MXPA97003121A - Alquilpoliglicosidos improves - Google Patents

Abstract

The present invention relates to a composition and process for increasing the aesthetic and tactile properties of an alkyl polyglycoside which involves the combination of an alkyl polyglycoside having the general formula, RO (Z) a, wherein R is a monovalent organic radical having from about 8 to about 18 carbon atoms, Z is a saccharide residue having 5 to 6 carbon atoms, it is already a number having a value from about 1 to about 6, with an aliphatic alcohol having from 1 to about 20 carbon atoms

Description

IMPROVED ALQUILPOLIBLICOSIDOS CROSS REFERENCE TO RELATED REQUESTS This application is a continuation of part of the Application can Ha. Of Series 08 / 338,701, filed on November 10, 1994, the entire contents of which are incorporated here by reference »FIELD OF THE INVENTION The present invention relates to a composition and a process for increasing the tactile and aesthetic properties of alkyl glycosides. More specifically, by the addition of an effective amount of an additive to an alkyl glycoside, both the tactile and aesthetic properties of the glycosides are significantly improved. BACKGROUND OF THE INVENTION The aesthetic properties of alkyl glycoside solutions can be eroded in a short period of time due to the crystallization of the alkyl glycoside. Once the solutions of ally, the viscosity of the solutions is increased to the point at which handling problems are observed due to the lack of homogeneity of the product. The phenomenon of crystallization in fats and lipids is a well-known phenomenon. All Fats and lipids usually form lamellar-like structures, but each substance has different unitary cell structures, ie, polymorphism. The crystalline structure of each modification depends on the geometric conformation and the chemical bonding of a molecule 5 in which the molecular interactions differ between different segments, as for example an attic chain, uti olef ina group in e « ? pec i is unsaturated fats, a final methyl group that stabilizes the lamellar-lamella interface, a glycerol group in ai lglitoero], -COOH in fatty acid, a polar front group in polar lipids, etc. Surfactants not strongly hydrated have phase diagrams that resemble the phase diagrams of ionic surfactants, suggesting the presence of a strong repulsion force between the micelles. These strong hydration repulsion forces are often balanced by the van der Waals attractive forces between the lipid bilayers that provide a uniform blend. It is known that at a temperature below the temperature of the transition, a mixture of water-water surfing exists in the known states as cage and gel, where the hydrocarbon chains of the surfactant molecules are found. in a transverse zigzag elongated state. A difference between the cnagel and gel phases can be recognized with the naked eye. In other words, the gel phase is in a semitransparent, homogeneous state, while the coagel phase consists of a hydrated crystalline state separated from the phase of salu > :? ón in water. This is considered to be due to the difference in the mode of binding forces operating in the piolar front region in the two phases. Probably, the predominant binding force »in the coagel phase is the electrostatic interaction between cationic front groups and their cantrations, while they are in the hydration interactions of the ge > l of both with water molecules. The physical deterioration of fatty products such as margarine, lard, and chocolate, to name but a few, depends on the size, morphology, and palmar structure of the fatty crystals, all of which are influenced primarily by the ecstatic conditions and in the form secondary, by the phase transformation. The mystical parameters in the crystallization processes involve the molecular grouping, sun va tac: i ón / deso va ta ta i on, adsorption, di ff c super / / / de de de de,, rear, rear rear rear rear rear rear rear rear rear rear rear rear rear rear rear rear rear etc. etc.. A crist li a ion involves two elementary processes: nucleation and crystal growth. Nucleation occurs when the solution or the melted phases deviate from the thermodynamic equilibrium to a large extent. Three nucleation phenomena occur in real systems: homogeneous nucleation in the very pure system and with a higher activation force; heterogeneous nucleation predominates either in an impure system or with a lower activation force; the secondary nucleation that becomes important when the preexisting crystals provide secondary nuclei in such a way that the precipitation is markedly improved. Some here Ignolics have a tendency to crystallize during storage at ambient temperatures due to their oversaturated state. Upon crystallization, the Ipolyphoside alkyls become cloudy, that is, cloudy and opaque in appearance due to the solids contained therein that precipitate from their ured state which, when coupled with the inhomogeneous state resulting from the Crystallized solution and related difficulties in handling operation such as pumping, is a highly undesirable phenomenon. In order to correct this typical undesirable state, the composition of Iqui Ipol i licosides must be heated to resolve the crystals. As you can imagine, this process is expensive and requires time. Another problem related to polyethylene alkyls refers to the undesirable tactile properties they offer when in contact with the human body, commonly known in the "co-branded" industry. More paticularly, the aforementioned lipids, when epilated on the hair and / or the skin tend to make them rough, dry and sticky, as would be applied to hair spray. In general terms, they have been stitched together, due to their non-ionic character, the cmergeruca relation with other sulfates, the tendency towards important foam formation and softness in terms of skin irritation, have become highly surfactant. "10 desirable for use in the personal care products industry, however, due to its tendency to provide this highly undesirable effect of crunch when it comes into contact cot \ the human body, its use in the personal care industry, in important quantities, has been limited. Typical hydrotropes, such as ethanol and SXS, have been found to be ineffective in maintaining the homogenity of Iqlo Ipolic acid solutions, and therefore to inhibit 2 Christianization. Accordingly, the initial object of this invention is to provide a composition in a process to increase the aesthetic properties of chemical products either by reducing them to good by eliminating them. tendency to rt? It can be used for prolonged periods of storage under ambient conditions. It is also an object of this invention to eliminate the creaking in the human hair and / or the skin as a result of the treatment with cleaning compositions containing 5-alkyl or 1-joside. COMPENDIUM DG THE INVENTION Other than the examples of operation, or when indicated otherwise, all the numbers that express quantities and ingredients or reaction conditions used here Or should they be understood as if they were modified in all cases by the term "approximately". Briefly, the present invention focuses on a composition comprising a first one that has the general formula I 15 ROfZ) "". íl > where R is a monovalent organic radical having from about 12 to about 16 carbon atoms; 7 is a saccharide residue having 5 or 6 carbon atoms; and a is a number that has a value of approximately 1 to approximately 6 and an additive selected from the group consisting of sulfates cié alkyl CA-CtO, unsaturated aliphatic carboxylic acids including their derivatives with hydr? Substitution; i or its salts, mats of unsaturated aliphatic sorbides, licarboxy acids branched aliphatics C8-r3¿ > , branched aliphatic tricarboxylic acids C6-C54, at 1 μsul fosuec n nados, a second l i 1 pol igl ic? Where the alkyl group has from 4 to 12 carbon atoms, alkyl alkoxyl esters, alkyl phosphate esters and aplo, aliphatic carboxylic acids, branched or unsaturated, at 1 coho1 is unsaturated, 1o1 and *. Guerbe, aliphatic polymers C & -C18 to Icax li two, alkoxylated penter iri tol, oxygenated pente irides, alkyl and aryl sulfonates, alkyl sulphonates, alkene sulphonates, alkylammonbox i lates or modicarboxy i lato, betaines, ca boxy derivatives and imidazole sides, carboxylate surfactants, and mixtures thereof, in a weight ratio between the primary alkyl and the organic ion and the additive of approximately 500 1 to about 15: 1, respectively. The present invention also provides a process for increasing the aesthetic and tactile properties of the polymer which comprises the addition of an effective amount of a selected additive within the scope of the invention. a group consisting of C sul-CJO alquilo alkyl sulfate, unsaturated aiiphatic carbohydrate acids including derivatives with hydroxy substitution thereof or their salts, sorbitan steams with unsaturated acids, dicarba acids aliphatic branched C8- '3, aliphatic branched-chain aliphatic acids C6-C54, at Iqui Isul fosucc iton, a second at Iqu t 1 pol i gl ICÓSJ where the alkyl group has from, 4 to JO carbon atoms, alkyl alkylcoxilates, alkyl phosphate esters and alkyl, branched aliphatic carboxylic acids, unsaturated alcohols, Guerbet alcohols, alkoxylated C6-C18 iglocosides, alkoxylated penter iri tol 5, straight alkoxy esters of penteritri tol, = _u) fonatos of alkyl and aplo, sulfonates of alkyl, sulfanatas of alquemlo, al qui lamí noc arbo;;? or mixtures thereof, betaines, carboxylated derivatives of imidazoline, carboxylates, and mixtures thereof, to a The first alkyl glycoside of the formula IR (Z) < i) wherein R is a monovalent organic radical having from