MXPA98005180A - Cosmetic or dermatological composition containing at least one fluorid silicone which has an alquine chain - Google Patents

Abstract

The present invention relates to a composition containing, as an ingredient, at least one fluorinated alkylsilicone that responds to one of the following formulas (I) and / or (II): (See Formula), wherein: R1 and R'1 represent independently an alkyl radical, linear or branched decaden, having from 1 to 6 carbon atoms, or a phenyl radical, R2 represents a group R1, -OH0- (CH2) fRF, where f is an integer ranging from 0 to 10, R3 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms, RF represents a radical of the formula - (CF2) q-CF3, where q is an integer ranging from 0 to 15, m and n represent an integer ranging from 1 to 50, and P represents an integer ranging from 0 to 2000, (See Formula), wherein: R 4 represents an alkyl radical, straight or branched chain, having 1 to 6 carbon atoms, or a phenyl radical, R 5 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms, or a phenyl radical, R'F represents a radical of the formula - (CF2) a-CF3, where a is an integer ranging from 0 to 15, and t represents an integer ranging from 1 to twenty

Description

COSMETIC OR DERMATOLOGICAL COMPOSITION CONTAINING AT LEAST ONE FLUORID SILICONE WHICH HAS A CHAIN RENTED DESCRIPTION OF THE INVENTION The present invention relates to a cosmetic or dermatological composition containing a fluorinated silicone having an alkyl chain as an ingredient capable of improving various essential properties. The use of fluorinated compounds in cosmetic compositions has already been proposed for their smoke-forming properties, as well as for their properties of softness and remanence in water. (J ~ Likewise, the use of perfluorinated hydrocarbon polymers in various types of cosmetic compositions is described in European patents EP-390206 and EP-494412. However, these perfluorinated hydrocarbon polymers have a chemical compatibility spectrum, mainly with fatty substances, relatively restricted, thus limiting the selection of the raw materials with which they can be associated and the nature of the compositions that contain them.In addition, they can only be present in relatively low proportions in cosmetic compositions. , Japanese patents JP-7 REF: 27799 103582 and JP 2-295913 propose the use of fluorinated silicones in cosmetic compositions, but these also have relatively restricted compatibility spectra, limiting in the same way the selection of the ingredients with which they can be associated, as well as the proportions in which they may be present in the compositions. It has now been discovered that a particular family of fluorinated silicones, namely the silicones fluorinated with an alkyl chain of 6 to 22 carbon atoms (hereinafter referred to as fluorinated alkylsilicones), have interesting properties considering their cosmetic or dermatological use. Fluorinated alkylsilicones can be mainly good smoke agents which, after application, cause the formation of a film that is both homogeneous, continuous, remnant and easy to remove. The fluorinated alkylsilicones of the compositions according to the present invention also constitute lubricating agents as well as very satisfactory elastic agents. In addition, these fluorinated alkylsilicones have a broader compatibility spectrum than fluorinated compounds such as fluorinated silicones and perfluoroethers described in the prior art, which makes it possible to prepare compositions with the help of substances that could not be used to date. .

