MXPA06011638A - Cosmetic composition comprising pigment and/or filler surface pre-treated with organic agent and electrophilic monomer - Google Patents

Abstract

Composition for the treatment of the keratinous material comprises an electrophilic monomer and a pigment and/or a filler i.e. previously treated on surface by an organic agent, where the pigment or the treated filler is different from mica covered with titanium and an organic pigment, in a medium. Independent claims are included for:(1) the process for the treatment of keratinous fibers, comprising application of the composition on keratinous fibers in presence of a nucleophilic agent+ADs- and (2) kit for the treatment of keratinous fibers, comprising a composition comprising the electrophilic monomer and optionally a polymerization inhibitor and a composition comprising a pigment and/or a filler previously treated on surface.

Description

COSMETIC COMPOSITION COMPRISING A PIGMENT AND / OR A CHARGE PREVIOUSLY TREATED ON SURFACE BY AN ORGANIC AGENT AND A MONOMERO ELECTROFILO DESCRIPTION OF THE INVENTION The present invention relates to a composition for the treatment of keratin materials such as skin, hair, eyelashes, nails, and in particular keratin fibers such as hair, which comprises, in a cosmetically medium acceptable at least one electrophilic monomer and at least one pigment and / or filler previously treated on the surface by at least one organic agent, said pigment or said filler being different from a mica coated with titanium and an organic pigment. In the field of dyeing keratin fibers, it is already known to color keratin fibers by different techniques from direct dyes or pigments for non-permanent dyes or dye precursors for permanent dyes. Non-permanent coloration or direct coloration consists of dyeing the keratin fibers with dye compositions containing direct dyes. These dyes are colored molecules and dyes that have an affinity for keratin fibers. They are applied on the keratin fibers for a time necessary to obtain Ref 176243 the desired coloration, and then clarify. The conventional dyes which are used are in particular dyes of the nitrobenzene, anthraquinone, nitropyridine, azoic, xanthenic, acridine, azinic, triarylmethane or natural dyes type. Some of these dyes can be used in clarifying conditions which allows to obtain visible colors on dark hair. It is also known to dye the keratin fibers permanently by the oxidation coloration. This coloring technique consists of applying to the keratin fibers a composition containing dye precursors such as oxidation bases and couplers. These precursors, under the action of an oxidizing agent, will form one or more colored classes in the hair. The variety of molecules used at the level of oxidation bases and copulators, allows obtaining a rich range of colors and the colors obtained are permanent, strong, and resistant to external agents, particularly light, weathering , washings, perspiration and friction. To be visible on dark hair, these two coloring techniques require prior or simultaneous discoloration of the keratin fibers. This decolorization step carried out with an oxidizing agent such as Hydrogen peroxide or persalts produces a non-negligible degradation of keratin fibers which alters their cosmetic properties. The hair then has a tendency to become rough, more difficult to disentangle and more fragile. Another method of coloring is to use pigments. In fact, the use of pigments on the surface of keratin fibers generally makes it possible to obtain visible colorations on darkened hair since the pigment on the surface hides the natural color of the fiber. The use of pigment for coloring keratin fibers is described, for example, in patent application FR 2 741 530, which recommends the use for coloration of keratin fibers of a composition comprising at least one dispersion of film-forming polymer particles comprising less an acid function and at least one pigment dispersed in the continuous phase of the said dispersion. The colorations obtained by this coloring mode have the drawback of having a low resistance to shampooing. In the field of the care of keratin materials, it is known to use fillers which confer properties of softness, gloss and, in the case of hair, volume and smoothing, to the said keratin materials. However, with classical treatment methods, the effects obtained they are often insufficient in terms of efficiency and durability. It is known from the patent application FR 2 833 489 hair treatment compositions from compositions comprising electrophilic monomers. A composition of this type allows to obtain perfectly coated and non-greasy hair. It is also known from the prior art that the polymerization of the electrophilic monomers can be accelerated by pigments or fillers. One can cite by way of example the patent US 5 290 825 which describes this phenomenon with the alkyl cyanoacrylates. The purpose of the present invention is to provide compositions for the treatment of keratin materials, and in particular of keratin fibers such as hair, which either permit visible dark coatings to be obtained without the need to lighten or discolor the fibers and which present a good resistance to washing with shampoo, or obtain a care effect in keratin materials and in particular hair that is sufficiently accentuated and durable over time and against classic treatments such as shampooing.

This aim is achieved with the present invention having as its object a composition for the treatment of the keratin materials comprising, in a cosmetically medium acceptable, at least one electrophilic monomer and at least one pigment and / or a filler previously treated on the surface by at least one organic agent, said pigment or said filler being treated on the surface different from a mica coated with titanium and a pigment organic. The composition according to the present invention allows in the case of the pigments to improve the visibility of the coloration on a dark keratin material. In particular, in the case of dark keratin fibers, a highly visible coloration is obtained without it being necessary to lighten or decolorize the keratin fibers and therefore without physical degradation of the keratin fibers. In addition, the coloration obtained has a good resistance to the various aggressions that hair may experience, such as shampooing, chafing, light, weathering, perspiration and permanent deformation. These properties are particularly remarkable in regard to the resistance of the coloration with respect to shampooing. The coloration is obtained in various shades, it is chromatic, strong, aesthetic and not very selective. Hair on the other hand has good cosmetic properties such as softness or a natural touch. In. the case of charges, compositions according to invention allow to obtain a good level of softness on the keratin materials, remaining with time and against shampooing. In addition, a good homogeneity of the effect on the keratin support is observed. On the other hand, the surface treatment of the pigments and / or fillers present in the composition according to the present invention makes it possible to obtain a good stability of the composition according to the invention. The subject of the present invention is also a method of treating the keratin fibers using the composition according to the invention, as well as the use of this composition for the treatment of keratin fibers. The subject of the present invention is also a treatment kit comprising, on the one hand, a pigment and / or a filler previously treated on the surface by at least one organic agent and, on the other hand, an electrophilic monomer. In the context of the invention, the pigment or the surface treated filler is different from a mica coated with titanium and an organic pigment, which means that the pigment or the filler treated on the surface is different from a mica coated with treated titanium. on the surface by an organic pigment. In the context of the invention, the pigments not treated on the surface have a solubility in water lower than 0. 01% at 20 ° C, preferably less than 0.0001%, and an absorption between 350 and 700 nm, preferably an absorption with a maximum. The untreated pigment on the surface, hereinafter called pigment, can be an organic pigment. By organic pigment, it means any pigment that meets the definition of the Ullmann encyclopedia in the organic pigment chapter. The organic pigment can be chosen in particular from the compounds nitrous, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex-type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone. The organic pigment (s) can be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, blue pigments encoded in the Color Index under the references Cl 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments coded in the Color Index under the references Cl 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the pigments greens coded in the Color Index under the references Cl 61565, 61570, 74260, the orange pigments coded in the Color Index under the references Cl 11725, 15510, 45370, 71105, the red pigments coded in the Color Index under the references Cl 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, the pigments obtained by oxidative polymerization of phenolic, indole derivatives such as are described in patent FR 2 679 771. These pigments can also be in the form of composite pigments such as described in patent EP 1 184 426. These composite pigments can be compounds particularly of particles comprising an inorganic core at least partially coated by an organic pigment and at least one binder which ensures the fixation of the organic pigments on the core. By way of example, mention may also be made of organic pigment pigment pastes such as the products sold by the HOECHST Company under the name: JAIME COSME YL IOG: Pigment YELLOW 3 (Cl 11710); JAUNE COSMENYL G: Pigment YELLOW 1 (Cl 11680); ORANGE COSMENYL GR: ORANGE Pigment 43 (Cl 71105); ROUGE COSMENYL R ": Pigment RED 4 (Cl 12085); CARMIN COSMENYL FB: Pigment RED (Cl 12490); VIOLET COSMENYL RL: Pigment VIOLET 23 (Cl 51319); BLEU COSMENYL A2R: Pigment BLUE 15.1 (Cl 74160); VERT COSMENYL GG: GREEN Pigment 7 (Cl 74260), NOIR COSMENYL R Pigment BLACK 7 (Cl 77266).