about 12 to about 16 carbon atoms; Z is a residue of saccharin having 5 or more carbon atoms; carbon; and a is a number that has a value of approximately 1 to approximately or. The present invention also provides a process for evaluating the tactile properties of solutions of the Ipolylosides when applied to hair and / or hair. the skin of the human being by contacting the hair and / or the skin of a human being with a composition that is based on: a) a lpol lgl icoside formula I: PO '7 > a < l > Wherein R is a monovalent organic radical having from about 8 to about 18 carbon atoms; Z is an extracting residue having 5 or 6 carbon atoms; a is a number that has a value of approximately J6 approximately and an effective amount of a 5-hydroxy acid having from 8 to approximately 36 carbon atoms; ib) a salt of an alkyl ether sulfate having an average degree of ethoxy lacióp of about 2; and (c) an N-alkoxy fatty acid amide lada, thereby providing said hair, skin, and human skin with an extensive feeling of stickiness, roughness, dryness, and combi nation: same. BRIEF DESCRIPTION OF THE IPUTES Fig1 is a bar graph illustrating the effect on the viscosity at a temperatof approximately 22.22 ° C when there are unsaturated fatty acids such as for example EMERSOL (R) 3J5, an unsaturated carboxylic acid, FMPOL < MR) 1008, an unsaturated aliphatic dihydric acid, and EMSOPB (MR) 2500, a sorbitan ester of Unsaturated alkyl is added at a level of active substances of 1.5% to GLL1C0P0M (MR) 625 CS SURFACTANT in approximately 40% active substances. Fig2 is a bar graph illustrating the effects on it. viscosity, at a temperatapproximately * - \ '~ \ p' C when the unsaturated fatty acids of Fig1 are added at a level of active substances of 1.5% to GLUCOPON (MR) 625 CSUP SURFACTANT in approximately 40% of active substances. Fig3 is a bar graph comparing the initial viscosity at 22.22"'C when the saturated fatty acids of» figt are aggregated at a level of active substances of 1.5% to GLUCOPON ÍMB) 625 CSUP SUPFACTANT at a level of active substances of approximately% versus viscosity after approximately 6 weeks of storage at 4 a.m., 4 a.C. Fig4 is a graph of Liarra which compares the initial serosity to 22. 22 * 0 when the fatty acids Nosaturates of Fig1 are added at a level of active substances of 1.5% to GLUCOPON (MP) 625 CSUP SURFACTANT at a level of active substances of approximately 40% versus the gel viscosity of about 6 anis of storage at about 450C. Fig5 is a bar graph illustrating the effect on the amount of foam formed at 22"22ßC and deionized water when the unsaturated fatty acids of Fig1 are added at a level of -finances. You go from 1.5% to TLUC0P0N (MR) 625 CS SURFACTANT at a level of approximately 40% active substances, as meas by the Ross Miles test. Fig6 is a bar graph illustrating the effect of the amount of foam formed at a temperatof 22.220C in deionized water when the unsaturated fatty acids of Fig1 are added at a level of active substances of t. 5% to GLUCOPON (MR) 625 CS SUPFACTANT at a level of approximately 40% active substances, as meas by the Poss Miles test. Fig7 is a bar graph illustrating the effect on the wetting capacity when the non-saturating fatty acids of Fig1 are added at a 1.5% active substance level to GLUCOPON (MR) 625 CS SURFACTANT in a level of approximately 4% of active substances, at a temperatof approximately 22.22 ° C in cessified water, in accordance with that meas by the wetland test of Draves. Fig8 is a bar chart qu &; illustrates the effect on the wetting capacity when the unsaturated fatty acids of Figure J are added at a level of active substances of 1.5% to GUIC0P0N (MR) 625 CS SURFACTANT at a level of approximately 4 < "% Of active substances, at a temperature of approximately 22.22 ° C in deionized water, in accordance with what is measured by the test of Moisture of Draves DETAILED DESCRIPTION OF THE INVENTION In general terms, it is desirable to improve both. The aesthetic and tactile properties of the J ili I plo iced. A glycolic surfactant is a sugar-derived surfactant typically less irritating to human skin than other surfactants, and even though it is a non-ionic surfactant, a J pol polyglycoside forms a stable foam per se, and also exerts the effect of stabilizing foam ion when combined with ammonium surfactants.Conventional body cleansers such as for example shampoos, either for the hair or for the body cont i nn surfactants ammonium compounds as a major component Due to the low skin irritation associated with the use of alkyl glycosides as the non-ionic surfactant, the use of IpoJ igl icosides as an ingredient has been an option in the fiersonal care industry. However, prior to mixing in cleaning compositions, there is a period of time during which the 3-fold polyols are shipped from the manufacturer's plant and stored in cylinders. It is during this period of time, that it seems very short, and that environmental conditions, which are stitched together, present a tendency to ristall ation, becoming turbid and more viscous. In addition, as mentioned above, the use of stitched algae as cleansers for hair and / or skin, to date, has been limited due to the aforementioned undesirable effect of crumbling caused by the 1 st igl ice. two when they come into contact with the human body. Accordingly, these bleached alkyls are used essentially in small amounts because of their cymergetic relationship with other surfactants, low level of skin irritation and tend to a significant foam formation. It has now been found "surprisingly that by adding an effective amount of the additives presented with the same amount of water, one can use three polyunsaturates as a primary surfactant in the formulation of products. for personal care, while at the same time presenting aesthetic properties that are often broken down on the basis of elimination or reduction of crystallization, together with the resulting increase in the viscosity of the 3-fold polystyrene. Accordingly, in accordance with the present invention, there is provided a composition having improved aesthetic and tactile properties, comprising a mixture of a first to a specific amount of formula I RO (7) to (I) where R is a monovalent organic radical having from about 8 to about 38 carbon atoms; Z is an extracting residue having 5 or 6 carbon atoms; and a is a numer, which has a value of approx., imadamente 1 to approximatively > , and an additive selected from the group consisting of C 6 -C 10 alkyl sulfate, aliphatic aliphatic carboxylic acids, including hydroxy-substituted derivatives of the same or their salts, esters, unsaturated aliphatic sorbitan acids, dicarbacids 1 aliphatic C8-C36 branched aliphatics, C6-C54 branched aliphatic carbohydrate carboxylic acids, alkyl sulphosuccinates, a second 3 J polyglycoside where the alkyl group has from 4 to 10 carbon atoms, alkoxylates of alkyl, esters of alkyl and pentose phosphate, branched aliphatic earboxylic acids, unsaturated alcohols, Guerbet alcohols, cycloalkyl alcohols C 6 to C 18 alkoxylated, alkoxylated penteryl tri tol, steres tie penteri tp alkoxylates, alkyl and aryl sulfonates, alkyl sulfonates, alkene sulphonates, alkyl aminecarboxylates, or well inadicarbox i latos, betas, carboxylated derivatives of idazoline, carboxylate surfers, and mixtures of isotos. * _ In one aspect of the present invention which relates to the elimination of the crystallization of alkylpolyols, The preferred polymers are the most susceptible to storage in the storage condition. Such alkyl glycosides are those that are sewn where the alk group contains 12 to 16 carbon atoms and the sugar residue is derived from glucose. Such alkyls that are made by reacting a mixture of fatty alcohols having from 12 to 16 carbon atoms and glucose and are commercially available, for example, from Henkel Corporation, as GLUCOPON (MR) 600 and GLUCOPON (MR) 625, SURFACTANT, or APG (MR) 600 and PAG 625 SURFACTANT. These alkyls have an average degree of polymerization, typically as the average number of repetitive units, or in the case of glucose units, per polymer chain, within the range of about 1.4 Approximately t.6. The pH of the alkyl glycoside is typically in the range of about 6 to about 12. The percentage levels of active substances of the phospholipid alkyls used in the present invention are within the range of about 5 to about 80. %, and preferably around 40%. The. C6-C30 alkyl sulfates which may be employed are short chain alkyl sulfates characterized by the formula P '- S04 - X + where X is Ua. 1, Mg and NH3 These sulfates may be manufactured from alkyl alcohols by sulfation S03 or by acidic or phonic sulphonates, unsaturated carboxylic acids, including their derivatives with hydroxy substitution and salts thereof, used in of the present invention have 6 to 22 carbon atoms Preferred unsaturated fatty acids include: linoleic acid and its sodium or potassium salt (readily available under the trademark EMERSOL (MP) 315); flax seed (commercially available under the trade name EMERY (MR) 643); or carboxylic acids to unsaturated acids with hydroxy substitution such as for example pinaleic acid, and mixtures thereof. It is also possible to use unsaturated aliphatic sorbides of the type where R35 and R36 is independently hydrogen or 0CP1 and where R1 is a C10-C22 hydrocarbon radical provided that x + y + z is a number between 5 and 30. Dimeric fatty acids and sodium salts can also be used the same ones that have the structure X-R2-X where R2 is a radix of C8-C36 hydrocarbon and X is COOH. Examples include the potassium salt of di-eric acid (commercially available under the trade name EMPOL (MR) 1008).

In the same way, trimeric fatty acids having from about 6 to about 54 carbon atoms can also be used as an additive. aliphatic dicarboxylic acids of the formula R3-CX- < C00H) 2 wherein R3 is a C16-C18 hydrocarbon radical and X is NH2 or N (R4) 2, where R4 is a C1-C4 hydrocarbon radical can also be used. Alkyl Ipolylics of short chain where the alkyl group has from about 4 to about 10 carbon atoms may also be employed to inhibit the crystal ionization. Alkylalcoxylates having the structure P.5- (EO) v- (PO) w-OH where R5 is a C8-C22 hydrocarbon radical, v is a number from about 0 to about 100 and w is a number of about Approximately 100, so that v + w 1, can also be used. Other additives that can be used are the alkyl sulfosuccinates characterized by the structure where R6 and R7, independently, are a saturated or unsaturated, straight or branched hydrocarbon radical, C8-C18 or H, provided that when R6 is H, R6 is not 1.8 equal to P.7, and M + is Na, K or ammonium. Alkyl and aryl phosphate esters characterized by structure 0 I Rß0-P-OM * OR 9 where R8 and R9 are, independently, a saturated or unsaturated hydrocarbon radical, straight or branched, C8-C22, which can be ethoxylated with 20 moles of ethylene oxide, or H, provided that when P.8 is H , R8 is not equal to R9, and M + is H, Na, or ammonium. Branched fatty acids of type R10-C00H, where RIO is a C4-C22 hydrocarbon radical. Unsaturated alcohols of the type R11-0H can also be empied. Guerbet spirits that has the formula where R12 and R13, independently, are a branched or straight C8-C10 hydrocarbon radical, and also Guerbet alcohol stears of the formula R14C00R15 where and R15 is a C8-C18 hydrocarbon radical. Another useful additive is a Iqui Ipol igl. alkoxylated icoside having the formula R16 ~ 0 (E0) f (PO) g (Z) n where Z is a glucose residue and n is a number of approximatively 1 to 5, f is approximately 0 to 100 and g is about 0 to 100 where f + g = 1. Ethoxylated pentertolotol and its esters having the formula CH, 0 (C2H40) AR 17 and R18 (OH4C2) 0CH2-C-CH2O (C2H40) CR CH20 (C2H40) BR; twenty where A + B + C + D is a number from 40 to 200 and where each of R17-R20 is independently H or OCR 40 where R40 is a C6-C22 hydrocarbon radical. Aliphatic alkyl and aryl sulfonates having the formula R21-S03-M + where R21 is a saturated or unsaturated straight or branched C8-C22 alkyl and aryl group can also be used. Alkylate the incarboxylates or inodicarboxylates that have the formula R22-NR23CH2CH2C00-M + where R22 is a C1-C1.8 aliphatic radical, linear or branched, saturated or unsaturated, R23 is H or CH2CH2C00- and M is Na , K, or ammonium.

Beta i nas that have the order R25 -fr Saturated or saturated aliphatic radical, R24 is methyl or 2-hydroxyethyl, X- is CH2C00- or CH2CH (0H) CH2S03-, and M + is Na, K or ammonium. It is also possible to use carboxylated derivatives of "" "imidazoline of the type R26C0NHCH2CH2NR27R28 where R26 is a C8-C22 alkyl group, straight or branched chain, saturated or unsaturated, R27 is CH2C00Na or CH2CH (0H) CH2S03N, and R28 is CH2CH20H. Carboxylate surfactants of the formula R29-C00M + where R29 is a straight or branched chain C8-C22 alkyl group, or R30C0NCH3CH2 where R30 is a C8-C22 group (ie sarcosinate), and M + is, K or ammonium. The compositions according to the present invention can also contain viscosity control additives. , for example aliphatic alcohols having from 1 to about 20 carbon atoms, an especially preferred aliphatic alcohol is ethanol. A preferred amount of viscosity control agent is from about 1% to about 20% by weight. In a preferred embodiment of the present invention, the weight ratio between the first alkyl glycolysis and the additive, present in the composition, is from about 500.1 to about 15: 1, respectively. An especially preferred weight ratio is approximately 25.1. The percentage of active substances of the alkyl glycosides is within the range of approximately 5-8%, and with a greater degree of preference than in 40%. In accordance with another aspect of the present invention, there is provided a process for increasing the aesthetic and tactile properties of alkyl glycosides that involve the addition of an effective amount of an additive to a first alkyl glycoside of formula I: ROÍ 7 > a (I) wherein R is a monovalent organic radical having from about 8 to about 18 carbon atoms; 7 is a saccharin residue having 5 or 6 carbon atoms; and a is a number that has a value of approximately 1 to approximately 6. The additives that can be used are the same as those described above.

