MXPA98006691A - Spread composition that comprises silicone pirogen - Google Patents
Spread composition that comprises silicone pirogenInfo
- Publication number
- MXPA98006691A MXPA98006691A MXPA/A/1998/006691A MX9806691A MXPA98006691A MX PA98006691 A MXPA98006691 A MX PA98006691A MX 9806691 A MX9806691 A MX 9806691A MX PA98006691 A MXPA98006691 A MX PA98006691A
- Authority
- MX
- Mexico
- Prior art keywords
- composition according
- alkyl ether
- polysaccharide
- composition
- gum
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 92
- 229920001296 polysiloxane Polymers 0.000 title description 7
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 39
- 150000004676 glycans Polymers 0.000 claims abstract description 25
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 25
- 239000005017 polysaccharide Substances 0.000 claims abstract description 25
- 150000004804 polysaccharides Polymers 0.000 claims abstract description 25
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000012074 organic phase Substances 0.000 claims abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 69
- 239000003921 oil Substances 0.000 claims description 24
- 239000000377 silicon dioxide Substances 0.000 claims description 23
- 239000002537 cosmetic Substances 0.000 claims description 14
- 230000002209 hydrophobic Effects 0.000 claims description 11
- 102000011782 Keratins Human genes 0.000 claims description 10
- 108010076876 Keratins Proteins 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 9
- 239000000665 guar gum Substances 0.000 claims description 9
- 235000010417 guar gum Nutrition 0.000 claims description 9
- 229960002154 guar gum Drugs 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 229920000591 gum Polymers 0.000 claims description 7
- 238000006467 substitution reaction Methods 0.000 claims description 7
- GZCGUPFRVQAUEE-KCDKBNATSA-N D-(+)-Galactose Natural products OC[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-KCDKBNATSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- WQZGKKKJIJFFOK-PHYPRBDBSA-N α-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 claims description 6
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 4
- 230000000295 complement Effects 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 4
- 229920000569 Gum karaya Polymers 0.000 claims description 3
- 229940039371 Karaya Gum Drugs 0.000 claims description 3
- 229920000161 Locust bean gum Polymers 0.000 claims description 3
- PNNNRSAQSRJVSB-BXKVDMCESA-N Rhamnose Chemical compound C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-BXKVDMCESA-N 0.000 claims description 3
- 241000934878 Sterculia Species 0.000 claims description 3
- 125000000089 arabinosyl group Chemical class C1([C@@H](O)[C@H](O)[C@H](O)CO1)* 0.000 claims description 3
- 239000000231 karaya gum Substances 0.000 claims description 3
- 235000010494 karaya gum Nutrition 0.000 claims description 3
- 239000000711 locust bean gum Substances 0.000 claims description 3
- 235000010420 locust bean gum Nutrition 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 230000001698 pyrogenic Effects 0.000 claims description 3
- OMDQUFIYNPYJFM-XKDAHURESA-N (2R,3R,4S,5R,6S)-2-(hydroxymethyl)-6-[[(2R,3S,4R,5S,6R)-4,5,6-trihydroxy-3-[(2S,3S,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N D-Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 229920000926 Galactomannan Polymers 0.000 claims description 2
- 229940029983 VITAMINS Drugs 0.000 claims description 2
- 229940021016 Vitamin IV solution additives Drugs 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 230000000111 anti-oxidant Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 150000002243 furanoses Chemical class 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 230000002335 preservative Effects 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000011782 vitamin Substances 0.000 claims description 2
- 235000013343 vitamin Nutrition 0.000 claims description 2
- 229930003231 vitamins Natural products 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N β-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 2
- 229920000570 polyether Polymers 0.000 abstract description 2
- 235000019198 oils Nutrition 0.000 description 21
- 210000000088 Lip Anatomy 0.000 description 13
- -1 dimethylsilyloxyl Chemical group 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910002012 Aerosil® Inorganic materials 0.000 description 9
- 210000000282 Nails Anatomy 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000005372 silanol group Chemical group 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N Benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 240000005497 Cyamopsis tetragonoloba Species 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N Decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N Dodecanol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 210000000744 Eyelids Anatomy 0.000 description 2
- 210000004209 Hair Anatomy 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N Isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N Methyl acetate Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 210000004400 Mucous Membrane Anatomy 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- 125000002306 tributylsilyl group Chemical group C(CCC)[Si](CCCC)(CCCC)* 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N 1,5-Pentanediol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2,6-dimethylheptan-4-one Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-Butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-Methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methylpentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 1