The pigment can also be a lacquer. By "lacquer" are meant the insolubilized dyes adsorbed on insoluble particles, the whole thus remaining insoluble in use remaining. The inorganic substrates onto which the dyes are adsorbed are, for example, alumina, silica, calcium and sodium borosilicate or calcium and aluminum borosilicate, and aluminum. Among organic dyes, mention may be made of cochineal carmine. Mention may also be made of the products known under the following names: D & C Red 21 (Cl 45 380), D & C Orange (Cl 45 370), D & C Red 27 (Cl 45 410), D & C Orange (Cl 45 425), D & C Red 3 (Cl 45 430), D & C Red 4 (Cl 15 510), D & C Red 33 (Cl 17 200), D & C Yellow (Cl 19 140), D & C Yellow 6 (Cl 15 985), D & C Green (Cl 61 570), D & C Yellow (Cl 77 002), D & C Green 3 (Cl 42 053), D & C Blue 1 (Cl 42 090). By way of examples of lacquers, the product known under the following designation may be mentioned: D & C Red 7 (Cl 15 850: 1). The pigment can also be a special effect pigment. By special effect pigments, pigments are understood that create in a general way a colored appearance (characterized by a certain tonality, a certain vivacity and a certain clarity) not uniform and changing in function of the observation conditions (light, temperature, observation angles, ...). They are opposed by the same to the white or colored pigments that provide a uniform opaque, semi-transparent or transparent classic color. There are two types of pigments with special effects, those with low refractive index such as fluorescent pigments, photochromes or thermochromes, and those with stronger refractive index such as nacres. or the sequins. As pigments with special effects, mention may be made of pearlescent pigments such as white pearlescent pigments such as titanium-coated mica, or bismuth oxychloride, colored pearlescent pigments such as mica titanium with iron oxides, mica titanium with particularly ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. Mention may also be made of pigments with interferential effect not fixed on a substrate such as liquid crystals (Helicones HC de acker), holographic interferential sequins (Geometric Pigments or Spectra f / x de. Spectratek). Pigments with special effects also include fluorescent pigments, either fluorescent substances in daylight or which produce a ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments and quantum dots, marketed for example by the Quantum Dots Corporation. The "quantum dots" are semi-conductive luminescent nanoparticles capable of emitting, under light excitation, a radiation that has a wavelength between 400 nm and 700 nm. These nanoparticles are known from the literature. In particular, they can be manufactured according to the methods described for example in US 6 225 198 or US 5 990 479, in the publications cited therein, as well as in the following publications: Dabboussi B.O. and col. "(CdSe) ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminiscent nanocristallites" Journal of physical chemistry B, vol 101, 1997, pages 9463-9475. and Peng, Xiaogang et al., "Epitaxial Growth of highly luminiscent CdSe / CdS core / shell nanocrystals with photostability and electronic accessibility" Journal of the American Chemical Society, vol. 119, No. 30, pages 7019-7029. The pigments with special effects also fluorescent pigments, either fluorescent substances in daylight or that produce an ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments.

