3-butanediol Method C 3-methyl-2-propyl-l, 3-butanediol Method D 2,2-diethyl-1,4-butanediol Method H 2 -methyl-2-propyl-1,4-butanediol Method H 2- (1 - methylpropyl) -1,4-butanediol Method H 2 -ethyl-2,3-dimethyl-1,4-butanediol Method F 2 -ethyl-3,3-dimethyl-1,4-butanediol Method F 2- (1, 1) -dimethylethyl) -1,4-butanediol 36976-70-2
2- (2-methylpropyl) -1,4-butanediol Method P 2 -methyl-3-propyl-1,4-butanediol 90951-76-1 3-methyl-2-isopropyl-1,4-butanediol 9g799-24- 3
Preferred isomers 2, 2-diethyl-1,3-butanediol 99799_77_s
2- (1-methylpropyl) -1, 3 -butanediol Method C
2 -butyl -1,3 -bu tanodi ol 83988-22-1
2-ethyl-2,3-dimethyl-1,3-butanediol Method D
2- (1,1-dimethylethyl) -1,3-butanediol 67271-58-3
2- (2-methylpropyl) -1, 3 -butanediol Method C
2 - . 2 - . 2 -metil -2- i sopropi 1-1, 3 -bu tanodi ol Method C
2-methyl-2-propyl 1-1,3 -bunediol 99799-79-8
3 - . 3-methyl-2-propyl 1-1, 3-butanediol Method D
2, 2-diethyl-l, 4-butanediol Method H
2-ethyl-2, 3-dimethyl-1,4-butanediol Method F
2-ethyl-3, 3-dimethyl-1,4-butanediol Method F
2- (1,1-dimethylethyl) -1,4-butanediol 36976-70-2
3-methyl-2-isopropyl-1,4-butanediol 99799-24-3
More preferred isomers 2- (1-methylpropyl) -1,3-butanediol Method C
2- (2-methylpropyl) -1,3-butanediol Method C
2-butyl-1,3-butanediol 83988-22-1 2-methyl-2-propyl-l, 3-butanediol 99799-79-8 3-methyl-2-propyl-l, 3-butanediol Method D 2.2 -diethyl-1,4-butanediol Method H 2-ethyl-2, 3-dimethyl-1,4-butanediol Method F 2 -ethyl-3, 3-dimethyl-1,4-butanediol Method F 2- (1, 1) -dimethylethyl) -1,4-butanediol 36976-70-2
TRIMETHYLPENTANODIOL ISOMERS Operable isomers 2,2, 3-trimethyl-1,3-pentanediol 35512-54-0 2, 2,4-trimethyl-1,3-pentanediol 144-19-4 2,3,4-trimethyl-1 , 3-pentanediol 116614-13-2 2, 4, 4-trimethyl-l, 3-pentanediol 109387-36-2 3,4, 4-trimethyl-l, 3-pentanediol 81756-50-5 2.2, 3 -trimethyl-l, 4-pentanediol Method H 2,2, 4-trimethyl-1,4-pentanediol 80864-10-4 2,3, 3-trimethyl-1,4-pentanediol Method H 2,3,4-trimethyl -l, 4-pentanediol 92340-74-4 3,3, 4-trimethyl-1,4-pentanediol 16466-35-6 2,2, 3-trimethyl-l, 5-pentanediol Method F 2.2, 4- trimethyl-l, 5-pentanediol 3465-14-3 2,3, 3-trimethyl-l, 5-pentanediol Method A
2,3,4-trimethyl-1,5-pentanediol 85373-83-7 2,3, 3-trimethyl-2,4-pentanediol 24892-51-1 2,3,4-trimethyl-2,4-pentanediol 24892 -52-2
Preferred isomers 2, 2, 3-trimethyl-1,3-pentanediol 3-5-512-54-0 2, 2,4-trimethyl-1,3-pentanediol 144-19-4 2,3,4-trimethyl- l, 3-pentanediol 116614-13-2 2,4, 4-trimethyl-1,3-pentanediol 109387-36-2 3,4, 4-trimethyl-1,3-pentanediol 81756-50-5
2. 2, 3-trimethyl-l, 4-pentanediol Method H 2, 2, 4-trimethyl-1,4-pentanediol 80864-10-4
2. 3, 3-trimethyl-1,4-pentanediol Method F 2,3,4-Trimethyl-1,4-pentanediol 92340-74-4 3,3, 4-trimethyl-1,4-pentanediol 16466-35-6 2 , 2, 3-trimethyl-l, 5-pentanediol Method A
2. 2, 4-trimethyl-l, 5-pentanediol 3465-14-3 2, 3, 3-trimethyl-1,5-pentanediol Method A
2. 3, 4 -trimeti 1-2, 4 -pentanediol 24892-52-2
Most preferred 2,3B-rimethyl-1,3-pentanediol 116614-13-2 2, 3, 4-trimethyl-1,4-pentanediol 92340-74-4
2, 2, 3-trimethyl-l, 5-pentanediol Method A 2, 2, 4-trimethyl-l, 5-pentanediol 3465-14-3 2,3, 3-dimethyl-1,5-pentanediol Method A
ETHERMETILPENTANODIOL ISOMERS Operable isomers 2-ethyl-2-methyl-l, 3-pentanediol Method C 2-ethyl-3-methyl-1,3-pentanediol Method D 2 -ethyl-4-methyl-1,3-pentanediol 148904 -97-6 3-ethyl-2-methyl-1,3-pentanediol 55661-05-7 2-ethyl-2-methyl-i, 4-pentanediol Method H 2 -ethyl-3-methyl-1,4-pentanediol Method F 2 -ethyl-4-methyl-1,4-pentanediol Method G 3-ethyl-2-methyl-1,4-pentanediol Method F 3 -ethyl-3-methyl-1,4-pentanediol Method F 2-ethyl -2-methyl-1, 5-pentanediol Method F 2-ethyl-3-methyl-1,5-pentanediol 54886-83-8 2-ethyl-4-methyl-1,5-pentanediol Method F 3 -ethyl-3 -methyl-1,5-pentanediol 57740-12-2 3 -ethyl-2-methyl -2,4-pentanediol Method G
More preferred isomers 2-ethyl-2-methyl-1,3-pentanediol Method C
2-Ethyl-3-methyl-1,3-pentanediol Method D 2-ethyl-4-methyl-1,3-pentanedione 148904-97-6 3-ethyl-2-methyl-1,3-pentanediol 55661- 05-7 2-ethyl-2-methyl-l, 4-pentanediol Method H 2-ethyl-3-methyl-1,4-pentanediol Method F 2-ethyl-4-methyl-1, pentanediol Method G 3-ethyl -3-methyl-l, 5-pentanediol 57740-12-2 3-ethyl-2-methyl-2,4-pentanediol Method G
ISOPHERES OF PROPYLPENTANODIOL Operable isomers 2- isopropyl -1, 3-pentanediol -Method D 2-propyl-1,3-pentanediol Method C 2-isopropyl-1,4-pentanediol Method H 2-propy1-1,4-pentanediol Method H 3- isopropyl-1,4-pentanediol Method H 2-isopropyl-l, 5-pentanediol 90951-89-6 3-propyl -2,4-pentanediol Method C
More preferred isomers 2-isopropyl-1,3-pentanediol Method D 2-propyl-1,3-pentanediol Method C 2-isopropyl-1,4-pentanediol Method H
2-propyl-1,4-pentanediol Method H
3-isopropyl-1, -pentanediol Method H
3 - . 3-propyl-2, 4-pentanediol Method C
ISOMMERS OF DIMETILHEXANODIOL Operable isomers 2, 2-dimethyl-l, 3-hexanediol 22006-96-8 2, 3-dimethyl-1,3-hexanediol Method D 2,4-dimethyl-1,3-hexanediol 78122-99-3 fl} 2,5-dimethyl-l, 3-hexanediol Method C 3,4 -dimethyl-1,3-hexanediol Method D 3, 5-dimethyl-1,3-hexanediol Method D 4,4-dimethyl-1,3-hexanediol Method C 4, 5-dimethyl-1,3-hexanediol Method C 2, 2-dimethyl-1,4-hexanediol Method F
?) 2, 3-dimethyl-l, 4-hexanediol Method F 2, 4-d? Meth? Ll, 4-hexanediol Method G 2,5-d? Methyl-1,4-hexanediol 22417-60-3 3 , 3-dimethyl-l, 4-hexanediol Method F 3, 4-d? Methyl-l, 4-hexanediol Method E 3, 5-dimethyl-1,4-hexanediol Method H 4,5-dimethyl-1, -hexanediol Method E 5, 5-dimethyl-1,4-hexanediol 38624-38-3
2, 2-dimethyl-1,5-hexanediol Method A 2,3-dimethyl-1,5-hexanediol 62718-05-2 2,4-dimethyl-1,5-hexanediol 73455-82-0 f 2,5- dimethyl-1,5-hexanediol 58510-28-4 3,3-dimethyl-1,5-hexanediol 41736-99-6 3,4-dimethyl-1,5-hexanediol Method A 3, 5-dimethyl-1, 5 -hexanediol Method G 4, 5-dimethyl-1,5-hexanediol Method F 2, 2-dimethyl-1,6-hexanediol 13622-91-8 flk 2,3-dimethyl-1,6-hexanediol Method F
2,4-dimethyl-1,6-hexanediol Method F 2, 5-dimethyl-1,6-hexanediol 49623-11-2 3,3-dimethyl-1,6-hexanediol Method F 3,4-dimethyl-1 6-hexanediol 65363-45-3 2,3-dimethyl-2,4-hexanediol 26344-17-2 f 2,4-dimethyl-2,4-hexanediol 2964g-22-7 2, 5-dimethyl-2, 4 -hexanediol 3899-89-6 3, 3-dimethyl-2,4-hexanediol 42412-51-1 3,4-dimethyl-2,4-hexanediol 90951-83-0
3, 5-dimethyl-2,4-hexanediol 159300-34-2 4, 5-dimethyl-2,4-hexanediol Method D 5, 5-dimethyl-2,4-hexanediol 108505-10-8 2, 3-dimethyl - 2, 5-hexanediol Method G
2,4-dimethyl-2, 5-hexanediol Method G 2,5-dimethyl-2,5-hexanediol 110-03-2 3, 3-dimethyl-2,5-hexanediol Method H 3, 4-dimethyl-2, 5-hexanediol 9g799-30-l 3, 3-dimethyl-2,6-hexanediol Method A
More preferred isomers 2,2-dimethyl-1,3-hexanediol 22006-96-8 2, 3-dimethyl-l, 3-hexanediol Method D 2,4-dimethyl-1,3-hexanediol 78122-99-3 2, 5-dimethyl-1,3-hexanediol Method C 3, 4-dimethyl-1,3-hexanediol Method D 3, 5-dimethyl-1,3-hexanediol Method D 4, -dimethyl-1,3-hexanediol Method C 4 , 5-dimethyl-l, 3-hexanediol Method C 2,2-dimethyl-1,4-hexanediol Method H 2, 3-dimethyl-1,4-hexanediol Method F 2,4-dimethyl-1,4-hexanediol Method G 2, 5-dimethyl-l, 4-hexanediol 22417-60-3 3, 3-dimethyl-1,4-hexanediol Method F 3,4-dimethyl-1,4-hexanediol Method E 3, 5-dimethyl-1 , 4-hexanediol Method H 4, 5-dimethyl-1,4-hexanediol Method E
, 5-dimethyl-l, -hexanediol 38624-38-3 2, 2-dimethyl-1,5-hexanediol Method A 2, 3-dimethyl-l, 5-hexanediol 62718-05-2
^ H 2, 4-dimethyl-l, 5-hexanediol 73455-82-0 2, 5-dimethyl-l, 5-hexanediol 58510-28-4 3, 3-dimethyl-l, 5-hexanediol 41736-99-6 3, 4-dimethyl-l, 5-hexanediol Method A 3,5-dimethyl-1,5-hexanediol Method G 4,5-dimethyl-1,5-hexanediol Method F fll 3, 3-dimethyl-2,6- hexanediol Method A
ETHYLEXANODIOL ISOMERS More preferred isomers 2-ethyl-l, 3-hexanediol 94-96-2 4-ethyl-l, 3-hexanediol Method C 2-ethyl-1,4-hexanediol 148904-97-6 4-ethyl-1 , 4-hexanediol 1113-00-4 2-ethyl-l, 5-hexanediol 58374-34-8 3-ethyl-2,4-hexanediol Method C 4-ethyl-2,4-hexanediol 33683-47-5 3- ethyl-2, 5-exanodium1 Method F
ISOTHERS OF METILHEPTANODIOL
Operable isomers 2-methyl-1,3-heptanediol 109417-38-1 3-methyl-1,3-heptane diol 165326"-88-5 4-methyl-1,3-heptane diol Method C 5-methyl- 1, 3 - heptanediol Method D 6-methyl-1,3-heptane diol Method C 2-methyl-1,4-heptane diol 15-66-03-7 3-methyl-1,4-heptanediol 7748-38-1 4-methyl-1, 4-heptanediol 72473-94-0 5-methyl-1, 4-heptanediol 63003-04-3 6-methyl-1,4-heptanediol 99799-25-4 2-methyl-1,5-heptane diol 141605-00-7 3-methyl-1,5-heptanediol Method A 4-methyl-1,5-heptanediol Method A 5-methyl-1,5-heptanediol 99799-26-5 6-methyl-1,5-heptanediol 57740-00-8 2-methyl-1,6-heptanediol 132148-22-2 3-methyl-1,6-heptanediol Method G 4-methyl-1,6-heptanediol 156307-84-5 5-methyl-1,6-heptanediol Method A 6-methyl-1,6-heptanediol 5392-57-4 2-methyl-2,4-heptanediol 38836-26-9 3-methyl-2,4-heptanediol 6964-04-1
4-methyl-2, 4-heptanediol 165326-87-4 5-methyl-2,4-heptanediol Method C 6-methyl- • 2,4-heptanediol 79356-95-9 f 2-methyl • 2,5- heptanediol 14160-5-02-9 3-methyl -2, 5-heptanediol Method G 4-methyl -2,5-heptanediol 156407-38-4 5-methyl • 2,5-heptanediol 148843-72-5 6-methyl -2, 5-heptanediol 51916-46-2 2-methyl -2,6-heptanediol 73304-48-0 f 3-methyl -2,6-heptanediol 29915-96-6 4-methyl -2,6-heptanediol 106257 -69-6 3-methyl-3, 4-heptanediol 18938-50-5 2-methyl-3, 5-heptanediol Method C 3-methyl-3,5-heptanediol 99799-27-6 4-methyl-3, 5 -heptanediol 156407-37-3
^ h Isomer 3 more preferred 2-methyl-1,3-heptanediol 109417-38-1 3-methyl-l, 3-heptane diol 165326-88-5 4-methyl-l, 3-heptane diol Method C 5-methyl-1 , 3-heptanediol Method D 6-methyl-l, 3-heptanediol Method C 2-methyl-1,4-heptanediol 15-6603-7 3-methyl-1,4-heptanediol 774838-1
-methyl-, 1,4-heptanediol 72473-94-0 -methyl- 1,4-heptanediol 63003-04-3 -methyl-1, -heptanediol 99799-25-4 -methyl-1,5-heptanediol 141605-00- 7-methyl-1,5-heptanediol Method A -methyl-1,5-heptanediol Method A -metxl-1,5-heptanediol 9979g-26-5-methoxy-1,5-heptanediol 57740-00-8-methyl- 1, 6-heptanediol 132148-22-2-methyl-1,6-heptanediol Method G-methyl-1,6-heptanediol 156307-84-5-methyl-1,6-heptanediol Method A-methyl-1, 6- heptanediol 5392-57-4-methyl-2, 4-heptanediol 38836-26-9-methyl-2, -heptanediol 6964-04-1 -methyl-2,4-heptanediol 165326-87-4 -methyl-2, 4 -heptanediol Method C -metxl- 2,4-heptanediol 79356-g5-g-methyl-2,5-heptanediol 141605-02-9-methyl-2,5-heptanediol Method H-methyl-2,5-heptanediol 156407- 38-4-methyl-2, 5-heptanediol 148843-72-5-methyl-2, 5-heptanediol 51916-46-2
2-methyl-2,6-heptanediol 73304-48-0 3 -methyl-2,6-heptanediol 29915-96-6 4-methyl-2,6-heptanediol 106257-69-6 3 -methyl-3, 4- heptanediol 18938-50-6 2-methyl-3, 5-heptanediol Method C 4-methyl-3,5-heptanediol 156407-37-3
OCTANODIOL ISOMERS Most preferred isomers 2-octanediol 90162-24-6 2, 5-octanediol 4527-78-0 2,6-octanediol Method A 2,7-octanediol 19686-96-5 3, 5-octanediol 24892-55 -5 3, 6-octanediol 24434-09-1
•
TABLE V
NONANODIOL ISOMERS
Chemical name CAS No. Preferred isomers 2,3,3, -tetramethyl-2,4-pentanediol 19424-43-2
Operable isomers 3-butyl tertiary-2,4-pentanediol 142205-14-9 2,5,5-trimet-l-2,4-hexanedione 97460-08-7 3, 3,4-trimethyl-2,4- hexanediol Method D 3,3,5-t-methyl-2,4-hexanediol 27122-58-3 3,5,5-trimethyl-2,4-hexanediol Method D 4,5,5-trimethyl-2,4- hexanediol Method D 3, 3, 4 -trimethyl-2,4-hexanediol Method H 3,3, 5-trimethyl-2,4-hexanediol Method G
BOX VY
ETHERIES ALKYLGLYCERÍLICOS, ETHER DI (HIDROXIALQUÍ ICOS) AND ETHER ARILGLYCERÍLICOS
Preferred monoglycerol ethers and derivatives 3 - (butyloxy) -1, 2-propanediol, trietoxylated 3 - (butyloxy) -1,2-propanediol, tetraethoxylated
Monoglycerol ethers and most preferred derivatives CAS No.
3- (n-pentyloxy) -1,2-propanediol 22636-32-4
3- (2-pentyloxy) -1,2-propanediol 3- (3-pentyloxy) -1,2-propanediol
3- (2-methyl-l-bufcyloxy) -1,2-propanediol 3- (iso-amyloxy) -1,2-propanediol 3- (3-methoxy-2-butyloxy) -1,2-propanediol fl) 3 - (cyclohexyloxy) -1, 2-propanediol 3- (1-cyclohex-l-enxoxy) -1,2-propanediol
2- (Pentyloxy) -1,3-propanediol 2- (2-pentyloxy) -1,3-propanediol 2- (3-pentyloxy) -1,3-propanediol 2- (2-methyl-1-butyloxy) -1 , 3-propanediol ^ B) 2- (iso-amyloxy) -1,3-propanediol 2- (3-methyl-2-butyloxy) -1,3-propanediol 2- (cyclohexyloxy) -1,3-propanediol 2 (1-cyclohex-l-enxloxy) -1, 3-propanediol
3- (Butyloxy) -1,2-propanediol, pentaethoxylated
3- (butyloxy) -1,2-propanediol, hexaethoxylated fl) 3- (butyloxy) -1,2-propanediol, heptaethoxylated 3- (butyloxy) -1,2-propanediol, octaethoxylated 3- (butyloxy) -1, 2 -propanediol, nonaethoxylated 3- (butyloxy) -1,2-propanediol, monopropoxylated 3- (butyloxy) -1,2-propanediol, dibutylexylated 3- (butyloxy) -1,2-propanediol, tributyleneoxylated
Most preferred di (hxdroxyalkyl) ethers
bis (2-h. ± hydroxyethyl) ether bis (2-hydroxycyclopentyl) ether
GLYCERIL EARS AROM TICOS Operable aromatic glyceryl ethers
3 - . 3 - . 3 - . 3-phenyloxy-1,2-propanediol 3-benzyloxy-1,2-propanediol 3- (2-pentylethyloxy) -1,2-propanediol
3- (l-Phenyl-2-propanyloxy) -1,2-propanediol
2-phenyloxy-1,3-propanediol 2- (m-cresyloxy) -1,3-propanediol 2- (p-cresyloxy) -1,3-propanediol 2-benzyloxy-1,3-propanediol 2- (2-phenylethyloxy) ) -1, 3-propanediol
2- (1-phenylethyloxy) -1,3-propanediol
Preferred aromatic glyceryl ethers
3-Phenyloxy-1,2-propanediol 3-benzyloxy-1,2-propanediol 3 - (2-phenylethyloxy) -1,2-propanediol
2- (m-cresyloxy) -1,3-propanediol 2- (p-cresyloxy) -1,3-propanediol
2 - . 2-benzyloxy-1, 3-propanediol 2 - (2-phenylethyloxy) -1,3-propanediol
Preferred aromatic glyceryl ethers 3-phenyloxy-1,2-propanediol 3-benzyloxy-1,2-propanediol 3- (2-phenylethyloxy) -1,2-propanediol 2- (m-cresyloxy) -1,3-propanediol 2 (p-cresyloxy) -1,3-propanediol 2- (2-phenylethyloxy) -1,3-propanediol
TABLE VII ALICYCLIC AND DERIVED DIOLES
Chemical name CAS No.
Cyclic diols and preferred derivatives 1- isopropyl -1,2-cyclobutanediol 59895-32-8
3-tyl-4-methyl-1,2-cyclobutanediol 3-propyl -1,2-cyclobutanediol 3-isopropyl-1,2-cyclobutanediol 42113 -90-6
1 - . 1 - ethyl -1, 2-cyclopentanediol 67396-17-2
1, 2-dimethyl-l, 2-cyclopentanediol 33046-20 -7
, 4-dimethyl-1,2-cyclopentanediol 89794-56-9, 4,5-trimethyl-1,3-cyclopentanediol, 3-dimethyl-1,2-cyclopentanediol 89794-57-0, 4-dimethyl-2, -cyclopentanediol 7-0051-69-3, 5-dimethyl-1,2-cyclopentanediol 89794-58-1 -ethyl -1, 2-cyclopentanediol, 4-dimethyl-1,2-cyclopentanediol -J70197-54-5 -ethyl -l, 2-cyclopentanediol
, 1-bis (hydroxymethyl) cyclohexane 2658-60-8, 2-bis (hydroxymethyl) cyclohexane 76155-27-6, 2-dimethyl-l, 3-cyclohexanediol 53023-07-7, 3 -bi s (hi hydroxymethyl) ) ciel ohexano 13022-98-5, 3-dimetil-l, 3-ciciohexanediol 12.8749-93-9, 6 -dimethyl-1,3-ciciohexanediol 164713-16-0-hydroxy-cyclohexaneethanol 40894-17-5 -hydroxy- cyclohexanemethanol 15753-47-6 - ethyl -1,3-cyclohexanediol 10601-18-0 -methyl-l, 2-cyclohexanediol 32718-65-7, 2-dimethyl-l, 3-cyclohexanediol 114693-83-3, 3- dimethyl-l, 4-cyclohexanediol 70156-82-0, 4-dimethyl-l, 3-cyclohexanediol, 5-dimethyl-1,3-cydohexanediol
, -dimetil-l, -ciciohexanodiol 34958-42-4 2-etil-l, 3-ciciohexanodiol 155433-88-8 2-hi droxici clohexanoethanol 24682-42-6
(B 2 -hydroxy: ethyl-1-cyclo-exanol 2-hydroxymethyl-cyclohexanol 89794-52-5 3-hydroxyethyl-1-cyclohexanol 3-hydroxy-cyclohexane tanol 86576-87-6 3-hydroxymethylcyclohexanol 3-methyl-1 , 2-cedhexanodium ol 23477-91-0 4, 4-dimethyl-1,3-cydohexanediol 14203-50-0 4, 5-dimethyl-l, 3-cyclohexanediol 4,6-dimethyl-1,3-cydohexanediol 16066 -66-3 4-ethyl-l, 3-cyclohexanediol 4-hydroxyethyl-1-cyclohexanediol 4-hydroxymethylcyclohexanol 33893-85-5 f) 4-methyl-1,2-cyclohexanediol 28832-27-1
, 5-dimethyl-1,3-cydohexanediol 51335-83-2 5-ethyl-l, 3-cydohexanediol
1, 2-cycloheptanediol 108268-28-6 2-methyl-l, 3-cycloheptanediol 101375-80-8 2-methyl-l, 4-cycloheptanediol 4-methyl-l, 3-cycloheptanediol
-methyl-1, 3-cycloheptanediol 5-methyl-1, 4-cycloheptanediol 90201-00-6
6-methyl-l, 4-cycloheptanediol
1,3-cyclooctanediol 101935-36-8
1,4-cyclooctanediol 73982-04-4
1, 5-cyclooctanediol 23418-82-8
1,2-cyclohexanediol 1,2-cyclohexanediol 1,2-cyclohexanediol 1,2-cyclohexanediol ethoxylate 1,2-cyclohexanediol 1,2-cyclohexanediol heptaethoxylate 1,2-cyclohexanediol octaetoxylated 1,2-cyclohexanediol nonaethoxylate of 1,2-cyclohexanediol monopropoxylate of 1,2-cyclohexanediol monobutyleneoxylate of 1,2-cyclohexanediol dibutyleneoxylate of 1,2-cyclohexanediol tributyleneoxylate of 1,2-cydohexanediol
Chemical name CAS No.
Cyclic diols and most preferred derivatives1-isopropyl-1,2-cyclobutanediol 59895-32-8 3-ethyl-4-methyl-1,2-cyclobutanediol 3-propyl-1,2-cyclobutanediol flj) 3-isopropyl-1,2-cyclobutanediol 42113-90 -6
1-Etxl-1,2-cyclopentanediol 67396-17-2
1, 2-dimethyl-l, 2-cyclopentanediol 33046-20-7
1, -dimethyl-l, -cyclopentanediol 89794-56-9
3, 3-dimethyl-l, 2-cyclopentanediol 89794-57-0
3, 4-dimethyl-1,2-cyclopentanediol 70051-69-3
3, 5-dimethyl-l, 2-cyclopentanediol 89794-58-1
3-ethyl-l, 2-cyclopentanediol 4, 4-dimethyl-1,2-cyclopentanediol 70197-54-5
4-ethyl-l, 2-cyclopentanediol
?) f 1, 1-bis (hydroxymethyl) cyclohexane 2658-60-8 1, 2-bis (hydroxymethyl) cyclohexane 76155-27-6 1,2-dimethyl-1,3-cydohexanediol 53023-07-7 1.3 -bis (hydroxymethyl) cyclohexane 13022-98-5 1-hydroxy-cyclohexanomethanol 15753-47-6 1-methyl-1,2-cydohexanediol 52718-65-7 3-hxdroxxmethylcyclohexanol 3-methyl-1,2-cydohexanediol 23477-91 -0
4, 4-dimethyl-l, 3-cyclohexanediol 14203-50-0
4, 5-dimethyl-l, 3-cyclohexanediol 4,6-dimethyl-l, 3-cyclohexanediol 16066-66-3
4-ethyl-l, 3-cydohexanediol 4-hydroxyethyl-1-cyclohexanol 4-hydroxymethylcyclohexanol 33893-85-5
4-methyl-l, 2-cydohexanediol 23832-27-1
Operable unsaturated alicyclic diols CAS Chemical name No. 1-ethenyl-2-ethyl-1,2-cyclobutanediol 58016-14-1 l, 2,3,4-tetramethyl-3-cyclobutene-l, 2-diol 90112-64- 4
3,4-diethyl-3-cyclobutene-l, 2-diol 142543-60-0
3- (1,1-dimethylethyl) -3-cyclobutene-l, 2-diol 142543-56-4
3-butyl-3-cyclobutene-l, 2-diol 142543-53-3
1,2-dimethyl-4-methylene-1,2-cyclopentanediol 103150-02-3
1-Ethyl-3-methylene-1,2-cyclopentanediol 90314-52-6
4- (1-propenyl) -1, 2-cyclopentanediol 128173-45-5
1-Ethyl-3-methyl-3-cyclopentene-1,2-diol 90314-43-5
1-ethenyl-1,2-cyclohexanediol 134134-16-0
1-methyl-3-methylene-1,2-cyclohexanediol 98204-78-5
1-metll-4-methylene-1,2-cyclohexanediol 133358-53-9
3-ethenyl-l, 2-cyclohexanediol 55310-51-5
4-ethene-1, 2-cyclohexanediol 85905-16-4 f) 2,6-dimethyl-3-cyclohexene-1,2-diol 81969-75-7
6, 6-dimethyl-3-cyclohexene-1,2-diol 61875-93-2
3, 6-d? Methyl-4-c? Clohexene-1, 2-diol 156808-73-0
4,5-dimethyl-4-cyclohexene-1,2-diol 154351-54-9
3-cyclooctene-l, 2-diol 170211-27-5 f 4-cyclooctene-l, 2-diol 124791-61-3
-cyclooctene-l, 2-diol 117468-07-2
TABLE VIII ALCOXYLED DERIVATIVES OF DIOLES FROM 3 TO 7 ATOMS OF CARBON
fl) In the following tables, "EO" means polyethoxylates, that is, - (CH2CH20) nCH3; "2Me-En" means 2 required Me-En groups; "PO" means polypropoxylates, - (CH (CH 3) CH 2?) N H; "BO" means polybutyleneoxy groups, (CH (CH2CH3) CH20) nH; and "n-BO" means poly (n-10-butyleneoxy) or poly (tetramethylene) oxy- (CH2CH2CH2CH20) nH groups. The alkoxylated derivatives indicated are all operable and those which are preferred are in bold type and listed in the second line. The synthesis methods
Typical non-limiting preparations for preparing alkoxylated derivatives are given in the copending application, incorporated herein by reference.
TABLE VIIIA
(a) the number of alkoxylated groups indicated in this table and in the following tables VIII corresponds to operable groups, the generic limits listed in the first line, and those that are preferred are in bold and listed in the second line. (b) The numbers in this column are the average group numbers (CH2CH20) in the polyethoxylated derivative. (c) The numbers in this column are average numbers of groups (CH2CH20) in the single methyl-capped polyethoxylated substituent of each derivative. (d) The numbers in this column are average numbers of groups (CH2CH20) in each of the two methyl-capped polyethoxylated substituents of each derivative. (e) The numbers in this column are average numbers of groups (CH (CH3) CH20) in the propoxylated derivative.
(f) The numbers in this column are average group numbers (CH2CH2CH2CH20) in the polytetramethyleneoxylated derivative.
(g) The numbers in this column are average numbers of groups (CH (CH2CH3) CH20) in the polybutoxyl derivative.
TABLE VIIIB
(a) the number of alkoxylated groups indicated in this table corresponds to operable groups, the generic limits listed in the first line, and those that are preferred are in bold and listed in the second line. (b) The numbers in this column are the average group numbers (CH2CH20) in the polyethoxylated derivative. (c) The numbers in this column are average numbers of groups (CH2CH2O) in the single polyethoxylated substituent capped with methyl of each derivative.
(d) The numbers in this column are average numbers of groups (CH2CH20) in each of the two methyl-capped polyethoxylated substituents of each derivative. (e) The numbers in this column are average numbers of groups (CH (CH3) CH0) in the propoxylated derivative.
(f) The numbers in this column are average group numbers (CH2CH2CH2CH2O) in the polytetramethyleneoxylated derivative. (g) The numbers in this column are average numbers of groups (CH (CH2CH3) CH20) in the polybutoxyl derivative.
TABLE VIIIC
(a) the number of alkoxylated groups indicated in this table corresponds to operable groups, the generic limits listed in the first line, and those that are preferred are in bold and listed in the second line. (b) The numbers in this column are the average group numbers (CH2CH20) in the polyethoxylated derivative. (c) The numbers in this column are average numbers of groups (CH2CH20) in the single methyl-capped polyethoxylated substituent of each derivative.
(d) The numbers in this column are average numbers of groups (CH2CH20) in each of the two methyl-capped polyethoxylated substituents of each derivative. (e) The numbers in this column are average numbers of groups (CH (CH3) CH20) in the propoxylated derivative.
(f) The numbers in this column are average numbers of groups (CH2CH2CH2CH2?) in the polytetramethyleneoxylated derivative. (g) The numbers in this column are average numbers of groups (CH (CH2CH3) CH20) in the polybutoxyl derivative.
TABLE VIIID
(a) the number of alkoxylated groups indicated in this table corresponds to operable groups, the generic limits listed in the first line, and those that are preferred are in bold and listed in the second line. (b) The numbers in this column are the average group numbers (CH2CH20) in the polyethoxylated derivative. (c) The numbers in this column are average numbers of groups (CH2CH20) in the single methyl-capped polyethoxylated substituent of each derivative. (e) The numbers in this column are average numbers of groups (CH (CH3) CH20) in the propoxylated derivative.
(f) The numbers in this column are average group numbers (CH2CH2CHCH20) in the polytetramethyleneoxylated derivative.
(g) The numbers in this column are average numbers of groups (CH (CH2CH3) CH20) in the polybutoxyl derivative.
TABLE VIIIE
a) the number of alkoxylated groups indicated in this table corresponds to operable groups, the generic limits listed in the first line, and those that are preferred are in bold and listed in the second line. (b) The numbers in this column are the average group numbers (CH2CH20) in the polyethoxylated derivative. (c) The numbers in this column are average numbers of groups (CH2CH20) in the single methyl-capped polyethoxylated substituent of each derivative. (e) The numbers in this column are average numbers of groups (CH (CH3) CH20) in the propoxylated derivative.
(f) The numbers in this column are average group numbers (CH2CH2CH2CH20) in the polytetramethyleneoxylated derivative.
TABLE IX
DIOLES AROM TICOS
Suitable aromatic diols include:
Chemical name CAS No. Operable aromatic diols l-phenyl-1,2-ethanediol 93-56-1
1-fen? 1-1, 2 -propanediol 1855-09-0
2-phenyl-1, 2-propanediol 87760-50-7
3-fem-1,2-propanediol 17131-14-5
1- (3-methylphenyl) -1,3-propanediol 5169g-43-5
1- (4-methylphenyl) -1,3-propanediol 159266-06-5
2 - . 2 - . 2 - . 2 - . 2 - . 2-methyl-1-phenyl-1,3-propanediol 139068-60-3
1-phenyl-l, 3-butanediol 118100-60-0
3 - . 3 - . 3 - . 3 - . 3 - . 3-phenyl-1,3-butanediol 68330-54-1
1-Phenol-1,4-butane-diol 136173-88-1
2-phenyl-1,4-butanediol 95840-73-6 l-phenyl-2,3-butanediol 169437-68-7
Preferred aromatic diols l-phenyl-l, 2-etapodiol 93 -56-1 l-phenyl-l, 2-propanediol 1855-09- 0
2- phenyl -1, 2-propanediol 87760-50-7
3 - Pheni 1 -1, 2 -propanodi or 17131-14 -5
1 - . 1 - . 1 - . 1 - . 1- (3-methylphenyl) -1,3-propanediol 51699-43 -5
1- (4-methylphenyl) -1,3-propanediol 159266-06-5
2-methyl-1-phenyl-1,3-propanediol 139068-60-3
1 - phenyl-1, 3-butanediol 118100-60-0
3-phenyl-1,3-butanediol 68330-54 -1
1 - feni 1 -1, 4 -b tanodi ol 136173 -88-1
Most preferred aromatic diols ^ P 1 -phenyl-1,2-propanediol 1855-09-0
2-phenyl-1,2-propanediol 87760-50-7
3-phenyl-1,2-propanediol 17131-14-5
1- (3-metxlfenil) -1,3-propanediol 51699-43-5
1- (4-methylphenyl) -1,3-propanediol 159266-06-5
2-methyl-l-phenyl-1,3-propanediol 139068-60-3 ^ P 3-phenyl-1, -butanediol 68330-54-1
1-Phenxyl-1,4-butanediol 136173-88-1
X. The main homologous or analogous solvents of the above structures, where the total number of hydrogen atoms is increased by the addition of
one or more additional CH2 groups, and the total number of hydrogen atoms remains the same by introducing links
doubles, are also useful examples including the following known compounds:
TABLE X EXAMPLES OF UNSATURATED COMPOUNDS
Operable unsaturated diols 2,2-dipropenyl-1,3-propanediol 55038-13-6
2- (1-pentenyl) -1,3-propanediol 138436-18-7
2- (2-methyl-2-propenyl) -2- (2-propenyl) -1,3- 121887-76-1 propanediol 2- (3-methyl-1-butenyl) -1,3-propanediol 138436-17 -6
2- (4-pentenyl) -1,3-propanediol 73012-4-6-1
2-Ethyl-2- (2-methyl-2-propenyl) -1,3-propanediol 91367-61-2
2-ethyl-2- (2-propenyl) -1,3-propanediol 27606-2"6-4
2-methyl-2- (3-methyl-3-butenyl) -1, 3-propanediol 132130-95-1
2, 2-diallyl-1,3-butane-diol 103985-49-5
2- (1-ethyl-l-propenyl) -1,3-butanediol 116103-35-6
2- (2-butenyl) -2-methyl-l, 3-butanediol 92207-83-5
2- (3-methyl-2-butenyl) -1,3-butanediol 98955-19-2
2-Ethyl-2- (2-propenyl) -1,3-butane-diol 122761-93-7
2-methyl-2- (l-methyl-2-propenyl) -1, 3-butanediol 141585-58-2
2, 3-bis (1-methylethylidene) -1,4-butanediol 52127-63-6
2- (3-methyl-2-butenyl) -3-methylene-1,4-butane-diol 115895-78-8
2- (1,1-dimethylpropyl) -2-butene- 1,4-diol 91154-01-7
2- (1-methylpropyl) -2-butene-1,4-diol gil54-00-6 f 2-butyl-2-butene-1,4-diol 153943-66-9
2-ethenyl-3-ethyl-l, 3-pentanediol 104683-37-6
2-ethenyl-4, 4-dimethyl-1,3-pentanediol 143447-08-9
3-methyl -2- (2 -propenyl) -1,4-pentanediol 139301-86-3
2- (1-propenyl) -1,5-pentanediol 84143-44-2
2- (2-propenyl) -1,5-pentanediol 134757-01-0 flt 2-ethylidene-3-methyl-l, 5-pentanediol 42178-93-8
2-propylidene-l, 5-pentanediol 58203-50-2
3-ethylidene-2,4-dimethyl-2,4-pentanediol 88610-19-9
2- (1,1-dimethylethyl) -4-pentene- 1,3-diol 109788-04-7
2-ethyl-2,3-dimethyl-4-pentene-1,3-diol 90676-97-4
) 4-ethyl-2-methylene-l, 4-hexanediol 66950-87-6
2,3,5-trimethyl-l, 5-hexadiene-3,4-diol 18984-03-7
-ethyl-3-methyl-l, 5-hexadiene-3,4-diol 18g27-12-3
2- (1-Methylethyl) -1,5-hexanediol 96802-18-5
2-ethenyl-l, 6-hexanediol 66747-31-7
,5-dimethyl-l-hexene-3,4-diol 169736-2g-2
,5-dimethyl-l-hexene-3,4-diol 120191-04-0
4-ethenyl-2, 5-dimethyl-2-hexene-1, 5-diol 70101-76-7
-etenyl-2, 5-dimethyl-3 -hexene- 1,6-diol "112763-52-7-ethyl-3-hexene-1,6-diol 84146-45-3, 4-dimethyl-3-hexen- 1,6-diol 125032-66-8, 5-dimethyl-4-hexene-2,3-diol 13295-61-9, 4-dimethyl-4-hexene-2,3-diol - 135367-17-8 - (2-propenyl) -5-hexene-l, 3-diol 74693-24-6, 3-dimethyl-5-hexene-2,3-diol 154386-00-2, 4-dimethyl-5-hexene-2, 3-diol 135096-13-8, 5-dimethyl-5-hexene-2,3-diol 134626-63-4-ethenyl-2,5-dimethyl-5-hexene-2,4-diol 155751-24-9 -methyl-5-methylene-l, 4-heptanediol 100590-2g-2, 3-dimethyl-l, 5-heptadiene-3, 4-diol 18927-06-5, 5-dimethyl-l, 5-heptadiene-3,4-diol 22607-16-5, 5-dimethyl-l, 5-heptadiene-3, 4 -diol 18g38-51-7, 6-bis (methylene) -1, 7-heptanediol 139618-24-9 -methylene- 1,7-heptanediol 71370-08-6, 4-dimethyl-1-heptene-3,5 -diol 155932-77-7, 6-dimethyl-l-heptene-3,5-diol 132157-35-8-ethenyl-5-methyl-l-heptene-3,5-diol 61841-10-9, 6- dimethyl-l-heptene-3,5-diol 109788-01-4, 6-dimethyl-2,4-heptadiene-2,6-diol 102605-95-8, 4-dimethyl-2,5-heptadiene-1, 7-diol 162816-19-5, 5,5-trimethyl-2,6-heptadiene-1,4-diol 115346-30-0
,6-dimethyl-2-heptene-l, 5-diol 103867-76-1
-ethyl-2-heptene-l, 5-diol 104683-39-8
2-methyl-2-heptene-l, 7-diol 74868-68-1 f 4,6-dimethyl-3-heptene-l, 5-diol 147028-43-3
3-methyl-6-methylene-3-heptene-l, 5-diol 109750-55-2
2,4-dimethyl-3-heptene-2,5-diol 98955-40-9
2,5-dimethyl-3-heptene-2,5-diol 24459-23-2
2,6-dimethyl-3-heptene-2,6-diol 160524-66-3
4,6-dimethyl-3-heptene-2,6-diol 59502-66-8 flk 2,4-dimethyl-5-heptene-1,3-diol-123363-69-9
3,6-dimethyl-5-heptene-l, 3-diol 96924-52-6
2, 6-dimethyl-5-heptene-1,4-diol 106777-98-4
3, 6-dimethyl-5-heptene-1, -diol 106777-99-5
2,3-dimethyl-5-heptene-2,4-diol 104651-56-1
2, 2-dimethyl-6-heptene-1,3-diol 140192-39-8 f 4- (2-propenyl) -6-heptene-1,4-diol 1727-87-3
, 6-dimethyl-6-heptene-1,4-diol 152344-16-6
2,4-dimethyl-6-heptene-1,5-diol 74231-27-9
2-ethylidene-6-methyl-6-heptene-l, 5-diol 91139-73-0
4- (2-propenyl) -6-heptene-2,4-diol 101536-75-8
,5-dimethyl-6-heptene-2,4-diol 9O753-77-6
4,6-dimethyl-6-heptene-2,5-diol 134876-94-1
-ethenyl-4-methyl-6-heptene-2,5-diol 65757-31-5
2 - . 2-methylene-1,3-octanediol 108086-78-8
2,6-dimethyl-l, 6-octadiene-3,5-diol 91140-06-5
3, 7-dimethyl-l, 6-octadiene-3, 5-diol 75654-19-2 f 2,6-dimethyl-l, 7-octadiene-3,6-diol 51276-33-6
2, 7-dimethyl-1,7-octadiene-3,6-diol 26947-10-4
3, 6-dimethyl-l, 7-octadiene-3,6-diol-31354-73-1
3-ethenyl-l-octene-3,6-diol 65757-34-8
2,7-dimethyl-2,4,6-octatriene-l, 8-diol 162648-63-7
3, 7-dimethyl-2, -octadiene-l, 7-diol 136054-24-5 flk 2,6-dimethyl-2, 5-octadiene-l, 7-diol 91140-07-7
3,7-diraethyl-2, 5-octadiene-l, 7-diol 117935-59-8
3,7-dimethyl-2,6-octadiene-l, 4-diol (Rosiridol) 101391-01-9
2-methyl-2,6-octadiene-l, 8-diol 149112-02-7
3,7-dimethyl-2,7-octadiene-l, 4-diol 91140-08-8
2, 6-dimethyl-2, 7-octadiene-1,5-diol 91140-? Gg f 2,6-dimethyl-2,7-octadiene-l, 6-diol (8-103619-06-3 hydroxylinalool) 2 , 7-dimethyl-2,7-octadiene-l, 6-diol 60250-14-8
2-octene-l, 4-diol - 40735-15-7
2-octene-l, 7-diol 73842-95-2
2-methyl-6-methylene-2-octene-l, 7-diol-91140-16-8
3, 7-dimethyl-3,5-octadiene-l, 7-diol 62875-09-6
2,7-dimethyl-3,5-octadiene-2,7-diol 7177-18-6
4 - . 4-methylene-3, 5-octanediol - 143233-15-2
, 6-dimethyl-3,7-octadiene-l, 6-diol 127446-29-1, 7-dimethyl-3,7-octadiene-2, 5-diol 171436-39-8, 6-dimethyl-3,7 -octadiene-2, 6-diol 150283-67-3 -methyl-3-octene-1,5-diol 147028-43-1 -methyl-3-octene-l, 5-diol 19764-77-3, 2 - dimethyl-4, 5-octadiene-l, 3-diol 39824-01-6, 6-dimethyl-4,7-octadiene-2,3-diol 51117-38-5, 6-dimethyl-4,7-octadiene- 2, 6-diol 59076-71-0 -methyl-4-octene-l, 6-diol 84538-24-9, 7-bis (methylene) -4-octene-l, 8-diol "109750-56-3 -methylene-4-octene-l, 8-diol 109750-58-5, 7-dimethyl-5,7-octadiene-1,4-diol 105676-78-6-methyl-5,7-octadiene-1,4 -diol 105676-80-0 -octene-l, 3-diol 130272-38-7 -methyl-6-octene-1,3-diol 110971-i -2-methyl-6-octene-1,4-diol 152715 -87-2-octene-l, 5-diol 145623-79-6-methyl-6-octene-l, 5-diol 116214-61-0-methyl-6-octene-3,5-diol 65534-66- g -methyl-6-octene-3,5-diol 156414-25-4 -raethyl-7-octene-l, 3-diol 155295-38-8 -methyl-7-octene-l, 3-diol 14245g-25 -4-methyl-7-octene-1,3-diol 132130-96-2
7-octene-l, 5-diol 7310-51-2
7-octene-l, 6-diol 1590gg-43-l
- . 5-methyl-7-ketene-1,6-diol 144880-56-8
2-methyl-6-methylene-7-octene-2,4-diol 72446-81-2
7-methyl-7-octene-2,5-diol 152344-12-2
2-methyl-7-octene-3,5-diol g8753-85-6
1 - . 1 - noneno -3,5- diol lig554-56-2 l-noneno-3, 7-diol 23866-g7-g
3-NONENE-2, 5-DIOL 165746-84-G
8 -. 8-methyl-4,6-nonadiene-1,3-diol 1240gg-52-l
4-NONENE-2, 8-DIOL 154600-80-3
6,8-nonadieno-l, 5-diol 108586-03-4
7-NONENE-2, 4-DIOL 30625-41-3
8-noneno-2,4-diol lig785-5g-0
8-NONENE-2, 5-DIOL 132381-58-9
1, 9-decadiene-3, 8-diol 103984-04-9 1, -decadiene-4,6-diol 138835-67-3
Preferred unsaturated diols 2,2-diallyl-1,3-butanediol 103985-49-5
2- (1-ethyl-1-propenyl) -1,3-butanediol 116103-35-6
2- (2-butenyl-2-methyl) -1,3-butanediol 92207-83-5
- 3-methyl-5-i > Tenii -1, 3 -butanediol 98955-19-2 -ethyl-2- (propenyl) -1,3 -butanediol 122761-93-7 -methyl-2- (l-methyl-2-propenyl) -1,3 -butanediol 141585-58-2, 3-bis (1-methylethylidene) -1,4-butanediol 52127-63-6
-etenyl-3-ethyl-l, 3-pentanediol 104683-37-6-ethenyl -4,4-dimethyl-1, -3-pen tanodi ol 143447-08-9 -methyl-2- (2-propenyl) - 1,4-pentanediol 139301-86-3 - (1,1-dimethylethyl) -4-pentane -1,3-diol 109788-04-7-ethyl-2,3-dimethyl-4-pentane-1,3- diol 90676-97-4
-ethyl-2-methylene-l, 4-hexanediol 66950-87-6, 3,5-trimethyl-l, -hexadiene-3,4-diol 18984-03-7 - (1-methyletenyl) -1,5 - hexanediol 96802-18-5 - ethenyl -2,5-dimethyl-2-hexen-1, 5-diol 70101-7_6-7
-methyl-5-methylene- 1,4-heptanediol 100590-29-2,6-dimethyl-2,4-heptadiene-2,6-diol 102605-95-8,5,5-trimethyl-2,6-heptadiene - 1, 4-diol 115346-30-0, 6-dimethyl-2-heptene-1, -diol 103867-76-1, 6-dimethyl-3-heptene-1, 5-diol 147028-45-3, 4 -dimethyl-5-heptene-l, 3-diol 123363-69-9, 6-dimethyl-5-heptene-l, 3-diol 96924-52-6
2, 6-dimethyl-5-heptene-1,4-diol 106777-V8-4
3, 6-dimethyl-5-heptene -1,4-diol 106777-99-5
2, 2-dimethyl-6-heptene -1,3-diol 140192-39-8
, 6-dimethyl-6-heptene-1,4-diol 152344-16-6
2,4-dimethyl -6-heptyne-1,5-diol 74231-27-9
2-ethylidene-6-methyl-6-heptene-l, 5-diol 91139-73-0
4- (2-propenyl) -6-heptene-2,4-diol _ 101536-75-8
3-ethenyl-l-octene-3,6-diol 65757-34-8
2,7-dimethyl-2,4,6-octariene-l, 8-diol 162648-63-7
2,6-dimethyl-2,5-octanediene-1,7-diol 91140-07-7 3,7-dimetdl-2, 5-octadiene-l, 7-diol 117935-59-8 3,7-dimethyl- 2,6-octadiene-l, 4-diol (Rosiridol) 101391-01-9 2-methyl-2,6-octadiene-l, 8-diol 149112-02-7
3,7-dimethyl-2,7-octadiene-1,4-diol 91140-08-8
2,6-dimethyl -2,7-octadiene-l, 5-diol 91140-09-9
2,6-dimethyl-2,7-octadiene-l, 6-diol (8-103619-06-3 hydroxylinalool) 2,7-dimethyl-2,7-octadiene-l, 6-diol 60250-14-8
2-methyl-6-methylene-2-octene-l, 7-diol 91140-16-8
2, 7 -d? Methyl-3, 5-octadiene-2, -diol 7177-18-6
4 - . 4-methylene-3,5-octanediol 143033-15-2
2,6-dimethyl-3,7-octadiene-l, 6-diol 127446-29-1
2-methylene-4-octene-l, 8-diol 109750-58-5
2-methyl-6-ketene-3, 5-diol 65534-66-9
-methyl- -octene -3,5 -diol 156414-25-4
2 - . 2 - . 2-methyl-6-methylene-7-ketene-2,4-diol 72446-81-2
7 -. 7-methyl-7-ketene-2, 5-diol 152344-12-2
2-methyl-7-ketene-3, 5-diol 98753-85-6
1 - . 1 -nonhene -3,5-diol 119554-56-2 l-nonene-3, 7-diol 23866-97-9 3-nonene-2, 5-diol 165746-84-9 4-nonene-2, 8- diol 154600-80-3 6, 8-nonadi no-l, 5-diol 108586-03-4 7 -nonne -2, 4-diol 30625-41-3 8-nonene-2, 4-dlol 119785-59- 0 8 -nonone -2, 5 -diol 132381-58-9
1, 9-decadiene-3, 8-diol 103984-04-9 l-9-decadiene-4,6-diol 138835-67-3
XI. mixtures thereof. There are no mono-oles of 1 to 2 carbon atoms that provide the clear concentrated fabric softening compositions of this invention. Only a mono-ol, n-propanol, provides acceptable performance (forms a transparent product and keeps it transparent at a temperature of about 4 ° C, or allows it to recover
subjected to reheating at room temperature), however its boiling point (PE) is undesirably low. Of the mono-oles of 4 carbon atoms, only 2-butanol and fl 2-methyl-2-propanol provide very good performance, but
2-methyl-2-propanol has an undesirably low PE. There are no mono-oles of 5 to 6 carbon atoms that provide transparent products except the unsaturated mono-oles described above and hereinafter. It has been found that some major solvents fl} having two hydroxyl groups in their chemical formulas are suitable for use in the formulation of the clear, liquid, concentrated fabric softener compositions of this invention. It has been found that the suitability of each principal solvent is surprisingly very selective, depending on the number of carbon atoms, the degree of flj) unsaturation, etc. The main solvents with solubility characteristics similar to the previous main solvents and which have at least some asymmetry will provide the same benefit. It has been
It was discovered that the appropriate main solvents have an approximate ClogP of 0.15 to 0.64, preferably of about 0.25 to 0.62, and more preferably of about 0.40 to 0.60.
For example, for the series of main solvents 1, -alkanodiol having the general formula H0-CH2-CHOH- (CHj) nH, where n is from 1 to 8, only 1, 2-hexanediol flJ (n = 4), which has a ClogP value of about 0.53, which
is within the effective ClogP range of about 0.15 to 0.64, is a good principal solvent, and is within the claims of this invention, while the others, for example, 1,2-propanediol, 1,2-butanediol, 1, 2-pentanediol,
1,2-octanediol, 1,2-decanediol, which have ClogP values
^ out of the effective range of 0.15 to 0.64, they are not, furthermore, of the hexanediol isomers, again, 1,2-hexanediol is a good principal solvent, while many other isomers are 1, 3 - hexanediol, 1,4-hexanediol, 1,5-hexanediol, 1,6-hexanediol, 2,4-hexanediol and 2,5-hexanediol;
that have ClogP values outside the effective range of 0.15 to fl ^ 0.64, are not. These are illustrated by the examples and comparative examples I-A and I-B (see below). There are no diols of 3 to 5 carbon atoms that provide a clear concentrated composition in the context of this invention. Although there are many diols of 6 carbon atoms which are possible isomers, only those indicated above are suitable for making transparent products and only: 2,3-dimethyl-l, 2-butanediol; 3,3-
dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2, 3-pentanediol, -4-methyl -2,3-pentanediol; 2, 3-hexanediol; 3, 4-hexanediol; 2-ethyl-l, 2-butanediol; 2-methyl-l, 2-fljl pentanediol; 3-methyl-l, 2-pentanediol; 4-methyl-l, 2-5 pentanediol; and 1,2-hexanediol are preferred, of which the most preferred are: 2-ethyl-1,2-butanediol; 2- methyl-1,2-pentanediol; 3-methyl-l, 2-pentanediol; 4-methyl-l, 2- pentanediol; and 1,2-hexanediol. There are more isomers of diols of 7 carbon atoms
Possible, but only those mentioned provide transparent products and the preferred ones are: 2-butyl-l, 3-butanediol;
2 - . 2-propyl-1,4-butanediol; 2-ethyl-l, 5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediyl; 2,3-dimethyl-3,4-pentanediol; 2- 15 methyl-1, 6-hexanediol; 3-methyl-l, 6-hexanediol; 1,3-flj heptanediol; 1, 4-heptane diol; 1,5-heptanediol; 1,6-heptanediol; of which the most preferred are: 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4, 4-dimethyl-2,3-pentanediol; 2,3- 20 dimethyl-3,4-pentanediol. Similarly, there are even more isomers of diols of 8 carbon atoms; but only those indicated provide transparent products and the preferred ones are: 2- (1,1-dimethyl-propyl) -1,3-propanediol; 2- (1,2-dimethyl-propyl) -1,3-
propanediol; 2- (1-ethyl-propyl) -1,3-propanediol; 2- (2,2-dimethyl-1-propyl) -1,3-propanediol, -2-ethyl-2-isopropyl-l, 3-propanediol, -2-methyl-2- (1-methylpropyl) -1, 3- propanediol; 2- ^ P-methyl-2- (2-methylpropyl) -1,3-propanediol; 2-butyl-tertiary-5-2-methyl-1,3-propanediol; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) -1,3-butanediol; 2-butyl -1, 3 -butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2- (1,1-dimethylethyl) -1,3-butanediol; 2- (2-methylpropyl) -1,3-butanediol; 2-methyl-2 ~ -propyl-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol;
To 3-methyl-2-propyl-l, 3-butanediol; 2,2-dimethyl-1,4-butanediol; 2-ethyl -2,3-dimethyl-1,4-butanediol; 2-ethyl-3, 3-dimethyl-l, 4-butanediol; 2- (1,1-dimethylethyl) -1,4-butanediol, -3-methyl-2-isopropyl-1,4-butane-diol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-1,3- pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3, 4, 4-trimethyl-f) 1,3-pentanediol; 2, 2, 3-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,4-pentanediol; 2, 3, 4-trimethyl-1,4-pentanediol; 3, 3, 4-trimethyl-l, 4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2, 2, 4-trimethyl-1, 5-pentanediol; 2, 3, 3-trimethyl-l, 5-pentanediol, -2,3,4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2- ethyl -3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1, 3-pentanediol; 3-ethyl-2-ethyl-l, 3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-l, 4-pentanediol, - 2-ethyl-4-
methyl -1,4-pentanediol; 3-ethyl-3-methyl-l, 5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-l, 3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl -1,4-pentanediol; 2-propyl-1,4-pentanediol 3-isopropyl-1,4-pentanediol propi1-2,4-pentanediol 2,2-dimethyl-1,3-hexanediol dimethyl-1,3-hexanediol 2,4-dimethyl -1, 3-hexanediol dimethyl-1,3-hexanediol 3,4-dimethyl-1,3-hexanediol dimethyl-1,3-hexanediol 4,4-dimethyl-1,3-hexanediol dimethyl-1,3 - hexanediol 2,2-dimethyl-1,4-hexanediol dimethyl-1,4-hexanediol 2,4-dimethyl-1,4-hexanediol dimethyl-1,4-hexanediol 3, 3-dimethyl-1,4- hexanediol dimethyl-1,4-hexanediol 3,5-dimethyl-1,4-hexanediol dimethyl-1,4-hexanediol 5,5-dimethyl-1,4-hexanediol dimethyl-1,5-hexanediol 2,3-hexanediol dimethyl-1,5-hexanediol dimethyl-1,5-hexanediol 2,5-dimethyl-1,5-hexanediol dimethyl-1,5-hexanediol 3,4-dimethyl-1,5-hexanediol dimethyl-1, 5-hexanediol 4,5-dimethyl-l, 5-hexanediol; dimethyl-2,6-hexanediol 2-ethyl-l, 3-hexanediol; 4-ethyl-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2-ethyl-1, 5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2, 5-hexanediol, -2-methyl-1,3-heptanediol; 3-methyl-1,3-heptane diol; 4-methyl-l, 3-heptane diol; 5-methyl-1,3-heptanediol; 6-methyl-l, 3-heptane diol; 2-methyl-1,4-heptanediol; 3-methyl-l, 4-heptanediol; 4-methyl-l, 4-
heptanediol; 5-methyl-l, 4-heptanediol; 6-methyl-l, 4-heptanediol; 2-methyl-l, 5-heptanediol; 3-methyl-l, 5-heptanediol; 4-methyl-l, 5-heptane diol; 5-methyl-l, 5-heptanediol; 6-methyl-l, 5-heptanediol; "2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol-6-methyl-1-6 heptanediol; 2-methyl-2, 4-heptanediol; 3-methyl-2,4-heptanediol, - 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4 heptanediol, 2-methyl-2,5-heptanediol, 3-methyl-2, 5-heptanediol, 4-methyl-2,5-heptanediol, 5-methyl-2,5-heptanediol, 6-methyl-2,5 heptanediol, 2-methyl-2,6-heptanediol, 3-methyl-2,6-heptanediol, 4-methyl-2,6-heptanediol, 3-methyl-3,4-heptanediol, 2-methyl-3 , 5-heptanediol, 4-methyl-3,5-heptanediol, 2,4-octanediol, 2,5-octanediol, 2,6-octanediol, 2,7-octanediol, 3,5-octanediol, and / or 3, 6-octanediol of which the following are the most preferred: 2- (1, 1-dimethyl-propyl) -1,3-propanediol; 2- (1,2-dimethyl-propyl) -1,3-propanediol; - (1-ethyl-propyl) -1,3-propanediol; 2- (2,2-dimethyl-propyl) -1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-methyl -2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-m) ethylpropyl) -1,3-propanediol; 2-butyl-tertiary-2-methyl-1,3-propanediol; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) -1,3-butanediol; 2- (2-methylpropyl) -1,3-
butanediol; 2-butyl -1, 3 -butanediol; 2-methyl-propyl -1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2, 2-diethyl-l, 4-butanediol; 2-ethyl-2, 3-dimethyl-1,4-butanediol; 2-et? L-3,3-dimet? L-1,4-butanediol, -2- (1,1-dimethylethyl) -1,4-butanediol; 2,3,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2, 3, 3-trimethyl-l, 5-pentanediol; 2-ethyl-2-methyl-1,3-pentanedione; 2-ethyl-3-methyl-l, 3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-et? L-4-met? L-l, 4-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-l, 3-pentanediol, 2-propyl-l, 3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-l, 4-pentanediol; 3-isopropyl-1,4-pentanediol; 3-propyl -2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol 2,5-dimethyl-1,3-hexanediol, 3,4-dimethyl-1,3-hexanediol 3,5-dimethyl-1,3-hexanediol; 4,4-d? Meth? -1,3-hexanediol 4,5-dimethyl-l, 3-hexanediol; 2,2-d-methyl-1,4-hexanediol 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol 4,5-dimethyl-1,4-hexanediol; 5,5 dimethyl-1,4-hexanediol 2,2-dimethyl-l, 5-hexanediol; 2,3 dimethyl-1, 5-hexanediol 2,4-dimethyl-l, 5-hexanediol; 2.5
dimethyl-1, 5-hexanediol 3, 3-dimethyl-l, 5-hexanediol; 3,4-dimethyl-1,5-hexanediol 3,5-dimethyl-l, 5-hexanediol; 4,5-dimethyl-1,5-hexanediol 3,3-dimethyl-2,6-hexanediol; 2-ethyl -1,3-hexanediol; 4-ethyl-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2-ethyl-l, 5-hexanediol; 3-ethyl-2, 4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-l, 3-heptane diol; 3-methyl-1,3-heptanediol 4-methyl-1,3-heptanediol 5-methyl-1,3-heptanediol 6-methyl-1,3-heptanediol 2-methyl-1,4-heptanediol 3-methyl-1 4-heptanediol 4-methyl-1,4-heptanediol 5-methyl-1,4-heptanediol 6-methyl-1,4-heptanediol 2-methyl-1, 5-heptanediol 3-methyl-1, 5-heptanediol 4 methyl-l, 5-heptanediol 5-methyl-l, 5-heptanediol 6-methyl-l, 5-heptanediol 2-methyl-l, 6-heptanediol 3-methyl-l, 6-heptanediol 4-methyl-1, 6-heptanediol 5-methyl-l, 6-heptanediol 6-methyl-1,6-heptanediol 2-methyl-2,4-heptane diol 3-methyl-2,4-heptanediol 4-methyl-2,4-heptanediol 5- methyl-2,4-heptanediol 6-methyl-2,4-heptanediol 2-methyl-2,5-heptanediol 3-methyl-2, 5-heptanediol 4-methyl-2,5-heptanediol 5-methyl-2, 5 -heptanediol 6-methyl-2, 5-heptanediol 2-methyl-2,6-heptanediol 3-methyl-2,6-heptanediol 4-methyl-2,6-heptanediol 3-methyl-3,4-heptanediol 2-methyl -3,5-heptanediol 4-methyl-3,5-
heptanediol; 2,4-octanediol; 2,5-ostanediol; 2,6-octanediol, 2,7,7-octanediol; 3, 5-octanediol; and / or 3, 6-octanediol. Preferred mixtures of 1,3-diols of eight fl) carbon atoms can be formed by the condensation of mixtures of butyraldehyde, isobutyraldehyde and / or methyl ethyl ketone (2-butanone), provided that there are at least two of these reactants in the reaction mixture, in the presence of highly alkaline catalyst followed by conversion by hydrogenation to form a "mixture of 1,3-diols of eight carbon atoms, ie, a mixture of 1,3-diols of 8 atoms of carbon consisting primarily of: 2,4,4-trimethyl-1,3-pentanediol; 2-ethyl-l, 3-hexanediol: 2,2-dimethyl-l, 3-hexanediol; 2-ethyl-4-methyl -1,3-pentanediol, 2-ethyl-3-methyl-1,3-pentanediol, 3,5-oethanediol, 2,2-dimethyl-2, 2,4-hexanediol: 2-methyl-3,5-heptanediol; and / or 3-methyl-3,5-fl) heptanediol, the level of 2,2,4-trimethyl-l, 3-pentanediol being less than half of any mixture, possibly together with other minor isomers resulting from condensation of the methylene group of 2-butanone, when
is present, instead of in the methyl group. • The formulability and other properties, such as odor, fluidity, lowering of the melting point, etc., of "some diols of 6 to 8 carbon atoms listed above in tables II-IV which are not preferred, may be
improved by polyalkoxylation. Also preferred are some of the diols of 3 to 5 carbon atoms which are alkoxylated. Preferred alkoxylated derivatives of the flj) diols of 3 to 8 carbon atoms above, [in the following description, "EO" means polyethoxylates, "En" means (CH2CH20) nH; Me-En means methyl-capped polyethoxylates - (CH2CH2?) NCH3; "2 (Me-En)" means 2 required Me-En groups; "PO" means polypropoxylates, - (CH (CH3) CH20) nH; "BO" means polybutenoxy groups, flj (CH (CH2CH3) CH20) nH; and "n-Bo" means poly (n-butyleneoxy) - (CH2CH2CH2CH2?) "H] groups include: 1,2-propanediol (C3) 2 (Me-E3_4); 1,2-propanediol (C3) P04; 2-methyl-l, 2-propanediol (C4) 2 (Me-E8.?0); 2-methyl-1,2-propanediol (C4) 2 (Me-E?); 2-methyl-l, 2-propanediol (C4)
P03; 1,3-propanediol (C3) 2 (Me-E8); 1,3-propanediol (C3) P06; f 2, 2-diethyl-l, 3-propanediol (C7) E4.7; 2, 2-d? Et? L-l, 3- propanediol (C7) PO ?; 2, 2-diethyl-l, 3-propanediol (C7) n-B02; 2, 2-dimethyl-1,3-propanediol (C5) 2 (Me E? _2); 2, 2-dimethyl-l, 3-propanediol (C5) P04; 2 (1-methylpropyl) -1,3-propanediol (C7)
E4.7; 2- (1-methylpropyl) -1,3-propanediol (C7) P0?, 2- (l-methylpropyl) -1,3-propanediol (C7) n-B02; 2 (2-methylpropyl) -1,3-propanediol (C7) E4-7; 2 (2-methylpropyl) -1,3-propanediol (C7) PO ?; 2 (2-methylpropyl) -1,3-propanediol (C7) n-B02; 2- et? L-l, 3-propanediol (C5) (Me E9.10); 2-ethyl-l, 3-propanediol
(C5) 2 (Me Ex); 2-ethyl-1,3-propanediol (C5) P03; 2-ethyl-2-methy1-1, 3-propanediol (C6) (Me E3.5); 2-ethyl-2-methyl-l, 3-propanediol (C6) P02; 2-ethyl-2-methyl-l, 3-propanediol (C6) fi BO ?; 2-isopropyl-1,3-propanediol (C6) (Me E3-6); 2-isopropyl-1,3-propanediol (C6) P02; 2-isopropyl-l, 3-propanediol (C6) BO ?; 2-methyl-1,3-propanediol (C4) 2 (Me E4-5); 2-methyl-l, 3-propanediol (C4) P05; 2-methyl-l, 3-propanediol (C4) B02; 2- methyl-2-isopropyl-l, 3-propanediol (C7) PO ?; 2-methyl-2-isopropyl-1,3-propanediol (C7) n-B02_3; 2-methyl-2-propyl-l, 3-fl | propanediol (C7) E4.7; 2-met? L-2-propyl-l, 3-propanediol (C7) P0 ?; 2-methyl-2-propyl-l, 3-propanediol (C7) nB02; 2-propyl-1,3-propanediol (C6) (Me E? .4); 2-propyl1-1, 3-propanediol (C6) P02; 2. 1, 2 -butanediol (C4) (Me ES-8); 1,2-butanediol 15 (C4) P02.3; 1,2-butanediol (C4) B0 ?; 2, 3-dimethyl-l, 2-f) butanediol (C6) E2-S; 2, 3-dimethyl-1,2-butanediol (C6) nB0?, - 2-ethyl-l, 2-butanediol (C6) E? .3; 2-ethyl-l, 2-butanediol (C6) n-B0 ?; 2-methyl-1,2-butane-diol (C5) (Me E-2); 2-methyl-l, 2-butanediol (C5) P0_; 3, 3-dimethyl-l, 2-butanediol (C6) E2.5; 3, 3-dimethyl-l, 2-butanediol (C6) n-BO?, -3-met? L-l, 2-butanediol (Me E? .2); 3-methyl-l, 2-butanediol PO?, - 1,3-butanediol (C4) 2 (Me E5.s), -1,3-butanediol (C4) B02; 2,2,3-trimethyl-1,3-butanediol (C7) (Me E? _3); 2, 2, 3-trimethyl-l, 3-butanediol (C7) P02; 2, 2-dimethyl-l, 3-butanediol (C6) (Me E6_
s); 2, 2-dimethyl-1,3-butanediol (C6) P03; 2, 3-dimethyl-l, 3-butanediol (C6) (Me E6.s); 2, 3-dimethyl-1,3-butane-diol (C6)
P03; 2-ethyl-l, 3-butanediol (C6) (Me E4.6); 2-ethyl-l, 3-f-butanediol (C6) P02-3; 2-ethyl-l, 3-butanediol (C6) BO?, - 2- ethyl-2-methyl-l, 3-butanediol (C6) (Me Ex); 2-ethyl-2-methyl-1,3-butanediol (C7) PO ?; 2-ethyl-2-methyl-l, 3-butanediol
(C7) n-B03; 2-ethyl-3-methyl-l, 3-butanediol (C7) (Me Ex); 2- ethyl-3-methyl-l, 3-butanediol (C7) P0 ?; 2-ethyl-3-methyl-l, 3-butanediol (C7) n-B03; 2-isopropyl-1,3-butanediol - (C7) (Me fl) Ex); 2-isopropyl-l, 3-butanediol- (C7) PO ?; 2-isopropyl-1, 3-butanediol- (C7) n-B03; 2-methyl-l, 3-butanediol- (C5) 2 (Me E2-3); 2-methyl-l, 3-butanediol- (C5) P04; 2-propyl-l, 3- butanediol- (C7) E6-8; 2-propyl-l, 3-butanediol- (C7) PO ?; 2- propy1-1, 3-butanediol- (C7) n-B02_3; 3-methyl-1,3-butanediol-15 (C5) 2 (Me E2_3); 3-methyl-l, 3-butanediol- (C5) P04; 1,4-f butanediol- (C4) 2 (Me E3-4); 1,4-butanediol- (C4) 2 P04-5; 2,2,3-trimethyl-1,4-butanediol- (C7) E6.9; 2, 2, 3-trimethyl-l, 4- butanediol- (C7) P0?, - 2, 2, 3-trimethyl-1,4-butanediol- (C7) n- BO2-3; 2, 2-dimethyl-1,4-butanediol- (C6) (Me E3.5); 2,2-dimethyl-20-1,4-butanediol- (C6) P02; 2, 2-dimethyl-l, 4-butanediol (C6) BO ?;
2,3-diraethyl-l, 4-butanediol (C6) (Me E3.6); 2, 3-dimethyl-l, 4- butanediol (C6) P02; 2, 3-dimethyl-l, 4-butanediol (C6) BO ?; 2- ethyl-l, 4-butansdiol (C6) (Me E? _4); 2-ethyl-l, 4-butanediol
(C6) P02; 2-ethyl-2-methyl-l, 4-butanediol (C7) E4.7; 2-ethyl-2-
methyl-1,4-butanediol (C7) PO; 2-ethyl-2-methyl-1,4-butanediol (C7) n-B02; 2-ethyl-3-methyl-1,4-butanediol (C7) E4.7; 2-ethyl-3-methyl-1,4-butanediol (C7) PO ?; 2-ethyl-3-methyl-1,4-flu) butanediol (C7) n-B02; 2-isopropyl-l, 4-butanediol (C7) E4_7; 5-isopropyl-l, 4-butanediol (C7) P0?, - 2-isopropyl-l, 4- butanediol (C7) n-B02; 2-methyl-l, 4-butanediol (C5) (Me E9.10); 2-methyl-1,4-butanediol (C5) 2 (Me Ex); 2-methyl-l, 4- butanediol (C5) P03; 2-propyl-l, 4-butanediol (C7) E2-5; 2- propy1-1, 4-butanediol (C7) n-BO; 3-ethyl-l-methyl-l, 4-} butanediol (C7) E6.8; 3-ethyl-l-methyl-l, 4-butanediol (C7) PO ?; 3-ethyl-l-methyl-l, 4-butanediol (C7) n-B02.3; 2, 3-butanediol (C4) (Me E9-? O); 2, 3-butanediol (C4) 2 (Me Ex); 2,3-butanediol (C4) P03_4; 2,3-dimethyl-2,3-butanediol (C6) E7.9; 2,3-dimethyl-2, 3-butanediol POj ,; 2,3-dimethyl-2,3-butanediol (C6) B02-3; 2-15 methyl-2, 3-butanediol (C5) (Me E2.5); 2-methyl-2, 3-butanediol f (C5) P02; 2-methyl-2,3-butanediol (C5) B0?, - 3. 1,2-pentanediol (C5) E7-10; 1, 2-pentanediol (C5) P0?, -1,2-pentanediol (C5) n-B03; 2-methyl-l, 2-pentanediol (C6) E? .3; 2-methyl-l, 2-pentanediol (C6) n-BO ?; 3-methyl-l, 2- 20 pentanediol (C6) E.3; 3-methyl-l, 2-pentanediol (C6) n-BO; 4- methyl-1,2-pentanediol (C6) E? _3; 4-methyl-l, 2-pentanediol (C6) n-BO ?; 1,3-pentanediol (C5) 2 (Me-E? _2); 1,3-pentanediol (C5) P03.4; 2, 2-dimethyl-1,3-pentanediol (C7) (Me-E?); 2,2-dimethyl-1,3-pentanediol (C7) PO ?; 2, 2-dimethyl-1,3-pentanediol (C7) n-
B03; 2, 2-dimethyl-l, 3-phenytoxyol (C7) (Me-E?); 2,2-dimethyl-1,3-pentanediol (C7) PO?, -2,2-dimethyl-1,3-pentanediol (C7) n-B03; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E?); 2,4-f dimethyl-1,3-pentanediol (C7) PO ?; 2,4-dimethyl-l, 3-pentanediol (C7) n-B03; 2-ethyl-l, 3-pentanediol (C7) E6_¡¡; 2- ethyl-1,3-pentanediol (C7) PO ?; 2-ethyl-l, 3-pentanediol (C7) n-B02-3; 2-methyl-l, 3-pentanediol (C6) 2 (Me-E4.5); 2-methyl-l, 3- pentanediol (C6) P02-3; 3, 4-dimethyl-l, 3-pentanediol (C7) (Me-Ex); 3,4-dimethyl-1,3-pentanediol (C7) PO ?; 3, 4-dimethyl-1,3-flux pentanediol (C7) n-B03; 3-methyl-l, 3-pentanediol (C6) 2 (Me-E4.6); 3-methyl-l, 3-pentanediol (C6) PO2-3; 4-dimethyl-l, 3- pentanediol (C7) (Me-E?); 4, 4-dimethyl-l, 3-pentanediol (C7) P0 ?; 4, 4-dimethyl-l, 3-pentanediol (C7) n-B03; 4-methyl-l, 3- pentanediol (C6) 2 (Me-E.6); 4-methyl-l, 3-pentanediol (C6) 15 P02-3; 1,4-pentanediol (C5) 2 (Me-Ex-2); 1,4-pentanediol (C5) fl) P03.4; 2, 2-dimethyl-1,4-pentanediol (C7) (Me-E?); 2,2-dimethyl-1,4-pentanediol (C7) P0 ?; 2, 2-dimethyl-l, 4-pentanediol (C7) n-B03; 2, 3-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2,3-dimethyl-l, 4-pentanediol (C7) P0; 2, 3-dimethyl-1,4-20 pentanediol (C7) n-B03; 2,4-dimethyl-l, 4-pentanediol (C7) (Me-E); 2,4-dimethyl-l, 4-pentanediol (C7) P0 ?; 2,4-diraethyl-1,4-pentanediol (C7) n-B03; 2-methyl-l, 4-pentanediol (C6) (Me-E4.6); 2-methyl-l, 4-pentanediol (C6) PO2-3; 3,3-dimethyl-1,4-pentanediol (C7) (Me-E?); 3, 3-dimethyl-l, 4-pentanediol
(C7) PO ?; 3, 3-dimethyl-l, 4-pentanediol (C7) n-B03; 3,4-dimethyl-l, 4-pentanediol (C7) (Me-E?); 3, 4-dimethyl-l, 4-pentanediol (C7) PO ?; 3, 4-dimethyl-l, 4-pentanediol (C7) n-f B03; 3-methyl-l, 4-pentanediol (C6) 2 (Me-E4.6); 3-methyl-l, 4-5 pentanediol (C6) P02-3; 4-methyl-l, 4-pentanediol (C6) 2 (Me-E _ 6); 4-methyl-l, 4-pentanediol (C6) PO? -3; 1,5-pentanediol (C5) (Me-E8-? O); 1,5-pentanediol (C5) 2 (Me-E?); 1,5-pentanediol (C5) P03; 2, 2-dimethyl-l, 5-pentanediol (C7) E4_7; 2,2-dimethyl-1,5-pentanediol (C7) P0?, -2, 2-dimethyl-l, 5-pentanediol (C7) fl} n-B02; 2,3-dimethyl-l, 5-pentanediol (C7) E4.7; 2,3-dimethyl-1,5-pentanediol (C7) PO ?; 2, 3-dimethyl-l, 5-pentanediol (C7) n-B02; 2,4-dimethyl-l, 5-pentanediol (C7) E.7; 2,4-dimethyl-1,5-pentanediol (C7) PO ?; 2,4-dimethyl-l, 5-pentanediol (C7) n-B02; 2-ethyl-l, 5-pentanediol (C7) E2_5; 2-ethyl-l, 5-15 pentanediol (C7) n-BO ?; 2-methyl-l, 5-pentanediol (C6) (Me E? _ F 4); 2-methyl-l, 5-pentanediol (C6) P02; 3, 3-dimethyl-l, 5-pentanediol (C7) E4.7; 3, 3-dimethyl-l, 5-pentanediol (C7) P0 ?; 3, 3-dimethyl-l, 5-pentanediol (C7) n-B? 2, -3-methyl-l, 5- pentanediol (C6) (Me-Ex_4); 3-methyl-l, 5-pentanediol (C6) P02;
2, 3-pentanediol (C5) (Me-E? _3); 2, 3-pentanediol (C5) P02; 2- methyl-2, 3-pentanediol (C6) E_7; 2-methyl-2, 3-pentanediol (C6) P0 ?; "2-methyl-2,3-pentanediol (C6) n-B02; 3-methyl-2,3-pentanediol (C6) E4-7; 3-methyl-2, 3-pentanediol (C6) P0?, - 3 - methyl -2, 3-pentanediol (C6) n-B02; 4-methyl-2, 3-pentanediol
(C6) E4 7; 4-methyl-2,3-petanediol (C6) PO ?; 4-methyl-2,3-pentanediol (C6) n-B02; 2,4-pentanediol (C5) 2 (Me-E2-t); 2,4-pentanediol (C5) P04; 2, 3-dimethyl-2,4-pentanediol (C7) (Me-f E2.4); 2,3-dimethyl -2,4-pentanediol (C7) P02; 2,4-dimethyl-2,4- pentanediol (C7) (Me-E2-4); 2,3-dimethyl-2,4-pentanediol (C7)
P02; 2-methyl -2,4-pentanediol (C7) (Me-E8.x0); 2-methyl-2,4-pentanediol (C7) P03; 3, 3-diraethyl-2,4-pentanediol (C7) (Me-E2-4); 3,3-dimethyl-2,4-pentanediol (C7) P02; 3-methyl-2,4-pentanediol (C6) (Me-Eß.? 0); 3-methyl-2,4-pentanediol (C6) P03t fl} 4. 1,3-hexanediol (C6) (Me-E2-5); 1, 3-hexanediol
(C6) P02; 1,3-hexanediol (C6) B0 ?; 2-methyl-l, 3-hexanediol
(C7) E6.8; -methyl-1,3-hexanediol (C7) PO ?; 2-methyl-l, 3-hexanediol (C7) n-B02-3; 3-methyl-l, 3-hexanediol (C7) E6_8; 3- methyl-1,3-hexanediol (C7) P0 ?; 3-methyl-l, 3-hexanediol (C7)
n-B02-3; 4-methyl-l, 3-hexanediol (C7) E6.8; 4-methyl-l, 3-f-hexanediol (C7) P0?, - 4-methyl-l, 3-hexanediol (C7) n-B02.3; 5- methyl-1,3-hexanediol (C7) E6.a; 5-methyl-l, 3-hexanediol (C7)
P0 ?; 5-methyl-l, 3-hexanediol (C7) n-B02_3; 1,4-hexanediol (C6)
(Me-E2_5); 1,4-hexanediol (C6) P02; 1, 4 -hexanediol (C6) BO ?;
2-methyl-l, 4-hexanediol (C7) E6.8; 2-methyl-l, 4-hexanediol (C7)
PO ?; 2-methyl-l, 4-hexanediol (C7) n-B02.3; 3-methyl-l, 4-hexanediol (C7) E6_8; 3-methyl-l, 4-hexanediol (C7) P0 ?; 3- methyl-1,4-hexanediol (C7) n-B02_3; 4-methyl-l, 4-hexanediol
(C7) Es.8; 4-methyl-l, 4-hexanediol (C7) POx; 4-methyl-l, 4-