In a preferred embodiment of the present invention, a J igic acid in accordance with formula 1 is. heated to a temperature in the range of from about 35 to about 70 * C, and preferably to about 40 < * C. The additive is then added to the heated aliquot, with stirring, in a weight ratio of from about 500: 1 to about 15: 1, and preferably about 25: 1. The addition of these types of additives reinforces the aesthetic and tactile properties of the alkylated glycosides without negatively affecting their physical properties or their performance, the practice of this invention can be observed aeiiconally taking into consideration the following 0 working examples, not limiting, and the benefits of the invention can be observed ad te nt 1 with reference to the comparison examples, INHIBITION OF CRYSTALLIZATION: EXAMPLES 5 Components of a poly jigsaw are prepared Listed in Table I. The crystallization inhibition effect of each composition was evaluated according to the following method.The results are also shown in Table I. In the examples 1-4 and in the comparative example 1, 40 grams of Glucopon (ptr) 625 CS SURFACTANT with 5% active substances, a composition of commercially available hydrochlorides available in Heni- l Corp. Ambler, PA, were loaded onto a specific pad and heated to a temperature of about 40 * C. Afterwards additives were added to the composition of alkyl glycosides with intensive mixing. After; environmental conditions were allowed to stand for a predetermined number of days. The examples were then evaluated in terms of their appearance to determine if the formation of crystals was visible to the human eye. Examples were then tested to determine their viscosities, foaming, wetting, and critical concentration of tícelas, the results of these tests, appear in Figure 1-8. TABLE I No. EMERSOL (MR) EMERSOL (MR) EMPOL (MR) EMSORB APPEARANCE 315 (l 315 (^ 1"08 (MR) 2500 j j 5 clear 2 1.5 clear _.? _5 clear 4 - . 4 - 1.5 clear Cl - cloudy * (all components are represented in grams) EMERSOL (MR) 315 < \ -) is the salt of potassium Acid lino! ico, commercially available ert Henkel Corp., Eutery Division, with 1.5% active substances. EMERSOL (MR) 315 (Na) is the sodium salt of linoleic acid, commercially available at Nkel Corp., EJmery Division, with 1.5% of active substances. "_ EMPOL (MR) 1008 is the potassium salt of dimer acid, commercially available from Henkel Corp., Emery Division, with 1.5% active substances. EMSORB (MR) 2500 is sorbitan manooleate, I will eat the Try 5 available from Hertl-eJ Corp., Emery Division, with 1.5% of all substances. Examples 5--8 and comparative example 2 1 i located in Table II were prepared in accordance with the foregoing using 80 grams of Glucopon (mr) 625 esup, with 40% of "*, 0 active substances, one commercially available alkyl composition commercially available from Hertkel Corp. The examples were then evaluated and tested, in accordance with previous Jo TABLE TI 15 No. EMEPS0L (MP) EMERS01 (MR) EMPOL (MR) EMSORB APPEARANCE :, 15 ü ") 315 (Na) 1008 (MR) 2? O 5 1.5 clear 6 1.5 clear 7 1.5 clear 8 - 1.5 Ciara C2 cloudy * (all components are represented by grams) As can be seen from the results of Tables I and JT, as well as from Figures 3-8, the addition of 25 one of Jos " , additives presented as, for example, an unsaturated fatty acid that has a terminal ammonium group significantly inhibits or retards the formation of chemical reactions of formula I, without affecting its physical properties. The improvement of the aesthetic appearance of an ali qi.ii I igj icosido is desired, it is of >If the crystallization is inhibited during storage under ambient conditions, the added additive is preferably added in a weight ratio between 1% and 15% by weight and approximately 5% by weight. s 1. T CTIL IMPROVEMENT: COMPOSITION A 336.0 grams of PLANTAREN (MR) ~ 2 ("> 00 (a commercially available 1% commercial Ic available at Hertkel Corp," Emery di ision), were heated to 50 After that, 26.9 grams of EMPOI (MR) 3088 were added, and the pH of the solution was adjusted to 7.2 with 31.6 grams of a 25% NaOH solution. The solution was to adjust the solids to approximately 50% The solution was then cooled to 25 ° C. The final product had a light yellow appearance and had a pH of 7.2 and a rool viscosity of about 2,950 cps. following formulations of? hampoo <. to determine the proportion of proportions They are defined by a composition of the active ingredients of the present invention versus a control group. FJEMPLO 9 COMPONENT% IN PFSO STANDAPOL (MR) ES-2 15. o STANDAMJI) (MR) SD 3.0 Co m p i n i A 1. e. citric acid solution, pH 6.5 2.0 water 6 .5 300. STANDAPOL (MR) ES-2 is an ammonia challenge factor that has a degree of approximately 2, available in H nl-the Corp ., Emery Division. STANDAMID (MR) SD e =. coe my DEA, available at Henl el Corp., Emery Division. EXAMPLE OF C0MARA T0N 3 COMPONENT-% IN PFSO STANDAPOL (MR) E ^, - '? 15.0 STANDAMID (MR) SD 3.0 PLANTAREN < MP) -2? 00 1. or thickener 0.5 citric acid solution, pH o, .5 2. O water 64.5 1 0. TEST PROCEDURE: Example 9 and comparison example 3 were used to wash human hair and then the sensation that it provided to the hair after washing was evaluated. The results showed that the people who used the composition of stitched 5 in accordance with the present invention had a soft and flexible shape. after washing. On the other hand, people who washed their hair with the comparison example 3 found that their hair (?) Was very sticky and tacky after washing. ** "0 Accordingly, it can be seen that by incorporating the alkyl composition of the present invention into personal care products, the resulting tactile properties are increased in an ignition manner. It will be noted, however, that in a process for washing human hair and / or skin, the amount of additive varies according to the particular type of cleaning formulation that is being used. Hair contains the following components: alkyl sulfates 08-20 C22 and their alkyls which may be ethoxylated with 1-50 moles of (EO), eocoamides and salts and a hundred of them, together with citric acid. The amount of liquid to be added will depend to a certain extent on the additional components used, others that will depend alignments. However, when the components include: (a) a first alkylated phosphate in combination with an additive selected from the group consisting of C6-C1U alkyl sulfate, unsaturated aliphatic carboxylic acids which are injected derivatives with hydroxy substitution thereof or their salts, sorbitan esters to the unsaturated isatics, branched C8-C36 aliphatic di-carboxylic acids, trie a rbox tic acids. C6 ~ C54 branched atoms, sulphonates of alkyl, a second to a polymer where the alkyl group has from 4 to 30 carbon atoms, alkyl alkylates, phosphate ester of alkyl and ring, carboxylic acids 1 ramified aliphatic alcohols, unsaturated alcohols, Guerbet alcohols, polyglycosides > C6-C38-alkyl-alkoxy, pentoyl-tri-alkoxy-alkyl ester, sulphonate and alkyl and alkyl, sulphonate, alkyl, sulphonate or alkoxy, ami noarbo;; 11 aos or imi nodi carboxylates, betaines, "carboxamide derivatives of iamidazole na, south actan" is carboxylated, and mixtures thereof; (b) alkyl sulfates) and their salts; (c) fatty acid amides, the percentage ratios for active substances of the components (a) + (b) :( c) will typically be within the range of about 1: 6 to 1: 4, and preferably Approximately 1: 1. The same applies to body cleaners. The preferred additive for use in body initiator formulations is a dicarboxylic acid having approximately 8 to about JJ6 carbon atoms. Those skilled in the art will recognize that changes can be made to the above-described embodiments of the present invention without departing from the broad concepts of the invention. Therefore, it is understood that this invention is not limited to the specific modalities presented but is intended to cover all the modifications that are within the scope and spirit. of the present invention in accordance with that defined in the scripts indicates attached ions.