The pigment can be a mineral pigment. By mineral pigment, it means any pigment that meets the definition of the encyclopedia. Ullmann in the inorganic pigment chapter. Mention may be made, among the mineral pigments useful in the present invention, of zirconium or cerium oxides, as well as of iron or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, the titanium dioxide. The following mineral pigments can also be used: Ta205, Ti3O5, i203, TiO, Zr02 in admixture with Ti02, Zr02, Nb205, Ce02, ZnS The pigment can also be a pearlescent pigment such as white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as mica coated with titanium and iron oxides, mica coated with titanium and particularly ferric blue or chromium oxide, mica coated with titanium and an organic pigment as previously defined as well as pearlescent pigments based on bismuth oxychloride, for example, the Cellini pigments marketed by Engelhard (Mica-Ti02-laque), Prestige marketed by Eckart (Mica-Ti02), Colorona marketed by Merck (Mica-Ti02 ~ Fe203) In addition to the nacres on a mica support, multi-layer pigments based on synthetic substrates can be considered such as alumina, silica, calcium and sodium borosilicate or borosilicate calcium and aluminum, and aluminum. The size of the pigment useful in the context of the present invention is generally between 10 nm and 200 μt, preferably between 20 nm and 80 μm, and more preferably between 30 nm and 50 μp. By filler, is meant a substantially colorless solid compound at room temperature and atmospheric pressure, and insoluble in the different ingredients of the composition, even when these ingredients are brought to a temperature above ambient temperature. The charges can be mineral or organic. The fillers can be particles of any shape, particularly platelets, spherical or oblong, whatever their crystallographic form (for example leaf, cubic, hexagonal, orthorhombic). Among the fillers which can be used in the compositions according to the invention, mention may be made of talc; the natural or synthetic mica; the silica; the kaolin; polyamide (Nylon®),?-ß-alanine and polyethylene powders; the polymer powders of tetrafluoroethylene (Teflon®); lauroyl-lysine; the starch; boron nitride; polymer powders of acrylic acid; the silicone resin microbeads, such as the "TOSPEARLS®" of the TOSHIBA Company; bismuth oxychlorides; calcium carbonate precipitate; he carbonate and magnesium carbonate; the idioxyapatite; hollow silica microspheres such as "SILICA BEADS SB 700 / HA® or" SILICA BEADS SB 700® "of the MAPRECOS Company, the" SUNSPHERES H-33® "and the" SUNSPHERES H-51® "of the ASAHI Company GLASS, acrylic polymer microspheres such as those of crosslinked acrylate copolymer "POLYTRAP 6603 ADSORBER®" of the Company RP SCHERRER and those of polymethyl methacrylate "MICROPEARL M 100®" of the SEPPIC Company, polyurethane powders such as hexamethylene diisocyanate copolymer powder and trimethylol hexyl lactone sold under the name "PLASTIC POWDER D-400®" by the TOSHIKI company, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids having from 22 carbon atoms, in particular from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate, polymer microcapsules or acrylate copolymers to methyl methacrylate, or also copolymers of vinylidene chloride and acrylonitrile, such as the "EXPANCEL®" of the EXPA CEL Company; organopolysiloxane crosslinked elastomeric powders such as those sold under the name "TREFIL POWDER E-506C" by the Dow Corning Company; and its mixtures. The charges treated at the surface or can not have an apparent diameter ranging from 0.01 to 150 pm and better than 0.5 to 150 μp ?. An apparent diameter corresponds to the diameter of the circle in which the elementary particle is inscribed according to its smallest dimension (thickness for the lamellae). The pigments and fillers previously treated at the surface useful in the context of the invention are pigments or fillers that have undergone totally or partially a surface treatment of a chemical, electronic, electro-chemical, mechanical-chemical or mechanical nature, with an organic agent such such as those described particularly in Cosmetics and Toiletries, February 1990, Vol. 105, pages 53-64 before being dispersed in the composition according to the invention. These organic agents can be, for example, chosen from the amino acids; waxes, for example carnauba wax and beeswax; fatty acids, fatty alcohols and their derivatives, such as stearic acid, hydroxystearic acid, stearyl alcohol, hydroxystearyl alcohol, lauric acid and its derivatives; the anionic surfactants; the lecithins; the sodium, potassium, magnesium, iron, titanium, zinc or aluminum salts of fatty acids, for example aluminum stearate or laurate; the metal alkoxides; polysaccharides, for example chitosan, cellulose and its derivatives; the polyethylene; (meth) acrylic polymers, for example polymethyl methacrylates; polymers and copolymers containing acrylate units; proteins; the alkanoamines; - le ¬ silicone compounds, for example silicones, polydimethylsiloxanes, alkoxysilanes, alkylsilanes, siloxysilicates; fluorinated organic compounds, for example perfluoroalkyl ethers; the fluoro-silicon compounds. The surface treatment in the sense of the present invention is such that a surface-treated pigment maintains its intrinsic pigment properties prior to treatment and a surface-treated filler retains its intrinsic load properties prior to treatment. For example, inorganic substrates such as alumina or silica on which organic dyes are adsorbed are not surface treated fillers in the sense of the present invention. The surface-treated pigments and fillers useful in the context of the invention may also have been treated by a mixture of these compounds and / or have undergone various surface treatments. The surface treated pigments and fillers useful in the context of the present invention can be prepared according to surface treatment techniques well known to those skilled in the art or found as such in commerce. Preferably, the pigments and / or the surface treated fillers are coated by an organic layer. The organic agent with which the pigments are treated and - Il ¬ the charges can be deposited on the pigments or charges by evaporation of solvent, chemical reaction between the surface agent molecules or creation of a covalent bond between the surface agent and the pigments or fillers. The surface treatment can thus be carried out for example by chemical reaction of a surface agent with the surface of the pigments or fillers and creation of a covalent bond between the surface agent and the pigments or fillers. This method is particularly described in US Pat. No. 4 578 266. Preferably, an organic agent linked to the pigments or to the fillers will be used covalently. The agent for the surface treatment may represent from 0.1 to 50% by weight of the total weight of the pigments or of the charges treated on the surface, preferably from 0.5 to 30% by weight, and even more preferably from 1 to 30% by weight. 10% by weight. Preferably, the surface treatments of pigments and fillers are chosen from the following treatments: a PEG-Silicone treatment such as the AQ surface treatment marketed by LCW; a Citosana treatment such as the CTS surface treatment marketed by LCW; a Trietoxicaprylsilane treatment as the AS surface treatment marketed by LCW; a Methicone treatment such as the SI surface treatment marketed by LCW; a Dimethicone treatment such as the Covasil 3.05 surface treatment marketed by LCW; a Dimethicone / Trimethylsiloxysilicate treatment as the Covasil 4.05 surface treatment marketed by LCW; a Lauroyl Lysine treatment as the LL surface treatment marketed by LCW; a Lauroil Lisine Dimethicone treatment as the LL / SI surface treatment marketed by LCW; a Myristate Magnesium treatment as the MM surface treatment marketed by LCW; an aluminum Dimiristat treatment as the MI surface treatment marketed by Miyoshi; a Perfluoropolimethyl isopropyl ether treatment as the FHC surface treatment marketed by LCW; an Isostearil Sebacato treatment as the HS surface treatment marketed by Miyoshi; a disodium stearoil Glutamate treatment as the NAI surface treatment marketed by Miyoshi; a Dimethicone / Glutamate disodium stearoil treatment as the SA / NAI surface treatment marketed by Miyoshi; a Perfluoroalkyl Phosphate treatment as the PF surface treatment marketed by Daito; a Copolymer Acrylate / Dimethicone and Perfluoroalkyl Phosphate treatment as the FSA surface treatment marketed by Daito; a Siloxane polymethylhydrogen / Perfluoroalkyl Phosphate treatment as the FS01 surface treatment marketed by Daito; - a Lauryl Lysine / Aluminum Tristearate treatment as the LL-StAl surface treatment marketed by Daito; an Octyltriethylsilane treatment as the OTS surface treatment marketed by Daito; - an Octyltriethylsilane / Phosphate treatment Perfluoroalkyl as the FOTS surface treatment marketed by Daito; a Copolymer Acrylate / Dimethicone treatment as the ASC surface treatment marketed by Daito; - an Isopropil Titanium Triisostearate treatment as the ITT surface treatment marketed by Daito; a Microcrystalline Cellulose and Carboxymethyl Cellulose treatment as the AC surface treatment marketed by Daito; a Cellulose treatment such as the C2 surface treatment marketed by Daito; Acrylate Copolymer treatment as the APD surface treatment marketed by Daito; - a Perfluoroalkyl Phosphate / Triisostearate Isopropyl Titanium treatment as the PF + ITT surface treatment marketed by Daito. The surface treated pigment (s) are generally present in the composition in total amounts generally comprised between 0.05 and 50% by weight of the total weight of the composition, preferably between 0.1 and 35% by weight, even more preferably between 0.5 and 20% in weigh. The surface-treated filler or fillers are generally not present in the composition in total amounts comprised between 0.05 and 95% by weight of the total weight of the composition, preferably from 0.1 to 50% by weight, even more preferably from 0.5 to 30. % in weigh. The composition according to the present invention can also comprise one or more charges not treated on the surface. The composition according to the present invention can also comprise one or more pigments not treated on the surface. By "electrophilic monomer" is meant a monomer capable of polymerizing by anionic polymerization in the presence of a nucleophilic agent. By anionic polymerization is meant the mechanism defined in the work "Advanced Organ c Chemistry", Third Edition by Jerry March, pages 151 to 161. Nucleophilic agents capable of initiating anionic polymerization are known systems capable of generating a carbanion in contact with an electrophilic agent, such as the hydroxide ions contained in the water at a neutral pH. Carbanion is understood to refer to the chemical classes defined in the "Advanced Organic Chemistry" book, Jerry March Third Edition, page 141. The electrolyte monomer (s) present in the composition of the invention can, for example, be chosen from: - the benzylidene malononitrile derivatives (A), 2- (4-chloro-benzylidene) -malononitrile (Al), ethyl 2-cyano-3-phenyl acrylate (B), 2-cyano-3 ~ (4-chloro-phenyl) acrylate of ethyl (Bl) described in Sayyah, J. Polymer Research, 2000, page 7: (A) (A1) (B) (B1) methylidenomalonate derivatives such as diethyl 2-methylene malonate (C) described by Hopff, Makromoleculare Chemie, 1961, page 95, De Keyser, J. Pharm. Sci, 1991, page 67 and Klemarczyk, Polymer, 1998, page 173: (C) 2-ethoxycarbonylmethyleneoxycarbonyl ethyl acrylate 3 (D) described by Breton, Biomaterials, 1998, page 271 Couvreur, Pharmaceutical Research, 1994, page 1270: - the itaconate and itaconimide derivatives such as dimethyl itaconate (E) by Bachrach, European Polymer Journal, 1976, page 563, N-butylitaconimide (F), N- (4-tolyl) itaconimide (G), N- (2-ethylphenyl) itaconimide (H), the N- (2,6-diethylphenyl) itaconimide (I) described by Wanatabe, J. Polymer Science: Part A: Polymer chemistry, 1994, page 2073. CCyvie (AND) R = Butyl (F), 4-tolyl (G), 2-ethylphenyl (H), 2,6-diethylphenyl (I) methyl a- (methylsulfonyl) acrylates (K), a- (methylsulfonyl) acrylates ethyl (L), methyl- (tert-butylsulfonyl) acrylates (M), tere-butyl (N) a- (methylsulfonyl) acrylates, tere-butyl (tert-butyl) -c- (tert-butylsulfonyl) acrylates (0) described by Gipstein, J. Org. Chem, 1980, p. 1486, and the derivatives 1, 1-bis- (methylsulfonyl) ethylene (P), 1-acetyl-l-methyl sulfonyl ethylene (Q), methyl OI- (methylsulfonyl) vinyl sulfonate (R), α-methylsulfonyl acrylonitrile (S) ) described by Shearer in US Pat. No. 2 748 050: (S) the sulfon derivatives of methyl vinyl (T) and phenyl vinyl sulfone (U) described by Boor, J. Polymer Science, 1971, page 249: ^ SOjMe ^ S02Ph 0) < u > the phenyl vinyl sulfoxide derivative (V) described by Kanga, Polymer preprints (ACS, Division of Polymer Chemistry), 1987, page 322: (V) the 3-methyl-N- (phenylsulfonyl) -1-aza-1,3-butadiene derivative (W) described by Bonner, Polymer Bulletin, 1992, page 517: acrylate and acrylamide derivatives such as: • N-propyl-N- (3-triisopropoxysilylpropyl) acrylamide (X) and N-propyl-N- (3 -triethoxysilylpropyl) acrylamide (Y) described by Kobayas i, Journal of Polymer Science , Part A: Polymer Chemistry, 2005, page 2754: · 2-hydroxyethyl acrylate (Z) and 2-hydroxyethyl methacrylate (AA) described by Rozenberg, International Journal of Plastics Technology, 2003, page 17: • N-butyl acrylate (AB) described by Schmitt, Macromolecules, 2001, page 2115 and tert-butyl acrylate (AC) described by Ishizone, Macromolecules, 1999, page 955. OBu OtBu (AB) (AC) The electrophilic monomer useful in the present invention can be cyclic or linear. When it is cyclic, the electro-attractor group is preferably hexcyclic, which means that it is not an integral part of the cyclic structure of the monomer. According to a particular embodiment of the invention, the electrophile monomer useful in the context of the invention has at least two electro-attractive groups. According to a preferred embodiment of the invention, the electrophilic monomer (s) are chosen from the compounds of formula (I): wherein: Ra and R2 designate each, independently of one another, a little or nothing electro-attractor (little or nothing inductive-attractor) such as: • a hydrogen atom, • a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, aromatic or not, preferably comprising from 1 to 20, better still from 1 to 10 carbon atoms, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted by one or more groups selected from OR, -COOR, -COR, -SH, -SR, -OH and the halogen atoms, • a polyorganosiloxane residue modified or not, • a polyoxyalkylene group; R3 and R4 designate each, independently of one another, an electro-attractor (or inductive-attractor) group selected from among the groups -N (R) 3+, -S (R) 2+, -SH2 +, - H3 + , -N02, -S02R, -C = N, -COOH, -COOR, -COSR, -CONH2, -CO HR, -F, -Cl, -Br, -I, -OR, -COR, -SH, - SR, -OH, linear or branched alkenyl groups, linear or branched alguinyl groups, mono- or polyfluoroalkyl groups of C1-C4, aryl groups such as phenyl, or aryloxy groups such as phenoxyloxy; R denotes a hydrocarbon group saturated or not, linear, branched or cyclic, preferably comprising from 1 to 20, better still from 1 to 10 carbon atoms, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted by one or more groups selected from -OR ', -COOR', -COR ', -SH, -SR', -OH, the halogen atoms, or a polymer residue which can be obtained by radical polymerization, by condensation or by opening cycle, R 'denoting an Ci-Ci0 alkyl radical.

