MXPA95004442A - Cosmeti compositions - Google Patents

Abstract

The cosmetic composition has an improved transfer consistency comprising: a) from about 0.1-60% by weight of trimethylated silica, b) from about 0.1-60% by weight of a volatile solvent having a viscosity from 0.5 to 100 centipoise to 25o; c) to approximately 0.1-60% by weight of a non-volatile oil having a viscosity of 200 to 1,000,000 centipoise at 25oC; and d) to approximately 0.1-80% of a cosmetically acceptable carrier

Description

1 COSMETIC COMPOSITIONS The invention relates to cosmetic compositions for application to the skin and hair. The cosmetic compositions are generally defined with compositions suitable for application to the human body. Compositions such as creams and lotions are used to moisten the skin and keep it in a soft condition and terza. Pigmented compositions such as blush base, lip pencil and scissors for eyes are used to color lips and skin, since color is one of the important reasons for using cosmetics cosmetics containing color must be formulated very carefully To provide maximum use and effect, one of the oldest problems with cosmetics such as the base, lip pencil, masks and the like is the tendency of the cosmetic to be transferred from the skin of the eyelashes to other surfaces such as articles of glass, silver or clothes. This not only produces dirt but also forces the user to reapply the cosmetic at shorter intervals. For example, traditional base compositions are emulsions of water and oil that contain pigments or can be anhydrous systems containing waxes and pigments. These formulations are applied and mixed on the skin to provide correct skin color and topography to provide a smooth and uniform appearance. The films are simply deposited on the surface and touched with the fingers to produce the transfer can be lumpy or uneven. Sweat or grease can be based on the film and cause runoff or staining if the skin comes in contact with clothes, clothes can get stained. The object of the invention is to formulate a cosmetic with a long-lasting adherence to the skin. Another object of the invention is to formulate a cosmetic that produces a film that is not disturbed when cleaned to clean grease or sweat. Another object of the invention is to formulate a cosmetic that of a film that is not transferred directly to the skin or to the utensils. Another object of the invention is to formulate a cosmetic that of a film that has low permeability to oil and water. The invention is directed to a cosmetic composition having improved strength comprising; a) about 0.1-60% by weight of trimethylated sphlisic acid; b) about 0.1-60% by weight of a volatile solvent having an approximate viscosity of 0.5 to 100 sp at 25 °; c) 0.1-60% of a non-vally oil having a viscosity of 200 to 1,000,000 sp at 25 °; d) 0.1-80% of a cosmetically acceptable carrier. The composition of the invention contains 0.1-60%, preferably 0.5-60%, more preferably 1-30%, of trimethylated silicic acid, also named s i loxica trimethyl, which are particles having an average size of 0.5 to 100 microns. The particles of the loci can be spherical or non-spherical. Volatile silicone and trimethylated lysosylic acid suitable for use in this invention may be made in accordance with US Pat. No. 4,983,388. The mixture can also be obtained from the Dow Corning Corporation under the trademarks Dow-2-0747 or 2-0749 of cosmetic fluid comprising approximately equal parts of a combination of volatile silicones (decamethylcyclopentasiloxane and octamethylcyclotetrasilxane) and s i 1 ixisi 1 icate. The solvents of the invention generally have a low viscosity of 0.5 to 100 preferably 0.5 to 20 and more preferably 0.5-10 sp to 25 °.

Volatile solvents suitable for use in the compositions of this invention include volatile low viscosity silicone fluids such as silicone silicones having the formula; CH.