These compounds can also be introduced into the compositions in a greater proportion, without affecting the homogeneity or the other properties, but on the contrary, they can improve them. The present invention aims at a cosmetic or dermatological composition containing as an ingredient at least one fluorinated alkylsilicone that responds to any of the following formulas (I) and / or (II): where: R? YR 'i independently represent an alkyl radical, straight or branched chain, having from 1 to 6 carbon atoms or a phenyl radical, R2 represents a radical R, -OH, or - (CH2) f-RF / where f is integer ranging from 0 to 10, R3 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms, RF represents a radical of the formula - (CF2) q-CF3, where q is an integer that goes from 0 to 10, and m represent an integer that goes from 1 to 50, and p represents an integer ranging from 0 to 2000, wherein: R4 represents an alkyl radical, straight or branched chain, having from 1 to 6 carbon atoms or a phenyl radical, R5 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms. carbon, R 'F represents a radical of the formula - (CF2) S-CF3, where s is an integer ranging from 0 to 15, and t represents an integer ranging from 1 to 2, 000 According to a particular embodiment of the cosmetic compositions according to the present invention, the fluorinated alkylsilicone corresponds to the formula (I), wherein: Ri, R '1 and R 2 represent a methyl radical, R 3 represents an alkyl radical linear chain having 6 to 22 carbon atoms, and n are integers ranging from 1 to 20, and q is an integer ranging from 1 to 13. According to another embodiment, in the compositions according to the present invention, Fluorinated alkylsilicone corresponds to formula (II), wherein: R4 represents a methyl radical, R5 represents a straight-chain alkyl radical, containing from 6 to 22 carbon atoms, and s represents an integer ranging from 1 to 13. Fluorinated alkylsilicones such as those defined above are known compounds that have already been described, mainly in US Pat. No. 5,473,038. In the compositions according to the present invention, the fluorinated alkylsilicone as defined above is generally present in a proportion ranging from 0.1 to 99% by weight, preferably from 1 to 80% by weight, based on total weight of the composition. According to a first particular embodiment of the compositions of the present invention, they are anhydrous and comprise an oil phase in a proportion ranging from 0.1 to 99.9% by weight, with respect to the total weight of the composition, wherein said oil phase contains: (i) from 0.1 to 99.9% by weight, based on the total weight of the composition, of a fluorinated alkylsilicone of the formula (I) and / or of the formula (II), and (ii) from 0 to 99.8% by weight, with respect to the total weight of the composition, of at least one fatty, solid or semi-solid body. This or these fatty substances can be selected from the group consisting of oils, waxes, gums and / or fatty substances known as pasty. A- The oils of the oil phase can be of mineral, animal, vegetable or synthetic origin, being able to be volatile or not, at room temperature. As oils of mineral origin, mention may be made in particular of paraffin oil and petrolatum oil. As oils of animal origin can be cited mainly squalane or perhydrosqualene. As oils of vegetable origin, mention may be made in particular of sweet almond oil, calophyllum oil, palm oil, avocado oil, jojoba oil, sesame oil, olive oil, castor oil and cereal germ oils such as for example wheat germ oil. As synthetic oils we can mention mainly: (1) the esters of the formula: R6-COOR7 wherein: R6 represents a residue of a higher fatty acid having from 7 to 20 carbon atoms, and R represents a hydrocarbon radical having from 3 to 30 carbon atoms. Preferred among these esters are: purcellin oil, butyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, butyl stearate, hexadecyl stearate, isopropyl stearate, octyl stearate, isocetyl stearate, oleate decyl, hexyl laurate, isononyl isononanoate, esters derived from lanolic acid such as isopropyl lanolate and isocetyl lanolate. Other synthetic oils which may be mentioned include isododecane, isohexadecane, polyisobutenes and hydrogenated polyisobutene, as well as the acetylglycerides, octanoates and decanoates of polyalcohols, such as glycol and glycerol, ricinoleates of alcohols and polyalcohols such as alcohol cetyl, propylene glycol dicaprylate and isopropyl adipate; (2) fatty alcohols such as oleic alcohol, linoleic alcohol, linolenic alcohol, isostearyl alcohol and octyldodecanol; (3) * silicon oils, such as straight chain polydiorganosiloxanes, optionally with functional groups, cyclic polydiorganosiloxanes and in particular cyclotetra- and penta-dimethicones, and organopolysiloxanes such as alkyl, alkoxy or phenyldimethicones and in particular phenyltrimethicone; (4) Fluorinated oils such as perfluoroalkanes and perfluoropolyethers and partially fluorinated hydrocarbon oils. B- The waxes of the oil phase can be of mineral, fossil, animal, vegetable or synthetic origin, or they can still be hydrogenated oils or solid fatty esters at 25 ° C. Among mineral waxes, mention may be made in particular of microcrystalline waxes, paraffin, Vaseline and Ceresin. Among the fossil waxes we can mention ozokerite and montan wax. Among waxes of animal origin there may be mentioned beeswax, whale sperm, lanolin wax as well as lanolin derivatives such as lanolin alcohols, hydrogenated lanolin, hydroxylated lanolin, acetylated lanolin, lanolin fatty acids and alcohol. acetylated lanolin. Among the waxes of vegetable origin we can mention mainly the waxes of candelila, carnauba wax, Japanese wax and cocoa butter.