By electro-attractor or inductive-attractor group (-1), any group more electronegative than carbon is understood. Reference may be made to the work PR Wells Prog. Phys. Org. Chem., Vol 6 111 (1968). By group little or nothing electro-attractor, is meant any group whose electronegativity is less than or equal to that of carbon. The alkenyl or alkynyl groups preferably have from 2 to 20 carbon atoms, better still from 2 to 10 carbon atoms. As a hydrocarbon group saturated or not, linear, branched or cyclic, preferably including from 1 to 20 carbon atoms, better still from 1 to 10 carbon atoms, there may be mentioned, in particular, linear or branched alkyl, alkenyl or alkynyl groups, such as methyl, ethyl, n-butyl, tere-butyl, iso-butyl, pentyl, hexyl, octyl, butenyl or butynyl; the cycloalkyl or aromatic groups. As the substituted hydrocarbon group, mention may be made, for example, of the hydroxyalkyl or polyhalogenoalkyl groups. As examples of unmodified polyorganosiloxane, mention may be made in particular of polyalkylsiloxanes such as polydimethylsiloxanes, polyarylsiloxanes such as polyphenylsiloxanes, polyarylalkylsiloxanes such as polymethylphenylsiloxanes.

Among the modified polyorganosiloxanes, mention may be made in particular of polydimethylsiloxanes with polyoxyalkylene and / or siloxy and / or silanol and / or amine and / or imine and / or fluoroalkyl groups. Among the polyoxyalkylene groups, mention may be made in particular of polyoxyethylene groups and polyoxypropylene groups preferably having from 1 to 200 oxyalkylenated units. Among the mono- or polyfluoroalkyl groups, groups such as - (CH 2) n- (CF 2) m-CF 3 or - (CH 2) n- (CF 2) m-CHF 2 with n = 20 and m = 1 to 20 can be mentioned particularly The substituents ¾ to R4 can optionally be replaced by a group having a cosmetic activity. The cosmetic activities particularly used are obtained from groups with coloring functions, antioxidants, UV filters and conditioning agents. As examples of group with coloring function, the azo, quinone, methinic, cyanomethinic and triarylmethane groups can be mentioned in particular. By way of examples with an antioxidant function group, mention may be made, in particular, of the butylhydroxyanisole (BHA), butylhydroxytoluene (BHT) or vitamin E type groups. By way of examples with the UV filter function group, the type groups may be particularly mentioned. benzophenones, cinnamates, benzoates, benzylidene-camphores and dibenzoylmethanes. By way of examples with a conditioning function group, cationic and fatty acid ester groups can be mentioned in particular. According to a preferred embodiment of the invention, the electrophilic monomer (s) are selected from among the monomers of the cyanoacrylate family of formula (II): R1 CN R2 COXR'3 wherein: X can designate NH, S, O; R'3 may designate a hydrogen atom or a group R; - R, ¾ and R2 are as defined above. In the formulas (I) and (II), Ri and R2 preferably represent a hydrogen atom. In the formula (II), X preferably denotes O and R '3 preferably represents a C6-Cio alkyl radical. As the compounds of formula (II), mention may be made of the monomers: a) belonging to the family of polyfluoroalkyl 2-cyanoacrylates such as the 2,2,3,3-tetrafluoropropyl ester of 2-cyano-2- acid propenoic of formula (III): or also 2, 2, 2-trifluoro-ethyl ester of 2-cyano-2-propenoic acid of formula (IV): b) belonging to the family of the alkyl or alkoxyalkyl 2-cyanoacrylates of formula (VI): wherein: - R'3 represents an alkyl radical of Ci-Cio, C2-Cio alkenyl or (C1-C4) alkoxy (C1-C10) alkyl, preferably a C1-C10 alkyl or (C1-6) alkoxy radical C4) (C1-C10) alkyl; ¾ and R2 are such as defined above. Mention may more particularly be made of ethyl 2-cyanoacrylate, methyl 2-cyanoacrylate, n-propyl 2-cyanoacrylate, isopropyl 2-cyanoacrylate, tere-butyl 2-cyanoacrylate, n-2-cyanoacrylate, -butyl, iso-butyl 2-cyanoacrylate, 3-methoxybutyl cyanoacrylate, n-decyl cyanoacrylate, hexyl 2-cyanoacrylate, 2-ethoxyethyl 2-cyanoacrylate, 2- 2-methoxyethyl cyanoacrylate, 2-octyl 2-cyanoacrylate, 2-propoxyethyl 2-cyanoacrylate, n-octyl 2-cyanoacrylate, allyl-2-cyanoacrylate, methoxypropyl 2-cyanoacrylate and cyanoacrylate iso-amyl. In formula (VI) such as that defined above, R'3 preferably represents a C6-Ci0 alkyl radical, and Ri and R2 represent a hydrogen atom.

In the context of the invention, it is preferred to use the monomers defined in b). The most particularly preferred monomers are the compounds of formula (VII) and their mixtures: wherein R'3 is chosen from the following radicals: - (CH2) 7-CH3; -CH (CH3) - (CH2) 5-CH3; -CH2-CH (C2H5) - (CH2) 3-CH3; - (CH2) 5-CH (CH3) -CH3; - (CH2) 4-CH (C2H5) -CH3. The monomers used according to the invention can be covalently fixed on supports such as polymers, oligomers or dendrimers. The polymer or oligomer can be linear, branched, comb or block. He The distribution of the monomers of the invention on the polymeric, oligomeric or dendritic structure can be statistically, terminally or in the form of blocks. The electrophilic monomer (s) are generally present in the composition according to the invention in an amount comprised between 0.1% and 80% by weight approximately of the total weight of the composition and preferably between 1% and 50% by weight approximately of the total weight of the composition. composition.