hexanediol (C7) n-B02-3; 5-methyl-l, 4-hexanediol (C7) Eß_8; 5- methyl-l, 4-hexanediol (C7) PO ?; 5-methyl-l, 4-hexanediol (C7) n-B02_3; 1,5-hexanediol (C6) (Me-E2_5); 1,5-hexanediol (C6) fl P02; 1,5-hexanediol (C6) BO ?; 2-methyl-l, 5-hexanediol (C7) E6. 5 8; 2-methyl-l, 5-hexanediol (C7) PO ?; 2-methyl-l, 5-hexanediol (C7) n-B02-3; 3-methyl-1,5-hexanediol (C7) Es_8; 3-methyl-l, 5-hexanediol (C7) P0 ?; 3-methyl-l, 5-hexanediol (C7) n-B02-3; 4- methyl-l, 5-hexanediol (C7) E6-8; 4-methyl-l, 5-hexanediol (C7) PO ?; 4-methyl-l, 5-hexanediol (C7) n-B02-3, -5-methyl-l, 5-f) hexanediol (C7) E6-8; 5-methyl-l, 5-hexanediol (C7) PO ?; 5- methyl-1,5-hexanediol (C7) n-BOa-3; 1, 6-hexanediol (C6) (Me-E? -2); 1, 6-hexanediol (C6) PO? .2; 1, 6-hexanediol (C6) n-B04; 2-methyl-l, 6-hexanediol (C7) E2_5; 2-methyl-l, 6-hexanediol (C7) n-BO ?; 3-methyl-l, 6-hexanediol (C7) E2.5; 3-methyl-l, 6-15 hexanediol (C7) n-BO ?; 2,3-hexanediol (C6) E2"5; 2,3-f) hexanediol (C6) n-BOx; 2,4-hexanediol (C6) (Me-E5.8); 2,4-hexanediol (C6) P03; 2-methyl-2,4-hexanediol (C7) (Me-E? _2); 2-methyl -2,4-hexanediol (C7) PO? -2; 3-methyl-2,4-hexanediol (C7) (Me-E? .2); 3-methyl-2,4-hexanediol (C7) PO? .2; 4-methyl-20 2, 4-hexanediol (C7) (Me-E? -2); 4-methyl -2,4-hexanediol (C7) P0? -2; 5-methyl-2,4-hexanediol (C7) (Me-E? .2); 5-methyl-2,4-hexanediol (C7) P0? -2; 2,5-hexanediol (C6) (Me-E5_8); 2,5-hexanediol (C6) P03; 2-Rethyl-2, 5-hexanediol (C7) (Me-E? -2); 2-methyl-2,5-hexanediol (C7) P0? -2; 3-methyl-2, 5-hexanediol
(C7) (Me-E? _2); 3-methyl-2,5-hexanediol (C7) P0? -2; 3,4-hexanediol (C6) B02_5; 3, 4-hexanediol (C6) n-B0 ?; 5. 1,3-heptane diol (C7) E3.6; 1, 3-heptanediol (C7) f) PO ?; 1,3-heptanediol (C7) n-B02; 1, 4-heptane diol (C7) E3_6;
1,4-heptanediol (C7) P0?, -1,4-heptanediol (C7) n-B02; 1,5-heptanediol (C7) E3.s; 1,5-heptanediol (C7) P0?, - 1,5-heptanediol (C7) n-B02; 1,6-heptanediol (C7) E3-6; 1,6-heptanediol (C7) PO ?; 1,6-heptanediol (C7) n-B02; 1,7- heptanediol (C7) E? -2; 1, 7-heptanediol (C7) n-BO ?; 2,4-fl) heptanediol (C7) E7.10; 2,4-heptanediol (C7) (Me-E?); 2,4-heptanediol (C7) PO ?; 2,4-heptanediol (C7) n-B03; 2,5-heptanediol (C7) E7.10; 2,5-heptanediol (C7) (Me-E?), 2,5-heptanediol (C7) PO ?; 2,5-heptanediol (C7) n-B03; 2,6-heptanediol (C7) E7_10; 2,6-heptanediol (C7) (Me-E?); 2.6- 15 heptanediol (C7) PO ?; 2,6-heptanediol (C7) n-B03; 3,5-f heptanediol (C7) E7-? 0; 3, 5-heptanediol (C7) (Me-E?); 3,5-heptanediol (C7) P0?, -3,5-heptanediol (C7) n-B03; 6. 3-methyl-2-isopropyl-l, 3-butanediol (C8) PO ?; 2, 3, 3 -trimethyl-2,4-pentanediol (C8) PO ?; 2, 2-diethyl-l, 3- 20-butanediol (C8) E2-5; 2,3-dimethyl-2,4-hexanediol (C8) E2.5; 2,4-dimethyl-2,4-hexanediol (C8) E2-s; 2,5-dimethyl-2,4-hexanediol (C8) E2.5; 3, 3-dimethyl -2,4-hexanediol (C8) E2_5; 3,4-dimethyl-2,4-hexanediol (C8) E2_5; 3, 5-dimethyl-2, 4-hexanediol (C8) E2.5; 4, 5-dimethyl-2,4-hexanediol (C8) E2-5;
,5-dimethyl-2,4-hexanediol (C8) E2_5; 2, 3-dimethyl-2, 5-hexanediol (C8) E2-5; 2,4-dimethyl-2, 5-hexanediol (C8) E2.s; 2,5-dimethyl-2,5-hexanediol (C8) E2-5; 3, 3-dimethyl-2,5-f-hexanediol (C8) E2-5; 3, 4-dimethyl-2, 5-hexanediol (C8) E2-5; 3-5-RETHYL 3,5-heptanediol (C8) E2-5; 2, 2-diethyl-l, 3-butanediol (C8) n-B0? -2; 2, 3-d? Methyl-2,4-hexanediol (C8) n -BO? .2; 2,4-dimethyl-2,4-hexanediol (C8) n-BO? -2; 2, 5-dimethyl-2, 4-hexanediol (C8) n-BO? _2; 3, 3-dimethyl-2,4-hexanediol (C8) n-B0? _2; 3,4-d? Met? L-2,4-hexanediol (C8) n-BO? .2; 3,5-dimethyl- ?? 2,4-hexanediol (C8) n -BO? -2; 4, 5-dimethyl-2,4-hexanediol (C8) n-BO? -2; 5, 5-dimethyl-2,4-hexanediol n-BO? _2; 2, 3-dimethyl-2, 5-hexanediol (C8-L n-BO? _2; 2,4-dimet? L-2, 5-hexanediol (C8) n- BO? .2; 2,5-dimethyl- 2,5-hexanediol (C8) n-BO.2; 3,3-dimethyl-2, 5-hexanediol (C8) n-BO? -2; 3,4-dimethyl-2, 5-hexanediol (C8)
n-BO? -2; 3-methyl-3,5-heptanediol (C8) n-BO? -2; 2- (l, 2-? K, dimethylpropyl) -1, 3-propanediol (C8) n-B0?, - 2-ethyl-2,3-dimethyl-1,3-butanediol (C8) n-B0 ?, - 2-methyl-2-isopropyl-1,3-butanediol (C8) n-B0 ?; 3-methyl-2-isopropyl -1,4-butanediol (C8) n-B0 ?; 2, 2, 3-tpmethyl-l, 3-pentanediol (C8) n-BO?, - 20 2, 2, 4-trimethyl-l, 3-pentanediol (C8) n-BO ?; 2, 4, 4-trimethyl-1,3-pentanediol (C8) n-BO ?; 3, 4, 4-trimethyl-l, 3-pentanediol (C8) n-BO ?; 2, 2, 3-trimethyl-l, 4-pentanediol (C8) n-BO ?; 2, 2, 4 -trimethyl-1,4-pentanediol (C8) n-BO ?; 2, 3, 3-trimethyl-1,4-pentanediol (CS) n-BO ?; 2, 3, 4-trimethyl-l, 4-pentanediol
(C8) n-BOi; 3, 3, 4-trimethyl-l, 4-pentanediol (C8) n-BO_; 2, 3, 4 -trimethyl-2,4-pentanediol (C8) n -B0?, - 4-ethyl-2,4-hexanediol (C8) n-BO ?; 2-methyl-2,4-heptanediol (C8) n -BO?, - f) 3-methyl-2,4-heptane-diol (C8) n-BO ?; 4-methyl-2,4-heptanediol 5 (C8) n-B0 ?; 5-methyl-2,4-heptanediol (C8) n-BO ?; 6-methyl-2,4-heptanediol (C8) n-BO ?; 2-methyl-2, 5-heptanediol (C8) n-B0?, - 3-methyl-2, 5-heptanediol (C8) n-B0 ?; 4-methyl-2, 5-heptanediol (C8) n-BO ?; 5-methyl-2, 5-heptanediol (C8) n-B0?, - 6-methyl-2,5-heptanediol (C8) n-B0 ?; 2-methyl-2,6-heptanediol (C8) n-BO ?; fl 3 -methyl -2,6-heptanediol (C8) n-BO ?; 4-methyl-2,6-heptanediol (C8) n-BO ?; 2-methyl-3,5-heptanediol (C8) n-B0?, 2- (1,2-dimethylpropyl) -1,3-propanediol (C8) E? _3; 2-ethyl-2, 3-dimethyl-1,3-butanediol (C8) E? _3; 2-methyl-2-isopropyl-l, 3-butanediol (C8) E? .3; 3-methyl-2-isopropyl-1,4-butanediol (C8) E_3; 2, 2, 3-trimethyl-1,3-pentanediol (C8) E? _3; 2, 2, 4-trimethyl-1,3-flu) pentanediol (C8) E? -3; 2, 4, 4-trimethyl-l, 3-pentanediol (C8) E? -3; 3, 4, 4-trimethyl-l, 3-pentanediol (C8) E? .3; 2,2,3-trimethyl-1,4-pentanediol (C8) E? .3; 2, 2, 4-trimethyl-l, 4-pentanediol (C8) E? -3; 2, 3, 3-trimethyl-1,4-pentanediol (C8) 20 E? .3; 2, 3, 4 -trimethyl-1,4-pentanediol (C8) E? _3; 3,3,4-trimethyl-1,4-pentanediol (C8) E? .3; 2, 3, 4-trimethyl-2,4-pentanediol (C8) E? .3; 4-ethyl-2,4-hexanediol (C8) E? .3; 2- methyl-2,4-heptanediol (C8) E? .3; 3-methyl -2,4-heptane diol (C8) E? .3; 4-methyl-2,4-heptanediol (C8) E? .3; 5-methyl-2,4-
heptanediol (C8) E? _3; 6-methyl-2,4-heptanediol (C8) E? -3; 2- methyl-2, 5-heptanediol (C8) E? _3; 3-methyl-2, 5-heptanediol (C8) E? .3; 4-methyl-2,5-heptanediol (C8)? 1-3; 5-methyl-2,5-f | heptanediol (C8) E? _3; 6-methyl-2, 5-heptanediol (C8) E? -3; 2-5-methyl-2,6-heptanediol (C8) E? .3; 3-methyl-2,6-heptanediol (C8) E? _3; 4-methyl-2,6-heptanediol (C8) E? .3; and / or 2-methyl-3,5-heptanediol (C8) E? _3; and 7. mixtures thereof. Of the nonano isomers, only 2,3,3,4- ^ tetramethyl-2,4-pentadiol is highly preferred. In addition to the major solvents aliphatic diols and some of their alkoxylated derivatives, described above and hereinafter, it was also found that some "specific dichloride ethers are solvents
main suitable for the formulation of compositions
^ Liquid, concentrated, transparent fabric softeners of the present invention. Similar to the main aliphatic diol solvents, it was found that the suitability of each main solvent is very selective,
depending for example on the number of carbon atoms in the specific diol ether molecules. For example, as shown in Table VI, for the series of glyceryl esters having the formula HOCH2-CHOH-CH2-O-R, wherein R is alkyl of 2 to 8 carbon atoms, only
monopentyl ethers with the formula HOCHi-CHOH-CHi-O-CsHxx (3 -pentyloxy-1,2-propanediol), wherein the group C5H ?? it comprises different pentyl isomers, have flLl ClogP values of about 0.25 to 0.62 and are suitable for the formulation of the transparent fabric softeners, liquids, concentrates of the present invention. These are illustrated by the examples and comparative examples XXXIIA-7 to XXXIIA-7F. It was also found that the cyclohexenyl derivative is appropriate, but not the cyclopentyl derivative. Similarly, selectivity is demonstrated in the selection of arylglyceryl ethers. Of the many possible aromatic groups, only a few phenol derivatives are appropriate. The same narrow selectivity is also found for the di (hydroxyalkyl) ethers. It has been
^ discovered that the bis (2-hydroxybutyl) ether is appropriate, but not the bis (2-hydroxypentyl) ether. For the di (cyclic hydroxyalkyl) analogs, the bis (2-hydroxycyclopentyl) ether is appropriate, but not the bis (2-hydroxycyclohexyl) ether. Non-limiting examples of synthesis methods for the preparation of some di (hydroxyalkyl) ethers are presented below. Butyl monoglyceryl ether (also called 3-butyloxy-1,2-propanediol) is not adequate enough
to form the transparent, liquid, concentrated fabric softeners of the present invention. However, their polyethoxylated derivatives, preferably near fl from triethoxylated to nonaethoxylated, more preferably from 5 pentaethoxylated to octaethoxylated, are the appropriate principal solvents, as shown in Table VI. All preferred alkyl glyceryl ethers and / or di (hydroxyalkyl) ethers have been identified? are in Table VI and most preferred are: 3- (n- ^ pentyloxy) -1,2-propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3-pentyloxy) -1,2-propanediol; 3- (2-methyl-l-butyloxy) -1,2-propanediol; 3- (iso-amyloxy) -1,2-propanediol; 3- (3-methyl-2-butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1,2-propanediol; 3- (1-cyclohex-l-enyloxy) -1,2-propanediol; 2- 15 (pentyloxy) -1,3-propanediol; 2- (2-pentyloxy) -1, 3- ^ propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-methyl-l-butyloxy) -1,3-propanediol, -2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) -1,3-propanediol; 2- (1-cyclohex-l-enyloxy) -1,3-propanediol;
3- (Butyloxy) -1,2-propanediol pentaethoxylated; 3- (Butyloxy) -1,2-propanediol hexaethoxylated; 3- (Butyloxy) -1,2-propanediol heptaethoxylated; 3- (Butyloxy) -1,2-propanediol octaethoxylated; 3- (Butyloxy) -1,2-propanediol nonaethoxylated; 3- (Butyloxy) -1,2-propanediol monopropoxylated; 3- (butyloxy) -1, 2-
dibutyleneoxylated propanediol; and / or 3- (butyloxy) -1,2-propanediol tributyleneoxylated. Preferred aromatic glyceryl ethers include: 3-phenyloxy-1,2-propanediol; fl 3-benzyloxy-l, 2-propanediol; 3- (2-phenylethyloxy) -1,2-5 propanediol; 1,2-propanediol, 2- (m-cresyloxy) -1,3-propanediol; 2- (p-cresyloxy) -1,3-propanediol; 2- (benzyloxy) -1,3-propanediol, -2- (2-phenylethyloxy) -1,3-propanediol; and mixtures thereof. The most preferred aromatic glyceryl ethers include: 3-phenyloxy-1,2-propanediol; 3- ^ benzyloxy-1,2-propanediol; 3- (2-phenylethyloxy) -1,2-propanediol; 1,2-propanediol; 2- (m-cresyloxy) -1,3-propanediol; 2- (p-cresyloxy) -1,3-propanediol; 2- (2-phenylethyloxy) -1,3-propanediol, and mixtures thereof. The most preferred di (hydroxyalkyl) ethers include: ether 15 bis (2-hydroxybutyl) and bis (2-hydroxycyclopentyl) ether;
A non-limiting example of synthesis methods for preparing the alkyl and aryl monoglyceryl ethers is given in co-pending application 08 / 679,694, incorporated herein by reference. Preferred alicyclic diols and their derivatives include (1) saturated diols and their derivatives including: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-l, 2-cyclobutanediol; 3- isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol;
1, 2-dimethyl-1,2-cyclopentanediol, -1,4-dimethyl-1, 2-cyclopentanediol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-d? Met? L-1,2-cyclopentanediol; 3, 4-dimethyl-l, 2-flj) cyclopentanediol; 4, 5-dimethyl-1,2-cyclopentanediol; 3-ethyl-5-l, 2-cyclopentanediol; 4, 4-dimethyl-1,2-cyclopentanediol; 4- ethyl-1,2-cyclopentanediol; 1,1-bis (bihydroxymethyl) cydohexane; 1,2-bis (bihydroxymethyl) cydohexane; 1,2-dimethyl-l, 3-cyclohexanediol; 1,3-bis (bihydroxymethyl) cydohexane; 1,3- ?? dimethyl-1,3-cydohexanediol; 1-hydroxy-cyclohexaneethanol; 1- hydroxy-cyclohexanemethanol; l-ethyl-l, 3-cyclohexanediol; 1- methyl-1,2-cydohexanediol; 2, 2-dimethyl-l, 3-cyclohexanediol; 2,3-dimethyl-1,4-cydohexanediol; 2,4-dimethyl-1, 3-cyclohexanediol; 2,5-dimethyl-1,3-cydohexanediol; 2,6-15 dimethyl-1,4-cydohexanediol; 2-ethyl-l, 3-cyclohexanediol; 2-f) hydrocyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2- hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3- hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3- methyl-1,2-cydohexanediol; 4, 4-d? Methyl-l, 3-cydohexanediol;
4, 5-dimethyl-1,3-cydohexanediol; 4, 6-dimethyl-l, 3-cyclohexanediol; 4-ethyl-l, 3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxyethyl-1-cyclohexanol; 4- hydroxymethylcyclohexanol; 4-methyl-l, 2-cyclohexanediol; 5,5-dimethyl? -1,3-cyclohexanediol; 5-ethyl-l, 3-cyclohexanediol;
1,2-cycloheptanediol; 2-methyl-l, 3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-l, 3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-l, 4-cycloheptanediol; 6-RETHYL-FJ) 1,4-cycloheptanediol; 1,3-cyclooctanediol, 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol diethoxylate; triethoxylate of I, 2-cyclohexanediol; 1, 2-cyclohexanediol tetraethoxylate, 1,2-cyclohexanediol pentaethoxylate; 1, 2-cyclohexanediol hexaethoxylate; 1, 2-cyclohexanediol heptaethoxylate, 1,2-f octetoxylate} cyclohexanediol; 1,2-cyclohexanediol nonaethoxylate; 1,2-cyclohexanediol monoethoxylate; 1,2-cyclohexanediol monobutylenoxylate; 1,2-cyclohexanediol dibutyleneoxylate; and / or tributyleneoxylate- of 1,2-cyclohexanediol. The saturated alicyclic diols and their most preferred derivatives are: 1-isopropyl-1, 2- ^ P-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3- propyl-1,2-cyclobutanediol; 3-isopropyl-1, 2-cyclobutanediol; 1-e il-1,2-cyclopentanediol; 1,2-dimethyl-1, 2-cyclopentanediol; 1,4-dimethyl-l, 2-cyclopentanediol; 3,3- 20 dimethyl-1,2-cyclopentanediol; 3, 4-dimethyl-l, 2-cyclopentanediol; 3, 5-dimethyl-l, 2-cyclopentanediol; 3-ethyl-1, -cyclopentanediol; 4, 4-dimethyl-l, -cyclopentanediol; 4- ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-1, 3-
cyclohexanediol; 1, -bis (hydroxymethyl) cydohexane; 1- hydroxy-cyclohexanemethanol; 1-methyl-l, 2-cydohexanediol; 3- hydroxymethylcyclohexanol; 3-methyl-1,2-cydohexanediol; 4,4-f | dimethyl-1,3-cydohexanediol; 4, 5-dimethyl-l, 3- 5-cydohexanediol; 4,6-dimethyl-l, 3-cyclohexanediol, 4-ethyl-1,3-cydohexanediol; 4-hydroxyethyl-l-cyclohexanol; 4- hydroxymethylcyclohexanol; 4-methyl-l, 2-cyclohexanediol; 1,2-cycloheptanediol; 1,2-cyclohexanediol pentaethoxylate; 1, 2-cyclohexanediol hexaethoxylate; 1,2- ^ Bk heptaethoxylate cyclohexanediol; 1, 2-cyclohexanediol octaethoxylate, 1,2-cyclohexanediol nonaethoxylate; 1, 2-cyclohexanediol monopropoxylate; and / or 1,2-cyclohexanediol dibutyleneoxylate. Preferred aromatic diols include: 1-15 phenyl-1,2-ethanediol, -1-phenyl-1,2-propanediol; 2-phenyl-1, 2-f} propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1, 3-butanediol; and / or 1-phenyl-1,4-butanediol, of which 1- 20 phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1, 3-propanediol; and / or 1-phenyl-1,4-butanediol; They are the most preferred.
As discussed herein above, all unsaturated materials that are related to the other principal solvents preferred herein by the same ratio, i.e., have more CH2 groups than the corresponding saturated major solvents and remain within the effective range ClogP, they are preferred. However, the preferred major unsaturated diol solvents are: 2,2-diallyl-1,3-butanediol; 2- (1-ethyl-1-propenyl) -1,3-butanediol; 2- (2-butenyl) -2-methyl-l, 3-flj butanediol, -2- (3-methyl-2-butenyl) -1, 3-butanediol; 2-ethyl-2- (2-propenyl) -1,3-butanediol; 2-methyl-2- (1-methyl-2-propenyl) -1,3-butanediol; 2, 3-bis (1-methylethylidene) -1,4-butanediol, -2-ethenyl-3-ethyl-1,3-pentanediol; 2-ethenyl-4, 4-dimethyl-1, 3-pentanediol; 3-methyl-2- (2-propenyl) -1,4-pentanediol; 2- (1,1-15 dimethylethyl) -4-pentene-1,3-diol; 2-ethyl-2, 3-dimethyl-4- ^ P-pentene-1,3-diol; 4-ethyl-2-methylene-1,4-hexanediol; 2,3,5-trimethyl-1,5-hexadiene-1,4-diol; 2- (1-methylethhenyl) -1,5-hexanediol; 4-ethenyl-2, 5-dimethyl-2-hexane-1,5-diol; 6-methyl-5-methylene-1,4-heptanediol; 4,6-dimethyl-2, 4-heptadiene-2,6,6-diol; 2, 5, 5-trimethyl-2,6-heptadiene-1,4-diol; 5, 6-dimethyl-2-heptene-1,4-diol; 4,6-dimethyl-3-heptene-1,5-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3, 6-dimethyl-5-heptene-1,3-diol; 2,6-dimethyl-5-heptene-1,4-diol; 3, 6-dimethyl-5-heptene-1, 4-diol; 2, 2-dimethyl-6-heptene-1,3-diol; 5, 6-dimethyl-6-hepteno-
1,4-dxol; 2,4-dimethyl-6-heptene-1, 5-diol; 2-ethylidene-6-methyl-6-heptene-1, 5-diol; 4- (2-propenyl) -6-heptene-2,4-diol; 3-ethenyl-l-octene-3,6-diol; 2, 7-dimethyl-2,4,6,6-octatriene-fl 1,8-diol; 2,6-dimethyl-2,5-octadiene-l, 7-diol; 3,7-dimethyl-5 2,5-octadiene-l, 7-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol. { Rosiridol); 2-methyl-2,6-octadiene-l, 8-diol, -3,7-dimethyl-2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-l, 5-diol; 2,6-dimethyl (8-hydroxy-nalo-olol) -2,7-octadiene-l, 6-diol; 2,7- dimethyl-2,7-octadiene-l, 6-diol; 2-methyl-6-methylene-2-octene-f | 1,7-diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene-3,5-octanediol; 2,6-dimethyl-3,7-octadiene-l, 6-diol; 2- methylene-4-ketene-1,8-diol; 2-methyl-6-octene-3,5-diol; 4- methyl-6-octene-3,5-diol; 2-methyl-6-methylene-7-octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; 15-l-nonene-3,5-diol; l-nonene-3, 7-diol; 3-nonene-2, 5-diol; 4-f? noneno-2, 8-diol; 6, 8-nonadieno-l, 5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1, 9-decadiene-3, 8-diol; and / or 1, 9-decadiene-4,6-diol. Said main alcohol solvent can also
Preferably selected from the group consisting of: 2-5-dimethyl-2,5-hexanediol; 2-ethyl-l, 3-hexanediol; 2-methyl-2-propyl -1,3-propanediol; 1,2-hexanediol and mixtures thereof. More preferably, said main alcohol solvent is selected from the group consisting of 2-ethyl-
1,3-hexanediol; 2-methyl-2-propyl-l, 3-propanediol; 1,2-hexanediol; and mixtures thereof. Even more preferable, said main alcohol solvent is selected from the f) group consisting of 2-ethyl-l, 3-hexanediol; 1,2-hexanediol; 5 and mixtures thereof. When several derivatives of the same diol with different alkyleneoxy groups can be used, for example, 2-methyl-2,3-butanediol with 3 or 5 ethyleneoxy groups, or 2 propyleneoxy groups, or 1 butyleneoxy group, fl is preferred} use the derivative with the least number of groups, that is, in this case, the derivative with a butyleneoxy group. However, when only about one to four ethyleneoxy groups are necessary to provide good formulability, these derivatives are also preferred. 15 f) UNSATURATED DIOLES
It has surprisingly been found that there is a clear similarity between the acceptability (formulability) of a saturated diol and its unsaturated counterparts or analogs, which have higher molecular weights. The unsaturated homologs / analogues have the same formulability as the predecessor saturated main solvent, with the proviso that the main unsaturated solvents have a methylene group
additional (ie, CH2) for each double bond in the chemical formula. In other words, there is an apparent "rule of addition" in which for each saturated primary solvent
From this invention, which is suitable for the formulation of concentrated, clear, fabric softening compositions, there are suitable unsaturated major solvents where one or more CH2 groups are added while, for each added CH2 group, two atoms are removed. of hydrogen from carbon atoms
? adjacent to the molecule to form a carbon-carbon double bond, thus keeping constant the number of hydrogen atoms in the molecule with respect to the chemical formula of the saturated main solvent "predecessor". This is due to the surprising fact that adding a group - 15 CH2 - to a chemical solvent formula has an effect of fl) increasing the ClogP value by about 0.53, while removing two adjacent hydrogen atoms to form a double bond has a effect of decreasing _ its ClogP value by approximately a similar amount, namely 0.48,
thus compensating for the addition of CH2. Accordingly, one goes from a saturated main solvent to the preferred higher molecular weight unsaturated analogs / homologs containing at least one carbon atom plus by inserting a double bond for each additional CH2 group, and thus the total number of
Hydrogen atoms remain the same as in the predecessor saturated solvent, while the ClogP value of the new solvent remains within the effective range of 0.15-0.64, f | preferably around 0.25 to 0.62, and more preferably 5 of about 0.40 to 0.60. The following are illustrative examples: 2 -2-dimethyl-6-heptene-1,3-diol (CAS No. 140192-39-8) is a preferred diol main solvent of 9 carbon atoms and can be considered to be derivatized by adding ^ Bk appropriately a CH2 group and a double bond to any of the following preferred diol main solvents of 8 carbon atoms: 2-methyl-1,3-heptanediol or 2,2-dimethyl-1,3-hexanediol, - 2.4 -dimethyl-5-heptene-1,3-diol (CAS No. 123363-15-69-9) is a preferred major diol solvent of 9 carbon atoms and can be considered to be derived by appropriately adding a CH2 group and a double bond to any of the following preferred diol main solvents of 8 carbon atoms: 2-methyl-1,3-heptanediol or 2,4-dimethyl-1,3-hexanediol; 2- (1-ethyl-1-propenyl) -1,3-butanediol (CAS No. 116106-35-6) is a preferred diol main solvent of "9 carbon atoms and may be considered to be derived by appropriately adding a group" CH and a double link to any
of the following preferred diol main solvents of 8 carbon atoms: 2- (1-ethylpropyl) -1,3-propanediol or 2- (1-methylpropyl) -1,3-butanediol. fl 2-Ethyl-3-ethyl-1,3-pentanediol (CAS No.
104683-37-6) is a preferred diol main solvent of 9 carbon atoms and can be considered to be derived by appropriately adding a CH2 group and a double bond to any of the following preferred diol main solvents of 8 carbon atoms: 3-ethyl- 2-methyl-l, 3-pentanediol or 2-ethyl- ^ p 3 -methyl-1,3-pentanediol. 3,6-Dimethyl-5-heptene-1,4-diol (CAS No. 106777- gg-5) is a preferred diol main solvent of 9 carbon atoms and can be considered to be derived by appropriately adding a CH2 group and a double bond To anybody
of the following preferred diol main solvents of 8
^ P carbon atoms: 3-methyl-l, 4-heptanediol, 6-methyl-l, 4-heptanediol or 3, 5-dimethyl-1,4-hexanediol. The 5,6-dimethyl-6-heptene-1,4-diol (for example CAS No. 152344-16-6) is a preferred primary diol solvent of
9 carbon atoms and it can be considered to derive it by appropriately adding a CH2 group and a double bond to any of the following preferred diol solvents of 8 carbon atoms: 5-methyl-1,4-heptanediol; 6-methyl-l, 4-heptanediol or 4,5-dimethyl-l, 3-hexanediol.
4-Methyl-6-octane-3, 5-diol (CAS No. 156414-25-4) is a preferred diol main solvent of 9 carbon atoms and can be considered to be derived by appropriately adding a CH2 group and a double bond to any of the following preferred preferred diol solvents of 8 carbon atoms: 3,5-octanediol, 3-methyl-2,4-heptanediol or 4-methyl-3,5-heptanediol. Rosiridol (CAS No. 101391-01-9) and isorosyridol (CAS No. 14g252-15-3) are two isomers of 3,7- ^ dimethyl-2,6-octadiene-1,4-diol, and are the preferred diol main solvents of 10 carbon atoms. It can be considered to derive them by appropriately adding two groups
CH2 and two double bonds to any of the following preferred diol main solvents of 8 atoms
Carbon: 2-methyl-l, 3-heptane diol; 6-methyl-l, 3-heptane diol;
. { fi) 3-methyl-l, 4-heptane diol; 6-methyl-l, 4-heptane diol; 2,5-dimethyl-1,3-hexanediol; or 3, 5-dimethyl-1,4-hexanediol. The 8-hydroxylinalool (CAS No. 103619-06-3, 2,5-dimethyl-2,7-octadiene-l, 6-diol) is a preferred main solvent of 10 carbon atoms and can be considered to be derived by appropriately adding two CH2 groups and two double bonds to any of the following preferred diol main solvents of 8 carbon atoms: 2-methyl-1,5-heptanediol; 5-methyl-l, 5-heptanediol; 2-methyl-l, 6-
heptanediol; 6-methyl-l, 6-heptanediol, - or 2, -dimethyl-l, 4-hexanediol. 2,7-Dimethyl-3,7-octadiene-2,5-diol (CAS No.
^ P 171436-39-8) is a preferred diol main solvent of 10 5 carbon atoms and can be considered to be derived by appropriately adding two CH2 groups and two double bonds to any of the following preferred diol solvents of 8 carbon atoms: 2, 5-octanediol; 6-methyl-1,4-heptane diol; 2-methyl-2,4-heptanediol; 6-methyl-2,4-flk heptanediol; 2-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; and 2,5-dimethyl-2,4-hexanediol. 4-Butyl-2-butene-1,4-diol (CAS No. 153943-66-9) is a preferred diol main solvent of 8 carbon atoms and may be considered to be derivatized by adding
A CH2 group and a double bond are suitably attached to any of the following preferred diol solvents of 7 carbon atoms: 2-propyl-l, 4-butanediol or 2-butyl-l, 3-propanediol. In the same way, there are cases where a counterpart
higher molecular weight unsaturated which is derived from an inoperable poor saturated solvent, is itself a poor solvent. For example, 3, 5-dimethyl-5-hexene-2, 4-diol (for example CAS No. 160429-40-3) is a poor unsaturated solvent of 8 carbon atoms, and can
considered to be derived from the following poor saturated solvents of 7 carbon atoms: 3-methyl-2,4-hexanediol; 5- methyl-2,4-hexanediol; or 2, 4-dimethyl-I, 3-pentanediol; and fl 2,6-dimethyl-5-heptene-1,2-diol (eg, CAS No. 141505-7 71-7) is a poor unsaturated solvent of 9 carbon atoms, and may be considered to be derived from the following poor saturated solvents of 8 carbon atoms: 2-methyl-1,2-heptanediol; 6-methyl-1,2-heptanediol; or 2, 5-dimethyl-l, 2-hexanediol. It has also been found that there is an exception in the previous addition rule, in which the main saturated solvents always have unsaturated analogues / homologues with the same degree of acceptability. The exception refers to the main solvents diol
saturates having the two hydroxyl groups located in aphix two adjacent carbon atoms. In some cases, but not always, inserting one or more CH2 groups between the two adjacent hydroxyl groups of a poor solvent results in an unsaturated homologue of higher molecular weight than
is more suitable for the transparent, concentrated, fabric softening formulation. For example, it can be considered to derive the preferred unsaturated 6,6-dimethyl-1-heptene-3, 5-diol (CAS No. 109788-01-4) which has no adjacent hydroxyl groups, from 2, 2-dimethyl- 3, 4-hexanediol
inoperable, which has adjacent hydroxyl groups. In this case, it is more reliable to consider that 6,6-dimethyl-1-heptane-3, 5-diol is derived from 2-methyl-3,5-heptanediol or
^^ of 5, 5-dimethyl-2,4-hexanediol which are solvents
preferred principals and do not have adjacent hydroxyl groups. Conversely, inserting CH2 groups between adjacent hydroxyl groups of a preferred principal solvent may result in an inoperable, higher molecular weight unsaturated solvent-diol. For example, it can be considered to derive the unsaturated unsaturated 2,4-dimethyl-5-hexene-2,4-diol (CAS No. 87604-24-8) which has no adjacent hydroxyl groups, starting from 2, 3- Preferred dimethyl-2, 3- pentanediol which has adjacent hydroxyl groups In this case, it is more reliable to derive the
unsaturated operable 2, 4-dimethyl-5-hexene-2,4-diol either "2-methyl-2,4-hexanediol or 4-methyl-2,4-hexanediol, which are inoperable solvents and do not They have adjacent hydroxyl groups, and there are also cases where an inoperable unsaturated solvent can be considered to be derived.
has no adjacent hydroxyl groups, from an inoperable solvent having adjacent hydroxyl groups, such as par 4, 5-dimethyl-6-hexene-1,3-diol and 3,4-cimethyl-l, 2-pentanediol. Consequently, in order to deduce the formulability of an unsaturated solvent that does not have groups
adjacent hydroxyl, start from a saturated low molecular weight homologue that also does not have adjacent hydroxyl groups. That is, in general, the
^^ relationship is more reliable when the distance / ratio of
the two hydroxyl groups is maintained. That is, it is reliable to start from a solvent saturated with adjacent hydroxyl groups to deduce the formulability of the higher molecular weight unsaturated homologs that also have adjacent hydroxyl groups. It has been discovered that the use of specific major alcohol solvents can produce stable, low viscosity, transparent fabric softening compositions at surprisingly low primary solvent levels, ie, less than 40% by weight
the composition when the softening active ingredients
"Have VI and cis / trans ratios has also been discovered that the use of the principal alcohol solvents can produce softener compositions highly concentrated fabric, which are stable and can be 0 diluted, for example, about 2:. 1 to 10 : 1, to produce compositions with lower levels of fabric softener that are still stable As previously discussed, it is desirable that the main solvents are kept in the lowest
possible levels in the present compositions to obtain translucency or transparency. The presence of water exerts an important effect on the need for solvents
^^ Main to obtain transparency of these
compositions. The higher the water content, the higher the level of the main solvent (in relation to the level of softener) necessary to achieve product transparency. Conversely, the lower the water content, the less solvent is needed (in relation to the softener). Thus, at low water levels of about 5% to 15%, the weight ratio of active softener to principal solvent is preferably from about 55:45 to 85:15, more preferable from about 60:40 to 80: twenty. At water levels of about 15% to 70%, the weight ratio of
main active solvent softener is preferably from
^ * about 45:55 to 70:30, more preferable about 55:45 to 70:30. But at high water levels of around 70% to 80%, the weight ratio of active softener to principal solvent is preferably about 30:70 to 55:45, more
preferably from about 35:65 to 45:55. At even higher water levels, the main solvent softener relationships should be even higher. Mixtures of the above main solvents are particularly preferred, since one of the problems associated with
Large amounts of solvents is protection. The mixtures decrease the amount of any other material that is present. Odor and flammability can be
™ also minimized through the use of mixtures,
especially when one of the main solvents is volatile or has an odor, which is more likely for low molecular weight materials. Suitable solvents that can be used at levels that would not be sufficient to produce a clear product are 2,2,4-fljl trimethyl-1,3-pentanediol; the ethoxylated, diethoxylated or triethoxylated derivatives of 2, 2, 4 -trimethyl-1, 3-pentanediol; the ethoxylated, diethoxylated or triethoxylated derivatives of 2,, 4-trimethyl-1,3-pentanediol; and / or 2-ethyl-1,3-hexanediol. For the purposes of this invention,
These solvents should only be used at levels that will not provide a stable or transparent product. Preferred mixtures are those where the majority of the solvent is one, or more, of those that have been identified herein as most preferred. The use of mixtures of
Solvents are also preferred, especially when one or more of the main solvents are solids at room temperature. In this case, the blends are fluid, or have lower melting points, thus improving the processability of the softening compositions.
It has also been found possible to replace part of a principal solvent or a mixture of principal solvents of this invention with a secondary solvent, or a mixture of secondary solvents, which by themselves are not 5 operable as a principal solvent of this invention, "as long as an effective amount of the main solvent (s) of this invention is still present in the concentrated, transparent fabric softener composition, an effective amount of the main solvent (s) ( It is
? this invention is at least greater than about 5%, preferably more than about 7%, more preferably greater than about 10% of the composition, when at least about 15% of the active softener is also present. The substitute solvent (s) can be used in
any level, but preferably almost equal to, or less
^^ a, the amount of operable master solvent, as defined above, which is present in the fabric softening composition. For example, even when 1,2-pentanediol, 1,3-20 octanediol and the hydroxy pivalyl hydroxy pivalate (hereinafter HPHP), having the following formula:
H0-CH2-C (CH3) 2-CH2-0-C0-C (CH3) 2-CH2-0H (CAS # 115-20-4)
are inoperable solvents according to this invention, the mixtures of these solvents with the main solvent, for example, with the preferred main solvent 1,2- ^ hexanediol, where the main solvent 1,2-hexanediol is present in effective levels , also provides transparent, concentrated fabric softening compositions. Some of the secondary solvents that can be used are those listed as inoperable above
™ J 'and hereafter, as well as some predecessor, non-alkoxylated solvents shown in Tables VIIIA-VIIIE. The main solvent can be used either to make a translucent or transparent composition, or to reduce the temperature at which the composition is
translucent or transparent. Thus, the invention also
^ includes the method for adding the main solvent, at the levels previously indicated, to a composition that is not translucent, or transparent, or that has a temperature where too high instability occurs, to make the
Translucent or transparent composition, or when the composition is clear, for example, at room temperature, or below a specific temperature, to reduce the temperature at which instability occurs, preferably at least about 5 ° C, more preferable to the
less near 10 ° C. The main advantage of the main solvent is that it provides the maximum advantage for a given solvent weight. It is understood that "solvent" as used herein, refers to the effect of the main solvent and not to its physical form at a given temperature, since some of the major solvents are solids at room temperature.