Among the synthetic waxes, mention may be made, in particular, of ethylene homopolymers and copolymers of ethylene with a monomer of the formula: CH2 = CH-R8 (III) wherein: Rs represents an alkyl radical having 1 to carbon atoms, an aryl or aralkyl radical. The alkyl radical of 1 to 30 carbon atoms is preferably a methyl, ethyl, propyl, isopropyl, butyl, decyl, dodecyl or octadecyl radical. It is also possible to use waxes obtained by Fisher-Tropsch synthesis, as well as silicone waxes. Among the hydrogenated solid oils at 25 ° C, mention may be made principally of hydrogenated castor oil, hydrogenated palm oil, hydrogenated tallow and hydrogenated coconut oil. Among the solid fatty esters at 25 ° C, mention may be made, in particular, of the monomyristate of propylene glycol and myristyl myristate. As waxes useful in the composition according to the present invention, cetyl alcohol, stearyl alcohol, monoglycerides, diglycerides and solid triglycerides at 25 ° C, stearic monoethanolamide *, colofan and their derivatives such as glycol abietates and glycerol, sucroglycerides and oleates, myristates, lanolates, stearates and dihydroxystearates of calcium, magnesium, zinc and aluminum. C- The pasty type fatty substances can be of mineral, animal, vegetable or synthetic origin. Among the pasty fatty substances, mention may be made, in particular, of synthetic esters such as arachidyl propionate, vinyl polylaurate, polyethylene waxes and organopolysiloxanes, such as alkyldimethicones, alkoxydimethicones or dimethicone esters. Of the different fatty substances enumerated above, the following are preferably used according to the present invention: (1) among the oils: isododecane, hydrogenated polyisobutene, squalane, isononyl isononanoate, cyclomethicones such as cyclotetramyone and pentadimethicone, and phenyltrimethicone; (2) between the waxes: (i) ethylene homopolymers with a weight average molecular weight between 200 and 1,000, mainly those marketed under the trademarks "Poli ax 500" and "Poli ax 655" by the Company BARECO, ( ii) ethylene copolymers with at least one monomer of the formula (III) wherein the radical R8 represents a methyl, ethyl, isopropyl, butyl, dodecyl or octadecyl radical, wherein these polymers have a weight average molecular weight of between 200 and 1,000. Among them, mention may be made of ethylene-propylene copolymers such as those marketed under the trademarks "Petrolite CP-7" and "Petrolite CP-12" by the company BARECO, and ethylene-hexene copolymers such as those marketed with the brands "Petrolite CH-7" and "Petrolite CH-12" by the company BARECO, (iii) microcrystalline waxes and ozokerite, (iv) beeswax; (3) As pasty fatty substances, arachidyl propionate. The anhydrous compositions according to the present invention may also contain another or a plurality of conventional cosmetic or dermatological additives or adjuvants. These anhydrous compositions can be present in different forms, such as mainly in the form of an oily gel, in the form of solid products such as compacted or sieved powders, or even bars such as, for example, lipsticks. When, the compositions according to the present invention are presented in the form of an oily gel, they generally contain, in addition to the components previously defined, an oily gelling agent. Among the oily gelling agents, mention may be made in particular of metal esters such as polyoxyaluminium stearate and aluminum or magnesium hydroxystearate, esters of glycol fatty acids, triglycerides, mixtures of fatty alcohols, cholesterol derivatives and in particular hydroxycholesterol and clay minerals in presence of oil, particularly those that belong to the group of montmorillonites. The oily gelling agents can be present in a very variable proportion, according to the desired texture of the compositions. However, in most cases they are present in a proportion ranging from 0.1 to 30% by weight, with respect to the total weight of the composition. These anhydrous compositions according to the present invention can be used mainly as personal care products, cleaning products, make-up removers or make-up products. When they are presented in the form of make-up products, they can be particularly bases for dyes, masks, eyeliners, lipsticks, shadows for the eyelids or eyes. These compositions are generally colored and contain as cosmetic adjuvants dyes and / or pigments already known in the field of make-up products.

