MXPA01003372A - Laundry detergent and/or fabric care compositions comprising chemical components linked to a cellulose binding domain - Google Patents

Abstract

The present invention relates to an improved chemical entity which comprises a chemical component linked to an amino acid sequence comprising a Cellulose Binding Domain (CBD) having a binding constant (Kr) for crystalline cellulose (Kr-c) of at least 10 l/gcellulose, and/or a binding constant for Avicel (Kr-av) and/or amorphous cellulose (Kr-am) of at least 1.5 l/gcellulose. The present invention further relates to laundry detergent and/or fabric care compositions comprising such an improved chemical entity, providing improved fabric care and cleaning benefits and cost effectiveness.

Description

COMPOSITIONS DETERGENTS OF LAUNDRY AND / OR OF CARE OF THE FABRIC COMPRISING CHEMICAL COMPONENTS LINKED TO A CELLULOSE UNION DOMAIN FIELD OF THE INVENTION The present invention relates to an improved chemical entity comprising a chemical component linked to an amino acid sequence comprising a cellulose binding domain (CBD) having a binding constant (Kr) for crystalline cellulose (Kr-c) of at least 10 l of cellulose, and / or a binding constant for Avicel (Kr-av) 'or amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose; and to its incorporation into a laundry detergent and / or te? a care detergent composition.

BACKGROUND OF THE INVENTION Modern detergent laundry and / or fabric care compositions contain various detergent ingredients that have one or more purposes in obtaining fabrics that are not only clean, fresh and disinfected, but also retain their appearance and integrity. Therefore, detergent components, such as perfumes, soil removal agents, fabric brighteners, fabric softeners, chelators, bleaching agents and bleach catalysts have been incorporated into laundry and / or fabric care detergent compositions. , dye fixatives and enzymes. When using said detergent components, it is important that some of these compounds are deposited on the fabrics to be effective during or after the washing and / or fabric care operation. An example is the use of cellulase enzymes for the treatment of fabrics consisting mainly of cellulose. The cellulose structures are depolymerized or cut into smaller fractions and therefore more soluble or dispersible. This activity, in particular on the fabrics, provides cleaning, restoration, smoothing and generally improved tactile sensation characteristics. However, it has been difficult to effectively incorporate the cellulase enzymes in modern detergents. In this regard, those skilled in the art have sought to use minimal amounts of cellulase for its most complete effectiveness, ensuring that most, if not all, of the cellulase enzyme comprised in the detergent composition is deposited on the fabric. For example, optimal cellulases would generally have a binding domain especially suitable for celluloses. In this way, they ensure that most of the cellulase enzyme included in the detergent composition will be deposited or otherwise bound to the fabric during the wash cycle to obtain the desired results. Consequently, there remains a need to formulate detergent and / or fabric care compositions in which the chemical components have a stronger and increased deposition on the fabrics, which would result in an improved action during the typical washing / care cycles of the cloth. There is also a need to ensure that the chemical components remain more effectively and prolonged on the fabric or fiber during the additional rinsing steps and during use. There also remains a need for such components to be formulated in a more cost-effective manner. The above objects have been achieved by formulating laundry detergent and / or fabric care compositions comprising an improved chemical entity containing a chemical component linked to an amino acid sequence comprising a cellulose binding domain (CBD) having a binding constant for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose. In WO 91/10732, novel cellulase enzyme derivatives are described which combine a core region derived from an endoglucanase which can be produced by a strain of Bacillus spp., NICMB 40250, with a CBD derived from another cellulase enzyme, or combining a core region derived from another cellulase enzyme with a CBD derived from said endoglucanase, for improved binding properties. In WO 94/07998 cellulase variants of a cellulase classified in the family 45 are described, which comprise a CBD, a catalytically active domain (CAD) and a region that binds the CBD to the CAD, where they have been added, deleted or substituted one or more amino acid residues; and / or another CBD is added at the opposite end of the CAD. WO 95/16782 refers to the cloning and high level of expression of novel truncated cellulase proteins, or derivatives thereof, in Trichoderma longibrachiatum, which comprise different core regions with several CBDs. WO 97/01629 describes the preparation of a cellulolytic enzyme in which the mobility of the cellulase component can be reduced by adsorption in an insoluble or soluble carrier, for example by the existing CBD or a newly introduced one. WO 97/28243 describes a process for the removal of bleach or dirt or spots of cellulosic fabrics, wherein the fabric is contacted in aqueous medium with a modified enzyme comprising a catalytically active amino acid sequence of a non-cellulolytic enzyme selected from amylases, proteases, lipases, pectinases and oxidoreductases, linked to an amino acid sequence comprising a cellulose binding domain, and a detergent composition comprising said modified enzyme and a surfactant. WO 98/00500 describes a composition comprising a protein deposition aid having high affinity for fibers or a surface, and having a beneficial agent adhered / adsorbed thereto. However, none of these documents describe an improved chemical entity with enhanced deposition, comprising a chemical component linked to an amino acid sequence that contains a cellulose binding domain and has a binding constant for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose. Thus defining an improved chemical entity that has a very high affinity for cellulose and is specially adapted to selectively bind to cotton fibers, ie, crystalline cellulose, Avicel, and / or amorphous cellulose; and that provides new, superior, increased and / or more cost-effective performance of the chemical components in a laundry and / or fabric care application.

BRIEF DESCRIPTION OF THE INVENTION The present invention relates to an improved chemical entity comprising a chemical component that is linked to an amino acid sequence comprising a cellulose binding domain having a binding constant (Kr) for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, preferably at least 20 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose, preferably 5 l / g of cellulose. This improved chemical entity has a very high affinity for cellulose and is especially adapted to selectively bind to cotton fibers, ie, crystalline cellulose, Avicel and / or amorphous cellulose.

The present invention also relates to laundry detergent and / or fabric care compositions comprising one or more improved chemical entities. These compositions provide new, improved and superior performance, more cost-effective, of the chemical components. In addition, the present invention relates to the use of the improved chemical entity to efficiently and effectively deposit a chemical component on a fabric.

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improved chemical entity comprising a chemical component linked to an amino acid sequence comprising a specific cellulose domain specifically selected for having a binding constant (Kr) for crystalline cellulose (Kr-c). ) of at least 10 l / g of cellulose, preferably at least 20 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr-am) of minus 1.5 l / g of cellulose, preferably 5 l / g of cellulose. The object of the present invention is to increase and / or improve the performance and cost effectiveness of a chemical component, increasing its deposition capacity. This object is achieved by the formulation of an improved chemical entity comprising a chemical component linked to an amino acid sequence comprising a selected cellulose binding domain. It has surprisingly been found that such improved chemical entities in which CBD has been particularly selected for its greatest deposition to cellulose, adhere to or otherwise contact the fabric more quickly. This results in a new, greater and / or increased yield of the chemical component on the surface of the fabric, or when it is released during or after the laundry and / or fabric care operations. Therefore, this allows to formulate compositions in a more cost effective manner, with a substantially increased deposition, and consequently greater benefits of the chemical entity. The present invention encompasses chemical entities with one or more chemical components linked to one or more amino acid sequences comprising one or more cellulose binding domains, potentially with one or more linker regions.

Cellulose Binding Domain (CBD) In the present context, the terms "amino acid sequence comprising a cellulose binding domain (CBD)" are used to indicate an amino acid sequence capable of effecting the binding of the cellulase to a substrate cellulose (for example, as described by P. Kraulis et al., "Determination of the three-dimensional structure of C terminal domain of cellobiohydrolase I from Trichoderma reesei: A study using nuclear magnetic resonance and hybrid distance geometry-dynamically simulated annealing" -Determination of the three-dimensional structure of the C-terminal domain of cellobiohydrolase I of 7. reesei: A study using nuclear magnetic resonance and dynamically simulated binding and hybrid distance geometry-, Biochemistry 28: 7241-7257, 1989). The classification and properties of cellulose binding domains are presented by P. Tomme and others in the symposium "Enzymatic degradation of insoluble polysaccharides" - Enzymatic degradation of insoluble polysaccharides - (ACS Symposium Series 618, edited by J.N. Saddler and M.H. Penner, ACS, 1995). The cellulose binding domains (and other carbohydrate binding domains) are polypeptide amino acid sequences that occur as integral parts of large polypeptides or proteins consisting of two or more polypeptide amino acid sequence regions, especially in hydrolytic enzymes ( hydrolases) typically comprising a catalytic domain containing the active site for hydrolysis of the substrate and a carbohydrate binding domain for the attachment of the carbohydrate substrate in question. Said enzymes may comprise more than one catalytic domain and one, two or three carbohydrate binding domains, and may also comprise one or more polypeptide amino acid sequence regions that link the carbohydrate binding domains with the catalytic domains, being denoted a region of the last type as a "linker" or "linker region".

Examples of hydrolytic enzymes comprising a cellulose binding domain are cellulase, xylanases, mannanases, arabinofuranosidases, acetylesterases and chitinases. "Cellulose binding domains" have also been found in algae, for example in the red alga Porphyra purpurea, in the form of a non-hydrolytic polysaccharide binding protein [see P. Tomme et al., "Cellulose-binding domains -Classification. and Properties in Enzymatic Degradation of Insoluble Carbohydrates "-cellulose binding domains, classification and properties in the enzymatic degradation of insoluble carbohydrates- John N. Saddler and Michael H. Penner (eds.), ACS Symposium Series, No. 618 (1996 )]. However, most known CBDs (which are classified and referred to by P. Tomme et al. (Cited work) as "cellulose binding domains"), are cellulase and xylase derivatives. In the present context, the term "cellulose binding domain" is understood in the same manner as in the antepor reference (P. Tomme et al., Cited work). The P. Tomme reference classifies more than 120"cellulose binding domains" in 10 families (l-X) that may have different roles or functions with respect to the binding mechanism of the substrate. However, it is anticipated that in the future new representatives of families and additional families will appear. In proteins / polypeptides in which CBDs occur (eg enzymes, typically hydrolytic enzymes such as cellulases), a CBD may be located at the N or C terminus or in an internal position.

The part of a polypeptide or protein (eg, a hydrolytic enzyme) that per se constitutes a CBD, typically consists of more than about 30 and less than about 250 amino acid residues. For example, the CBDs listed and classified in family I according to P. Tomme et al. (Cited work), consist of 33-37 amino acid residues; those listed and classified in the lia family consist of 95-118 amino acid residues; the listings and classified in the VI family consist of 85-92 amino acid residues; whereas a CBD (derived from a Clostridium thermocellum cellulase) listed and classified in the Vil family consists of 240 amino acid residues. Therefore, the molecular weight of an amino acid sequence that per se constitutes a CBD, will usually be on the scale from about 4kD to about 40kD, and usually below about 35kD. Cellulose binding domains can be produced by recombinant techniques such as those described by H. Stalbrand et al., "Applied and Environmental Microbiology" - Environmental and applied microbiology, March, 1995, pages 1090-1097; E. Brun et al. (1995) Eur. J. Biochem. 231, pages 142-148; J.B. Coutinho et al. (1992) Molecular Microbiology 6 (9), pages 1243-1252. To isolate a cellulose binding domain, for example from a cellulase, various genetic engineering approaches can be used. One method uses a restriction enzyme to remove a portion of the gene and then fuse in the frame the remaining gene-vector fragment to obtain a mutated gene that encodes a protein truncated by a particular gene fragment. Another method involves the use of exonucleases such as Ba131, to systematically suppress nucleotides, either externally from the 5 'and 3' ends of the DNA, or internally from a restricted space within the gene. These gene suppression methods result in a mutated gene encoding a shortened gene molecule, whose expression product can then be evaluated for substrate binding capacity (e.g. cellulose binding). Suitable substrates for evaluating binding capacity include cellulosic materials such as Avicel ™ and cotton fibers. Other methods include the use of a selective or specific protease capable of cutting a CBD, for example a terminal CBD, from the remainder of the polypeptide chain of the protein in question.

Selected cellulose binding domains The present invention relates to an improved chemical entity wherein the chemical component is linked to one or more amino acid sequences comprising one or more cellulose binding domains, characterized in that they have a binding constant (Kr ) for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, preferably 20 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr- am) of at least 1.5 l / g of cellulose, preferably 5 l / g of cellulose; and hereafter referred to as "CBD selected".

The relative binding constant (Kr) for binding to regenerated cellulose (amorphous-swollen cellulose in phosphoric acid, PASC), crystalline cellulose (bacterial microcrystalline cellulose-BMCC) or Avicel (microcrystalline cellulose -Avicel PH101) at 4 ° C and pH 7.0 , is defined as Kr = [No] Ka (as described by PE Johnson et al. (1996) Biochem. 35, 13895-13906); and is determined from the slope of a graph of 1 / [Xb] against 1 / [XT], using double-weighted least-squares analysis; where [N0] is the concentration of binding sites in the absence of ligand (mol (g of cellulose) "1), Ka is the equilibrium constant of association (L mol'1), [Xb] is the concentration of ligand bound (mol (g of cellulose) "1) and [Xf] is the concentration of udder ligand (molar) (NR Gilkes et al. (1992), J. Biol. Chem., 267 pages 6743-6749). Microcrystalline cellulose (Avicel PH101) can be obtained from FMC International (Little Island, County Cork, Ireland). Bacterial microcrystalline cellulose (BMCC) can be prepared from Acetobacter xylinum cultures (ATCC 23769), as described by Gilkes et al., 1992 (cited above). Regenerated cellulose (PASC) can be obtained by treatment with phosphoric acid from Avicel PH101, as reported by Coutinho et al. (1992) Mol. Microbiol. 6, 1243-1252. CBDs suitable for the present invention are derived from a strain of fungi or bacteria, preferably from family I, II, III or IV according to the current classification [see P. Tomme et al. (Cited work)]. Preferred CBDs are those selected from the fungal strain of the family I that have a binding constant for Avicel (Kr-A) and / or amorphous cellulose (Kr-a) of at least 1.5 l / g of cellulose. Also preferred are selected CBDs of the bacterial strain of family II, III or IV and having a binding constant for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, preferably 20 l / g of cellulose; and / or a binding constant for Avicel (Kr-av) and / or amorphous cellulose (Kr-am) of at least 5 l / g of cellulose. The most preferred CBDs for the purposes of the present invention are selected from: Cellulase CBD E3 from Thermomonospora fusca; CBD Cellulozome from Clostridium cellulovorans, commercially available from Sigma; CBD of family 45, originated from the cellulase of the fungus Humicola insolens, sold under the trademark "Carezyme" by Novo Nordisk A / S, and / or mixtures thereof. Carezyme is an endoglucanase of family 45, derived from Humicula insolens DSM1800 which has a molecular weight of approximately 43kDa and exhibits cellulolytic activity.

Linker Region The improved chemical entities of the present invention may additionally comprise one or more linker regions. The term "linker region" indicates a region that abuts the selected CBD and binds them to the chemical components. Suitable linker regions, if included in the improved chemical entity of the present invention, are characterized by having one or more attachment points for a chemical component, and one or more portions that are covalently bound to the selected CBD. Preferably, the linker regions of the present invention will encompass at least one point of attachment to the cellulose binding domain and more than one reactive group available for attachment to a chemical component, and hereinafter referred to as a "polyreactive linker region. " When present, this linker region can be obtained chemically or by recombination techniques. Linker regions suitable for the purposes of the present invention are: (1) The polyethylene glycol derivatives described in the catalog of Shearwater Polymers Inc. January 1996, such as the nucleophilic PEGs, the carboxyl PEGs, the electrophilically activated PEGs, the selective sulfhydryl PEGs, the heterofunctional PEGs, the biotin PEGs, the vinyl derivatives, the PEG silanes and the PEG phospholipids. In particular, suitable non-amino acid linker regions are the heterofunctional PEG, polymers (X-PEG-Y) from Shearwater such as PEG (NPC) 2, PEG- (NH 2) 2, t-BOC-NH-PEG -NH2, t-BOC-NH-PEG-CO2NHS, OH-PEG-NH-tBOC, FMOC-NH-PEG-CO2NHS, or PEG (NPC) 2 MW3400 from Sigma. (2) Other suitable linker regions are glutaric dialdehyde in 50% by weight aqueous solution, from Aldrich; Disuccinimidyl suberate (DSS), from Sigma; N-hydroxysuccinimide ester of y-maleimidobutyric acid (GMBS), from Sigma; 1-ethyl-3- (3-dimethylaminopropyl) carbodiimide hydrochloride (EDC), from Sigma; and dimethylsuberimidate hydrochloride (DMS), from Sigma; 1-Ethyl-3- (3-dimethylaminopropyl) carbodiimide, N-ethyl-5-phenylisoxao-3-sulfonate, 1-cyclohexyl-3- (2-morpholinoethyl) carbodi demethoxy-p-toluenesulfonate, N -ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline or glutaraldehyde. (3) Also suitable are the interleavers described in the 1999/2000 catalog of Pierce Products of Pierce Company, under the title "Interlacing reagents": the compounds SMPH, SMCC, LC-SMCC and, preferably, the Sulfo-KMUS compound. Preferred linker regions among these are the polymers PEG (NPC) 2, (NH 2) 2-PEG, t-BOC-NH-PEG-NH 2, MAL-PEG-NHS, VS-PEG-NHS from Shearwater and / or the Sulfo-KMUS compound by Pierce. Suitable polyreactive linker regions include polyacrylic acid / maleic acid polymers, polyvinyl alcohol polymers and / or amine-containing compounds, such as those described in copending application PCT / US 98/20491, filed September 30, 1998 by P &G, incorporated herein by reference. These amine-containing compounds include aminoaryl derivatives, substituted amines and amides, glucamines, chitosan dendrimers / saccharides, amine-derived polysaccharides, and peptide polymers. (1) Polyacrylic acid / maleic acid: Polymers of acrylic acid, maleic acid and / or mixtures thereof, which are suitable, are those in which one of the acidic portions is covalently bound to an NH2 group present in the sequence of amino acids of the selected CBD. The other acid units are the reactive groups available as potential binding groups for the chemical components through their alcohol / amine groups. (2) polyvinyl alcohol polymers. These polymers may or may not comprise the portion containing the polymerization initiator. - Without the acid portion containing the polymerization initiator, this polymer can be linked, for example, to the reactive group of aspartic acid or glutamic acid present in the amino acid sequence of the selected CBD, by means of an esterification reaction. The polyvinyl alcohol polymer further comprises reactive hydroxyl groups, available for the attachment of chemical components containing acid / aldehyde. With an acid portion containing the polymerization initiator, this acid portion of the polymer polymerization initiator, for example, can be linked to an NH2 group present in the amino acid sequence of the selected CBD. The polyvinyl alcohol polymer further comprises reactive hydroxyl groups, available for the attachment of chemical components containing acid / aldehyde. (3) Amine-containing compounds are also suitable, such as those described in copending application PCT / US 98/20491, filed September 30, 1998 by P & G, which is incorporated herein by reference, and which has the following general structure: B- (NH2) n; wherein B is a carrier material and n is an index having a value of at least 1. Among the inorganic carriers, the preferred primary amines are those selected from monomers or organic-organosilicon polymers or copolymers of amino compounds derived from organosilane, siloxane, silazane, alumano, aluminosiloxane or aluminosilicate. Typical examples of such carriers are: organosiloxanes with at least one primary amine moiety such as diaminoalkylsiloxane [H2NCH2 (CH3) 2Si] O, or organoaminosilane (C6H5) 3SiNH2, described in "Chemistry and Technology of Silicone" - Chemistry and Silicon Technology-, W. Noli, Academic Press Inc., 1998, London, pages 209, 106). Among the organic carriers, the preferred primary amines are those selected from aminoaryl derivatives, polyamines, amino acids, and derivatives thereof; amines and substituted amides; glucamines; dendrimers; polyvinylamines with a MW of 600-50K; polyvinyl alcohol substituted with amino with a MW ranging from 400-300,000; polyoxyethylene-bis [amine]; polyoxyethylene-bis [6-aminohexyl]; N, N'-bis- (3-aminopropyl) -1,3-propanediamine, linear or branched; 1,4-bis- (3-aminopropyl) piperazine, and mixtures thereof. Preferred aminoaryl derivatives are the aminobenzene derivatives which include the alkyl esters of 4-aminobenzoate compounds, and are preferably selected from ethyl 4-aminobenzoate, phenylethyl 4-aminobenzoate, phenyl 4-aminobenzoate, 4-amino-N'- (3-aminopropyl) benzamide, and mixtures thereof. Polyamines suitable for use in the present invention are the polymers of polyethylenimines, poly [oxy (methyl-1,2-ethanediyl)], - (2-aminomethylethyl) - (2-aminomethyl-ethoxy) - (= CAS No. 9046-10-0); poly [oxy (methyl-1,2-ethanediyl)], -hydro) - (2-aminomethylethoxy) -, ether with 2-ethyl-2- (hydroxymethyl) -1,3-propanediol (= CAS No. 39423- 51-3); commercially available under the trade names of Jeffaminas T-403, D-230, D-400, D-2000; 2,2 ', 2"-triaminotriethylamine; 2,2'-diamino-diethylamine; 3,3'-dinaminodipropylamine; 1,3-bis-aminoethylcyclohexane, commercially available from Mitsibushi and the commercially available C12 Sternomines from Clariant , such as Stemamin (propyleneamine) n with n = 3/4, and mixtures thereof The preferred polyamines are polyethyleneimines commercially available under the trademark Lupasol, such as Lupasol FG, G20, wfv, PR8515, WF, FC, G20, G35, GI00, HF, P, PS, SK, SNA Preferred substituted amines and amides for use herein are selected from nipecotamide, N-coco-1, 3-propeny diamine, N-oleyl-1,3-propenyl diamine N- (tallowalkyl) -1,3-propanediamine, 1,4-diaminocyclohexane, 1,2-diaminocyclohexane, 1,1-diaminododecane, and mixtures thereof Other primary amine compounds suitable for use herein are glucamines, preferably selected from 2,3,4,5,6-pentamethoxy-glucamine, 6-acetylglucamine, glucamine, and mixtures thereof.

