MXPA97005504A

MXPA97005504A - Composition that comprises a polymeric system and use of said system mainly in cosmet

Info

Publication number: MXPA97005504A
Application number: MXPA/A/1997/005504A
Authority: MX
Inventors: De La Poterie Valerie
Original assignee: L'oreal
Priority date: 1996-07-24
Filing date: 1997-07-21
Publication date: 1998-11-09

Abstract

The present application relates to a composition susceptible to be applied to the skin, the semi-mucous membranes and / or the mucous membranes, which comprise a polymeric system that includes an aqueous dispersion of film-forming polymer particles, said polymeric system allowing obtaining a manageable and flexible film. The invention also relates to the use of a polymer system of this type in such a composition, mainly cosmetic.

Description

COMPOSITION THAT COMPRISES A SYSTEM. POLYMERIC AND USE OF SAID SYSTEM MAINLY IN COSMETICS. DESCRIPTION OF THE INVENTION The present invention relates to a composition mainly cosmetic capable of being applied on the skin, semi-mucous and / or mucous membranes. Said composition comprises in particular an aqueous dispersion of smoke polymer particles and can be used as a makeup product. The compositions to be applied on the skin, the semi-mucous and / or the mucous membranes, of the red lip-like type or foundation, are generally presented in the form of a stick, a flexible paste or a cast paste, and comprise fatty substances. such as oils, paste compounds and / or waxes, and a particular phase generally composed of fillers and pigments. These compositions, when applied on this support, however, have the disadvantage of transferring. This is understood by the fact that the cpm position is susceptible to deposit, at least in part, on certain sooortes with which it is contacted, such as a glass, a cup, a garment or the skin. Upon depositing, said composition leaves a stain on said support. Therefore, it follows a persistence REF: 25169 mediocre composition on the skin, semi-mucous membranes or mucous membranes, and the need to regularly renew its application. On the other hand, the appearance of unacceptable stains on certain garments and especially on the collars of blouses can lead some women away from the use of this tioo of garment. Another drawback of these compositions lies in the migration problem. Indeed, it has been found that certain compositions have a tendency to spread within wrinkles and / or skin folds, in the case of foundation stains; in the wrinkles that surround the lips, in the case of red lips; in the folds of the eyelid in the case of eye shadows. It has also been found, in the case mainly of: the eye shadows, the appearance of grooves in the makeup, generated by the movements of the eyelids. It was found additionally that the eyeliners could also run. All these phenomena produce an unesthetic effect that is obviously desired to avoid. For several years, many companies of eos mystics are interested in cosmetic compositions, - mainly red lips or make-up "without transfer" So, have been considered compositions of lipstick "without transfer" containing from 1 to 70% by weight of liquid silicone resin with repetitive units of silicates, from 10 to 98% by weight of a volatile silicone oil and powdery fillers. However, the film obtained on the lips after the evaporation of the silicone oil has the drawback of becoming uncomfortable in the course of time (feeling of dryness and tightness). Lip colors ** without transference are also known which contain a volatile silicone and a silicone resin comprising an esterified chain pending having at least 12 carbon atoms.The red lipstick film has the main disadvantage of lacking of convenience in the application, in particular of being too dry Thus, in a general manner, the association of volatile oils with certain silicone compounds allows obtaining a result "without satisfactory transference". However, the films obtained after the application of these compositions and the evaporation of the volatiles have, however, the disadvantage of being relatively matte and thus lead to a poor gloss. Therefore, there remains a need for a cosmetic composition that transfers little or nothing at all, ie, of a "non-transfer" composition, which may be good cosmetic properties., and in particular that - allows obtaining a film that can be, at choice, more or less bright. The object of the present invention is to propose a composition that makes it possible to obtain a film of very good behavior, that does not transfer and that does not stain a support with which it would be in contact, and that does not migrate with the course of time, allowing to obtain a makeup and / or a bright movie. Thus, an object of the invention is the use in a composition susceptible to be applied to the skin, the semi-mucous and / or mucous membranes, of a polymer system comprising an aqueous dispersion of smoke polymer particles, said polymeric system allowing obtaining a film having a Young's modulus of less than about 200 MPa. Another object of the invention is the use to make-up, protect and / or treat non-therapeutically the skin, the semi-mucous and / or mucous membranes, in particular the lips of the face, of said olimeric system or of a -composition comprising it. Another object is the use for the manufacture of a composition intended to therapeutically treat the skin, semi-mucous membranes and / or mucous membranes, in particular the lips of the face, of a polymer system or of a composition. Crue understands it.