Yes-0 n CH. wherein • n is from 1 to 7. Polymethyl esters are also suitable and generally have from 2 to 9 silicone atoms and are of the formula; (CH3) Si - or - (- SiCH3) 2-) n-Si (CH3) 3 where n is from 0 to 7. These silicones are available from several sources including Dow Corning Corporation and General Electric. Silicones from Dow Corning are sold under the brand names Dow Corning 244, 245, 344, 345 and 200 of fluids. These fluids comprise octa ethylcycltetrasiloxane, decamethylcyclopentasiloxane, hexamethyldisiloxane or mixtures thereof. Also suitable are volatile components in straight or branched chain hydrocarbons having from 8 to 20 carbon atoms, more preferably from 10 to 16. Suitable hydrocarbons are decane, dodecane, tetradecane, tridecane and isoparaffins with 8 to 20 carbon atoms as presented in US Patent Nos. 3,439,088 and 3,818,105. Volatile hydrocarbons have a molecular weight of 160 to 180 and a boiling range of 105 to 320 and a viscosity of less than 10 sp at 25o. Such paraffin hydrocarbons are obtainable under the trademark ISPARS, and from Permethyl Cropratin. Such paraffinic hydrocarbons with 8 to 20 carbon atoms such as isoparaffin C] ^ manufactured under the trademark Permethil 99A isoparaffin C ^ 2 are distributed per Presperse having the trademark Permethyl 99A. Several C15 isoparaffins are commercially available, such as isohexadecane bearing the trademark Permethil R Trade Mark, are also suitable. The volatile solvent can be a mixture of volatile silicoíina and isoparafinasA ratio of 1:20 to 20: 1 respectively, is suggested. The volatile solvent preferably has from 1 to 40%, preferably from 5 to 40% by weight of the total composition. The non-volatile oil has a viscosity of 200 to 1,000,000 at 25 °, preferably from 00 to 600,000 centipoise at 5 °, and has a range of 0.1-40% preferably 0.5-30% by weight of the composition. The non-volatile oil may comprise esters of the formula RCO-OR '' wherein R and R 'are each independently an alkyl, alkenyl or straight or branched chain alkoxy of 1 to 25 preferably 4 to 20 ats of carbon. Examples of such esters include isotridecyl isonidenate, PEG-4 diheptanoate, isostearyl neopentanoate, tridecyl neopentanoate, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, coco-dicaprylate / caprate, isostearate decyl, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, octyl palmitate, dioctyl malate, myristate myristyl, octododecane, as well as the esters presented on pages 24 and 26 of the CTFA Cosmetic Ingredient Handbk (manual of cosmetic ingredients) 1988 Edition. The non-volatile oil may also comprise high viscosity aceties having a viscosity of 100,000 to 250,000 cp at 25 °, such oils include castor oil, lamnin derivatives, triiscetyl ether, triglycerides of 10 to 18 carbon atoms. carbon, caprico / capric triglinides, coconut oil, corn oil, cottonseed oil, hydrogenated castor oil, oil flax seed, mink oil, olive oil, corduroy oil, ilipe bait, rape seed oil, soybean oil, sunflower seed oil, bait, tricaprine, thihydroxistear ina, tr ii sotear ina, trilaurine, Trichinolein, triamirin, triolein, tripalmi tena, tristearin, tr i 1 inolein, walnut oil, wheat germ oil, cholesterol, as well as oils set out on pages 26 and 27 of CTFA Cosmetic Ingredient Handbok, first 1988 Edition. Also suitable as non-volatile oil are glyceryl esters and derivatives such as castor oil, glyceryl stearate, glyceryl dioleate, glycoceryl distearate, glyceryl trioctanoate, glyceryl distearate, glyceryl linoleate, glyceryl myristate, glyceryl isostearate. , isostearate, PEG castor oils, PEG glyceryl oleates, glycerol stearate PEG, glyceryl PTG bait, and those that are stable on pages 28 - 29 of the CTFA Cosmetic Ingredient Handbo ok, First Edition 1988. Nonvolatile non-volatile hydrocarbon oils such as isoparaffins, hydrogenated polyisobutane, mineral oil, squalene, petrolatum, and the like are also suitable. Also suitable as non-volatile oils are derivatives such as hydrogenated lanolin alcohol lalonin, acetylated lanolin ricinoleate, lanet acetates solfates, lanolin acid, lanolin linoleate, lanolin wax, PEG hydrogenated lanolins, PEG linolines, alcohol esters PEG, and those established in page 35 of CTFA Cosmtic Ingredient Hanndbook, First Edition, 1988. Non-volatile non-fluorinated silicones are also suitable for non-volatile such silicones have a viscosity of 200 to 600,000 centicoques, preferably 350 to 100,000 centitroques at 25 °. . Suitable silicones include amodime icone, bisphene Ihexamet icona, dimethicone, dimethicone copolyol, dimethiconol, dimethicone, dimethicone sopoliol, dimethiconol, hexadecyl methicone, hexamethyl and l-disiloxane, methicone, phenyl trimethoxide, simetocona, dimet i lydrogens iloxana, dimethicone stearoxi, stearoxitrimet ilsi wool, vini ldimet icona, and mixtures thereof. Such silicones are available from Dow Corning as the formulation aid 3225C, fluids Dw 10 and 13, or similar products put on the market by Goldschmidt under the ABIL brand. Also suitable as non-volatile oils are various fluorinated oils such as fluorinated silicones or perfluoro polyesters. Fluorine silicones such as encapsulated fluorosilicone oil at the trimethylsilyl end are especially suitable., prspilmetilsiloxane, poly thiofluoro and similar silicones, such as those presented in US Pat. No. 5,118.46. The non-volatile components may comprise mixtures of fluoros and lichens and dimethyl and dimethyl polyxanes. They may also comprise perfluoro polyesters such as those presented in U.S. Patent Nos. 5,183.58, 4,803,067, and 5,183,588. These per-fluoropoly's are commercially available from Montefluos under the Fomblin brand. Other oils, non-volatile oils, include desolbitan derivatives such as sorbitan beeswax, PEG, sorbitan isostearate PEG, sorbitan lanolate PEG, sorbitan laurate PEG, sorbitan oleate PEG, sorbitan palmitate PEG, sorbitan stearate PEG, polysorbates, sirbran trioleate , sorbitan steroquattes, sorbitan stearates, sorbitan trioleates, sorbitan sorbitrate and the like, as set out on page 44 of the CTFA Cosmetic Ingredient Handbook, First Edition 1988. The compositions of the invention contain 0. 1 to 80% of a cosmetically acceptable carrier which may be a water / oil emulsion, a colored cosmetic such as liquid flush or powder based, shadows, mascara, concealer, lipstick and the like.