According to a second embodiment of the compositions according to the present invention, these are dispersions in water-in-oil (water / oil) or oil-in-water (oil / water) emulsion form, which are essentially constituted by (i) an oil phase in a proportion ranging from 0.1 to 50% by weight, with respect to the total weight of the composition, wherein said oil phase contains a fluorinated alkylsilicone of that of the formula (I) and / or the formula (II) as defined above, in a proportion ranging from 0.1 to 50% by weight, with respect to the total weight of the composition; (ii) an aqueous phase in a proportion ranging from 50 to 98.9% by weight, with respect to the total weight of the composition; and (iii) at least one emulsifying agent in a proportion ranging from 1 to 10% by weight, based on the total weight of the composition in the form of an emulsion. It has been found that, contrary to the fluorinated oils used above, the fluorinated alkylsilicones of the formula (I) and / or the formula (II) make it possible to obtain emulsions of very good stability with respect to time and storage conditions. As emulsifying agents or surfactants which can be used in the compositions according to the present invention of the water / oil or oil / water emulsion type, mention may be made in particular of the silicone surfactants, in particular those which they belong to the family of the alkyldimethicone or alkoxydimethicone copolyols. Among the copolyols of alkyldimethicone or alkoxydimethicone, mention may be made, in particular, of the compounds corresponding to the following general formula: wherein: R is a hydrogen atom, an alkyl radical of 1 to 16 carbon atoms, alkoxy or acyl, R 'is an alkyl or alkoxy radical of 8 to 22 carbon atoms, u = 0 to 200, v = 1 to 40, = 1 to 100, the molecular weight of the radical -0- (C2H40 -) - (C3H60 -) - R x y is from 250 to 2,000, where x and y are selected in such a way that the weight ratio of the oxyethylene / oxypropylene groups is between 100: 0 and :80.

Among the commercial products that may contain all or a part of the copolyol alkyl silicones used in accordance with the present invention, mention may be made in particular of those marketed under the trademarks "Abil WE09", "Abil EM90" or "Abil S08" by the company GOLDSCHMIDT, "Q2 5200" or "Q2 3225C" by the company DOW CORNING and "218 1138" by the company GENERAL ELECTRIC. These emulsions are preferably in the form of creams and can be used as personal care, cleaning or make-up products. They can also constitute skin protection products against various types of aggressions, thanks to the excellent film quality formed by the fluorinated alkylsilicone of the formula (I) and / or the formula (II), after its application. The compositions according to the present invention can also constitute excellent solar products when UVA and / or UVB sunscreens and / or nano-sized pigments are introduced. When these compositions are products for make-up, they can be mainly dye bases containing a certain proportion of pigments and / or dyes. The compositions according to the present invention which are of the anhydrous type or are in dispersion form, exhibit excellent cosmetic properties such as mainly a better ease of application, a great softness and produce obtaining a homogeneous makeup. These make-up compositions also have an excellent resistance to transfer to other different supports to which they were applied. The term "transfer or transfer" is understood as the displacement of a fraction of the composition by contact with another support, either of the same nature or of a different nature. This property is particularly interesting when the compositions have a lot of color. For exampleWhen makeup compositions are shadows for eyelids, eyeliners or masks, this property prevents the transfer of compositions to hands by rubbing or by eye contact. For compositions in the form of lipstick, this property allows limiting the lipstick to the hands or even to the cheeks of another person. In addition, this property also allows to avoid staining the dining napkins and staining glass containers, cups and others. When the compositions according to the present invention are bases for dyeing, this property allows mainly to prevent the transfer or transfer of the base for dyeing to the neck of the shirts and thus avoid staining them.

According to a third embodiment of the compositions of the present invention, these are in the form of nail products, such as nail varnishes or nail care products, comprising a fluorinated alkylsilicone of the formula (I) and / or of the formula (II) as defined above, in a proportion ranging from 0.1 to 99.9% by weight, with respect to the total weight of the composition. Preferably, according to this embodiment, the compositions are in the form of nail varnish and contain: (i) a fluorinated alkylsilicone of the formula (I) and / or the formula (II) in a proportion ranging from 2 to 40% by weight, with respect to the total weight of the varnish, (ii) a solvent system for varnish, and i (iii) a fumaric substance. According to this embodiment, the solvent system of the varnish is generally present in a proportion ranging from 55 to 90% by weight, with respect to the total weight of the varnish. Although the solvent system can be of the aqueous type, it is preferably constituted by a mixture of various volatile organic solvents, so that relatively short drying times can be obtained. Among these solvents there may be mentioned acetone, ethyl acetate, butyl acetate, 2- acetate methoxyethyl, methyl ethyl ketone, methyl isobutyl ketone, methyl acetate, amyl acetate and isopropyl acetate. The solvent system may also comprise a diluent which is preferably a hydrocarbon, straight or branched chain, saturated, such as hexane or octane, or even aromatic hydrocarbon such as toluene or xylene, in a proportion ranging generally from 10 to 35. % by weight, with respect to the total weight of the varnish. The solvent system may also include other volatile solvents such as ethanol, n-butanol, n-propanol, isopropanol or mixtures thereof. In addition to the fluorinated alkylsilicone of the formula (I) and / or the formula (II), the composition according to the present invention may also comprise a smoke-forming substance. This smoke substance is generally present in a proportion ranging from 5 to 35% by weight, with respect to the total weight of varnish. Among these smoke substances one can cite the nitrocellulose type "RS" or "SS" and in particular the nitrocellulose type 1/4 second RS, the nitrocellulose type 1/2 second RS, the nitrocellulose type 1/2 second SS and nitrocellulose type 3/4 second RS. As the fumed substance, polyvinyl derivatives such polyvinyl butyrate can also be used according to the present invention.