Another object is a composition susceptible to be applied to the skin, the semi-mucous membranes and / or the mucous membranes, mainly a lip-red composition without trans ferensia, it comprises a polymeric system comprising an aqueous dispersion of polymer particles. filmóge no, said polymeric system allowing the obtaining of a film having a Young's modulus less than about 200 MPa. It has been found that the composition according to the invention is easily applicable and extends in a simple and uniform manner on the skin, the semi-mucous membranes and the mucous membranes, in particular on the lips of the face. The composition according to the invention finds a particularly interesting application in the field of treatment and / or make-up of the skin, mucous membranes and / or semi-mucous membranes. It is understood primarily by mucosa, the inner part of the lower eyelid; between the semi-mucous membranes, it is understood more particularly - the lips of the face. The composition according to the invention allows obtaining a homogeneous film, which has a light texture and which is comfortable to wear throughout the day. The film is not adherent at all, being soft, manageable, elastic and flexible on the skin; it adapts to the movements of the support on which it is deposited, without grinding and / or detaching. Adheres - mainly perfectly on the lips of the face. The composition according to the invention finds a very particular application in the field of products -of make-up of the lips of the face, mainly -as red lips. It also finds another advantageous application in the field of eyeliners. On the other hand, the film obtained can be very bright, or more or less matte, depending on the nature of the constituents of the composition, from which a wider range of make-up, brightener or matte products is deduced, at your choice. Therefore, the composition according to the invention comprises a polymer system comprising at least an aqueous dispersion of smoke polymer particles. Among the smoke-forming polymers which can be used in the framework of the present invention, mention may be made of synthetic polymers of the polycondensate or radiolime type, polymers of natural origin, and mixtures thereof. They may also be made, among policonden-SADOS, the anionic, cationic, nonionic or amphoteric polyurethanes, polyurethane-asrílicos, the -acrílicos polyurethanes, polyurethanes-polyvinylpyrrolidones, -poliéster-polyurethanes, polyether-polyurethanes, po liureas, polyurethane-polyurethanes, and their mixtures. The polyurethane may be, for example, an aromatic copolymer poliureta not, polyurea / urethane or polyurea, alifátiso, cycloaliphatic or comprising, alone or in mixture, - at least one aliphatic polyester origin sequence -linear or branched and / or cycloaliphatic v / o aromatic, v / o at least one sequence of aliphatic - and / or cycloaliphatic and / or aromatic polyether origin, and / or at least one siliconized sequence, whether or not substituted or not, for example polydimethylsiloxane or poly. e-tylphenylsiloxanes, and / or at least one sequence comprising fluorinated groups. The polyurethanes as defined in the invention can also be obtained from beef-polyester, branched or not, or alkyds comprising hydrophilic antigens phones that are modified by reaction with a diisocyanate and a bifunctional organic compound (for example dihydro, diamino or hydroxyamino), comprising also either a carboxylic acid or carboxylate group or a sulphonic acid or sulphonate group, or alternatively a neutralizable tertiary Arina group or an ammonium group - quaternary. Mention may also be made of polyesters, amide polyesters, polyester chain polyesters, polyamides, and epoxy ester resins.