Also preferred are the polyethyleneimine and / or polypropyleneimine dendrimer compounds, and the commercially available Starburst polyamidoamine (PAMAM) dendrimers, generation G0-G10 from Dendritech, and the Astromol dendrimers, generation 1-5 from DSM, being DiAminoButane Polyamine dendrimers, DAB (PA) x with x = 2nx4, and n being generally comprised between 0 and 4 Other preferred primary amine compounds are: -polyvinylamines with a molecular weight (MW) ranging from 600, 1200, 3K, 20K, 25K or 50K; -polyvinyl alcohol substituted with amine, with a MW that varies from 400-300,000: -polyoxyethylene-bis- [amine], available for example from Sigma; -polyoxyethylene-bis- [6-aminohexyl], available for example from Sigma; -N, N'-bis- (3-aminopropyl) -1, 3-propanediamine, linear or branched (TPTA); -1,4-bis- (3-aminopropyl) piperazine (BNPP). The most preferred compounds are ethyl 4-aminobenzoate, polyethylene imine polymers commercially available under the trademark Lupasol, such as Lupasol FG, G20, wfv, PR8515, WF, FC, G20, G35; G100, HF, P, PS, SK, SNA; glucamine; the diaminobutane dendrimers Astramol, polyvinylamines with a MW that varies from 600, 1200, 3K, 20K, 25K or 50K; substituted polyvinyl alcohol, with a MW that varies from 400-300,000; polyoxyethylene-bs- [amine]; polyoxyethylene-bis- [6-aminohexyl]; Linear or branched N, N'-bis- (3-aminopropyl) -1,3-propanediamine; 1,4-bis- (3-aminopropyl) piperazine, and mixtures thereof. The highly preferred primary amine compounds are selected from ethyl 4-aminobenzoate, polyethylene imine polymers commercially available under the trademark Lupasol, such as Lupasol FG, G20, wfv, PR8515, WF, FC, G20, G35; G100, HF, P, PS, SK, SNA; the diaminobutane dendrimers Astramol; Linear or branched N, N'-bis- (3-aminopropyl) -1,3-propanediamine; 1,4-bis- (3-aminopropyl) piperazine, and mixtures thereof. Preferably, the compounds are selected from ethyl 4-aminobenzoate, polyethylene imine polymers commercially available under the trademark Lupasol, such as Lupasol FG, G20, wfv, PR8515, WF, FC, G20, G35; G100, HF, P, PS, SK, SNA; Linear or branched N, N'-bis- (3-aminopropyl) -1,3-propanediamine; 1,4-bis- (3-aminopropyl) piperazine, and mixtures thereof. The most preferred polyreactive linker regions for use in the present invention are amino acids and their derivatives, especially ester and amide derivatives. These peptide polymers bind to the selected CBD via a peptide bond. The most preferred compounds are those that provide a greater substantivity of surface due to their functional characteristic. Suitable amino acids have the following functionality of formula: Suitable amino acids for use herein are selected from tyrosine, tryptophan, lysine, glutamic acid, glutamine, aspartic acid, arginine, asparagine, phenylalanine, proline, glycine, serine, histidine, threonine, methionine, and mixtures thereof. Homopolymers with the same amino acids or heteropolymers with different amino acids are suitable. For example, the amino acids serine, threonine and tyrosine possess the hydroxyl reactive group; the cysteine has a reactive SH group, the amino acids asparagine and glutamine possess an amido reactive group, and the lysine an amino reactive group. The linkage will preferably be carried out on tyrosine, cysteine or lysine. Especially, the free NH2 group of a lysine amino acid, or the terminal amino acid within the peptide polymer, is used as a binding point for chemical compounds containing aldehyde, enone, ketone, or acid or halogen moieties. Also suitable are amino acid derivative compounds selected from tyrosine ethylate, glycine methylate, tryptophan ethylate, and mixtures thereof. These peptide polymers can be linked to the amino acid sequence comprising a cellulose binding domain, by means of recombinant technology. An example of the recombinant technique that describes the expression of an enzyme with the CBD of different origin, is described by S. Karita et al. (1996), Journal of Fermentation and Bioengineering, vol. 81, No.6, pages 553-556. The polyreactive linker region may comprise from 1 to about 100 amino acid residues, in particular from 2 to 40 amino acid residues, for example, from 2 to 15 amino acid residues. It is preferred to use amino acids that are less favored by the surrounding proteases. In fact, any combination of amino acids can be selected to obtain maximum efficiency in weight and protease stability. Suitable amino acid linker regions are the cellulase linker of family 45 of Humicola insolens, the NifA gene of! CiP linker of Klebsiella pneumoniae, the CiP linker of the OmpA gene of E. coli, the cellulase linker E3 of Thermomonospora fusca, and the cellulase linker CenA; preferably the cellulase linker of family 45 of Humicola insolens, and the cellulase linker E3 of Thermomonospora fusca. Depending on the activity sought of the adhering chemical component, said chemical components can be linked permanently or temporarily to the selected CBD and / or linker region. Therefore, the present invention also encompasses chemical entities in which the chemical component is linked to the CBD and / or the linker region selected, by means of a weak link. Said weak link is a bond that can be enzymatically cut, oxidized, cut by light and / or hydrolyzed radiation, during or after the washing / care of the fabric operation, to release the chemical component (s). Examples of weak bonds are the base bonds of Shiff or of beta-amino-ketone.

The chemical components The present invention relates to an improved chemical entity comprising a chemical component linked to a selected CBD. The chemical component is, within the context of the present invention, any compound that has a desirable effect on a fiber or fabric. The chemical components encompassed in the improved chemical entity are preferably selected from perfumes, sanitizers, insect control agents, fabric softening agents, soil removal agents, bleaching agents, dye fixing agents, brighteners, surfactants and / or mixtures. thereof. The most preferred components are the perfume components, insect control agents, sanitizing agents, bleaching agents, and / or mixtures thereof. In addition to these chemical entities, the compositions of the present invention may comprise the same unmodified chemical components. The chemical component of the present invention can be encapsulated. Suitable encapsulation material includes starches, poly (vinyl acetate), urea / formaldehyde condensate-based materials. Particularly suitable encapsulating materials are water-soluble capsules consisting of a polysaccharide matrix and polyhydroxy compounds such as those described in GB 1, 464,616. Other suitable water soluble encapsulating materials comprise the dextrins derived from acid esters of non-gelatinized starch of substituted dicarboxylic acids, such as those described in the patent of E.U.A. No. 3,455,838. These acid ester dextrins are preferably prepared from starches such as waxy maize, waxy sorghum, sago, tapioca and potato. Suitable examples of such encapsulating materials include N-Lok, manufactured by National Starch. The N-Lok encapsulating material consists of a modified corn starch and glucose. The starch is modified by adding substituted monofunctional groups such as octenylsuccinic acid anhydride.

Perfumes Most consumers have come to expect scented laundry products, and expect that washed fabrics will also have a pleasant fragrance. Consumers also want washed fabrics to keep the fragrance pleasant over time. The perfume additives make the laundry compositions more aesthetically pleasing to the consumer, and in some cases the perfume imparts a pleasant fragrance to the fabrics treated therewith. However, often the amount of perfume transferred from an aqueous wash solution to the fabrics is marginal, and does not last long on the fabric. Fragrance materials are often very expensive, and their ineffective use in fabric softener compositions to add in the rinse, and ineffective release of the rinse to fabrics, result in a very high cost for both consumers and consumers. fabric softener manufacturers. Therefore, the industry continues to seek a more efficient and effective release form of the fragrance in laundry detergent and / or fabric care compositions, especially to improve the provision of lasting fragrance in rinsed fabrics. Therefore, the industry continues to seek improved alternatives to generate fragrances through economic and effective means. The present invention encompasses an improved perfume entity in which at least one chemical component is a perfume composition linked to a selected CBD. The perfume compound binds to the CBD and / or to the linker region selected by means of a weak bond. It is considered that improved perfume substantivity will be achieved by linking perfume compounds to a selected CBD. Without wishing to be bound by theory, it is believed that the slow hydrolysis of the weak link within the improved perfume entity will improve the release of the perfume. Actually, after the operation of washing or care of clothes, the weak link will be hydrolyzed and the perfume will be released. It has surprisingly been found that these improved perfume entities provide a more pleasant and lasting fragrance through economic and effective means. For example, it is known that alcohols represent key aromas in perfumery. However, many alcohols are too volatile to remain perceptibly on the dry fabrics and / or are not substantive enough to be optimally deposited on the fabric, such as in a softening operation during washing. The binding of these perfume alcohols with the selected CBD and / or linker region can be achieved, for example, by an ester linkage to a carboxylic group of the polyreactive linker region, or to a succinic acid molecule which alone is linked to a hydroxy group of the polyreactive linker region. A further example is perfumery aldehydes, known to provide a fresh scent on fabrics, and especially on dry fabrics. However, many perfume aldehydes are not sufficiently deposited on the fabrics and / or are too volatile. A known solution of the technique consists of using a second matter! of perfume containing an amine group to form a Shiff base. Said bases of Shiff present a higher residuality on the fabrics, but have a poor substantivity in the cloth and cause a change in the character of the aldehyde perfume. Therefore, the improved perfume entities encompassed in the present invention provide a high substantivity in the fabric, which results in a reduction in the waste of the fabric care wringer's perfume in the wash, as well as retention and deposition. of the perfume on the fabrics during the whole washing. In addition, these improved perfume entities provide a significant release of the perfume in dry washed fabrics, giving a lasting fragrance. Moreover, the amine groups encompassed within the CBD and / or linker region of the present invention have no odor impact or change the character of the perfume. Fully formulated fragrance can be prepared using many known odoriferous ingredients, of both natural and synthetic origin. The range of natural raw materials can encompass not only easily volatile components, but also moderately and slightly volatile ones; and that of synthetics may include representatives of virtually all kinds of fragrant substances, as will be evident from the following illustrative compilation. In this list of perfume ingredients, some are commercial names conventionally known to those skilled in the art, and also include isomers. Said isomers are also suitable for use in the present invention. A typical description of suitable ketones and / or aldehydes, traditionally used in perfumery, can be found in "Perfume and Flavor Chemicals" - Chemical agents for perfume and flavoring - Vol. I and II, S. Arctander, Allured Publishing, 1994, ISBN 0-931710-35-5. For the purposes of the present invention, products based on aldehydes or ketones are preferred. - Natural products such as absolute tree moss, basil oil, citrus fruit oils (such as bergamot oil, tangerine oil, etc.), absolute mastix, bayberry oil, palmarosa oil, patchouli oil, olive oil bitter orange from Paraguay, wormwood oil; - Alcohols such as farnesol, geraniol, linalool, phenylethyl alcohol, rodinol, cinnamic alcohol; Aldehydes such as citral, Helional ™, alpha-hexyl-cinnamaldehyde, hydroxy-citronellal, Lilial ™ (p-tert-butyl-alpha-methyldihydrocinnamaldehyde), methyl nonylacetaldehyde, 1 -decanal, benzaldehyde, florhidral, 2,4-dimethyl-3-cyclohexen- 1 -carboxaldehyde; cis / trans-3,7-dimethyl-2,6-octadien-1-al, heliotropin; 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde; 2,6-nonadienal; alpha-n-amyl cinnamic aldehyde, P.T. bucinal, liral, cimal, methyl-nonyl-acetaldehyde, hexanal, trans-2-hexenal, and mixtures thereof; - Ketones such as allylonone, alpha-ionone, beta-ionone, isoraldein (isomethyl-alpha-ionone), methylionone, alpha-damascone, delta-damascone, iso-damascone, carvone, gamma-methyl-ionone, Iso-E-Super 2,4,4,7-tetramethyl-oct-6-en-3-one, benzylacetone, beta-damascone; damascenone, methyldihydrojasmonate, methylredrilone, and mixtures thereof; - Esters such as allyl phenoxyacetate, benzyl salicylate, cinnamyl propionate, citronellyl acetate, citronellyl ethoxolate, decyl acetate, dimethylbenzylcarbinyl acetate, dimethylbenzylcarbinyl butyrate, ethyl acetoacetate, ethyl acetylacetate, hexenyl isobutyrate, ethyl acetate, linalyl, methyl dihydrojasmonate, styrallylacetate, vetyveryl acetate, etc .; Lactones such as gamma-undecalactone, various components frequently used in perfumery such as moss ketone, indole, p-menthane-8-thiol-3-one, and methyl-eugenol; Acétals and ketals that include the well-known acetals and ketals of methyl and ethyl, as well as acetals or ketals based on benzaldehyde, those comprising phenylethyl moieties, or more recently developed specialties such as those described in a U.S. patent. entitled "Acetáis and Ketals of Oxo-tetralins and Oxo-lndanes" -Acetals and ketals of oxotetralins and oxoindanes-, see the patent of E.U.A. No. 5,084,440, issued on January 28, 1992, issued to Givaudan Corp .; - Recent synthetic specialties include the enol ethers of oxotetralins and alkyl substituted oxoindanes, such as those described in the patent of E.U.A. No. 5,332,725, of July 26, 1994, granted to Givaudan; or the Schiff bases described in the U.S. patent. No. 5,264,615, of December 9, 1991, granted to Givaudan. When contained in the compositions of the present invention, these improved perfume entities will generally comprise from 0.001% to 20%, preferably from 0.01% to 5% by weight of the composition.

Hygienic Agents The present invention encompasses an improved hygienic entity wherein at least one chemical component is a hygienic agent linked to an amino acid sequence comprising a selected CBD. The sanitary agent will be bonded to the CBD, and / or to the selected linker region, by means of a weak link, to release the active material during or after the washing or care of the fabric operation. Preferably, the sanitary agent comprises a reactive hydroxyl, carboxyl or aldehyde moiety. It has surprisingly been found that such improved hygienic entities provide a very long and very efficient control of the growth of microorganisms on the stored and used fabrics. This improved hygienic entity can be incorporated into a laundry detergent and / or fabric care detergent composition of the present invention. Disinfection includes all the positive effects obtained by inhibiting or reducing microbial activity on fabrics and other surfaces, such as preventing the development of bad odor and growth of bacteria and fungi. For example, it prevents the development of bad smell on the stored and used fabrics. In particular, the composition of the present invention will inhibit or at least reduce the bacterial and / or fungal growth on the wet fabric that awaits subsequent washing operations., and thereby prevent the formation of a bad smell. Here, the term hygienic agents covers fungicides and antimicrobials that when applied to fabrics prevent or reduce the growth of fungi or bacteria, respectively. The disinfecting benefits of the detergent laundry and / or fabric care compositions of the present invention can be evaluated by the minimum inhibitory concentration (MIC), described by Tuber, Lung. Dis. August 1994, 75 (4): 286-90; J. Clin. Microbiol. May 1994, 32 (5): 1261-7; and J. Clin. Microbiol. October 1992, 30 (10): 2692-7. Preferred antibacterial compounds are pentadecanol, cinnamaldehyde, ionone, glutaraldehyde, citronellal. Other suitable antimicrobial compounds with a hydroxyl, carboxyl or aldehyde moiety are described in Paríums Cosmétiques Actualités No. 125, nov. 1995, 51-4. Other suitable antibacterial components are Nerodol, which for example can be linked to the carboxylic or succinic acid groups linked to the alcohol group of the CBD and / or linker region selected. A further example are the compounds Cipamaldehyde and / or beta-ionone, which for example can form a base of Shiff or β-amino ketone, with the NH 2 groups of the CBD and / or linker region selected. The microbiocidally active ingredients described in the manual "Disinfectants and Antiseptics" - Disinfectants and antiseptics - edited by J.M. Ascenzi, and in WO 97/46218, such as 2-hydroxydiphenyl ether, phenol derivatives, diphenyl compounds, benzyl alcohol, chlorhexidine, C12-14 alkyl betaines and C8-18 fatty acid amidoalkyl betaines, amphoteric surfactants, trihalocarbanilides and salts of quaternary ammonium. Also suitable are the cationic germicides described in EP 843 002 and in WO 98/24314, and antibacterial agents triclosan, triclocarban, DMDM hydantoin, pyroctone olamine, zinc pyrithione, selenium disulfide, climnazole and 3- methyl-4- (1-methylethyl) phenol. Other examples of suitable fungicides are given in WO 94/10286 (Henkel), CA943 429 (Unilever) and US Pat. No. 3,426,024 (Henkel). Preferred antimicrobials are 2-thiocyanomethylthiobenzothiazole (Busan 30 WB ex Buckmann), butyl 4-hydroxybenzoate (butylparabens ex Nipa Labs), propyl 4-hydroxybenzoate (propylparabens ex Nipa Labs), terpineol, borneol, fenchyl alcohol trichlorocarbanilidem, Irgasan DP300 ( 2,4,4'-trichloro-2'-hydroxydiphenyl ether) and the higher homologues of hydroxybenzoate esters. Additional examples of bactericides used in the hygienic agent entities of this invention, include formaldehyde, 2-bromo-2-nitro-propane-1,3-diol, sold by Inolex Chemicals, Philadelphia, Pennsylvania, under the trademark Bronopol®, and a a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one, sold by Rohm and Haas Company under the brand Kathon. Suitable hygienic agents also include: 1- or 2-hexadecanol, 2-tetradecanol, 1-pentadecanol, 1-undecanol, 2-dodecanol, 1-tridecanol, nerolidiol, hinokitiol, tropolone, berberine, citronellic acid, curcumin, N-oxide of 2-mercaptopyridine, ellagic acid (dihydrate), 3-t-butyl-5-methylsalicylic acid, 3-, 4- or 5-methylsalicylic acid, 1-nonanol, decyl alcohol, cinnamaldehyde, S- or R-citronellal, citronellol , beta-ionone, thujone, coumarin and derivatives, geraniol, citral, thymol, isobutyl- or isopropyl-quinoline, 2-butyl-5-methylphenol, 2-mercapto-3-pyridinol, perilylic alcohol, 6-hydroxy-1, 3-benzoxathiol-2-one, BOAT, iso-eugenol, ment-1-en-9-ol, 2-t-butyl-4-methylphenol, kojic acid, camphene, carveol, dihydroxycarboxylic acid, sojasmona, menthol, cineol, terpinol, camphor, 2-t-butyl-methylphenol, 2-tridecanone, acetylsalicylic acid, salicylaldoxime, undecylenic aldehyde, nerol, 3,5,5-trimethyl-1-hexanol, adipic acid, thiosalicylic acid, OH-benzoic acid, -methylbenzothiazole, caryophyllene, allyl socianate, carvone, alpha-pinene, salicylic acid, alpha-ionone, 2OH- or 3OH-phenethyl alcohol, trimethoxy BP, undecyl aldehyde, cineole, anisaldehyde, bornyl acetate, salicylhydroxamic, benzofuran Car. , syringaldehyde. Preferably, the levels of the hygienic agent entity should be such as to prevent the growth of bacteria and fungi on the fabrics, rather than only to prevent growth within the laundry detergent and / or fabric care compositions per se. When included in the compositions of the present invention, these improved hygienic entities will generally be comprised at a level of 0.00001% to 20%, preferably 0.001% to 5% by weight of the total composition.

Insect Control Agents The present invention encompasses improved insect control entities wherein at least one chemical component is an insect control agent linked to an amino acid sequence comprising a selected CBD. It has been surprisingly determined that such improved insect control entities provide for much longer insect control by the slow release of the insect control agent. Said improved insect control agent entities can be incorporated into laundry detergent and / or fabric care compositions. These improved insect control entities are linked to the selected CBD and / or linker region, preferably by means of a weak link, to release the active material over time. For example, these materials can be linked to the NH2 group present in the selected CBD and / or linker region, by means of a Shiff base or a Michael reaction. The term "insect control agent" refers to both insecticides and insect repellents, either individually or as mixtures. Examples of insect repellents can be found in the chemical technology Kirk-Othmer encyclopedia, fourth edition, volume 13, pages 474 to 478. Suitable insect repellents include aldehyde-based compounds such as citronellal and rotundial, compounds based on enone such as butopironoxyl (Indalone ™), benzyl benzoate, bíoaletrin and dimetrin, N, N-diethyl toluamide ("DEET"), N, N-diethylbenzamide, p-menthane-3,8-diol, 1 S, 3S , 4S, 6S-Carene-3,4-diol (Sumitomo-U.S. Patent No. 5,130,136), 1-piperidinecarboxylic acid, 2- (2-hydroxyethyl) -1-methylpropyl ester, 1- (3-cyclohexen-1- il-carbonyl) -2-methylpiperidine, 1- (3-cyclohexen-1-yl-carbonyl) piperidine, N, N-diethylmandelamide, isopulegol hydrate, ethyl-3- (N-butyl-N-acetyl) aminopropionate, diisopropyl adipate, a-biasal, yerbabuena oil, benzyl alcohol, N, N-diethylphenylacetamide, vitamin E, lemon balm oil, coconut oil, cedroleo, geraniol, lemon oil, thyme oil, rosemary oil, peppermint oil, geranium oil, eugenol, 3-acetyl-2- (2,6-dimethyl-5-heptenyl) oxazolidine, acid lactone (2-hydroxymethylcyclohexyl) ) acetic acid and eucalyptol. Other insect control agents are based on pyrethroid insecticides, in particular 3-phenoxybenzyl-DL-cis, trans-3- (2,2-dichlorovinyl) -2,2-di-methylcyclopropane-carboxylate (permethrin). . In WO 98/17772 the insect repellent agent prcpionate of 3- (N-butylacetamino) ethyl is described for use in detergents. Preferred insect repellents are the aldehyde-based compounds such as citronellal and rotundial. When included in the compositions of the present invention, these improved insect control entities will generally be comprised at a level of 0.1% to 40%, preferably 0.1% to 10% by weight of the composition.