ALKYL LACTATES
Some ethers of alkyl lactates, for example, ethyl lactate and isopropyl lactate, have ClogP values within the effective range of about 0.15 to
0. 64, and can form clear, concentrated fabric softening compositions with the softening active ingredients of this invention, but need to be used at a slightly higher level than the more effective diol solvents such as 1,2-hexanediol. They may also be used to replace some of the other major solvents of this invention to form clear, concentrated fabric softening compositions. This is illustrated in the example
I-C
III. OPTIONAL INGREDIENTS
(A) Solvents soluble in water of low weight
^ * molecular can also be used at levels from 0% to
12%, preferably from about 1% to 10%, more preferably from about 2% to 8%. Water-soluble solvents can not provide a transparent product at the same low levels of principal solvents described above, but can provide a transparent product when the
The main solvent is not enough to provide a completely transparent product. The presence of these water-soluble solvents is therefore highly desirable.
These solvents include, ethanol, isopropanol; 1,2-propanediol; 1,3-propanediol; propylene carbonate, etc.,
but do not include any of the main solvents (B).
^ These water-soluble solvents have a higher affinity for water in the presence of hydrophobic materials as active softeners than the main solvents.20 (B) POLISHERS
The compositions herein may also optionally contain about 0.005% to 5% by weight of certain types of hydrophilic optical brighteners that
they also provide an inhibition action of color transfer. If used, the compositions herein will preferably comprise about 0.001% to 1% by weight of these optical brighteners. The hydrophilic optical brighteners useful in the present invention are those having the structural formula:
Wherein R1 is selected from anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl; R2 is selected from N-2-5-bis-hydroxyethyl, N-2-hydroxyethyl-N-methylamino, morphino,
™ chlorine and amino; and M is a salt-forming cation such as sodium or potassium. When in the above formula, R1 is anilino, R2 is N-2-bis-hydroxyethyl and M is a cation like sodium, the 0 brightener is acid 4, 4 '-bis [(4-anilino-6- (N-2 -bi? -hydroxyethyl) -s-triazine-2-yl) amino] -2-2 'stilbene disulfonic acid and disodium salt. This particular brightener species is marketed commercially under the trade name Tinopal-UNPA-GX® by Ciba Corporation. The Tinopal-UNPA-GX is the
Preferred hydrophilic optical brightener useful in the compositions added to the rinse herein. When in the previous formula Rl is aniline, R2 is
^ N-2-hydroxyethyl-N-2-methylamine and M is a cation such as sodium, 5 the brightener is disodium salt of 4,4'-bis [(4-anilino-6 (N-2-hydroxyethyl-N- methylamino) -s-triazine-2-yl) amino] 2, 2'-stilbenedisulfonic acid. This particular species of optical brightener is marketed commercially under the trade name of Tinopal 5BM-GX® by Ciha-Geigy
? P Corporation. When in the above formula, R1 is anilino, R2 is morpholino, and M is a cation such as sodium, the brightener is 4,4'-bis [(4-anilino-6-morphino-s-triazine-2- il) amino] 2, 2'-stilbenedisulfonic acid. This species
particular of optical brightener is marketed
^ commercially under the brand name Tinopal AMS-GX® by Ciba-Geigy Corporation.
(C) OPTIONAL VISCOSITY / DISPERSIBILITY MODIFIERS 20 Relatively concentrated compositions containing saturated and unsaturated diester quaternary ammonium compounds can be made stable without the addition of concentration aids. However,
compositions of the present invention may require organic and / or inorganic concentrating aids to achieve even higher concentrations and / or to comply with
«I stability standards depending on the others
ingredients These concentration aids which typically can be viscosity modifiers, may be necessary, or preferred, to ensure stability under extreme conditions when using levels of particular softening active ingredients. The concentration auxiliary surfactant lffs are typically selected from the group consisting of (1) simple long chain alkyl cationic surfactants; (2) nonionic surfactants; (3) amine oxides, - (4) fatty acids; and (5) mixtures thereof. These
auxiliaries are described in the patent application in
™ 'P & G serial procedure No. 08 / 461,207, filed on June 5, 19g5, by Wahl and co-inventors, specifically on page 14, line 12 through page 20, line 12, which is incorporated herein by reference . When said dispersibility aids are present, the total level is about 2% to 25%, preferably about 3% to 17%, more preferably about 4% to 15%, and even more preferably about 5% to about of 13% by weight of the composition. These materials can be added
as part of the raw material of the softening active ingredient (I), for example, the long chain single cationic alkyl cationic surfactant and / or the fatty acid, &bgr;, which are reactants used to form the active ingredient fabric softener biodegradable as discussed above, or added as a separate component The total level of dispersibility aid includes any amount that may be present as part of component (I).
(I) COMPOUND MONO-ALQUÍLICO CATIÓNICO OF AMMONIUM QUATERNARIO
When the cationic quaternary ammonium monoalkyl compound is present, it is typically present
at a level of about 2% to 25%, preferably about 3% flj 'to 17%, more preferable about 4% to 15%, and even more preferably about 5% to 13% by weight of the composition , the total quaternary ammonium cationic monoalkyl compound being at least at an effective level. These cationic quaternary ammonium monoalkyl compounds useful in the present invention are preferably quaternary ammonium salts of the general formula:
[R "N + (R5) 3] A- where ^^ R4 is an alkyl or alkenyl group of 8 to 22
carbon atoms, preferably alkyl or alkenyl group of 10 to 18 carbon atoms; more preferable alkyl or alkenyl group of 10 to 14 carbon atoms or 16 to 18 carbon atoms; Each R5 is an alkyl or substituted alkyl group
1 to 6 carbon atoms (eg, hydroxy alkyl), preferably alkyl group of 1 to 3 carbon atoms, for example, methyl (most preferred), ethyl, propyl and the like, a benzyl group, hydrogen , a polyethoxylated chain with about 2 to 20 oxyethylene units,
preferably about 2.5 to 13 oxyethylene units, more
^ P 'preferable about 3 to 10 oxyethylene units, and mixtures thereof; and A "is as defined above (Formula
(D) • Especially preferred dispersibility aids are the monolauryl trimethyl ammonium chloride and the monosebo trimethyl ammonium chloride available from Witco under the tradename Varisoft® 471 and monooleyl trimethyl ammonium chloride available from Witco under the trade name Varisoft® 417 .
The R4 group may also be attached to the cationic nitrogen atom through a group containing one, or more, ester, amide, ether, amine, ^ c linker groups. , which may be desirable to increase the concentration of component (I), etc. These linker groups are preferably within one to three carbon atoms of the nitrogen atom. The quaternary cationic monoalkyl compounds also include the alkyl choline esters of from 8 to 22 carbon atoms. Preferred dispersibility aids of this type have the formula:
RXC (O) -o-CH2CH2N + (R) 3 A "
where R1, R and A "are as defined
^ D previously. Highly preferred dispersibility aids include coconut ester choline of 12 to 14 carbon atoms and tallow ester choline of 16 to 18 carbon atoms. Suitable long-chain, biodegradable, long-chain alkyl dispersion aids containing an ester linkage in the long chains are described in US Pat. No. 4,840,738, Hardy and Walley,
issued on June 20, 1989, said patent is incorporated herein by reference. When the dispersibility aids contain alkyl choline esters, preferably the compositions also contain a small amount, preferably of
2% to 5% by weight of the organic acid composition. Organic acids are described in European patent application 404,471, de Machín and co-inventors, published on December 27, 1990, supra, which is incorporated herein by reference. Preferably the organic acid is selected from the group consisting of glycrylic acid, acetic acid, citric acid, and mixtures thereof. The ethoxylated quaternary ammonium compounds which can serve as the dispersibility aid include ethylbis (polyethoxyethanol) alkylammonium ethyl sulfate with 17 moles of ethylene oxide, available under the tradename Variquat® 66 in Sherex
Chemical Company; polyethylene glycol (15) oleammonium chloride, available under the tradename Ethoquad® 0/25 from Akzo, and the polyethylene glycol (15) cocomonium chloride, available under the trade name Ethoquad®
C / 25 of Akzo. The long single chain materials correspond to the softening active ingredients discussed
previously, where only one R1 group is present in the molecule. The group Rl or the group YR1, is usually replaced by a group R. ™ Although the main function of the auxiliary "
of dispersibility is to increase the dispersibility of the ester softener, preferably the dispersibility aids of the present invention also have some softening properties to boost the softening performance of the composition. Accordingly, preferably the compositions of the present invention are essentially free of non-nitrogenated ethoxylated nonionic dispersion aids, which will reduce the overall softening performance of the compositions. _ ^
Also, the quaternary compounds that have
a long simple alkyl chain, can protect the
The cationic softener is to interact with ammonium surfactants and / or detergency builders which are transported to the rinse from the wash solution. It is highly desirable to have enough compound
long single chain quaternary, or cationic polymer to match the anionic surfactant. This provides improved wrinkle control. The ratio of fabric softener active ingredient to simple long chain compound is typically from about 100: 1 to 2: 1,
preferably from about 50: 1 to 5: 1, more preferably from about 13: 1 to 8: 1. Under high detergent carryover conditions, the ratio is preferably around 5: 1 to 7: 1. Typically the single long chain compound is present at a level of about 10 ppm to 25 ppm in the rinse.
(2) AMINO OXIDES
fljr Suitable amine oxides include those with an alkyl or hydroxyalkyl portion of about 8 to 22 carbon atoms, preferably about 10 to 18 carbon atoms, more preferably about 8 to 14 carbon atoms, and two alkyl portions selected from
group consisting of alkyl groups and hydroxyalkyl groups
"with about 1 to 3 carbon atoms, examples include dimethyloctylamine oxide", diethyldecylamine oxide, bis (2-hydroxyethyl) dodecylamine oxide, methylethylhexadecylamine oxide,
dimethyl-hydroxyoctadecylamine, and coconut dimethylamine fatty acid oxide.
(D) STABILIZERS
The stabilizers may be present in the compositions of the present invention. The term
"Stabilizer" as used here, includes agents
^ Intioxidants and reductives. These agents are present
at a level of about 0% to 2%, preferably about 0.01% to 0.2%, more preferably about 0.035% to 0.1% for antioxidants, and preferably, about 0.01% at
0. 2% for reductive agents. This ensures good odor stability under storage conditions at 0 ° long term.Antioxidant stabilizers and reductive agents are especially critical for products without fragrance or low fragrance (without perfume or with little perfume) Examples of antioxidants that can be added 5 to the compositions of this invention, include a mixture
^ PXe ascorbic acid, ascorbic palmitate, propyl gallate, available from Eastman Chemical Products, Inc., under the trade names Tenox®PG and Tenox®S-1; a mixture of BHT
(Butylated hydroxytoluene), BHA (butylated hydroxyanisole), 0-propyl gallate, and citric acid, available from Eastman
Chemical Products Inc., under the trade name Tenox®6, butylated hydroxytoluene, available from UOP Process Division under the trademark Sustane® BHT; tertiary butylhydroquinone, Eastman Chemical Products, Inc., as Tenox®
TBHQ; natural tocopherols, Eastman Chemical Products, Inc., as Tenox® GT-1 / GT-2; and butylated hydroanisole, Eastman Chemical Products, Inc., as BHA; long chain esters
Ftle 8 to 22 carbon atoms of gallic acid, for example,
dodecyl gallate; Irganox®1035; Irganox® B 1171; Irganox®1425; Irganox®B 3114, - Irganox®B 3125and mixtures thereof, preferably Irganox® B 3125; Irganox®B 1425; IrganoxßB 3114; and mixtures thereof; more preferable Irganox®B 3125 alone or mixed with citric acid and / or other chelators such as isopropyl l-B-hydrocitrate, Deqest®2010, available from Monsanto _ with a chemical name of 1-hydroxyethylidene-1, 1- diphosphnadic acid (ethyl acid). rónico), and Tiro®, available at Kodak with a chemical name of 4,5-dihydroxy-m-benzene-sulfadic acid / sodium salt and DTPA®, available from
Aldrich with a chemical name of ^ ^ diethylenetriaminpentaacetic acid.
(E) MUGRE'S ELIMINATING AGENT
In the present invention, an optional grime remover may be added. The addition of the soil release agent can occur in combination with the premix, in combination with the acid / water seat, before or after the addition of electrolyte, or after
that the final composition is elaborated. The softening composition prepared by the process of the present invention may contain from 0% to about 10%,
™ 'preferably from 0.2% to about 5% of a soil removing agent. Preferably, this grime remover is a polymer. The grime removal agents useful in the present invention include copolymer blocks of terephthalate and polyethylene oxide or polypropylene oxide, and the like. fl,) A preferred soil removal agent is a copolymer having blocks of terephthalate and polyethylene oxide. More specifically, these polymers are composed of repeating units of ethylene terephthalate terephthalate of polyethylene oxide in a molar ratio.
units of ethylene terephthalate to fljl terephthalate oxide units. polyethylene from about 25:75 to 35:65, said e.thylene oxide terephthalate contains polyethylene oxide blocks having molecular weights of about 300 to 2000. The molecular weight of this agent
grime remover is on the scale of about 5,000 to 55,000. Another preferred grime remover is a crystallizable polyester with repeated units of ethylene terephthalate units containing from about 10% a
about 25% by weight of the ethylene terephthalate units together with from about 10% to 50% by weight units of polyethylene oxide terephthalate, derivatives
^ a polyethylene glycol of approximate average molecular weight
from 300 to 6,000, and the molar ratio of ethylene terephthalate units to polyoxyethylene terephthalate units in the crystallizable polymer compound is between 2: 1 and 6: 1. Examples of this polymer include the commercially available materials Zelcon 4780® (from lOWDupont) and Milease T® (from ICI). The most preferred filtering agents are polymers of the generic formula:
O O O O 15 X- (OCH2CH2) p (0-C-R14-C-OR15) u (0-C-R4-OC-0) (CH2-CH20-) n-X
In which each X can be an appropriate crown group, with each X typically being selected from the group consisting of H, alkyl or acyl groups containing from about 1 to 4 carbon atoms, p is selected for its solubility in water and generally it is about 6 to 112, preferably about 20 to 50. U is critical for the formulation in a liquid composition having a relatively high ionic strength. There will be very few materials
in which u is greater than 10. Furthermore, there must be at least 20%, preferably at least 40%, of material in which u reaches about 3 to 5. ^ 'The portions R14 are essentially portions 1,4- 5 pentylene. As used herein, the term "the R14 portions are essentially portions 1, 4 -pentylene" refers to the compounds where the R14 portions consist entirely of 1, 4-pentylene portions, or are substituted-Partially with other arylene portions or alkarylene, alkenyl portions, alkenylene portions, or mixtures thereof. The arylene and alkarylene portions which may be partially substituted by 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphne-ylene, 1,4-naphthylene, 2,2-biphenylene, 4, 4-biphenylene, 4, 4-biphenylene, and mixtures thereof
same. The alkylene and alkenylene portions which may be partially substituted include 1,3-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexamethylene, 1,7-heptamethylene, 1,8-octamethylene, , 4-cyclohexene and mixtures thereof. For the R14 portions, the degree of partial substitution with portions other than 1,4-phenylene should be such that the dirt removal properties of the compound are not adversely affected to any great extent. Generally the degree of partial substitution that
can be tolerated depends on the length of the main structure of the composite, that is, longer main structures may have larger partial replacements for the 1, 4-phenylene portions, usually the compounds, where the R14 contains around from 50% to 100% of 1, 4-phenylene portions (from 0% to about 50% of portions other than 1,4-phenylene) have a suitable grime removal activity, for example, polyesters made in accordance with The present invention with a ratio of lIPJ 'moles of 40:60 of isophthalic acid (1,3-phenylene) to terephthalic acid (1,4-phenylene) have a suitable grime removal activity. Most polyesters used in the manufacture of fibers contain units of ethylene terephthalate, usually desirable
minimize the degree of partial substitution with portions
WV other than 1, 4-phenylene for better grime removal activity. Preferably, the portions R14 consist entirely (i.e., contain 100%) in 1,4-phenylene portions, that is, each R 14 portion is 1,4-20 phenylene. For the R15 portions, the appropriate ethylene or substituted ethylene portions include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy-1, 2-propylene, and mixtures thereof. Preferably, the
R15 portions are essentially ethylene portions, portions
1, 2 -propylene, or mixtures thereof. The inclusion of a higher percentage of ethylene portions tends to improve the.
^ Elimination activity of dirt from the compounds ._
Surprisingly, the inclusion of a higher percentage of 1,2-propylene portions tends to improve the water solubility of the compounds. Accordingly, the use of 1,2-polypropylene portions or a similar branched equivalent is pJ! desirable for the incorporation of any substantial part of the soil removal component in liquid fabric softening compositions. Preferably, about 75% to 100% are 1, 2- ropylene portions. The value for each p is at least about 6, and
preferably at least about 10. The value for each n ^ usually reaches about 12 to 113. Typically, the value for each p is in the range of about 12 to 43. A more complete discussion of soil removal agents is contained in US Patents 4,661,267, of
Decker, Konig, Straathof, and Gosselink, issued on April 28, 1987; 4,711,730, Gosselink and Diehl, issued December 8, 1987; 4,749,596 to Evans, Huntington, Stewart, Wolf, and Zimmerer, issued June 7, 1988; 4,818,569, by Trinh, Gosselink and Rattinger, issued on 4
April 1989; 4,877, 896, by Maldonado, Trinh and Gosselink, issued on October 31, 1989; 4, g56,447, Gosselink and co-inventors, issued September 11, ig90; and 4,976,879, Maldonado, Trinh and Gosselink, issued December 11, 1990, all of these patents incorporated herein by reference. These grime removal agents can also act as foam dispersants.
or (F) FOAM DISPERSANT
In the present invention, the premix can be combined with an optional foam dispersant, other than the grime removal agent, and heated to a temperature up to or above the melting point (s) of the
^ components. The preferred foam dispersants herein are formed by highly ethoxylating hydrophobic materials. The hydrophobic material may be a fatty alcohol, fatty acid, fatty amine, fatty acid amide, amine oxide, quaternary ammonium compound, or the hydrophobic portions used to form grime-eliminating polymers. Preferred foam dispersants are highly ethoxylated, for example, close to more than 17, preferably around
of more than 25, more preferable near more than 40, moles of ethylene oxide per molecule above average, with the ethylene oxide portion of about 76% to 97%,
^ preferably about 81% to 94%, of molecular weight
total. The level of foam dispersant is sufficient to maintain the foam at an acceptable level, preferably not noticeable, for the consumer, under the conditions of use, but not sufficient to affect. 0 ~ adversely the softness. For some purposes it is desirable that the foam be non-existent. Depending on the amount of anionic or non-ionic detergent, etc., used in the wash cycle of a typical washing procedure, the efficiency of the rinse steps prior to the introduction of the compositions herein, and the hardness of the Water,"
The amount of anionic or nonionic detergent surfactant and builder (especially phosphates and zeolites) trapped in the fabric (wash) will vary. Normally, the minimum amount of foam dispersant 0 requires at least about 2%, preferably at least about 4% (at least 6% and preferably at least 10% for maximum foam voiding) based on the level of active ingredient softener However, at levels of about 10% (relative to the softening material) or more,
the loss of product softening efficiency is jeopardized especially when the fabrics contain high proportions of nonionic surfactant which has been absorbed during the washing operation. 5 The preferred foam dispersants are: Brij
700®; Varonic U-250®; Genapol T-500®, Genapol T-800®; Plurafac A-79®; and Neodol 25-50®.
(G) BACTERICIDES? Examples of bactericides used in the compositions of this invention include glutaraldehyde, formaldehyde, 2-bromo-2-nitropropane-1, 3-diol sold by
Inolex Chemicals, located in Philadelphia, Pennsylvania,
under the tradename Bronopol®, and a mixture of 5- ™ chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazoline-3-one sold by Rohm and Haas Company under the name Kathon commercially from about 1 to 1,000 ppm by weight of the agent. 20 (H) PERFUME
The present invention may contain any perfume compatible with the softener. The perfumes
appropriate are discussed in the US patent. 5,500,138, by Bacon and co-inventors, issued on March 19, 196, said patent incorporated herein by reference. ^ ^ As used herein, the perfume includes
fragrant substance or mixture of substances including natural odoriferous substances (ie obtained by extraction of flowers, herbs, leaves, roots, bark, wood, shoots or plants), artificial (ie, a mixture of different natural oils or lßPr constituents of oils) and synthetic (that is, produced synthetically). These materials are often accompanied by auxiliary materials, such as fixatives, extenders, stabilizers and solvents. These auxiliaries are also included within the meaning of
"perfume" as used herein. Typically,
^ P perfumes are complex mixtures of a variety of organic compounds. Examples of perfume ingredients useful in the perfumes of the compositions of the present invention
include, but are not limited to, hexyl cinnamic aldehyde, amyl cinnamic aldehyde; amyl salicylate; hexyl salicylate; terpineol; 3, 7-dimethyl-cis-2, 6-octadien-1-ol; 2,6-dimethyl-2-octanol; 2,6-dimethyl-7-octen-2-ol; 3, 7-dimethyl-3-octanol; 3, 7-dimethyl-trans-2, 6-octadien-l-
ol; 3, 7-dimethyl-6-octen-1-ol; 3, 7-dimethyl-l-octanol; 2- methyl-3- (para-tert-butylphenyl) -propionaldehyde; 4- (4-hydroxy-4-methylphenyl) -3-cyclohexene-1-carboxaldehyde; ^^ tricyclodecenyl propionate; Tricialodecenyl acetate;
anisaldehyde; 2-methyl-2- (para-iso-propylphenyl) -propionaldehyde; ethyl 3-methyl-3-phenyl glycidate; 4- (para-hydroxyphenyl) -butan-2-one; 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -2-buten-1-one; para-methoxyacetophenone; para-methoxy-alpha-phenylpropene; methyl-2-n-lJβ-hexyl-3-oxo-cyclopentane carboxylate; gamma undecalactone. Additional examples of fragrance materials include, but are not limited to, orange oil, lemon oil, grapefruit oil, bergamot oil, clove oil, gamma dodecalactone.; methyl-2- (2- 15 pentyl-3-oxo-cyclopentyl) acetate; Beta-naphthyl methyl ether; methyl- ^ P 'beta-naphthyl ketone; coumarin; decylaldehyde; benzylaldehyde, - 4-tert-butylcyclohexenyl acetate, - alpha, alpha-dimethylphenethyl acetate; methylphenylcarbinyl acetate; Schiff base of 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-20 carboxyaldehyde; and methyl-antranilate; ethylene glycol cyclic diester of tridecanic acid; 3,7-dimethyl-2,6-octadiene-1-nitrile; methyl gamma fonona; alpha ionone; beta ionone; petitgrain; methylredrilone; 7-Acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene;
methyl ionone; methylene-1, 6, 10 -trimethyl-2, 5, 9-cyclododecatrien-1-yl ketone; 7-acetyl-l, 1, 3, 4, 4, 6-hexamethyl tetralin; 4- acetyl-6-tert-butyl-l, 1-dimethyl indane; benzophenone; 6-cycloethyl-1, 1, 2, 3, 3, 5-hexamethyl indan; 5-acetyl-3-isopropyl-1, 1, 2, 6-tetramethyl indan; 1-dodecanal; 7-hydroxy-3,7-dimethyl octanal; 10-undecen-l-al; iso-hexenyl cyclohexyl carboxaldehyde; formyl tricyclodecan, cyclopentadecanolide; 16-hydroxy-9-hexadecenic acid lactone; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-0 ™ tenzopyran; ambroxane; dodecahydro-3a-6, 6, 9a-tetramethylnaphtho- [2, lb] furan; cedrol; 5- (2,2,3-trimethylcyclopent-3-enyl) -3-methylpentan-2-ol; 2-ethyl-4- 2, 2, 3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol; caryophyllenyl alcohol, - cedrile acetate; para-tert-5 butylcyclohexyl acetate; patchouli; resignide olíbano; Laburnum
^ P vetivert; balsam of copaiba; fir balsam; and condensation products of: hydroxy citronellal and methyl anthranilate; hydroxy-citronellal and indole; phenyl acetaldehyde and indole; 4- (4-hydroxy-4-methyl pentyl) '- 3-cyclohexene-1-carboxyaldehyde and methyl anthranilate. More examples of perfume components are geraniol; geranyl acetate; linalool; linalyl acetate; tetrahydrolinalool; citronellol; citronellyl acetate; dihydromyrcenol; Dihydromyrcenyl acetate;
tetrahydromyrcenol; torpinyl acetate; nopol; nopyl acetate; 2-phenylethanol; 2-phenylethyl acetate; benzyl alcohol; benzyl acetate; benzyl salicylate;
^ benzyl benzoate; strirallyl acetate;
-dimethylbenzylcarbinol; trichloromethylphenylcarbinyl methylphenylcarbinyl acetate; isononyl acetate; vetiveril acetate; vetiverol; 2-methyl-3- (p-tert-butylphenyl) -propanal; 2-methyl-3- (p-isopropylphenyl) -propanal; 3- (p-tert-butylphenyl) -propanal; 4- (4-methyl-3-pentenyl) -3- IßO 'cyclohexenecarbaldehyde; 4-acetoxy-3-pentyl-ehydrohydroran; methyl dihydrojasmonate; 2-n-heptylocyclopentanone; 3- methyl-2-pentyl-cyclopentanone; n-decanal; n-dodecanal; 9- decenol-1; phenoxyethyl isobutyrate; phenylacetaldehyde dimethylacetal; phenylacetaldehyde diethylacetal;
geranonitrile; citronelonitrile; acetal cedril; 3- isocamfilcyclohexanol; cedrylic methylether; isolongifolanone; aubepino nitrile; aubepino; heliotropin; eugenol; vanillin; diphenyl oxide; hydroxy ionone ionones; methyl ionones; isomethyl ionones; irons; cis-3- 20 hexenol and esters thereof, indane moss fragrances; fragrances of tetralin moss; moss isocroman fragrances; macrocyclic ketones; fragrances of macrolactone moss; ethylene brasilate.
The perfumes useful in the compositions of the present invention are substantially free of halogenated and nitromusked materials. ^^ Appropriate solvents, diluents or carriers
For the perfume ingredients mentioned above are as examples, ethanol, isopropanol, diethylene glycol, monoethyl ether, dipropylene glycol, diethyl phthalate, triethyl citrate, etc. The amount of these solvents, diluents or carriers incorporated in perfumes lfljr is preferably kept to the minimum necessary to provide a homogeneous perfume solution. The perfume may be present at a level of from about 0% to 15%, preferably about 0.1% to 8%, and more preferably from about 0.2% to 5% by weight of the
finished composition. The softening compositions of
• W fabric of the present invention provide improved perfume deposition in the fabric.
(I) CHELATING AGENTS 20 The compositions and methods herein may occasionally employ one or more chelating agents ("chelators") of copper or nickel. These water-soluble chelating agents can be selected from the
group consisting of amine carboxylates, amino phosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, as defined below. The whiteness and / or gloss of the fabrics 5 are substantially improved or restored by these chelating agents and the stability of the materials in the compositions is improved. Amine carboxylates useful as chelating agents herein include those
^ l ethylenediaminetetraacetates (EDTA), N-hydroxyethylenediaminetriacetates, nitrilotriacetates
(NTA), ethylenediamine tetrapropionates, NN'-ethylenediamine diglutamates, N, N'-2-hydroxypropylenediamine disuccinates, triethylenetetramine hexaacetates,
diethylenetriaminepentaacetates (DTPA), and ethanediglycine,
^ 'including its water soluble salts such as the alkali metal, ammonium and substituted ammonium salts and mixtures thereof. The amino phosphonates are also suitable for use as chelating agents in the compositions of the invention when at least low levels of total phosphorus are allowed in the detergent compositions, and include ethylenediaminetetrakis (methylenephosphonates), diethylenetriamine-N, N, N ', N ", N" -pentakis (methane-phosphonate) (DETMP) and 1-hydroxyethane-1, 1-diphosphonate (HEDP).
Preferably, these amino phosphathates do not contain alkyl or alkenyl groups with more than 6 carbon atoms. Chelating agents are typically used in ^ * the current rinse procedure at approximate levels of 2 ppm to 25 ppm, for periods of 1 minute to several hours of soaking. The preferred EDDS chelator used in this
(also known as N-N'-ethylenediamine disuccinate) is the material described in US Pat. No. 4,704,233, cited hereinabove, and has the formula (shown in free acid form):
HN (L) C2H4N (L) H
wherein L is a group CH2 (COOH) CH2_ (COOH). ^ P ^ As described in the patent, EDDS can be prepared using maleic anhydride and ethylenediamine. The preferred biodegradable [S, S] isomer of EDDS can be prepared by reacting L-aspartic acid with 1,2-20 dibromoethane. EDDS has advantages over other chelators in that it is effective for chelating copper and nickel cations, is available in biodegradable form, and does not contain phosphorus. The EDDS used herein as a chelator is typically in its salt form, ie in
where one or more of the four acidic hydrogens is replaced by a water-soluble M cation, such as sodium, potassium, ammonium, trimethylammonium and the like. How it was made
^ 'Notice above, the EDDS chelator is also used
typically in the present rinse process at approximate levels of 2 ppm to 25 ppm for periods from 1 minute to several hours of soaking. At certain pH the EDDS are preferably used with zinc cations. A wide variety of chelators can be used in the present. Undoubtedly, simple polycarboxylates, such as citrate, oxydisuccinate, and the like, can also be used, although these chelators are not as effective as amino carboxylates and phosphonates, on a weight basis. According to this, the levels of use
can be adjusted to take the grades into account
^ V different chelating effectiveness. Chelators of the present preferably will have a constant stability (of the fully ionized chelator) for copper ions of at least about 5, preferably at
At least about 7. Typically, chelators will contain about 0.5% to 10%, more preferably about 0.75% to 5%, by weight of the compositions herein, in addition to those which are stabilizers. The
Preferred chelators include DEMTP, DETPA, NTA, EDDS and mixtures thereof.
(J) CATIÓNIC POLYMERS 5 The compositions herein may contain from about 0.001% to 10%, preferably about 0.01% to 5%, more preferably from about 0.1% to 2%, of catidic polymer, which typically has a weight molecular lfl, * about 500 to 1,000,000, preferably about 1,000 to 500,000, more preferable about 1,000 to 250,000, and even more preferable about 2,000 to 100,000, and a charge density of at least about 0.01 meq / gm. , preferably from about 0.1 to 8 meq / gm, more preferable
from about 0.5 to 7, and even more preferable from about 2 to 6.
In order to provide the benefits of the cationic polymers, and especially the cationic polymers containing amine, or imine groups, said cationic polymer is preferably primarily in the aqueous phase
continues. The cationic polymers of the present invention can be amine salts or quaternary ammonium salts. Preferred are quaternary ammonium salts. These include catidnic derivatives of natural polymers such as
some polysaccharides, gums, starch and certain synthetic catidnic polymers such as polymers and copolymers of cationic vinylpyridine or vinylpyridinium halides.
^^ Preferably the polymers are soluble in water, per instance up to the extent of at least 0.5% by weight at 20 ° C. Preferably they have molecular weights of from about 600 to 1,000,000, more preferable from 600 to 500,000, still more preferable from 800 to 300,000, and especially from about 1,000 to 10,000. As a rule
J ^ ß general, the lower the molecular weight, the higher the degree of substitution (DS) by catidnical groups, usually quaternary, which is desirable, or correspondingly, the lower the degree of substitution, the higher the weight desirable molecular, but
There does not seem to be a precise relationship. In general,
The cationic polymers should have a charge density of at least about 0.01 meq / gm, preferably from about 0.1 to 8 meq / gm, more preferably from about 0.5 to 7, and even more preferably from about 2 to 6. 20 The appropriate desirable cationic polymers are described in the Ingredients Dictionary "CTFA International Cosmetics, Fourth Edition, JM Nikitakis and coinventores, editors, published by the Cosmetics, Toiletries and Fragrances Association, 19gi,
incorporated here as a reference. The list includes the following: Polysaccharide gums, guar gum and bean grasshoppers, which are galactomanam gums
available in the trade, and are preferred. Thus Guar gums are marketed under the trade names CSAA M / 200, CSA 200/500 by Meyhal and Stein-Hall, and hydroxyalkylated guar gums are available from the same suppliers. Other polysaccharide gums available in the trade include: Xantan gum, Ghatti gum, tamarind gum, gum arabic, and agar, cationic guar gums and methods for making them are discussed in British Patent 1,136,842 and US Patent 4,031,307. have a 5 SD from 0.1 to about 0.5. J An effective cationic guar gum is the Jaguar C-13S (Trade name Meyhall) Cationic guar gums are a highly preferred group of cationic polymers in the compositions according to with the invention and act as scavengers for residual anionic surfactants and also enhance the softening effect of cationic textile softeners even when used in restrooms containing little or no residual anionic surfactant The other polysaccharide based rubbers can
be quaternized similarly and act sustantially in the same way with variations of degrees of effectiveness.
The appropriate starches and derivatives are starches
'natural as those obtained from corn, wheat, barley, etc., and
of roots such as potatoes, tapioca, etc., and dextrins, particularly pyrodextrins such as British gum and white dextrin. Some very effective individual cationic polymers are the following: polyvinyl pyridine, weight 0 * ßrmolecular about 40,000, with about 60% of the quaternized pyridine nitrogens available; the copolymer of molar proportions 70/30 of vinyl pyridine / styrene, approximate molecular weight of 43,000, with about 45% of the quaternized pyridine nitrogens 5 available as above; the copolymers of
™ ^ 77/23 and 57/43 molar proportions of vinyl priridine / methyl methylacrylate, molecular weight of about 43,000, with about 97% of the quaternized pyridine nitrogens available as above. 0 Cationic polymers are effective in compositions at very low concentrations per instance of 0.001% by weight to 0.2% especially from 0.02% to 0.1%. In some instances the effectiveness seems to fail.
when the content exceeds some optimum level, as for polyvinylpyridine and its styrene copolymer about 0.5%. Some other effective cationic polymers are:
'' The vinyl pyridine copolymer and the N-vinyl pyrrolidone
(63/37) with about 40% of the quaternized pyridine nitrogens available; the copolymer of vinyl pyridine and acrylonitrile (60/40), quaternized as above; the copolymer of N, N-dimethylamino ethyl methacrylate and styrene
(55/45) quaternized as previously in about 75% of the available amino nitrogens. The Eudragit E (Trade name of Rohm GmbH) quaternized as previously in about 75% of the available amino nitrogens. It is believed that Eudragit E is a copolymer of N, N-dialkyl amine alkyl methacrylate and a neutral acrylic acid ester, and has
molecular weight of around 100,000 to 1,000,000; he ? copolymer of N-vinyl pyrrolidone and N, N-diethyl amino methyl methacrylate (40/50), quaternized in about 50% of available amino nitrogens. These cationic polymers can be prepared in a known manner
quaternizing the basic polymers. Still other cationic polymer salts are the quaternized polyethylene imines. These have at least 10 repeated units, some of which are quaternized. Commercial examples of polymers of this class are also
sold under the generic trade name 'lcostat by
Allied Colloids. Typical examples of polymers are discussed in US Pat. No. 4,179,382, incorporated herein by reference. Each polyamine nitrogen, provided it is primary, secondary or tertiary, is defined below as a member of one of three general classes: simple substituted, quaternized or oxidized. The polymers are made neutral by soluble anions such as chlorine (Cl "), bromine (Br"), iodine (I ") or any other negatively charged radical such as sulfate (S042") and methosulfate (CH3SO3"). Polyamine-specific major materials are described in U.S. Patent 2,182,306, Ulrich Flj 'and co-Inventors, issued December 5, 1939;
US 3,033,746, Mayle and co-inventors, issued May 8, 1962; US Patent 2,208,095, to Esselmann and co-inventors, issued July 16, 1940; US Patent 2,806,839, of 20 Crowther, issued September 17, 1957, and the patent
US 2,553,696, Wilson, issued May 21, 1951; all incorporated here as reference.
Examples of modified polyamine cationic polymers of the present invention comprising PEI are illustrated in formulas I-II: "Formula I reviews a cationic polymer containing a PEI backbone where all substitutable nitrogens are modified by hydrogen replacement with a polyoxyalkylenoxy unit, - (CH2CH2O) 7H, which has the formula
FORMULA I
This is an example of a cationic polyamine polymer that is completely modified by a type of portion. Formula II delineates a cationic polyamine polymer comprising a PEI backbone where all substitutable primary amine nitrogens are modified by replacing hydrogen with a unit
polyoxyalkyleneoxy, - (CH2CH20) 7H, the molecule is then modified by subsequent oxidation l all oxidizable primary and secondary nitrogens to N-oxides, "said cationic polyamine polymer has the formula:
FORMULA II
Another polyamine cationic polymer comprises a PEI backbone wherein all of the hydrogen atoms in the backbone are substituted and some amine units in the backbone are quaternized. The substituents are polyoxyalkyleneoxy units - (CH 2 CH 20) 7 H, or methyl groups. Yet another related polyamine cationic polymer comprises a PEI backbone where the nitrogens of the backbone are modified by substitution (ie
say by - (CH2CH20) 7H, or methyl), quaternized, oxidized to N-oxides or combinations thereof. Naturally, mixtures of any of the cationic polymers described above can be
employees, and the selection of individual polymers or particular mixtures can be used to control the physical properties of the compositions such as their viscosity and the stability of the aqueous dispersions. In order to be more effective, the cationic ifl polymers herein must be, at least at the level discussed herein, in the continuous aqueous phase. To ensure that the polymers are in the continuous aqueous phase, they are preferably added at the end of the process for making the compositions. The active ingredients
fabric softeners are normally present in the formula
"ß of vesicles After the vesicles have formed, and while the temperature is lower than about 29 ° C, the polymers are added.
(K) OTHER OPTIONAL INGREDIENTS
SILICONES
The silicone herein can be a polydimethyl siloxane (polydimethyl silicon or PDMS), or a derivative thereof, for example, aminosilicones, ethoxylated silicones, etc. The PDMS, preferably is one with a low molecular weight, for example, one having a viscosity
V 'is about 2 to 5000 cSt, preferably about 5 to 500 cSt, more preferable about 25 to 200 cSt. Silicone emulsions can be conveniently used to prepare the compositions of the present invention. However, preferably, the silicone is such that it is, at
less initially, not emulsified. That is, the silicon
* V must be emulsified in the composition itself. In the process of preparing the compositions, the silicone is preferably added to the "water seat", which comprises the water and, optionally, any other
ingredients that normally remain in the aqueous phase. The low molecular weight PDMS is preferred for use in the fabric softening compositions of this invention. The lower the molecular weight of the PDMS, the easier it is to formulate without pre-emulsification.