The polyesters can be obtained, in a known manner, by polycondensation of aliphatic or aromatic diacids with aliphatic or aromatic diols or polyols. As aliphatic diacids, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid or sebacic acid can be used. As aromatic diacids, terephthalic acid or isophthalic acid can be used, or else a derivative such as phthalic anhydride. As aliphatic diols, ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, cyclohexane dimethanol, 4,4"- (1-methylpropylidene) bisphenol can be used.As polyols, they can be used to glycerol, pentaerythritol, sorbitol, trimethylolpropane, amide polyesters can be obtained analogously to polyesters, or polycondensation of diacids with diamines or amino alcohols.As diamine, ethylenediamine, hexamethylenediamine, meta- As para-phenylene diamine, the monoethanolamine can be used as the anionic group-carrying monomer which can be used during the polycondensation, for example dimethylol propionic acid, trimethic acid or a derivative such as trimellitic anhydride or a derivative such as trimellitic anhydride, the sodium salt of 3-sulfo-entanediol acid, the sodium salt of 5-sulfo-1,3-benzenedicarboxylic acid. The fatty chain polyesters can be obtained by the use of fatty chain diols during the polycondensation. Epoxiester resins can be obtained by polysondensation of fatty acids with a condensate at the ends of the polymers of the radical type can be mainly polymers, or copolymers, acrylic and / or vinyl. preferably anionic radical polymers: As an anionic group-carrying monomer which can be used during radical polymerization, acrylic acid, methacrylic acid, crotonic acid, maleic anhydride, 2-acrylamido 2-methyl acid may be mentioned Sulfonic propane The acrylic polymers can result from the co-polymerization of monomers selected from the stealers and / or the amides of acrylic acid or methacrylic acid As an example of thioo ester monomers, there may be mentioned methyl methacrylate, ethyl methacrylate, butyl methacrylate, isobutyl ethacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate. amide-typeomers, there may be mentioned N-t-butyl acrylamide and N-t-octyl acrylamide. Acrylic polymers obtained by the polymerization of ethylenically unsaturated monomers containing hydrophilic groups, preferably non-ionic in nature, such as hydroxyethyl acrylate, 2-hydroxypropyl acrylate, hydroxyethyl methacrylate, 2-hydroxymethacrylate, are preferably used. -propyl. Vinyl polymers can result from the homopolymerization or copolymerization of monomers selected from vinyl esters, styrene or butadiene. As an example of vinyl esters, mention may be made of vinyl acetate, vinyl neodecanoate, vinyl pivalate, vinyl benzoate and vinyl t-butyl benzoate. It is also possible to use acrylic copolymers / silicones, or even nitrocellulose / acrylic copolymers. The polymers of natural origin, possibly modified, can be chosen among the gum resin, ac, gumpaste, dammars, elemi, copal, cellulose derivatives, and their mixtures. Mention may also be made of the polymers resulting from the radical polymerization of one or several radical atoms inside and / or partially on the surface, of pre-existing particles of at least one polymer selected from the group constituted by the ooliu -retans, polyureas, polyesters, polyestera-midas and / or alkyds. These polymers are genetically called hybrid polymers. The aqueous dispersion comprising one or more smoke-forming polymers can be prepared by the person skilled in the art on the basis of his general knowledge, in order to improve the smoke character of a polymer, for example by reducing its vitreous transition temperature, it is possible to add a coalescing agent to the dispersion, which can be chosen from the known coalescence agents. In the present description, "fumino polymer dispersion" means a dispersion capable of forming a film, comprising or not comprising a coalescing agent. The dry matter content of said aqueous dispersions according to the present invention may be of the order of 5-60% by weight, preferably 30-40%. The composition may comprise 1-60% by weight, preferably 5-40% by weight of dry matter of polymeric polymers. The size of the polymer particles in aqueous dispersion may be between 10 * 500 nm, and preferably between 20 and 150 mm, which makes it possible to obtain a film having a considerable brightness, in order to realize the present invention, it is necessary, therefore, that the polymer system allows obtaining a film on the support on which it is deposited. Said film must have, in the measurement conditions defined before the examples, a Young's modulus of less than about 200 MPa, preferably less than about 100 MPa, and preferably less than 80 MPa. On the other hand, in a preferred embodiment, said polymer system can be chosen so as to allow obtaining a film having an elongation greater than about 200% and preferably, greater than 300%, and / or a hardness less than 110, preferably less than 70, more preferably less than 55. The methods of measuring the elongation, the hardness and the Youns modulus (modulus of elasticity) are described before the examples. In order to obtain the Young's modulus and eventually the desired hardness and / or elongation, the polymer system according to the invention may comprise, in addition to the aqueous dispersion of filmo polymer particles, a compound capable of influencing this. or these characteristics, namely, a plasticizing agent. Said plasticizing agent can be chosen among all the compounds known to the person skilled in the art as capable of fulfilling the desired function. This agent may be water-soluble