Bleaching agents The present invention encompasses an improved bleaching entity wherein at least one chemical component is a bleaching agent linked to an amino acid sequence comprising a selected CBD. Said bleaching agent can be selected from hydrophilic bleach activators, hydrophobic bleach activators, metal catalysts and / or photoactivated bleach. It has surprisingly been found that the bleaching action with said improved bleaching agent entities results in improved and increased bleaching / removal of stains / dirt and maintenance of whiteness. The present invention also encompasses laundry detergent and / or fabric care compositions comprising said improved bleaching entities. Without wishing to be limited by theory, it is believed that the bleaching / removal of stains / dirt and improved whiteness maintenance result from the generation of oxygen radicals, the perhydrolysis of peracetic acid or peracid occurring very close to the fabric. Said peracetic acid or peracid is less diluted in the washing solution because the bleaching entity of the present invention is deposited very efficiently on the fabric and thereby improves the bleaching action on the fabric. Preferably, the bleach activator is linked to the selected CBD by a linker region, preferably by a polyreactive linker region. Without wishing to be bound by theory, it is believed that the presence of this linker region provides flexibility to the bleach activator, allowing it to move around the CBD and perform its bleaching action more efficiently on the fabric. (1) Hydrophilic bleach activator: For example, tetraacetylethylene diamine (TAED) is a common bleach activator used in laundry detergents; form peracetic acid in the presence of H2O2. It is known that the two NH2 groups of ethylenediamine are diacetylated to form TAED. Without wishing to be bound by theory, it is believed that diacetylation of the free NH2 groups of the selected CBD and / or linker region forms a substantive hydrophilic bleach activator in the web. The hydrophilic bleach activator of the TAED type can be ligated for example by a diacetylation reaction with any NH2 group of the CBD and / or linker region selected from the present invention. (2) Hydrophobic bleach activators: such as nonanoylbenzenesulfonate, are common bleach activators used in laundry detergents. It has surprisingly been found that the phenolic portion can be replaced with that which is present in the amino acid tyrosine present in the selected CBD and / or linker region. Active hydrophobic bleach activator precursors such as the nonanyl unit can be ligated with the phenol group of an amino acid such as tyrosine, present in the CBD and / or peptide linker region selected. Similarly, if no phenol entity is available in the selected CBD and / or linker region, a phenol unit can be linked to an NH2 group in this selected CBD and / or linker region. In general, hydrophobic bleach activators can be ligated to the selected CBD and / or linker region, for example by a reaction on the NH2 groups. Other examples of suitable hydrophobic bleach activators are: nonanoyloxybenzenesulfonate (NOBS, described in US Patent No. 4,412,934), 3,5-trimethylhexanoloxybenzenesulfonate (ISONOBS, described in EP 120,591) or pentaacetylglucose (PAG) or N-nonanoyl phenolsulfonate ester -6-aminocaproic acid (NACA-OBS, described in WO 94/28106), which are perhydrolyzed to form a peracid as the active bleaching species, leading to an improved bleaching effect. Also suitable are bleach activators based on a leaving group of caprolactam, such as benzoylcaprolactam and hexanoylcaprolactam quaternary ammonium; the imide activators such as N-nonanoyl-N-methyl-acetamide and the non-symmetric acyclic imide bleach activator of the following formula, as described in copending patent applications of E.U.A. from Procter & Gamble Serial No. 60 / 022,786 (filed July 30, 1996) and No. 60 / 028,122 (filed October 15, 1996): wherein Ri is a straight or branched chain saturated or unsaturated alkyl group of C7-Ci3, R2 is a straight or branched chain saturated or unsaturated alkyl group of C -? - C8 and R3 is a saturated or unsaturated chain alkyl group linear or branched CrC. These bleach activators can be linked, for example, to any NH2 group in the polyreactive linker region. Also suitable are the preformed peracids, such as nonilamidoperoxiadipic acid and N, N-phthaloylaminoperoxycaproic acid, and the diacyl peroxides such as dibenzoyl peroxide. (3) Metal catalysts: A third type of bleach activator that may be embedded in the improved bleach entity of the present invention are the metal catalysts described below. For example, these catalysts can be ligated, via their blocking cyclo-azo moieties, with the NH2 groups of the CBD and / or linker region selected. Examples of catalysts containing meta! for use in bleaching compositions, include cobalt-containing catalysts such as the salts of cobalt pentaamineacetate (III) and manganese-containing catalysts such as those described in EPA 549 271; EPA 549 272; EPA 458 397; patent of E.U.A. No. 5,246,621; EPA 458 398; patent of E.U.A. No. 5,194,416 and US patent. No. 5,114,611. Patent application No. 94870206.3 discloses a bleaching composition comprising a peroxy compound, a bleaching catalyst containing manganese and a chelating agent. (4) Photoactivated bleach: Another group of suitable bleach activators that can be included in the improved bleach entity of the present invention is that of photoactivated bleach. For example, the linkage can be carried out between the NH2 groups and the benzyl groups of these photoactivated bleaches, activated by preliminary bromination. Suitable photoactivated bleaching agents are the sulphonated phthalocyanines of zinc and / or aluminum. These materials can be deposited on the substrate during the washing operation. After irradiation with light, in the presence of oxygen, such as by hanging the clothes to be dried in daylight, the sulfonated zinc phthalocyanine is activated and consequently the substrate is bleached. The preferred zinc phthalocyanine and a fctoactivated bleaching process are described in the US patent. 4,033,718. Typically, the compositions herein will contain from about 0.025% to about 1.25% by weight of sulfonated zinc phthalocyanine. In addition to this improved bleaching entity, the compositions of the present invention may also comprise bleaching species such as hydrogen peroxide, PB1, PB4 and percarbonate, with a particle size of 400-800 microns, typically present at levels of 1% to 25%. % by weight of the total composition. When included in the compositions of the present invention, these improved bleaching entities will generally be comprised at a level of 0.001% to 40%, preferably 0.1% to 10% by weight of the total composition.

Fabric Softening Agents The present invention encompasses an improved fabric softening entity wherein at least one chemical component is a fabric softening agent linked to an amino acid sequence comprising a selected CBD. It has surprisingly been found that such improved fabric softening entities provide anti-wrinkle properties, against the formation of pellets and against shrinkage of the fabrics, as well as softness of the fabric. These improved softening entities can be incorporated into a laundry detergent and / or fabric care composition. In recent years, consumer desire for durable ironing cloth garments, particularly cotton cloth garments, has increased. Durable ironing garments include garments that resist wrinkling of the fabric both during use and during washing operations. Durable ironing clothes can greatly reduce the manual labor associated with laundry, eliminating the ironing sometimes necessary to prevent wrinkling of the garment. However, in most commercially available durable ironing fabrics, the ability of the fabric to resist wrinkling over time is reduced as the garment is worn and washed repeatedly. Therefore, the improved fabric softening entities of the present invention, help to eliminate this problem by providing excellent anti-wrinkling properties, due to an effective deposition of the improved softening entity on the fabric. Suitable fabric softening agents are dialkyl units which can be ligated, for example, by dialkylation of the NH2 groups comprised in the selected CBD and / or linker region. Preferably, said fabric softening entities will not comprise a weak link. The dialkyl units suitable for the compositions of the present invention can be extracted from the following cationic surfactants softeners currently used in the context of laundry and / or fabric care detergents. The alkyl or alkenyl chain will contain at least 1 1 carbon atoms, preferably at least 16 carbon atoms. The chain can be straight or branched. Specific examples of the alkyl or alkenyl chains herein include: (1) N, N-di (tallowyloxyethyl); (2) N, N-di (2-tallowoyloxy-2-oxo-ethyl); (3) N, N-di (2-tallowyloxyethylcarbonyloxyethyl); (4) N- (2-tallowoyloxy-2-ethyl) -N- (2-tallowoyloxy-2-oxo-ethyl); (5) N- (2-tallowoyloxy-2-oxoethyl) -N- (tallowyl); and (6) 1,2-diisoxyloxy; and mixtures of any of the above materials. Preferred alkyl chains for the purposes of the present invention are N, N-di (tallowyloxyethyl), wherein the tallow chains are at least partially unsaturated. Other suitable fabric softening agents include quaternary ammonium softening compounds having a solubility in water at pH 2.5 and 20 ° C of less than 10 g / l. It is particularly advantageous if the fabric softening agent is a quaternary ammonium compound in which at least one long chain alkyl group is attached to the quaternary ammonium compound by at least one ester linkage. In the patent of E.U.A. No. 4,137,180 (Naik) and WO 93/23510 are suitable cationic softeners. Clay and silicone are also suitable as softening components. Suitable clays include stratified stratified clay, preferably one having a cation exchange capacity as described in GB 1, 400, 898 and USP 5,019,292. Especially preferred are clays that are 2: 1 layer phyllosilicates that have a net charge efficiency in the range of 0.2 to 0.4 g equivalent per half cell unit, as described in EP 350 288 (Unilever). The present invention also encompasses any polymeric lubricant suitable for softening a fabric. These include silicone, and in particular those described in GB 1, 549,180; EP 459 821 (Unilever) and EP 459 822 (Unilever).

When included in the present invention, these improved fabric softening entities will generally be comprised at a level of 0.5% to 50%, preferably 1% to 30%, preferably 2% to 15% by weight of the composition.

Dye fixing agents The present invention encompasses an improved dye fixing entity, wherein at least one chemical component is a dye binding agent linked to an amino acid sequence comprising a selected CBD. It has surprisingly been found that such improved colorant setting entities provide improved properties against wear and color appearance. Laundry detergent and / or fabric care compositions comprising an improved colorant setting entity are also included in the present invention. In reality, colored garments tend to wear out and show loss of color appearance. A part of this loss in color appearance can be attributed to abrasion in the washing operation, particularly in automatic washing machines and automatic laundry dryers. Dye fixing agents are well-known commercially available materials that are designed to improve the appearance of the dyed fabric by reducing the loss of dye from the fabrics due to washing. Many dye fixatives are cationic and are based on various organic nitrogen compounds quaternized or cationically charged in some other way. The fixators are available under various trade names from various suppliers. Representative examples include CROSCOLOR PMF (July 1981, Code No. 7894) and CROSCOLOR NOFF (January 1988, code No. 8544) from Crosfield; INDOSOL E-50 (February 27, 1984, ref No. 6008.35.84, based on polyethyleneamine) from Sandoz; SANDOFIX TPS, also available from Sandoz, is a preferred polycationic fixative for use herein, and SANDOFIX SWE (cationic resinous compound), REWIN SRF, REWIN SRF-O and REWIN DWR from CHT-Beitlich GMBH. Other cationic dye fixing agents are described in "Aftertreatments for Improving the Fastness of Dyes on Textile Fibers" by Christopher C. Cook (REV. PROG. COLORATÍON Vol. 12, 1982). Additional suitable dye fixing agents for use in the present invention are ammonium compounds such as fatty acid diamine condensates, for example hydrochloride, acetate, methylsulfate and oleyldietilaminoethylamide benzyl hydrochloride, oleylmethyl diethylenediamine methosulfate, monostearylethylene methosulfate. -diaminotrimethylammonium, and oxidized products of tertiary amines; derivatives of polymeric alkyldiamines, condensates of polyamine-cyanuric chloride and aminated glycerol dichlorhydrins. When included in the compositions of the present invention, these improved colorant setting entities will generally be comprised at a level of from 0.01% to 30%, preferably from 0.1% to 15% by weight of the composition.

Soil Removal Agents The present invention encompasses an improved soil removal entity, wherein at least one chemical component is a soil removal agent linked to an amino acid sequence comprising a selected CBD. It has surprisingly been found that such improved soil removal entities provide better deposition of the soil removing agent on the fabric and therefore better soil removal action. Also included in the present invention are laundry and / or fabric care detergent compositions comprising said improved soil removal entity. The soil removal agents suitable for the present invention are oligomers of ethylene glycol, polyethylene glycol and derivatives such as transesterified polyethylene glycols and propylene polyoxyethylene. Other suitable soil removal agents useful in the compositions of the present invention are conventionally copolymers or terpolymers of terephthalic acid with ethylene glycol and / or propylene glycol units in various arrangements. Examples of such polymers are described in the patents of E.U.A. commonly assigned Nos. 4116885 and 4711730, and in published European patent application No. 0 272 033. A particular preferred polymer in accordance with EP-AO 272 033, has the formula: (CH3 (PEG) 43) 0.75 (POH) 0.25 [T-PO) 2.8s-PEG) -0.4] T (PO- H) 0.25 ((PEG) 43CH3) 0.75 where PEG is - (002 ^) 0-, PO is (OC3H6O) and T is (PCOC6H4CO). Modified polyethers are also very useful as random copolymers of dimethyl terephthalate, dimethyl sulfoisophthalate, ethylene glycol and 1,2-propanediol, the end groups consist mainly of sulfobenzoate and secondarily of monoesters of ethylene glycol and / or propanediol. The objective is to obtain a polymer blocked at both ends with sulfobenzoate groups; "mainly", in the present context means that most of said copolymers will be blocked at their ends with sulfobenzoate groups. However, some copolymers will be little less than completely blocked, and therefore, their end groups may consist of monoester of ethylene glycol and / or 1,2-propanediol, whereby they consist "secondarily" of said species. The polyesters selected herein contain about 46% by weight of dimethylterephthalic acid, about 16% by weight of 1,2-propanediol, about 10% by weight of ethylene glycol, about 13% by weight of dimethyl sulfobenzoic acid and about 15% by weight. of sulfoisophthalic acid, and have a molecular weight of about 3,000. The polyesters and their method of preparation are described in detail in EPA 311 342. Other soil removers currently used in the context of detergents are those of the U.S.A. No. 4,968,451, November 6, 1990 of J.J. Scheibel and E.P. Gosselink: such ester oligomers can be prepared by (a) ethoxylating allyl alcohol, (b) by reacting the product of (a) with dimethyl terephthalate ("DMT") and 1,2-propylene glycol ("PG") in a process of two transesterification / oligomerization steps; and (c) reacting the product of (b) with sodium metabisulfite in water; the non-ionic 1, 2-propylene / polyoxyethylene terephthalate polyesters blocked at their ends of the U.S. patent. No. 4,711, 730 of December 8, 1987 for Gosselink and others, for example those produced by transesterification / oligomerization of poly (ethylene glycol) methyl ether, DMT, PG and poly (ethylene glycol) ("PEG"); the anionic oligomers partially and completely blocked at their ends, of the U.S. patent. No. 4,721, 580 of January 26, 1988 for Gosselink, such as the oligomers of ethylene glycol ("EG"), PG, DMT and Na-3,6-dioxa-8-hydroxyoctanesulfonate; Blocked non-ionic polyester block oligomeric compounds, from the U.S.A. No. 4,702,857 of October 27, 1987 from Gosselink, for example produced from DMT, Me-blocked PEG and EG and / or PG, or a combination of DMT, EG and / or PG, Me-blocked PEG and Na-dimethyl- 5-sulfoisophthalate; and the anionic esters of terephthalate blocked at their ends, especially sulfoaroyl, of the patent of E.U.A. No. 4,877,896, of October 31, 1989 to Maldonado, Gosselink and others, the latter being typical of the SRA's useful in both laundry and fabric conditioning products, one example being an ester composition made from the monosodium salt of m-sulfobenzoic acid, PG and DMT, optionally but preferably comprising added PEG, for example PEG 3400. Another preferred soil remover is a sulphonated end blocked type, which is described in the US patent. No. 5,415,807. When included in the compositions of the present invention, these improved soil removal entities will generally be comprised at a level of from 0.01% to 20%, preferably from 0.1% to 5% by weight of the total composition.

Brighteners The present invention encompasses an improved brightener entity, wherein at least one chemical component is a brightener linked to an amino acid sequence comprising a selected CBD. It has surprisingly been found that such improved brightening entities provide greater deposition of the brightener on the cloth and therefore better whiteness maintenance action. In addition, it has been found that various brighteners not commonly used in the field of detergents could also be used in the present invention, thanks to their greater substantivity in the fabrics, in particular during a smoothing operation during washing. Preferably, said improved polishing entities will not comprise a weak link. Laundry and / or fabric care detergent compositions comprising an improved brightener entity are also included. Suitable brighteners for the compositions of the present invention are: Carbocyclic compound types such as diethyrylbenzenes, di-styrylbiphenyls and divinyl-ethylbenes; Triazinylaminostilbenes; Stilbenzyl-2H-triazoles such as stilbene-2H-naphtho [1,2-d] triazoles and bis (1, 2,3-triazol-2-yl) stilbenes; Benzoxazoles such as stilbenzylbenzoxazoles and bis (benzoxazoles); Furans, benzo [b] furans and benzimidazoles such as bis (benzo [b] furan-2-yl) biphenyls and cationic benzimidazoles; - 1, 3-Diphenyl-2-pyrazolines; Coumarinas; Naphthalimides; Derivatives of 1, 3,5-triazin-2-yl. For example, a coumarin-type brightener can be attached to the selected NH2 group or amido group of the CBD and / or linker region. Preferred are bleach-stable brighteners such as 1,4-di (2-methylaminostyryl) benzene.

Other suitable brighteners that can be linked to the selected CBD according to the present invention are the hydrophilic optical brighteners having the structural formula: wherein R-) is selected from anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl; R2 is selected from N-2-bis-hydroxyethyl, N-2-hydroxyethyl-N-methylamino, morpholino, chloro and amino; and M is a salt-forming cation such as sodium or potassium. - When in the above formula, Rj is anilino, R2 is N-2-bis-hydroxyethyl, and M is a cation such as sodium, the brightener is acid 4,4 ', bis [(4-aniolin-6- ( N-2-bis-hydroxyethyl) -s-triazin-2-yl) amino] -2,2'-stilbene-disulfonic acid and its disodium salt. This particular brightener species is marketed under the Tinopal-UNPA-GX brand by Ciba-Geigy Corporation. Tinopal-UNPA-GX is the preferred hydrophilic optical brightener useful in the add-on compositions in the present rinse. - When in the above formula R1 is anilino, R2 is N-2-hydroxyethyl-N-2-methylamino and M is a cation such as sodium, the brightener is the disodium salt of 4,4'-bis [4] -anilino-6- (N-2-hydroxyethyl-N-methylamino) -s-triazin-2-yl) amino] -2,2'-stilbenedisulfonic acid. This particular brightener species is marketed under the Tinopal 5BM-GX brand of Ciba-Geigy Corporation.

- When in the above formula Ri is anilino, R2 is morpholino and M is a cation such as sodium, the brightener is the sodium salt of 4,4'-bis [(4-anilino-6-morphino-s-triazin -2-yl) amino] 2,2'-stilbenedisulfonyl. This particular brightener species is marketed under the Tinopal AMS-GX brand of Ciba-Geigy Corporation. Other suitable optical brighteners are of an anionic character, examples of which are 4,4'-bis- (2-diethanolamino-4-anilino-s-triazin-6-ylamino) estylben-2: 2'd. disodium sulfonate, 4, 4'-bis- (2-morpholino-4-anilino-s-triazin-6-ylamino-stilbene-2: 2-disulfonate disodium, 4,4'-bis- (2,4-dianilino) Disodium-4-triazin-6-ylamino) stilbene-2: 2'-disulfonate, 4 ', 4"-bis- (2,4-dian-yl-s-triazin-6-ylamino) stilbene-2- monosodium sulfonate, disodium 4,4'-bis- (2-anilino-4- (N-methyl-N-2-hydroxyethylamino) -s-triazin-6-ylamino) dis-2,2'-disulfonate, 4,4'-bis- (4-phenyl-2,1)Disodium, 3-triazol-2-yl) -estylben-2,2'-disulfonate, 4,4'-bis (2-anyl-4- (1-methyl-2-hydroxyethylamino) -s Disodium-triazin-6-ylamino) stilbene-2,2'-disulfonate, 2- (stilbe-4"- (naphtho-1 ', 2': 4,5) -1, 2,3-triazole-2" -sulfonate of sodium and 4,4'-bis (2-sulphotryl) biphenyl The highly preferred brighteners are the specific brighteners of co-pending European patent application No. 95201943.8 When included in the compositions of the present invention, these brightening entities will be generally comprised at a level from 0.001% to 10%, preferably from 0.005% to 3.5% by weight of the composition.

Other suitable guiding components Other suitable chemical components that can be bound to a cellulose binding domain selected in accordance with the present invention are latexes and resins. Latexes are defined as suitable materials for refining the folds of the fabric. Suitable materials include a homopolymer such as 9802 (Vinamul). The resins prevent the formation of balls on the fabrics. Suitable resins are Knittex BE from Ciba-Geigy or silicas such as Crosanol NS from Crosfield.

Laundry Detergent and Fabric Care Components Laundry detergent and / or fabric care compositions of the invention will comprise at least one additional fabric detergent and / or care component. The precise nature of these additional components, and the levels of incorporation thereof, will depend on the physical form of the composition and the nature of the cleaning operation for which it is used. As already mentioned above, all the components that can be bound to a cellulose binding domain selected in accordance with the present invention can also be incorporated into the laundry detergent and / or fabric care compositions of the present invention. invention in its conventional unmodified form. The chemical entities of the present invention are generally incorporated in laundry detergent and / or fabric care detergent compositions at a level of 0.00001% to 50%, preferably from 0.001% to 20%, preferably from 0.1% to 10% by weight of the total composition. When formulated as suitable compositions for use in a washing machine washing method, the compositions of the invention preferably contain both a surfactant and a builder, and additionally one or more detergent components preferably selected from polymeric organic compounds, bleaching agents. , additional enzymes, suds suppressors, dispersants, lime soap dispersants, suspending and anti-redeposition agents and corrosion inhibitors. The laundry compositions may also contain softening agents as additional detergent components. The detergent laundry and / or fabric care compositions of the present invention further comprise, preferably, a detergent ingredient selected from cationic surfactants, dye transfer inhibiting polymers, builders, in particular zeolite A and tripol phosphate. of sodium- and / or clays. The compositions of the invention, for example, can be formulated as washing and hand washing detergent compositions, including laundry additive compositions and compositions suitable for use in the rinsing and / or pretreatment of soiled fabrics, and fabric softener compositions to be added. in the rinse. The pre-treatment or post-treatment of fabric includes compositions for the care of the fabric in gel, aerosol and liquid. A rinse cycle is also contemplated with or without the presence of softening agents. The compositions of the invention can also be used as detergent additive products in solid or liquid form. Said additive products are intended to complement or reinforce the action of conventional detergent compositions and can be added at any step of the washing operation. The laundry and / or fabric care detergent compositions according to the invention can be liquid, in paste, gels, sticks, tablets, aerosol, foam, powder or granules. Also, the granulated compositions may be in "compact" form and the liquid compositions in a "concentrated" form. If necessary, the density of laundry detergent compositions herein ranges from 400 to 1200 g / liter, preferably 600 to 950 g / l of composition, measured at 20 ° C. The "compact" form of the compositions herein is best reflected by its density and, in terms of composition, by the amount of inorganic filler salt; the inorganic filler salts are conventional ingredients of the detergent compositions in powder form; In conventional detergent compositions, the filler salts are present in substantial amounts, typically from 17 to 35% by weight of the total composition. In compact compositions, the filler salt is present in amounts not greater than 15% of the total composition, preferably not greater than 10%, most preferably not greater than 5% by weight of the composition. The inorganic filler salts, as understood in the present compositions, are selected from the alkali metal and alkaline earth metal salts of sulfates and chlorides. A preferred filler salt is sodium sulfate. The liquid detergent compositions according to the present invention may also be in "concentrated form"; in such a case, the liquid detergent compositions according to the invention will contain a lower amount of water compared to conventional liquid detergents. Typically, the water content of the concentrated liquid detergent is preferably less than 40%, preferably less than 30%, and preferably less than 20% by weight of the detergent composition.