Creams and lotions are generally water and oil emulsions containing water, humectants, surfactants, preservatives, sunscreen, dry particulate matter and the like. Generally the ranges are 0.1-80% water, 0.01-10% humectants, 0.01-5% surfactants, 0.001-5% preservatives and 0.001-5% sun protectants. Suitable moisturizing emulsifiers, active surfactants, presevatives and sunscreens are established in the CTFA Cosmetic Ingredient Handbook, First Edition 1 88. The creams can be anhydrous or watery, and water, moisturizers, active tense, thickeners rotectores of sun, preservatives as mentioned above, can also be included. The creams and lotions of the invention are particularly good vehicles for sunscreens. In particular about 0-01-10% by weight of various sun-protecting compounds such as PABA and derivatives thereof can be incorporated in the cream or lotion because they exhibit superior transfer resistance characteristics, the sunscreens will also be able to remain on the skin for a longer period of time. Suitable creams according to the invention are the sun shields comprising; i-csu / - ae aciao silicon trimetiiataüo l-4-u% ae solvent voiatn? . _ > -5.5% non-volatile oil 0.1-70% dry particulate matter Dry particulate matter is selected from titanium dioxide and other powdered materials that provide good protection against the sun, usually titanium dioxide forms most of the dry matter . Preferably the compositions comprise a carrier which is a colored cosmetic composition such as lipstick, powder, blush, powder or liquid base shades and the like. Suitable facial powders generally contain a dry particulate matter having a particle size of 0.02 to 200, preferably 0.5 to 100 microns. The particulate matter may be colored or non-colored, for example white, and in particular the pigments are considered as powders for the purposes of this invention. Suitable powders include bismuth oxychloride, mica with titanium, smoked silica, spherical silica, polymethyl methacrylate teflon, boron nitride, acrylate polymer, aluminum silicate, octenyl succinate, aluminum starch, benonite, calcium silicate, cellulose, chalk , corn starch, diatomaceous earth, Fuller's earth, glyceryl ally, bectorite, hydrated silica, kaolin, magnesium aluminum silicate, magnesium carbonate, magnesium hydroxide, magnesium silicate, magnesium trisilicate, maltodextrin, montmorillonite , microcrystalline cellulose, rice starch, silica, talc, mica, titanium dioxide, zinc laurate, zinc myristate, zinc neodecanoate, zinc rosinate, zinc stearate, polyethylene, alumina, atapulgi-t, calcium carbonate, Calcium silicate, tracer, naylon, siliceous silicate, silk powder, sericite, soybean meal, tin oxide, titanium hydroxide, phosphate, nut shell powder, or mixtures thereof ism. The above powders can be surface treated with lecithin, amino acid, mineral oil, silicone oil and various other agents, alone or in combination, which cover the surface of the powder and turn the hydrophobic particles. The powder component may also comprise various organic and inorganic pigments, the organic ones being various aromatic types including azo, indigoid, triphenylmethane, anthraquinone, and canteen dye which are designated as DAC and FDC blue, cafes, oranges, red rings and the like. The organic pigments consist of insoluble metal salts or classified color additives that are referred to as "Lakes".