Claims (7)

1. fifty

   REVIVAL ICATIONS 1. A composition of a Iq? Ig IJPosidos that includes:

   (a) A first alky1-polyglycoside having the general formula I RO (Z) to (I) wherein P is a monovalent organic radical having from about 8 to about 39) carbon atoms; Z is an extracting residue having 5 or 6 carbon atoms; and a is a number that has a value of approximately 1 to approximately 6, and (b) an a > : selected group within the group consisting of their C6-C10 alkyl phenyls, saturated aliphatic carboxylic acids including derivatives with hydroxy substitution thereof or their salts, sorbary esters such unsaturated aliphatics, branched C8-C36 aliphatic dicarboxylic acids, branched C6-C54 aliphatic branched carboxylic acids, sulphuric acid sulfates, a second to which is the same, where the Alkyl group has from 4 to 30 carbon atoms, alkyl alkoxies, alkyl and aliphatic phosphate esters, branched aliphatic carboxylic acids, unsaturated alcohols, Guerbet alcohols, 3-hydroxy-6-C18 alkoxy , alkoxylated pententptoJ, aleoxylated pentepthoxy esters, alkyl and aryl phthalates, sulphonates of 3] uilo, alchemlo sulfopates, to Iqui laminocarbo? 1 cough either - iminoti i carbsxi Jato, betaines, carboxylated derivatives of irnidazole ina, carboxylate surfactants, and mixtures of the same, in a weight ratio between the 1 1 1 1 1 located within a range