or insoluble in water and may optionally be in the form of an aqueous dispersion. In particular, customary plasticizers, such as: glycols and their derivatives such as diethylene glycol ethyl ether, diethylene glycol methyl ether, diethylene glycol butyl ether or even diethylene glycol hexylene, ethylene glycol can be mentioned, alone or as a mixture. ethyl ether, ethylene glycol butyl ether, ethyl hexylene glycol; - esters of glycerol, propylene glycol derivatives and in particular propylene glycol phenyl ether, propylene glycol diacetate, di propylene glycol butyl ether, tripropylene glycol butyl ether, propylene glycol methyl ether, dipropylene glycol ethyl ether, tripropylene glycol methyl ether and diethylene glycol methyl ether, propylene glycol, butyl ether, esters of mainly carboxylic acids, such as citrates, phthalates, adipates, carbonates, tartrates, phosphates, sebacates, oxyethylenated derivatives such as oxygenated oils, mainly vegetable oils such as castor oil; the silicone oils. water-soluble or aqueous dispersion polymers, having a low vitreous transition temperature, lower than 25 [deg.] C., preferably lower than 15 [deg.] C. The amount of plasticizing agent can be chosen by the person skilled in the art on the basis of his general knowledge, - in order to obtain a polymeric system that leads to a film having the desired mechanical properties, while retaining cosmetically acceptable properties in the composition. The composition can also comprise at least one water-soluble dye and / or at least one pigment, used in the usual way in the field of cosmetics and skin care. By pigments, it is necessary to comprise white or colored particles, mineral or organic, insoluble in the medium, intended to color and / or opacify the composition. The pigments may be present in the composition in a proportion of 0-20% by weight of the final composition, and preferably in a proportion of 1-5%. They can be - white or colored, mineral and / or organic, of usual size or nano-electric. Mention may be made, among pigments and mineral nanopigments, of zirconium or cerium titanium oxides, as well as oxides of zinc, of iron or of chromium, of ferric blue. Among the organic elements, one can cite carbon black, and barium, strontium, calcium, aluminum lacquers. Among the water-soluble dyes, mention may be made of the usual dyes of the field considered, such as the poppy disodium salt, the alizarin green disodium salt, the quinoline yellow, the trisodium salt of amaranth, the disodium salt of -tartrazine, the monosodium salt of rhodamine, the disodium salt of fuchsin, xanthophyll. Any known additive can also be added to the composition according to the invention, such as thickening agents, for example clays, gums, silicas, cellulose derivatives, a synthetic polymer such as an acrylic polymer or an associative polymer of polyurethane type; a natural gum such as xanthan gum; extension agents; dispersants, preservatives; antifoaming agents; wetting agents; UV filters? perfumes; -loads; cosmetic or pharmaceutical active agents; hydrates; vitamins and their derivatives; biological materials and their derivatives. Of course, the person skilled in the art will endeavor to select this or these possible additives and / or their quantity, so that the advantageous properties of the composition according to the invention are not substantially altered by the considered addition. The pH of the final composition obtained is preferably less than 9. Well understood, this composition should be able to be deposited on a support such as skin, mucous membranes and / or semi-mucous membranes. The composition according to the invention can be present in a fluid, gelled, i-solid, manageable paste, even solid such as stick or stick. In particular, she finds a cosmetic application of makeup, mainly as lipstick, foundation makeup, shadow of cheeks or eyelid shadow, or even eyeliner. It is also possible to consider an application in the field of treatment compositions, of solar or self-tanning compositions, of dermatological compositions or even of pharmaceutical compositions or to apply on the skin, semi-mucous and / or mucous membranes. . The invention is illustrated in more detail in the following examples. A / Measurement of elongation The elongation of the film, obtained is measured according to the ASTM Standards, volume 06.01 D 2370--92"Standard Test Method for Tensile Properties of 0rga.nic Coatings *". B / Measurement of hardness The hardness of the film is measured according to ASTM D-43-66, or standard NF-T 30-016 (October 1981), with the help of a pendulum from Persoz. The film deposited on the support should have a thickness of approximately 300 microns before drying. After drying for 24 hours, at 30 ° C and under a relative humidity of 50%, a film having a thickness of approximately 100 microns is obtained.; then its hardness is measured at 30 * C and 50% - relative humidity. C / Young's modulus (or modulus of elasticity) Young's modulus (modulus of elasticity) is based on ASTM Standards, volume 06.01 D 2370-92"Standard Test Method for Tensile Properties of Organic - Coatings". The film deposited on the support should have a thickness of approximately 300 microns before drying. After drying for 7 days at 21 ° C and under a relative humidity of 50%, a film having a thickness of about 100 microns is obtained. The ués- - after measures have a width of 5 mm and a thickness of - 100 microns. The distance between the jaws is 25 mm. The traction speed is 1000 mm per minute. In the context of Example 1, a measurement is also made for a tensile speed of 10 mm per minute.