As another fumaric substance, different cellulose derivatives of nitrocellulose, acrylic polymers or copolymers, resins of the acrylic, styrenic, acrylate-styrenic and vinyl type, vinyl copolymers, polyester polymers, resins of the like, can be used according to the present invention. type arylsulfonamide and alkylated resins. The varnishes according to the present invention may also contain a plasticizing agent, which is generally present in a proportion ranging from 5 to 20% by weight, with respect to the total weight of the varnish. The plasticizing agents allow to regulate the flexibility of the film without diminishing its strength or its physical strength. Among the plasticizing agents there may be mentioned: tricresyl phosphate, benzyl benzoate, tributyl phosphate, butyl acetyl trinoleate, triethyl citrate, tributyl acetyl citrate, dibutyl phthalate and camphor. The products for the nails according to the present invention can be colorless or colored. When they are colorful, they contain pigments and / or dyes already known in the field of nail varnishes. In accordance with a fourth particular embodiment of the compositions of the present invention, these are hair compositions containing a cosmetic vehicle which is selected from the group consisting of alcoholic and hydroalcoholic solutions, at least one fluorinated alkylsilicone of the formula (I) and / or of the formula (II) such as those defined above, in a proportion ranging from 60 to 99.5% by weight, with respect to the total weight of the composition. The alcohol is preferably ethanol or isopropanol, generally present in the hydroalcoholic solutions in a proportion ranging from 60 to 99.5% by weight, with respect to the total weight. These hair compositions in the form of lotions to be sprayed or even in the form of aerosols, are easily applied and form a continuous and homogeneous film, allowing a very satisfactory coverage of the hair, which is easily removed with the application of shampoo. In addition, the hair compositions according to the present invention can contain various additives and ingredients that are used in the hair treatment field, such as mainly UV filters, and thus constitute compositions intended to protect hair dyes from hair. effects of the sun. Although reference has been made above to the lotions in a more particular way, the hair compositions according to the present invention can also be presented in the form of liquid emulsions which allow a good impregnation of the hair.

The compositions according to the present invention, as described above, may also contain one or a plurality of conventional cosmetic adjuvants, such as vitamins, hormones, antioxidants, preservatives, fillers, perfumes, thickeners, moisturizing agents, wetting agents. , anionic, nonionic or amphoteric polymers or active or dermatological cosmetics. Among these adjuvants, fillers are generally present in make-up or cleaning products, or in dermatological products, in a maximum proportion of approximately 99.9% by weight, with respect to the total weight of the composition. These fillers, in the form of very fine powders, can be of natural or synthetic origin. These may include: a) mineral powders such as talc, kaolin, mica, silica, silicates, alumina, zeolites, hydroxyapatite, cericite, titanium dioxide, micatitaniums, barium sulfate, bismuth oxychloride, gold nitride and metal powders such as aluminum powder; b) vegetable powders such as corn, wheat or rice starch powders; c) organic powders such as nylon, polyamide, polyester, polytetrafluoroethylene or polyethylene powders.