Inorganic pigments include colored iron oxides of chromium and ultramarine hydroxide and chromium and mixtures thereof. The percentage of pigments used in the powder component will depend on the type of cosmetic formulated, blushes, shades, lip pencils and the like will contain higher percentages of the pigment in the powder phase usually from 5 to 50% of the total composition. Generally the pigment powder ratio is 1:20 to 20: 1. The usual powder compositions comprise; 0.1-60% sil.xysilicate trimethyl; 0.1-60% of a volatile solvent having a viscosity of 0.5 to 100 sp at 25 °; 0.1-60% of a non-volatile oil having a viscosity of 200 to 1,000,000 cp at 25 °; and 0.1-80% of a dry particulate material. The composition of the invention can also be incorporated into masks that generally comprise a film, waxes, emulsifiers and pigment. Mask compositions are; 0.1-15% trimethyl siloxysilicate; 0.1-40% of a volatile solvent having a viscosity of 0.5 to 350 cp (centipoise) at 25 °; 0.1-10% of a non-volatile oil; 0.1-30% dry particulate material; 0. 1-20% film maker; 0.1-30% yield; 0.1-10% emulsifier. Preferably the volatile solvent comprises a mixture of a volatile silicone and a volatile hydrocarbon and the dry material comprises a combination of pigments and non-pigment powders. Suitable film formers include acacia gum, cellulose derivatives, guar derivatives, and those set forth on pages 68-69 of the CTFA Cosmetic Ingredient Handbook First Edition, 1988. Suitable waxes have a boiling point of 33 to 45 ° and include natural and synthetic waxes such as blackberry wax, beeswax, candelilla wax, carnauba, ceresin, cetyl esters, hydrogenated jojoba oil, hydrogenated jojoba wax, bran wax, rice wax, Japanese wax, jojoba butter , jojoba oil, jojoba wax, lanolin wax, bison, montanic acid, ouricuri, rice bran, ozokerite, lacquer, synthetic beeswax, and synthetic wax etc. Suitable emulsifiers are like those established on pages 90-94 of the C.T.F.A Cosmetic Ingredient Handbook, First Edition 1988. The composition of the invention can also be incorporated in water and oil for bases. The base or Makeup usually contains water and pigment, in addition to an oil base. Suitable base cosmetic compositions comprise; 0.1-20% trimethyl siloxysilicate; 0.1-40% of a volatile solvent with a viscosity of 0.5 to 350 centistokes; 0.1-25% of a volatile oil having a viscosity of 350 to 1,000,000 cp at 25 °; 0.1-70% dry particulate material having a particle size of 0.2 to 100 microns; 0.1-50% water. Preferably the non-volatile oils are dimethicone and dimethicone copolyol and the pigment to powder ratio is from 1:20 to 20: 1. The cosmetically acceptable vehicle can also be a blush; those comprising; o.l-20% trimethyl siloxysilicate; 0.1-30% of a volatile solvent having a viscosity of 0.5 to 100 cp at 25 °; 0.1-25% of a non-volatile oil with a viscosity of 200 to 1,000,000 cp at 25 °. 0.1-10% water; 0.1-70% dry particulate material with a size of 0.02 to 100 microns.