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 1
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 229910002017 Aerosil® 255 Inorganic materials 0.000 description 1
- 229910002019 Aerosil® 380 Inorganic materials 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 210000003467 Cheek Anatomy 0.000 description 1
- 240000009226 Corylus americana Species 0.000 description 1
- 235000001543 Corylus americana Nutrition 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- AEMOLEFTQBMNLQ-YMDCURPLSA-N D-Galacturonic acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-YMDCURPLSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N Diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 210000004709 Eyebrows Anatomy 0.000 description 1
- 210000000720 Eyelashes Anatomy 0.000 description 1
- 210000001061 Forehead Anatomy 0.000 description 1
- 240000007842 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000006669 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- MLFHJEHSLIIPHL-UHFFFAOYSA-N Isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229940039717 Lanolin Drugs 0.000 description 1
- 241000208467 Macadamia Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- 210000004080 Milk Anatomy 0.000 description 1
- 229940057874 PHENYL TRIMETHICONE Drugs 0.000 description 1
- 239000004698 Polyethylene (PE) Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N Propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N Propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 240000005204 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 240000003670 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 244000044822 Simmondsia californica Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940095076 benzaldehyde Drugs 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M caproate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000005824 corn Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- YXLIPLQEUAJSCY-UHFFFAOYSA-N cyclohexane;dodecane Chemical compound C1CCCCC1.CCCCCCCCCCCC YXLIPLQEUAJSCY-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XYQREBYZFVVGCJ-UHFFFAOYSA-N icosan-10-ol Chemical compound CCCCCCCCCCC(O)CCCCCCCCC XYQREBYZFVVGCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N n-heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N oxo-oxoalumanyloxy-[oxo(oxoalumanyloxy)silyl]oxysilane;dihydrate Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000009666 routine test Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000000699 topical Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Abstract
The invention relates to a thickened composition containing pyrogenic silica and a polysaccharide alkyl ether formed of units comprising at least two different osidic rings each unit comprising at least one hydroxyl group substituted by a saturated hydrocarbon alkyl chain. The invention also relates to the use of a pyrogenic silica and polysaccharide alkyl ether as a thickening agent in a composition comprising an organic phase comprising at least one solvent medium of polyether alkyl ether.
Description
Thick Composition Comprising Pirogenated Silica
DESCRIPTION OF THE INVENTION
The invention relates to a thick composition containing pyrogenic silica associated with a new thickener, intended in particular for the cosmetic and / or dermatological fields. The invention also relates to a use of this composition for the treatment of keratin materials such as the skin, nails, eyelashes, eyebrows, hair or mucous membranes such as the lips and the inside of the eyelids. In cosmetic and dermatological compositions, it is common to thicken non-aqueous phases to obtain the desired consistency. The thick compositions make it easier to take the product out of its packaging without significant loss, limit the diffusion of the product to the local treatment area, distribute the product regularly over the local treatment area or even use the product in quantities enough to obtain the desired cosmetic or dermatological effect. REP. 27961 This thickening is essential for compositions such as those for treatment, hygiene or make-up products, such as lipsticks that must be distributed evenly over the local surface to be treated, as well as for the hair compositions that must be extended and Distribute regularly along the keratin fibers and do not drip on the forehead, nape, face or in the eyes. To thicken the compositions, it is known to add fumed silica as a thickening agent (see application FR-A-1453089). When you want to prepare sufficiently thick compositions, it is necessary to add a significant amount of pyrogenic silica. This is mainly the case when it is desired to thicken a composition comprising a polar medium such as for example ethyl acetate, ethanol or oils of vegetable origin. However, the addition of a significant amount of this thickener alters the cosmetic properties of the composition: in fact the composition becomes less comfortable during application and in the course of time after application. This is mainly the case for a red lipstick where the red film is not comfortable to wear on the lips and causes a feeling of tightness.