Surfactant System The detergent laundry and / or fabric care compositions according to the present invention will preferably comprise a surfactant system wherein the surfactant can be selected from nonionic and / or anionic and / or cationic surfactants and / or ampholytic and / or zwitterionic and / or semi-polar. The preferred surfactants are cationic. It has been found surprisingly that the compositions of the present invention additionally comprising a surfactant will provide improved and improved fabric care and cleaning, including care of color, appearance of the fabric, anti-wear properties of the fabric, properties antistatic and / or softness.

The surfactant is typically present at a level of 0. 1% to 60% by weight. The preferred levels of incorporation are from 1 to 35% by weight, most preferably from 1 to 30% by weight of the laundry detergent and / or fabric care compositions according to the invention. The surfactant is preferably formulated to be compatible with the enzyme components present in the composition. In liquid or gel compositions, the surfactant is most preferably formulated in a manner that promotes, or at least does not degrade, the stability of any enzyme in these compositions. Suitable cationic detersive surfactants for use in the laundry detergent and / or fabric care detergent compositions of the present invention are those having a long chain hydrocarbyl group. Examples of said cationic surfactants include ammonium surfactants such as alkyltrimethylammonium halides and. the surfactants that have the formula: [R2 (OR3) and] [R4 (OR3) and] 2R5N + X- wherein R ^ is an alkyl or alkylbenzyl group having from about 8 to about 18 carbon atoms in the alkyl chain, each R3 is selected from a group consisting of -CH2CH2-, -CH2CH (CH3) -, -CH2CH (CH2OH) -, -CH2CH2CH2-, and mixtures thereof; each R 4 is selected from the group consisting of C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl, benzyl ring structures formed by joining the two groups R4 -CH2CHOH-CHOHCOR6CHOHCH2OH, wherein R6 is any hexose or hexose polymer having a molecular weight less than about 1000, and hydrogen when and is not 0; R5 is the same as R O is an alkyl chain in which the total number of carbon atoms of R ^ plus R5 is not greater than about 18; each y is from 0 to approximately 10 and the sum of the values of y is from 0 to approximately 15; and X is any compatible anion. The quaternary ammonium surfactant suitable for the present invention has the formula (I): Formula wherein R1 is a short chain alkyl (C6-C10) or alkylamidoalkyl of the formula (II): Formula II and is 2-4, preferably 3, wherein R2 is H or a C1-C3 alkyl, wherein x is 0-4, preferably 0-2, most preferably 0, wherein R3, R4 and R5 are each same or different, and may be either a short chain alkyl (C1-C3) alkyl or alkoxylated alkyl the formula (III), wherein X "is a counterion, preferably a halide, for example, chloride or methylisulfate.

Formula lll Re is C-j -C4 and z is 1 or 2.

Preferred quaternary ammonium surfactants are those defined in formula I, wherein R-1 is C 1, C 10 or mixtures thereof, x = o, R 3, R 4 = CH 3 and R 5 = CH 2 CH 2 OH.

Highly preferred cationic surfactants are the water-soluble quaternary ammonium compounds useful in the present composition, having the formula: R- | R2R3R4N + X "(i) wherein R- | is C8-C alkyl <6> to one of R2, R3 and R4 is independently C-1-C4 alkyl, C-1-C4 hydroxyalkyl, benzyl and - where x has a value of 2 to 5 and x is an anion.Not more than one of R2, R3 or R4 must be benzyl.The preferred length of the alkyl chain for Rj is C-12-C15, particularly when the alkyl group is a mixture of chain lengths derived from palm or coconut seed fat, that is synthetically derived by olefin accumulation or synthesis of OXO alcohols. Preferred groups for R2, R3 and R4 are methyl and hydroxyethyl groups, and the anion X can be selected from halide, methosulfate, acetate and phosphate ions. Examples of quaternary ammonium compounds of the formula (i), suitable for use herein, are: cocotrimethylammonium chloride or bromide; cocomethyldihydroxyethylammonium chloride or bromide; decyltriethylammonium chloride; decildimethylhydroxyethylammonium chloride or bromide; C12-C15 dimethylhydroxyethylammonium chloride or bromide; cocodimethylhydroxyethyl ammonium chloride or bromide; myristyltrimethylammonium methylisulfate; lauryl dimethylbenzylammonium chloride or bromide; lauryldimethyl (ethenoxy) 4 ammonium chloride or bromide; choline esters (compounds of formula (i) wherein Ri is CH2-CH2-0-C12 alkyl. 4 and R2R3R4 are methyl). OR di-alkylimidazolines [compounds of formula (i)].

Other cationic surfactants useful herein are also described in the patent of E.U.A. No. 4,228, 044, Cambre, issued on October 14, 1980, and in the European patent application EP 000,224.

The cationic softening components of typical fabrics include the active agents quaternary ammonium fabric softeners insoluble in water, or its corresponding amine precursor, being used most commonly ammonium chloride or ammonium methylisulfate long The cationic softeners that are preferred among these They include the following: 1) Disodbodimethylammonium chloride (DTDMAC); 2) hydrogenated disodbodimethylammonium chloride; 3) hydrogenated disodbodimethylammonium methylisulfate; 4) distearyldimethylammonium chloride; ) dioleldimethylammonium chloride; 6) dipamitylhydroxyethylmethylammonium chloride; 7) stearylbenzyldimethylammonium chloride; 8) sebotrimethylammonium chloride; 9) hydrogenated sebotrimethylammonium chloride; ) alkylhydroxyethyldimethylammonium chloride of C 2-14) alkyldihydroxyethyldimethylammonium chloride of C < | 2- 8 12) di (stearoyloxyethyl) dimethylammonium chloride (DSOEDMAC); 13) di (tallowoxyethyl) dimethylammonium chloride; 14) diseboimidazolinium methylisulfate; 15) 1- (2-tallowamemidoethyl) -2-tallowylimidazolium methiisulfate. Biodegradable quaternary ammonium compounds have been presented as alternatives for traditionally used long chain dialkyl ammonium chlorides and methylsulfates. Said quaternary ammonium compounds contain long chain alkyl (en) yl groups interrupted by functional groups such as carbox: lo groups. Such materials and fabric softening compositions containing them are described in numerous publications such as EP-A-0,040,562 and EP-A-0,239,910. The quaternary ammonium compounds and amine precursors of the present have the formula (I) or (II), below: (i) (ii) wherein Q is selected from -OC (O) -, -C (O) -O-, -OC (O) -O-, NR4-C (O) -, C (0) - NR4-; R1 is (CH2) n-Q-T2 or t3; R2 is (CH2) m-Q-T4 or T $ or R3; R is C 1 -C 4 alkyl or C 1 -C 4 hydroxyalkyl or H; R 4 is H or C 1 -C 4 alkyl or C 1 -C 4 hydroxyalkyl; T "l, T2, t3, t4 and T $ are independently C-11-C22 alkyl or alkenyl, n and m are integers from 1 to 4, and X" is an anion compatible with the softener. Non-limiting examples of anions compatible with softener include chloride or methylisulfate. The alkyl or alkenyl chain T "l, T2, t, T4 and T5 must contain at least 1 1 carbon atoms, preferably at least 16 carbon atoms The chain can be straight or branched Sebum is a source Suitable and inexpensive of long chain alkyl and alkenyl material Particularly preferred are compounds in which T ^, T2, t3, t4 and T5 represent the mixture of long chain materials typical for tallow Specific examples of quaternary ammonium compounds for use in the aqueous fabric softening compositions herein include: 1) N, N-di (tallowyloxyethyl) -N, N-dimethylammonium chloride; 2) N, N-di methylisulfate (tallowyloxy); -ethyl) -N-methyl, N- (2-hydroxyethyl) ammonium, 3) N, N-di (2-tallowyloxy-2-oxo-ethyl) -N, N-dimethylammonium chloride; N, N-di (2-tallowyl-oxy-ethylcarbonyl-oxy-ethyl) -N, N-dimethylammonium chloride 5) N- (2-tallowyloxy-2-ethyl) -N- (2 -sexyol-2-oxo-ethyl) -N, Nd-methyl-ammonium; 6) N, N, N-tri (tallowyl-oxy-ethyl) -N-methylated chloride monoxide; 7) N- (2-tallowyl-oxy-2-oxo-ethyl) -N- (tallowyl-N, N-dimethylammonium chloride and 8) 1,2-diisobutyl-oxy-3-tri chloride; methylammoniumpropane and mixtures of any of the above materials. When included, the laundry detergent and / or fabric care compositions of the present invention typically comprise from 0.2% to about 25%, preferably around 1% to about 8% by weight of said cationic surfactants. The polyethylene oxide, polypropylene and polybutylene oxide condensates of alkylphenols are suitable for use as the nonionic surfactant of the surfactant systems of the present invention, with the polyethylene oxide condensates being preferred. These compounds include the condensation products of alkylphenols having an alkyl group containing from about 6 to about 14 carbon atoms, preferably from about 8 to about 14 carbon atoms, either in a straight chain or branched chain configuration , with the alkylene oxide. In a preferred embodiment, the ethylene oxide is present in an amount of about 2 to about 25 moles, preferably about 3 to about 15 moles of ethylene oxide per mole of alkylphenol. Commercially available nonionic surfactants of this type include Igepal ™ CO-630, marketed by GAF Corporation; and Triton ™ X-45, X-114, X-100 and X-102, all marketed by Rohm & Haas Company. These surfactants are commonly known as alkylphenol alkoxylates (for example, alkylphenol ethoxylates). The condensation products of primary and secondary aliphatic alcohols with from about 1 to about 25 moles of ethylene oxide are suitable for use as the nonionic surfactant of the nonionic surfactant systems of the present invention. The alkyl chain of the aliphatic alcohol may be either straight or branched, primary or secondary, and generally contains from about 8 to about 22 carbon atoms. The condensation products of alcohols having an alkyl group containing from about 8 to about 20 carbon atoms, preferably from about 10 to about 18 carbon atoms, with from about 2 to about 10 moles of ethylene oxide are preferred. mol of alcohol. About 2 to about 7 moles of ethylene oxide are present, and most preferably 2 to 5 moles of ethylene oxide per mole of alcohol in said condensation products. Examples of commercially available nonionic surfactants of this type include Tergitol ™ 15-S-9 (the linear alcohol condensation product of C-n-C-15 with 9 moles of ethylene oxide), Tergitol ™ 24-L-6 NMW (the condensation product of C12-C14 primary alcohol with 6 moles of ethylene oxide with a limited molecular weight distribution), both marketed by Union Carbide Corporation; Neodol ™ 45-9 (the linear alcohol condensation product of C14-C-15 with 9 moles of oxide of ethylene), Neodol ™ 23-3 (the linear alcohol condensation product of C- | 2_C? 3 with 3.0 moles of ethylene oxide), Neodol ™ 45-5 (the linear alcohol condensation product of C14-C -15 with 7 moles of ethylene oxide), Neodol ™ 45-5 (the linear alcohol condensation product of C14-C-15 with 5 moles of ethylene oxide), marketed by Shell Chemical Company; Kyro ™ EOB (the alcohol condensation product of C- | 3-Ci 5 with 9 moles of ethylene oxide), marketed by The Procter & Gamble Company, and Genapol LA O3O or O5O (the condensation product of C12-C14 alcohol with 3 or 5 moles of ethylene oxide), marketed by Hoechst. The preferred scale of HLB in these products is 8-11, and most preferred is 8-10. Also useful as nonionic surfactants of the surfactant systems of the present invention are the alkylpolysaccharides described in the U.S.A. No. 4,565,647, Filling, issued January 21, 1986, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms, and a polysaccharide, for example, a polyglycoside, a hydrophilic group containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 units of saccharide. Any reducing saccharide containing 5 or 6 carbon atoms can be used, for example, the glucose, galactose and galactosyl moieties can replace the glucosyl moieties (optionally the hydrophobic moiety is attached in the 2-, 3-, 4- positions). , etc., thus giving a glucose or galactose as opposed to a glucoside or galactoside). The intersaccharide bonds can be, for example, between the position one of the additional saccharide units and the 2-, 3-, 4- and / or 6- positions of the preceding saccharide units. Preferred alkyl polyglycosides have the formula R2O (CnH2nO) t (glycosy1) x wherein R2 is selected from the group consisting of alkyl, alkylphenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof, wherein the alkyl groups contain from about 10 to about 18, preferably from about 12 to about 14, carbon atoms; n is 2 or 3, preferably 2; t is from 0 to about 10, preferably 0; and x is from about 1.3 to about 10, preferably about 1.3 to about 3, most preferably from about 1.3 to about 2.7. The glycosyl is preferably derived from glucose. To prepare these compounds, the alcohol or alkylpolyethoxylated alcohol is first formed, and then reacted with glucose or a glucose source to form the glucoside (linkage at position 1). The additional glycosyl units can then be linked between their position 1 and the preceding glycosyl units in the 2-, 3-, 4- and / or 6- position, preferably predominantly in the 2-position. The condensation products of ethylene oxide with a hydrophobic base, formed by the condensation of propylene oxide with propylene glycol, are also suitable for use as the additional nonionic surfactant systems of the present invention. The hydrophobic portion of these compounds will preferably have a molecular weight of from about 1500 to about 1800, and will exhibit insolubility in water. The addition of polyoxethylene portions to this hydrophobic portion tends to increase the water solubility of the molecule in general, and the liquid character of the product is retained to the point where the polyoxethylene content is about 50% of the total weight of the product. condensation product, which corresponds to condensation with up to about 40 moles of ethylene oxide. Examples of compounds of this type include some Plurafac LF404 and Pluronic ™ surfactants commercially available from BASF. Also suitable for use as nonionic surfactants of the nonionic surfactant system of the present invention are the condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine. The hydrophobic portion of these products consists of the reaction product of ethylene diamine and excess propylene oxide, and generally has a molecular weight of about 2500 to about 3000. This hydrophobic portion is condensed with ethylene oxide to the extent that the product of The condensation contains about 40% to about 80% by weight of polyoxyethylene and has a molecular weight of about 5000 to about 11,000. Examples of this type of nonionic surfactant include some of the Tetronic ™ compounds, commercially available from BASF. Preferred for use as nonionic surfactants of the surfactant systems of the present invention are the polyethylene oxide condensates of alkylphenols, the condensation products of primary and secondary aliphatic alcohols with from about 1 to about 25 moles of ethylene oxide, alkylpolysaccharides and mixtures thereof. Preferred are the alkylphenol ethoxylates of C3-C- | 4 having 3 to 15 ethoxy groups and the alcohol ethoxylates of Cs-C ^ s (preferably an average of C- | rj) having 2 to 10 ethoxy groups, and mixtures thereof. The highly preferred nonionic surfactants are the polyhydroxy fatty acid amide surfactants of the formula R2- C - N - Z, Or II R I, wherein R1 is H, or R1 is C1-C4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl or a mixture thereof, R2 is hydrocarbyl of C5-31 and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly attached to the chain, or a derivative alkoxylated thereof. Preferably, R1 is methyl, R2 is a chain C11-C15 alkyl straight or C- alkyl or alkenyl; g-C-i8. such as cocoalkyl or mixtures thereof, and Z is derived from a reducing sugar such as glucose, fructose, maltose and lactose, in a reductive amination reaction. Suitable anionic surfactants to be used are the linear alkylbenzene sulfonate and alkyl ether sulfonate surfactants, which include linear esters of C8-C20 carboxylic acids (ie, fatty acids) that are sulphonated with gaseous SO3 according to "The Journal of the American Oil Chemists Society, 52 (1975), pp. 323-329. Suitable starting materials would include natural fatty substances such as those derived from tallow, palm oil, etc. The preferred alkyl ether sulphonate surfactant, especially for applications of laundry, comprises alkylster-sulfonate surfactants of the structural formula: OR R3 - CH - C - OR4 SO3M wherein R3 is a C8-C20 hydrocarbyl. preferably a alkyl, or combination thereof, R is a C 1 -C 7 hydrocarbyl, preferably an alkyl or a combination thereof, and M is a cation which forms a water soluble salt with the alkyl ether sulphonate. Suitable salt-forming cations include metals such as sodium, potassium and lithium, and substituted or unsubstituted ammonium cations such as monoethanolamine, diethanolamine and triethanolamine. Preferably, R3 is C < ? o-C- | 6 and R ^ is methyl, ethyl or isopropyl. Preferred especially the methylstersulfonates wherein R3 is C- | o-C- alkyl; 6- Other suitable anionic surfactants include the alkyl sulfate surfactants which are salts or water soluble acids of the formula ROSO3M, wherein R is preferably a hydrocarbyl of C- | n-C24, preferably an alkyl or hydroxyalkyl having a component C10-C20 alkyl. preferably, an alkyl or a C12-C- hexaryloxyalkyl; 8- and M is H or a cation, for example, an alkali metal cation (eg, sodium, potassium, lithium), or ammonium or substituted ammonium (eg, methyl-, dimethyl-, and trimethylammonium cations and cations of quaternary ammonium such as tetramethylammonium cations and dimethylpiperidinium, and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, mixtures thereof, and the like). Typically, alkyl chains of C-12-C-I6 are preferred for lower wash temperatures (e.g., below about 50 ° C), and alkyl chains of C? G-18 are preferred for higher wash temperatures. (for example, above 50 ° C approximately). Other anionic surfactants useful for detersive purposes may also be included in the laundry detergent and / or fabric care detergent compositions of the present invention. These may include salts (including, for example, sodium, potassium, ammonium and substituted ammonium salts such as mono-, di- and triethanolamine salts) of soap, C8-C22 primary or secondary alkanesulfonates. C3-C24 olefinsulfonates, sulfonated polycarboxylic acids prepared by sulfonation of the pyrolyzed product of alkaline earth metal citrates, for example, as described in British Patent Specification No. 1, 082,179, C3-C24 alkyl polyglycol ether sulphates (containing up to 10 moles of ethylene oxide); alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethers sulfates of ethylene oxide, paraffinsulfonates, alkyl phosphates, isethionates, such as acyl isethionates, N-acyltaurates, alkylsuccinamates and sulfosuccinates, monoesters of sulfosuccinates (especially saturated and unsaturated C-12-C18 monoesters) and diesters of sulfosuccinates (especially saturated and unsaturated Cg-C12 diesters), acyl sarcosinates, alkylpolyacharide sulfates such as alkyl polyglucoside sulfates (non-sulphonated non-ionic compounds are described below), branched primary alkyl sulphates and alkylpolyethoxycarboxylates, such as those of the formula RO (CH 2 CH 2?) k- CH 2 COO-M +, wherein R is a C 8 -C 22 alkyl. k is an integer from 1 to 10, and M is a soluble salt forming cation. Resin acids and hydrogenated resin acids are also suitable, such as rosin, hydrogenated rosin and rosin acids, as well as hydrogenated rosin acids present in, or derived from, tallow tree oil. Additional examples are described in "Surface Active Agents and Detergents" -Surfactants and detergents- (Vol. I and II of Schwartz, Perry and Berch). A variety of such surfactants are also generally described in the US patent. No. 3,929,678, issued December 30, 1975 to Laughiin et al., In column 23, line 58, to column 29, line 23 (incorporated herein by reference). When included herein, the laundry detergent compositions of the present invention typically comprise from about 1% to about 40%, preferably from about 3% to about 20%, by weight of said anionic surfactants. Highly preferred anionic surfactants include alkoxylated alkylsulfate surfactants which are water soluble salts or acids of the formula RO (A) mSO3M, wherein R is an unsubstituted C-10-C24 alkyl or hydroxyalkyl group having one component C10-C24 alkyl. preferably a C12-C20 alkyl or hydroxyalkyl. preferably, C12-C18 alkyl or hydroxyalkyl. A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, preferably between about 0.5 and about 3, and M is H or a cation which may be, for example, a metal cation ( for example, sodium, potassium, lithium, calcium, magnesium, etc.), or an ammonium or substituted ammonium cation. Ethoxylated alkyl sulphates, as well as propoxylated alkyl sulfates are also contemplated herein. Specific examples of substituted ammonium cations include methyl-, dimethyl-, and trimethylammonium cations, and quaternary ammonium cations such as tetramethylammonium and dimethylpiperidinium cations, and those derived from alkylamines such as ethylamine, diethylamine, triethylamine, mixtures thereof and Similar. Exemplary surfactants are polyethoxylated alkyl sulfate (1.0) from C <; | 2-C- | 3 (Ci2-Ci8E (1.0) M), polyethoxylated alkyl sulfate (2.25) of C12-C18 (C- | 2-C? 3E (2-25) M), polyethoxylated alkyl sulfate (3.0) of c12"c18 (Ci2-CidE (3.0) M), and polyethoxylated alkyl sulfate (4.0) of C12-C18 (Ci2-Ci8E (4.0) M), in which M is conveniently selected from sodium and potassium. preferred are branched anionic surfactants in the middle part of the chain, described in the co-pending US applications Ser. Nos. 97/06485, US 97/06474, US 97/06339, US 97/06476 and US 97/06338, and in WO 97/39091, incorporated herein by reference, The compositions of the present invention generally comprise from 0.1% to 50%, preferably from 0.5% to 40%, preferably from 1% to 35% by weight of the composition. total, of one or more long chain alkyl surfactant compounds branched in the middle part of the chain, of the formula: Ab-X-B, wherein: (I) Ab is a hydrophobic portion of branched alkyl or in the middle part of the chain, which has a total of 9 to 22 carbons in the portion, preferably from 12 to about 18, which has: (1) a longer linear carbon chain attached to the -XB portion in the scale from 8 to 21 carbon atoms; (2) one or more C1-C3 alkyl portions branching from this longer linear carbon chain; (3) at least one of the branching alkyl portions is directly attached to a carbon of the longest linear carbon chain at a position within the scale of the carbon 2 position, continuing from the position of carbon 1 (# 1) that is attached to the -XB portion, to the position of the terminal carbon minus 2 carbons (carbon (? -2)), and (4) when more than one of these compounds is present, the average total number of atoms of carbon in the Ab-X portions in the formula above, is on the scale of more than 11 to 20, preferably 14.5 to about 18, preferably about 15 to about 17; (II) B is a hydrophilic portion selected from sulfates, sulfonates, amine oxides, polyoxyalkylene, preferably polyoxyethylene and polyoxypropylene, alkoxylated sulfates, polyhydroxy portions, phosphate esters, glycerolsulfonates, polygluconates, polyphosphate esters, phosphonates, sulfosuccinates, sulfosuccinamates, carboxylates polyalkoxylates, glucamides, taurinates, sarcosinates, isethionates, dialkanolamides, monoalkanolamides, monoalkanolamide sulphates, diglycolamides, diglycollamides, glycerol esters, glycerol estersulfates, glycerol ether sulfates, polyglycerol ethers, polyglycerol ether sulfonates, polyglycerol esters, sorbitan, polyalkoxylated sorbitan esters, ammonium alkane sulphonates, amidopropyl betaines, alkylated quats, alkylated / polyhydroxyalkylated quats, imidazolines, 2-yl succinates, sulphonated alkylesters and sulfonated fatty acids; and (III) X is selected from -CH2- and -C (O) -.

