MXPA98008676A - Soluble grease vitamin emulsions, suitable for spraying on food - Google Patents
Soluble grease vitamin emulsions, suitable for spraying on foodInfo
- Publication number
- MXPA98008676A MXPA98008676A MXPA/A/1998/008676A MX9808676A MXPA98008676A MX PA98008676 A MXPA98008676 A MX PA98008676A MX 9808676 A MX9808676 A MX 9808676A MX PA98008676 A MXPA98008676 A MX PA98008676A
- Authority
- MX
- Mexico
- Prior art keywords
- vitamin
- spraying
- fat
- soluble
- gelatin
- Prior art date
Links
- 235000013343 vitamin Nutrition 0.000 title claims abstract description 50
- 239000011782 vitamin Substances 0.000 title claims abstract description 50
- 229930003231 vitamins Natural products 0.000 title claims abstract description 50
- 239000000839 emulsion Substances 0.000 title claims abstract description 23
- 238000005507 spraying Methods 0.000 title claims description 17
- 235000013305 food Nutrition 0.000 title abstract description 10
- 229940088594 Vitamin Drugs 0.000 title description 27
- 150000003722 vitamin derivatives Chemical class 0.000 title description 27
- 239000004519 grease Substances 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 229940029983 VITAMINS Drugs 0.000 claims abstract description 23
- 229940021016 Vitamin IV solution additives Drugs 0.000 claims abstract description 23
- 229920000159 gelatin Polymers 0.000 claims description 18
- 235000019322 gelatine Nutrition 0.000 claims description 18
- 108010010803 Gelatin Proteins 0.000 claims description 17
- 235000011852 gelatine desserts Nutrition 0.000 claims description 17
- 239000008273 gelatin Substances 0.000 claims description 16
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Vitamin C Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- 229960005070 ascorbic acid Drugs 0.000 claims description 10
- 229960005055 SODIUM ASCORBATE Drugs 0.000 claims description 9
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 claims description 9
- 235000010378 sodium ascorbate Nutrition 0.000 claims description 9
- 235000015496 breakfast cereal Nutrition 0.000 abstract description 4
- 239000000969 carrier Substances 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229960002747 Betacarotene Drugs 0.000 description 4
- OENHQHLEOONYIE-VYAWBVGESA-N beta-Carotene Natural products CC=1CCCC(C)(C)C=1\C=C\C(\C)=C/C=C/C(/C)=C\C=C\C=C(\C)/C=C/C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-VYAWBVGESA-N 0.000 description 4
- 235000013734 beta-carotene Nutrition 0.000 description 4
- 239000011648 beta-carotene Substances 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N Simethicone Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 235000019688 fish Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 2
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- LKUNXBRZDFMZOK-UHFFFAOYSA-N 1-monocaprylglycerol Chemical compound CCCCCCCCCC(=O)OCC(O)CO LKUNXBRZDFMZOK-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- BVDRUCCQKHGCRX-UHFFFAOYSA-N 2,3-dihydroxypropyl formate Chemical compound OCC(O)COC=O BVDRUCCQKHGCRX-UHFFFAOYSA-N 0.000 description 1
- YJISHJVIRFPGGN-UHFFFAOYSA-N 5-[5-[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxy-6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical class O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 YJISHJVIRFPGGN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 229940067606 Lecithin Drugs 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 210000004080 Milk Anatomy 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000828 canola oil Substances 0.000 description 1
- 235000019519 canola oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019545 cooked cereal Nutrition 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000005824 corn Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229940080812 glyceryl caprate Drugs 0.000 description 1
- 235000011868 grain product Nutrition 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 235000010935 mono and diglycerides of fatty acids Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-M stearate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O QIQXTHQIDYTFRH-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000699 topical Effects 0.000 description 1
Abstract
The present invention relates to an emulsion composition of fat-soluble non-flavored vitamins, which can be sprayed onto food at room temperature, particularly in breakfast cereals, ready to be eaten for the purpose of fortifying with vitamins to foodstuffs.
Description
SOLUBLE GREASE VITAMIN EMULSIONS, SUITABLE FOR SPRAYING ON FOODS
FIELD OF THE INVENTION The present invention relates to the emulsion composition of fat-soluble, flavorless vitamins that can be sprayed onto food, particularly ready-to-eat breakfast cereals, for purposes of vitamin fortification of foods.