These different powders can also be coated, for example with metal salts of fatty acids, amino acids, lecithins, collagen, silicon compounds, fluorinated compounds or with any other conventional coating. In addition to the fillers, the dyes and pigments also enter not only the anhydrous compositions for make-up or in the form of dispersions, but also in nail varnishes. The dyes and / or pigments are generally present in a maximum proportion of about 40% with respect to the total weight of the composition. In lipsticks, the ratio of at least one dye and / or pigment is generally from about 0.1 to 15% by weight, based on the total weight of the lipstick. Among the colorants of the makeup products and mainly in the lipsticks, mention may be made of the eosin derivatives, such as the D &C Red No. 21 and the halogenated fluorescein derivatives, such as the D &C Network No. 27 , D &C Red Orange No. 5 in association with D &C Network No. 21 and D &C Orange No. 10. Among the pigments that may be mineral or organic, or even metal lacquers, mention may be made of titanium dioxide , zinc oxide, the D &C Network No. 36 and the D &C Orange No. 17, calcium lacquers from D &C Network No. 7, 11, 31 and 34, barium lacquers from D &C Network No. 12, strontium lacquer from D &C Network No. 13, aluminum lacquers from FD &C Yellow No. 5, FD &C Yellow No. 6, D &C Network No. 27, D &C Network No. 21, FD &C Blue No. 1, iron oxides, manganese violet, chromium oxide and ultramarine blue. Among the most widely used nail varnish pigments, mention may be made of D &C Network No. 8, 10, 30 and 36, barium lacquers of D &C Network No. 6, 9 and 12, calcium lacquers of D &C Network No. 7, 11, 21 and 34, strontium lacquer from D &C Network No. 30, as well as D &C Orange No. 17 and D &C Blue No. 6. Nail varnishes they may also contain titanium dioxide to impart a certain opacity, as well as certain iridescent substances such as guanine and products that allow the pigments to be prevented from settling, such as modified montmorillonite clays, such as, for example, Bentone 27, Bentone 34 or Bentone 38 The present invention will now be illustrated with the following Examples, in which the amounts are expressed by weight. EXAMPLE 1: Transfer-resistant Lipstick A lipstick is prepared by mixing the following ingredients: Phase A - Fluorinated Alkylsilicone (a) 20 g - Arachidyl Propionate 9 g - Ethylene homopolymer marketed under the trademark "Poliwax 500" by the BARECO Company 16 g Phase B - Cyclotetradimethicone marketed under the registered trademark "Dow Corning 244 Fluid" by the company Dow Corning 46 g Phase C - Pigments 9 g (a) Fluoroalkylsilicone of the formula (I), wherein R ^, R 'and R2 represent a methyl radical, R3 represents a straight-chain alkyl radical having 16 carbon atoms, RF represents a radical - (CF2) s ~ CF3, q equals 5, m, n and p are, respectively, equal 10, -20 and 50. This lipstick was prepared by heating the ingredients of Phase A at a temperature of about 95 ° C. After completing the fusion, the pigments are added (Phase C) and then, at 60 ° C, Phase B. It is then homogenized with the help of a motor-type turbine at a speed of 3000 r / min. Then the homogenous mixture obtained at 85 ° C can be emptied into molds for lipstick. After cooling, the lipsticks are removed from the molds. The obtained lipsticks are applied very easily on the lips, to which they give a great softness. The lipsticks, after their application, also present an excellent retention; that is, an excellent resistance to use. In addition, they have a good resistance to transfer or handover. EXAMPLE 2: Transfer or Transfer Resistant Lipstick This lipstick is obtained following the same procedure described in Example 1, from the following phases: Phase A - Fluorinated Alkylsilicone (b) 20 g - Arachidyl Propionate 9 g Ethylene homopolymer, marketed under the trademark "Polywax 500" by the BARECO Society 16 g Phase B - Cyclotetradimethicone marketed under the trademark "" Dow Corning 244 fluid "by the company Dow Corning 46 g Phase C - Pigments 9 g (b) Fluoroalkylsilicone of the formula (II), wherein R4 represents a methyl radical, R5 represents a straight chain alkyl radical having 16 carbon atoms, R 'F represents a radical - (CF) 8 ~ CF3 and t is equal to 1. This lipstick, which differs from the preceding one by the nature of the fluorinated alkylsilicone present, has excellent retention and comfort properties. JEMPLO 3: Transfer or transfer-resistant lipstick Following the conventional method of preparing lipsticks, the following ingredients were mixed: - Fluorinated alkylsilicone (same as Example 1) ... 8 g - Hydrogenated polyisobutene 28 g - Polybutene 10 g - Diisostearyl malate 5 g - Octyldodecanol 5 g - Oxypropylenated lanolin with 5 moles of propylene oxide 5 g - Modified hectorite (Bentone) 0.8 g - Ethylene homopolymer marketed under the trademark "Polywax 500" by the BARECO Company 11 g - Octacosanil stearate 4 g - Hydrogenated coconut oil 5 g - Polydimethylsiloxane (5 cst) 9.54 g - Pigments 8.66 g The lipstick obtained has a great softness to the application and causes the formation of a film on the lips, comfortable and not greasy. EXAMPLE 4: Base for Dye The base for dyeing is prepared in the form of a water-in-oil (W / O) emulsion with the aid of the following ingredients: Oil Phase A - Poly-4-glyceryl isostearate and cetyldimethicone copolyol, and the hexyl laurate, marketed under the trademark "Abil WE09" by the company GOLDSCHMIDT 5 g - Fluorinated alkylsilicone (same as Example 1) .... 15 g - Pigments (iron oxide and titanium dioxide) coated with polydimethylsiloxanes 7 g Aqueous Phase B - Conservative c.b.p. - Water c.b.p 100 g This W / O emulsion is obtained by dispersing the pigments in the Oil Phase at room temperature. Then, Aqueous Phase B is incorporated with agitation by means of a motor-type turbine at a speed of 3000 r / min. EXAMPLE 5: A nacreous nail varnish was prepared with the following ingredients: - Nitrocellulose 12 g - Rented resin 5 g - Tributyl acetylcitrate 3 g - Fluorinated alkylsilicone (same as Example 1) .... 3 g - Isopropyl alcohol 8 g - Hectorite 1 g - Pearlescent pigments 0.5 g - Ethyl acetate / butyl acetate c.b.p 100 g This varnish was obtained with a strong agitation and under pressure, dispersing the hectorite in a part of the nitrocellulose and * the mixture of acetates, and then the rest of the ingredients was added.