The electrophilic monomer (s) useful in the context of the present invention can be synthesized according to the known methods described in the literature. In particular, the monomers of the cyanoacrylate family can be synthesized according to the teaching of US 3 527 224, US 3 591 767, US 3 667 472, US 3 995 641, US 4 035 334 and US 4 650 826. In the present invention, the monomers are preferably chosen from monomers capable of polymerizing on keratin fibers under cosmetically acceptable conditions. In particular, the polymerization of the monomer is preferably carried out at a temperature of less than or equal to 80 ° C, preferably between 10 ° C and 80 ° C, preferably between 20 ° C and 80 ° C, which does not prevent completion of the Application by means of a helmet drying, a brush marking or a smoothing or curling tongs. The nucleophilic agent (s) can be applied regardless of the composition of the invention. They can also be added to the composition of the invention at the time of use. In this case, the composition according to the invention also comprises at least one nucleophilic agent. According to a particular embodiment of the invention, the nucleophilic agent (s) are chosen from molecular compounds, oligomers, dendrimers and polymers that carry at least one nucleophilic function selected from the functions R2N ~, NH2 ~, Ph3C ~, R3C ~ , PhNH ", pyridine, ArS", RC = C ", RS ~, SH ~, RO", R2NH, ArO ", N3 ~, OH", ArN¾, N¾, I ", Br ~, Cl" RCOO ", SCN ", ROH, RSH, WCO", CN ", N03 ~, Cl04 ~, H20, where Ph represents a phenyl group, where Ar represents an aryl group and R represents an alkyl group of Ci-Ci0. Preferably, the nucleophilic agent is water. The cosmetically acceptable medium of the composition of the invention is preferably in the form of an anhydrous and non-hygroscopic medium. Anhydrous medium means a medium containing less than 1% water. The cosmetically acceptable medium of the composition of the invention is preferably chosen from: • the. aromatic alcohols such as the benzyl alcohol; • fatty alcohols; · Modified or non-modified polyols such as glycerol, glycol, propylene glycol, dipropylene glycol, butylene glycol, butyl diglycol; • volatile or non-volatile silicones such as cyclopentasiloxane, cyclohexasiloxane, polydimethylsiloxanes modified or not by phenyl and / or siloxy and / or silanol and / or amine and / or imine and / or fluoroalguyl and / or carboxylic and / or betaine functions and / or quaternary ammonium; • mineral, organic or vegetable oils; • oxyethylenated waxes or not, paraffins, alkanes and more particularly C5-Ci0 alkanes; • fatty acids, fatty amides, fatty esters and more particularly benzoates or fatty alcohol salicylates; and its mixtures. The cosmetically acceptable medium of the composition of the invention can also be in the form of a direct or inverse emulsion and / or be encapsulated, the electrophilic monomers being kept in an anhydrous medium until the moment of use. The dispersed or continuous phase of the emulsion can be constituted by water, an aliphatic alcohol of QL-C4, silicones or their mixtures. The capsules or microcapsules containing the composition of the invention can be dispersed in an anhydrous medium as defined above, water, a C1-C4 aliphatic alcohol or mixtures thereof. The composition according to the invention can also understand at least one polymerization inhibitor. Preferably, the polymerization inhibitor (s) are inhibitors of anionic and / or radical polymerization. Examples of anionic and / or radical polymerization inhibitors include sulfur dioxide, nitric oxide, organic acids such as sulfonic acid, phosphoric acid or acetic acid, lactone, boron trifluoride. , hydroquinone and its derivatives such as hydroquinone monoethyl ether, tertiary butyl hydroquinone, benzoquinone and its derivatives such as duroquinone, catechol and its derivatives such as t-butyl catechol and methoxyicatecol, anisole and its derivatives such as methoxyanisole or hydroxyanisole, pyrogallol and its derivatives, p-methoxyphenol, - hydroxybutyl toluene, alkyl sulfates, alkyl sulphites, alkyl sulphones, alkyl sulphoxides, alkyl sulphides, mercaptans, 3-sulfonene and their mixtures The alkyl groups preferably designate groups having from 1 to 6 carbon atoms. The polymerization inhibitor (s) are generally present in the composition according to the invention in an amount comprised between 0.01% and 10% by weight approximately of the total weight of the composition and, even more preferably between 0.05% and 5% by weight approximately of the weight total of the composition. The composition according to the invention can also comprising at least one thickener polymer that has no reactivity on the electrophilic monomer (s) useful in the context of the present invention. By way of examples of thickening polymers which have no reactivity to the electrophilic monomer (s) used in the context of the invention, polymethyl methacrylate (PMMA) or cyanoacrylate-based copolymers, such as those described in US Pat. US Pat. No. 6,224,622. The thickening polymer (s) are generally present in the composition according to the invention in an amount comprised between 0.1% and 50%, preferably between 0.5% and 25%. They are among others useful for modulating the polymerization rate of the electrophilic monomers. The composition according to the invention can also contain additional compounds conventionally used in cosmetics. These compounds can be selected from reducing agents, fatty substances, organomodified silicones or not, thickening agents other than the thickener polymers defined above, cationic, anionic, neutral or amphoteric polymers, softeners, anti-foam agents, moisturizing agents, emollient agents, alkalizing agents, anti-oxidants, anti-free radical agents, guelatants, antiplicular agents, agents regulators of seborrhea, tranquillizers, plasticizers, sunscreens, direct dyes (natural or non-natural) or oxidation (bases and / or couplers), pigments, mineral fillers, clays, colloidal minerals, nacres, perfumes, peptizers, preservatives, anionic, cationic, amphoteric, zwitterionic or non-ionic surfactants, fixative or non-fixative polymers, conditioning polymers, hydrolyzed or non-hydrolyzed proteins, enzymes, amino acids, oligopeptides, peptides, vitamins, saccharides, oligosaccharides, polysaccharides hydrolyzed or not, modified or not, polyacids amines, fatty alcohols branched or not, animal, vegetable or mineral waxes, ceramides, pseudoceramides , hydroxylated organic acids, polyisobutenes and poly (α-olefins), fatty esters, anionic polymers in dissolved or dispersed form, poly nonionic mers in dissolved or dispersed form. Of course, the person skilled in the art will try to choose this or these possible additional compounds in such a way that the advantageous properties intrinsically related to the composition according to the invention are not, or substantially, altered by the addition (s) considered. The composition according to the invention can be presented in various forms, such as lotions, sprays, foams and be applied in the form of shampoo or after shampooing. The composition according to the invention can also contain a propellant. The propellant is generally constituted by a compressed or liquefied gas usually used for the preparation of aerosol compositions. Preferably, the compressed or liquefied gas is selected from air, carbon gas, compressed nitrogen, a soluble gas such as dimethyl ether, halogenated hydrocarbons such as fluorinated or non-halogenated hydrocarbons, and mixtures thereof. The composition according to the invention can be presented as such or result from mixing at the time of use of two compositions. For example, the first composition may comprise the electrophilic monomer (s) and the second composition may comprise the pigment (s) and / or the surface treated charge (s). The process according to the present invention comprises the application on the gouratinous fibers of a composition comprising, in a cosmetically acceptable medium, at least one pigment and / or a filler previously treated on the surface and at least one electrophilic monomer as defined above. in the presence of at least one nucleophilic agent. According to a variant of the method of the invention, the application of the composition according to the invention is carried out in at least two stages, one of the steps consists in applying to the keratin fibers a composition comprising the pigment and / or the surface treated charge (s) and the other stage consists of in applying a composition comprising the electrophilic monomer (s) to the keratin fibers, the order of the steps being indifferent. The useful nucleophilic agent can be used pure, in solution, in the form of an emulsion or encapsulated. It may be present in the composition containing the surface treated pigment. It can also be applied separately. In this case, it is possible for example to previously impregnate the keratin fibers with the help of this nucleophilic agent. In the case where the nucleophile agent is water, it is possible to previously humidify the gueratin fibers with the help of an aqueous solution whose pH has been adjusted with the help of acidifying and / or alkalizing agents. Among the acidulating agents, mention may be made, by way of example, of mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, acid lactic, sulfonic acids.

Among the alkalizing agents can be mentioned, example title, ammonia, alkali carbonates, alkanolamines such as mono-, di- and triethanolamines as well as their derivatives, sodium or potassium hydroxides and the compounds of formula (VII) below: wherein W is a propylene moiety optionally substituted by a hydroxyl group or a C1-C4 alkyl radical; Ra, ¾, Rc and Rd, identical or different, represent a hydrogen atom, a C1-C4 alkyl radical or Ci-C4 hydroxyalkyl. According to a particular embodiment of the invention, the nucleophilicity of the keratin fibers is increased by chemical transformation of the keratin material. By way of example, it is possible to apply to the keratin fibers, before the application of the composition according to the invention as defined above, at least one keratin-reducing agent in order to reduce the disulphide bridges they make up in part the keratin in thiols. Among the useful keratin reducing agents, there may be mentioned: • anhydrous sodium thiosulfate; · Sodium metabisulfite powder; • Thiourea • Ammonium sulphite; • thioglycolic acid; • thiolactic acid; • ammonium thiolactate; • the glycerol mono-thioglycolate • the ammonium thioglycolate; • thioglycerol; • 2,5-dihydroxybenzoic acid; • diammonium thioglycolate; • strontium thioglycolate; • calcium thioglycolate; • zinc formo-sulfoxylate; • isooctyl thioglycolate; • dl-cysteine; • monoethanolamine thioglycolate. In order to improve, among others, the adhesion of the polycyanoacrylate formed in situ, keratin fibers can be previously treated with all types of polymers, or a hair treatment, such as a direct or oxidation coloring, a permanent or a straightening. The application of the compositions to the keratin fibers may or may not be followed by rinsing and / or drying The drying can be done with a helmet, or a hair dryer and / or with straightening strands. These compositions may also contain various additional compounds as defined above. According to the method according to the invention, it is possible to perform multiple overlaps of applications. The subject of the present invention is also a kit for the treatment of keratin fibers, characterized in that it contains a composition comprising at least one pigment and / or a filler previously treated on the surface as defined above and a composition comprising at least one electrophilic monomer as defined and optionally at least one polymerization inhibitor. According to a particular embodiment of the kit according to the invention, the composition comprising the pigment (s) and / or the surface treated charge (s) further comprises at least one nucleophilic agent as defined above. According to another particular embodiment of the kit according to the invention, the kit also contains a composition that includes at least one nucleophilic agent as defined above. According to a first variant of the invention, the composition comprising the pigment (s) and / or surface treated charge (s) and the composition comprising the electrophilic monomer (s) and optionally the polymerization inhibitor (s) are present in a single anhydrous composition. According to a second variant, the composition comprising the pigment (s) and / or the surface-treated charge (s) is an aqueous composition and the composition comprising the electrophilic monomer (s) and optionally the polymerization inhibitor (s) is an anhydrous composition. The electrophilic monomer (s) are present in the composition comprising them in a concentration generally comprised between 0.05 and 30% by weight approximately of the total weight of the composition, preferably between 0.01 and 50% by weight, and even more preferably between 0.1 and 50% by weight. 20% by weight. Another subject of the present invention is the use for the treatment of keratin fibers of a composition as defined above. In the case where the composition comprises one or more pigments treated on the surface, the treatment of the keratin fibers is a coloration. In the case where the composition comprises one or more surface treated fillers, the treatment of the keratin fibers is a precaution.