Preferred branched anionic surfactants in the middle part of the chain are those of the above formula wherein the portion A13 is a branched primary alkyl portion having the formula: R R1 R2 CH3CH2 (CH2) wCH (CH2)? CH (CH2) and CH (CH2) z- where the total number of carbon atoms in the branched primary alkyl portion of this formula, including branching R, R1 and R3 , is from 13 to 19; R, R 1 and R 2 are each independently selected from hydrogen and C 1 -C 3 alkyl, preferably methyl, provided that R, R 1 and R 2 are not all hydrogen and, when z is 0, at least R or R 1 is not it is hydrogen; w is an integer from 0 to 13; x is an integer from 0 to 13; "y" is an integer from 0 to 13; z is an integer from 0 to 13; and w + x + y + z is from 7 to 13. Most preferably, said surfactant has the formula: or mixtures thereof; in dor > of M represents one or more cations; a, b, d and e are integers, a + b is from 10 to 16, d + e is from 8 to 14 and where in addition: when a + b = 10, a is an integer from 2 to 9 and b is an integer of 1 to 8; when a + b = 1 1, a is an integer from 2 to 10 and b is an integer of 1 to 9; when a + b = 12, a is an integer from 2 to 1 1 and b is an integer from 1 to 10; when a + b = 13, a is an integer from 2 to 12 and b is an integer of 1 to 1 1; when a + b = 14, a is an integer from 2 to 13 and b is an integer of 1 to 12; when a + b = 15, a is an integer from 2 to 14 and b is an integer of 1 to 13; when a + b = 16, a is an integer from 2 to 15 and b is an integer of 1 to 14; when d + e = 8, d is an integer from 2 to 7 and e is an integer from 1 to 6; when d + e = 9, d is an integer from 2 to 8 and e is an integer from 1 to 7; when d + e = 10, d is an integer from 2 to 9 and e is an integer from 1 to 8; when d + e = 11, d is an integer from 2 to 10 and e is an integer of 1 to 9; when d + e = 12, d is an integer from 2 to 11 and e is an integer of 1 to 10; when d + e = 13, d is an integer from 2 to 12 and e is an integer from 1 to 11; when d + e = 14, d is an integer from 2 to 13 and e is an integer of 1 to 12; whereby, when more than one of these sulfate surfactants is present in the surfactant system, the average total number of carbon atoms in the primary alkyl portions is 11 to 20, preferably 14.5 to 18. Preferred particularly that said surfactant having an Ab-X portion, comprises 11 to 20, preferably 16 to 18 carbon atoms, and B is a sulfate group. The detergent laundry and / or fabric care compositions of the present invention may also contain ampholytic, zwitterionic and semipolar surfactants, as well as other nonionic and / or anionic surfactants other than those already described in I presented. The ampholytic surfactants are also suitable for use in laundry detergent and / or fabric care detergent compositions of the present invention. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or as aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be a straight or branched chain. One of the aliphatic substituents contains at least about 8 carbon atoms, usually from about 8 to about 18 carbon atoms, and at least one contains an anionic water solubilization group, eg, carboxy, sulfate, sulfonate . See the patent of E.U.A. No. 3,929,678 to Laughiin et al., Issued December 30, 1975, column 19, lines 18-35, for examples of ampholytic surfactants. When included, the laundry detergent and / or fabric care compositions of the present invention typically comprise from 0.2% to about 15%, preferably from about 1% to about 10% by weight of said ampholytic surfactants. Zwitterionic surfactants are also suitable for use in laundry detergent and / or fabric care compositions. These surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines or derivatives of quaternary ammonium compounds, quaternary phosphonium or tertiary sulfonium. See the patent of E.U.A. No. 3,929,678 to Laughiin et al., Issued December 30, 1975, in column 19 line 38, to column 22 line 48, for examples of zwitterionic surfactants. When included, the laundry detergent and / or fabric care compositions of the present invention typically comprise from 0.2% to about 15%, preferably from about 1% to about 10% by weight of said zwitterionic surfactants. Semi-polar nonionic surfactants are a special category of nonionic surfactants that include water-soluble amine oxides containing an alkyl portion of about 10 to about 18 carbon atoms and 2 portions selected from the group consisting of alkyl groups and groups hydroxyalkyl containing from about 1 to about 3 carbon atoms; water-soluble phosphine oxides containing an alkyl portion of about 10 to about 18 carbon atoms and two portions selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms; and water soluble sulfoxides containing an alkyl portion of about 10 to about 18 carbon atoms, and a portion selected from the group consisting of alkyl and hydroxyalkyl portions of about 1 to about 3 carbon atoms. Semi-polar nonionic surfactants include the amine oxide surfactants having the formula: 0 t R3 (OR4) xN (R5) 2 wherein R3 is an alkyl, hydroxyalkyl or alkylphenyl group, or mixtures thereof, containing from about 8 to about 22 carbon atoms; R 4 is an alkylene or hydroxyalkylene group containing from about 2 to about 3 carbon atoms, or mixtures thereof; x is from 0 to approximately 3; and each R 5 is an alkyl or hydroxyalkyl group containing from about 1 to about 3 carbon atoms, or a polyethylene oxide group containing from about 1 to about 3 ethylene oxide groups. The R ^ groups can be attached to each other, for example, through an oxygen or nitrogen atom to form a ring structure. These amine oxide surfactants include in particular CJ Q-CI SV alkyldimethylamine oxides C8-C- 2- alkoxyethyldihydroxyethylamine oxides When included, the laundry detergent and / or fabric care detergent compositions of the present invention typically comprise from about 0.2% to about 15%, preferably from about 1% to about 10% by weight of said semi-polar nonionic surfactants. The detergent laundry and / or fabric care composition of the present invention may further comprise, preferably, an associated surfactant selected from the group of primary or tertiary amines. Primary amines suitable for use herein include amines according to the formula R-1 NH2, wherein R-j is an alkyl chain of C-C-12. preferably CQ-C ^ \ Q, or R4X (CH2) n. X is -O-, -C (O) NH- or -NH-, R4 is an alkyl chain of C6-C12. n is between 1 to 5, preferably 3. The alkyl chains of R- | they may be straight or branched and may be interrupted with up to 12, preferably less than 5, portions of ethylene oxide. Preferred amines according to the above formula are the n-alkylamines. Amines suitable for use herein may be selected from 1-hexyl amine, 1-octyl amine, 1-decylamine and laurylamine. Other preferred primary amines include C3-C- | or > octyloxypropylamine, 2-ethylhexyloxypropylamine, laurylamidopropylamine and amidopropylamine. Tertiary amines suitable for use herein include tertiary amines having the formula R- | R2R3N, where R- | and R2 are alkyl chains of C- | -C8 or - (CH ^ -CH-O)? H R3 is an alkyl chain of Cg-C ^ preferably Cg-C-jo. or R3 is R4X (CH2) n. wherein X is -O-, - C (O) NH- or -NH-, R4 is one of C4-C12. n is between 1 to 5, preferably 2-3. R5 is H or C1-C2 alkyl and x is between 1 and 6. R3 and R4 can be linear or branched; the alkyl chains of R3 may be interrupted with up to 12, preferably less than 5, portions of ethylene oxide. Preferred tertiary amines are R? R2 3N, where R- | is an alkyl chain of Cg-C-j2. F * 2 and ^ 3- are C-) -C3 alkyl or - (CH- CH-0)? H where R5 is H or CH3 and x = 1-2. Amidoamines of the formula are also preferred: O R- C-NH- (CH2) n-N- (R2) 2 where R- | is C 1 -C 2 alkyl. n is 2-4, preferably n is 3; R2 and R3 is C? -C4.

Highly preferred amines of the present invention include 1-octylamine, 1-hexylamine, 1-decylamine, 1-dodecylamine, C3-oxypropylamine C-io- N-coco-1-3-diaminopropane, cocoalkyldimethylamine, lauryldimethylamine, Auryl-bis (hydroxyethyl) amine, coco-bis (hydroxyethyl) amine, lauryl amine propoxylated with 2 moles, octyl amine propoxylated with 2 moles, lauryl amidopropyldimethylamine, amidopropyldimethylamine of C3-C? Amidopropyldimethylamine of C10. Highly preferred amines for use in the compositions herein are 1-hexyl amine, 1-octylamine, 1-decylamine, 1-dodecylamine. Especially convenient are n-dodecyldimethylamine and bishydroxyethylcocoalkylamine, and 7-fold ethoxylated oleylamine, laurylamidopropylamine and cocoamidopropylamine.

Conventional detergent enzymes Enzymes suitable for use in the compositions of the present invention include enzymes selected from cellulases, hemicellulases, peroxidases, proteases, glucoamylases, amylases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tanases, pentosanas, mannanases, β-glucanases, arabinosidases, hyaluronidase , chondroitinase, laccase or mixtures thereof. A preferred combination is a cocktail of conventional applicable enzymes such as protease, amylase, lipase, cutinase and / or cellulase, in conjunction with one or more plant cell wall degrading enzymes. Cellulases useful in the present invention include both bacterial and mycotic cellulases. Preferably, they will have an optimum pH of between 5 and 12, and a specific activity of more than 50 CEVU / mg (Cellulose Viscosity Unit). Suitable cellulases are described in the U.S.A. No. 4,435,307, Bargesgoard et al., J 61078384 and WO 96/02653, which describe mycotic cellulases produced respectively from Humicola insolens, Trichoderma, Thielavia and Sporotrichum. EP 739 982 describes cellulases isolated from novel Bacillus species. Suitable cellulases are also described in GB-A-2,075,028; GB-A-2,095,275; DE-OS-2,247,832 and WO 95/26398. Examples of said cellulases are the cellulases produced by a strain of Humicola insolens (Humicola grísea var. Thermoidea), particularly the DSM 1800 strain of Humicola. These cellulases originating from Humicola insolens having a molecular weight of about 50Kda, an isoelectric point of 5.5 and containing 415 amino acids are preferred; and a ~ 43kD endoglucanase derived from Humicola insolens, DSM 1800, exhibiting cellulase activity; a preferred endoglucanase component has the amino acid sequence described in PCT patent application No. WO 91/17243. Also suitable are cellulases EGlll from Trichoderma longibrachiatum described in WO 94/21801, Genencor, published September 29, 1994. Especially suitable cellulases are those having color care benefits. Examples of said cellulases are the cellulases described in the European patent application No. 91202879.2, filed on November 6, 1991 (Novo). Carezyme and Celluzyme (Novo Nordisk A / S) are especially useful. See also WO 91/17244 and WC 91/21801. Other cellulases suitable for fabric care and / or cleaning properties are described in WO 96/34092, WO 96/17994 and WO 95/24471. Said cellulases are normally incorporated in the detergent composition at levels of 0.0001% to 2% pure enzyme by weight of the detergent composition. The enzyme system can be used as a bleaching agent: Hydrogen peroxide can also be present by adding an enzyme system (ie, an enzyme and a substrate therefor) that is capable of generating hydrogen peroxide at the beginning or during the operations of washing and / or rinsing. Such enzyme systems are described in the patent application EP 91202655.6, filed on October 9, 1991. The peroxidase enzymes are used in combination with oxygen sources, for example, percarbonate, perborate, persulfate, hydrogen peroxide, etc., and with a phenolic substrate as a bleaching-enhancing molecule. They are used for "bleaching in solution", that is, to avoid the transfer of dyes or pigments removed from the substrates during the washing operations, to other substrates in the washing solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidase such as chloro- and bromoperoxidase. Peroxidase-containing detergent compositions are described, for example, in the PCT International Application WO 89/099813, WO 89/09813 and European Patent Application No. 91202882.6, filed on November 6, 1991, and EP No. 96870013.8 , filed on February 20, 1996. The laccase enzyme is also suitable. The increments are generally comprised at a level of 0.1% to 5% by weight of the total composition. Preferred incrementers are substituted phenoxyzine and phenoxyzine, 10-phenothiazinopropionic acid (PPT), 10-ethylphenothiazine-4-carboxylic acid (EPC), 10-phenoxazinopropionic acid (POP) and 10-methylphenoxazine (described in WO 94/12621). , substituted syringates (substituted C3-C5 alkylsalicylates) and phenols. Percarbonate or sodium perborate are the preferred sources of hydrogen peroxide. Said peroxidases are normally incorporated in the detergent composition at levels of 0.0001% to 2% of active enzyme by weight of the detergent composition. Other preferred enzymes that can be included in the detergent compositions of the present invention include lipases. Suitable lipase enzymes for detergent use include those produced by microorganisms of the Pseudomonas group, such as Pseudomonas stutzeri ATCC 19.154, such as those described in British Patent 1, 372, 034. Suitable lipases include those that show a positive immunological cross-reaction with the lipase antibody, produced by the microorganism Pseudomonas fluorescent IAM 1057. This lipase is available from Amano Pharmaceutical Co. Ltd., Nagoya, Japan, under the tradename Lipase P "Amano", hereinafter referred to as "Amano-P". Other suitable commercial lipases include Amano-CES, lipases ex Chromobacter viscosum, for example Chromobacter viscosum var. lipoliticum NRRLB 3673, from Toyo Jozo Co., Tagata, Japan; Chromobacter viscosum lipases from U.S. Biochemical Corp, E.U.A. and Disoynth Co., The Netherlands, and lipases ex Pseudomonas gladioli. Particularly suitable lipases are lipases such as M1 Lipase and Lipomax (Gist-Brocades) and Lipolase and Lipolase Ultra (Novo), which have been found to be very effective when used in combination with the compositions herein. invention. Also suitable are the lipolytic enzymes described in EP 258 068, WO 92/05249 and WO 95/22615 from Novo Nordisk, and in WO 94/03578, WO 95/35381 and WO 96700292 from Unilever. Also suitable are cutinases [EC 3.1.1.50] that can be considered as a special type of lipase, particularly lipases that do not require interfacial activation. The addition of cutinases to detergent compositions has been described for example in WO-A-88/09367 (Genencor); WO 90/09446 (Plant Genetic System) and WO 94/14963 and WO 94/14964 (Unilever). The lipases and / or cutinases are normally incorporated in the detergent composition at levels from 0.0001% to 2% pure enzyme per weight of the detergent composition. Suitable proteases are the subtilisins that are obtained from particular strains of ß. subtilis and B. licheniformis (subtilisin BPN and BPN '). A suitable protease is obtained from a strain of Bacillus, which has a maximum activity in the entire pH range of 8-12, developed and sold as ESPERASE® by Novo Industries A / S of Denmark, hereinafter "Novo". The preparation of this enzyme and analogous enzymes is described in GB 1, 243,784 of Novo. Other suitable proteases include ALCALASE® 'DURAZYM® and SAVINASE® from Novo and MAXATASE®, MAXACAL®, PROPERASE® and MAXAPEM® (manipulated protein Maxacal) from Gist-Brocades. Proteases described in patent applications EP 251 446 and WO 91/06637, BLAP® protease described in WO 91/02792, and variants described in WO 95/23221 are also suitable for the present invention. See also a high pH protease of Baccillus sp NCIMB 40338 described in WO 93/18140 A of Novo. Enzymatic detergents comprising protease, one or more other enzymes, and a reversible protease inhibitor are described in WO 92/03529 A by Novo. When desired, a protease having reduced adsorption and increased hydrolysis is available, which is described in WO 95/07791 of Procter & Gamble. A recombinant trypsin-like protease for detergents, suitable for the present invention, is described in WO 94/25583, by Novo. Other suitable proteases are described in EP 516 200, Unilever. The proteolytic enzymes also include modified bacterial serine proteases such as those described in European Patent Application Serial No. 87 303761.8, filed on April 28, 1987 (in particular pages 17, 24 and 98), and which is called here "Protease B", and in European patent application 199,404, Venegas, published October 29, 1986, which refers to a modified bacterial serine proteolytic enzyme which is called "Protease A" here. The one here called "Protease C", which is a variant of a Bacillus alkaline serine rotease in which lysine replaces arginine in position 27, tyrosine replaces valine in position 104, serine replaces asparagine in position 123 and alanine replaces threonine in position 274. Protease C is described in WO 91/06637. Also included herein are genetically modified variants, particularly of protease C. A preferred protease, referred to as "Protease D," is a carbonyl hydrolase variant having an amino acid sequence that is not found in nature, and which is derived from a precursor carbonyl hydrolase by substituting a different amino acid with a plurality of amino acid residues at a position in said carbonyl hydrolase equivalent to the +76 position, preferably also in combination with one or more positions of amino acid residues equivalent to those selected from the group consisting of +99, +101, +103, +104, +107, +123, +27, +105, +109, +126, +128, +135, +156, +166, +195, +197, +204, + 206, +210, +216, +217, +218, +222, +260, +265 and / or +274, according to the numeration of the subtilisin of Bacillus amyloliquefaciens, as described in WO 95/10591 and WO 95/10592. The "protease D" variants preferably have the amino acid substitution in 76/103/104, preferably the N76D / S103A / V104I substitution. Also suitable is a carbonyl hydrolase variant of the protease described in WO 95/10591 having an amino acid sequence derived by replacing a plurality of amino acid residues in the precursor enzyme, corresponding to the +210 position in combination with one or more than the following residues: - 33, +62,? -67, +76, +100, +101, +103, +104, +107, +128, +129, +130, +132; +135, +156, +158, +164, +166, +167, +170, +209, +215, +217, +218 and +222, where the numbered position corresponds to the subtilisin of Bacillus amyloliquefaciens natural, or to equivalent amino acid residues in other carbonyl hydrolases or subtilisins, such as Bacillus lentus subtilisin (co-pending patent application published under WO 98/55634). Highly preferred proteases are multiply substituted protease variants. These protease variants comprise a substitution of an amino acid residue with another natural amino acid residue at an amino acid residue position corresponding to position 103 of the subtilisin of Bacillus amyloliquefaciens, in combination with a substitution of corresponding amino acid residue positions to positions 1, 3, 4, 8, 9, 10, 12, 13, 16, 17, 18, 19, 20, 21, 22, 24, 27, 33, 37, 38, 42, 43, 48, 55 , 57, 58, 61, 62, 68, 72, 75, 76, 77, 78, 79, 86, 87, 89, 97, 98, 99, 101, 102, 104, 106, 107, 109, 111, 114 , 116, 117, 119, 121, 123, 126, 128, 130, 131, 133, 134, 137, 140, 141, 142, 146, 147, 158, 159, 160, 166, 167, 170, 173, 174 , 177, 181, 182, 183, 184, 185, 188, 192, 194, 198, 203, 204, 205, 206, 209, 210, 211, 212, 213, 214, 215, 216, 217, 218, 222 , 224, 227, 228, 230, 232, 236, 237, 238, 240, 242, 243, 244, 245, 246, 247, 248, 249, 251, 252, 253, 254, 255, 256, 257, 258 , 259, 260, 261, 262, 263, 265, 268, 269, 270, 271, 272, 274 and 275, of Bacillus amyloliquefaciens subtilisin; when said protease variant includes a substitution of amino acid residues at the positions corresponding to positions 103 and 76, there is also a substitution of an amino acid residue at one or more amino acid residue positions other than amino acid residue positions corresponding to positions 27, 99, 101, 104, 107, 109, 123, 128, 166, 204, 206, 210, 216, 217, 218, 222, 260, 265 or 274 of Bacillus amyloliquefaciens subtilisin and / or variants of multiply substituted protease comprising a substitution of an amino acid residue with another natural amino acid residue at one or more amino acid residue positions corresponding to positions 62, 212, 230, 232, 252 and 257 of Bacillus amyloliquefaciens subtilisin , as described in PCT applications Nos. PCT / US 98/22588, PCT / US 98/22482 and PCT / US 98/22486, all filed on October 23, 1998 from The Procter & Gamble Company. Preferred multiple-substituted protease variants have the amino acid substitution 101/103/104/159/232/236/245/248/252, most preferably 101 G / 103A / 1041 / 159D / 232V / 236H / 245R / 248D / 252K, according to the numeration of the subtilisin of Bacillus amyloliquefaciens. The proteolytic enzymes are incorporated in the detergent compositions of the present invention at a level of from 0.0001% to 2%, preferably from 0.001% to 0.2%, most preferably from 0.005% to 0.1% pure enzyme by weight of the composition. Amylases (a and / or ß) can be included for the removal of carbohydrate-based spots. In WO 94/02597, Novo Nordisk A / S, published on February 3, 1994, cleaning compositions incorporating mutant amylases are described. See also WO 95/10603, Novo Nordisk A / S, published April 20, 1995. Other amylases known to be used in cleaning compositions include both α and β amylases. The α-amylases are known in the art and include those described in the U.S. patent. No. 5,003,257; EP 252,666; WO / 91/00353; FR 2,676,456; EP 285,123; EP 525,610; EP 368,341; and in the description of British Patent No. 1, 296,839 (Novo). Other suitable amylases are the amylases of improved stability described in WO 94/18314, published on August 18, 1994 and WO 96/05295, Genencor, published on February 22, 1996, as well as the amylase variants having a further modification in the immediate parent, available from Novo Nordisk A / S, described in WO 95/10603, published April 1995. Amylases described in EP 277 216, WO 95/26397 and WO 96/23873 (all from Novo Nordisk) are also suitable. Examples of commercial α-amylase products are Purafect Ox Am® from Genencor, and Termamyl®, Ban®, Fungamyl® and Duramyl®, all available from Novo Nordisk A / S, Denmark. WO 95/26397 describes other suitable amylases: α-amylases characterized by having a specific activity at least 25% higher than the specific activity of Termamyl® at a temperature range of 25 ° C to 55 ° C, and at a pH value on a scale of 8 to 10, as measured by the Phadebas® α-amylase activity test. Preferred are the variants of the above enzymes, described in WO 96/23873 (Novo Nordisk). Preferably, the variants are those which show improved thermal stability, preferably those in which at least one amino acid residue equivalent to F180, R181, G182, T183, G184 or K185 has been deleted from the original α-amylase. Particularly preferred are variants having improved thermal stability comprising amino acid deletions R181 * + G182 * or T183 * + G184 *. Other amylolitic enzymes with improved properties with. regarding the level of activity, and the combination of thermal stability and a higher activity level, are described in WO 95/35382. The amylolytic enzymes are incorporated in the detergent compositions of the present invention at a level of from 0.0001% to 2%, preferably from 0.00018% to 0.06%, most preferably from 0.00024% to 0.048% pure enzyme by weight of the composition. The aforementioned enzymes may have any suitable origin, such as vegetable, animal, bacterial, mycotic and yeast.