   5 from about 500: 1 to about 35: t.
2. 2. The composition of confidentiality with the rei indication 1, where said relation between said first to J, which is said additive is approximately 25: 3.
3. 3. The composition of claim 3, wherein said "additive" is an unsaturated aliphatic carboxylic acid q and includes its derivative with hydroxy substitution or its salt.
4. 4. The composition of re-indication 1, wherein said additive is an alkyl or alkyl alkyl sulfonate.
5. 5. The composition of claim 1, wherein said additive is 1 to 1 qui J ami norca rbox i to the i (itinnd ic rbox i to 6.
6. 6. The composition of the additive falls: i 3, where said additive is a C6-C10 alkyl sulfate 7. The composition ei indicates ion 1, where said additive is a branched aliphatic dicocarboxylic acid C8-

   8. The composition of the rei indicates i n t, wherein said additive is a tricyclic acid, branched aliphatic acid 06- C 4. The composition of claim 1 wherein said additive is an unsaturated aliphatic sorbitan ester. l. The composition of claim 1 wherein said additive is a single alkyl phosphate. 11. The composition of claim 1 wherein said additive is a second J q? 13 pol i and 1 icos i or where the alkyl group has from 4 to 10 carbon atoms. 12. The composition of claim 1 wherein said additive is a carboxyl alcohol. 33. The composition of the reagent 3 wherein said additive is an alkyl phosphate ester and anchor 14. The composition of claim 1 wherein said additive is a branched aliphatic carboxylic acid. The composition of claim 3 wherein said additive is an unsaturated alcohol The composition of claim 1 wherein said additive is a Guerbet alcohol 17. The composition of claim 1 wherein said additive is an aliquot. The polyacrylamide CB-C18 glycoside 18. The composition of the reagent t wherein said additive is a penter or tritoi ale oxy beat or its ester 19. The composition of claim 1 wherein said additive is a penteri ester tp bol alkoxy lactose 20. the composition>: ie claim 1 wherein said additive is a succinate or alkyl and aryl 21. The composition of claim 1 wherein said additive is urta beta ina. 22. The composition of claim 1 wherein said additive is a derivative of? imidazoline carboxy lacia. 3; . L fields of l rei v i rt d ic ic 3 where ci i cho

   5 additive is a carboxylate surfactant. 24. The composition > of claim 1 wherein said first aliquot is filled with an aqueous solution which has a percentage of active substances within the range of approximately 5 to approximately 80%. claim 24 wherein said percentage of active substances is approximately 40 * /.

   26. The composition of the rei indication 1 that has a ptl of about 7.2. 27. The composition & The rediction where dit-has salt > 1: 5 said unsaturated aliphatic caryoxylic arid is selected from the group consisting of potassium salt of Jinoleieo, a sodium salt of linolenic acid, a. The potassium of linoleic acid, a sodium salt of linolenic acid and mixtures of the same. 28. A process for improving the aesthetic and tactile properties of an alkylated polyol comprising the addition of an effective amount of a selected agent within the group consisting of C 6 -C 10 alkyl sulfates, aliphatic carboxylic acids, or aliphatic carboxylic acids. unsaturated including derivatives 0 with hydroxy substitution thereof and their salts, esters ** '> : ie sorbí so unsaturated Jifaticos, áidos, branched C8 - C36 branched aliphatic carboxylic acids, branched C6 - C54 aliphatic tpcarbui licos, its alkyl phosphonates, a a 1 i pol 1 short chain icos i where the alkyl group has de-1 4 to 30 carbon atoms, alkyl alkoxylates, esters: alkyl phosphate and aplo, acids - arbu JJ i eos branched to ticos, alcohols unsaturated, Guerbet's alcohols, at 1 μl C6-C18 glycosylates, at JOC oxides, pertte itptoJ ale: o: ally, penteptntal als or penteptntal alkoxies, sulphonates alkyl and anlous sulphonates, alkyl sulphonates » :), sulfonates of alque lo, alq? i lamí nocarboxi latos or i my nod icarbo i la to, betaines, deri ados carb? I sides of cyclozol-1a, -surfactants of carboxylate, and mixtures thereof, to a first to 1-ion-I polysulphide of formula I: P0 (Z) to (I) where R is a monovalent organic radical having immeasurably 8 to approximately 18 carbon atoms; Z is a sacral resin having 5 or 6 carbon atoms, or is already a number having the value of Approximately 1 to approximately 6. 2. The process of claim 28 wherein said first alkyl glycol and additive are present in a pontier ratio of approximately 500: 3 to approximately 15: 1, respectively.