Silicone derivatives such as aminofunctional silicones, quaternized silicones and silicone derivatives, which contain Si-OH, Si-H, and / or Si-Cl bonds,
"ß * can be used, however, these silicone derivatives
are usually more substantive for the fabrics and can be intensified on the fabrics after repeated treatments to cause a true reduction in the absorbency of the fabric. When added to the water, the cloth softener composition deposits the biodegradable cationic fabric softening active ingredient on the surface of the fabric to provide softness effects on the fabric. However, in a typical washing procedure, using an automatic washing machine, the absorbency of
water of the cotton fabric is appreciably reduced fl, l when there is more than about 40 ppm, especially when there is more than 50 ppm, of the biodegradable cationic fabric softener active ingredient in the rinse water. Silicone improves the water absorbency of the fabric, especially for
fabrics treated recently, when used with this level of fabric softener without adversely affecting the fabric's softness performance. The mechanism by which this improvement in water absorbency occurs is not understood, since silicones are inherently
hydrophobic It is very surprising that there is an improvement in water absorbency, rather than additional loss of water absorbency. '' The amount of PDMS needed to provide
a remarkable improvement in water absorbency depends on the initial performance of soapability, which, on the other hand, depends on the type of detergent used in the wash. The effective amounts reach approximately from 2 ppm to 50 ppm in the rinse water, preferably around 1 to 20 ppm. The ratio of PDMS to softening active ingredient is about 2: 100 to 50: 100, preferably about 3: 100 to 35: 100, more preferably about 4: 100 to 25: 100. As noted above, this typically requires about 0.2% to 20%,
preferably about 0.5% to 10%, more preferably about 1% to 5% silicon. The PDMS also improves the ease of ironing as well as improving the soaking characteristics of the fabrics. When the composition for the care of fabrics
contains an optional grime remover polymer, the amount of PDMS deposited on the cotton fabric increases and the PDMS improves the removal benefits of grime on the polyester webs. Also, the PDMS improves the rinsing characteristics of the compositions for
care of fabrics reducing the tendency of the compositions to foam during rinsing. Surprisingly, there is little, if any, reduction in the smoothing characteristics of the compositions for fabric care as a result of the presence of relatively large amounts of PDMS. The present invention may include other optional components conventionally used in textile treatment compositions, for example, dyes, preservatives, surfactants, anti-shrinking agents, fabric crispers, locating agents, germicides, fungicides, antioxidants such as proteases, cellulases, amylases, lipases, etc., and the like. The particularly preferred ingredients
include water-soluble calcium or magnesium compounds,
'J' that provide additional stability. Chloride salts are preferred, but salts of acetate, nitrate, etc. can be used. The level of said calcium and / or magnesium salts is from 0% to about 2%, preferably around
from 0.05% to 0.5%, more preferable from about 0.1% to 0.25%. The present invention may also include other compatible ingredients, including those described in the pending applications with serial numbers: 08 / 372,068, filed on January 12, 1995, by Rusche et al.
co-inventors; 08 / 372,490, filed on January 12, 19g5, by Shaw and co-inventors, and 08 / 277,558, filed on July 1, 1994, by Hartman and co-inventors, incorporated into the
'' present as a reference. Many synthesis methods can be used to prepare the main solvents of this invention. Appropriate methods are described in the pending application mentioned above, but are not considered to be limiting. All parts, percentages, proportions and reasons herein are by weight unless otherwise specified and all numerical values are approximations based on normal confidence limits. All the documents cited are, in their relevant part,
incorporated herein by reference. flj 'The following non-limiting examples show transparent or translucent products with acceptable viscosities. The compositions in the following examples are
made by first preparing a seat _ of oil of active ingredient softener at room temperature. The softening active ingredient may be heated, if necessary, to melt if the softening active ingredient is not fluid at room temperature. The ingredient
Active softener is mixed using a 1KA RW 25® mixer for about 2 to 5 minutes at about 150 rpm. Separately, an acid / water seat is prepared by mixing the HCl with deionized water (DI) at room temperature. If the active softener and / or main solvent (s) are not fluid at room temperature and need to be heated, the acid / water seat must also be heated to an appropriate temperature, for example, around of 38 ° C and maintaining ío'jdicha temperature with a bain-marie. The main solvent (s) (melted at appropriate temperatures if their melting points are higher than room temperature) are added to the softening premix and said premix is mixed for about 5 minutes. He
acid / water seat is then added to the premix
Smoothing and mixing for about 20 to 30 minutes or until the composition is clear and homogeneous. The composition is allowed to cool to room temperature. The following are fabric softening active ingredients (FSA) of NjN-di (acyl-fatty acid) -N, -dimethyl ammonium chloride with approximate distributions of given fatty acyl groups, which are used in the following to prepare the following compositions .
The following are fabric softening active ingredients (FSA) which are used hereinafter to prepare the following compositions. '' FSA1: Dioleldimethylammonium chloride 5 FSA2 -. Di (canola) dimethylammonium chloride FSA3: Diisostearyldimethylammonium chloride FSA4: l-methyl-l-oleylamidoethyl-2-oleylimidazolinium methylisulfate (eg, Varisoft® 36g?) FSA5: 1-methyl-l- (canola) araidoethyl - io'b-oleylimidazolinium FSA6: l-oleylamido-ethyl-2-oleylimidazoline FSA7: 1- (canola) amidoethyl-2- (canola) imidazoline FSA8: [R? -C (O) -NH-CH2CH2-N (CHs) (CH2CH2OH) -CH2CH2-NH-C (O) -Ri] + CH3S04"wherein Rx-C (0) is an oleyl group (for example Varisoft®222LT) f FSAg: [R8-C (0) -NH -CH2CH2-N (CH3) (CH2CH2OH) -CH2CH2-NH- C (0) -R8] + CH3S04"wherein R8-C (0) is the (calanola) alkyloyl group FSA10:
H3SO4 T
where R1 is derived from oleic acid. FSA11: di (hydrocarbyl) dimethylammonium chloride, where the hydrocarbyl group is derived from a mixture of ^ P "oleic acid (fatty acid of FSA1) and isostearic acid of 5 FSA3 in an approximate weight ratio of 65:35. di (hydrocarbyl) dimethylammonium chloride, where the hydrocarbyl group is derived from a mixture of fatty acid from canola (fatty acid of FSA2) and tallow fatty acid in an approximate weight ratio of 65:35 l FSA13: chloride oleyltrimethylammonium
EXAMPLE I
Component 1 2 3 ^ 4 5 6 2 .1. % weight% weight% weight% weight% weight% weight% weight% weight f FSA1 24 FSA2 26.6 FSA3 26.6 - FSA4 26.6 FSA5 26.6 FSA6 16.6 --- FSA7 16.6.
FSA8, 26.6
FSA13 2.6 1 1
Ethanol 6 6 6 6 6 6 6 6
1,2-hexanodiol 17 17 17 17 17 17 17 17
W HCl (a) (a) (a) (a) (a) (a) (a) (a)
Perfume 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2
Katon 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm
Water DI Rest Rest Rest Rest Rest Rest Rest
(a) until the composition is adjusted to about 3.5-f 4.0 The above examples show transparent products with acceptable viscosities.
EXAMPLE II
Component 1 2 3 4 5 6 7 8% weight% weight% weight% weight% weight% weight% weight% weight
FSAg 26.6 FSA10 26.6 FSA11 26.6 FSA12 26.6 FSA1 FSA1
FSA2 26.6
FSA2 - -.- 26.6
FSA13 2.6 2. 6 1, 2 -hexanediol 17 17 17 17 17 17 17 17
1,2-6,8 2-pentanediol 1,2-octanediol 1 2-ethyl-l, 3- 8-hexanediol
pentanediol HCl (a) (a) (a) (a) (a) (a) (a) (a)
Perfume 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2
Katon 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm 3 ppm
Water DI Rest Rest Rest Rest Rest Rest Rest
(a) Until adjusting the pH of the composition to about 3.5-4.0. The above examples show transparent products with acceptable viscosities.
EXAMPLE III
Component 1 2 3 4 5 6 7 8
5so% weight% weight% weight% weight% weight% weight% weight
FSA1 39.3 14. í FSA1 SA3 26 -i- FSA4 26.6 _ ^ _-_- FSA5 27.5 FSA6 16 FSA7 __26.9 FSA8 45 -
) FSA9 _ 43_.2
FSA13 1 3.9 1.5 3- (pentyloxy) -18 1,2-propanediol 1,2- 18 bis (hydroxymethyl) cydohexane 1,2-hexanediol 10 20 20 20
bis (hydroxymethyl) cyclohexane Hexylene glycol - 6 Ethanol 6 6 4 6 10 4 6 10
Isopropanol 2 4
HCl (a) (a) (a) (a) (a) (a) (a) (a)
Perfume 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2
Katon 3 ppm 3 ppm 3 ppm 3 ppm 5 ppm 5 ppm 5 ppm 5 ppm
Water DI Rest Rest Rest Rest Rest Rest Rest
(a) Until adjusting the pH of the composition to about 3.5-4.0. The above examples show transparent products with acceptable viscosities.
EXAMPLE VIII
SOFTENERS ON A BASE OF 100% ACTIVE INGREDIENTS
Component (% weight) 1 2 3 4
Varisoft-475 26.0 --- --- -
Varisoft-36g? --- 26.0 --- --- Varisoft-222LT --- --- 26.0 - "
Varisoft-222LM --- --- --- 26.0
Isopropanol 2.9 --- 2.9 2.9
1, 2-hexanediol 20.0 20.0 20.0 17.0
HCl (1N) 0.25 0.25 0.25 0.25
Perfume 1.25 1.25 1.25 1.25
Claims (2)
- NOVELTY OF THE INVENTION CLAIMS 1. - A stable, aqueous fabric softening composition containing: A. About 2% to 80% of softener active ingredient selected from the group consisting of: (1) a softener having the formula: R4.m- ^ '- R1 ,, A "where each m is 2 or 3, each R1 is a hydrocarbyl or hydrocarbyl substituent of 6 to 22 carbon atoms, but no more than one is less than 12 carbon atoms and then the other is at least 16, where the Value Iodo is around 70 to 140 with a cis / trans ratio of about 1: 1 to 50: 1, each R is H or a short chain alkyl or hydroxyalkyl group of 1 to 6 carbon atoms, group, benzyl, or (R2O) 0.4H wherein R2 is an alkylene group of 1 to 6 carbon atoms; and A "is a softener-compatible nest; (2) a softener that has the formula wherein each R, R1 and A "have the definitions given above, each R2 is an alkylene group of 1 to 6 carbon atoms, and G is an oxygen atom or a group - '' NR-; (3) a softener which has the formula wherein R1, R2 and G are defined as above; lfljl (4) reaction products of substantially unsaturated and / or branched chain fatty acids with dialkylenetriamines in, for example, a molecular ratio of about 2: 1; (5) a softener having the formula: [R1-C (O) -NR-R-N (R) 2 -R3-NR-C (O) -R1] + A-, where R, R1, R2, R3 and A- are defined as above; (6) the 'J' reaction product of substantially unsaturated and / or branched chain fatty acid with hydroxyalkyl alkylene diamines in a molecular ratio of about 2: 1, said reaction products contain 20 compounds of the formula: R 1 -C (O) -NH-R2-N (R 3 OH) -C (O) -R 1, wherein R 1, R 2 and R 3 are defined as above; (7) A softener that has the formula: wherein R, R, R and A "are defined as above, and (8) mixtures thereof, B. Less than about 40% by weight of the main solvent composition having a ClogP of about 0.15 to 0.64, and at least some degree of symmetry, said main solvent contains insufficient amounts of solvents selected from the group consisting of: 2, 2, 4-trimethyl-1,3-pentanol, the ethoxylated, diethoxylated, or triethoxylated derivatives of 2, 2,4-trimethyl-1,3-pentanediol and / or 2-ethylhexyl-1,3-diol to provide a stable aqueous composition by themselves, said main solvent being sufficient to make the compositions at least translucent; Optionally, but preferably, an effective amount, sufficient to improve the transparency, of water soluble solvents of low molecular weight such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate, etc., said solvents being soluble in water on a level that will not form compositions ransparent by themselves; D. Optionally from 0% to about 15% perfume; E. Optionally, from 0% to about 2% stabilizer; F. Optionally, an amount effective to improve the transparency, of calcium salt and / or magnesium soluble in water, preferably chloride; and G. The rest of water. '^ 2.- The aqueous fabric softening composition, Stable, of claim 1, containing: A. About 13% to 75% of said fabric softening active ingredient (1) further characterized in that each R1 is a hydrocarbyl or substituted hydrocarbyl substituent of 14 to 20 carbon atoms, but no more than one has 12 carbon atoms and then the other is at least about 16, including polyunsaturated alkyl, and where the Iodine Value of a fatty acid containing this group R1 is about 80 to 130 with a cis / trans ratio of about 2-.1 to 40: 1, and each_R1 can also be a group of 16 to 18 carbon atoms 15 of branched chain; each R is H or an alkyl group or * '' short chain hydroxyalkyl of 1 to 3 carbon atoms; benzyl, or group (R2O) 0-4H; and A "is a softener-compatible anion selected from the group consisting of chloride, bromide, methylisulfate, etiisulfate, sulfate and nitrate; 20 about 10% to 35% by weight of the composition of said main solvent having a ClogP of about 0.25 to 0.62; C. Optionally, from about 1% to 10%, and in sufficient quantity to improve the transparency, of water-soluble solvents of low molecular weight selected from the a group consisting of ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate, and mixtures thereof; said solvents being soluble at a level that does not "forms transparent compositions by themselves, D. Optionally from 0% to about 15% perfume, E. Optionally, from 0.01% to about 0.2% stabilizer, F. Optionally, an effective amount to improve transparency, calcium salt and / or magnesium soluble in water, preferably chloride, and G. The remainder of water 3. The aqueous, stable fabric softening composition of claim 1 which contains: A. From 13% to 75 % of said softening active ingredient that has the formula: wherein each R1 is a hydrocarbyl or substituted hydrocarbyl substituent of 14 to 20 carbon atoms, but no more than has 12 carbon atoms and then the other at least about 16, and where the Iodine Value of a fatty acid containing this group R1 is from about 80 to 130 with a cis / trans ratio of from about 2: 1 to 40: 1, more preferably from about 3: 1 to 30: 1, and each R1 also it can be a group of 16 to 18 carbon atoms of branched chain; each R is H or a short chain alkyl or hydroxyalkyl group of 1 to 3 carbon atoms; benzyl, or group 'z (R2O) 0-4H; and A- is an anion compatible with softener 5 selected from the group consisting of chloride, bromide, methylisulfate, etiisulfate, sulfate and nitrate; each R2 is an alkylene group of 1 to 6 carbon atoms; and G is an oxygen atom or a group -NR-; B. From about 12% to 35% by weight of the composition of said main solvent, having ^ P said main solvent a ClogP of about 0.40 to 0.60; C. Optionally, from about 2% to 8%, and sufficient to improve the transparency, of water-soluble solvents of low molecular weight such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, propylene carbonate; D. 15 Optionally from 0.2% to about 5% perfume; AND. Jl Optionally, from 0.035% to about 0.01% stabilizer; F. Optionally, an amount effective to improve the transparency, of calcium salt and / or magnesium soluble in water, preferably chloride; and G. The rest of water. 4. The stable, aqueous fabric softening composition of claim 3, said composition being transparent and containing: A. About 13% to 75% by weight of the composition of said fabric softener; said fabric softening compound has the formula: 5 wherein each R is a hydrocarbyl or substituted hydrocarbyl substituent of 14 to 20 carbon atoms, but not more than one with less than 12 carbon atoms and then the other at least about 16, and where the Iodine Value of an acid fat containing this group R1 is from about 80 to lfl,) 130 with a cis / trans ratio of from about 2: 1 to 40: 1, more preferable about 3: 1 to 30: 1, and each Rl can also be a group of 16 to 18 carbon atoms of branched chain; A "is a softener-compatible anion selected from the group consisting of chloride, bromide, 15 methylisulfate, etiisulfate, sulfate and nitrate; each R2 is a fljl alkylene group of 1 to 6 carbon atoms, - and G is an oxygen atom or a group -NR-; B. From about 14% to 35% by weight of the composition of said main solvent, said main solvent having a ClogP of about .0.40 to 20 0.60; C. Optionally, from about 2% to 8%, and sufficient to improve the transparency, of solvents soluble in water of low molecular weight selected from the group consisting of ethanol, isopropanol, propylene glycol, 1,3-propanediol and propylene carbonate; D. Optionally from 0% to close to 15% perfume; E. Optionally, from 0% to about 2% stabilizer; F. Optionally, an effective amount to improve transparency, calcium salt and / or magnesium 'soluble in water, preferably chloride; and G. The rest of 5 water. 5. The composition of claim 1, further characterized in that said ClogP is close to 0.25 to 0.62. 6. The composition of claim 1 wherein the said main solvent is selected from the group consisting of 2,3-dimethyl-2,3-butanediol; 2, 3-dimethyl-l, 2-butanediol; 3, 3-dimethyl-l, 2-butanediol; 2-methyl-2, 3-butanediol; 3-methyl-2, 3-butanediol; 4-methyl-2,3-butanediol; 2, 3-hexanediol, -3,4-hexanediol; 2- 15-ethyl-1,2-butanediol; 2-methyl-l, 2-pentanediol; 3-methyl-1, 2'-pentanediol; 4-methyl-l, 2-pentanediol; 1,2-hexanediol; and mixtures thereof; 7. - The composition of claim 6 further characterized in that the main solvent is selected from the group consisting of: 2,3-dimethyl-l, 2-butanediol; 3, 3-dimethyl-l, 2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3 pentanediol; 4-methyl-2,3-pentanediol, -2,3-hexanediol; 3, 4-hexanediol; 2-ethyl-l, 2-butanediol; 2-methyl-l, 2-pentanediol; 3-methyl-l, 2- pentanediol; 4-methylene-1,2-pentanediol; 1,2-hexanediol; and mixtures thereof. 8. The composition of claim 7, further characterized in that said main solvent is 5 selected from the group consisting of: 2-ethyl-l, 2-butanediol; 2-methyl-l, 2-pentanediol; 3-methyl-l, 2- pentanediol; 4-methyl-l, 2-pentanediol; and 1,2-hexanediol; and mixtures thereof. 9. The composition of claim 8, characterized in that said main solvent is 1,2-hexanediol. 10. The composition of claim 1 further characterized in that said main solvent is selected from the group consisting of: 2-butyl-l, 3- 15 propanediol; 2, 2-diethyl-l, 3-propanediol; 2- (1-methylpropyl) -V 1, 3-propanediol; 2- (2-methylpropyl) -1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2, 3, 3-trimethyl-1,2-butane-diol; 2- ethyl-2-methyl-l, 4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-l, 4-butanediol; 2-isopropyl-1, -butanediol; 2,2- 20 dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl-1,5-pentanediol; 3, 3-dimethyl-l, 5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4, 4-dimethyl-2,3-pentanediol, 2,3-dimethyl-3,4-pentanediol; 2-ethyl-l, 5-pentanediol; 2-methyl- 1,6-hexanediol; 3-methyl-l, 6-hexanediol; 2-methyl-2,3-hexanediol; 3-methyl -2, 3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3, 4-hexanediol; 3-methyl-3,4- 'i' hexanediol; 1,3-heptane diol; 1,4-heptane diol; 1,5- 5 heptanediol; 1,6-heptanediol; and mixtures thereof. 11. The composition of claim 1 further characterized in that said main solvent is selected from the group consisting of: 2-butyl-l, 3-propanediol 2-propyl-l, 4-butanediol; 2-ethyl-l, 5-lfl pentanediol 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2, 3- pentanediol 3,4-dimethyl-2,3-pentanediol; 4, 4-dimethyl-2, 3-pentanediol 2,3-dimethyl-3,4-pentanediol; 2-methyl-l, 6-hexanediol; 3-methyl-l, 6-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptane diol; 1,6-heptanediol; and mixtures of 15 the same. 12. The composition of claim 11, further characterized in that said main solvent is selected from the group consisting of: 2,3-dimethyl-2, 3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3, 4-dimethyl-2, 3-20 pentanediol; 4, 4-dimethyl-2,3-pentanediol; 2, 3-dimethyl-3, 4-pentanediol, - and mixtures thereof. 13. The composition of claim 1, wherein said main solvent is selected from the group consisting of: 2- (2-methylbutyl) -1,3-propanediol; 2- (1,1- dimethylpropyl) -1,3-propanediol, -2- (1, 2-dimethylpropyl) -1,3-propanediol, -2- (1-ethylpropyl) -1,3-propanediol; 2- (1-methylbutyl) -1,3-propanediol; 2- (2, 2-dimethylpropyl) -1,3- • Wf propanediol; 2- (3-methylbutyl) -1,3-propanediol; 2-butyl-2-5 methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1-, 3-propanediol; 2-methyl-2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-methylpropyl) -1,3-propanediol; 2-butyl-tertiary-2-methyl-1,3-propanediol; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) -1,3-butanediol; 2-butyl-l, 3-f | butanediol; 2-ethyl-2, 3-dimethyl-l, 3-butanediol; 2- (1,1-dimethylethyl) -1,3-butanediol; 2- (2-methylpropyl) -1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol; 3-methyl-2-isopropyl-1,3-butanediol, -3-methyl-2-propyl-1,3-butanediol, -2,2-diethyl-1,4-butanediol; 2-methyl-2-propyl-l, 4-butanediol; 2 (1-methylpropyl) -1,4-fl-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2- (1,1-dimethylethyl) -1,4-butanediol; 2- (2-methylpropyl) -1,4-butanediol; 2-methyl-3-propy1-1, 4- butanediol; 3-methyl-2-isopropyl-1,4-butanediol; 2,2,3- 20 trimethyl-1,3-pentanediol; 2, 2, 4-trimethyl-1,3-pentanediol; 2, 3, 4-trimethyl-1,3-pentanediol; 2, 4, 4-trimethyl-l, 3-pentanediol; 3, 4, 4-trimethyl-1,3-pentanediol; 2, 2, 3-trimethyl-1,4-pentanediol; 2, 2, 4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3, 4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-l, 5-pentanediol; 2, 2, 4-trimethyl-l, 5-pentanediol; 2, 3, 3-trimethyl-1, 5-pentanediol; 2, 3, 4-trimethyl-l, 5-pentanediol; 2,3,3- "trimethyl-2,4-pentanediol; 2,3,4-trimethyl-2,4-pentanediol; 2-5 ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-l, 3-pentanediol; 2-ethyl-4-methyl-l, 3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-l, 4-pentanediol; 2-ethyl-3-raethyl-l, 4-pentanediol; 2-ethyl-l-methyl-l, 4-pentanediol; 2- ethyl-4-methyl-l, 4-methane diol; 3-ethyl-2-methyl-l, 4-pentanediol; l (fl3-ethyl-3-methyl-l, 4-pentanediol; 2-ethyl-2-methyl-l, 5-pentanediol; 2-ethyl-3-methyl-l, 5-pentanediol; 2-ethyl-4- methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2'-isopropyl-1,5-pentanediol; -propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl -l, 3-hexanediol, 3,4-dimethyl-1,3-hexanediol, 3,5-dimethyl-1,3-hexanediol, 4,4- 20 dimethyl-1,3-hexanediol, 4,5-dimethyl- 1, 3-hexanediol, 2,2-dimethyl-1,4-hexanediol, 2,3-dimethyl-1,4-hexanediol, 2,4-dimethyl-1,4-hexanediol, 2,5-dimethyl-1, 4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,5-dimethyl-1,4- Hexanediol; 5.5- dimethyl-1,4-hexanediol; 2, 2-dimethyl-l, 5-hexanediol dimethyl-1,5-hexanediol; 2,4-dimethyl-1,5-hexanediol dimethyl-1,5-hexanediol; 3, 3-dimethyl-l, 5-hexanediol dimethyl-1,5-hexanediol; 3, 5-dimethyl-l, 5-hexanediol dimethyl-1,5-hexanediol; 2, 2-dimethyl-l, 6-hexanediol dimethyl-1,6-hexanediol; 2,4-dimethyl-l, 6-hexanediol dimethyl-1,6-hexanediol; 3, 3-dimethyl-l, 6-hexanediol dimethyl-1,6-hexanediol; 2,3-dimethyl-2,4-hexanediol dimethyl-2,4-hexanediol; 2, 5-dimethyl-2,4-hexanediol 'dimethyl-2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol dimethyl-2,4-hexanediol; 4,5-dimethyl-2,4-hexanediol dimethyl-2,4-hexanediol; , 3-dimethyl-2,5-hexanediol; dimethyl-2, 5-hexanediol; 2,5-dimethyl-2,5-hexanediol; dimethyl-2, 5-hexanediol; 3,4-dimethyl-2, 5-hexanediol; dimethyl-2,6-hexanediol; 2-ethyl-l, 3-hexanediol; 4-ethyl-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2- ethyl-1, 5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2, 5-hexanediol; 2-methyl-l, 3-heptane diol; 3-methyl-1,3-heptanediol, 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-l, 3-heptane diol; 2-methyl-l, 4-heptanediol; 3-methyl-1,4-heptanediol 4-methyl-l, 4-heptanediol; 5-methyl-l, 4-heptanediol 6-methyl-l, 4-heptanediol; 2-methyl-l, 5-heptanediol 3-methyl-l, 5-heptanediol; 4-methyl-l, 5-heptanediol 5-methyl-l, 5- heptanediol; 6-methyl-1, 5-heptanediol; 2-met? L-l, 6-heptanediol; 3-methyl-l, 6-heptanediol; 4-methyl-l, 6-heptanediol; 5-methyl-l, 6-heptanediol; 6-methyl-l, 6'-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2,4- 5-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-met? L-2, 5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; -methyl-2,6-) heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3, 5-octanediol; 3, 6-octanediol; and mixtures thereof. 14. The composition of claim 13 J1 further characterized in that said main solvent is selected from the group consisting of: 2- (1,1-dimethylpropyl) -1,3-propanediol; 2- (1,2-dimethylpropyl) -1,3-propanediol; 2- (1-ethylpropyl) -1,3-propanediol; 2- (2,2- 20 dimethylpropyl) -1,3-propanediol-ol, -2-methyl-2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-methylpropyl) -1,3-propanediol; 2 - . 2-butyl-tertiary-2-methyl-1,3-propanedione; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) -1,3-butanediol; 2-butyl-l, 3-butanediol; 2-ethyl-2, 3-dimethyl-1,3-butane-diol; 2- (1,1- dimethylethyl) -1,3-butanediol, -2- (2-methylpropyl) -1,3-butanediol; 2-methyl-2-propyl-l, 3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2, 2-diethyl-l, 4-butanediol; 2-ethyl- ™ 2,3-dimethyl-1,4-butanediol; 2-ethyl-3, 3-dimethyl-1,4,4-butanediol; 2- (1,1-dimethylethyl) -1,4-butanediol; 3-methyl-2-isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2, 4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3, 4, 4-trimethyl-1,3-pentanediol; 2, 2, 3-trimethyl-1,4-pentanediol; 2,2,4-lofrtrimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3, -trimethyl-l, 4-pentanediol; 2, 2, 3-trimethyl-l, 5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2, 3, 3-trimethyl-l, 5-pentanediol; 2,3,4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-l, 3-pentanediol; 2- 15 ethyl-3-methyl-l, 3-pentanediol; 2-ethyl-4-methyl-l, 3-w pentanediol; 3-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-l, 4-pentanediol; 2-ethyl-4 ^. methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-l, 3-pentanediol; 2-isopropyl-1,4-pentanediol; 2- propyl-l, 4-pentanediol; 3-isopropyl-l, 4-pentanediol; 2- isopropyl-1,5-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2, 3-dimethyl-l, 3-hexanediol; 2,4-diraethyl-l, 3-hexanediol; 2,5-dimethyl-l, 3-hexanediol; 3,4- dimethyl-1,3-hexanediol; 3, 5-d? Met? L-l, 3-hexanediol d? Met? L-1,3-hexanediol; 4, 5-dimethyl-l, 3-hexanediol 2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol 4-d? Met? L-1,4-hexanod? Ol 2,5-dimethyl-l, 4-hexanediol 3-dimethyl-1,4-hexanediol 3,4- dimethyl-1,4-hexanediol 5-dimethyl-1,4-hexanediol; 4, 5-d? Methyl-l, 4-hexanediol 5-dimethyl-1,4-hexanediol, -2,2-dimethyl-1,5-hexanediol 3-dimethyl-1,5-hexanediol; 2,4-dimet? L-l, 5-hexanedione; 5-dimethyl-1,5-hexanediol; 3, 3-dimet? L-l, 5-hexanediol 4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol 5-dimethyl? -1,5-hexanediol; 3, 3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-et? L-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2-ethyl-l, 5-hexanediol; 3-ethyl-2,4-hexanedione; 4-et? L-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-l, 3-heptane diol; 3-methyl-l, 3-heptanediol; 4-methyl-l, 3-heptane diol; 5-methyl-l, 3-heptanediol; 6-methyl-l, 3-heptane diol; 2-methyl-1,4-heptanediol; 3-methyl-l, 4-heptanod? Ol; 4-met? L-l, 4-heptanediol; 5-methyl-l, 4-heptanediol; 6-methyl-l, 4-heptanediol; 2-metll-l, 5-heptanod? Ol; 3-methyl-1,5-heptanediol; 4-methyl-l, 5-heptane diol; 5-methyl-l, 5-heptanediol; 6-methyl-1, 5-heptanediol; 2-met? L-l, 6-heptanediol; 3-methyl-l, 6-heptanediol; 4-methyl-l, 6-heptanediol; 5-methyl-l, 6-heptanediol; 6-methyl-l, 6- heptanediol; 2-methyl -2,4-heptane diol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl -2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3, 5-octanediol; 3, 6-octanediol; and mixtures thereof. 15. The composition of claim 14, further characterized in that said main solvent is selected. from the group consisting of: 2- (1,1-dimethylpropyl) -1,3-propanediol; 2- (1,2-dimethylpropyl) -1,3-propanediol; 2- (1-ethylpropyl) -1,3-propanediol; 2- (2,2-dimethylpropyl) -1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-methyl-2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-methylpropyl) -1,3-propanediol; 2-butyl-tertiary-2-methyl-1,3-propanediol; 2- (1-methylpropyl) -1,3-butanediol; 2- (2-methylpropyl-l, 3-butanediol); 2-butyl-1,3-butane-diol; 2-methyl-2-propyl -1,3-butanediol; 3-methyl-2-isopropyl-l, 3-butanediol; 2, 2-diethyl-l, 4-butanediol; 2-ethyl-2, 3-dimethyl-1,4-butanediol; 2-ethyl-3, 3-dimethyl-1,4-butanediol; 2- (1,1- dimethylethyl) -1,4-butanediol; 2, 3, 4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 2,2,3-imethyl-1,5-pentanediol; 2, 2, 4-trimethyl-l, 5-pentanediol; 2,3, 3-trimethyl-. 