In the above compositions it is preferred that the non-volatile oils are dimethylhydrogen, siloxane, dimethicone, dimethiconol, and fluoro silicone. The cosmetic vehicle can be a shadow, the shadows contain pigment or dust as well as waxes and oils. Preferred shading compositions comprise; 0.1-20% trimethyl siloxysilicate; 0.1-30% of a volatile solvent having a viscosity of 0.5 to 100 cp at 25 °; 0.1-40% oil does not voltail; 0.1-60% dry particulate material having a particle size of 0.02 to 100 microns. In the above shade composition it is preferred that the volatile solvent comprises cyclomethicone and the non-volatile oil comprises dimethiconol. The cosmetically acceptable vehicle may also be a concealer which generally comprises the pigment, powder, wax and other such preservative moisturizing ingredients and others such as those mentioned. A preferred composition of the invention is a corrector comprising; 0.1-15% trimethyl siloxysilicate; 0.1-40% of a volatile solvent with a viscosity of 0.5 to 100 cp at 25 °; 0. 1-35% of a non-volatile oil with a viscosity of 350 to 1,000,000 cp at 25 °; 0.1-40% of a dry particulate material with a particle size of 0.2 to 100 microns. In that corrector composition it is preferred that the non-volatile oil have fluorinated silicone dimethylpolysiloxane, or mixtures thereof. The acceptable cosmetic vehicle can be a lipstick. These lipsticks comprise wax, oil and pigment. Preferred compositions comprise; 0.1-60% trimethyl siloxysilicate; 0.1-60% volatile solvent, 0.1-60 a non-volatile oil; 0.1-80% dry particulate material; 0.1-40% wax. Lipstick compositions may contain one or more antioxidant preservatives thickeners emulsifiers and the like. The ingredients may be selected from those set forth in the C.T.F.A Cosmestic Ingredient Handbook, First Edition, 1988. The compositions of the invention provide cosmetic that adhere well to the skin and exhibit improved transfer resistance. The invention will be further described with reference to the following illustrative examples.