Background Vitamin fortification of foods is a common practice in the food industry. The manufacturers of ready-to-eat cereals (LPC) are especially interested in the vitamin fortification of their products. See, "Breakfast Cereals And How They Are Made," edited by R.B. Fast and E.F. Caldwell, chapter 7, pages 197-209 and chapter 10, pages 275-277 that describe the importance of vitamin fortification and the sprinkling of vitamin as fortification methods vitamins. In addition, US-3, 558, 323 of Hoffmann-LaRoche
(US '323) describes a vitamin composition suitable for fortifying complete fluid milk and skimmed dry skimmed milk. The composition comprises: (a) 47 to 92% of a gelatin product of a reaction (ie, modified) prepared by reacting gelatin, ascorbic acid and sorbitol, (b) from 5 to 15% of an edible saturated oil as be coconut oil; and (c) 5 to 50% of a fat-soluble vitamin. US '323 discloses that the gelatin used to form the reacted (ie modified) gelatin is type A or B. The modified gelatin product is not a real gelatin, it is a polypeptide material having essentially zero flavor and a molecular weight of 1200 at 2500 and a viscosity of 5 to 10 millipoises. Vitamin fortification is also achieved by incorporating the vitamin in the cereal. Specifically, US 5,368,870 (General Mills) states that topical application of the vitamin often results in a substantial chemical and physical loss of the vitamins and also gives off flavors. US x870 describes a method for incorporating beta-carotene into a cooked cereal dough prior to the formation of the pieces. US 5,270,063 (Kellogg) describes the incorporation of beta-carotene into cereal products in the form of small droplets insoluble in water. Beta carotene is encapsulated in gelatin to form small droplets. These small droplets are then added to the initial material of the bulk cereal during the cooking process or when the process is complete. It is evident that there is a need in the art for a vitamin composition that can be sprayed onto foods at room temperature, which does not exhibit stability and flavor problems associated with the prior art. Applicants have surprisingly discovered a water-soluble vitamin emulsion that is stable and taste-free.
Compendium An emulsion composition of a fat-soluble vitamin, which can be applied by spraying consists of: (a) from 1 to 20% of a mixture of fat-soluble vitamins (b) from 2 to 6% in gelatin (c) from 15 to 45% sodium ascorbate.
DETAILED DESCRIPTION An emulsion composition of a fat-soluble vitamin, which can be applied by spraying, consists of: (a) from 1 to 20% of a mixture of fat-soluble vitamins (b) from 2 to 6% in gelatine (c) from 15 to 45% sodium ascorbate.
Preparation of the emulsion of fat-soluble vitamins, which can be applied by spraying, of the present invention. The vitamin emulsion which can be applied by spraying is prepared according to the methods known to those skilled in the art, by combining elements (a), (b), and (c) in H20. Specifically, the gelatin is dissolved in water at 40 ° C with vigorous mixing. The mixture of fat-soluble vitamins and sodium ascorbate are added as cold dissolved gelatin at room temperature while still being aspersible.
Element (a) Mixture of fat-soluble vitamins The fat-soluble vitamin mixture contains fat-soluble vitamins, carriers of vegetable oils and emulsifiers. Fat-soluble vitamins are selected from A, beta-carotene, D, E, and K. These vitamins are available in concentrated form from BASF Corporation, Mt. Olive, NJ. The preferred fat-soluble vitamins are A, D and E. 10-70% of the concentrated vitamin is mixed with 0-30% of the carrier vegetable oil to prepare a vitamin / carrier mixture suitable for use in an emulsion that can be applied by sprinkling. Suitable vegetable oil carriers include, but are not limited to, corn oil, cottonseed oil, peanut oil, soybean oils, canola oil, palm or coconut oil. The vitamin / carrier mixture is then combined with emulsifiers. These emulsifiers include, but are not limited to propylene glycol, mono and diglycerides, mono oleates, dimethyl polysiloxane (substantially free of hydrolysable chloride and alkoxy groups), emulsifiers and defoamers, polyethylene glycol, polyoxyethylene 40 mono stearate, propylene glycol alginate, silicon dioxide and sorbitan mono stearate, glyceryl caprate, glyceryl oleate, hydrogenated cottonseed glyceride, mono and diglycerides of fatty acids, polyethylene glycol, propylene glycol and lecithin. Preferred emulsifiers are propylene glycol and mono and diglycerides. Specifically, the fat-soluble vitamin mixture is prepared by mixing 40 to 70% of the vitamin / carrier mixture with 30 to 60% of the emulsifiers. Preferably, 50 to 60% of the vitamin / carrier mixture is combined with 40 to 50% emulsifiers, and more preferably 55 to 60% of the vitamin / carrier mixture is combined with 40 to 45% emulsifiers to prepare mixtures of fat-soluble vitamins. Finally, the mixture of fat-soluble vitamins prepared as described above is present in an emulsion which can be applied by spraying at a concentration of 1 to 20%, preferably 5 to 15%, and more preferably at a concentration of 5 as 10%.
Element (b) Gelatin Gelatin useful in the practice of the present invention, includes, but is not limited to, type A and B gelatins, gelatin of all animals, including pork, beef and fish. The preferred gelatin is obtained from fish. The gelatin is present in the emulsion which can be applied by spraying at a concentration of 2 to 6%, preferably 2 to 3%, and more preferably at a concentration of 2.5 to 3.0%.