In addition, the composition tends to resect the lips and to present an unsatisfactory coverage. It is also known to associate other thickening agent with fumed silica. For example, US-A-5071639 discloses a nail polish composition comprising hydrophilic or hydrophobic silica and a clay such as bentone. However, the clays have the drawback of rendering the composition opaque and matt and it is not possible to obtain transparent or translucent compositions of glossy appearance. The object of the present invention is to propose a transparent or translucent thick composition, containing pyrogenic silica, which has good cosmetic properties and does not have the aforementioned drawbacks. The Applicant Firm has discovered that a composition of this type could be obtained by associating the pyrogenic silica with a particular thickener. The subject of the present invention is therefore a composition comprising pyrogenic silica, characterized in that it also comprises at least one polysaccharide alkyl ether formed of units comprising at least two different osidic cycles, each unit comprising at least one hydroxyl group substituted by a saturated hydrocarbon alkyl chain, and an organic phase comprising at least one solvent medium of said alkyl ether. Thanks to the combination of the pyrogenic silica and the polysaccharide alkyl ether, the composition accng to the invention is transparent or translucent and has a high viscosity. In addition, the composition has good cosmetic properties: during application on keratin materials, the composition is not sticky; It is easy to apply and offers a pleasant sensation during and after its application, without leaving feeling of tightness. In particular, it is possible to obtain a soft red lipstick in the application and that leaves on the lips a homogenous and covering film, comfortable to wear, which does not dry the lips. In addition, it has a brighter appearance than that of the prior art containing silica. Although the invention is particularly well adapted to the cosmetic field, it is applied in any field that needs to obtain thick compositions, including solid compositions and mainly in the fields of agri-food, veterinary, dermatological, pharmaceutical, wood (stick of pigments and wax for the Furniture restoration) . In the thickener associated with pyrogenic silica, "hydrocarbon alkyl chain" means a straight or branched chain, comprising from 1 to 24, preferably from 1 to 10, better from 1 to 6 and more especially from 1 to 3 carbon atoms. carbon. In particular, the alkyl chain is chosen from the saturated chains and mainly methyl, ethyl, ethenyl, n-propyl, propenyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl. These alkyl ethers can be manufactured as described in EP-A-281 360, EP-A-708114, EP-A-281360. According to a preferred embodiment of the invention, the polysaccharide alkyl ether has a weight average molecular weight greater than 100 000, and preferably greater than 200 000. This molecular weight can be up to 1 million. This alkyl ether can comprise from one to six and better from two to four hydroxyl groups per unit, substituted by a saturated or unsaturated hydrocarbon alkyl chain. Osidic cycles are chosen mainly from mannose, galactose, glucose, furanose, rhamnose, arabinose.
According to a preferred embodiment of the invention, the polysaccharide alkyl ether is an alkyl ether of a gum and more particularly of a globally non-ionic gum, that is to say comprising little or no ionic group. Suitable gums include, for example, guar gum whose unit comprises a galactose and a mannose, locust bean gum whose unit comprises a galactose and a mannose, karaya gum which is a complex mixture of rhamnose, galactose and acid. galacturónico, the gum that is a complex mixture of arabinose, galactose and galacturonic acid. According to a preferred embodiment of the invention, the polysaccharide alkyl ether is a derivative of guar gum. Thus, the alkyl ether advantageously is an alkylated chain galactomannan of Ci to C6 alkyl and better of Ci to C3 and more particularly guarethylated guar having a degree of substitution of 2 to 3 and mainly of about 2.5 to 2.8. , as described in documents RD 95378007 (October 1995) and EP-A-708114.