1, 5-pentanediol; 2-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-3-5 methyl-1,3-pentanediol; 2-ethyl-4-methyl-l, 3-pentanediol; 3-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-2-methyl-l, 4-pentanediol; 2-ethyl-3-methyl-l, 4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-3-methyl-l, 5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1, 3-pentanediol; 2-lo'propyl-l, 3-pentanediol 2-isopropyl-1,4-pentanediol; propyl-1,4-pentanediol 3-isopropyl-1,4-pentanediol; propyl-2,4-pentanediol 2,2-dimethyl-1,3-hexanediol; dimethyl-1, 3-hexanediol 2,4-dimethyl-l, 3-hexanediol; dimethyl-1, 3-hexanediol-3-dimethyl-l, 3-hexanediol; 15-dimethyl-1,3-hexanediol-4-dimethyl-l-3-hexanediol; * • * dimethyl-1,3-hexanediol-2-dimethyl-l, 4-hexanediol, -dimethyl-1,4-hexanediol-2-dimethyl-l 4-hexanediol; dimethyl-1, 4-hexanediol 3 3-dimethyl-l 4-hexanediol; dimethyl-1,4-hexanediol-3-dimethyl-4-hexanediol; 20-dimethyl-1,4-hexanediol-5-dimethyl-4-hexanediol-dimethyl-1,5-hexanediol-2-dimethyl-1-hexanediol; dimethyl-1, 5-hexanediol-2-dimethyl-l-hexanediol, -dimethyl-1,5-hexanediol-3-dimethyl-l-hexanediol, -dimethyl-1,5-hexanediol 4,5-dimethyl-l 5-hexanediol; dimethyl-2,6-hexanediol; 2-ethyl-l, 3-hexanediol; 4-ethyl-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2- ethyl-1, 5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4- ^ "hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3-heptane diol; 5-methyl-l, 3-heptane diol; 4-methyl-l, 3-heptane diol; 5-methyl-1,3-heptanediol; 6-methyl-l, 3-heptane diol; 2-methyl-l, 4-heptanediol 3-methyl-1,4-heptanediol; 4-methyl-l, 4-heptanediol 5-methyl-1,4-heptanediol; 6-methyl-l, 4-heptanediol 2-methyl-1, 5-heptanediol; 3-methyl-l, 5-lc'Jlheptanediol 4-methyl-l, 5-heptanediol; 5-methyl-l, 5-heptanediol 6-methyl-l, 5-heptane diol; 2-methyl-l, 6-heptanediol 3-methyl-1,6-heptanediol; 4-methyl-l, 6-heptanediol 5-methyl-1,6-heptanediol; 6-methyl-l, 6-heptanediol 2-methyl-2,4-heptanediol; 3-methyl-2, 4- 15 heptanediol 4-methyl-2,4-heptane diol; 5-methyl-2, 4- '-' heptanediol 6 -methyl-2,4-heptanediol; 2-methyl-2, 5-heptanediol 3-methyl-2,5-heptanediol; 4-methyl-2, 5-heptanediol 5-methyl-2,5-heptanediol; 6-methyl-2, 5-heptanediol 2-methyl-2,6-heptanediol; 3-methyl-2,6,6-heptanediol 4-methyl-2,6-heptanediol; 3-methyl-3, 4-heptanediol 2-methyl-3,5-heptanediol; 4-methyl-3, 5-heptanediol 2,4-octanediol; 2,5-octanediol; 2,6-octanediol, 2,7-octanediol; 3, 5-octanediol and / or 3,6-octanediol; and mixtures thereof. 16. - The composition of claim 15 further characterized in that said main solvent is selected from the group consisting of 2,3,4,4-tetramethyl- '2,4-pentanediol; 3-butyl tertiary-2,4-pentanediol; 2,5,5- 5 trimethyl-2,4-hexanediol; 3,, 4-trimethyl-2,4-hexanediol; 3,3,5-trimethyl-2,4-hexanediol; 3,5, 5-trimethyl-2, 4-hexanediol; 4, 5, 5-trimethyl-2,4-hexanediol; 3, 3, 4-trimethyl-2,5-hexanediol; 3, 3, 5-trimethyl-2,5-hexanediol and mixtures thereof. 17. The composition of claim 16 further characterized in that said principal solvent is 2,3,3,4-tetramethyl-2,4-pentanediol. 18. The composition of claim 1 further characterized in that said main solvent is 15 selected from the group consisting of: 3- (n-pentyloxy) -1, 2- < V propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3-pentyloxy) -1,2-propanediol; 3- (2-methyl-l-butyloxy) -1,2-propanediol; 3- (iso-amyloxy) -1,2-propanediol, -3- (3-methyl-2-butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1,2-20 propanediol; 3- (1-cyclohex-l-enyloxy? I) -1,2-propanediol, -2- (pentyloxy) -1,3-propanediol, -2- (2-pentyloxy) -1,3-propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-methyl-l-butyloxy) -1,3-propanediol; 2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) - 1,3-propanediol; 2- (2-1-cyclohex-l-enyloxy) -1,3-propanediol; 3- (butyloxy) -1,2-propanediol, triethoxylated; 3- (butyloxy) -1,2-propanediol, tetraethoxylated; 3- (butyloxy) -1,2- 'J > propanediol, pentaethoxylated; 3- (butyloxy) -1,2-propanediol, 5-hexaethoxylated; 3- (butyloxy) -1,2-propanediol, heptaethoxylated; 3- (butyloxy) -1,2-propanediol, octaethoxylated; 3- (butyloxy) -1,2-propanediol, nonaethoxylated; 3-phenyloxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3- (2-phenylethyloxy) -1,2-propanediol; 3- (1-phenyl-2-propanyloxy) -1,2-propanediol; 2-fl | phenyloxy-1,3-propanediol; 2- (m-cresyloxy) -1,3-propanediol; 2- (p-cresyloxy) -1,3-propanediol; 2-benzyloxy-1, 3-propanediol, -2- (2-phenylethyloxy) -1,3-propanediol; 2- (1-phenylethyloxy) -1,3-propanediol; bis (2-hydroxybutyl) ether; Bis (2-hydroxycyclopentyl) ether; and mixtures thereof. 19. The composition of claim 18, characterized in that said main solvent is selected from the group consisting of: 3- (n-pentyloxy) -1,2-propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3-pentyloxy) -1,2-propanediol; 3- (2-methyl-l-butyloxy) -1,2-20 propanediol; 3- (iso-amyloxy) -1,2-propanediol; 3- (3-methyl-2-butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1,2-propanediol; 3- (1-cyclohex-l-enyloxy) -1,2-propanediol; 2- (pentyloxy) -1,3-propanediol; 2- (2-pentyloxy) -1,3-propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-methyl-l- butyloxy) -1,3-propanediol; 2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) -1,3-propanediol; 2- (2-1-cyclohex-l-enyloxy) -1,3-propanediol; '3- (butyloxy) -1,2-propanediol, pentaethoxylated; 3- (butyloxy) -5,1, -propanediol, hexaethoxylated; 3- (Butyloxy) -1,2-propanediol, heptaethoxylated; 3- (butyloxy) -1,2-propanediol, octaethoxylated; 3- (butyloxy) -1,2-propanediol, nonaethoxylated, -3-phenyloxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3- (2-phenylethyloxy) -1,2-propanediol; 2- (m-cresyloxy) -1,3-fl propanediol; 2- (p-cresyloxy) -1,3-propanediol; 2-benzyloxy-1,3-propanediol; 2- (2-phenylethyloxy) -1,3-propanediol; bis (2-hydroxybutyl) ether; bis (2-hydroxycyclopentyl) ether, and mixtures thereof. 20. The composition of claim 19 15 further characterized in that said main solvent is J1 selected from the group consisting of: 3- (n-pentyloxy) -1, 2-propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3-pentyloxy) -1,2-propanediol; 3- (2-methyl-l-butyloxy) -1, 2-propanediol; 3- (iso-amyloxy) -1,2-propanediol; 3- (3-methyl-2- 20 -butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1, 2-propanediol; 3- (1-cyclohex-l-enyloxy) -1,2-propanediol; 2- (pentyloxy) -1,3-propanediol; 2- (2-pentyloxy) -1,3-propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-methyl-l-butyloxy) -1,3-propanediol; 2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) -1,3-propanediol; 2- (2-1-cyclohex-l-enylaxy) -1,3-propanediol, -3- (butyloxy) -1,2-propanediol, pentaethoxylated; 3- (Butyloxy) - * 1,2-propanediol, hexaethoxylated; 3- (butyloxy) -1,2-5 propanediol, heptaethoxylated; 3- (butyloxy) -1,2-propanediol, octaethoxylated; 3- (butyloxy) -1,2-propanediol, nonaethoxylated, -3-phenyloxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3- (2-phenylethyloxy) -1,2-propanediol; 2- (m-cresyloxy) -1,3-propanediol; 2- (p-cresyloxy) -1,3-propanediol; 2- (2-l-phenylethyloxy) -1,3-propanediol; 2- (1-phenylethyloxy) -1,3-propanediol; bis (2-hydroxybutyl) ether; Bis (2-hydroxycyclopentyl) ether; and mixtures thereof. 21. The composition of claim 1, further characterized in that said main solvent is 15 selected from the group consisting of: 1-isopropyl-2, 2- 'J' cyclobutanediol; 3-ethyl-4-methyl-l, 2-cyclobutanediol; 3- propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-l, 2-cyclopentanediol; 1,2-dimethyl-l, 2-cyclopentanediol; 1,4-dimethyl-l, 2-cyclopentanediol; 2,4,5- 20 trimethyl-1,3-cyclopentanediol; 3, 3-dimethyl-l, 2-cyclopentanediol; 3, 4-dimethyl-l, 2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4, 4-dimethyl-1,2-cyclopentanediol; 4-ethyl-l, 2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2- bis (hydroxymethyl) cydohexane; 1,2-dimethyl-l, 3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cydohexanediol; 1, 6-dimethyl-1, 3 '' '-cyclohexanediol; 1-hydroxy-cyclohexaneethanol; 1-hydroxy-5-cyclohexanemethanol; 1-ethyl-1,3-cydohexanediol; 1-methyl-l, 2-cyclohexanediol; 2,2-dimethyl-1,3-cydohexanediol; 2,3-dimethyl-1,4-cydohexanediol; 2,4-dimethyl-l, 3-cyclohexanediol; 2,5-dimethyl-1,3-cydohexanediol; 2,6-dimethyl-1,4-cydohexanediol; 2-ethyl-l, 3-cydohexanediol; 2- P hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2- hydroxymethylcyclohexanol; 3-hydroxyethyl-l-cyclohexanol; 3- hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3- methyl-1,2-cydohexanediol; 4, 4-dimethyl-l, 3-cydohexanediol; 4, 5-dimethyl-1,3-cydohexanediol; 4,6-dimethyl-l, 3- 15-cydohexanediol; 4-ethyl-l, 3-cydohexanediol; 4-hydroxyethyl-V 1 -cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5, 5-dimethyl-1,3-cydohexanediol; 5-ethyl-1,3-cydohexanediol; 1,2-cycloheptanediol; 2-methyl-l, 3-cycloheptanediol; 2-methyl-l, 4-cycloheptanediol; 4-methyl-1, 3-cycloheptanediol; 5-methyl-l, 3-cycloheptanediol; 5-methyl-l, 4-cycloheptanediol; 6-methyl-l, 4-cycloheptanediol; 1,3- cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol diethoxylate; 1,2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1, 2-cyclohexanediol heptaethoxylate; 1, 2-cyclohexanediol octaethoxylate; 1,2- ^ V nioethoxylate cyclohexanediol; 1, 2-cyclohexanediol monopropoxylate; 5-cyclohexanediol monobutylenoxylate; dibutyleneoxylate of 1,2-cydohexanediol; 1,2-cyclohexanediol tributyleneoxylate; 1-ethenyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4-tetramethyl-3-cyclobutene-1,2-diol; 3, 4-diethyl-3-cyclobutene-1,2-diol; 3- (1,1-dimethylethyl) -3-cyclobutene-1,2-ifl diol; 3-butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene-1, -cyclopentanediol; l-ethyl-3-methylene-l, 2-cyclopentanediol; 4- (1-propenyl) -1,2-cyclopentanediol; 1- ethyl-3-methyl-3-cyclopentene-1,2-diol; 1-ethenyl-l, 2-cyclohexanediol; l-methyl-3-methylene-l, 2-cydohexanediol; 1- 15 methyl-4-methylene-1,2-cydohexanediol; 3-ethenyl-l, 2- 'J' -cyclohexanediol; 4-ethenyl-l, 2-cydohexanediol; 2,6-dimethyl-3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene-1,2-diol; 3, 6-dimethyl-4-cyclohexene-1,2-diol; 4, 5-dimethyl-4-cyclohexene-1,2-diol; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; 5-cyclooctene-1,2-diol; and mixtures thereof. 22. The composition of claim 21, further characterized in that said main solvent is selected from the group consisting of: 1-isopropyl-l, 2-cyclobutanediol; 3-ethyl-4-methyl-1, -cyclobutanediol; 3- propi1-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-l, 2-cyclopentanediol; 1,2-dimethyl-l, 2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 3,3- '•' dimethyl-1,2-cyclopentanediol; 3, 4-dimethyl-l, 2-5-cyclopentanediol; 3, 5-dimethyl-l, 2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4, 4-dimethyl-1,2-cyclopentanediol; 4- ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane; 1,2-bis (hydroxymethyl) cyclohexane; 1,2-dimethyl-l, 3-cyclohexanediol; 1,3-bis (hydroxymethyl) cyclohexane, -1-fl hydroxy-cyclohexanemethanol; 1-methyl-1,2-cydohexanediol; 3- hydroxymethylcyclohexanol; 3-methyl-1,2-cydohexanediol; 4,4-dimethyl-1,3-cydohexanediol; 4, 5-dimethyl-l, 3-cyclohexanediol; 4,6-dimethyl-1,3-cydohexanediol; 4-ethyl-1,3-cydohexanediol; 4-hydroxyethyl-l-cyclohexanol; 4- 15 hydroxymethylcyclohexanol; 4-methyl-l, 2-cydohexanediol; 1,2- 'Cycloheptanediol; 1,2-cyclohexanediol pentaethoxylate; 1, 2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1, 2-cyclohexanediol octaethoxylate, 1,2-cyclohexanediol nonaethoxylate; monopropoxylate 1, 2-cyclohexanediol; 1,2-cyclohexanediol dibutylexylate; and mixtures thereof. 23. The composition of claim 1, further characterized in that said main solvent is selected from the group consisting of: 1. 1, 2-propanediol (C3) 2 (Me-E? _4); 1,2-propanediol (C3) P04; 2-methyl-l, 2-propanediol (C4) (Me-E4.?0); 2-methyl-l, 2-propanediol (C4) 2 (Me-E?); 2-methyl-l, 2-propanediol (C4) P03; 2-methyl-l, 2-propanediol (C4) B0 ?; 1,3-propanediol (C3) 2 (Me-E6.8); 1,3- 5-propanediol (C3) P05-6; 2, 2-diethyl-l, 3-propanediol (C7) E? .7; 2, 2-diethyl-l, 3-propanediol (C7) PO ?; 2, 2-diethyl-l, 3-propanediol (C7) n-BO? -2; 2, 2-dimethyl-l, 3-propanediol (C5) 2 (Me-E? _2); 2, 2-dimethyl-l, 3-propanediol (C5) P03_4; 2- (1-methylpropyl) -1,3-propanediol (C7) E? -7; 2- (1-methylpropyl) - ',} 1,3-propanediol (C7) PO ?; 2- (1-methylpropyl) -1,3-propanediol (C7) n-BO? _2; 2- (2-methylpropyl) -1,3-propanediol (C7) E? .7; 2- (2-methylpropyl) -1,3-propanediol £ C7) PO?, 2- (2-methylpropyl) -1,3-propanediol (C7) n-BO? _2; 2-ethyl-l, 3-propanediol (C5) (Me-E6_? O); 2-ethyl-l, 3-propanediol (C5) 2 (Me-E?); 2-ethyl-l, 3- 15 propanediol (C5) P03; 2-ethyl-2-methyl-l, 3-propanediol (C6) f (Me-E? -β); 2-ethyl-2-methyl-l, 3-propanediol (C6) P02; 2-Ethyl-2-methyl-1,3-propanediol (C6) BO ?; 2-isopropyl-l, 3-propanediol (C6) (Me-E? -s); 2-isopropyl-1,3-propanediol (C6) P02; 2- isopropyl-1,3-propanediol (C6) BO ?; 2-methyl-l, 3-propanediol 20 (C4) 2 (Me-E2_5); 2-methyl-l, 3-propanediol (C4) P04_5; 2-methyl-1,3-propanediol (C4) B02; 2-methyl-2-isopropyl-l, 3-propanediol (C7) E2_9; 2-methyl-2-is'opropyl-1,3-propanediol (C7) P0 ?; 2-methyl-2-isopropyl-l, 3-propanediol (C7) n-BO? _3; 2-methyl-2-propyl-l, 3-propanediol (C7) E? _7; 2-methyl-2-propyl- 1,3-propanediol (C7) PO ?; 2-methyl-2-propyl-l, 3-propanediol (C7) n-BO? -2; 2-propyl-1,3-propanediol (C6) (Me-E? _4); 2- propyl-1,3-propanediol (C6) P02; 2-propyl-1,3-propanediol w (C6) BO ?; 2. 1, 2 -butanediol (C4) (Me-E2_8); 1,2-butanediol 5 (C4) PO2-3; 1,2-butanediol (C4) BO ?; 2, 3-dimethyl-l, 2-butanediol (C6) E? _6; 2,3-dimethyl-1,2-butanediol (C6) n-BO? .2; 2-ethyl-l, 2-butanediol (C6) E? _3; 2-ethyl-l, 2-butanediol (C6) n-BO ?; 2-methyl-l, 2-butanediol (C5) (M-eE? .2); 2-methyl-l, 2-butanediol (C5) PO?, -3,3-dimethyl-l, 2-butanediol (C6) E? -S; f 3, 3-dimethyl-l, 2-butanediol (C6) n-B0? .2; 3-methyl-l, 2- butanediol (C5) (Me-E? .2); 3-methyl-l, 2-butanediol (C5) P0Xj-1,3-butanediol (C4) 2 (Me-E3-s); 1,3-butanediol (C4) P05; 1,3-butanediol (C4) B02; 2, 2, 3-trimethyl-1,3-butanediol (C7) (Me-E? _3); 2, 2, 3-trimethyl-l, 3-butanediol (C7) P0? .2; 2,2-dimethyl-1,3-butanediol (C6) (Me-E3.8); 2, 2-dimethyl-1,3-butanediol f (C6) P03; 2,3-dimethyl-l, 3-butanediol (C6) (Me-E3-8); 2,3-dimethyl-1,3-butanediol (C6) P03; 2-ethyl-l, 3-butanediol (C6) (Me-E? _6); 2-ethyl-l, 3-butanediol (C6) P0a_3; 2-ethyl-l, 3- butanediol (C6) B0 ?; 2-ethyl-2-methyl-1,3-butanediol (C7) (Me-Ex); 2-ethyl-2-methyl-l, 3-butanediol (C7) PO?, - 2-ethyl-2-methyl-1,3-butanediol (C7) n-B02_4; 2-ethyl-3-methyl-l, 3-butanediol (C7) (Me-E?); 2-ethyl-3-methyl-l, 3-butanediol (C7) P0 ?; 2- ethyl-3-methyl-l, 3-butanediol (C7) n-B02_4; 2-isopropyl-1, 3-butanediol (C7) (Me-E?); 2- isopropyl-1,3-butanediol (CZ) P0 ?; 2-isopropyl-l, 3-butanediol (C7) n-B02_4; 2-methyl-l, 3- butanediol (C5) 2 (Me-E? .3); 2-methyl-l, 3-butanediol (C5) P04; 2-propyl-1,3-butanediol (C7) E2_9; 2-propyl-1,3-butanediol f (C7) PO ?; 2-propyl-1,3-butanediol (C7) n-B0? _3; 3-methyl-1,3-butanediol (C5) 2 (Me-E? .3); 3-methyl-l, 3-butanediol (C5) P04; 1,4-butanediol (C4) 2 (Me-E2.4); 1,4-butanediol (C4) P04.5; 1,4-butanediol (C4) B02; 2, 2, 3-trimethyl-1,4-butanediol (C7) E2.9; 2, 2, 3-trimethyl-1,4-butanediol (C7) P0 ?; 2, 2, 3-trimethyl-1,4-butanediol (C7) n -BO? .3; 2, 2-dimethyl-1,4-butanediol (C6) fl (Me-E? .s); 2, 2-dimethyl-1,4-butanediol (C6) P02; 2,2-dimethyl-1,4-butanediol (C6) B0?, -2,3-dimethyl-1,4-butanediol (C6) (Me-E? -6); 2, 3-dimethyl-1,4-butanediol (C6) P02; 2,3-dimethyl-1,4-butanediol (C6) BO ?; 2-ethyl-l, 4-butanediol (C6) _ (Me-E ?, 4); 2-ethyl-l, 4-butanediol (C6) P02; 2-ethyl-l, 4-butanediol 15 (C6) BO ?; 2-ethyl-2-methyl-1,4-butanediol (C7) E? .7; 2-ethyl-2-fl-methyl-1,4-butanediol (C7) PO ?; 2-ethyl-2-methyl-1,4-butanediol (C7) n-B0? .2; 2-ethyl-3-methyl-l, 4-butanediol (C7) E? .7; 2-ethyl-3-methyl-1,4-butanediol (C7) PO?, - 2-ethyl-3-methyl-l, 4- butanediol (C7) n-BO? _2; 2-isopropyl-1,4-butanediol (C7) Ex.7; 20 2-isopropyl-1,4-butanediol (C7) PO ?; 2- isopropyl-1, 4- butanediol (C7) n-BO? _2; 2-methyl-l, 4-butanediol- (C5) (MeEd-10); 2-methyl-l, 4-butanediol- (C5) 2 (Me-Ex); 2-methyl-l, 4- butanediol- (C5) P03; 2-methyl-l, 4-butanediol- (C5) BO?, - 2-propyl-1,4-butanediol- (C7) E? -5; 2-propyl-l, 4-butanediol- (C7) n-BO? .2; 3-ethyl-i-methyl-1,4-butanediol- (C7) E2_9; 3-ethyl-l-methyl-1,4-butanediol- (C7) PO ?; 3-ethyl-l-methyl-l, 4- butanediol- (C7) n-BO? -3; 2,3-butanediol (C4) (Me-Es-? 0); 2,3- butanediol (C4) 2 (Me-E?); 2, 3-butanediol (C4) P03-4; 2,3-5 butanediol (C4) BO?, - 2, 3-dimethyl-2,3-butanediol (C6) E3_9; 2,3-dimethyl-2,3-butanediol (C6) PO?, -2,3-dimethyl-2, 3- butanediol (C6) n-BO? _3; 2-methyl-2, 3-butanediol (C5) (Me-E? _ 5); 2-methyl-2,3-butanediol (C5) P02; 2-methyl-2, 3-butanediol (C5) BO ?; 3. 1,2-pentanediol (C5) E3_10; 1, 2-pentanediol (C5) l'l PO ?; 1,2-pentanediol (C5) n-B02-3; 2-methyl-l, 2-pentanediol (C6) E? _3; 2-methyl-l, 2-pentanediol (C6) n-BOx; 2-methyl-l, 2- pentanediol (C6) BO ?; 3-methyl-l, 2-pentanediol (C6) E? -3; 3- methyl-1,2-pentanediol (C6) n-BO ?; 4-methyl-l, 2-pentanediol (C6) E? _3; 4-methyl-l, 2-pentanediol (C6) n-BO ?; 1,3- 15 pentanediol (C5) 2 (Me-E? .2); 1,3-pentanediol (C5) P03.4; 2,2-f dimethyl-1,3-pentanediol (C7) (Me-Ex.); 2, 2-dimethyl-l, 3- pentanediol (C7) PO ?; 2, 2-dimethyl-l, 3-pentanediol (C7) n-B02-4; 2, 3-dimethyl-l, 3-pentanediol (C7) (MeEx); 2, 3-dimethyl-l, 3- pentanediol (C7) P0 ?; 2,3-dimethyl-1,3-pentanediol (C7) n-B02_ 20 4; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E?); 2,4-dimethyl-1,3-pentanediol (C7) PO ?; 2,4-dimethyl-l, 3-pentanediol (C7) n-B02-4; 2-ethyl-l, 3-pentanediol (C7) E2-9; 2-ethyl-l, 3- pentanediol (C7) PO?, - 2-ethyl-l, 3-pentanediol (C7) n-B0? -3; 2- methyl-l, 3-pentanediol (C6) 2 (Me-E? .6); 2-methyl-l, 3- pentanediol (C6) P02_3; 2-methyl-l, 3-pentanediol (C6) BO ?; 3, 4-dimethyl-l, 3-pentanediol (C7) (Me-E?); 3, 4-dimethyl-l, 3- pentanediol (C7) PO ?; 3, 4-dimethyl-l, 3-pentanediol (C7) n-B02- 'i' 4; 3-methyl-l, 3-pentanediol (C6) (MeE? .6); 3-methyl-l, 3- 5 pentanediol (C6) P02.3; 3-methyl-l, 3-pentanediol (C6) B0?, -4,4-dimethyl-l, 3-pentanediol (C7) (Me-E?); 4, 4-dimethyl-l, 3- pentanediol (C7) PO ?; 4, 4-dimethyl-l, 3-pentanediol (C7) n-B02_ 4; 4-methyl-1,3-pentanediol (C6) (MeE? _6); 4-methyl-l, 3- pentanediol (C6) P02.3; 4-methyl-l, 3-pentanediol (C6) BO ?; f) 1,4-pentanediol (C5) 2 (MeE? _2); 1,4-pentanediol (C5) P03.4; 2, 2-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2, 2-dimethyl-l, 4-pentanediol (C7) PO ?; 2, 2-dimethyl-l, 4-pentanediol (C7) nB02_ 4; 2, 3-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2,3-dimethyl-1,4-pentanediol (C7) PO?, -2,3-dimethyl-l, 4-pentanediol (C7) n-B02-4; 2,4-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2,4-fl-dimethyl-1,4-pentanediol (C7) P0?, -2,4-dimethyl-l, 4-pentanediol (C7) n-B02-4; 2-methyl-l, 4-pentanediol (C6) (Me-E? .s); 2-methyl-l, 4-pentanediol (C6) P02-3; 2-methyl-l, 4- pentanediol (C6) B0?, - 3, 3-dimethyl-l, 4-pentanediol (C7) 20 (MeEx); 3, 3-dimethyl-1,4-pentanediol (C7) P0?, - 3,3-dimethyl-1,4-pentanediol (C7) n-B02-4; 3, 4-dimethyl-l, 4-pentanediol (C7) (Me-E?); 3, 4-dimethyl-l, 4-pentanediol (C7) PO ?; 3,4-dimethyl-1,4-pentanediol (C7) n-B02_4; 3-methyl-1,4-pentanediol (C6) 2 (Me-E? S); 3-methyl-l, 4-pentanediol (C6) P02.3; 3-methyl- 1,4-pentanediol (C6) BO?, - 4-methyl-l, 4-pentanediol (C6) 2 (Me-E? .6); 4-methyl-l, 4-pentanediol (C6) P02_3; 4-met? L-l, 4- pentanediol (C6) BO ?; 1,5-pentanediol (C5) (Me-E4-? 0); 1,5-p pentanediol (C5) 2 (Me-E?); 1,5-pentanediol (C5) P03; 2,2- 5 dimethyl-1,5-pentanediol (C7) E? _7; 2, 2-dimethyl-l, 5-pentanediol (C7) P0 ?; 2,2-dimet? L-l, 5-pentanediol (C7) n-BO? -2; 2,3-d? Methyl-l, 5-pentanediol (C7) E? _7; 2, 3-dimethyl-l, 5-pentanediol (C7) P0 ?; 2, 3-dimethyl-l, 5-pentanediol (C7) n -BO? -2; 2,4-dimethyl-1,5-pentanediol (C7) E.7; 2, 4-dimethyl-l, 5-pentanediol f (C7) P0 ?; 2,4-dimethyl-l, 5-pentanediol (C7) n-B0? .2; 2-ethyl-l, 5- pentanediol (C7) E? -5; 2-et? L-l, 5-pentanediol (C7) n-BO? _2; 2- methyl-1,5-pentanediol (C6) (Me-E? _4); 2-methyl-l, 5-pentanediol (C6) P02; 3, 3-dimethyl-l, 5-pentanediol (C7) E? -7; 3,3-dimethyl-1,5-pentanediol (C7) P0?, - 3, 3-dimethyl-l, 5-pentanediol (C7) n-BO_2; 3-met? L-1, 5-pentanediol (C6) (Me-E? _4); 3-methyl-1, 5-pentanediol (C6) P02; 2, 3-pentanediol (C5J) (Me-E? -3); 2,3- pentanediol (C5) P02; 2-methyl-2, 3-pentanediol (C6) E? .7; 2- methyl-2, 3-pentanediol (C6) P0 ?; 2-methyl-2, 3-pentanediol (C6) n-BO? -2; 3-methyl-2, 3-pentanediol (C6) E? -7; 3-met? L-2,3- 20 pentanediol (C6) PO ?; 3-methyl -2, 3-pentanediol (C6) n-B0? -2; 4- methyl -2, 3-pentanediol (C6) E? _7; 4-methyl-2, 3-pentanediol (C6) P0 ?; 4-methyl-2,3-pentanediol (C6) n-B0? _2; 2, 4-pentanod? Ol (C5) 2 (Me-E? .4); 2,4-pentanodol (C5) P04; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E? _4); 2,3-dimethyl-2,4-pentanediol (C7) P02; 2,4-dimethyl-2,4-pentanediol (C7) (Me-E? _4); 2,4-dimethyl-2,4-pentanediol (C7) P02; 2-methyl-2, 4-pentanediol (C7) (Me-E5.?0); 2-methyl -2,4-pentanediol (C7) P03; 3,3-f dimethyl -2,4-pentanediol (C7) (Me-E? -4); 3, 3-dimethyl-2, 4-5 pentanediol (C7) P02; 3-methyl-2, 4-pentanediol (C6) "(Me-Es_ xo); 3-methyl-2,4-pentanediol (C6) P03; 4. 1, 3-hexanediol (C6) (Me-E? _5); 1,3-hexanediol (C6) P02; 1,3-hexanediol (C6) B0?, - 2-methyl-l, 3-hexanediol (C7) E2_9; 2-methyl-l, 3-hexanediol (C7) POi, - 2-methyl-l, 3-hexanediol (C7) n-BO? -3; 2-methyl-l, 3-f-hexanediol (C7) BO ?; 3-methyl-l, 3-hexanediol (C7) E2.9; 3- methyl-l, 3-hexanediol (C7) P0 ?; 3-methyl-l, 3-hexanediol (C7) n- BO1.3; 4-methyl-l, 3-hexanediol (C7) E2.9; 4-methyl-l, 3-hexanediol (C7) P0 ?; 4-methyl-l, 3-hexanediol (C7) n -BO? _3; 5- methyl-1,3-hexanediol (C7) E2.9; 5-methyl-l, 3-hexanediol 15 (C7) P0 ?; 5-methyl-l, 3-hexanediol (C7) n-BO? -3; 1,4-hexanediol f (C6) (Me-E? _5); 1,4-hexanodiol (C6) P02; 1,4-hexanediol (C6) B0 ?; 2-methyl-l, 4-hexanediol (C7) E2-; 2-methyl-l, 4-hexanediol (C7) P0 ?; 2-methyl-l, 4-hexanediol (C7) n-B0? _3; 2-methyl-l, 4-hexanediol (C7) E2.9; 3-methyl-l, 4-hexanediol (C7) P0 ?; 3- 20 methyl-1,4-hexanediol (C7) n -BO? .3; 4-methyl-l, 4-hexanediol (C7) E2.9; 4-methyl-1,4-hexanediol (C7) PO ?; 4-methyl-l, 4-hexanediol (C7) n-BO? _3; 5-methyl-l, 4-hexanediol (C7) E2.9; 5- methyl-1,4-hexanediol (C7) P0?, - 5-methyl-1,4-hexanediol (C7) n- BO? -3; 1,5-hexanediol (C6) (Me-E? .5); 1, 5-hexanediol (C6) P02; 1, 5-hexanediol (C6) BOi, -2-methyl-l, 5-hexanediol (C7) E2_9; 2- methyl-1,5-hexanediol (C7) P0 ?; 2-methyl-l, 5-hexanediol (C7) n-B0? _3; 3-methyl-l, 5-hexanediol (C7) E2.9; 3-methyl-1, 5-wJ 'hexanediol (C7) P0 ?; 3-methyl-l, 5-hexanediol (C7) n-B0x.3; 4-5-methyl-1,5-hexanediol (C7) E2-; 4-methyl-l, 5-hexanediol (C7) P0 ?; 4-methyl-l, 5-hexanediol (C7) n -BO? .3; 5-methyl-l, 5-hexanediol (C7) E2-9; 5-methyl-l, 5-hexanediol (C7) P0 ?; 5- methyl-1,5-hexanediol (C7) n-BO? -3; 1, 6-hexanediol (C6) (Me-E? -2); 1, 6-hexanediol (C6) PO? _2; 1, 6-hexanediol (C6_) n-B04; 2-methyl-l, 6-hexanediol (C7) E? _5; 2-methyl-l, 6-hexanediol (C7) n-B0? _2; 3-methyl-l, 6-hexanediol (C7) E? .5; 3-methyl-l, 6-hexanediol (C7) n-BO? _2; , 3-hexanediol (C6) E? _5; 2,3- hexanediol (C6) n-BO; 2, 3-hexanediol (C6) BO?; 2,4-hexanediol (C6) (Me-E3.8); 2,4-hexanediol (C6) P03; 2-methyl-15 2,4-hexanediol (C7) (Me-E? .2); 2-methyl-2,4-hexanediol (C7) fl PO? .2; 3-methyl-2,4-hexanediol (C7) (Me-E? _2); 3-methyl-2,4-hexanediol (C7) PO? _2; 4-methyl-2,4-hexanediol (C7) (Me-E? _2); 4-methyl -2,4-hexanediol (C7) PO? _2; 5-methyl -2,4-hexanediol (C7) (Me-E? .2); 5-methyl -2,4-hexanediol (C7) PO? .2; 2,5-20 hexanediol (C6) (Me-E3_8); 2,5-hexanediol (C6) P03; 2-methyl-2, 5-hexanediol (C7) (Me-E? -2); 2-methyl-2, 5-hexanediol (C7) P0? .2; 3-methyl-2, 5-hexanediol (C7) (Me-E? _2); 3-methyl-2,5-hexanediol (C7) PO? _2; 3,4 hexanediol (C6) E0?: 5; 3,4-hexanediol (C6) n-BOi; 3, 4-hexanediol (C6) BO ?; 5. 1.3- heptanediol (C7) E? -7; 1,3-heptane diol (C7) PO?; 1,3-heptanediol (C7) n-B0? -2; 1,4-heptanediol (C7) E? _7; 1,4-heptanediol (C7) P0 ?; 1, 4-heptane diol (C7) n-BO? -2; 1,5-heptanediol (C7) E? _7; 1,5-heptanediol (C7) PO ?; 1,5-heptanediol (C7) n-BO? -2; 1, 6-heptanediol (C7) E? .7; 1,6-heptanediol (C7) PO ?; 1, 6-heptanediol (C7) n -BO? _2; 1,7-heptanediol (C7) E? -2; 1, 7-heptanediol (C7) n-BO ?; 2,4-heptanediol (C7) E3-10; 2,4-heptanediol (C7) (Me-E?); 2,4-heptanediol (C7) PO ?; 2,4-heptanediol (C7) n-B03; 2,5-heptanediol (C7) E3.?0; 2,5-heptanediol (C7) (Me-E?); 2,5-heptanediol (C7) PO ?; 2,5-heptanediol (C7) _ n-B03; 2,6-heptanediol (C7J E3-10; 2,6-heptanediol (C7) (Me-E?); 2,6-heptanediol (C7) PO ?; 2,6-heptanediol (C7) n-B03; , 5-heptanediol (C7) E3-? 0; 3, 5-heptanediol (C7) (Me-E?); 3,5-heptanediol (C7) P0 ?; 3, 5-heptanediol (C7) n-B03; 6. 3-methyl-2-isopropyl-l, 3-butanediol (C8) PO ?; 2, 3, 3-trimethyl-2, 4-pentanediol (C8) PO ?;, 2-diethyl-l, 3-butanediol (C8) E2_S; 2,3-dimethyl-2,4-hexanediol (C8) E2.5; 2,4-dimethyl-2,4-hexanediol (C8) E2_5; 2, 5-dimethyl-2, -hexanediol (C8) E2-5; 3,3-dimethyl-2,4-hexanediol (C8) E2-5; 3,4-dimethyl-2,4-hexanediol (C8) E2.5; 3, 5-dimethyl-2,4-hexanediol (C8) E2.5; 4,5-dimethyl-2,4-hexanediol (C8) E2.s; 5, 5-dimethyl-2,4-hexanediol (C8) E2.5; 2, 3-dimethyl-2, 5-hexanediol (C8) E2 ^ "; 2,4-dimethyl-2, 5-hexanediol (C8) E2.5; 2,5-dimethyl-2, 5- hexanediol (C8) E2-5; 3, 3-dimethyl-2, 5-hexanediol (C8) E2_5; 3,4-dimethyl-2, 5-hexanediol (C8) E2_s; 3-methyl-3, 5-heptanediol (C8) E2-5; 2, 2-diethyl-l, 3-butanediol (C8) n-B0? -2; 2,3- ™ dimethyl-2,4-hexanediol (C8) n-B0? -2; 2, 4-dimethyl-2,4,6-hexanediol (C8) n-B0? _2; 2,5-dimethyl-2,4-hexanediol (C8) n- BO? .2; 3, 3-dimethyl-2,4-hexanediol (C8) n-BO? -2; 3,4-dimethyl-2,4-hexanediol (C8) n-B0? .2; 3, 5-dimethyl-2,4-hexanediol (C8) n-BO? -2; 4, 5-dimethyl-2,4-hexanediol (C8) n-BO? -2; 5, 5-dimethyl-2, 4-hexanediol (C8) n-BO? _2; 2, 3-dimethyl-2, 5-hexanediol (C8) l'n -BO? -2; 2,4-dimethyl-2,5-hexanediol (C8) n-BO? -2; 2,5-dimethyl-2, 5-hexanediol (C8) n-BO? .2; 3, 3-dimethyl-2, 5-hexanediol (C8) n -BO? .2; 3,4-dimethyl-2,5-hexanediol (C8) n-B0? -2; 3-methyl-3,5-heptanediol (C8) n-BO? .2; 2- (1, 2-dimethylpropyl) -1, 3-propanediol (C8) n-BO ?; 2-ethyl-2, 3-dimethyl-l, 3-butanediol 15 (C8) n-B0 ?; 2-methyl-2-isopropyl-l, 3-butanediol (C8) n-BO ?; f 3 -methyl-2-isopropyl-1,4-butanediol (C8) n-BO?, - 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO?, - 2, 2, 4 -trimethyl-l, 3- pentanediol (C8) n-BO ?; 2,4, 4-trimethyl-l, 3-pentanediol (C8) n-BO? 3, 4, 4-trimethyl-l, 3-pentanediol (C8) n-BO?, - 2,2,3-20 trimethyl-1,4-pentanediol (C8) n-B0 ?; 2, 2, 4-trimethyl-l, 4-pentanediol (C8) n-B0 ?; 2, 3, 3-trimethyl-l, -pentanediol (C8) n-BO ?; 2, 3, 4 -trimethyl-1,4-pentanediol (C8) n-BO?, - 3,3,4-trimethyl-1,4-pentanediol (C8) n-B0?, - 2, 3, 4- trimethyl-2, 4- pentanediol (C8) n -BO?, - 4-ethyl-2,4-hexanediol (C8) n -B0?, - 2- methyl-2,4-heptanediol (C8) n-BOx; 3-methyl-2,4-heptanediol (C8) n-BO ?; 4-methyl-2,4-heptanediol (C8) n-BO ?; 5-methyl-2,4-heptanediol (C8) n-BO ?; 6-methyl-2,4-heptanediol (C8) n-BO ?; 2-methyl-2, 5-heptanediol (C8) n-B0?, - 3-methyl-2,5-heptanediol (C8) n-BO ?; 4-methyl-2, 5-heptanediol (C8) n-B0; 5-methyl-2,5-heptanediol (C8) n-B0?, - 6-methyl-2, 5-heptanediol (C8) n-BO ?; 6-methyl-2,5-heptanediol (C8) n-BO ?; 2-methyl-2,6-heptanediol (C8) n-BO ?; 3-methyl-2,6-heptanediol (C8) n-BO ?; 4-methyl-2,6-heptanediol (C8) n-BO ?; 2-methyl-3, 5-heptanediol (C8) n-B0?, 2- (1,2-dimethylpropyl) -1,3-propanediol (C8) E? .3; 2-et? L-2,3-dimethyl-1,3-butanediol (C8) E? .3; 2-methyl-2-isopropyl-l, 3-butanediol (C8) E? .3; 3-methyl-2-isopropyl-1,4-butanediol (C8) E? -3; 2, 2, 3-trimethyl-l, 3-pentanediol (C8) E? _3; 2, 2,4-trimethyl-1,3-pentanediol (C8) E? -3; 2, 4, 4-trimethyl-l, 3-pentanediol (C8) E? _3; 3, 4, 4-trimethyl-l, 3-pentanediol (C8) E? .3; 2, 2, 3-trimethyl-1,4-pentanediol. (C8) E? .3; 2,2,4-trimethyl-1,4-pentanediol (C8) E? .3; 2, 3, 3-trimethyl-l, 4-pentanediol (C8) E? -3; 3, 3, 4-trimethyl-l, 4-pentanediol (C8) E? _3; 2,3,4-trimethyl-2,4-pentanediol (C8) E? _3; 4-ethyl-2,4-hexanediol (C8) E? .3; 2-methyl-2,4-heptanediol- (C8) E? -3; 3-methyl-2,4-heptanediol (C8) E? -3; 4-methyl-2,4-heptanediol (C8) E? -3; 5-methyl-2,4-heptanediol (C8) E? _3; 6-methyl-2,4-heptanediol (C8) Ea-3; 2-methyl-2, 5-heptanediol (C8) E? .3; 3-methyl-2, 5-heptanediol (C8) E? _3; 4-methyl-2, 5-heptanediol (C8) E? -3; 5-methyl-2, 5-heptanediol (C8) E? _3; 6-methyl-2, 5- heptanediol (C8) E? -3; 2-methyl-2,6-heptanediol (C8) E? -3; 3-methyl -2,6-heptanediol (C8) E? .3; 4-methyl-2, 6-heptanediol (C8) f E? -3, - and / or 2-methyl-3,5-heptanediol (C8) E? _3; and 7. Mixtures of 5 the same. 24. - The composition of claim 23 further characterized in that said main solvent is selected from the group consisting of: 1. 1, 2-propanediol (C3) 2 (Me-E3_4); 1,2-propanediol (C3) PO "; 2-methyl-1, 2-IA 'propanediol (C4) (Me-E8-10); 2-methyl-l, 2-propanediol (C4) 2 (Me-E?); 2-methyl-l, 2-propanediol (C4) P03; 1,3-propanediol (C3) 2 (Me-E8); 1,3-propanediol (C3) P05; 2, 2-diethyl-l, 3-propanediol (C7) E4.7; 2, 2-diethyl-l, 3-propanediol (C7) PO?, -2,2-diethyl-l, 3-propanediol (C7) n-B02; 2, 2-dimethyl-l, 3- 15 propanediol (C5) 2 (Me-E? -2); 2, 2-dimethyl-1,3-propanediol (C5) P04; 2- (1-methylpropyl) -1,3-propanediol (C7) E4.7; 2- (1-methylpropyl) -1,3-propanediol (C7) P0 ?; 2- (1-methylpropyl) -1,3-propanediol (C7) n-B02; 2- (2-methylpropyl) -1,3-propanediol (C7) E4.7; 2- (2-methylpropyl) -1,3-propanediol (C7) 20 P0 ?; 2- (2-methylpropyl) -1,3-propanediol (C7) n-B02; 2-ethyl-1,3-propanediol (C5) (Me-E9_? 