The origin can also be mesophilic or extremophilic (psychrophilic, psychrotrophic, thermophilic, barophilic, alkalophilic, acidophilic, halophilic, etc.). Purified or non-purified forms of these enzymes can be used. By definition, mutants of natural enzymes are also included. Mutants can be obtained, for example, by protein engineering and / or genetics, chemical and / or physical modifications of natural enzymes. It is also common practice the expression of the enzyme by host organisms in which the genetic material responsible for the production of the enzyme has been cloned. Said enzymes are normally incorporated in the detergent laundry and / or fabric care compositions of the present invention, at levels of 0.0001% to 2% pure enzyme by weight of the composition. Enzymes can be added as separate individual ingredients (pills, granules, stabilized liquids, etc., containing an enzyme), or as mixtures of two or more enzymes (eg, cogranulates). Other suitable ingredients for use in the compositions of the present invention are the enzyme oxidation scavengers described in co-pending European patent application 92870018.6, filed on January 31, 1992. Examples of said enzyme oxidation scavengers are the Ethoxylated tetraethylenepolyamines. A range of enzyme materials and means for their incorporation into synthetic detergent compositions is also disclosed in WO 9307263 A and WO 9307260 A from Genencor International, WO 8908694 A from Novo, and US Pat. No. 3,553,139, January 5, 1971 for McCarty et al. Enzymes are also described in the US patent. No. 4,101, 457, Place et al., July 18, 1978 and in the patent of E.U.A. No. 4,507,219, Hughes, March 26, 1985. Enzyme materials useful for liquid detergent formulations and their incorporation into such formulations are described in US Pat. No. 4,261, 868, Hora et al., April 14, 1981. Enzymes to be used in detergents can be stabilized by various techniques. Enzyme stabilization techniques are described and exemplified in the US patent. 3,600,319, August 17, 1991, Gedge et al., EP 199,405 and EP 200,586, October 29, 1986, Venegas. Enzyme stabilization systems are also described, for example, in the U.S. patent. No. 3,519,570. A useful Bacillus, sp. AC13, which gives proteases, xylanases and cellulases, is described in WO 9401532 A de Novo.

Benefits of color care and fabric care Other suitable technologies that provide a type of color care benefit can also be included. Examples of these technologies are metallocatalysts for color maintenance. Said metallocatalysts are described in copending European patent application No. 92870181.2. Dye fixing agents, polyolefin dispersion against wrinkles and improved water absorbency, perfume and aminofunctional polymer for color care treatment, and perfume substantivity, are additional examples of fabric care / color care technologies, and are described in co-pending patent application No. 96870140.9 filed on November 7, 1996. Another suitable fabric softening agent may be of inorganic or organic type. Inorganic softening agents are exemplified by the smectite clays described in GB-A-1 400 898 and in the US Pat. No. 5,019,292. Organic fabric softening agents include the water insoluble tertiary amines described in GB-A1 514 276 and EP-B0 011 340, and their combination with monosales of C12-C14 quaternary ammonium is described in EP-B 0 026 527 and EP-BO 026 528, and long chain diamides as described in EP-BO 242 919. Other useful organic ingredients of fabric softening systems include high molecular weight polyethylene oxide materials., as described in EP-A-0 299 575 and 0 313 146. Preferably, laundry detergent and / or fabric care detergent compositions of the present invention will comprise a smectite clay. It has surprisingly been found that said compositions provide improved anti-wrinkle properties, static control, softness of the fabric and anti-wear properties of the fabric. Smectite clay levels are usually in the range of 2% to 20%, preferably 5% to 15% by weight, the material being added as a dry combined component to the rest of the formulation. Organic fabric softening agents, such as water-insoluble tertiary amines or long-chain diamide materials, are incorporated at levels of 0.5% to 5% by weight, normally from 1% to 3% by weight, while the materials of high molecular weight polyethylene oxide and water soluble cationic materials are added at levels of 0.1% to 2%, usually from 0.15% to 1.5% by weight. These materials are normally added to the spray-dried portion of the composition, although in some cases it may be more convenient to add them as dry combined particles, or to spray them as molten liquid over the other solid components of the composition.

Bleaching agent Other detergent ingredients that can be included in laundry detergent and / or fabric care detergent compositions of the present invention include bleaching agents. The bleach component for use herein may be any of the bleaching agents useful for cleaning compositions, including oxygen bleach and others known in the art. The bleaching agent suitable for the present invention may be an activated or non-activated bleaching agent. A category of oxygen bleaching agent that can be used encompasses percarboxylic acid bleaching agents and salts thereof. Suitable examples of this class of agents include magnesium monoperoxyphthalate hexahydrate, the magnesium salt of meta-chloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid and diperoxydecanedioic acid. Such bleaching agents are described in the U.S.A. No. 4,483,781, patent of E.U.A. No. 740,446, the European patent application 0,133,354 and the patent of E.U.A. No. 4,412,934. Most preferred bleaching agents also include 6-nonylamino-6-oxoperoxycaproic acid, as described in the US patent. No. 4,634,551. Another category of bleaching agents that can be used encompasses halogen bleaching agents. Examples of hypohalogenide bleaching agents, for example, include trichloroisocyanuric acid and the sodium and potassium dichloroisocyanurates and N-chloro and N-bromoalkanesulfonamides. Such materials are usually added to 0.5-10% by weight of the finished product, preferably 1-5% by weight. Acylated citrate esters such as those described in co-pending European patent application No. 91870207.7 are also suitable activators. Useful bleach activators, including peroxyacids and bleach systems comprising bleach activators and peroxygen bleach compounds for use in the compositions of the present invention, are described in co-pending applications USSN 08 / 136,626, PCT / US 95/07823, WO 95 / 27772, WO 95/27773, WO 95/27774 and WO 95/27775. Hydrogen peroxide may also be present by adding an enzymatic system (i.e., an enzyme and a substrate therefor), which is capable of generating hydrogen peroxide at the beginning or during the washing and / or rinsing operations. Such enzyme systems are described in the patent application EP 91202655.6, filed on October 9, 1991.

Improved detergency system The compositions according to the present invention will furthermore preferably comprise a detergency builder system, preferably selected from zeolite and / or sodium tri-poly phosphate. It has surprisingly been found that the laundry detergent and / or fabric care compositions of the present invention additionally comprising a builder provide improved, improved fabric care and care, including fabric appearance, anti-aging properties. wear and / or antistatic properties. Any conventional improved detergency system is suitable for use herein, including aluminosilicate materials, silicates, polycarboxylates, alkyl- or alkenylsuccinic acid and fatty acids, materials such as ethylenediaminetetraacetate, diethylenetriaminepentamethylenenacetate, metal ion sequestrants such as aminopolyphosphonates, particularly acid. ethylenediaminetetramethylenephosphonic acid and diethylenetriaminepentamethylenephosphonic acid. Phosphate builders can also be used in the present invention.

Suitable builders can be an inorganic ion exchange material, usually an inorganic aluminosilicate hydrated material, most particularly a hydrated synthetic zeolite such as zeolite A, X, B, HS or hydrated MAP. Another suitable inorganic builder material is layered silicate, for example, SKS-6 (Hoechst). SKS-6 is a crystalline layered silicate consisting of sodium silicate (Na 2 Si 2 g). Suitable polycarboxylates containing a carboxy group include lactic acid, glycolic acid and ether derivatives thereof, as described in Belgian Patents Nos. 831, 368, 821, 369 and 821, 370. Polycarboxylates containing two groups ca. boxi include the water-soluble salts of succinic acid, mationic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, and also the ether carboxylates described in the German Offenlegenschrift 2,446,686 and 2,446,687, and the US Patent No. 3,935,257, and the sulfinylcarboxylates described in Belgian Patent No. 840,623. Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates, as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No. 1, 379,241, lactooxysuccinates described in the application from the Netherlands 7205873, and oxypolycarboxylate materials such as 2-oxa-1,1,3-propane tricarboxylates described in British Patent No. 1, 387,447. Polycarboxylates containing four carboxy groups include the oxydisuccinates described in British Patent No. 1, 261, 829; 1, 1, 2,2-ethane tetracarboxylates, 1, 1, 3,3-propanotetracarboxylates and 1,1, 2,3-propanotetracarboxylates. Polycarboxylates containing sulfo substituents include the sulfosuccinate derivatives described in British Patents Nos. 1, 398, 441 and 1, 398, 422, and in the US patent. No. 3,936,448, and the pyrolyzed sulphonated citrates described in British Patent No. 1, 082,179, while British Patent No. 1, 439,000 discloses polycarboxylates containing phosphorus substituents. The alicyclic and heterocyclic polycarboxylates include cyclopentane-cis-cis-tetracarboxylates, cyclopentadiene-pentacarboxylates, 2,3,4,5-tetrahydrofuran-cis-cis-cis-tetracarboxylates, 2,5-tetrahydrofuran-cis-dicarboxylates, 2,2, 5,5-tetrahydrofuran-tetracarboxylates, 1, 2,3,4,5,6-hexane-hexacarboxylates and carboxymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol. Aromatic polycarboxyiates include the derivatives of mellitic acid, pyromellitic acid and phthalic acid described in British Patent No. 1, 425,343. Of the above, preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, most particularly citrates. Preferred builder systems for use in the present compositions include a mixture of a water-insoluble aluminosilicate improver such as zeolite A or a layered silicate (SKS-6), and a water-soluble carboxylate chelating agent, such as citric acid. Preferred improvers are zeolite A and sodium tripolyphosphate. Preferred builder systems include a mixture of a water insoluble aluminosilicate builder such as zeolite A, and a water soluble carboxylate chelating agent such as citric acid. Preferred builder systems for use in the liquid detergent compositions of the present invention are soaps and polycarboxylates. Other suitable builder materials which can be part of the builder system for use in granular compositions, include inorganic materials such as carbonates, bicarbonates and alkali metal silicates, and organic materials such as organic phosphonates, aminopoly-alkylene phosphonates and aminopolycarboxylates. Other suitable water-soluble organic salts are homo- or copolymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of this type are described in GB-A-1, 596,756. Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, such copolymers having a molecular weight of 20,000 to 70,000, especially about 40,000. Builder salts are usually included in amounts of 5% to 80% by weight of the composition, preferably 10% to 70%, and more usually 30% to 60% by weight.

Chelating Agents Laundry detergent and / or fabric care compositions herein may also optionally contain one or more iron and / or manganese chelating agents. Such chelating agents can be selected from the group consisting of aminocarboxylates, aminophosphates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, all as defined below. Without intending to be limited by theory, it is believed that the benefit of these materials is due in part to their exceptional ability to remove iron and manganese ions from the washing solutions by forming soluble chelates. Aminocarboxylates useful as optional chelating agents include ethylenediaminetetracetates, N-hydroxyethylenediaminetriacetates, nitrilotriacetates, ethylenediaminetetrapropionates, triethylenetetra-aminohexaacetates, diethylenetriaminepentaacetates and etapoldiglicines, alkali metal, ammonium and substituted ammonium salts thereof, and mixtures thereof. The aminophosphates are also suitable for use as chelating agents in the compositions of the invention, when at least low levels of total phosphorus are allowed in the detergent compositions, and include ethylene diamine tetrakis (methylene phosphonates) as DEQUEST. Preferably, these aminophosphonates do not contain alkyl or alkenyl groups with more than about 6 carbon atoms. Polyfunctionally substituted aromatic chelating agents are also useful in the compositions herein. See the patent of E.U.A. No. 3,812,044 issued May 21, 1974 to Connor et al. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy-3,5-disulfobenzene. A biodegradable chelator that is preferred to be used herein is ethylene diamine disuccinate ("EDDS"), especially the [S, S] isomer as described in the U.S.A. No. 4,704,233, November 3, 1987 by Hartman and Perkins. The compositions herein may also contain water-soluble salts of methylglycine diacetic acid (MGDA) (or the acid form) as an associated chelator or builder, useful for example with nonsoluble builders such as zeolites, layered silicates and the like. . If used in the compositions of the present invention, these chelating agents should generally comprise from about 0.1% to about 15%, preferably, from about 0.1% to about 3.0% by weight of the compositions.

Foam suppressor Another optional ingredient is a foam suppressor, exemplified by silicones and silica-silicone blends. Silicones can generally be represented by alkylated polysiloxane materials, while silica is normally used in finely divided forms exemplified by silica aerogels and xerogels and hydrophobic silicas of various types. These materials can be incorporated as particles in which the suds suppressor is conveniently incorporated in a releasable manner in a waterproof or water dispersible detergent substantially non-surfactant vehicle. Alternatively, the foam suppressant can be dissolved or dispersed in a liquid vehicle and applied by spraying it on one or more of the other components. A preferred silicone foam controller agent is described by Bartollota et al. In the U.S. patent. No. 3,933,672. Other particularly useful foam suppressors are the self-emulsifying silicone foam suppressors which are described in the German patent application DTOS 2 646 126, published on April 28, 1977. An example of these compounds is DC- 544, commercially available from Dow Corning, which is a siloxane-glycol copolymer. An especially preferred foam controlling agent is the foam suppressor system comprising a mixture of silicone oils and 2-alkylalkanols. A suitable 2-alkylalcanol is 2-butyloctanol, commercially available under the brand name Isofol 12R. Such a foam suppressor system is described in co-pending European patent application N 92870174.7, filed on November 10, 1992. Especially preferred silicone foam controlling agents are described in co-pending European patent application No. 92201649.8. Said compositions may comprise a silicone / silica mixture, in combination with fumed non-porous silica such as Aerosil.RTM. The foam suppressors described above are usually employed at levels of 0.001% to 2%, preferably from 0.01% to 1% by weight of the compositions herein.

Dispersants Laundry detergent and / or fabric care compositions of the present invention may also contain dispersants: Suitable organic water-soluble salts which are homo- or copolymeric acids or their salts, in which the polycarboxylic acid comprises at least minus two carboxylic radicals separated from one another by no more than two carbon atoms. Polymers of this type are described in GB-A-1, 596,756. Examples of such salts are the polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, said copolymers have a molecular weight of 1,000 to 100,000. Especially, the acrylate-methacrylate copolymer such as 480N, which has a molecular weight of 4000, at a level of 0.5-20% by weight in the composition, can be added to laundry detergent and / or laundry care compositions. fabric of the present invention. The compositions of the invention may contain a lime soap peptizer compound, which preferably has a lime soap dispersion power (LSDP), as defined below, of not more than 8, preferably not more than 7, very preferably not more than 6. The lime soap peptizer compound is preferably present at a level of 0% to 20% by weight. A numerical measurement of the effectiveness of a lime soap peptizer is given by the lime soap dispersion power (LSDP), which is determined using the lime soap dispersant test as described in an H.C. Borghetty and C.A. Bergman, J. Am. Oil. Chem. Soc, volume 27, p. 88-90, (1950). This lime soap dispersion test method is widely used by practitioners of this technique referred to, for example, in the following articles: W.N. Linfield, "Surfactant Science Series", Volume 7, p. 3, W.N. Linfield, "Tenside surf. Det.", Volume 27, pgs. 159-163, (1990); and M.K. Nagarajan, W.F. Masler, "Cosmetics and Toiletries", volume 104, pgs. 71-73, (1989). The LSDP is the ratio of the percentage by weight of dispersing agent to sodium oleate required to disperse the lime soap deposits formed by 0.025 g of sodium oleate in 30 ml of water with an equivalent hardness of 333 ppm of CaCO3 (Ca: Mg = 3.2). Surfactants having an adequate lime soap peptising capacity will include certain amine oxides, betaines, sulfobetaines, alkyl ethoxy sulfates and ethoxylated alcohols. Exemplary surfactants having an LSDP of not more than 8 to be used in accordance with the present invention include dimethylamine oxide of C- | g- C- | 3. C12-C18 alkyl ethoxylates with an average degree of ethoxylation of 1-5, particularly in C-12-15 alkylcytoisulfate surfactant with an ethoxylation degree of approximately 3 (LSDP = 4) and ethoxylated C14-C-15 alcohols with an average degree of ethoxylation of 12 (LSDP = 6) or 30, sold under the trade names Lutensol A012 and Lutensol A030, respectively, by BASF GmbH.

Polymeric lime soap peptizers suitable for use herein are described in the article by M.K. Nagarajan, W.F. Masler, which is in "Cosmetics and Toiletries", volume 104, pgs. 71-73, (1989). Lime soap peptizers such as 4- [N-octanoyl-6-aminohexanoyl] benzenesulfonate, 4- [N-nonanoyl-6-aminohexanoyl] benzene sulfonate, 4- [N-decanoyl-] can also be used as lime soap peptizer compounds. 6-aminohexanoyl] benzenesulfonate and mixtures thereof; and nonanoyloxybenzenesulfonate together with hydrophilic / hydrophobic bleach formulations.

Inhibition of dye transfer The detergent laundry and / or care compositions of the fabric of the present invention will furthermore preferably comprise compounds for inhibiting dye transfer from one fabric to another, of the solubilized and suspended dyes found therein. during the washing operations of colored fabrics. It has surprisingly been found that the laundry detergent and / or fabric care composition of the present invention further comprising a dye transfer inhibiting agent will provide superior, improved fabric care, including appearance of color and / or properties. against the wear of the fabric.

Polymeric Dye Transfer Inhibitory Agents Laundry detergent and / or fabric care compositions in accordance with the present invention will also preferably comprise from 0.001% to 10%, preferably from 0.01% to 2%, most preferably 0.05. % to 1% by weight of polymeric dye transfer inhibiting agents. Said polymeric dye transfer inhibiting agents are normally incorporated in the cleaning compositions to inhibit the transfer of dyes from the colored fabrics onto other fabrics washed therewith. These polymers have the ability to form complexes with, or adsorb to, the fugitive dyes that come out of the colored fabrics, before the colorants have the opportunity to become attached to other articles in the wash. Polymeric dye transfer inhibiting agents which are especially suitable are polymers of polyamine N-oxide, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polymers of polyvinylpyrrolidone, polyvinyl-oxazolidones and polyvinylimidazoles or mixtures thereof. The addition of said polymers also improves the performance of the enzymes according to the invention. (a) Polyamine N-oxide polymers Polyamine N-oxide polymers suitable for use in the compositions herein, contain units having the following structural formula: P I Or A? R wherein P is a polymerizable unit, to which the group R-N-O may be attached, or wherein the group R-N-O forms part of the polymerizable unit, or a combination of both.

O O O II II II A is NC, CO, C, -O-, -S-, -N-; x is 0 or 1; R are aliphatic, aliphatic, ethoxylated, aromatic, heterocyclic or alicyclic groups, or any combination thereof, to which the nitrogen of the N-O group may be attached, or wherein the nitrogen of the N-O group is part of these groups. The N-O group can be represented by the following general structures: O (R1)? - N I- (R2) y = ° N- (R1) X (R3) z wherein R1, R2 and R3 are aliphatic, aromatic, heterocyclic or alicyclic groups or combinations thereof, "x" and / or "y" and / or "z" is 0 or 1, and wherein nitrogen may be attached of the NO group, or where the nitrogen of the NO group forms part of these groups. The N-O group can be part of the polymerizable unit (P) or it can be attached to the polymeric backbone, or a combination of both. Suitable polyamine N-oxides, wherein the N-O group forms part of the polymerizable unit, comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups. One class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the NO group is part of the R group. The preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyridine , pyrrole, imidazole, pyrrolidine, piperazine, quinoline, acridine and derivatives thereof. Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the NO group is attached to the group R. Other suitable N-oxides of polyamine are the polyamine oxides to which the group is attached NO a. The polymerizable unit. A preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic group wherein the nitrogen of the functional group is NOT part of said group R Examples of these classes are the polyamine oxides wherein R is a heterocyclic compound such as pyridine, pyrrole, midazole and derivatives thereof. Another preferred class of polyamine N-oxides are the polyamine oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic group wherein the nitrogen of the functional group is NOT attached to said R groups. these classes are polyamine oxides wherein the R groups can be aromatic such as phenyl. Any polymer skeleton can be used, provided that the amine oxide polymer formed is soluble in water and has dye transfer inhibiting properties. Examples of suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamides, polyimides, polyacrylates and mixtures thereof. The amine N-oxide polymers of the present invention typically have a ratio of amine to amine N-oxide from 10: 1 to 1: 1000000. However, the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or by an appropriate degree of N-oxidation. Preferably, the ratio of amine to amine N-oxide is from 2: 3 to 1: 1000000. Most preferably from 1: 4 to 1: 000000, most preferably still from 1: 7 to 1: 1000000. The polymers of the present invention actually encompass random or block copolymers wherein one type of monomer is an amine N-oxide and the other type of monomer is either an amine N-oxide or not. The amine oxide unit of the polyamine N-oxides have a pKa <; 10, preferably pKa < 7, most preferably pKa < 6. Polyamine oxides can be obtained in almost any degree of polymerization. The degree of polymerization is not critical, as long as the material has the desired water solubility and the desired dye suspension power. Typically, the average molecular weight is within the range of 500 to 1,000,000; preferably from 1,000 to 50,000, most preferably from 2,000 to 30,000, most preferably even from 3,000 to 20,000. (b) Copolymers of N-vinylpyrrolidone and N-vinylimidazole The polymers of N-vinylimidazole and N-vinylpyrrolidone used in the present invention have an average molecular weight scale of 5,000 to 1,000,000, preferably 20,000 to 200,000. Highly preferred polymers for use in detergent compositions in accordance with. present invention, comprise a polymer selected from copolymers of N-vinylimidazc! and N-vinylpyrrolidone, wherein said polymer has an average molecular weight scale of from 5,000 to 50,000, most preferably from 8,000 to 30,000, most preferably even from 10,000 to 20,000. The average molecular weight scale was determined by light scattering, as described by Barth H. G. and Mays J. W., Chemical Analysis Vol 113, "Modern Methods of Polymer Characterization" - Modern methods of polymer characterization. The highly preferred N-vinylimidazole and N-vinylpyrrolidone copolymers have an average molecular weight scale of from 5,000 to 50,000, preferably from 8,000 to 30,000, most preferably from 10,000 to 20,000. The copolymers of N-vinylimidazole and N-vinylpyrrolidone characterized to have said scale of average molecular weight, provide excellent dye transfer inhibiting properties, while not adversely affecting the cleaning action of the detergent compositions formulated therewith. The N-vinylimidazole-N-vinylpyrrolidone copolymer of the present invention has a molar ratio of N-vinylimidazole to N-vinylpyrrolidone from 1 to 0.2, most preferably from 0.8 to 0.3, most preferably from 0.6 to 0.4. (c) Polyvinylpyrrolidone Laundry detergent and / or fabric care compositions of the present invention can also use polyvinylpyrrolidone ("PVP"), which has an average molecular weight of from about 2,500 to about 400,000, preferably from about 5,000 to about 200,000, preferably from about 5,000 to about 50,000, and most preferably from about 5,000 to about 15,000. Suitable polyvinyl pyrrolidones are commercially available from ISP Corporation, New York, NY and Montreal, Canada under the trademarks PVP K-15 (molecular weight of 10,000 with viscosity), PVP K-30 (average molecular weight of 40,000), PVP K-60 (average molecular weight of 160,000), and PVP K-90 (average molecular weight of 360,000). Other suitable polyvinyl pyrrolidones which are commercially available from BASF Corporation, include Sokalan HP 165 and Sokalan HP 12; the polyvinyl pyrrolidones are known to those skilled in the detergent field (see, for example, EP-A-262,897 and EP-A-256,696). (d) Polyvinyloxazolidone Laundry detergent and / or fabric care compositions of the present invention can also use polyvinyloxazolidone as a polymeric dye transfer inhibiting agent. Said polyvinyloxazolidones have an average molecular weight of from about 2,500 to about 400,000, preferably from about 5,000 to about 200,000, preferably from about 5,000 to about 50,000, and most preferably from about 5,000 to about 15,000. (e) Polyvinylimidazole The detergent compositions of the present invention can also use polyvinylimidazole as a polymeric dye transfer inhibiting agent. Said polyvinylimidazoles have an average molecular weight of from about 2,500 to about 400,000, preferably from about 5,000 to about 200,000, preferably from about 5,000 to about 50,000, and from about 5,000 to about 15,000 is most preferred. (f) Interlaced polymers Laundry detergent and / or fabric care compositions of the present invention can use interlaced polymers. The interlaced polymers are polymers whose skeleton is interconnected to some degree; these links can be of a chemical or physical nature, possibly with active groups in the skeleton or on the ramifications; Interlaced polymers have been described in The Journal of Polymer Science, volume 22, pages 1035-1039. In one embodiment, the entangled polymers are made in such a way that they form a rigid three-dimensional structure that can trap dyes in the pores formed by the three-dimensional structure. In another embodiment, the entangled polymers trap the dyes by swelling. Said entangled polymers are described in co-pending patent application 94870213.9.