This rubber is in particular those sold by the company ® Aqualon under the names N-HANCE-AG 200 and N-HANCE AG
® The alkyl ether concentration depends on the galenic form, the consistency sought for the composition. In particular, the weight ratio of the amount of solvent and / or oil to the amount of thickener is chosen, for example, in the range from 5 to 1000. The composition according to the invention may contain, for example, an amount of alkyl ether of polysaccharide which it ranges from 0.1 to 16% by weight, relative to the total weight of the organic phase (solvent and / or oil) of the composition, and preferably from 0.5 to 8% by weight. The pyrogenic silica capable of being used in the composition according to the invention may be in the form of hydrophilic pyrogenated silica or pyrogenic hydrophobic silica. Pyrogenic silicas may be obtained by hydrolysis at high temperature of a volatile silicon compound in an oxyhydrous flame, producing a silica finely divided. This process makes it possible mainly to obtain hydrophilic silicas which have a significant number of silanol groups on their surface. Such hydrophobic silicas are marketed, for example, under the names ® ® ® "AEROSIL 130", "AEROSIL 200" AEROSIL 255"," AEROSI
® ® 300"," AEROSIL 380"by the company Degussa," CAB-O- ® ® ®
SIL HS-5"," CAB-O-SIL EH-5"," CAB-O-SIL LM-130", ® ®" CAB-O-SIL MS-55"," CAB-O-SIL M-5"for society
Cabot. It is possible to chemically modify the surface of said silica, by chemical reaction generating a decrease in the number of silanol groups.
Mainly silanol groups can be replaced by hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups can be: trimethylsiloxyl groups, which are obtained mainly by treatment of pyrogenic silica in the presence of exametildisilazane. Silicas treated in this way are called "silica sililato" according to the CTFA (6th edition, 1995). They are marketed by ® example under the references "AEROSIL R812" by the company ® Degussa, "CAB-O-SIL TS-530" by the company
Cabot. dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained mainly by treating pyrogenated silica in the presence of polydimethylsiloxane or dimethyldiclorsilane. Silicas thus treated are called "Silica dimethyl sililate" according to the CTFA (6th edition, 1995). The references "AEROSIL R972", "AEROSIL R974" by the company Degussa, "CAB-O-SIL TS-610", "CAB-O-SIL TS- ® 720" by the company Cabot are marketed for example under ® ® . According to the invention, hydrophobic silicas are preferably used. The pyrogenated silica mainly has a particle size which can be nanometric or micrometric, for example ranging from approximately
to 200 nm. The composition according to the invention may comprise pyrogenated silica in an amount ranging from
O, 5% to 25% by weight, relative to the total weight of the organic phase of the composition, preferably from 1% to 20% by weight, and better than 1% to 10% by weight. According to the invention, the solvent medium of the polysaccharide alkyl ether present in the composition can be an organic solvent or an oil. In other words, polysaccharide alkyl ether is a thickener of organic solvents and oils. By oils, all liquid fat is understood at room temperature. The organic solvent may be, for example, chosen from: liquid ketones at room temperature such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone, acetone; alcohols liquid at room temperature such as ethanol, isopropanol, diacetone alcohol, 2-butoxyethanol, the exanol cycle; the liquid glycols at room temperature such as ethylene glycol, propylene glycol, pentylene glycol; the propylene glycol ethers which are liquid at room temperature, such as propylene glycol monoethyl ether, propylene glycol monomethyl ether acetate, dipropylene glycol mono n-butyl ether; short chain esters (having from 3 to 8 carbon atoms in total) such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate, isopentyl acetate; liquid ethers at room temperature such as diethyl ether, dimethyl ether or diclordiethylether; liquid alkanes at room temperature such as decane, heptane, dodecane cyclohexane; aromatic cyclic compounds liquid at room temperature such as toluene and xylene;