Example 1 Aqueous dispersions are prepared comprising different polymers. The composition is deposited on a support to form a film. The Young's modulus of the obtained film is measured and the behavior of the film on the lips is appreciated. The - • Young module is measured for two speeds: 10 mm / minute and 1000 mm per minute. The following results are obtained: The polyurethanes 1,2 and 4 are polyurethanes / polyesters. The polyurethanes 5 and 6 are polyurethanes / polyethers. Therefore, it is found that a suitable film is obtained, which has a good behavior and is relatively manageable, when the polymer allows the obtaining of a film having a Young's modulus less than about 200 MPa, measured at a speed-of 1000 mm per minute. This corresponds to a module lower than approximately 340 MPa measured for a speed of 10 mm / minute.

Example 2 An eye liner is prepared having the following composition: aqueous polyurethane dispersion (Young's modulus: 44.3 MPa at 1000 mm / min.) 95 g pigment 2 g - plasticizing agent (glycerin) 1.25 g A composition easy to apply on the eye contour is obtained, which gives a satin stroke and does not transfer or run.

EXAMPLE 3 A lipstick having the following composition is prepared: aqueous polyurethane dispersion (Young's modulus: 75 MPa at 1000 mm / min.) 95 g - pigment 1 g plasticizer (lyerine) 1.25 g A composition is obtained easy to apply on the lips; the film obtained is very bright; does not - transfer and does not migrate in the folds; resists well and adapts to the movements of the lips.

E-stage 4 (counter-example) A red lip is prepared having the following composition; - aqueous polyurethane dispersion (Young's modulus: 434 MPa at 1000 mm / min,) 95 s pigment 1 g plasticizing agent (glycerin). '1.25 g A film is obtained that cracks very quickly after its application on the lips. It is noted that in relation to this date, the best method known by the applicant to carry out the aforementioned invention, is the conventional one for the manufacture of the objects or products to which it refers.

Having described the invention as above, the contents of the systems are claimed as property. 15 20 25