EXAMPLE 1 A base composition or makeup was made as follows; % WEIGHT 1 Ciclomethicone / dimethicone copolyol 20.85 1 Cesquiolate orbital 0.05 1 propylparaben 0.10 1 titanium dioxide 8.00 1 red iron oxide / methicone 0.47 1 Yellow iron oxide / methicone 1.16 1 Black iron oxide / methicone 0.18 1 Mica / dimethicone 0.98 2 Naylon 12 / lecithin 2.00 2 Boron nitride 4.00 3 Cyclomethicone 1.0 3 Dimethicone 1.50 3 Dow Corning 2-0747 15.00 3 Tribejenin 2.00 4 Glyceryl glycinate / isoparaffin C9-11 5.00 5 Water 30.00 6 Methylparaben 0.20 6 Trisodium EDTA 0.20 6 Glycol Eutylene 4.50 7 Alcohol DS 40b 3.0 the ingredients of sequence 1 were ground in the colloidal mill one after the other until there was no color or white not dispersed. Then ingredients 2 were milled until dispersed in the main beaker sequence 1 and 2 were loaded and heated to 55-60 °. Then sequence 3 was added. When all the tribegenin was fused the ingredients of the sequence 4 the ingredients of sequence 5 were added to the aqueous phase in a lateral beaker and a pre-mixing of the ingredients of sequence 6 was heated to 50-55 °. Just prior to the emulsification, the ingredients of the sequel 7 were added to the aqueous phase. The aqueous phase and the oil phase were then mulsified using a homogenizer for 15 minutes, the mixture was cooled using a paddle mixer. EXAMPLE 2 A mask composition was made as follows; % in weigh Carnauba wax 4.25 Wax candelilla 9.25 Sheep wax 4.60 Synthetic wax 4.85 BHA - - 0.05 Parabens of propyl 0.10 Glioerol rosinate Isoparaffin 12.00 9 to 11 carbon atoms. Acid Lanolin 6.00 Isododecano 16.40 Oleilo Alcohol 1.00 Black iron oxide 10.00 Silica 4.50 Polyethylene 2.00 Water 7.60 Methyl paraben 0.35 Sodium EDTA 0.10 Sodium dehydroacetate 0.30 Yeast of glycoprotein 1.00 Ammonium Keratin 0.05 Ammonium hydroxide 0.60 Dow Corning 2-0747 15.00 The ingredients were mixed one after the other. EXAMPLE 3 A blush was made as follows; % IN WEIGH Cosmetic fluid Dow Corning 32.50 Silastico Dow Corning 07-4350 5.50 (silica, methyl siloxane and methyl vinyl) Dimethicone / dimethiconol 3.00 Boron Nitrate 5.00 Talc 4.00 Water 2.00 Ethylene alcohol 3.00 Iron oxide 3.00 Red lacquer No.30 1.80 Titanium dioxide 4.00 Quaternium 18 hectorite / cyclomethicone 20.00 Cyclomethicone 12.20 Trifluoropropylmethylpolysiloxane 4.00 (Dow Corning FS-1265) EXAMPLE 4 A corrector was made as follows; % IN WEIGH Dow Corning 2-0747 20 .00 Iron oxides 4, .00 Titanium Dioxide 14, .00 Talc 8, .00 Water 3 .00 Ethylene alcohol 3. .00 Silastico Dow Corning 07-4350 7, .00 Dimethyl polysiloxane 10,. 00 Ciclomethicone 19, .00 Trifluoropropylmethyl polysiloxane 4, .00 (Dow Corning FS-1265) EXAMPLE 5 Eyeshadows were made as follows; % IN WEIGHT Talc Mica 22-41 20.00 Zinc stearate 1.50 Talc / polyethylene 5.00 Mica / titanium dioxide Polyethylene 10- °° 1.50 Oxychloride 4.49 Titanium Dioxide 4.00 Black iron oxide 0.15 Yellow iron oxide 0.35 Red iron oxide 0.60 Dow Corning 2-0747 22.00 Cyclone icona 2.00 Cyclomethicone / dimethiconol 3.00 caprylate cocoate 3.00 EXAMPLE 6 A sun blocking cream was made as follows; % ON WEIGHT Dow Corning 2-0747 30.00 Iron oxides 3.50 Titanium dioxide 20.00 Zinc oxide 5.00 Boron nitrate 8.00 Syllable Dow corning Q7-4350 7.00 Hexamethyl disiloxane 10.00 Cyclomethicone 11.50 Trifluoropropylmethyl polysiloxane 5.00 EXAMPLE 7 The shading formula of Example 5 (ES) was subjected to a sample test. Three models were requested to apply eye shadows on the eyelids. Fourteen hours later the models were shown to perform the analysis as follows; DO NOT. OF MODELS IF IT WAS NOT Smooth and creamy 3 0 It was easy to apply 3 0 Does the ES have a good deposit? 3 0 Does the ES have good coverage? 3 0 Does ES look good? 3 0 How long did the ES stay? 12 hours-2 models 10 hours-1 model

Claims (2)