liquid aldehydes at room temperature such as benzaldehyde, acetaldehyde; These solvents are more particularly suitable for the makeup or removal of the nails: the composition then constitutes a nail polish, a nail treatment product or a nail polish solvent. Among the oils which can be used as the solvent medium of the polysaccharide alkyl ether according to the invention, there may be mentioned, for example: oils of vegetable origin such as liquid triglycerides, for example sunflower, corn, soya, jojoba, pumpkin oils, of pips of grapes, sesame, hazelnut, apricot, macadamia, castor, triglycerides of caprylic / capric acids such as those sold by STEARINERIES DUBOIS or sold under the names MIGLYOL 810, 812, and 818 by the company DYNAMIT NOBEL. - oils of animal origin such as lanolin, oils of mineral origin, synthetic oils such as fatty alcohols such as octyl-2-dodecanol; the esters and in particular the esters of fatty acids, and especially the esters having a total number of carbon atoms chosen between 12 and 80 and better between 16 and 50; phenylated silicones, and mainly phenyl tri eticones, diphenyl dimethicones, polymethylphenyl siloxanes. The technician knows, by his knowledge, to determine by simple routine tests the oils that solubilize the alkyl ether of polysaccharide. Complementary oils, non-solvents of the polysaccharide alkyl ether, can also be added to the composition. As a complementary oil, mention may be made in particular of liquid silicone resins and gums at room temperature, partially fluorinated hydrocarbon oils, perfluorinated oils, silicone oils free of aromatic groups such as linear or branched polysiloxanes such as polydimethyl polysiloxanes, polyethylmethyl polysiloxanes. , polyoalkylmethylsiloxanes and the cyclic polysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane or mixtures thereof; the fluorinated silicone oils; the polysiloxanes functionalized by one or more hydroxyl functions and / or one or more polyether groups such as the dimethicones copolyols; linear or branched hydrocarbons, such as petroleum jelly, isohexadecane, isododecane. The alkyl ether solvents of polysaccharide (organic solvent or oil) can be present in a proportion of 59 to 99.4% by weight, based on the total weight of the organic phase of the composition, and better than 72% to 98.5% . The complementary oils may be added to the composition in an amount ranging from 0% to 75% by weight, based on the total weight of the organic phase, and better than 0% to 50% by weight. It is also possible to incorporate an aqueous phase into the composition according to the invention, in particular in an amount ranging from 0% to 95% by weight relative to the total weight of the composition, and better from 3 to 85%. The composition according to the invention can also comprise all the ingredients conventionally used in the aforementioned fields and more especially in the cosmetic and dermatological fields. These ingredients are selected in particular from preservatives, vitamins, aqueous or fatty phase thickeners different from that of the invention, perfumes, surfactants, antioxidants, fillers, pigments, waxes, cosmetic or dermatological active agents. liposoluble or water-soluble, and their mixtures. The composition according to the invention can also contain lipid vesicles of the ionic and / or nonionic type. The amounts of these different ingredients are those conventionally used in the relevant fields and for example from 0.01% to 20% of the total weight of the composition. The nature of these ingredients and their proportion must be compatible with obtaining thick stable compositions according to the invention. The composition of the invention can be presented under all galenic forms normally used for a topical or oral application, and mainly in the form of a gel, an emulsion, a dispersion, a multiphase system and mainly two-phase. This composition can have the appearance of a milk, a cream, a paste, a molten or molded solid and mainly a stick. The composition according to the invention can be used advantageously for the treatment, makeup (nail polish, eye liner, mask, foundation, anti-dark circles, eyelid or cheek shadow, lipstick), or the treatment of keratin materials and / or mucous membranes according to the nature of active agents used.
The invention also relates to the use of a pyrogenic silica and a polysaccharide alkyl ether such as those defined above as a thickening agent of a composition comprising an organic phase comprising at least one solvent medium of said alkyl ether. The invention also relates to a method of cosmetic treatment, make-up or make-up removal of keratin and / or mucous materials consisting of applying a composition on the keratin and / or mucous materials as described above. The following examples are given by way of illustration and without limitation.