0); 2-ethyl-l, 3-propanediol (C5) 2 (Me-E); 2-ethyl-l, 3-propanediol (C5) P03; 2-ethyl-2-methyl-1,3-propanediol (C6) (Me-E3-6); 2-ethyl-2-methyl-l, 3-propanediol (C6) P02; 2-ethyl-2-methyl-l, 3-propanediol (C6) BO ?; 2-isopropyl-1,3-propanediol (C6) (Me-E3.s); 2-isopropyl-1,3-propanediol (C6) P02; 2-isopropyl-1,3-propanediol (C6) BO ?; 2-methyl-l, 3-propanediol (C4) 2 (Me-E4.5); 2-methyl-l, 3-propanediol (C4) P05; 2-methyl-l, 3-propanediol (C4) B02; 2-5 methyl-2-isopropyl-1,3-propanediol (C7) E6-9; 2-methyl-2-isopropyl-1,3-propanediol (C7) P0 ?; 2-methyl-2-isopropyl-l, 3-propanediol (C7) n-B02_3; 2-methyl-2-propyl-l, 3-propanediol (C7) E4_7; 2-methyl-2-propyl-l, 3-propanediol (C7) P0 ?; 2- methyl-2-propyl-l, 3-propanediol (C7) n-B02; 2-propyl-1,3-propanediol (C6) (Me-E? -4); 2-propy1-1, 3-propanediol (C6) P02; 2. 1,2-butanediol (C4) (Me-E6.s); 1,2-butanediol (C4) P0-3; 1,2-butanediol (C4) B0?, -2, 3-dimethyl-l, 2-butanediol (C6) E2-5; 2, 3-dimethyl-l, 2-butanediol (C6) n-B0?, - 2-ethyl-l, 2-butanediol (C6) E? -3; 2-ethyl-l, 2-butanediol (C6) n-BO ?; 2-5 methyl-1,2-butanediol (C5) (Me E? -2); 2-methyl-l, 2-butanediol (C5) PO ?; 3, 3-dimethyl-1,2-butanediol (C6) E2-5; 3,3-dimethyl-1,2-butanediol (C6) n-BO ?; 3-methyl-1,2-butanediol (C5) (Me-E? -2); 3-methyl-l, 2-butanediol (C5) PO ?; 1,3-butanediol (C4) 2 (Me-E5-6); 1,3-butanediol (C4) B02; 2, 2, 3-trimethyl-1,3-butanediol (C7) (Me-E? _3), -2,2,3-trimethyl-l, 3-butanediol (C7) P02; 2, 2-dimethyl-l, 3-butanediol (C6) (Me-E6_8); 2,2-dimethyl-1,3-butanediol (C6) P03; 2, 3-dimethyl-l, 3-butanediol (C6) (Me-E6-8); 2, 3-dimethyl-l, 3-butanediol (C6) P03; 2-ethyl-l, 3- butanediol (C6) (Me-E4-S); 2-ethyl-l, 3-butanediol (C6) P02.3; 2-ethyl-l, 3-butanediol (C6) BO ?; 2-ethyl-2-methyl-l, 3-butanediol (C7) (Me-E?); 2-ethyl-2-methyl-l, 3-butanediol (C7) _PO ?; 2-ethyl-2-methyl-l, 3-butanediol (C7) n-B03; 2-ethyl-3-methyl-1,3-butanediol (C7) (Me-E?); 2-ethyl-2-methyl-l, 3- butanediol (C7) P0?, - 2-ethyl-3-methyl-l, 3-butanediol (C7) n-B03; 2-isopropyl-1,3-butanediol (C7) (Me-E?); 2-isopropyl-1,3-butanediol (C7) PO ?; 2-isopropyl-l, 3-butanediol (C7) n-B03; 2-methyl-l, 3-butanediol (C5) 2 (Me-E2_3), -2-methyl-l, 3-butanediol (C5) P04; 2-propy1-1, 3-butanediol (C7) E6-8; 2- propyl-l, 3-butanediol (C7) P0 ?; 2-propyl-1,3-butanediol (C7) n-B02-3, -3-methyl-1,3-butanediol (C5) 2 (Me-E2.3); 3-methyl-l, 3- butanediol (C5) P04; 1,4-butanediol (C4) 2 (Me-E3.4); 1,4-butanediol (C4) P04.5; 2, 2, 3-trimethyl-1,4-butanediol (C7) E6_9; 2, 2, 3-trimethyl-1,4-butanediol (C7) PO ?; 2, 2, 3-trimethyl-1,4-butanediol (C7) n-B02-3; 2, 2-dimethyl-l, 4-butanediol (C6) (Me-E3.6), -2,2-dimethyl-1,4-butanediol (C6) P02; 2,2-dimet? -1- 1,4-butanediol (C6) BOx; 2, 3-dimethyl-1,4-butanediol (C6) (Me-E3.d), -2,3-dimethyl-1,4-butanediol (C6) P02; 2,3-dimethyl-1,4-butanediol (C6) B0 ?; 2-ethyl-l, 4-butanediol (C6) (Me-E? _- 4); 2-ethyl-1,4-butanediol (C6) P02; 2-ethyl-2-methyl-l, 4- butanediol (C7) E4_7; 2-ethyl-2-methyl-l, 4-butanediol (C7) PO ?; 2-ethyl-2-methyl-l, 4-butanediol (C7) n-B02; 2-ethyl-3-methyl-1,4-butanediol IC7) E4.7; 2-ethyl-3-methyl-l, 4-butanediol (C7) PO ?; 2-ethyl-3-methyl-1,4-butanediol (C7) n-B02; 2-isopropyl- 1,4-butanediol (C7) E4-7; 2-isopropyl-l, 4-butanediol (C7) PO ?; 2- isopropyl-1,4-butanediol (C7) n-B02; 2-methyl-l, 4- butanediol- (C5) (MeE9.?0); 2-methyl-l, 4-butanediol- (C5) 2 (Me-f Ex); 2-methyl-1,4-butanediol- (C5) P03; 2-propyl-l, 4-5-butanediol- (C7) E2.5; 2-propyl-l, 4-butanediol- (C7) n-BO ?; 3- ethyl-l-methyl-l, 4-butanediol- (C7) Es.8; 3-ethyl-l-methyl-l, 4- butanediol- (C7) PO ?; 3-ethyl-l-methyl-l, 4-butanediol- (C7) n-B02-3; 2,3-butanediol (C4) (Me-E9_10); 2,3-butanediol (C4) 2 (Me-E?); 2,3-butanediol (C4) P03_4; 2, 3-diraethyl-2, 3- "butanediol (C6) E7.9; 2,3-dimethyl-2,3-butanediol (C6) PO ?; 2,3-dimethyl-2,3-butanediol (C6) B02-3; 2-methyl-2, 3-butanediol (C5) (Me-E2-5); 2-methyl-2, 3-butanediol (C5) P02; 2-methyl-2,3-butanediol (C5) BO?, - 3. 1, 2-pentanediol (C5) E7.?0; 1,2- pentanediol (C5) P0 ?; 1,2-pentanediol (C5) n-B03; 2-methyl-1, 2-pentanediol (C6) E? .3; 2-methyl-l, 2-pentanediol (C6) n- ^^ BOi, -3-methyl-l, 2-pentanediol (C6) E? -3; 3-methyl-l, 2- pentanediol (C6) n-BO ?; 4-methyl-l, 2-pentanediol (C6) E? .3; 4- methyl-l, 2-pentanediol (C6) n-BO ?; 1,3-pentanediol (C5) 2 (Me-E1-2); 1,3-pentanediol (C5) P03.4; 2, 2-dimethyl-l, 3-pentanediol 20 (C7) (Me-E?); 2, 2-dimethyl-l, 3-pentanediol (C7) PO ?; 2,2-dimethyl-l, 3-pentanediol (C7) n-B03; 2, 3-dimethyl-l, 3- pentanediol (C7) (MeEx); 2, 3-dimethyl-l, 3-pentanediol (C7) PO ?; 2,3-dimethyl-1,3-pentanediol (C7) n-B03; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E?); 2, 4-dimethyl-l, 3-pentanediol (C7) POi; 2,4-dimethyl-l, 3-pentanediol (C7) n-B03; 2-ethyl-1,3-pentanediol (C7) E6-8; 2-ethyl-l, 3-pentanediol (C7) PO ?; 2-ethyl-l, 3-pentanediol (C7) n-B02-3; 2-methyl-l, 3-pentanediol (C6) 2 (Me-E4.6); 2-methyl-l, 3-pentanediol (Q6) P0-2-3; 3,4-_-5-dimethyl-1,3-pentanediol (C7) (Me-Ei); 3, 4-dimethyl-1, 3- pentanediol (C7) POi; 3, 4-dimethyl-l, 3-pentanediol (C7) n-B03; 3-methyl-l, 3-pentanediol (C6) 2 (MeE4-β); 3-methyl-l, 3- pentanediol (C6) P02_3; 4, 4-dimethyl-l, 3-pentanediol (C7) (Me-Ex); 4, 4-dimethyl-1,3-pentanediol (C7) POi, -4,4-dimethyl-l, 3-1 ™ pentanediol (C7) n-B03; 4-methyl-l, 3-pentanediol (C6) 2 (MeE4_6); 4-methyl-l, 3-pentanediol (C6) P02-3; 1,4-pentanediol (C5) 2 (MeE? -2); 1,4-pentanediol (C5) P03_4; 2, 2-dimethyl-l, 4-pentanediol (C7) (Me-E?); 2, 2-dimethyl-l, 4-pentanediol (C7) PO ?; 2, 2-dimethyl-l, 4-pentanediol (C7) nB03; 2, 3-dimethyl-l, 4-15 pentanediol (C7) (Me-E?); 2, 3-dimethyl-l, 4-pentanediol (C7) POi; 2, 3-dimethyl-l, 4-pentanediol (C7) n-B03; 2,4-dimethyl-1,4-pentanediol (C7) (Me-Ei); 2, 4-dimethyl-l, 4-pentanediol (C7) POi; 2,4-dimethyl-l, 4-pentanediol (C7) n-B03; 2-methyl-1,4-pentanediol (C6) (Me-E4-s); 2-methyl-l, 4-pentanediol (C6) 20 P02.3; 3, 3-dimethyl-l, 4-pentanediol (C7) (MeEx); 3, 3-dimethyl-1,4-pentanediol (C7) VO; 3, 3-dimethyl-l, 4-pentanediol (C7) n-B03; 3, 4-dimethyl-l, 4-pentanediol (C7) (Me-Ei); 3,4-dimethyl-l, 4-pentanediol (C7) P0 ?; 3, 4-dimethyl-l, 4-pentanediol (C7) n-BQ3; 3-methyl-l, 4-pentanediol (C6) 2 (Me-E4- e); 3-methyl-l, 4-pentanediol (C6) P02.3; 4-methyl-l, 4- pentanediol (C6) 2 (Me-E4.6); 4-methyl-l, 4-pentanediol (C6) P02_3; 1,5-pentanediol (C5) (Me-E8.?0); 1,5-pentanediol (C5) 2 (Me-E?); 1,5-pentanediol (C5) P03; 2, 2-dimethyl-1,5- pentanediol (C7) E4-7, -2,2-dimethyl-l, 5-pentanediol (C7) P0 ?; 2, 2-dimethyl-l, 5-pentanediol (C7) n-B02; 2, 3-dimethyl-l, 5-pentanediol (C7) E4.7; 2, 3-dimethyl-l, 5-pentanediol (C7) P0 ?; 2,3-dimethyl-l, 5-pentanediol (C7) n-B02; 2,4-dimethyl-l, 5- pentanediol (C7) E4-7; 2, 4-dimethyl-l, 5-pentanediol (C7) P0?, - 0 ™ ^ 2,4-dimethyl-l, 5-pentanediol (C7) n-B02, -2-ethyl-l, 5-pentanediol ( C7) E2_5; 2-ethyl-l, 5-pentanediol (C7) n-B0 ?; 2- methyl-1,5-pentanediol (C6) (Me-E? -4); 2-methyl-l, 5-pentanediol (C6) P02; 3, 3-dimethyl-1, 5-pentanediol CC7) Et.7; 3,3-dimethyl-1,5-pentanediol (C7) PO ?; 3, 3-dimethyl-l, 5-pentanediol (C7) n-5 B02; 3-methyl-l, 5-pentanediol (C6) (Me-E? -4); 3-methyl-1, 5-pentanediol (C6) P02; 2, 3-pentanediol (C5) (Me-E? -3); 2,3- pentanediol (C5) P02; 2-methyl-2, 3-pentanediol (C6) E4.7; 2- methyl-2,3-pentanediol (C6) P0?, - 2-methyl-2,3-pentanediol (C6) n-B02; 3-methyl-2, 3-pentanediol (C6) E4.7; 3-methyl-2,3-0 pentanediol (C6) P0 ?; 3-methyl-2, 3-pentanediol (C6) n-B02; 4- methyl-2, 3-pentanediol (C6) E4.7; 4-methyl-2, 3-pentanediol (C6) PO ?; 4-methyl-2,3-pentanediol (C6) n-B02; 2, 4-pentanediol (C5) 2 { Me-E2-4); 2, 4-pentanediol (C5) P04; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E2_4); 2, 3-dimethyl-2,4-pentanediol (C7) P02; 2,4-dimethyl-2,4-pentanediol (C7) (Me-E2.4); 2,4-dimethyl-2,4-pentanediol (C7) P02; 2-methyl-2,4-pentanediol (C7) (Me-E8.?o); 2-methyl-2, -pentanediol (C7) P03; 3,3- Fdimethyl-2,4-pentanediol (C7) (Me-E2_4); 3, 3-dimethyl-2, 4-5 pentanediol (C7) P02; 3-methyl-2,4-pentanediol (C6) (Me-E8-xo); 3-methyl -2,4-pentanediol (C6) P03; 4. 1, 3-hexanediol (C6) (Me-E2_5); 1,3-hexanediol (C6) P02; 1, 3-hexanediol (C6) BO?, - 2 -methyl-1,3-hexanediol (C7) Es.8; 2-methyl-l, 3-hexanediol- (C7) P0 ?; 2-methyl-l, 3-hexanediol (C7) n-B02-3; 3-methyl-l, 3- F ~ hexanediol (C7) E6-8; 3-methyl-l, 3-hexanediol (C7) PO ?; 3- Retyl-1,3-hexanediol (C7) n-B02_3; 4-methyl-l, 3-hexanediol (C7) E6_8; 4-methyl-l, 3-hexanediol (C7) PO; 4-methyl-l, 3-hexanediol (C7) n-B02-3; 5-methyl-l, 3-hexanediol (C7) E6.8; 5- methyl-1,3-hexanediol (C7) PO ?; 5-methyl-l, 3-hexanediol (C7) n-B02_3; 1, -hexanediol (C6) (Me-E2_5); 1,4-hexanediol (C6) P02; f 1,4-hexanediol (C6) BO ?; 2-methyl-l, 4-hexanediol (C7) E6_8; 2- methyl-1,4-hexanediol (C7) P0?, - 2-methyl-1,4-hexanediol (C7) n- B02.3; 2-methyl-l, 4-hexanediol (C7) E6-S; 3-methyl-l, 4-hexanediol (C7) P0 ?; 3-methyl-l, 4-hexanediol (C7) n-B02-3; 4-20 methyl-1,4-hexanediol (C7) E6-S; 4-methyl-l, 4-hexanediol (C7) P0 ?; 4-methyl-l, 4-hexanediol (C7) n-B02.3; 5-methyl-l, 4-hexanediol (C7) E6.8; 5-methyl-l, 4-hexanediol (C7) P0?, - 5-methyl-1,4-hexanediol (C7) n-B02-3; 1,5-hexanediol (C6) (Me-E2-5); 1, 5-hexanediol (C6) P02; 1,5-hexanediol (C6) BOi; 2- methyl-1, 5-hexanediol (C7) E6_8; 2-methyl-l, 5-hexanediol (C7) P0 ?; 2-methyl-l, 5-hexanediol (C7) n-B02_3; 3-methyl-l, 5-hexanediol (C7) E6.8; 3-methyl-l, 5-hexanediol (C7) P0 ?; 3- methyl-1,5-hexanediol (C7) n-B02-3; 4-methyl-l, 5-hexanediol 5 (C7) E6_8; 4-methyl-l, 5-hexanediol (C7) P0 ?; 4-methyl-l, 5-hexanediol (C7) n-B02_3; 5-methyl-l, 5-hexanediol (C7) E6-8; 5- 'methyl-1, 5-hexanediol (C7) P0?, - 5-methyl-l, 5-hexanediol (C7) n-B02-3; 1, 6-hexanediol (C6) (Me-E? _2); 1, 6-hexanediol (C6) PO? _ 2; 1, 6-hexanediol (C6) n-B04; 2-methyl-l, 6-hexanediol (C7) E2_ 5; 2-methyl-l, 6-hexanediol (C7) n-B0?, - 3-methyl-l, 6-hexanediol (C7) E2.5; 3-methyl-l, 6-hexanediol (C7) n-B0 ?; 2, 3-hexanediol (C6) E2.5; 2, 3-hexanediol (C6) n-BO ?; 2, 3-hexanediol (C6) BO ?; 2,4-hexanediol (C6) (Me-E5_8); 2,4-hexanediol (C6) P03; 2- methyl-2,4-hexanediol (C7) (Me-E? .2); 2-methyl-2,4-hexanediol 15 (C7) PO? -2; 3-methyl-2,4-hexanediol (C7) (Me-E? _2), - 3-methyl-f? 2, 4-hexanediol (C7) PO? -2, -4-methyl-2,4-hexanediol (C7) (Me-E? -2); 4-methyl-2, 4-hexanediol (C7) P0? .2; 5-methyl-2,4-hexanediol (C7) (Me-E? .2); 5-methyl-2,4-hexanediol (C7) P0? -2; 2,5-hexanediol (C6) (Me-E5-8); 2,5-hexanediol (C6) P03; 2-20 methyl-2, 5-hexanediol (C7) (Me-E? .2); 2-methyl-2, 5-hexanediol (C7) PO? _2; 3-methyl-2,5-hexanediol (C7) (Me-E? -2); 3-methyl-2, 5-hexanediol (C7) PO? .2; 3,4 hexanediol (C6) EO? .5; 3,4- hexanediol (C6) n-B0 ?; 5. 1, 3-heptane diol (C7) E3_6; 1,3-heptanediol (C7) P0X; 1,3-heptanediol (C7) n-B02; 1,4- heptanediol (C7) E3-s; 1,4-heptanediol (CZ) P0 ?; 1,4-heptanediol (C7) n-B02; 1,5-heptanediol (C7) Ex.6; 1,5-heptanediol (C7) P0X; 1,5-heptanediol (C7) n-B02; 1,6-heptanediol (C7) Ex-s; 1, 6-heptanediol (C7) P0 ?; 1,6- 5 heptanediol (C7) n-B02; 1, 7-heptane diol (C7) E? .2; 1,7- heptanediol (C7) n-BO ?; 2,4-heptanediol (C7) E7-? 0; 2,4-heptanediol (C7) (Me-E?); 2,4-heptanediol (C7) P0X; 2,4-heptanediol (C7) n-B03; 2,5-heptanediol (C7) E7.?0; 2,5-heptanediol (C7) (Me-E?); 2, 5-heptanediol (C7) P0 ?; 2.5-1 Heptanediol (C7) n-B03; 2,6-heptanediol (C7) E7_? 0; 2,6-heptanediol (C7) (Me-Ex), -2,6-heptanediol (C7) PO?, -2,6-heptanediol (C7) n-B03; 3, 5-heptanediol (C7) E7_? 0; 3,5-heptanediol (C7) (Me-Ei); 3, 5-heptanediol (C7) P0?, - 3,5-heptanediol (C7) n-B03; 6. 3-methyl-2-isopropyl-l, 3- 15-butanediol (C8) POi, -2,3,3-trimethyl-2,4-pentanediol (C8) F ^ POi; 2, 2-diethyl-l, 3-butanediol (C8) E2-5; 2,3-dimethyl-2, 4-hexanediol (C8) E2-5; 2,4-dimethyl-2,4-hexanediol (C8) E2-5; 2,5-dimethyl-2,4-hexanediol (C8) E2_5; 3, 3-dimethyl-2, 4-hexanediol (C8) E2-5; 3,4-dimethyl-2,4-hexanediol (C8) E2-5; 20 3, 5-dimethyl-2,4-hexanediol (C8) E2_5; 4, 5-dimethyl-2, 4-hexanediol (C8) E2_5; 5, 5-dimethyl-2,4-hexanediol (C8) E2_5; 2,3-dimethyl-2, 5-hexanediol (C8) E2.5; 2,4-dimethyl-2, 5-hexanediol (C8) E2_5; 2,5-dimethyl-2, 5-hexanediol (C8) E2_5; 3,3-dimethyl-2,5-hexanediol (C8) E2.5; 3, 4-dimethyl-2, 5- hexanediol (C8) E2-5; 3-methyl-3, 5-heptanediol (C8) E2-5; 2,2-diethyl-l, 3-butanediol (C8) n -BO? .2; 2, 3-dimethyl-2, 4-hexanediol (C8) n-B0? _2; 2, 4-dimethyl-2, -hexanediol (C8) n -B0? .2; 2,5-dimethyl-2,4-hexanediol (C8) n-B0? -2; 3, 3-dimethyl-5,2,4-hexanediol (C8) n-B?! 2; 3, 4-dimethyl-2,4-hexanediol (C8) n-BO? _2; 3,5-dimethyl-2,4-hexanediol (C8) n-B0? -2; 4,5-dimethyl-2,4-hexanediol (C8) n-B0? .2; 5, 5-dimethyl-2,4-hexanediol (C8) n-B0? _2; 2,3-dimethyl -2,5-hexanediol (C8) n -BO? -2; 2,4-dimethyl-2, 5-hexanediol (C8) n-B0? .2; 2,5-dimethyl-2,5-hexanediol (C8) 1 ™ n-B0? -2; 3,3-dimethyl-2, 5-hexanediol (C8) n-BO? -2; 3, 4-dimethyl-. 2, 5-hexanediol (C8) n -BO? .2; 3-methyl-3, 5-heptanediol (C8) n -BO? -2; 2- (1,2-dimethylpropyl) -1,3-propanediol (C8) n-BO ?; 2- ethyl-2, 3-dimethyl-l, 3-butanediol (C8) n -BO?, - 2-methyl-2-isopropyl-l, 3-butanediol (C8) n-BOi; 3-methyl-2-isopropyl-1,4-butanediol (C8) n-BO?, - 2, 2, 3-trimethyl-l, 3-pentanediol fl (C8) n-BO ?; 2, 2, 4-trimethyl-l, 3-pentanediol (C8) n-BO ?; 2, 4, 4-trimethyl-l, 3-pentanediol (C8) n-BOx; 3, 4, 4-trimethyl-1,3-pentanediol (C8) n-B0 ?; 2, 2, 3-trimethyl-l, 4-pentanediol (C8) n-B0 ?; 2, 2, 4-trimethyl-l, 4-pentanediol (C8) n-B0 ?; 20 2, 3, 3-trimethyl-1,4-pentanediol C8) n-BO ?; 2, 3, 4-trimethyl-1,4-pentanediol (C8) n-BO ?; 3, 3, 4-trimethyl-l, 4-pentanediol (C8) n-BO ?; 2,3,4-trimethyl-2,4-pentanediol (C8) n-B0?, - 4-ethyl-2,4-hexanediol (C8) n-B0?, - 2-methyl-2,4-heptanediol ( C8) n-BO ?; 3-methyl-2,4-heptanediol (C8) n-BOi, - 4-methyl-2,4- heptanediol (C8) n-BO ?; 5-methyl-2, 4-heptanediol (C8) n-BO ?; 5-methyl-2,4-heptanediol (C8) n-BO ?; 6-methyl-2,4-heptanediol (C8) n-BO ?; 2-methyl-2, 5-heptanediol (C8) n-BO ?; 3-methyl-2,5-fheptanediol (C8) n-BOi; 4-methyl-2, 5-heptanediol (C8) n-BO ?; 5-methyl-2,5-heptanediol (C8) n-BO; 6-methyl-2, 5-heptanediol_ (C8) n-BOi, - 2-methyl-2,6-heptanediol (C8) n-BO?, - 3-methyl-2,6-heptanediol (C8) n-BO ?; 4-methyl-2,6-heptanediol (C8) n-B0?, -2-methyl-3,5-heptanediol (C8) n-BOi; 2- (1,2-dimethylpropyl) -1,3-propanediol (C8) E? -3; 2-ethyl-2, 3-dimethyl-l, 3-butanediol (C8) E? -3; 2-methyl-2-isopropyl-l, 3-butanediol (C8) E? -3; 3- methyl-2-isopropyl-1,4-butanediyl (C8) E? _3; 2,2,3-trimethyl-1,3-pentanediol (C8) E? -3; 2, 2, 4-trimethyl-l, 3-pentanediol (C8) E? -3; 2, 4, 4-trimethyl-1,3-pentanediol (C8) E? _3; 3,4,4-trimethyl-1,3-pentanediol (C8) E? -3; 2, 2, 3-trimethyl-l, 4-15 pentanediol (C8) E? -3; 2, 2, 4-trimethyl-1,4-pentanediol (C8) f E? -3; 2, 3, 3-trimethyl-l, 4-pentanediol (C8) E? _3; 2,3,4-trimethyl-1,4-pentanediol (C8) E? -3; 3, 3, 4-trimethyl-l, 4-pentanediol (C8) E-3; 2, 3, 4-trimethyl-2,4-pentanediol (C8) E? -3; 4-ethyl-2,4-hexanediol (C8) E? _3; 2-methyl-2,4-heptanediol 20 (C8) E? _3; 3-methyl-2,4-heptanediol (C8) Ea.3; _4-methyl-2,4-heptanediol (C8) E? .3; 5-methyl-2,4-heptanediol (C8) E? _3; 6- methyl-2,4-heptanediol (C8) E? .3; 2-methyl-2, 5-heptanediol (C8) E? -3; 3-methyl-2, 5-heptanediol (C8) E? -3; 4-methyl-2,5-heptanediol (C8) E? -3; 5-methyl-2, 5-heptanediol (C8) E? .3; 6- methyl-2, 5-heptanediol (C8) E? _3; 2-methyl-2,6-heptanediol (C8) _ E? -3; 3-methyl-2,6-heptanediol (C8) E? -3; 4-methyl-2,6-heptanediol (C8) E? .3; and / or 2-methyl-3,5-heptanediol (C8) E? _3; and 7. mixtures thereof, 25. The composition of claim 1 further characterized in that said main solvent is selected from the group consisting of: 1-phenyl-1, 2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- ^ 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1, 3-propanediol; 1- phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol, -1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; l-phenyl-2,3-butanediol; and mixtures thereof. 26. The composition of claim 25 in Wherein said main solvent is selected from the group f consisting of: 1-phenyl-1,2-ethanediol; l-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 1- (3-methylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3,8-butanediol; 1-phenyl-1,4-butanediol; and mixtures thereof. 27. The composition of claim 26 further characterized in that said main solvent is selected from the group consisting of: l-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-2, 2- propanediol; 1- (3-methylphenyl) -1,3-propanediol, -1- (4-methylphenyl) -1,3-propanediol; 2-methyl-1-phenyl-1, 3-propanediol; and / or 1-phenyl-1,4-butanediol; and mixtures thereof. 5. The composition of claim 1 further characterized in that said main solvent is selected from the group consisting of: solvents which are homologous, or analogous, of the following parent compounds where one or more CH2 groups are added, 10 ^ while for each CH2 group added, 2 hydrogen atoms are removed from the adjacent carbon atoms in the molecule to form a carbon-carbon double bond, thus keeping the number of hydrogen atoms in the molecule constant, the parent compounds include the following: I. Mono-15 oles including: a. N-propanol; and / or b. 2 -butanol or 2-methyl-F 2 -propanol; II. Isomers of hexanediol including: 2,3-dimethyl-2,3-butanediol; 2, 3-dimethyl-1,2-butane-diol; 3,3-diraethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol; 4-methyl-2, 3-pentanediol, -2,3-hexanediol; 3, 4-hexanediol; 2-ethyl-l, 2-butanediol; 2-methyl-l, 2- pentanediol; 3-methyl-l, 2-pentanediol; 4-methyl-l, 2- pentanediol; and / or 1,2-hexanediol; III. Isomers of heptanediol including: 2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2- (1-methylpropyl) -1,3-propanediol; 2- (2- methylpropyl) -1,3-propanediol; 2- (2-methylpropyl) -1,3-propanediol; 2-methyl-2-propyl-l, 3-propanediol; 2,3,3- ^ _ trimethyl-1, -butanediol; 2-ethyl-2-ethyl-l, 4-butanediol; 2- Fetyl-3-methyl-l, 4-butanediol; 2-propyl-l, 4-butanediol; 2-5 isopropyl-1,4-butanediol; 2, 2-dimethyl-l, 5-pentanediol; 2,3-dimethyl-l, 5-pentanediol; 2,4-dimethyl-l, 5-pentanediol; 3,3-dimethy1-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3, 4-dimethyl-2,3-pentanediol, -4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; 2-0-phlethyl-1, 5-pentanediol; 2-methyl-l, 6-hexanediol; 3-methyl-l, 6-hexanediol; 2-methyl-2,3-hexanediol, 3-methyl-2,3-hexanediol, 4-methyl-2,3-hexanediol; 5-methyl-2, 3-hexanediol; 2-methyl-3,4-hexanediol; 3-methyl-3, 4-hexanediol; 1,3-heptane diol; 1,4-heptanediol; 1,5-heptanediol; and / or 1, 6-heptanediol; IV. 5 Octane diol isomers, including: 2- (2-methylbutyl) -1, 3-propanediol; 2- (1,1-dimethylpropyl) -1,3-propanediol; 2- (1,2-dimethylpropyl) -1,3-propanediol; 2- (1-ethylpropyl) -1,3-propanediol; 2- (1-methylbutyl) -1,3-propanediol; 2- (2,2-dimethylpropyl) -1,3-propanediol; 2- (3-methylbutyl) -1,3-0 propanediol; 2-butyl-2-methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol, 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2- (1-methylpropyl) -1,3-propanediol; 2-methyl-2- (2-methylpropyl) -1,3-propanediol; 2-butyl-tertiary-2-methyl-l, 3-propanediol; 2, 2-diethyl-l, 3-butanediol; 2- (1-methylpropyl) - 1,3-butanediol; 2-butyl-1,3-butanediol; 2-ethyl-2, 3-dimethyl-1,3-butanediol; 2- (1,1-dimethylethyl) -1,3-butanediol; 2-12- Fmethylpropyl-1,3-butanediol); 2-methyl-2-isopropyl-l, 3-butanediol; 2-methyl-2-propyl-l, 3-butanediol; 3-methyl-2-isopropyl-1,3-butanediol; 2-Rethyl-2-propyl-l, 3-butane-diol; 3 - . 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2, 2-diethyl-1, -butanediol; 2-methyl-2-propyl-l, 4-butanediol; 2 (1-methylpropyl) -1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3, 3-dimethyl-1,4-butanediol; F2- (1,1-dimethylethyl) -1,4-butanediol; 2- (2-methylpropyl) -1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3-methyl-2-isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-l, 3-pentanediol; 2, 4, 4-trimethyl-1,3-pentanediol; 3, 4, 4-trimethyl-1,3-pentanediol; 2, 2, 3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2, 3, -trimethyl-1,4-pentanediol; 3, 3, 4-trimethyl-1,4-pentanediol; 2, 2, 3-trimethyl-l, 5-pentanediol; 2, 2, 4-trimethyl-1,5-pentanediol; 2, 3, 3-trimethyl-l, 5-pentanediol; 2,3,4-trimethyl-1,5-pentanediol; 2, 3, 3-trimethyl-2,4-pentanediol; , 3, 4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-3-methyl-l, 3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl-l, 3-pentanediol; 2-ethyl-2-methyl-l, 4-pentanediol; 2-ethyl-3-methyl-l, 4-pentanediol; 2- ethyl 4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-3-methyl-l, 5-pentanediol; 2-ethyl-4-I methyl-1,5-pentanediol; 3-ethyl-3-methyl-l, 5-pentanediol; 3- ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl -1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2- propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2- isopropyl-l, 5-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol 4,5-dimethyl-1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol 2,2-dimethyl-l, 5-hexanediol; 2,3-dimethyl-1,5-hexanediol 2,4-dimethyl-l, 5-hexanediol; 2,5-dimethyl-1, 5-hexanediol 3, 3-dimethyl-l, 5-hexanediol; 3,4-dimethyl-1,5-hexanediol 3,5-dimethyl-l, 5-hexanediol; 4,5-dimethyl-1,5-hexanediol 2,2-dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol 2,4-dimethyl-1,6-hexanediol; 2,5-dimethyl-1,6-hexanediol 3,3-dimethyl-1,6-hexanediol; 3,4-dimethyl-1,6-hexanediol 2,3-dimethyl-2,4-hexanediol; 2,4- dimethyl-2,4-hexanediol 2,5-dimethyl-2,4-hexanediol 3,3-dimethyl-2,4-hexanediol 3,4-dimethyl-2,4-hexanediol 3,5-dimethyl-2, 4- hexanediol 4, 5-dimethyl-2,4-hexanediol; 5.5 I dimethyl-2,4-hexanediol, 3-dimethyl-2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol 3,4-dimethyl-2,5-hexanediol; 3,3 dimethyl-2,6-hexanediol 2-ethyl-1,3-hexanediol; 4-ethyl-l, 3-hexanediol; 2-ethyl-l, 4-hexanediol; 4-ethyl-l, 4-hexanediol; 2-ethyl-1, 5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-f-hexanediol; 3-ethyl-2, 5-hexanediol; 2-methyl-l, 3-heptanediol 3-methyl-1,3-heptanediol; 4-methyl-l, 3-heptane diol; 5-methyl-1,3-heptanediol; 6-methyl-l, 3-heptane diol; 2-methyl-1,4-heptanediol; 3-methyl-l, 4-heptanediol 4-methyl-l, 4-heptanediol; 5-methyl-l, 4-heptanediol 6-methyl-l, 4-5 heptanediol; 2-methyl-l, 5-heptanediol 3-methyl-l, 5-heptanediol; 4-methyl-l, 5-heptanediol 5-methyl-l, 5-heptanediol; 6-methyl-l, 5-heptanediol 2-methyl-l, 6-heptanediol; 3-methyl-l, 6-heptanediol 4-methyl-l, 6-heptanediol, -5-methyl-1,6-heptanediol 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol 3-methyl-2,4-heptanediol; 4-methyl-2, -heptanediol 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol 4-methyl-2,5-heptanediol; 5-methyl-2, 5-heptanediol 6-methyl-2,5- heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2, 4-octanodol; 2,5-5 octanediol; 2,6-octanediol; 2,7,7-octanediol; 3, 5-octanodol and / or 3,6-octanediol. V. Nonanodiol isomers, including: 2,3, 3, 4-tetramethyl-2,4-pentanediol; 3-butyl-2,4-pentanediol; 2, 5, 5-trimethyl-2,4-hexanediol; 3, 3,4-tpmethyl-2,4-hexanediol; 3, 3, 5-tpmethyl-2,4-hexanediol; 3,5,5-l Fir tpmethyl-2,4-hexanediol; 4, 5, 5-trimethyl-2,4-hexanedione; 3, 3, 4-trimethyl-2, 5-hexanodol and / or 3, 3, 5-trimethyl-2,5-hexanodol. SAW. Glyceryl ethers and / or di (hydroxyalkyl) ethers, including: 3- (n-pentyloxy) -1, 2-propanediol; 3- (2-pentyloxy) -1,2-propanediol; 3- (3- 15-pentyloxy) -1,2-propanediol; 3- (2-methyl-l-butyloxy) -1, 2-propanediol; 3- (iso-amyloxy) -1,2-propanediol; 3- (3-methyl-2-butyloxy) -1,2-propanediol; 3- (cyclohexyloxy) -1,2-propanediol; 3- (1-cyclohex-l-emloxy) -1, 2-propanediol; 2- (pentyloxy) -1,3-propanediol; 2- (2-pentyloxy) -1,3-20 propanediol; 2- (3-pentyloxy) -1,3-propanediol; 2- (2-met? L-l-butyloxy) -1,3-propaned? Ol; 2- (iso-amyloxy) -1,3-propanediol; 2- (3-methyl-2-butyloxy) -1,3-propanediol; 2- (cyclohexyloxy) -1,3-propanediol; 2- (1-c? Clohex-l-enilox?) -1, 3-propanediol; 3- (butyloxy) -1,2-propanediol, triethoxylated; 3- (butyloxy) - 1,2-propanediol, tetraethoxylated; 3- (butyloxy) -l, 2-propanediol, pentaethoxylated; 3- (butyloxy) -1, 2 -pr panodiol, Ryexaethoxylated; 3- (Butyloxy) -1,2-propanediol, heptaethoxylated; 3- (Butyloxy) -1,2-propanediol, octaethoxylated; and / or 3- 5 (butyloxy) -1,2-propanediol, nonaethoxylated; VII. Saturated and unsaturated alicyclic diols and their derivatives, including: (a) The saturated diols and their derivatives, including: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-l, 2-cyclobutanediol; 3-10 isopropyl-1,2-cyclobutanediol, -1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-l, 2-cyclopentanediol; 1,4-dimethyl-l, 2-cyclopentanediol; 2, 4,? -trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3, 4-dimethyl-l, 2-cyclopentanediol; 3, 5-dimethyl-l, 2-cyclopentanediol; 3-ethyl- \ 5 ^ 1,2-cyclopentanediol; 4, 4-dimethyl-l, 2-cyclopentanediol, -4-ethyl-1,2-cyclopentanediol; 1,1-bis (hydroxymethyl) cyclohexane r 1, 2-bis (hydroxymethyl) cyclohexane, -1,2-dimethyl-l, 3-cyclohexanediol, -1,3-bis (hydroxymethyl) cyclohexane; 1,3-dimethyl-1,3-cydohexanediol; 1, 6-dimethyl-l, 3- 20 cyclohexanediol; 1-hydroxy-cyclohexaneethanol; 1-hydroxy-cyclohexanemethanol, -1-ethyl-1,3-cyclohexanediol; 1-methyl-l, 2-cyclohexanediol; 2, 2-dimethyl-l, 3-cyclohexanediol; 2,3-dimethyl-1,4-cydohexanediol; 2,4-dimethyl-1, 3-cyclohexanediol; 2,5-dimethyl-1,3-cydohexanediol; 2,6- dimethyl-1,4-cyclohexanediol; 2-ethyl-l, 3-cyclohexanediol; 2- hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2- ^^ hydroxymethylcyclohexanol; 3-hydroxyethyl-l-cyclohexanol; 3- hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-5 methyl-1, -cydohexanediol; 4, 4-dimethyl-l, 3-cyclohexanediol; 4, 5-dimethyl-1,3-cydohexanediol; 4, 6-dimethyl-l, 3-cyclohexanediol; 4-ethyl-l, 3-cydohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-l, 2-cyclohexanediol; 5, 5-dimethyl-1,3-cydohexanediol; 5-ethyl-ß 1, 3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-l, 3-cycloheptanediol; 2-methyl-l, 4-cycloheptanediol; 4-methyl-l, 3-cycloheptanediol; 5-methyl-l, 3-cycloheptanediol; 5-methyl-l, 4-cycloheptanediol; 6-methyl-l, 4-cycloheptanediol; 1,3- cyclooctanediol; 1,4-cyclooctanediol; 1,5-cyclooctanediol; 15, 1,2-cyclohexanediol diethoxylate; 1,2-cyclohexanediol triethoxylate; tetraethoxylate of 1, -cyclohexanediol; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1, 2-cyclohexanediol heptaethoxylate; 1, 2-cyclohexanediol octaethoxylate; 1,2- 20 cyclohexanediol nonaethoxylate; 1, 2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutylenoxylate; dibutyleneoxylate of 1,2-cyclohexanediol and / or 1,2-cyclohexanediol tributyleneoxylate; and (b) the unsaturated alicyclic diols including: l-ethenyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4- tetramethyl-3-cyclobutene-1,2-diol; 3, 4-diethyl-3-cyclobutene-1,2-diol; 3- (1,1-dimethylethyl) -3-cyclobutene-1,2-diol; 3- _ butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene-l, 2-cyclopentanediol; l-ethyl-3-methylene-l, 2-cyclopentanediol; 4-5 (1-propenyl) -1,2-cyclopentanediol; l-ethyl-3-methyl-3-cyclopentene-1,2-diol; 1-ethenyl-l, 2-cyclohexanediol; 1- methyl-3-methylene-1,2-cydohexanediol; l-methyl-4-methylene-1,2-cydohexanediol; 3-ethenyl-1,2-cydohexanediol; 4-ethenyl-1,2-cydohexanediol; 2,6-dimethyl-3-cyclohexene-1,2-diol; ltr 6, 6-dimethyl-3-cyclohexene-1,2-diol; 3,6-diraethyl-4-cyclohexene-1,2-diol; 4, 5-dimethyl-4-cyclohexene-1,2-diol; 3- cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol and / or 5-cyclooctene-1,2-diol; VIII. Alkoxylated derivatives of diols of 3 to 8 carbon atoms including: 1,2-propanediol 15 (C3) 2 (Me-Eu-? 4), -1,2-propanediol (C3) P04; 2-methyl-l, 2-f1 propanediol (C4) (Me-E4_? 0); 2-methyl-l, 2-propanediol (C4) 2 (Me-Ei); 2-methyl-1,2-propanediol (C4) P03; 2-methyl-l, 2-propanediol (C4) n-B0? 2; 1,3-propanediol (C3) 2 (Me-E6.8); 1,3-propanediol (C3) P05.S; 2, 2-diethyl-l, 3-propanediol (C7) E? _7; 2, 2-diethyl-l, 3-propanediol (C7) P0?, -2, 2-diethyl-l, 3-propanediol (C7) n-BO? -2; 2, 2-dimethyl-1,3-propanediol (C5) 2 (Me-E? _2); 2, 2-dimethyl-1,3-propanediol (C5) P03_4; 2- (1-methylpropyl) -1,3-propanediol (C7) E? -; 2- (1-methylpropyl) -1,3-propanediol (C7) PO ?; 2- (1-methylpropyl) -1, 3-propanediol (C7) n-BO? -2; 2- (2-methylpropyl) -1,3-propanediol. (C7) E? -7; 2- (2-methylpropyl) -1,3-propanediol (C7) P0 ?; 2- (2-methylpropyl) -1,3-propanediol (C7) n-BO? _2; 2-ethyl-l, 3-propanediol (C5) (Me-Es-? O); 2-ethyl-l, 3-propanediol (C5) 2 (Me-E?); 2-ethyl-l, 3-5 propanediol (C5) P03; 2-ethyl-l, 3-propanediol (C5) BO ?; 2- ethyl-2-methyl-l, 3-propanediol (C6) (Me-Ei-s); 2-ethyl-2-methyl-1,3-propanediol (C6) P02; 2-ethyl-2-methyl-l, 3-propanediol (C6) BOi; 2-isopropyl-1,3-propanediol (C6) (Me-E? _6); 2- isopropyl-1,3-propanediol (C6) P02; 2-isopropyl-l, 3-propanediol (C6) BO ?; 2-methyl-l, 3-propanediol (C4) 2 (Me-E2_ 5); 2-methyl-l, 3-propanediol (C4) P04-5; 2-methyl-l, 3-propanediol (C4) B02; 2-methyl-2-isopropyl-l, 3-propanediol (C7) E2_9; 2-methyl-2-isopropyl-1,3-propanediol (C7) P0?, - 2-methyl-2-isopropyl-1,3-propanediol (C7) n-BO? -3; 2-methyl-2- 15 propyl-l, 3-propanediol (C7) E? -7; 2-methyl-2-propyl-l, 3-f propanediol (C7) P0X; 2-methyl-2-propyl-l, 3-propanediol (C7) n-BO? -2, - 2-propyl-1,3-propanediol (C6) (Me-E ?? 