1. NOVELTY OF THE INVENTION Having described the present invention as above, the content of the following is claimed as property; CLAIMS 1.- A cosmetic composition comprising; a) about 0.1 to about 60% by weight of trimethylated silynic acid also called trimethyl siloxysilicate; b) from about 0.1 to approx. 60% by weight of a volatile solvent having a viscosity of 0.5 to 100 centipoise at 25 °; c) about 0.1 to about 60% by weight of a non-volatile oil having a viscosity of 200 to 1,000,000 centipoise at 25 ° and d) about 0.1 to 80% of an acceptable carrier as a cosmetic.
2. 2. A composition according to claim 1, wherein the trimethyl siloxysilicate has an average particle size of about 0.5 to 100 microns. - - 3. a composition according to claim 1 and 2, wherein the volatile solvent comprises a cyclic silicone, a linear silicone, a paraffin with 8 to 20 carbon atoms or a mixture thereof. 4. A composition according to any of the preceding claims comprising; a) 0.5-50% trimethyl silosilicate; b) 1-40% of a volatile silica; c) 0.1-40% by weight of a non-volatile oil; d) 10-70% of a carrier acceptable as a cosmetic. 5. A composition according to a preceding claim wherein the carrier acceptable as a cosmetic is in the form of a lotion. 6. A composition according to any of claims 1 to 4 wherein the cosmetically acceptable carrier is in the form of an anhydrous cream. 7. A composition according to claim 6, comprising; a) 1-30% trimethyl siloxysilicate; b) 1-40% volatile solvent; c) 0.5-30% non-volatile oil; d) 0.1-70% dry particulate material. 8. A composition according to one of claims 1 to 3, wherein the carrier acceptable as coswmeti is in the form of a face powder 9. A composition according to claim 8, having the formula: a) 0.1-60 % trimethyl siloxiliciato; b) 0.1-80% a volatile solvent; c) 0.1-60% non-volatile oil; d) 0.1-80% dry particulate material having 5 to 50% pigment in the powder phase. 10. A composition according to one of claims 1 to 3, wherein the carrier acceptable as a cosmetic is in the form of a mask. 11. A composition according to claim 10, comprising; a) 0.1-15% trimethyl siloxysilicate; b) 0.1-40% of a volatile solvent; c) 0.1-10% non-volatile silicone; d) 0.1-30% dry particulate material having from 5 to 50% pigment in the particle phase; e) 0.1-20% film former; f) 0.1-30% wax; and g) 0.1-10% emulsifier. 12. A composition according to one of claims 1 to 3, wherein the cosmetic acceptable carrier is in the form of a water or oil emulsion base or foundation. 13. A composition according to claim 12, comprising 0.1 20% trimethyl siloxysilicate; b) 0.1-40% volatile solvent; c) 0.1-50% non-volatile oil; d) 0.1-70% dry particulate material; which has a pigment to powder ratio of 1020 to 20: 1; and e) 0.1-50% water 14.- a composition according to any of claims 1 to 3, wherein the cosmetically acceptable carrier is in the form of an eye shadow. 15. a composition according to claim comprising 0.1-20% trimethyl siloylcalate; 0.1-30% volatile solvent; 0.1-40% oil4 non-volatile; 0.1-60% dry particulate material. 16. A composition according to claims 1 to 3, wherein the carrier acceptable as a cosmetic is in the form of a concealer. 17. A composition according to claim 16, comprising; 0.1-15% trimethyl siloxysilicate; 0.1-40% volatile solvent; 0.1-35% non-volatile oil; and 0.1-40% dry particulate material. 18. A composition according to claim 1 to 3, wherein the acetable carrier as a cosmetic is in the form of a lipstick. 19. A composition according to claim 18, comprising; 0.1-60% trimethyl siloxysilicate; 0.1-60% volatile silicone;

   0. 1-60% non-volatile oil; 0.1-80% dry particulate material; and 0.1-40% wax. 10 fifteen twenty 25