Example 1
A red lip was prepared according to the invention and a comparative lipstick comprising only pyrogenic silica as a thickener.
The compositions were the following, the amounts being expressed in grams:
®
(1) sold under the name AEROSIL K972 by
Degussa ®
(2) sold under the name N-HANCE AG 200 by
Aqualon The ethylguar was added to the oil mixture heated to 90-95 ° C to form the gel, then the pyrogenated silica was dispersed in the gel and the pigments were added. The mixture was triturated by three passes in the three-roll crusher. The polyethylene wax was then incorporated and the mixture was heated to 100-105 C. The mixture was poured into a mold at the temperature of 98-100 ° C, then allowed to cool. After demolding, the cosmetic properties of the two products were evaluated. It was found that the lipstick according to the invention left on the lips a more opaque film, more homogeneous, more comfortable to wear, less dusty than that obtained with the comparative product. In addition, the red according to the invention dries the lips less.
Example 2:
A pasty lipstick having the following composition was prepared: hydrophobic pyrogenated silica (1) 7.64 g
Ethylene chain guar gum of substitution degree of approximately 2.5 (2) 0.59 g - Phenyltrimethicone sold under the ® designation DC 556 by the company Dow Corning 89.77 g
Pigments 2 g ®
(1) sold under the name AEROSIL R972 by
Degussa ®
(2) sold under the name N-HANCE AG 200 by
Aqualon The mixture of oil, silica and guarethylated was prepared according to the procedure given in Example 1. The pigments were then added, then the mixture was triturated by three passes in the three-roll crusher. A paste was obtained that is easily applied on the lips and that leaves a film comfortable to wear without drying the lips.
Example 3:
A paste-like red lip having the following composition was prepared according to the operating mode of Example 2: hydrophobic pyrogenated silica (1) 7.52 g
Ethylene chain guar gum of substitution degree of approximately 2.5 (2) 0.94 g
Glyceryl Triheptanoate 85.54 g
Nacreous 6 g
® (1) sold under the name AEROSIL R972 by Degussa ® (2) sold under the name N-HANCE AG 200 by
Aqualon A paste was obtained that is applied comfortably on the lips, has a good covering power and the deposited film does not provide a feeling of tightness.
Example 4:
A paste-like lipstick having the following composition was prepared according to the operating mode of Example 2:
Hydrophobic pyrogenated silica (1) 7.52 g Ethylene chain guar gum of substitution degree of approximately 2.5 (2) 0.94 g
Sesame oil 85.54 g
Nacreous 6 g
® (1) sold under the name AEROSIL R972 by
Degussa ® (2) sold under the name N-HANCE AG 200 by Aqualon A paste was obtained that is easily applied on the lips and leaves on them a homogeneous film, comfortable to wear.
Example 5:
Hydrophobic pyrogenated silica (3) 10 g Ethyl chain guar gum of substitution degree of approximately 2.5 (2) 2 g
Octil-2 dodecanol 88 g
® (3) sold under the name AEROSIL R974 by
Degussa
A clear gel was obtained having a viscosity of 7.3 Pa.S (measured in the Contraves TBS, a
° C, equipped with a mobile No. 4 that rotates at the frequency of 50 Hz). This gel can serve as the basis for any cosmetic or dermatological composition.
Example 6:
Hydrophobic pyrogenated silica (3) 10 g
Guar etilado of degree of substitution of approximately 2.5 (2) 2 g Castor oil 88 g
® (3) sold under the name AEROSIL R974 by
Degussa
A clear gel was obtained having a viscosity of 57.5 Pa.S (measured in the Contraves TBS, at 25 ° C, equipped with a mobile No. 5 that rotates at the frequency of 50 Hz). This gel can serve as the basis for any cosmetic or dermatological composition.
It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is the conventional one for the manufacture of the objects or products to which it refers.
Having described the invention as above, property is claimed as contained in the following:
Claims (23)
1. Composition comprising pyrogenic silica, characterized in that it also comprises at least one polysaccharide alkyl ether formed from units comprising at least two different osidic rings, each unit comprising at least one hydroxyl group substituted by a saturated hydrocarbon alkyl chain, and organic phase comprising at least one solvent medium of said alkyl ether.