Others Other components such as soil suspending agents, soil removal agents, optical brighteners, abrasives, bactericides, tarnish inhibitors and / or coloring agents may be employed. Suitable antiredeposition and soil suspending agents herein include cellulose derivatives such as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose, and homo- or copolymeric acids or their salts. Polymers of this type include the polyacrylates and copolymers of maleic anhydride-acrylic acid previously mentioned as builders, as well as copolymers of maleic anhydride with ethylene, methylvinyl ether or methacrylic acid, constituting maleic anhydride at least 20 moles per one hundred percent of the copolymer. These materials are normally used at levels of 0.5% to 10%, preferably 0.75% to 8%, preferably 1% to 6% by weight of the composition. Other useful polymeric materials are polyethylene glycols, particularly those of molecular weight 1000-10000, more particularly 2000 to 8000, and most preferably about 4000. These are used at levels of 0.20% to 5%, preferably from 0.25% to 2.5% in weigh. These polymers, and the aforementioned homo- or copolymer polycarboxylate salts, are valuable for improving the maintenance of whiteness, the deposition of ash from the fabric, and the cleaning action on mud, proteinaceous and oxidizable soils in the presence of metal impurities. of Transition. It is well known in the art that free chlorine in tap water rapidly deactivates enzymes comprised in detergent compositions. Therefore, the use in the formulas of a chlorine scavenger such as perborate, ammonium sulfate, sodium sulfite or polyethyleneimine, at a level above 0.1% by weight of the total composition, will provide improved stability of the detergent enzymes during washing. In the European patent application 92870018.6, filed on January 31, 1992, compositions comprising a chlorine scavenger are described. Alkoxylated polycarboxylates such as polyacrylate preparations are useful herein to provide greater fat-removing action. Such materials are described in WO 91/08281 and PCT 90/01815 on page 4 and following, incorporated herein by reference. Chemically, these materials comprise polyacrylates having an ethoxy side chain for every 7-8 acrylate units. The side chains are of the formula - (CH2CH2O) m (CH2) nCH3, where m is 2-3 and n is 6-12. The side chains are ester bonded to the polyacrylate backbone to provide a "comb" type polymer structure. The molecular weight may vary, but typically ranges from about 2000 to about 50,000. Said alkoxylated polycarboxylates may comprise from about 0.05% to about 10% by weight of the compositions herein.

Washing Method The compositions of the invention can be used essentially in any method of washing, cleaning and / or care of the fabric, including soaking methods, pretreatment methods, methods with rinsing steps to which an auxiliary composition can be added of separate rinsing, and post-treatment methods. The process described herein comprises contacting the fabrics with a wash solution in the usual manner and exemplified below. A conventional laundry method comprises treating the soiled fabric with an aqueous liquid having dissolved or dispersed an effective amount of the laundry detergent and / or fabric care detergent composition. Such methods are preferably carried out at 5 ° C to 95 ° C, especially between 10 ° C and 60 ° C. The pH of the treatment solution is preferably from 7 to 12. The following examples are designed to exemplify the compositions of the present invention, but are not necessarily designed to limit or otherwise define the scope of the invention. In detergent compositions, the enzyme levels are expressed by pure enzyme by weight of the total composition, and unless otherwise indicated, the detergent ingredients are expressed by weight of the total compositions. The identifications of the abbreviated components have the following meanings: LAS: Sodium alkylbenzenesulfonate lineel of C-j 1_13 TAS: Sodium tallow alkyl sulfate CxyAS: Sodium alkylsulphate of C < | x-C- | and CxySAS: Sodium Alkylsulfate of C? x-C- | and secondary (2,3) CxyEz: Primary alcohol of C- | x-C- | and predominantly linear condensed with an average of z moles of ethylene oxide CxyEzS: Sodium alkyl sulfate of C- | x-C < | and condensed with an average z mole of ethylene oxide QAS: R2.N + (CH3) 2 (C2H4OH) with R2 = C12-C < | 4 QAS 1: R2.N + (CH3) 2 (C2H OH) with R2 = Cß-Ci 1 APA: C3-C- Amidopropyl dimethylamine or Soap: Linear sodium alkylcarboxylate derived from an 80/20 mixture of tallow fatty acids and coconut STS: Sodium toluenesulfonate CFAA: Alkyl-N-methylglucamide of C-? 2-C-? TFAA: Alkyl-N-methylglucamide of C? -Ci8 TPKFA: C12-C14 whole cut fatty acids DEQA: Di (tallowoxyethyl) dimethylammonium chloride DEQA (2): Di (tallowyloxyethyl-bidentate) hydroxyethyl-methylammonium metho sulphate DTDMAMS: Disodbodimethylammonium methysulfate SDASA : Stearylmethoxylamine: triple pressed stearic acid, 1: 2 ratio Silicate: Amorphous sodium silicate (Si? 2: Na2? = 1.6-3.2 ratio) Zeolite A: Hydrated sodium aluminosilicate of formula Na-? 2 (AIO2SiO2 2.27H2O having a primary particle size on the scale of 0.1 to 10 microns (weight expressed on an anhydrous basis). Na-SKS-6: Crystalline layered silicate of the formula d-Na2Si2? 5 Citrate: Trisodium citrate dihydrate with an activity of 86.4% and with a particle size distribution of between 425 and 850 microns Citrus: Anhydrous citric acid Borate : Sodium Borate Carbonate: Anhydrous sodium carbonate with a particle size between 200 and 900 microns Bicarbonate: Carbonate anhydrous sodium acid with a particle size distribution between 400 and 1200 microns Sulphate: Anhydrous sodium sulfate Mg Sulfate: Sulphate of anhydrous magnesium STPP: Sodium tripolyphosphate TSPP Tetrasodium pyrophosphate MA / AA: Acrylate / maleate 4: 1 copolymer, average molecular weight of approximately 70,000-80,000 MA / AA 1: Acrylate / maleate random copolymer 6: 4, average molecular weight of about 10,000 AA: Sodium polyacrylate polymer with an average molecular weight of 4,500 PB1: Anhydrous sodium perborate of nominal formula NaB 2-H2 2 PB 4: Perborate sodium tetrahydrate of nominal formula NaB? 2.3H2O.H2? 2 Percarbonate: Anhydrous sodium percarbonate of nominal formula 2Na2CO3.3H2? 2 TAED: Tetraacetylethylenediamine NOBS: Nonanoyloxybenzenesulfonate in the form of the sodium salt NACA-OBS: (6-nonamidocaproyl) oxybenzenesulfonate CBD-NACA-OBS: Reaction product of the cellulose cellulose binding sold under the trademark Carezyme by Novo Nordisk A / S, with polytyrosine linker, and (6-nonamidocaproyl) oxybenzenesulfonate (DTPA) molecules: diethylenetriaminepentaacetic acid HEDP: 1, 1-hydroxyethanediphosphonic acid DETPMP: Diethylenetriaminpenta (methylenephosphonate), marketed by Monsanto under the brand Dequest 2060. EDDS: Ethylenediamine-NN-disuccinic acid, isomer [S, S] in the form of its sodium salt. Photoactivated bleach: Sulfonated zinc phthalocyanine encapsulated in soluble dextrin polymer Photoactivated bleach 1: Sulfonated aluminum phthalocyanine encapsulated in soluble dextrin polymer Protease: Proteolytic enzyme sold under the trademark Savinase, Alcalase, by Novo Nordisk A / S, the variant of " D "protease with the N76D / S103A / V104I substitution, and the protease described in PCT applications Nos. PCT / US 98/22588, PCT / US 98/22482 and PCT / US 98/22486, with amino acid substitution 101 G / 103A / 1041 / 159D / 232V / 236H / 245R / 248D / 252K Amylase: Amylolytic enzyme sold under the brand names Termamyl® and Duramyl®, available from Novo Nordisk A / S and variants that have improved thermal stability with deletions of amino acids R181 * + G182 * or T183 * + G184 *, as described in WO 95/35382.

Lipase: Lipolytic enzyme sold under the brand name Lipolase, Lipolase Ultra by Novo Nordisk A / S and Lipomax by Gist-Brocades.

Cellulase: Cellulite enzyme sold under the brand name Carezyme, Celluzyme and / or Endolase by Novo Nordisk A / S CMC: Carboxymethylcellulose sodium PVP: Polyvinyl polymer, with an average molecular weight of 60,000 PVNO: N-oxide of polyvinylpyridine, with a weight average molecular weight of 50,000 PVPVI: Copolymer of vinylimidazole and vinylpyrrolidone, with an average molecular weight of 20,000 1: 4,4'-bis (2-sulphotryl) biphenyl disodium brightener Polimer 2: 4,4'-bs (4 disodium -anthi-6-morpholino-1, 3,5-triazin-2-yl) stilbene-2,2'-disulfonate Silicone antifoam: Polydimethylsiloxane foam controller with siloxane-oxyalkylene copolymer as agent of dispersion with a ratio of said controller to said dispersing agent from 10: 1 to 100: 1 Foam suppressor: 12% silicone / silica, 18% stearyl alcohol, 70% starch in granular form Opacador: Mix of water-based monostyrene latex, sold by BASF Aktiengesellschaft under the brand Lytron 621 SRP 1: Anionically blocked poly esters at the ends SRP 2: Poly (1, 2-propylene terephthalate) diettoxylated short block polymer QEA: bis ((C2H5?) (C2H4? N) (CH3) -N + -C6H12-N + - ( CH3) bis ((C2H5?) - (C2H4? N), where n = from 20 to 30 PEI: Polyethyleneimine with an average molecular weight of 1800 and an average degree of ethoxylation of 7 ethyleneoxy residues per nitrogen SCS: Cumene sulphonate of sodium HMWPEO: High molecular weight polyethylene oxide PEGx: Polyethylene glycol with a molecular weight of x PEO: Polyethylene oxide with an average molecular weight of 5,000 TEPAE: Ethoxylated tetraethylene pentaamine CBD-Rotundial: CBD reaction product of cellulase E3 from Thermomonospora fusca with Rotundial CBD-Damascona molecules: Cellulozome CBD reaction product from Clostridium cellulovorans, sold under the Cellulose Binding Domain brand from Sigma, with a-Damascona molecules CBD-PRP-1: Cellulose CBD reaction product from Clostridium cellulovorans, sold under the Cellulose Binding Domain brand from Sigma, with polylysine linker, and 2,4-dimethyl-3-cyclohexane-1-carboxaldehyde EXAMPLE 1 In accordance with the present invention, this example illustrates the coupling of a citral perfume, a glutaraldehyde hygiene agent or citronellal insect control agent, to the selected CBD: Cellulozome CBD from Clostridium cellulovorans. The reaction in equal moles takes place under mild conditions (pH 6 to 9.5 from 1 to 48 hours, see for example Wirth P. et al., 1991, Biorg. Chem., 19, 133, 1991, and Chamow SM et al. Bioconjugate Chem., 4, 133, 1994). Chemical components such as perfume (citral or 2,4-dimethyl-3-cyclohexane-1-carboxaldehyde), insect control agent (citronellal) and hygienic agent (glutaraldehyde) are linked to the NH2 groups of the CBD and / or linker region selected, by means of a Schiff base reaction. The reaction could also be completed in anhydrous ethanol containing a drying agent such as sodium sulfate. Since the selected CBD has 10 mills and / or if there is a polyreactive linker region comprising more than one lysine, the reaction is identical with the appropriate number of chemical agents per reactant group. For example, 10 equivalents of aldehyde per mole 'of the selected CBD containing 10 pots will be added. The selected CBD is not volatile and does not change the character of the aldehyde.

+ H2O Improved release is obtained on the dry fabrics by the slow hydrolysis of the selected CBD / perfume bond.

I Citral Cloth EXAMPLE 2 The following high density laundry detergent compositions were prepared according to the present invention: II lll IV V VI LAS 8.0 8.0 8.0 2.0 6.0 6.0 TAS 0.5 - 0.5 1.0 0.1 C46 (S) AS 2.0 2.5 - - - - C25AS - - 7.0 4.5 5.5 C68AS 2.0 5.0 7.0 - - - C25E5 - 3.4 10.0 4.6 4.6 C25E7 3.4 3.4 1.0 - _ _ C25E3S 2.0 5.0 4.5 QAS 0.8 QAS1 - - - 0.8 0.5 1.0 Zeolite A 18.1 18.0 14.1 18.1 20.0 18.1 Cítrico - - - 2.5 - 2.5 Carbonate 13.0 13.0 27.0 10.0 10.0 13.0 Na-SKS-6 - - - 10.0 - 10.0 Silicate 1.4 1.4 3.0 0.3 0.5 0.3 Citrate - 1.0 - 3.0 - - Sulfate 26.1 26.1 26.1 6.0 - - Mg Sulfate 0.3 - - 0.2 - 0.2 MA / AA 0.3 0.3 0.3 4.0 1.0 1.0 CMC 0.2 0.2 0.2 0.2 0.4 0.4 PB4 9.0 9.0 5.0 _ _ _ I II III IV V VI Percarbonate - - - - 18.0 18.0 TAED 1.5 0.4 1.5 - 3.9 4.2 NACA-OBS - 2.0 1.0 - - - DETPMP 0.25 0.25 0.25 0.25 - - SRP1 - - - 0.2 - 0.2 EDDS - 0.25 0.4 - 0.5 0.5 CFAA - 1.0 - 2.0 - - HEDP 0.3 0.3 0.3 0.3 0.4 0.4 QEA - - - 0.2 - 0.5 Protease 0.009 0.009 0.01 0.04 0.05 0.03 Amylase 0.002 0.002 0.002 0.006 0.008 0.008 Cellulase 0.0007 0.0006 0.0007 0.0008 0.0007 0.001 Lipasa 0.006 - - 0.01 0.01 0.01 Photoactivated bleach (ppm) 15 15 15 - 20 20 PVNO / PVPVI - - - 0.1 - - Polisher 1 0.09 0.09 0.09 - 0.09 0.09 Perfume 0.3 0.3 0.3 0.4 0.4 0.4 Silicone antifoam 0.5 0.5 0.5 - 0.3 0.3 CBD-Damascona 1.0 2.0 0.5 1.0 5.0 0.1 Density in g / l 850 850 850 850 850 850 850 Various and secondary up to 100% EXAMPLE 3 The following granular detergent compositions of particular utility were prepared under the European washing conditions in machine, in accordance with the present invention.