It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention. Having described the invention as an antecedent, what is contained in the following is claimed as property.

Claims (16)

1. CLAIMS 1. A cosmetic or dermatological composition, characterized in that it contains as an ingredient when a fluorinated alkylsilicone that responds to one of the following formulas (I) and / or (II): wherein: Ri and R 'i independently represent an alkyl radical, straight or branched chain, having 1 to 6 carbon atoms, or a phenyl radical, R 2 represents a group Ri, -OH or - (CH 2) f RF, where f is an integer number ranging from 0 to 10, R3 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms, RF represents a radical of the formula - (CF2) -CF3, where q is an integer that goes from 0 to 15, and m represent an integer that goes from 1 to 50, and p represents an integer ranging from 0 to 2000, wherein: R4 represents an alkyl radical, straight or branched chain, having 1 to 6 carbon atoms, or a phenyl radical, R5 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms; carbon, R 'F represents a radical of the formula - (CF2) S-CF3, where s is an integer ranging from 0 to 15, and t represents a whole integer that goes. from 1 to 2000.
2. 2. A composition according to claim 1, characterized in that the fluorinated alkylsilicone corresponds to the formula (I), wherein: Ri / R '1 and R2 each represent a methyl radical, R3 represents a radical linear chain alkyl having from 6 to 22 carbon atoms, m and n are integers ranging from 1 to 20, and q is an integer ranging from 1 to 13.
3. 3. A composition according to claim 1, characterized in that the fluorinated alkylsilicone corresponds to formula (II), wherein: R4 represents a methyl radical, R5 represents a straight-chain alkyl radical, having from 6 to 22 carbon atoms, s represents an integer ranging from 1 to 13.
4. 4. A composition according to any of the preceding claims, characterized in that the fluorinated alkylsilicone is present in a proportion ranging from 0.1 to 99.9% by weight, with respect to the total weight of the composition.
5. 5. A composition according to any of the preceding claims, characterized in that the composition is an anhydrous composition containing an oil phase, in a proportion ranging from 0.1 to 99.9% by weight, with respect to the total weight of the composition, in wherein the oil phase contains: (i) from 0.1 to 99.9% by weight, based on the total weight of the composition, of a fluorinated alkylsilicone of the formula (I) and / or of the formula (II), and (ii) from 0 to 99.8% by weight, with respect to the total weight of the composition, of at least one liquid, solid or semi-solid fatty body.
6. 6. A composition according to claim 5, characterized in that the fatty body is selected from the group consisting of isododecane, hydrogenated polyisobutene, squalene, isononanoate of isononyl, cyclotetradimethicone and pentadimethicones, phenyltrimethicones, ethylene homopolymers, ethylene copolymers with at least one monomer of the following formula (III): CH2 = CH-R8 (III) wherein: R8 represents an alkyl radical having from 1 to 30 carbon atoms, an aryl or aralkyl radical, wherein the homopolymers and copolymers have a weight average molecular weight of between 200 and 1000, microcrystalline waxes, ozokerite, beeswax, candelila wax and arachidyl propionate.
7. 7. A composition according to any of the preceding claims, characterized in that it is in the form of an oily gel, a compacted powder, a sieved powder or a stick.
8. 8. A composition according to claim 7, characterized in that the bar is a lipstick containing at least one dye and / or pigment, in a proportion ranging from 0.1 to 15% by weight, with respect to the total weight of the composition in the form of lipstick.