The invention will be more fully illustrated with the aid of the following non-limiting examples. EXAMPLES Example 1: The following composition was made: 0 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The obtained wick has a soft touch.

Example 2: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with a dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The dye composition has good stability over time.

Example 3: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The dye composition has good stability over time.

Example 4: The following composition was made 0. 5 g of this composition were applied to a wick of gray hair at 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with a dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The cosmetic properties of the wick obtained are very satisfactory.

Example 5: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The cosmetic properties of the wick are very satisfactory.

Example 6: The following composition was made: 0 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The obtained wick has a soft touch.

Example 7: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of rest at room temperature, the wick was dried with the dryer for 2 minutes.The wick was colored yellow and the coloration obtained is resistant to shampooing.The dye composition has a good stability over time .

Example 8: The following composition was made: 0 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white lg. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The cosmetic properties of the wick obtained are very satisfactory.

Example 9: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The cosmetic properties of the wick obtained are very satisfactory.

Example 10: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The obtained wick has a natural touch.

Example 11: | The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored yellow and the coloration obtained is resistant to shampooing. The obtained wick has a natural touch.

Example 12: The following composition was made: 0 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored red and the remanence of the coloration obtained is good, particularly with respect to shampooing.

Example 13: The following composition was made: 0 5 of this composition were applied on a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored in orange and the coloration obtained is resistant to shampooing. The obtained wick has a natural touch.

Example 14: The following composition was made: 0. 5 of this composition were applied on a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick was colored in bronze and the coloration obtained is resistant to shampooing. The obtained wick has a soft touch.

Example 15: The following composition was made: 0. 5 g of this composition were applied to a wick of gray hair with 90% clean and moist natural white of 1 g. After 15 minutes of standing at room temperature, the wick was dried with the dryer for 2 minutes. The wick has a soft touch that is remnants of shampooing. It is noted that in relation to this date the best method known by the applicant to carry out the aforementioned invention is that which is clear from the present description of the invention.

Claims (47)