Element (c) Sodium ascorbate Sodium ascorbate useful in the practice of the present invention is available from BASF Corporation, Mt.
Olive, NJ. Sodium ascorbate is present in the emulsion that can be applied by spraying at a concentration of 15 to
45%, preferably 25 to 40% and more preferably at a concentration of 30 to 38%. Elements (a), (b), and (c) are optionally combined with water-soluble starch and food-grade defoamers. Water soluble starch useful in the practice of the present invention includes, but is not limited to, modified food starch, preferably obtained from corn. The starch is present in emulsion at a concentration of 0.5 to 5%, preferably 1 to 4%, and more preferably at a concentration of 3 to 4%. Food grade defoamers useful in the practice of the present invention include, but are not limited to, silicone-based defoamers, dimethyl polysiloxane (substantially free of hydrolysable chloride and alkoxy groups), polyethylene glycol, polyoxyethylene monostearate 40, propylene glycol alginate, silicon dioxide and sorbitan mono stearate. Preferred defoamers are Dow Corning's polydi-ethylsiloxane / silica blends. The defoaming agent is present in the emulsion which can be applied by spraying at a concentration of 0 to 0.1%, preferably from 0 to 0.05%, and more preferably at a concentration of 0.02 to 0.03%. The present invention is illustrated by the following non-limiting examples:
Example 1 - Formulation in emulsion that can be applied by spraying.
Example 2 - Emulsion formulation that can be applied by spraying.
Example 3 - Emulsion formulation that can be applied by spraying
Example 4 - Emulsions that can be applied by spraying, preferred
The emulsion is sprayed onto food, particularly cereal, according to methods known to those skilled in the art, for example, see, "Breakfast Cereals and How They Are Made," edited by R.B. fast and E.F. Caldwell, chapter 7, pages 197-209 and chapter 10, pages 275-277 that describe the importance of vitamin fortification and the vitamins that can be applied by sprinkling as a method of vitamin fortification.
Claims (1)
- CLAIMS An emulsion composition of fat-soluble vitamins, which can be applied by spraying consists of: (a) from 1 to 20% of a mixture of fat-soluble vitamins (b) from 2 to 6% gelatin (c) from 15 to 45% sodium ascorbate. An emulsion composition of fat-soluble vitamins, which can be applied by spraying consists of: (a) from 5 to 15% of a mixture of fat-soluble vitamins (b) from 2 to 3% gelatin (c) from 25 to 40% sodium ascorbate. An emulsion composition of fat-soluble vitamins, which can be applied by spraying consists of: (a) from 5 to 10% of a mixture of fat-soluble vitamins (b) from 2.5 to 3% gelatin (c) from 30 to 38% sodium ascorbate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08956866 | 1997-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA98008676A true MXPA98008676A (en) | 1999-09-01 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3176934B2 (en) | Water-dispersible formulations containing hydrophobic natural pigments, their production and use | |
| Igoe | Dictionary of food ingredients | |
| US4390550A (en) | Intermediate mositure frozen foods | |
| Gordon et al. | Carotenoids as food colorants | |
| US4234611A (en) | Soft intermediate-moisture frozen puddings and fillings | |
| AU602106B2 (en) | Butter flavored granules | |
| EP1545248B2 (en) | Interface stabilisation of a product with 2 or more phases with a protein-polysaccharide complex | |
| EP1562437B1 (en) | Particulate creamer comprising fat and food compositions comprising said creamer | |
| AU2006269568A1 (en) | Food articles with delivery devices and methods for the preparation thereof | |
| JP2002501386A (en) | Storage stable complete food premix | |
| US3617309A (en) | Puffed food product and method of producing | |
| CA2216531C (en) | Sauce base composition | |
| CA2248748C (en) | Fat soluble vitamin emulsions suitable for spraying onto foodstuffs | |
| Holownia et al. | Tocopherol losses in peanut oil during pressure frying of marinated chicken strips coated with edible films | |
| JPH10248487A (en) | Fat composition for batter liquid and batter liquid for fried food | |
| Bauernfeind et al. | Nutrification of foods with added vitamin A | |
| MXPA98008676A (en) | Soluble grease vitamin emulsions, suitable for spraying on food | |
| WO2001028350A1 (en) | Low density marshmallow-like products and methods of producing the same | |
| KR100712017B1 (en) | Food additive | |
| Smith | Food demands of the emerging consumer: the role of modern food technology in meeting that challenge | |
| JPH08173074A (en) | Batter liquid for fried food | |
| JP2004097113A (en) | Fat-soluble vitamins-containing food and drink product, and method for stabilizing fat-soluble vitamins | |
| AU672640B2 (en) | Flavoured low fat food products | |
| JP2022180342A (en) | gelatin composition | |
| CA1101265A (en) | Method of manufacture of a butter spread |