Claims

REVIVALS 1. Use in a composition susceptible to be applied to the skin, semi-mucous membranes and / or mucous membranes, of a polymeric system comprising an aqueous dispersion of polymers of polymeric particles or allowing said polymeric system to obtain a film. having a Young's modulus less than about 200 MPa.
2. Use to make up, protect and / or treat the skin, the semi-mucous membranes and / or the mucous membranes, in particular the lips of the face, of a poiimeric system or of a composition that comprises it, comprising said system an aqueous dispersion of particles of fumarogenic polymer and which allows obtaining a film having a lower Young's modulus - approximately 200 MPa.
3. Use for the manufacture of a composition intended to treat the skin, the semi-mucous and / or the mucous membranes, in particular the lips of the face, of a polymeric system or of a composition comprising it, comprising said composition. The system comprises an aqueous dispersion of smoke polymer particles and which makes it possible to obtain a film having a Young's modulus of less than about 200 MPa.
4. Use according to one of the preceding claims, in order to obtain a film of very good behavior and / or that does not transfer and / or that does not migrate and / or that does not stain.
5. Use according to one of the preceding claims, in order to obtain a manageable and / or elastic and / or flexible film on the skin and / or a film that adapts to the movements of the skin and / or that is not cracks and / or does not detach.
6. Use according to one of the preceding claims, in order to obtain a bright film. 1 . Use according to one of the preceding claims, in which the smoke polymer is selected from: polyurethanes, polyurethanes, polyurethanes, polyurethanes, polyvinylpyrrolidones, oleares, polyurea-polyurethanes, polyester-polyurethanes , polyether-polyurethanes, polyesters, polyesters, fatty chain polyesters, polyamides, epoxy ester resins; polymers, or conical, acrylic and / or vinyl; acrylic-silicone copolymers, nitrocellulose-acrylic copolymers; polymers of natural origin, optionally modified; the cellosic derivatives; the polymers resulting from the radical polymerization of one or more radical monomers inside and / or partially on the surface of reexisting particles of at least one polymer selected from the group consisting of polyurethanes, polyureas, polyurethanes, polyesters, polyesteramides and / or alkyds; and its mixtures. 8. Use according to one of the preceding claims, in which the polymer particles in aqueous dispersion have a size comprised between 10-500 -nm, preferably comprised between 20 and 150 nm. 9. Use according to one of the preceding claims, wherein the composition comprises 1-60% by weight, preferably 5-40% by weight of dry matter of fumaric polymer. 10. Use according to one of the preceding claims, in which the polymer system allows obtaining a film having a Young modulus less than about 100 MPa, preferably less than about 80 MPa. 11, - Use according to one of the preceding claims, wherein the polymer system allows obtaining a film having an elongation greater than about 200%, preferably greater than 300%, and / or having a hardness less than 110. , preferably less than 70, more preferably less than 55. 12. Use according to one of the preceding claims, in the dream the polymer system also comprises a waste agent. 13. Use according to claim 12, wherein the plasticizing agent is chosen from glycols and their derivatives; the glycerol esters; the derivatives of propylene glycol; acid esters such as cyrates, phthalates, adipates, carbonates, tartrates, phosphates, sebacates; oxyethylenated derivatives such as oils; water-soluble or aqueous dispersion polymers, having a low vitreous transition temperature, below 25 * C, preferably below 15 ° C, and mixtures thereof, 14. Use according to one of the preceding claims, wherein the composition further comprises at least one water-soluble dye and / or at least one pigment 15. The use according to claim 14, wherein the pigment is present at a ratio of 0-20% by weight in the final composition, preferably at a rate of -1-5% by weight, 16.- Use according to one of claims 14 to 15, in which the pigment can be chosen from titanium, zirconium or cerium oxides, oxides from zinc, iron or chromium, ferric blue, carbon black, barium, strontium, calcium, aluminum lacquers and nanopignets. 17. - Use according to claim 14, in which the water-soluble dye is chosen from the poppy-disodium salt, the disodium green salt of alizar! na, the quinoline yellow, the trisodium salt of amaranth, the disodium salt of tartrazine, the monosodium salt of rhodamine, the disodium salt of fuchsin, the xanthophyll, 18. Use according to one of the preceding claims, in a make-up product such as-a red lipstick, a foundation makeup, a shadow of cheeks or a shadow of eyelids, an eyeliner; in a treatment composition; in a lonely composition; in a self-tanning composition. 