14); 2-propyl-1,3-propanediol (C6) P02; 2-propyl-1,3-propanediol (C6) BOi .; 2. 1,2-butanediol (C4) (Me-E2-8); 1,2-butanediol (C4) P02-3; 20 -butanediol (C4) BO?, - 2, 3-dimethyl-l, 2-butanediol (C6) Ex. 6; 2,3-dimethyl-l, 2-butanediol (C6) B0? -2; 2-ethyl-l, 2-butanediol (C6) E? _3; 2-ethyl-l, 2-butanedi (C6) BOi, -2-methyl-1,2-butanediol (C5) (Me E? _2); 2-methyl-l, 2-butanediol (C5) POi; 3, 3-dimethyl-l, 2-butanediol (C6) Ex-6; 3,3-dimethyl- 1,2-butanediol (C6) BO? -2; 3-methyl-l, 2-butanediol (C5) (Me-E? -2); 3-methyl-l, 2-butanediol (C5) PO; 1,3-butanediol (C4) ^ 2 (Me-E ??. ??); 1,3-butanediol (C4) P05; 1,3-butanediol (C4) B02; 2, 2, 3-trimethyl-1,3-butanediol (C7) (Me-E? .3); 2,2,3-5 trimethyl-1,3-butanediol (C7) PO? .2; 2, 2-dimethyl-l, 3-butanediol (C6) (Me-E3.8); 2, 2-dimethyl-l, 3-butanediol (C6) P03; 2,3-dimethyl-l, 3-butanediol (C6) (Me-E3-8); 2,3-dimethyl-1,3-butanediol (C6) P03; 2-ethyl-l, 3-butanediol (C6) (Me-E ?. 6); 2-ethyl-l, 3-butanediol (C6) P02-3; 2-ethyl-l, 3-butanediol 0f1 (C6) BO ?; 2-Ethyl-2-methyl-1,3-butanediol (C7J (Me-Ei); 2-ethyl-2-methyl-1,3-butanediol (C7) PO ?; 2-ethyl-2-methyl-1, 3- butanediol (C7) n-B02_4; 2-ethyl-3-methyl-l, 3-butanediol (C7) (Me-E?); 2-ethyl-3-methyl-l, 3-butanediol (C7) POi; 2-ethyl-3: methyl-1,3-butanediol (C7) n-B02-4; 2-isopropyl-1,3-butanediol 5 (C7) (Me-E?); 2-isopropyl-l, 3-butanediol (C7) P0?, - 2-isopropy1-1, 3-butanediol (C7) n-B02-4; 2-methyl-l, 3-butanediol (C5) 2 (Me-E? -3); 2-methyl-l, 3-butanediol (C5) P04; 2-propyl-1,3-butanediol (C7) E2.9; -propyl-1,3-butanediol (C7) P0L; 2 -propi1-1, 3 -butanediol (C7) n -BO? _3; 3-methyl-l, 3-butanediol 0 (C5) 2 (Me-E? -3); 3-methyl-l, 3-butanediol (C5) P04; 1,4-butanediol (C4) 2 (Me-E2-4); 1,4-butanediol (C4) P04-5; 1,4-butanediol (C4) B02; 2, 2, 3-trimethyl-1,4-butanediol (C7) E2.9; 2, 2, 3-trimethyl-1,4-butanediol (C7) P0 ?; 2, 2, 3-trimethyl-l, 4- butanediol (C7) n-B0? -3; 2, 2-dimethyl-l, 4-butanediol (C6) (Me- E? -6); 2, 2-dimethyl-1,4-butanediol (C6) P02; 2, 2-dimethyl-l, 4-butanediol (C6) BO ?; 2, 3-dimethyl-1,4-butanediol (C6) (Me-E? -s); 2, 3-dimethyl-1,4-butanediol (C6) P02; 2, 3-dimethyl-1,4-butanediol (C6) B0?, - 2-ethyl-1,4-butanediol (C6) (Me- En.?4); 2-ethyl-l, 4-butanediol (C6) P0; 2-ethyl-l, 4-butanediol (C6) BO?, - 2-ethyl-2-methyl-1,4-butanediol (C7) E? .7; 2-Ethyl-2-methyl-1,4-butanediol (C7) PO?, - 2-ethyl-2-methyl-1,4-butanediol (C7) n-BO? -2; 2-ethyl-3-methyl-l, 4-butanediol (C7) E? -7; 2-ethyl-3-methyl-l, 4-butanediol (C7) PO ?; 2-ethyl-3-methyl-1,4-butanediol (C7) n-B0? -2; 2-isopropyl-l, 4-butanediol (C7) E? -7; 2-isopropyl-1,4-butanediol (C7) PO ?; 2- isopropyl-1,4-butanediol (C7) n-B0? _2; 2-methyl-l, 4-butanediol- (C5) (MeEs-? 0); 2-methyl-l, 4-butanediol- (C5) 2 (Me-E?); 2-methyl-l, 4-butanediol- (C5) P03; 2-methyl-l, 4-butanediol- (C5) B0?, - 2-propyl-1,4-butanediol- (C7_) E? .5; 2-propyl-l, 4-butanediol- (C7) n-B0? 2; 3-ethyl-l-methyl-1,4-butanediol- (C7) E2.9; 3-ethyl-l-methyl-l, 4-butanediol- (C7) PO ?; 3-ethyl-l-methyl-l, 4-butanediol- (C7) n-BO? -3; 2,3-butanediol (C4) (Me-E? .6); 2,3-butanediol (C4) 2 (Me-E?); 2, 3-butanediol (C4) P03-4; 2,3-butanediol (C4) B0?, - 2,3-dimethyl-2,3-butanediol (C6) E3-9"; 2,3-dimethyl-2,3-butanediol (C6) P0 ?; 2, 3-dimethyl-2, 3-butanediol (C6) BO1-3; 2-methyl-2, 3-butanediol (C5) (Me-E? .5); 2-methyl-2,3-butanediol (C5) 2P02; 2-methyl-2, 3-butanediol (C5) n-B0 ?; 2-methyl-2, 3-butanediol (C5) BOi, - 3. 1,2- pentanediol (C5) E3_? 0; 1,2-pentanediol (C5) P0 ?; 1,2-pentanediol (C5) n-B02-3; 2-methyl-l, 2-pentanediol (C6) E? -3; ^ 2-methyl-l, 2-pentanediol (C6) n-B0 ?; 2-methyl-l, 2-pentanediol (C6) BOi, -3-methyl-l, 2-pentanediol (C6) E? -3; 3-methyl-l, 2- pentanediol (C6) n-BOi; 3-methyl-l, 2-pentanediol (C6) BOj .; 4- methyl-l, 2-pentanediol (C6) E? -3; 4-methyl-l, 2-pentanediol (C6) n-BOi; 4-methyl-l, 2-pentanediol (C6) BOi; 1,3-pentanediol (C5) 2 (Me-Ex-2); 1,3-pentanediol (C5) P03_4; 2, 2-dimethyl-l, 3-pentanediol (C7) (Me-E?); 2, 2-dimethyl-l, 3-pentanediol (C7) fPO ?; 2, 2-dimethyl-l, 3-pentanediol (C7) n-B02-4; 2,3-dimethyl-1,3-pentanediol (C7) (Me-E?); 2, 3-dimethyl-l, 3-pentanediol (C7) POi; 2,3-dimethyl-l, 3-pentanediol (C7) _ n-B02.4; 2,4-dimethyl-1,3-pentanediol (C7) (Me-Ei); 2,4-dimethyl-l, 3- pentanediol (C7) POi; 2,4-dimethyl-l, 3-pentanediol (C7) n-B02. _ 4; 2-ethyl-l, 3-pentanediol (C7) E2.9; 2-ethyl-1,3-pentanediol (C7) POi; 2-ethyl-l, 3-pentanediol (C7) n-BO? -3; 2-methyl-l, 3- pentanediol (C6) 2 (Me-E? _6); 2-methyl-l, 3-pentanediol (C6J P02_3; 2-methyl-l, 3-pentanediol (C6) n-BOi; 2-methyl-l, 3- pentanediol (C6) BOi; 3,4-dimethyl-l , 3-pentanediol (C7) (Me-Ei); 3,4-dimethyl-1,3-pentanediol (C7) POi, -3,4-dimethyl-l, 3- pentanediol (C7) n-B02_4; methyl-l, 3-pentanediol (C6) 2 (Me- E? -6); 3-methyl-l, 3-pentanediol (C6) P02_3; 3-methyl-l ', 3- pentanediol (C6) n-BOi 4,4-dimethyl-l, 3-pentanediol (C7J POi; 4, 4-dimethyl-l, 3-pentanediol (C7) n-B02.4; 4-methyl-l, 3- pentanediol (C6) 2 (MeE_6); 4-methyl-l, 3-pentanediol (C6) P02-3; 4-met? L-1, 3-pentanediol (C6) B0 ?; 1,4-pentanediol (C5) 2 (Me-E? -2); 1,4-pentanediol (C5) P03_4; 2, 2-dimethyl-l, 4-pentanediol (C7) (Me-Ex); 2, 2-dimethyl-l, 4-pentanediol (C7) P0?, -2,2-dimethyl-1,4-pentanediol (C7) nB02-4; 2,3-dimethyl-1,4-pentanediol (C7) (Me-Ei); 2,3-dimethyl-1,4-pentanediol (C7) POi; 2,3-dimet? L-l, 4-pentanediol (C7) n-B02-4, -2,4-d? Methyl-l, 4-pentanod? Ol (C7) (Me-Ei); 2, 4-d? Methyl-l, 4-pentanediol (C7) PO ?; 2,4-d? Methyl-l, 4-pentanediol (C7) n-B02-4; 2-methyl-l, 4-pentanediol (C6) (Me-E? .6); 2-methyl-1,4-pentanediol (C6) P02_3; 2-methyl-l, 4-pentanediol (C6) n-BO?, -2-methyl-1,4-pentanediol (C6) BO ?; 3, 3-dimethyl-l, 4-pentanediol (C7) (Me-E?); 3, 3-dimethyl-l, 4-pentanediol (C7) PO ?; 3, 3-dimethyl-1,4-pentanediol (C7) n-B02_4; 3,4-dimet? L-1,4-pentanod? Ol (C7) (Me-Ei); 3, 4-dimethyl-l, 4-pentanediol (C7) POi; 3, 4-dimethyl-l, 4-pentanediol (C7) n-B02_t; 3-metll-1,4-pentanediol (C6) 2 (Me-E? -6); 3-methyl-l, 4-pentanediol (C6) P02-3; 3-methyl-l, 4-pentanediol (C6) BO ?; 4-methyl-l, 4-pentanediol (C6) 2 (Me-E? _5); 4-methyl-l, 4-pentanediol (C6) P02-3; 4-methyl-l, 4-pentanediol (C6) BOi; 1,5-pentanediol (C5) (Me-E4-? O); 1,5-pentanediol (C5) 2 (Me-Ex); 1,5-pentanediol (C5) P03; 2, 2-dimethyl-l, 5-pentanediol (C7) E? _7; 2, 2-dimethyl-l, 5-pentanediol (C7) PO ?; 2, 2-dimethyl-l, 5-pentanediol (C7) n-BO? -2, -2,3-dimethyl-l, 5-pentanod? Ol (C7) E? _7; 2,3-dimethyl-l, 5-pentanediol (C7) P0X; , 3-dimethyl-l, 5-pentanediol (C7) n-B0? -2; 2,4-dimethyl-l, 5-pentanediol (C7) B? _7; 2,4-dimethyl-l, 5-pentanediol (C7) P0 ?; 2,4-dimethyl-l, 5-pentanediol (C7) n-BO? -2; 2-ethyl-l, 5-pentanediol (C7) E? -5; 2-ethyl-1, 5-pentanediol (C7) n -BO? .2; 2-methyl-l, 5-pentanediol_ (C6) (Me-E ??.? 4); 2-methyl-l, 5-pentanediol (C6) P02; 3,3-dimethyl-1,5-pentanediol (C7) E? .7; 3, 3-dimethyl-l, 5-pentanediol (C7) P0 ?; 3, 3-dimethyl-l, 5-pentanediol (C7) n-B0? .2; 3-methyl-1, 5-pentanediol (C6) (Me-E? -? 4); 3-methyl-l, 5-pentanediol (C6) P02; 2,3-pentanediol (C5) (Me-E? -3); 2, 3 -pentanediol (C5) P02; 2-methyl-2,3-pentanediol (C6) E? _7; 2-methyl-2,3-pentanediol (C6) PO ?; 2-methyl-2, 3-pentanediol (C6) n-BO? -2; 3-methyl-2, 3-pentanediol (C6) E? -7; 3-methyl-2, 3-pentanediol (C6) PO ?; 3-methyl-2, 3-pentanediol (C6) n-B0? .2; "4-methyl-2, 3-pentanediol (C6) E? .7; 4-methyl-, 3-pentanediol (C6) P0X; 4-methyl-2, 3-pentanediol (C6) n-B0? .2; 2, 4-pentanediol (C5) 2 (Me- E? -? 4); 2,4-pentanediol (C5) P04; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E ?? -? 4); 2, 3-dimethyl-2,4-pentanediol (C7) P02; 2,4-dimethyl-2,4-pentanediol (C7) (Me-E-14); 2,4-dimethyl-2,4-pentanediol (C7) P02; 2-methyl-2, 4-pentanediol (C7) (Me-E5, xo); 2-methyl-2,4-pentanediol (C7) P03; 3, 3-dimethyl-2,4-pentanediol (C7) (Me-E ?? 14); 3, 3-dimethyl-2,4-pentanediol (C7) P02; 3-methyl-2,4-pentanediol (C6) (Me-E5-? 0); 3-methyl-2,4-pentanediol (C6) P03; 4. 1, 3-hexanediol (C6) (Me-E? _5); 1,3-hexanediol (C6) P02; 1,3-hexanediol (C6) BOi; 2-methyl-1,3-hexanediol (C7) E2-9; 2-methyl-l, 3-hexanediol (C7) P0 ?; 2- ^ me il-1,3-hexanediol (C7) n -BO? _3; 2-methyl-l, 3-hexanediol (C7) BO; 3-methyl-l, 3-hexanediol (C7) E2-9; 3-methyl-l, 3-hexanediol (C7) P0X; 3-methyl-l, 3-hexanediol (C7) n-BO-3; 4- methyl-1,3-hexanediol (C7) E2.9; 4-methyl-l, 3-hexanediol (C7) P0X; 4-methyl-l, 3-hexanediol (C7) n-BOx-3; 5-methyl-l, 3-hexanediol CC7) E2-9; 5-methyl-l, 3-hexanediol (C7) P0 ?; 5- methyl-1,3-hexanediol (C7) n-BO? -3; 1,4-hexanediol (C6) (Me-0fE? _5); 1,4-hexanediol (C6) P02; 1,4-hexanediol (C6) B01 # 2- 2- methyl-1,4-hexanediol (C7) E2.9; 2-methyl-l, 4-hexanediol (C7) PO ?; 2-methyl-l, 4-hexanediol (C7) n-BO? _3; 2-methyl-l, 4-hexanediol (C7) E2-9; 3-methyl-l, 4-hexanediol (C7) P0?, -3-methyl-1,4-hexanediol (C7) n-BO? -3; 4-methyl-l, 4-hexanediol 5 (C7) E2-9; 4-methyl-l, -hexanediol (C7) POx; 4-methyl-l, 4-hexanediol (C7) n-BOx.3; 5-methyl-l, 4-hexanediol (C7) E2-9; 5- methyl-1,4-hexanediol (C7) PO ?; 5-methyl-l, 4-hexanediol (C7) n- BO? .3; 1,5-hexanediol (C6) (Me-E? _5); 1, 5-hexanediol (C6) P02; 1, 5-hexanediol (C6) BO ?; 2-methyl-l, 5-hexanediol (C7) E2-s; 2-0 methyl-1, 5-hexanediol (C7) PO ?; 2-methyl-l, 5-hexanediol (C7) n- BO? _3; 3-methyl-l, 5-hexanediol (C7) E2-9; 3-methyl-l, 5-hexanediol (C7) PO; 3-methyl-l, 5-hexanediol (C7) n-BO? -3; 4- methyl-l, 5-hexanediol (C7) E2_9; 4-methyl-l, 5-hexanediol (C7) PO ?; 4-methyl-l, 5-hexanediol (C7) n-BO? -3; 5-methyl-l, 5- hexanediol (C7) E2-9; 5-methyl-l, 5-hexanediol (C7) P ??; 5- methyl-1,5-hexanediol (C7) n -BO? .3; 1, 6-hexanediol (C6) (Me- ^ E? _2); 1, 6-hexanediol (C6) PO? -2; 1, 6-hexanediol (C6) n-B04; F 2-methyl-l, 6-hexanediol (C7) E? -5; 2-methyl-l, 6-hexanediol (C7) n-BO? _2; 3-methyl-1, 6-hexanediol (C7) E_-5; 3-methyl-l, 6-hexanediol (C7) n-BO? _2; 2, 3-hexanediol (C6) Ex.5; 2,3- hexanediol (C6) n-BO ?; 2,3-hexanediol (C6) BO ?; 2,4-hexanediol (C6) (Me-E3.8); 2,4-hexanediol (C6) P03; 2-methyl-2,4-hexanediol (C7) (Me-E? _2); 2-methyl-2,4-hexanediol (C7) _ PO1-2; 3-methyl-2,4-hexanediol (C7) (Me-E? _2); 3-methyl-2,4-hexanediol (C7) PO? -2; 4-methyl -2,4-hexanediol (C7) (Me-E? _2); 4-methyl-2,4-hexanediol (C7) PO? -2; 5-methyl-2,4-hexanediol (C7) (Me-E? .2); 5-methyl-2,4-hexanediol (C7) PO? -2; 2,5-hexanediol (C6) (Me-E3.8); 2,5-hexanediol (C6) P03; 2-methyl-2, 5-hexanediol (C7) (Me-E? .2); 2-methyl-2, 5-hexanediol (C7) PO1-2; 3-methyl-2, 5-hexanediol (C7) (Me-E? _2) _; 3-methyl-2,5-hexanediol (Cl) P0? -2; 3,4 hexanediol (C6) BO? .5; 3,4- hexanediol (C6) n-BO ?; 3, 4-hexanediol (C6) J30x; 5. 1,3- heptanediol (C7) E? -7; 1,3-heptanediol (C7) POi, -1,3-heptanediol (C7) n-B0? -2; 1,4-heptanediol (C7) E? _7; 1,4-heptanediol (C7) POi; 1, 4-heptanediol (C7) n-BO? _2; 1,5-heptanediol (C7) E? -7; 1,5-heptanediol (C7) POi; 1,5-heptanediol (C7) n-B0? _2; 1, 6-heptanediol (C7) E? -7; 1,6-heptanediol (C7) POi, -1,6-heptanediol (C7) n-B0? -2; 1,7- heptanediol (C7) E? -2; 1, -heptanediol (C7) n-BOi, -2,4-heptanediol (C7) E3.10; 2,4-heptanediol (C7) (Me-E?); 2,4- ^ heptanediol (C7) P0?, -2, 4-heptanediol (C7) n-B03; 2,5-heptanediol (C7) E3-? 0; 2,5-heptanediol (C7) (Me-E?); 2,5- 5 heptanediol (C7) PO ?; 2,5-heptanediol (C7) n-B03; 2,6-heptanediol (C7) E3-? 0; 2,6-heptanediol (C7) (Me-E?); 2,6-heptanediol (C7) P0?, -2,6-heptanediol (C7) n-B03; 3,5- heptanediol (C7) E3-10; 3, 5-heptanediol (C7) (Me-E?); 3,5- ^ _ heptanediol (C7) PO ?; 3, 5-heptanediol (C7) n-B03; 6. 3-0 Methyl-2-isopropyl-l, 3-butanediol (C8) POx; 2, 3, 3-trimet? L- 2, 4-pentanediol (C8) PO?, -2,2-diethyl-l, 3-butanediol (C8) E2-5; 2,3-dimethyl-2,4-hexanediol (C8) E2-5; 2,4-dimethyl-2,4-hexanediol (C8) E2-s; 2,5-dimethyl-2,4-hexanediol (C8) E2.5; 3,3-dimethyl-2,4-hexanediol (C8) E2-5; 3, 4-dimethyl-2, 4- ^ hexanediol (C8) E2-s; 3, 5-dimethyl-2,4-hexanediol (C8) E2_5; 4,5-dimethyl-2,4-hexanediol (C8) E2-5; 5, 5-dimethyl-2,4-hexanediol (C8) E2_5; 2, 3-dimethyl-2, 5-hexanediol (C8) E2-5; 2,4-dimethyl-2,5-hexanediol (C8) E2-5; 2,5-dimethyl-2, 5-hexanediol (C8) E2-5; 3, 3-dimethyl-2, 5-hexanediol (C8) E2-5; 0 3,4-dimethyl-2, 5-hexanediol (C8) E2.5; 3-methyl-3, 5-heptanediol (C8) E2-5; 2, 2-diethyl-l, 3-butanediol (C8) n-BO? .2; 2,3-dimethyl-2,4-hexanediol (C8) n-B0? _2; 2,4-dimethyl-2,4-hexanediol (C8) n-BO? -2; 2, 5-dimethyl-2,4-hexanediol C8) n- BO.2; 3,3-dimethyl-2,4-hexanediol (C8) n-BO? _2, - 3,4-dimethyl- 2, 4-hexanediol (C8) n-BO? .2, - 3, 5-dimethyl-2,4-hexanediol (C8) n-B0? -2; 4,5-dimethyl-2,4-hexanediol (C8) n-B0? .2; 5,5-dimethyl- ^, -hexanediol (C8) n -B0? .2; 2, 3-dimethyl-2, 5-hexanediol (C8) n-BO? _2; 2,4-dimethyl-2,5-hexanediol (C8) n-B0? -2; 2,5-dimethyl-2, 5-hexanediol (C8) n-B0? .2; 3, 3-dimethyl-2, 5-hexanediol (C8) n-B0? -2; 3, 4-dimethyl-2, 5-hexanediol (C8) n-B0? -2; 3-methyl-3,5-heptanediol. (C8) n -BO? .2; 2- (1, 2-dimethylpropyl) -1, 3-propanediol (C8) n -BO?, - 2-ethyl-2,3-dimethyl-l, 3-butanediol ^ (C8) n-BO ?; 2-methyl-2-isopropyl-l, 3-butanediol (C8) n-BO?, - 3-methyl-2-isopropyl-l, 4-butanediol (C8) n-B0?, - 2,2,3- trimethyl-1,3-pentanediol (C8) n-B0 ?; 2, 2, 4-trimethyl-l, 3- pentanediol (C8) n-B0?, -2,4,4-trimethyl-l, 3-pentanediol (C8) n-BOi; 3, 4, 4-trimethyl-l, 3-pentanediol (C8) n-BOi; 2,2,3-trimethyl-1,4-pentanediol (C8) n-BOi; 2, 2, 4-trimethyl-l, 4-pentanediol (C8) n-BOi; 2, 3, 3-trimethyl-l, 4-pentanediol (C8 n-BOi; 2,3,4-trimethyl-1,4-pentanediol (C8) n-BOi; 3,3,4-trimethyl-1,4) -pentanediol (C8) n-BO ?; 2, 3, 4-trimethyl-2,4-pentanediol (C8) n-BO ?; 4-ethyl-2,4-hexanediol (C8) n-BO ?; 2- methyl-2, 4-heptanediol (C8) n-B0 ?; 3-methyl-2,4-heptanediol (C8) n-BOi; 4-methyl-2,4-heptanediol (C8) n-BO ?; 5- methyl-2,4-heptanediol (C8) n-B0?, - 5-methyl-2,4-heptanediol (C8) n-BO ?; 6-methyl-2,4-heptanediol (C8) n-B0 ?; 2-methyl-2, 5-heptanediol (C8) n-B0 ?; 3-methyl-2, 5-heptanediol (C8) n-BO ?; 4-methyl-2,5-heptanediol (C8) n-BO? 5-methyl-2, 5-heptanediol (C8) n-BO ?; 6-methyl-2, 5-heptanediol (C8) n-BO ?; 6-methyl-2, 5-heptanediol (C8) n-BOi; 2-methyl-2,6-heptanediol (C8) n-BO ?; 3-methyl-2,6- _. Heptanediol (C8) n-BOx; 4-methyl-2,6-heptanediol (C8) n-BO ?; 2-methyl-3, 5-heptanediol (C8) n-BOi; 2- (1,2-dimethylpropyl) -1,3-propanediol (C8) E? _3; 2-ethyl-2, 3-dimethyl-l, 3-butanediol (C8) E? -3; 2-methyl-2-isopropyl-l, 3-butanediol (C8) E? _3; 3- methyl-2-isopropyl-1,4-butanediol (C8) E? -3; 2, 2, 3 -trimethyl-1,3-pentanediol (C8) E? -3; 2, 2, 4-trimethyl-l, 3-pentanediol (C8) E? .3; 2, 4, 4-trimethyl-l, 3-pentanediol IC8) E? -3; 3,4,4-ftrimethyl-1,3-pentanediol (C8) E? .3; 2,2,3-trimethyl-l, 4- pentanediol (C8) E? -3; 2, 2, 4-trimethyl-l, 4-pentanediol (C8) E? _3; 2, 3, 3-trimethyl-l, 4-pentanediol (C8) E? .3; 2,3,4-trimethyl-1,4-pentanediol (C8) Ex.3; 3, 3, _4-trimethyl-l, 4-pentanediol (C8) E? .3; 2, 3, 4-trimethyl-2,4-pentanediol (C8) 5 E? .3; 4-ethyl-2,4-hexanediol (C8) E? -3; 2-methyl-2,4-heptanediol (C8) E? -3; 3-methyl -2,4-heptane diol (C8) E? _3; 4-methyl-2,4-heptanediol (C8) E? -3; 5-methyl-2,4-heptanediol (C8) Ex-3; 6- methyl-2,4-heptanediol (C8) E? -3; 2-methyl-2, 5-heptanediol (C8) E1.3; 3-methyl-2,5-heptanediol (C8) E? _3; 4-methyl-2,5-0 heptanediol (C8) E? _3; 5-methyl-2, 5-heptanediol (C8) E? .3; 6- methyl-2, 5-heptanediol (C8) E? .3; 2-methyl-2,6-heptanediol (C8) E? -3; 3-methyl-2,6-heptanediol (C8) E? -3; 4-methyl-2,6-heptanediol (C8.) Ex.3; and / or 2-methyl-3,5-heptanediol (C8) E? _3; and 7. mixtures thereof; IX. Aromatic diols * - including: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol, -j 2 -phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1- (3- ^ -ethylphenyl) -1,3-propanediol; 1- (4-methylphenyl) -1,3-propanediol; 2-methyl-l-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol; 2-phenyl-1,4-butanediol; and / or 1-phenyl-2,3-butanediol; and X. Mixtures of them 2g.- The composition of claim 1 ^^ characterized further because said main solvent is - »10 Fs1 selected from the group consisting of: 2, -di-2-propenyl-1,3-propanediol; 2- (1-pentenyl) -1,3-propanediol, -2- (2-methyl-2-propenyl) -2- (2-propenyl) -1,3-propanediol; 2- (3-methyl-1-butenyl) -1,3-propanediol; 2- (4-pentenyl) -1,3-propanediol; 2-ethyl-2- (2-methyl-2-propenyl) -2- (2-propenyl) -1,3- 1 ^ ". propanediol; 2-ethyl-2- (2-propenyl) -1,3-propanediol; 2-methyl-2- (3-methyl-3-butenyl) -1,3-propanediol; 2, 2-diallyl-1, 3-butanediol; 2- (1-ethyl-1-propenyl) -1,3-butanediol; 2- (2-butenyl) -2-methyl-1,3-butane-diol; 2- (3-methyl-2-butenyl) -1,3-butanediol; 2-ethyl-2- (2-propenyl) -1, 3-butanediol; 2-methyl-2- (l-methyl-2-propenyl) -1, 3-butanediol; 2,3-bis (l-methylethylidene) -1,4-butanediol; 2- (3-methyl-2-butenyl) -3-methylene-1,4-butanediol; 2- (1,1-dimethylpropyl) -2-butene-1, 4-diol; 2- (1-methylpropyl) -2-butene-1,4-diol; 2-butyl-2-butene-1,4-diol; 2-ethenyl-3-ethyl-l, 3-pentanediol; 2-ethenyl-4,4- dimethyl-1,3-pentanediol; (3-methyl-2- (2-propenyl) -1,4-pentanediol; 2- (1-propenyl) -1,5-pentanediol; 2- (2-propenyl) -1,5-pentanediol; 2-ethylidene; 3-methyl-1, 5-pentanediol, 2-propylidene-1,5-pentanediol, 3-ethylidene-2,4-dimethyl-2,4- pentanediol, 2- (1,1-dimethylethyl) -4- pentene-1, 3-diol, 2-ethyl-2, 3-dimethyl--pentene-1,3-diol, 4-ethyl-2-methylene-1,4-hexanediol, 2, 3, 5-trimethyl-1 , 5-hexadiene-3,4-diol, 5-ethyl-3-methyl-1,5-hexadiene-3,4-diol, 2- (1-methylethyl) -1,5-hexanediol, 2-ethenyl-1 6-hexanediol; 5,5-dimethyl-l-hexene-ltr 3,4-diol; 4-ethenyl-2, 5-dimethyl-2-hexene-1,5-diol; 2-ethenyl-2, 5 - dimethyl-3-hexene-1,6-diol; 2-ethyl-3-hexene-1, 6-diol; 3,4-dimethyl-3-hexen-1, 6-diol; 2,5-dimethyl- 4 -hexene-2, 3- diol, 3,4-dimethyl-4-hexene-2,3-diol, 3- (2-propenyl) -5-hexene-2,3-diol, 2,3-dimethyl- 5-hexene-2,3-diol; 3,4-dimethyl-15-hexene-2,3-diol; 3,5-dimethyl-5-hexene-2,3-diol; 3-ethenyl-2, 5 -dimethyl-5-hexene-2,4-diol; 6-methyl-5-methylene-l, 4-heptanediol; 2,3-dimethyl l-1, 5-heptadiene-3,4-diol, -2,5-dimethyl-1,5-heptadiene-3,4-diol; 3,5-dimethyl-l, 5-heptadiene-3,4-diol; 2,6-bis (methylene) -1,7-heptanediol; 4-methylene-l, 7- 20 heptanediol; 2,4-dimethyl-l-heptene-3,5-diol; 2,6-dimethyl-l-heptene-3,5-diol; 3-ethenyl-5-methyl-1-heptene-3, 5-diol; 6,6-dimethyl-1-heptene-3,5-diol; 4,6-dimethyl-2,4-heptadiene-2,6-diol; 4,4-dimethyl-2,5-heptadiene-1, 7-diol; 2, 5, 5-trimethyl-2,6-heptadien-1,4-diol; 5, 6-dimethyl-2-heptene-2,6-diol; 5- ethyl-2-heptene-l, 5-diol; 2-methyl-2-hepten-1, 7-diol; 4,6-dimethyl-3-heptene-1,5-diol; 3-methyl-6-methoxy-3-heptene -1,7-diol; 2,4-dimethyl-3-heptene-2,5-diol; 2,5-dimethyl-3-heptene-2,5-diol; 2,6-dimethyl-3-heptene-2,6-diol; 4,6-dimethyl-3-heptene-2,6-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3, 6-dimethyl-5-heptene-1, -diol; 2, 3-dimethyl-5-heptene-2,4-diol; 2, 2-dimethyl-6-heptene-1,3-diol; 4- (2-propenyl) -6-heptene-1,4-diol; 5,6-dimethyl-6-heptene-1,4-diol; 2,4-dimethyl-6-heptene-1,5-diol; 2-ethylidene-6-methyl-6-heptene-1,5-diol; 4- (2-propenyl) -6-heptene-2,4-diol; 5, 5-dimethyl-6-heptene-2,4-diol; 4,6-dimethyl-6-heptene-2,5-diol; 5-ethenyl-4-methyl-6-heptene-2,5-diol; 2-methylene-1,3-octanediol; 2,6-dimethyl-1,6-octadiene-3,5-diol; 3, 7-dimethyl-l, 6-octadiene-3,5-diol; 2,6-dimethyl-l, 7-octadiene-3,6-diol; 2,7-dimethyl-l, 7-octadiene-3,6-diol; 3,6-dimethyl-l, 7-octadiene-3,6-diol; 3-ethenyl-1-octene-3,6-diol; 2,7-dimethyl-2,4,6-octatriene-1,8-diol; 3,7-dimethyl-2,4-octadiene-l, 7-diol; 2,6-dimethyl-2,5-octadiene-l, 7-diol; 3, 7-dimethyl-2-, 5-octadiene-l, 7-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-l, 8-diol; 3, 7-dimethyl-2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-l, 5-diol; "2,6-dimethyl-2,7-octadiene-1,6-diol (8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6-diol; 2-octene-1, 4- diol, 2-octene-l, 7-diol, 2-methyl-6-methylene-2-ketene-1,7-diol, 3,7-dimethyl-3, 5- octadiene-1, 7-diol; 2,7-dimethyl-3, S-octadiene-1,7-diol; 4-methylene-3,5-octanediol; 2,6-dimethyl-3,7-octadiene-l, 6-diol; ^, 7-dimethyl-3,7-octanedien-2,5-diol; 2,6-dimethyl-3,7-octadiene-2,6-diol; 4-methyl-3-octene-1, 5-diol; 5-methyl-3- 5 octene-1,5-diol; 2, -dimethyl-4,6-octadiene-l, 3-diol; 2,6-dimethyl-4,7-octadiene-2,3-diol; 2,6-dimethyl-4,7-octadiene-2,6-diol; 7-methyl-4-octene-1, 6-diol; 2-methylene-2,7-bis (methylene); 2,7-dimethyl-5,7-octadiene-1,4-diol; 7-methyl- -5,7-octadiene-1,4-diol: 5-octene-1,3-diol; 7-methyl-6-octene-0 1,3-diol; 7-methyl-6-octene-1,4-diol; 6-octene-1, 5-diol; 7- methyl-6-octene-l, 5-diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol; 2-methyl-7-octene-l, 3-diol; 4-methyl-7-octene-l, 3-diol; 7-methyl-7-octene-l, 3-diol; 7-octene-l, 5-diol; 7-octene-1, 6-diol; 5-methyl-7-octene-1, 6-diol; 2-methyl-1, 6-methylene-7-octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2- methyl-7-octene-3,5-diol; l-nonene-3, 5-diol; l-nonene-3, 7-diol; 3-nonene-2, 5-diol; 8-methyl-4,6-nonadiene-1,3-diol; 4- noneno-2, 8-diol; 6-nonadiene-1, 5-diol; 7-nonene-2,4-diol; 8-noneno-2,4-diol; 8-nonene-2,5-diol; 1, 9-decadiene-3,8-diol; 0 1, -decadiene-4, 6-diol; and mixtures thereof; The composition of claim 1 further characterized in that said main solvent is selected from the group consisting of: 2,2-diallyl-1,3-butanediol; 2- (1-ethyl-1-propenyl) -1,3-butanediol; 2- (2- butenyl) -2-methyl-l, 3-butanediol; 2- (3-methyl-2-butenyl) -1, 3-butanediol; 2-ethyl-2- (2-propenyl) -1,3-butanediol; 2-methyl-2- ^ 1-methyl-2-propenyl) -1,3-butanediol; 2, 3-bis (1-methylethylidene) -1,4-butanediol; 2-ethenyl-3-ethyl-l, 3-pentanediol; 2-ethenyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2- (2-propenyl) -1,4-pentanediol; 2- (1,1-dimethylethyl) -4-pentene-1,3-diol; 2-ethyl-2, 3-dimethyl-4-pentene-l, 3-diol; 4-ethyl-2-methylene-1,4-hexanediol; 2,3,5-trimethyl-l, 5-hexadiene-3,4-diol; 2- (1-methylethhenyl) -1,5-hexanediol; 4- etenyl-2, 5-dimethyl-2-hexene-1, 5-diol; 6-methyl-5-methylene-1,4-heptanediol; 4,6-dimethyl-2,4-heptadiene-2,6-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-dimethyl-2-heptene-1, 4-diol; 4,6-dimethyl-3-heptene-1,5-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3, 6-dimethyl-5-heptene-1,3-diol; 2,6-dimethyl-5-heptene-1,4-diol; 3, 6-dimethyl-5-heptene-1,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 5,6-dimethyl-6-heptene-1,4-diol; 2,4-dimethyl-6-heptene-1,5-iol; 2-ethylidene-6-methyl-6-heptene-1,5-diol; 4- (2-propenyl) -6-heptene-2,4-diol; 3- ethenyl-l-octene-3,6-diol; 2, 7-dimethyl-2,4,6,6-octariene-1, 8-diol; 2,6-dimethyl-2,5-octadiene-l, 7-diol; 3,7-dimethyl-2, 5-octadiene-1,7-diol; 3, 7-dimethyl-2, 6-octadiene-1,4-diol (Rosiridol), 2-methyl-2,6-octadiene-1, 8-diol; 3,7-dimethyl-2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-l, 5-diol; 2,6-dimethyl-2,7-octadiene-l, 6-diol (8-hydroxylinalool); 2,7- dimethyl-2,7-octadiene-l, 6-diol; 2-methyl-6-methylene-2-octene-1,7-diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene- ^^ 3,5-octanediol; 2,6-dimethyl-3,7-octadiene-l, 6-diol; 2- methylene-4-octene-l, 8-diol; 2-methyl-6-octene-3,5-diol; 4-5-methyl-6-octene-3,5-diol; 2-methyl-6-methylene-7-octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; l-nonene-3,5-diol; l-nonene-3, 7-diol; 3-nonene-2, 5-diol; 6, 8-nonadieno-l, 5-diol; 7-nonene-2,4-diol; 8-nonene-2, 4- ^ diol; 8-nonene-2,5-diol; 1, 9-decadiene-3y 8-diol; 1.9-10 decadiene-4,6-diol; and mixtures thereof; 31. The composition of claim 1 further characterized in that the softening active ingredient contains up to about 20% monoester compound in which m is 2 and a YR1 is -OH, -N (R) H, or -C (0) ) OH- 32.- The composition of claim 1 further characterized in that at low water levels of about 5% to 15%, the ratio of weight active ingredient softener to principal solvent is about 55:45 to 85:15; at water levels of about 15% to 70%, the 20 weight ratio active ingredient softener to main solvent is around 45:55 to 70:30; and at high water levels of about 70% to 80%, the ratio of weight active ingredient softener to main solvent is around 30:70 to 55:45. 33. - The composition of claim 32 further characterized in that at low water levels of 5% to 15%, the weight ratio of active ingredient softener to principal solvent is about 60:40 to 5 80:20; at water levels of about 15% to 70%, the ratio of weight active ingredient softener to main solvent is around 55:45 to 70:30; and at high water levels of about 70% to 80%, the ratio of weight m active ingredient softener to principal solvent is 0 from around 35:65 to 45:55. 34. The composition of claim 1, which is translucent or transparent at 25 ° C, which contains solvents other than the main solvent B, the main solvent amount B being at least about 5% by weight of the composition. , wherein the composition is not translucent or transparent at 25 ° C in the absence of the principal solvent B. 35.- The composition of claim 1 which contains one, or more, of the following optional ingredients: (a) brightener at a level from about 0.005% 0 to 5%; (b) dispersibility aid at a level of about 2% to 25%; (c) soil removal agent at a level of from 0% to about 10%; (d) foam dispersant at a level of about 2% to 10%; (e) stabilizer selected from the group consisting of antioxidant, reducing agent, chelator, and mixtures thereof, at a level of 0% to about 2%; (f) bactericidal at a level of about 0.005% to 5%; and (g) __ chelating agent in addition to any chelator in (e), at a level of about 0.5% to 10%. 36. A premix of the components of claim 1 consisting essentially of: said biodegradable fabric softener active ingredient A; principal solvent B; and optionally, said water soluble solvent C. 37. The composition of claim 1 further characterized in that the level of perfume is from about 0.1% to 8%. 38.- The composition of claim 37 further characterized because the level of perfume is from about 0.29% to 5%. 39.- A stable, transparent, aqueous fabric softening composition that contains: A. From about 2% to 80% softening active ingredient containing at least 2 hydrocarbyl groups of 6 to 22 carbon atoms., But no more one is less than 12 carbon atoms and then the other is at least 16 carbon atoms, the groups having a VI of about 70 to 140, or branched; and B. Less than about 40% by weight of the composition of the main solvent has a ClogP of about 0.15 to 0.64, and at least some degree of asymmetry, said main solvent contains insufficient amounts of solvents selected from the group consisting of 2, 2, 4-trimethyl-1,3-pentanediol; ethoxylated, diethoxylated or triethoxylated derivatives of 2,2,4-trimethyl-1,3-pentanediol, - and / or 2-ethylhexyl-1,3-diol, to provide a stable aqueous composition by themselves, said solvent being sufficient main to make the compositions transparent. 40. An article of manufacture comprising the composition of claim 1 in a clear bottle. 41. The article of claim 40 further characterized in that the bottle has a slightly blue tint, sufficient to compensate for any slightly yellow color of the composition. 42. The article of claim 41 further characterized in that the bottle has an ultraviolet light filter incorporated in the wall of the bottle to protect the composition. 43. - A composition according to claim 1 further characterized in that said main solvent B is present in an effective amount, but less than the amount required to obtain stability and the composition becomes stable by the addition of another solvent that is inoperable by itself to obtain stability. 44. The process for making a transparent fabric softening composition using the premix of claim 36 and adding said premix to a water seat containing water, acid to create a pH of about 1.5 to 5; and, optionally, an effective amount of water soluble calcium and / or magnesium salt. F SUMMARY OF THEINVENTION The main solvents, especially monool and diol main solvents, having a ClogP of about 0.15 to about 0.64, preferably about 0.25 to about 0.62, and more preferably about 0.40 to about 0.60, which have the capacity are described. of making clear aqueous fabric softening compositions containing relatively high concentrations of fabric softening active agents having hydrocarbon portions or highly unsaturated branched chains in two long chain hydrophobic groups with specific cis / trans ratios and having long chain hydrocarbon groups with an IV of around 70 to about 140 for the unsaturated groups corresponding to fatty acids with the same number of carbons and the same configuration, and said main solvents are used at levels of less than about 40%, - the softening active agents of fabrics are preferably prepared in p resistence of chelating agent and / or antioxidant, as described herein; said materials are new; other solvents may be present; the premixes of the fabric softening active agents, the major solvents and optionally other solvents, are useful in the preparation of complete formulations eliminating / limiting the need to apply heating. » fifteen CR / cgt * P99 / 538F
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60/028904 | 1996-10-21 | ||
US028904 | 1996-10-21 |
Publications (1)
Publication Number | Publication Date |
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MXPA99003721A true MXPA99003721A (en) | 1999-10-14 |
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