Composition according to claim 1, characterized in that two to four hydroxyl groups per unit are replaced by a saturated hydrocarbon alkyl chain.
Composition according to any one of the preceding claims, characterized in that the saturated hydrocarbon alkyl chain comprises from 1 to 24 carbon atoms.
Composition according to any one of the preceding claims, characterized in that the saturated hydrocarbon alkyl chain comprises from 2 to 10 carbon atoms.
Composition according to any one of the preceding claims, characterized in that the alkyl chain is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl radicals.
6. Composition according to any one of the preceding claims, characterized in that the osidic cycles are chosen from the group consisting of mannose, galactose, glucose, furanose, rhamnose, arabinose.
Composition according to any one of the preceding claims, characterized in that the polysaccharide alkyl ether is an alkyl ether of a gum chosen from guar gum, locust bean gum, karaya gum, gum trapping and their mixtures .
8. Composition according to any one of the preceding claims, characterized in that the alkyl ether is an alkylated chain galactomannan of Ci to C6 alkyl and better of Ci to C3.
Composition according to any one of the preceding claims, characterized in that the polysaccharide alkyl ether is ethyl chain guar gum with a degree of substitution of 2 to 3.
10. Composition according to any one of the preceding claims, characterized in that the polysaccharide alkyl ether has a weight average molecular weight greater than 200 000.
11. Composition according to any one of the preceding claims, characterized in that the alkyl ether of polysaccharide is present in an amount such that the ratio (by weight) of the amount of solvent and / or oil to the amount of alkyl ether of polysaccharide is chosen in the range from 5 to 1000.
12. Composition according to any one of of the preceding claims, characterized in that the polysaccharide alkyl ether is present in an amount ranging from 0.1 to 16% of the total weight of the organic phase and better than 0.5 to 8% of the total weight of the organic phase of the composition.
Composition according to any one of the preceding claims, characterized in that the pyrogenated silica is chosen from hydrophobic pyrogenic silicas.
Composition according to any one of the preceding claims, characterized in that the pyrogenated silica is present in an amount ranging from 0.5% to 25% by weight, preferably from 1 to 20% by weight, based on the total weight of the organic phase of the composition.
Composition according to any one of the preceding claims, characterized in that the solvent medium of said alkyl ether is an organic solvent and / or an oil.
Composition according to any one of the preceding claims, characterized in that it comprises at least one non-solvent complementary oil of polysaccharide alkyl ether.
Composition according to any one of the preceding claims, characterized in that it also comprises at least one ingredient chosen from the group consisting of preservatives, vitamins, perfumes, surfactants, antioxidants, fillers, pigments, waxes, and their mixtures.
Composition according to any one of the preceding claims, characterized in that it is present in the form of a gel, an emulsion, a dispersion, a multiphase system.
Composition according to any one of the preceding claims, characterized in that it is present in the form of a lipstick.
20. Use of a pyrogenated silica associated with a polysaccharide alkyl ether formed of units comprising at least two different osidic rings, each unit comprising at least one hydroxyl group substituted by a saturated hydrocarbon alkyl chain as the thickening agent of a composition comprising an organic phase which comprises at least one solvent medium of said alkyl ether.
21. Use according to claim 20, characterized in that the polysaccharide alkyl ether is an alkyl ether of a gum selected from guar gum, locust bean gum, karaya gum, gum adragant and mixtures thereof.
22. Process for the cosmetic treatment of keratin and / or mucosal materials, characterized in that a composition according to any one of claims 1 to 19 is applied to the keratin and / or mucosal materials. makeup of keratin and / or mucosal materials, characterized in that a composition according to any one of claims 1 to 19 is applied to the keratin and / or mucosal materials.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9710758 | 1997-08-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA98006691A true MXPA98006691A (en) | 1999-09-20 |
Family
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