19. Composition susceptible to be applied on the skin, semi-mucous and / or mucous membranes, characterized in that it comprises a polymeric system comprising an aqueous dispersion of smoke polymer particles, said polymer system permitting the obtaining of a film that has a Young's modulus less than approximately 200MPa. 20. Composition according to claim 19, allowing said composition after application-obtaining a film of very good behavior and / or that does not transfer and / or does not migrate and / or does not stain. 21. Composition according to one of claims 19 to 20, said composition allowing the application of obtaining a glossy film. 22. Composition according to one of claims 19 to 21, characterized in that the smoke polymer is chosen from polyurethanes, polyurethanes-acrylics, polyurethanes-polyvinylpyrrolidones, polyureas, polyurea-polyurethanes, polyester-polyurethanes, polyether-polyurethanes, polyesters, polyesters, amides, fatty chain polyesters, polyamides, epoxy ester resins; the polymers, or copolymers e-ros, acrylic and / or vinyl; the acrylic-silicone copolymers, the nitrocellulose-acrylic copolymers; the natural oriferous polishers, possibly modified; the cellulose derivatives; the polymers resulting from the radical polymerization of one or several radical monomers inside and / or partially on the surface of pre-existing particles of at least one polymer selected from the group consisting of polyurethanes. polyureas, polyesters, polyesteramides and / or alkyds; and its mixtures. 23. Composition according to one of claims 19 to 22, characterized in that the particles of polymers in aqueous dispersion have a size comprised between 10-500 nm, preferably between 20 and 150 nm. 24.- Composition according to one of claims 19 to 23, characterized in that it comprises 1-60% by weight, preferably 5-40% by weight of dry matter of fumaric po mous. 25. Composition according to one of claims 19 to 24, characterized in that the polymer system allows obtaining a film having a Young's modulus of less than about 100 MPa, preferably less than about 80 MPa. 26.- Composition according to one of claims 19 to 25, characterized in that the polymer system allows obtaining a film having an elongation greater than approximately 200%, preferably greater than 300% and / or having a hardness lower than 110, preferably less than 70, more preferably less than 55. 27. Composition according to one of claims 19 to 26, characterized in that the polymer system also comprises a plasticizing agent. 28.- Composition according to claim 27, characterized in that the plasticizing agent is chosen among the glycols and their derivatives; the glycerol esters; the propylene glycol derivatives; esters of acids-such as citrates, phthalates, adipates, carbonates, tarries, phosphates, sebacates; oxyethylenated derivatives such as oils; water-soluble polymers or aqueous dispersion, having a low vitreous transition temperature, lower than 25 ° C, preferably lower than 15 ° C; and its mixtures, 29. Composition according to one of claims 19 to 28, characterized in that it also comprises at least one water-soluble dye and / or at least one floor, 30.- Composition according to claim 29, characterized in that the pigments they are present at a rate of 0-20% by weight, and preferably lr-5% by weight. 31, - Composition according to one of claims 29 to 30, characterized in that the pigments are selected from the oxides of titanium, zirconium or zinc, the oxides of zinc, iron or chromium, ferric blue, carbon black, barium lacquers, estrus? calcium, aluminum, and their nanopigments. 32. Composition according to claim 29, characterized in that the water-soluble dye is chosen from the poppy disodium salt, the disodium salt of alizarin green, the yellow of quinoline, the trisodium salt of amaranth, the disodium salt of tartrazine. , the nosodic salt of rhodamine, the disodic salt of fuchsin, the xan tofila. 33.- Composition according to one of claims 19 to 32, intended to make up, protect and / or treat the skin, semi-mucous, and / or mucous membranes. 34, - Composition according to one of claims 19 to 33, characterized in that it is presented under the form of a make-up product such as a lipstick, a foundation, a shadow of the cheeks or a shadow of the eyelids, or an eye liner. 35.- Composition according to one of claims 19 to 33, characterized in that it is presented under the form of a treatment composition, a dermatological composition, a pharmaceutical composition, a solar composition, a self-tanning composition, to apply on the skin, semi-mucous membranes and / or mucous membranes. 36.- Lipless red composition, characterized in that it comprises a polymeric system comprising an aqueous dispersion of particles -fumino polymer allowing said polymeric system to obtain a film having a -Young modulus of less than about 200. MPa.