I II III LAS 5.5 7.5 7.0 TAS 1.25 1.9 0.3 C24AS / C25AS - 2.2 2.2 C25E3S - 0.8 1.0 C45E7 3.25 - 3.0 TFAA - - - C25E5 - 5.5 - QAS 0.8 - - QAS1 - 0.7 0.7 STPP 19.7 - - Zeolite A - 19.5 17.0 NaSKS-6 / citric acid (79:21) - 10.6 - Na-SKS-6 - - 10.0 Carbonate 6.1 21.4 18.0 Bicarbonate - 2.0 2.0 Silicate 6.8 - - Citrate - - - Sulfate 39.8 - 12.0 Mg Sulphate - - - I II lll MA / AA 0.5 1.6 1.0 CMC 0.2 0.4 0.4 PB4 5.0 12.7 - Percarbonate - - 15.0 TAED 0.5 3.1 - CBD-NACA-OBS 0.8 0.5 2.0 DETPMP 0.25 0.2 0.2 HEDP - 0.3 0.3 QEA - - - Protease 0.009 0.03 0.02 Lipasa 0.003 0.003 0.004 Cellulase 0.0006 0.0006 0.0007 Amylase 0.002 0.002 0.003 PVNO / PVPVI - - - PVP 0.9 1.3 0.9 SRP1 - - - Photoactivated bleach (ppm) 15 27 20 Photoactivated bleach 1 (ppm) 15 - - Rinse aid 1 0.08 0.2 0.15 Rinse aid 2 - 0.04 - Perfume 0.3 0.5 0.3 Silicone antifoam 0.5 2.4 2.0 Density in g / l 750 750 750 Various and secondary up to 100% EXAMPLE 4 The following detergent formulations of particular utility were prepared under European conditions of machine washing, according to the present invention: I! L lll Blown powder LAS 6.0 5.0 11.0 TAS 2.0 - - Zeolite A 24.0 - - STPP - 27.0 24.0 Sulphate 4.0 6.0 13.0 MA / AA 1.0 4.0 6.0 Silicate 1.0 7.0 3.0 CMC 1.0 1.0 0.5 Brightener 1 0.2 0.2 0.2 Silicone antifoam 1.0 1.0 1.0 DETPMP 0.4 0.4 0.2 Spray Rinse aid 0.02 - - C45E7 - - - C45E2 2.5 2.5 2.0 C45E3 2.6 2.5 2.0 Perfume 0.5 0.3 0.5 Silicone antifoam 0.3 0.3 0.3 lll Dry additives QEA - - - EDDS 0.3 - - Sulfate 2.0 3.0 5.0 Carbonate 6.0 13.0 15.0 Citrus 2.5 - - QAS1 0.5 - - Na-SKS-6 10.0 - - Percarbonate 18.5 - - PB4 - 18.0 10.0 TAED 0.5 2.0 - CBD-NACA-OBS 2.0 1.0 3.0 CBD-PRP1 2.0 1.0 1.5 Cellulase 0.0004 0.0006 0.0006 Protease 0.03 0.03 0.03 Lipase 0.008 0.008 0.008 Amylase 0.003 0.003 0.003 Brightener 1 0.05 - - Various and secondary up to 100% EXAMPLE 5 The following detergent formulations were prepared granules according to the present invention: III IV V VI Blown powder LAS 23.0 8.0 7.0 9.0 7.0 7.0 TAS - - - - 1.0 - C45AS 6.0 6.0 5.0 8.0 - - C45AES - 1.0 1.0 1.0 - - C45E35 - - - - 2.0 4.0 Zeolite A 10.0 18.0 14.0 12.0 10.0 10.0 MA / AA - 0.5 - - - 2.0 MA / AA1 7.0 - - - - - AA - 3.0 3.0 2.0 3.0 3.0 Sulfate 5.0 6.3 14.3 11.0 15.0 19.3 Silicato 10.0 1.0 1.0 1 0 1.0 1.0 Carbonate 15.0 20.0 10.0 20.7 8.0 6.0 PEG4000 0.4 1.5 1.5 1.0 1.0 1.0 DTPA - 0.9 0.5 - - 0.5 Rinse aid 2 0.3 0.2 0.3 - 0.1 0.3 Spray C45E7 - 2.0 - - 2.0 2.0 C25E9 3.0 - - - - - C23E9 - - 1 1..55 2 2..00 - 2 2..00 Perfume 0.3 0 0..33 0 0..33 2 2..00 0 0..33 0 0..33 Agglomerates C45AS - 5 5..00 5 5..00 2 2..00 -. 5 5.00 LAS - 2 2..00 2 2..00 - - 2 2..00 Zeolite A _ 7 7..55 7 7..55 8 8..00"_ 7 7..55 1 II lll IV V VI Carbonate - 4.0 4.0 5.0 - 4.0 PEG4000 - 0.5 0.5 - - 0.5 Miscellaneous (water, etc.) - 2.0 2.0 2.0 - 2.0 Dry additives QAS - - - - 1.0 - Cítrico - - - - 2.0 - PB4 - - - - 12.0 1.0 PB1 4.0 1.0 3.0 2.0 - - Percarbonate - - - - 2.0 10.0 Carbonate - 5.3 1.8 - 4.0 4.0 NOBS 4.0 - 6.0 - - 0.6 Metuccelulosa 0.2 - - - - Na-SKS-6 8.0 - - - - - STS - - 2.0 - 1.0 - Cumene sulphonic acid - 1.0 - - - 2.0 Protease 0.02 0.02 0.02 0.01 0.02 0.02 Lipasa 0.004 - 0.004 - 0.004 0.008 Amylase 0.003 - 0.002 - 0.003 - Cellulase 0.0003 0.0005 0.0005 0.0007 0.0005 o.ooa PVPVI - - - - 0.5 0.1 PVP - - - - 0.5 - PVNO - - 0.5 0.3 - - QEA - - - - 1.0 - SRP1 0.2 0.5 0.3 _ 0.2 - IV VI Silicon antifoam 0.2 0.4 0.2 0.4 0.1 Mg sulfate - - 0.2 - 0.2 CBD-Damascona - 2.0 1.0 - - CBD-Rotundial 1.0 0.5 0.1 3.0 2.0 5.0 Various and secondary up to 100% EXAMPLE 6 The following detergent formulations that do not contain bleach, of particular use in washing color laundry, were prepared according to the present invention: I II Blown powder Zeolite A 15.0 15.0 Sulphate - 5.0 LAS 3.0 3.0 DETPMP 0.4 0.5 CMC 0.4 0.4 MA / AA 4.0 4.0 lll Agglomerates C45AS - - 11.0 LAS 6.0 5.0 - TAS 3.0 2.0 - Silicate 4.0 4.0 - Zeolite A 10.0 15.0 13.0 CMC - - 0.5 MA / AA - - 2.0 Carbonate 9.0 7.0 7.0 CBD-Damascona sprinkler 2.0 1.0 3.0 CBD-PRP1 3.0 • - 4.0 Perfume 0.3 0.3 0.5 C45E7 4.0 4.0 4.0 C25E3 2.0 2.0 2.0 Dry additives MA / AA - - 3.0 Na-SKS-6 - - 12.0 Citrate 10.0 - 8.0 Bicarbonate 7.0 3.0 5.0 Carbonate 8.0 5.0 7.0 PVPVI / PVNO 0.5 0.5 0.5 Transferase 0.001 1.0 0.01 Substrate 0.1 - 5.0 Protease 0.03 0.02 0.05 Lipase 0.008 0.008 0.008 1 II lll Amylase 0.01 0.01 0.01 Cellulase 0.0008 0.001 0.001 Silicone antifoam 5.0 5.0 5.0 Sulphate - 9.0 - Density (g / liter) 700 700 700 Various and secondary Up to 100% EXAMPLE 7 The following detergent formulations were prepared according to the present invention: lll IV Granule base Zeolite A 30.0 22.0 24.0 10.0 Sulfate 10.0 5.0 10.0 7.0 MA / AA 3.0 - - - AA - 1.6 2.0 - MA / AA1 - 12.0 - 6.0 LAS 14.0 10.0 9.0 20.0 C45AS 8.0 7.0 9.0 7.0 C45AES - 1.0 1.0 - Silicate - 1.0 0.5 10.O Soap 2.0 _ _ 1 II lll IV Rinse aid 1 0.2 0.2 0.2 0.2 Carbonate 6.0 9.0 10.0 10.0 PEG4000 - 1.0 1.5 - DTPA - 0.4 - - Spray C25E9 - - - 5.0 C45E7 1.0 1.0 - - C23E9 - 1.0 2.5 - Perfume 0.2 0.3 0.3 - CBD-Damascona 1.0 0.5 0.2 1.0 CBD-PRP1 3.0 5.0 1.0 - Dry additives Carbonate 5 0 10.0 18.0 8.0 PVPVI / PVNO 0.5 - 0.3 - Pectinase 0.005 0.01 0.01 0.005 Protease 0.03 0.03 0.03 0.02 Lipasa 0.008 - - 0.008 Amylase 0.002 0.002 Cellulase 0.0002 0.0005 0.0005 0.0002 NOBS - 4.0 - 4.5 PB1 1.0 5.0 1.5 6.0 Sulfate 4.0 5.0 - 5.0 SRP1 - 0.4 - - Foam suppressor - 0.5 0.5 - Various and secondary up to 100% EXAMPLE 8 The following detergent formulations were prepared granules according to the invention: II lll Blown powder Zeolite A 20.0 - 15. STPP - 20.0 - Sodium sulphate - - 5.0 Carbonate - - 5.0 TAS - - 1.0 LAS 6.0 6.0 6.0 C68AS 2.0 2.0 - Silicate 3.0 8.0 - MA / AA 4.0 2.0 2.0 CMC 0.6 0.6 0.2 Polisher 1 0.2 0.2 0.1 DETPMP 0.4 0.4 0.1 STS - - 1.0 Spray C45E7 5.0 5.0 4.0 Silicone antifoam 0.3 0.3 0.1 Perfume 0.2 0.2 0.3 CBD-Rotundial 1.0 3.0 3.0 lll Dry additives QEA - - 1.0 Carbonate 14.0 9.0 10.0 PB1 1.5 2.0 - PB4 18.5 13.0 13.0 TAED 2.0 2.0 2.0 QAS - - 1.0 Photoactivated bleach 15ppm 15ppm 15ppm Na-SKS-6 - - 3.0 Lacasa 0.02 0.06 0.003 Incrementador 1.0 0.8 0.8 Protease 0.03 0.03 0.007 Lipase 0.004 0.004 0.004 0.005 0.006 0.006 0.006 0.003 Cellulase 0.0002 0.0002 0.0005 Sulfate 10.0 20.0 5.0 Density (g / liter) 700 700 700 Miscellaneous and secondary Up to 100% EXAMPLE 9 The following detergent formulations were prepared according to the present invention: Blown powder Zeolite A 15.0 15.0 15.

Sulfate 5.0 - LAS 3.0 3.0 3.0 QAS 1.5 1.5 DETPMP 0.4 0.2 0.4 EDDS 0.4 0.2 CMC 0.4 0.4 0.4 MA / AA 4.0 2.0 2.0 Agglomerate LAS 5.0 5.0 5.0 TAS 2.0 2.0 1.0 Silicate 3.0 3.0 4.0 Zeolite A 8.0 8.0 8.0 Carbonate 8.0 8.0 4.0 CBD-Damascona spray 1.0 0.5 3.0 Perfume 0.3 0.3 _ C45E7 2.0 2.0 2.0 C25E3 2.0 Citrate Dry Additives 5.0 2.0 Bicarbonate - 3.0 - Carbonate 8.0 15.0 10.0 TAED 6.0 2.0 5.0 PB1 14.0 7.0 10.0 1 II lll PEO - - 0.2 Clay bentonite - - 10.0 Mananase 0.005 0.002 0.0008 Protease 0.03 0.03 0.03 Lipase 0.008 0.008 0.008 Cellulase 0.001 0.0007 0.001 Amylase 0.01 0.01 0.01 Silicone antifoam 5.0 5.0 5.0 Sulfate - 3.0 - Density (g / liter) 850 850 850 Miscellaneous and secondary up to 100% EXAMPLE 10 The following detergent formulations were prepared according to the present invention: I II III IV LAS 18.0 14.0 24.0 20.0 QAS 0.7 1.0 - 0.7 TFAA - 1.0 - - C23E56.5 - - 1.0 - C45E7 - 1.0 - - C45E3S 1.0 2.5 1.0 _ I II lll IV STPP 32.0 18.0 30.0 22.0 Silicate 9.0 5.0 9.0 8.0 Carbonate 11.0 7.5 10.0 5.0 Bicarbonate - 7.5 - - PB1 3.0 1.0 - - PB4 - 1.0 - - CBD-NACA-OBS 1.5 0.8 - - DETPMP - 1.0 - - DTPA 0.5 - 0.2 0.3 SRP1 0.3 0.2 - 0.1 MA / AA 1.0 1.5 2.0 0.5 CMC 0.8 0.4 0.4 0.2 PEÍ - - 0.4 - Sulfato 20.0 10.0 20.0 30.0 Mg Sulfate 0.2 - 0.4 0.9 Protease 0.03 0.03 0.02 0.02 Amílasa 0.008 0.007 - 0.004 Lipase 0.004 - 0.002 - Cellulase 0.0003 0.0001 0.0003 0.0001 Photo-activated bleach 30 ppm 20 ppm - 10 ppm Perfume 0.3 0.3 0.1 0.2 CBD-Damascona - 1.0 0.5 2.0 Rinse aid 1/2 0.05 0.02 0.08 0.1 Various and secondary up to 100% EXAMPLE 11 The following liquid detergent formulations were prepared according to the present invention (the levels are given in parts by weight): 1 II lll IV V LAS 11.5 8.8 - 3.9 - C25E2.5S - 3.0 18.0 - 16.0 C45E2.25S 11.5 3.0 - 15.7 - C23E9 - 2.7 1.8 2.0 1.0 C23E7 3.2 - - - - CFAA - - 5.2 - 3.1 TPKFA 1.6 - 2.0 0.5 2.0 Citrus (50%) 6.5 1.2 2.5 4.4 2.5 Ca formate 0.1 0.06 0.1 - - Na formate 0.5 0.06 0.1 0.05 0.05 SCS 4.0 1.0 3.0 1.2 - Borato 0.6 - 3.0 2.0 2.9 Na hydroxide 5.8 2.0 3.5 3.7 2.7 Ethanol 1.75 1.0 3.6 4.2 2.9 1, 2-Propanediol 3.3 2.0 8.0 7.9 5.3 Monoethanolamine 3.0 1.5 1.3 2.5 0.8 TEPAE 1.6 - 1.3 1.2 1.2 Protease 0.03 0.01 0.03 0.02 0.02 Lipasa - - 0.002 - - 1 II lll IV V Amylase - - - 0.002 - Cellulase 0.001 0.0002 0.0002 0.0005 0.0 SRP1 0.2 - 0.1 - - DTPA - - 0.3 - - PVNO - - 0.3 - 0.2 Rinse aid 1 0.2 0.07 0.1 - - Silicone antifoam 0.04 0.02 0.1 0.1 0.1 CBD-Damascona 2.0 0.2 4.0 0.6 2.0 Various and water Up to 100% EXAMPLE 12 The following liquid formulations were prepared according to the present invention (the levels are given in parts by weight): I II III IV LAS 10.0 13.0 9.0 - C25AS 4.0 1.0 2.0 10.0 C25E3S 1.0 - - 3.0 C25E7 6.0 8.0 13.0 2.5 TFAA - - - 4.5 APA - 1.4 - - TPKFA 2.0 - 13.0 7.0 Citrus 2.0 3.0 1.0 1.5 lll IV Dodecenyl / tetradecenylsuccinic acid 12.0 10.0 - - Rapeseed fatty acid 4.0 2.0 1.0 - Ethanol 4.0 4.0 7.0 2.0 1, 2-Propanediol 4.0 4.0 2.0 7.0 Monoethanolamine - - - 5.0 Triethanolamine - - 8.0 - TEPAE 0.5 - 0.5 0.2 DETPMP 1.0 1.0 0.5 1.0 Protease 0.02 0.02 0.01 0.008 Lipasa - 0.002 - 0.002 Amylase 0.004 0.004 0.01 0.008 Cellulase 0.0005 0.0008 0.0003 0.002 SRP2 0.3 - 0.3 0.1 Boric acid 0.1 0.2 1.0 2.0 Ca chloride - 0.02 - 0.01 Rinse aid 1 - 0.4 - - Foam suppressor 0.1 0.3 - 0.1 Oparant 0.5 0.4 - 0.3 CBD-Damascona 0.4 0.2 2.0 1.0 NaOH up to pH 8.0 8.0 7.6 1.7 Various and water Up to 100% EXAMPLE 13 The following liquid detergent formulations according to the present invention were prepared (levels are given in parts by weight): 1 II lll IV LAS 25.0 - - - C25AS - 13.0 18.0 15.0 C25E3S - 2.0 2.0 4.0 C25E7 - - 4.0 4.0 TFAA - 6.0 8.0 8.0 APA 3.0 1.0 2.0 - TPKFA - 15.0 11.0 11.0 Citrus 1.0 1.0 1.0 1.0 Dodecenyl / tetradecenylsuccinic acid 15.0 - - - Rapeseed fatty acid 1.0 - 3.5 - Ethanol 7.0 2.0 3.0 2.0 1, 2-Propanediol 6.0 8.0 10.0 13.0 Monoethanolamine - - 9.0 9.0 TEPAE - - 0.4 0.3 DETPMP 2.0 1.2 1.0 - Protease 0.08 0.02 0.01 0.02 Lipasa - - 0.003 0.003 Amylase 0.004 0.01 0.01 0.01 Cellulase 0.0003 0.0006 0.004 0.003 SRP2. _ 0.2 0.1 I II lll IV Boric acid 1.0 1.5 2.5 2.5 Clay bentonite 4.0 4.0 - - Brightener 1 0.1 0.2 0.3 - Foam suppressor 0.4 - - - Oparant 0.8 0.7 - - CBD-Damascona - 0.2 0.6 - CBD-Rotundial 2.0 3.0 5.0 2.0 NaOH up to pH 8.0 7.5 8.0 8.2 Miscellaneous and water Up to 100% EXAMPLE 14 The following liquid detergent compositions according to the invention were prepared (levels are given in parts by weight).

I LAS 27.6 18.9 C45AS 13.8 5.9 C13E8 3.0 3.1 Oleic acid 3.4 2.5 Citric 5.4 5.4 Hydroxide 0.4 3.6 Ca formate 0.2 0.1 Na formate _ 0.5 Ethanol 7.0 - Monoethanolamine 16.5 8.0 1, 2-Propanediol 5.9 5.5 Xylenesulfonic acid - 2.4 TEPAE 1.5 0.8 Protease 0.05 0.02 Cellulase 0.0003 0.0006 PEG - 0.7 Brightener 2 0.4 0.1 CBD-Rotundial 10.0 1.0 Perfume 0.5 0.3 Various and water Up to 100% EXAMPLE 15 The following granular fabric detergent compositions were prepared which provide "softening during washing" ability according to the present invention: 1 II C45AS - 10.0 LAS 7.6 - C68AS 1.3 - C45E7 4.0 _. C25E3 5.0 Cocoalkyldimethyl-hydroxyethylammonium chloride 1.4 1.0 Citrate 5.0 3.0 Na-SKS-6 - 11.0 Zeolite A 15.0 15.0 MA / AA 4.0 4.0 DETPMP 0.4 0.4 PB1 15.0 - Percarbonate - 15.0 TAED 5.0 5.0 Smectite clay 10.0 10.0 HMWPEO - 0.1 Protease 0.02 0.01 Lipase 0.02 0.01 Amylase 0.03 0.005 Cellulase 0.001 0.0009 Silicate 3.0 5.0 Carbonate 10.0 10.0 Foam suppressor 1.0 4.0 CMC 0.2 0.1 CBD-Damascona 0.8 1.2 Water / several Up to 100% EXAMPLE 16 The following fabric softening compositions were added to the rinse according to the present invention: 1 II lll DEQA (2) 20.0 20.0 20.0 Celulasa 0.001 0.001 0.001 HCL 0.03 0.03 0.03 Antifoam agent 0.01 0.01 0.01 Blue dye 25 ppm 25 ppm 25 ppm CaCI2 0.20 0.20 0.20 CBD-Rotundial 5.0 - 2.0 CBD-Damascona - 5.0 6.0 Perfume 0.90 0.90 0.90 Various and water Up to 100% EXAMPLE 17 The following fabric softening and fabric conditioner compositions were added to the dryer according to the present invention.

I II III IV V DEQA 2.6 19.0 - - - DEQA (2) - - - - 51.8 DTMAMS - - - 26.0 - SDASA - - 70.0 42.0 40.2 Stearic acid of IV = 0 0.3 - - - - Neodol 45-13 - - 13.0 - - Hydrochloric acid 0.02 0.02 - - - Ethanol - - 1.0 - - Cellulase 0.0001 0.001 0.0005 0.005 0.0003 Perfume 1.0 1.0 0.75 1.0 1.5 Glycoperse S-20 - - - - 15.4 Glycerol monostearate - - - 26.0 - Digeranyl succinate - - 0.38 - - • Silicone antifoam 0.01 - - - Electrolyte - 0.1 - - - CBD-Damascona 0.6 1.0 2.0 0.4 3.0 CBD Rotundial 10.0 0.1 - 1.0 - Clay - - - 3.0 - Dye 10 ppm 25 ppm 0.01 - - Water and secondary 100% 100% - - - EXAMPLE 18 The following bar detergent compositions for laundry were prepared in accordance with the present invention: I II III VI V III VI V LAS - - 19.0 15.0 21.0 6.75 8.8 - C28AS 30.0 13.5 - - - 15.75 11.2 22.5 Na Laurato 2.5 9.0 - - - - - - Zeolite A 2.0 1.25 - - - 1.25 1.25 1.25 Carbonate 20.0 3.0 13.0 8.0 10.0 15.0 15.0 10.0 Carbonate Ca 27.5 39.0 35.0 - - 40.0 - 40.0 Sulfate 5.0 5.0 3.0 5.0 3.0 - - 5.0 TSPP 5.0 - - - - 5.0 2.5 - STPP 5.0 15.0 10.0 - - 7.0 8.0 10.0 Bentonite clay - 10.0 - - 5.0 - - - DETPMP - 0.7 0.6 - 0.6 0.7 0.7 0.7 CMC - 1.0 1.0 1.0 1.0 - - 1.0 Talcum - - 10.0 15.0 10.0 - - - Silicate - - 4.0 5.0 3.0 - - - PVNO 0.02 0.03 - 0.01 - 0.02 - - MA / AA 0.4 1.0 - - 0.2 0.4 0.5 0.4 SRP1 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Amylase - - 0.01 - - - 0.002 - Protease - 0.004 - 0.003 0.003 - - 0.003 Lipase - 0.002 - 0.002 - - - - Cellulase .0008 .0003 .0002 .0003 .0003 .0002 .0005 .0005 PEO - 0.2 - 0.2 0.3 - - 0.3 Perfume 1.0 0.5 0.3 0.2 0.4 - - 0.4 Mg sulfate - - 3.0 3.0 3.0 - - - 1 II lll VI V lll VI V CBD-Damascona 1.0 - 2.5 1.0 3.0 - 0.2 0.4 CBD-Rotundial 1.0 0.5 2.5 - 0.5 0.5 - 0.04 Rinse aid 0.15 0.1 0.15 - - - - 0.1 Photoactivated bleach (ppm) - 15.0 15.0 15.0 15.0 - - 15.0 CBD-Damascona 1.0 _ 2.5 1.0 3.0 _ 0.2 0.4

Claims (15)

NOVELTY OF THE INVENTION CLAIMS

1. - A chemical entity comprising a chemical component linked to an amino acid sequence comprising a cellulose binding domain, characterized in that said amino acid sequence comprising said cellulose domain, has a binding constant for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or for amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose.

2. The chemical entity according to claim 1, further characterized in that said amino acid sequence comprising a cellulose binding domain, has a binding constant for crystalline cellulose (Kr-c) of at least 20 l / g of cellulose, and / or a binding constant for Avicel (Kr-av) and / or for amorphous cellulose (Kr-am) of at least 5 l / g of cellulose.

3. The chemical entity in accordance with the claims 1-2, further characterized in that said amino acid sequence comprising a cellulose binding domain having a binding constant for Avicel (Kr-av) and / or for amorphous cellulose (Kr-am) of at least 1.5 l / g of cellulose, is selected from a mycotic class of the family I.

4. The chemical entity according to claims 1-2, further characterized in that said amino acid sequence comprising a cellulose binding domain having a constant of binding for crystalline cellulose (Kr-c) of at least 10 l / g of cellulose, preferably 20 l / g of cellulose, and / or has a binding constant for Avicel (Kr-av) and / or for amorphous cellulose ( Kr-am) of at least 1.5 g / g of cellulose, is selected from a bacterial class of family II, III or IV.

5. The chemical entity according to claims 1-4, further characterized in that said amino acid sequence comprising a cellulose binding domain is selected from: CBD of the family 45 of the endoglucanase derived from Humicola insolens DSM 1800 with a molecular weight of approximately 43kDa, CBD of cellulase E3 from Thermomonospora fusca; Cellulozome CBD of Clostridium cellulovorans, and / or mixtures thereof.

6. The chemical entity according to claims 1-5, further characterized in that the chemical component is linked to said amino acid sequence comprising a cellulose binding domain by means of a linker region.

7 '.- The chemical entity according to claim 6, further characterized in that the linker region is an amino acid linker region.

8. The chemical entity according to claim 6, further characterized in that the linker region is a polymer selected from PEG (NPC) 2, (NH2) 2-PEG, t-BOC-NH-PEG-NH2, MAL-PEG -NHS and / or polymers of VS-PEG-NHS.

9. - The chemical entity according to any of the preceding claims, further characterized in that said chemical component is linked to said amino acid sequence comprising a cellulose binding domain, or said linker region, by means of a weak link.

10. The chemical entity according to any of the preceding claims, further characterized in that said chemical component is selected from perfumes, hygienic agents, insect control agents, fabric softening agents, soil removal agents, bleaching agents, agents f dyeing agents, polishes, latexes, resins and / or mixtures thereof; preferably perfumes, hygienic agents, insect control agents and / or mixtures thereof.

11. A laundry detergent and / or fabric care composition comprising a detergent ingredient for laundry and / or fabric care, and a chemical entity as claimed in any of the preceding claims.

12. The detergent composition of laundry and / or care of the fabric according to claim 11, further characterized in that it is in the form of an additive, a pretreatment composition, a post-treatment composition, a treatment composition for soaking and / or a rinsing treatment composition.

13. - A cleaning method comprising the step of contacting a fabric with a chemical entity as claimed in any of claims 1-10, or with a detergent laundry and / or fabric care composition such as which is claimed in claims 11-12, to provide cleaning of a fabric, including removal of dirt and stains and / or maintenance of whiteness of the fabric and / or inhibition of dye transfer.

14. A method comprising the step of contacting a fabric with a chemical entity as claimed in claims 1-11, or with a detergent laundry and / or fabric care composition such as that claims in claims 11-12, to provide care of a fabric, including anti-wrinkle properties, against the formation of pellets, against shrinkage of the fabric, softness of the fabric, freshness of the fabric, appearance of color and anti-wear properties of the cloth.

15. A method comprising the step of contacting a fabric with a chemical entity as claimed in claims 1-10, or with a detergent laundry and / or fabric care composition such as that claims in claims 11-12, to provide disinfection and / or insect control.