1. CLAIMS Having described the invention as foreword, the content of the following claims is claimed as property: 1. Composition for the treatment of keratin materials characterized in that it comprises, in a cosmetically acceptable medium, at least one electrophilic monomer and at least one pigment and / or a filler previously treated on the surface by an organic agent, said pigment or said filler being treated on the surface different from a mica coated with titanium and an organic pigment. Composition according to claim 1, characterized in that the pigment (s) are organic and chosen from pigments of the nitrous, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone type. perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone. 3. Composition according to claim 1, characterized in that the pigment (s) are compound pigments formed by particles comprising an inorganic core at least partially coated with an organic pigment and at least with a binder which ensures the fixation of the organic pigments on the nucleus. 4. Composition according to claim 1, characterized in that the pigment (s) are lacquers consisting of an inorganic substrate selected from alumina, silica, calcium and sodium borosilicate, borosilicate calcium and aluminum, and aluminum on the which is adsorbed an organic dye. Composition according to claim 1, characterized in that the pigment (s) are pigments with special effects selected from pearlescent pigments, pigments with interferential effects not fixed on a substrate, fluorescent pigments, phosphorescent pigments, photochromic pigments, the thermochromic pigments, the quantum dots. Composition according to claim 1, characterized in that the pigment (s) are pearlescent pigments selected from mica coated with titanium and iron oxides or chromium oxide, mica coated with titanium and an organic pigment, pearlescent pigments based on of bismuth oxychloride. Composition according to claim 1, characterized in that the pigment (s) are mineral and chosen from zirconium or cerium oxides, as well as iron or chromium oxides, manganese violet, ultramarine blue, hydrate of chromium and ferric blue, titanium dioxide. 8. Composition according to any one of claims 1 to 7, characterized in that the filler or fillers are chosen from talc, natural or synthetic mica, silica, kaolin, bismuth oxychlorides, precipitated calcium carbonate, carbonate and magnesium hydrocarbonate, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules. Composition according to any one of Claims 1 to 7, characterized in that the filler (s) are chosen from: polyamide, poly-α-alanine and polyethylene powders, tetrafluoroethylene polymer powders, lauroyl lysine, starch, boron nitride, polymer powders of acrylic acid; - the silicone resin microbeads; the microspheres of acrylic polymers; polyurethane powders; metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms; - the microcapsules of polymers or copolymers of acrylate or methyl methacrylate, or also of copolymers of vinylidene chloride and of acrylonitrile; the organopolysiloxane crosslinked elastomer powders. 10. Composition in accordance with any of the " previous claims, characterized in that the load (s) have an apparent diameter ranging from 0.01 to 150 um. Composition according to any one of the preceding claims, characterized in that the organic agent with which the pigments and fillers are treated is chosen from the amino acids; the waxes; fatty acids, fatty alcohols and their derivatives; the anionic surfactants; the lecithins; the sodium, potassium, magnesium, iron, titanium, zinc or aluminum salts of fatty acids; the metal alkoxides; the polysaccharides; the polyethylene; the (meth) acrylic polymers; polymers and copolymers containing acrylate units; proteins; the alkanoamines; the silicone compounds; the fluorinated organic compounds; the fluoro-silicon compounds. 12. Composition according to claim 11, characterized in that the organic agent with which the pigments and fillers are treated is chosen from among the PEG silicones; the chitosan; trietoxicaprilyl silane; the methicones; the dimethicones; dimethicone / trimethylsiloxysilicate; lauroyl lysine; the lauroyl lysine dimethicones; Magnesium myristate; the aluminum dimyristate; perfluoropolyimethylisopropyl ether; isostearyl sebacate; disodium stearoyl glutamate; the dimethicone / disodium stearoyl glutamates; perfluoroalkyl phosphate; the acrylate / dimethicone copolymer and perfluoroalkyl phosphate associations; the polymethylhydrogen siloxane / perfluoroalguyl phosphate; lauryl lysine | / aluminum tristearate; octyltriethylsilane; the associations octilytrietilsilano and perfluoroalguilo phosphate; the acrylate / dimethicone copolymer; isopropyl titanium triisostearate; microcrystalline cellulose and carboxymethyl cellulose; the cellulose; the acrylate copolymers; the perfluoroalguyl phosphate / isopropyl titanium triisostearate. 13. Composition according to any one of the preceding claims, characterized in that the pigments and / or the surface-treated fillers are coated by an organic layer. Composition according to any one of the preceding claims, characterized by the organic agent with which the pigments are treated and the fillers can be deposited on said pigments or the said fillers by evaporation of solvent, gum reaction between the surface agent molecules or creation of a covalent bond between the surface agent and pigments or fillers. 15. Composition according to claim 14, characterized in that the organic agent with which the pigments and fillers are treated is related to said pigments and to the indicated charges covalently. 16. Composition in accordance with any of the previous claims, characterized in that the agent with which the pigments and fillers are treated represents from 0.1 to 50% by weight of the total weight of the pigments or of the charges treated at the surface. Composition according to any of the preceding claims, characterized in that the surface treated pigment (s) are present in a concentration comprised between 0.05 and 50% by weight of the total weight of the composition. 18. Composition according to any of the preceding claims, characterized in that the load (s) are present in the composition in an amount comprised between 0.05 and 95% by weight of the total weight of the composition. 19. Composition according to any one of the preceding claims, characterized in that it comprises at least one untreated load on the surface. Composition according to any one of the preceding claims, characterized in that it comprises at least one untreated pigment on the surface. 21. Composition according to any one of the preceding claims, characterized in that the electrophilic monomer or monomers are chosen from the compounds of formula (I): in which: Ri and R2 designate each, independently of one another, a group little or nothing electro-attractor; and R3 and R4 designate each, independently of one another, an electro-attractor group. 22. Composition according to claim 21, characterized in that Rx and R2 represent, independently of one another, a hydrogen atom; a hydrocarbon group saturated or not, linear, branched or cyclic, comprising from 1 to 20 carbon atoms and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted by one or more groups selected from - OR, -COOR, -COR, -SH, -SR, -OH and the halogen atoms; a polyorganosiloxane residue modified or not; a polyoxyalkylene group; designating R as a saturated or non-saturated, linear, branched or cyclic hydrocarbon group, comprising from 1 to 20 carbon atoms, and optionally containing one or more nitrogen, oxygen, sulfur atoms and optionally substituted by one or more groups selected from OR ', -COOR', -COR ', -SH, -SR', -OH and the halogen atoms, or a polymer residue, where R 'is a C1-C10 alkyl radical. 23. Composition according to claim 21, or 22, characterized in that R3 and R4 are chosen, independently from each other, between the groups -N (R) 3+, -S (R) 2+, -SH2 +, -NH3 +, - NO 2, - SO 2 R, -C = N, -COOH, -COOR, -COSR, -CONH 2, -CONHR, -F, -Cl, -Br, -I, -OR, -COR, -SH, -SR, - OH, linear or branched alkenyl groups, linear or branched alkynyl groups, mono- or polyfluoroalkyl groups of C1-C4, aryl and aryloxy groups; designating R as a saturated or non-saturated, linear, branched or cyclic hydrocarbon group, preferably comprising from 1 to 20 carbon atoms, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted by one or more groups selected from -OR ', -COOR', -COR ', -SH, -SR', OH and the halogen atoms, or a polymer residue, where R 'is a C1-C10 alkyl radical. Composition according to any one of the preceding claims, characterized in that the electrophilic monomer (s) are selected from among the monomers of the cyanoacrylate family of formula (II): in which: X can designate NH, S, O; it can designate a hydrogen atom or a group R; R, Ri and R2 are as defined in Claim 22. Composition according to any of claims 21 to 24, characterized in that Ri and R2 represent a hydrogen atom. 26. Composition according to claim 24 or 25, characterized in that X designates 0. 27. Composition according to any of claims 24 to 26, characterized in that R'3 represents an alkyl radical of C6-Ci0. Composition according to any of the preceding claims, characterized in that the electrophilic monomer (s) are selected from among the monomers of the family of the 2-cyanoacrylates of alkyl or alkoxyalkyl of formula (VI): wherein: R'3 represents an alkyl radical of Ci-Cio, C2-C10 alkenyl or (C1-C4) alkoxy alkyl (CI ~ QLO); Ri and R2 are as defined in claim 22. 29. Composition according to claim 28, characterized in that R'3 represents a C6-C10-30 alkyl radical. Composition according to claim 28 or 29, characterized in that ¾ and R2 represent a hydrogen atom. Composition according to any of the preceding claims, characterized in that the electrophilic monomer (s) are chosen from the compounds of formula (VII) and their mixtures: H HCCNOOtf, m wherein R'3- is chosen from the following radicals: - (CH2) 7-CH3; -CH (CH3) - (CH2) 5-CH3; -CH2 ~ CH (C2H5) - (CH2) 3-CH3; - (CH2) 5-CH (CH3) -CH3; - (CH2) 4-CH (C2H5) -CH3. 32. - Composition according to any of the preceding claims, characterized in that the electrophilic monomer or monomers are present in an amount comprised between 0.1% and 80% by weight approximately of the total weight of the composition. 33. Composition according to any of the preceding claims, characterized in that the cosmetically acceptable medium is anhydrous. 34. Composition according to claim 33, characterized in that the cosmetically acceptable medium is chosen from: • aromatic alcohols; • fatty alcohols; • Modified or unmodified polyols; • volatile or non-volatile silicones; • mineral, organic or vegetable oils; »oxyethylenated or non-oxyethylene waxes, paraffins, alkanes; • fatty acids, fatty amides, fatty esters; and its mixtures. 35. Composition according to any of the preceding claims, characterized in that it also comprises at least one nucleophilic agent. 36. Composition according to claim 35, characterized in that the nucleophilic agent is water. 37. Process for the treatment of keratin fibers, characterized in that it comprises the application to keratin fibers of a composition as defined in any one of claims 1 to 34 in the presence of at least one nucleophilic agent. 38. Method according to claim 37, characterized in that the application of the composition for the coloring of the keratin fibers is carried out in at least two stages, in which one of the steps consists in applying on Keratin fibers A composition comprising the pigment (s) and / or the surface-treated filler (s) and the other step consists of applying to the keratin fibers a composition comprising the electrophilic monomer (s), the order of the steps being indifferent. 39. Method according to claim 37 or 38, characterized in that the nucleophilic agent is applied separately. 40. Method according to claim 37 or 38, characterized in that the nucleophilic agent is present in the composition comprising the surface-treated pigment (s). 41. Method according to any one of claims 37 to 40, characterized in that it comprises a step consisting in applying to the keratin fibers at least one keratin-reducing agent, before the application of the composition for the coloring of the materials. 42. Kit for the treatment of keratin fibers, characterized in that it contains a composition comprising at least one electrophilic monomer according to any of claims 1 and 21 to 31 and optionally at least one polymerization inhibitor and a composition comprising at least one a pigment and / or a filler previously treated on the surface as defined in any of claims 1 to 16. 43. Kit according to claim 42, characterized in that the composition comprising the pigment (s) and / or the surface-treated charge (s) further comprises at least one nucleophilic agent as defined in claim 35 or 36. 44. Kit according to claim 42, characterized in that it also contains a composition comprising at least one nucleophilic agent as defined in claim 35 or 36. Kit according to any of claims 42 to 44, characterized in that the composition comprising the pigment (s) and / or the surface-treated charge (s) and the composition comprising the electrophilic monomer (s) and optionally the polymerization inhibitor (s) are present in a single anhydrous composition. 46. Kit according to any of claims 42 to 44, characterized in that the composition comprising the pigment (s) and / or the surface-treated charge (s) is an aqueous composition and the composition comprising the electrophilic monomer (s) and optionally the Polymerization inhibitors is an anhydrous composition. 47. Use for the treatment of keratin fibers of a composition according to any of claims 1 to 36.