9. 9. A composition according to any of claims 1 to 4, characterized in that it is in the form of a stable dispersion of water type in oil or oil in water, comprising (i) an oil phase in a proportion ranging from 0.1 to 50% by weight, based on the total weight of the composition, wherein the oil phase contains a fluorinated alkylsilicone of the formula (I) ) and / or of the formula (II) according to any of claims 1 to 3, in a proportion ranging from 0.1 to 50% by weight with respect to the total weight of the composition, (ii) an aqueous phase in a proportion ranging from 50 to 98.9% by weight, with respect to the total weight of the composition, and (iii) at least one emulsifying agent in a proportion ranging from 1 to 10% by weight, with respect to the total weight of the composition. composition.
10. 10. A composition according to claim 9, characterized in that the oil phase contains at least one fatty substance such as defined in claim 6.
11. 11. A composition according to claim 9, characterized in that the emulsifying agent is selected from the A group consisting of alkyldimethicone or alkoxydimethicone copolyols of the following general formula: wherein: R is a hydrogen atom, an alkyl radical of 1 to 16 carbon atoms, alkoxy or acyl, R 'is an alkyl or alkoxy radical of 8 to 22 carbon atoms, u = 0 to 200, v = 1 at 40. w = 1 to 100, wherein the molecular weight of the radical -0- (C2H40) x- (C3HgO) and R is from 250 to 2000, xyy are selected in such a way that the weight ratio of the oxyethylene / groups oxypropylene is between 100: 0 and 20:80.
12. 12. A composition according to any of claims 1 to 4, characterized in that it is a composition for make-up or for the care of the nails, which contains a fluorinated alkylsilicone of the formula (I) and / or the formula (II) ) in a proportion ranging from 0.1 to 99.9% by weight, with respect to the total weight of the composition.
13. 13. A composition according to claim 12, characterized in that it is in the form of a nail varnish and contains: (i) a fluorinated alkylsilicone of the formula (I) and / or the formula (II) in an amount ranging from 2 to 40% by weight, with respect to the total weight of the varnish, (ii) a mixture of solvents for varnish, and (iii) a fumaric substance.
14. 14. A composition according to claim 13, characterized in that the mixture of solvents is present in a proportion ranging from 55 to 90% by weight and the smoke substance in a proportion ranging from 5 to 35% by weight, with respect to to the total weight of the composition in the form of a nail varnish.
15. 15. A composition according to any of claims 1 to 4, characterized in that the composition is a capillary composition comprising, in a cosmetic vehicle selected from the group consisting of alcoholic and hydroalcoholic solutions, at least one fluorinated alkylsilicone of the formula (I) and / or formula (II) in a proportion ranging from 0.5 to 40% by weight, with respect to the total weight of the composition.
16. 16. A composition according to any of the preceding claims, characterized in that the composition also contains at least one conventional cosmetic adjuvant selected from the group consisting of: consists of fillers, UVA and / or UVB sunscreens, vitamins, hormones, antioxidants, preservatives, dyes, pigments, perfumes, thickening agents, moisturizing agents, wetting agents, anionic, nonionic or amphoteric polymers and cosmetic or dermatological active substances. SUMMARY OF THE INVENTION The present invention relates to a composition containing, as an ingredient, at least one fluorinated alkylsilicone that responds to one of the following formulas (I) and / or (II): R2-Si (I) wherein: R and R 'independently represent an alkyl radical, straight or branched chain, having 1 to 6 carbon atoms, or a phenyl radical, R 2 represents a group Ri, -OH or - (CH 2) f-RF , wherein f is an integer ranging from 0 to 10, R3 represents an alkyl radical, straight or branched chain, having from 6 to 22 carbon atoms, RF represents a radical of the formula - (CF2) q- CF3, where q is an integer that goes from 0 to 15, and m represent an integer that goes from 1 to 50, and p represents an integer that goes from 0 to 2000, wherein: R4 represents an alkyl radical, straight or branched chain, having 1 to 6 carbon atoms, or a phenyl radical, R 5 represents an alkyl radical, straight or branched chain, having 6 to 22 carbon atoms, or a phenyl radical, R 'F represents a radical of the formula - (CF2) S-CF3, where s is an integer ranging from 0 to 15, and t represents an integer ranging from 1 to 2000.