   5"" "" "30. The process of claim 29 wherein said ratio is about 25: 1, 31. The process of claim 28 wherein said additive is a saturated aliphatic carboxylic acid including its

   5 derivative with hydroxy substitution or its salt. 32. The process of claim 31 wherein said carboxylic acid 11 co-aliphatic #: > saturated is in the form of a s l. 33. The process of the relinquishment where it has left said unsaturated aliphatic carboxylic acid is selected from the group consisting of potassium sl, lirtoleic acid, a sodium salt of Noleic acid, potassium salt of nitrogen acid, hydrogen peroxide solution, and the like: 5 34. The process of claiming 28% of the weight ratio between said first 1 st polished polyol and said additive is approximately 25: 3. 35. The process of claim 28 wherein said additive is a CJ alkyl sulfonate of alchemyl. 36. The process of re-indication 28 said additive is an alkylamino ca rbo il o or? m? nodi carbo 11 ato 37. The process of claim 28 wherein said additive is a C6-010 alkyl sulfate 38. The processing of the rei i dica in 28 wherein said aditi or 5 is a branched aliphatic dicarboxylic acid 08-C36.

   39. The process of claim 28 wherein said additive is a C6-C54 branched aliphatic branched alkyl acid.40. The process according to claim 28 wherein said additive is an unsaturated aliphatic sorbitan. 41. The process of claim 28 wherein said additive is a su1 alkyl phosphate. 42. The process of Claim 28 wherein said additive is a polysiloxane of short chain alkyl wherein the alkyl group is from 4 to 30 carbon atoms. 43. The process of re-indication 28 wherein said additive is an alkyl alkoxylate. 44. The process of claim 28 is a phosphab ester of said additive. of rent »:! and aril. 45. The process of claim 28 wherein said additive is a branched branched carfcioxilic acid. 46. The process of claim 28 wherein said additive is an unsaturated alcohol. 47. The process of claim 28 wherein said additive is a Guerbet alcohol. 4. The process of claim 28 wherein said additive is an a-lactic acid-lactic acid C8-C18. 49. The rei indication process 28 don > of said additive is a pententp ol a 1 cox i side. 50. fr l p > This is the reason for the rejection of the 2E5 where the additive is an ester penter with an alternating pressure.

   51. The process of claim 28 wherein said additive is an alkyl and a ryl sulfonate. 52. The process of claim 28 wherein said additive is a be t a. 53. The process of reimbursement 28 where said additive is a derivative carboxy 3 ada of i iidade midazal. 54. FJ process of J3 claim 28 where said additive is a surf c Lante r abo 11 ato. 55. FJ process of claim 28 wherein said ppmer alkyl phosphate is an aqueous solution having a percentage of active substances within a range of about 5 to about 80 *. 56. The process of claim 55 where said percentage of active substances is approximately 40%: 57. A process to clean the hair or skin of a human being that comprises 1-e contact of hair or human skin and combinations of the same with a toiitpasipón Je cleaning consisting of: (a) a J qu 13 po I ig J i stitched from formula J: RO (7) to J where R is a radic The monovalent organic having approximately 8 to about 38 carbon atoms; Z is a saccharide residue having 5 or 6 atoms > : ie carbon; a is a number that has a value of about 1 to about 6 and an effective amount of additive urt of 58

   dicarboxylic acid having about 8 to about 36 carbon atoms; (b) a salt of an alkyl ether sulfate having an average degree of ethoxylation of about 2; and (c) an amide of fatty acid Na +, which gives said hair, human skin and a combination thereof a sensation free of jossy stickiness, roughness, dryness and combinations thereof. the same. 58. The process of claim 57 wherein said di-carboxylic acid is selected from the group consisting of the azelaic acid, ac:? »D». r.ebáe ico, cid d? mér? »; > .3, and mixtures thereof. 59. The process of claim 58 wherein said dicarboxylic acid is a dimeric acid having approximately 36 carbon atoms. 60. The process of claim 57 wherein R in formula I is an alkyl group which has from about 2 to about 36 poplars > .ie cirbon ?. 61. The process in accordance with Claim 57 where? a in the formula J is a number of about 1.4 to ap rily 1.6. 62. A process of conferring with Claim 57 which further comprises the addition of the salt of an alkyl ether sulfate having an average degree of ethoxylation of apyloxy only 2 and a fatty acid amide N ~ a3 cox i 1. ada.

   63. The process of the reaction in which said salt of an alkyl ether sulfate is sodium laurel sulfate having an average degree of ethoxylation of apyloxy is very low.

   64. The process in claim 57 wherein said fatty acid amine N-a lc av 11 ada is crossed DEA. 65. The process of re-indication 57 where the components (a) -Ic) are combined in a percentage ratio of the active substances of (a) + (b) s (c) from Approximately 3..6 to about 3 :4. 66. The process of rei indication 65 where said relationship > of (a) + (b): (> ') is approximately 3: 3. 66. What are the fields of reference 1 that also includes a signal that is from 1 to approximately? ¿Volume of ca bonus. 67. The composition of claim 66 wherein said alcohol is ethanol. 68. The process of claim 28 wherein said additive consists additionally of an aliphatic alcohol having

   1 to approximately 20 carbon atoms. 69. The proe of J rei indication 68 where said alcohol is ethanol.