MX9606540A - Process for the preparation of crystalline vinylaromatic polymers having an essentially syndiotactic structure. - Google Patents
Process for the preparation of crystalline vinylaromatic polymers having an essentially syndiotactic structure.Info
- Publication number
- MX9606540A MX9606540A MX9606540A MX9606540A MX9606540A MX 9606540 A MX9606540 A MX 9606540A MX 9606540 A MX9606540 A MX 9606540A MX 9606540 A MX9606540 A MX 9606540A MX 9606540 A MX9606540 A MX 9606540A
- Authority
- MX
- Mexico
- Prior art keywords
- preparation
- syndiotactic structure
- vinylaromatic polymers
- crystalline
- essentially syndiotactic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The present invention discloses a process for the preparation of crystalline vinylaromatic polymers having an essentially syndiotactic structure, said process comprising polymerizing vinylaromatic monomers, alone or mixed with at least another monomer in the presence of a catalyst system essentially consisting of A) a titanium or zirconium complex selected from those having general formula MR1R2R3R3, A1MR1R2R3, A1A2MR1R2; B) a catalyst selected from an alkylaluminoxane and a boron compound having the formula (II): BX1X2X3 or one of their salts; C) a tin derivative having the general formula: SnR5R6R7R8.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT95MI002701A IT1277677B1 (en) | 1995-12-21 | 1995-12-21 | PROCEDURE FOR THE PREPARATION OF CRYSTALLINE VINYLAROMATIC POLYMERS WITH PREDOMINANTLY SYNDIOTACTIC STRUCTURE |
MIMI95A002701 | 1995-12-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
MXPA96006540A MXPA96006540A (en) | 1997-06-01 |
MX9606540A true MX9606540A (en) | 1997-06-28 |
Family
ID=11372771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9606540A MX9606540A (en) | 1995-12-21 | 1996-12-17 | Process for the preparation of crystalline vinylaromatic polymers having an essentially syndiotactic structure. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5728784A (en) |
EP (1) | EP0780405B1 (en) |
JP (1) | JPH09183811A (en) |
AT (1) | ATE176248T1 (en) |
CA (1) | CA2191361A1 (en) |
DE (1) | DE69601457T2 (en) |
DK (1) | DK0780405T3 (en) |
ES (1) | ES2128815T3 (en) |
GR (1) | GR3029595T3 (en) |
IT (1) | IT1277677B1 (en) |
MX (1) | MX9606540A (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6274752B1 (en) | 1996-02-20 | 2001-08-14 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
US6291695B1 (en) | 1996-02-20 | 2001-09-18 | Northwestern University | Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon |
US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
IT1286031B1 (en) * | 1996-10-24 | 1998-07-07 | Enichem Spa | PROCESS FOR THE PRODUCTION OF VINYLAROMATIC POLYMERS WITH A HIGH DEGREE OF SYNDIOTAXY |
NL1004992C2 (en) * | 1997-01-14 | 1998-07-15 | Dsm Nv | Use of compounds containing Si, Ge, Sn or Pb as a cocatalyst in the polymerization of olefins. |
JP2002514247A (en) | 1997-01-14 | 2002-05-14 | ディーエスエム エヌ.ブイ. | Olefin polymerization method |
ITMI980934A1 (en) | 1998-04-30 | 1999-10-30 | Enichem Spa | PROCEDURE FOR THE PREPARATION OF PRODUCTS BASED ON VINYLAROMATIC POLYMERS WITH A PREDOMINALLY SYNDIOTACTIC STRUCTURE |
CN1117106C (en) * | 1999-06-24 | 2003-08-06 | 中国石油化工集团公司 | Syndiotactic poly styrene polymer |
US6982306B2 (en) | 2003-11-26 | 2006-01-03 | Chevron Phillips Chemical Company, L.P. | Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1276748C (en) | 1985-07-29 | 1990-11-20 | Michitake Uoi | Styrene polymers |
IL84798A (en) | 1986-12-15 | 1991-09-16 | Montedison Spa | Production of crystalline vinyl aromatic polymers having mainly a syndiotactic structure |
US4978730A (en) | 1987-12-24 | 1990-12-18 | Idemitsu Kosan Company Limited | Process for producing styrene-based polymers and catalyst for use therein |
IT1231774B (en) * | 1989-08-03 | 1991-12-21 | Enichem Anic Spa | CATALYST AND PROCEDURE FOR THE POLYMERIZATION AND COPOLYMERIZATION OF ALFA OLEFINE. |
US5326837A (en) * | 1992-11-20 | 1994-07-05 | Mobil Oil Corporation | Catalyst systems for syndiospecific polymerization of styrenes |
EP0675139B1 (en) * | 1994-03-31 | 1998-10-14 | Idemitsu Kosan Co., Ltd. | Process for producing styrenic polymer |
IT1276801B1 (en) * | 1995-06-30 | 1997-11-03 | Enichem Spa | PROCEDURE FOR THE PREPARATION OF CRYSTALLINE VINYLAROMATIC POLYMERS WITH PREDOMINANTLY SYNDIOTACTIC STRUCTURE |
US5644009A (en) * | 1995-11-27 | 1997-07-01 | Industrial Technology Research Institute | Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same |
-
1995
- 1995-12-21 IT IT95MI002701A patent/IT1277677B1/en active IP Right Grant
-
1996
- 1996-11-12 DK DK96118100T patent/DK0780405T3/en active
- 1996-11-12 DE DE69601457T patent/DE69601457T2/en not_active Expired - Fee Related
- 1996-11-12 AT AT96118100T patent/ATE176248T1/en not_active IP Right Cessation
- 1996-11-12 EP EP96118100A patent/EP0780405B1/en not_active Expired - Lifetime
- 1996-11-12 ES ES96118100T patent/ES2128815T3/en not_active Expired - Lifetime
- 1996-11-26 CA CA002191361A patent/CA2191361A1/en not_active Abandoned
- 1996-11-27 US US08/757,251 patent/US5728784A/en not_active Expired - Fee Related
- 1996-12-17 MX MX9606540A patent/MX9606540A/en not_active Application Discontinuation
- 1996-12-24 JP JP8343764A patent/JPH09183811A/en active Pending
-
1999
- 1999-03-05 GR GR990400682T patent/GR3029595T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE69601457T2 (en) | 1999-06-10 |
ITMI952701A1 (en) | 1997-06-21 |
ATE176248T1 (en) | 1999-02-15 |
EP0780405B1 (en) | 1999-01-27 |
JPH09183811A (en) | 1997-07-15 |
US5728784A (en) | 1998-03-17 |
ITMI952701A0 (en) | 1995-12-21 |
CA2191361A1 (en) | 1997-06-22 |
DK0780405T3 (en) | 1999-09-13 |
IT1277677B1 (en) | 1997-11-11 |
ES2128815T3 (en) | 1999-05-16 |
EP0780405A1 (en) | 1997-06-25 |
GR3029595T3 (en) | 1999-06-30 |
DE69601457D1 (en) | 1999-03-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |