MX9502839A - Mezclas de poliisocianato/poliamina y su uso para la produccion de recubrimientos de poliurea. - Google Patents
Mezclas de poliisocianato/poliamina y su uso para la produccion de recubrimientos de poliurea.Info
- Publication number
- MX9502839A MX9502839A MX9502839A MX9502839A MX9502839A MX 9502839 A MX9502839 A MX 9502839A MX 9502839 A MX9502839 A MX 9502839A MX 9502839 A MX9502839 A MX 9502839A MX 9502839 A MX9502839 A MX 9502839A
- Authority
- MX
- Mexico
- Prior art keywords
- groups
- present
- polyisocyanate
- production
- components
- Prior art date
Links
- 229920002396 Polyurea Polymers 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 229920000768 polyamine Polymers 0.000 title abstract 2
- 229920001228 polyisocyanate Polymers 0.000 title abstract 2
- 239000005056 polyisocyanate Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 150000004705 aldimines Chemical class 0.000 abstract 2
- CKLJMWTZIZZHCS-REOHCLBHSA-L aspartate group Chemical group N[C@@H](CC(=O)[O-])C(=O)[O-] CKLJMWTZIZZHCS-REOHCLBHSA-L 0.000 abstract 2
- 239000008199 coating composition Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3253—Polyamines being in latent form
- C08G18/3256—Reaction products of polyamines with aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3253—Polyamines being in latent form
- C08G18/3259—Reaction products of polyamines with inorganic or organic acids or derivatives thereof other than metallic salts
- C08G18/3262—Reaction products of polyamines with inorganic or organic acids or derivatives thereof other than metallic salts with carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
La presente invencion se refiere a una composicion de recubrimientos que está libre de polioles y que contiene a) un componente de poliisocianato, b) una aldimina en base al producto de reaccion de una poliamina que tiene 2 o más grupos amino primarios, con un aldehído y c) un compuesto que contiene grupos aspartato, en donde los componentes a), b) y c) están presentes en una cantidad suficiente para proporcionar una relacion equivalente de grupos isocianato o grupos aldimina y grupos aspartato de 0.5:1 a 20:1 y en donde el componente c) está presente en una cantidad suficiente para formar una solucion clara dentro de 60 minutos de mezclado de los componentes a), b) y c), con la condicion de que la cantidad del componente c) sea de al menos 5% en peso, en base al peso de los componentes b) y c). La presente invencion también se refiere a un recubrimiento de poliurea preparado a partir de esta composicion de recubrimiento.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/273,551 US5516873A (en) | 1994-07-11 | 1994-07-11 | Polyisocyanate/polyamine mixtures and their use for the production of polyurea coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9502839A true MX9502839A (es) | 1997-05-31 |
Family
ID=23044400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9502839A MX9502839A (es) | 1994-07-11 | 1995-06-28 | Mezclas de poliisocianato/poliamina y su uso para la produccion de recubrimientos de poliurea. |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US5516873A (es) |
| CA (1) | CA2153451A1 (es) |
| MX (1) | MX9502839A (es) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5973097A (en) * | 1994-06-06 | 1999-10-26 | Basf Corporation | Aldimine based coating compositions and pigment dispersions |
| DE19542119C1 (de) * | 1995-11-11 | 1997-02-13 | Herberts Gmbh | Überzugsmittel und Verfahren zur Herstellung von Mehrschichtüberzügen |
| US6399736B1 (en) * | 1997-03-11 | 2002-06-04 | Huntsman Petrochemical Corporation | Method of preparing spray elastomer systems |
| US6013755A (en) * | 1997-03-11 | 2000-01-11 | Huntsman Petrochemical Corporation | Method of preparing an aliphatic polyurea spray elastomer system |
| DE19731540A1 (de) * | 1997-07-23 | 1999-01-28 | Herberts Gmbh | Überzugsmittel und deren Verwendung bei Verfahren zur Mehrschichtlackierung |
| US5859163A (en) * | 1997-08-22 | 1999-01-12 | Bayer Corporation | Allophanate group-containing polyisocyanates improved compatibility with aldimines |
| DE19822842A1 (de) | 1998-05-22 | 1999-11-25 | Bayer Ag | 2K-PUR-Korrosionsschutz-Decklack |
| US6005062A (en) | 1998-07-02 | 1999-12-21 | 3M Innovative Properties Company | Secondary aspartic acid amide esters |
| US6107436A (en) * | 1998-10-05 | 2000-08-22 | 3M Innovative Properties Company | Polyfunctional polymer |
| US6350823B1 (en) | 1998-10-05 | 2002-02-26 | 3M Innovative Properties Company | Pavement marking composition |
| US6403063B1 (en) | 1999-07-26 | 2002-06-11 | Kenneth I. Sawyer | Method of treating nail fungus |
| US6355829B2 (en) * | 1999-09-02 | 2002-03-12 | Bayer Corporation | Aspartate-terminated urea/urethane prepolymers and their use in coating compositions |
| US6401724B1 (en) | 1999-10-11 | 2002-06-11 | Par Pharmaceuticals Incorporated | Method of applying a cosmetic nail lacquer or polish to a nail |
| US6369189B1 (en) | 1999-12-07 | 2002-04-09 | Reichhold, Inc. | Hindered amine adducts for polyurea systems |
| US6482333B1 (en) | 1999-12-30 | 2002-11-19 | Bayer Corporation | Polyurea coatings from dimethyl-substituted polyaspartic ester mixtures |
| US20030013835A1 (en) * | 2001-04-25 | 2003-01-16 | Anastasios Zahariadis | 100% polyurea elastomeric system, process for producing and use thereof |
| EP1384735A1 (de) * | 2002-07-26 | 2004-01-28 | Sika Technology AG | Polyaldimin enthaltende Polyurethanzusammensetzung |
| CA2473437A1 (en) * | 2002-01-18 | 2003-07-24 | Sika Technology Ag | Two-constituent polyurethane composition having high early strength |
| WO2004018171A1 (en) | 2002-08-20 | 2004-03-04 | Roof Matrix, Inc. | Non-toxic hydrophobic elastomeric polymer chemistry system for wood preservation |
| US6774206B2 (en) | 2002-09-26 | 2004-08-10 | Bayer Polymers Llc | Polyaspartate resins with improved flexibility |
| US6774207B2 (en) * | 2002-09-26 | 2004-08-10 | Bayer Polymers Llc | Polyaspartate resins with good hardness and flexibility |
| US6790925B2 (en) * | 2002-12-05 | 2004-09-14 | Bayer Polymers Llc | In-situ preparation of polyaspartic ester mixtures |
| US7276288B2 (en) * | 2003-01-03 | 2007-10-02 | E. I. Du Pont De Nemours & Co. | Durable coating compositions containing aspartic compounds |
| US20070043197A1 (en) * | 2003-07-07 | 2007-02-22 | Huntsman Petrochemical Corporation | Polyurea polymers from secondary polyether polyamines |
| US20050059790A1 (en) * | 2003-09-16 | 2005-03-17 | Roesler Richard R. | Process for preparing aspartates |
| US20060011295A1 (en) * | 2004-07-14 | 2006-01-19 | Karsten Danielmeier | Aspartic ester functional compounds |
| US7417094B2 (en) * | 2004-11-18 | 2008-08-26 | Pripro Polymer, Inc. | Cross-linked thermoplastic polyurethane/polyurea and method of making same |
| US7540990B1 (en) * | 2004-11-18 | 2009-06-02 | Callaway Golf Company | Cross-linked thermoplastic polyurethane/polyurea and method of making same |
| US7608303B2 (en) | 2004-12-15 | 2009-10-27 | E.I. Du Pont De Nemours And Company | Durable coating compositions containing aspartic amine compounds |
| US7674499B2 (en) * | 2004-12-15 | 2010-03-09 | E.I. Du Pont De Nemours And Company | Durable coating compositions containing novel aspartic amine compounds |
| US7682665B2 (en) * | 2004-12-15 | 2010-03-23 | E.I. Du Pont De Nemours And Company | Durable coating compositions containing novel aspartic amine compounds |
| US20060228485A1 (en) * | 2004-12-15 | 2006-10-12 | Lenges Christian P | Durable coating compositions containing aspartic amine compounds |
| US7449242B2 (en) | 2004-12-15 | 2008-11-11 | E.I. Du Pont De Nemours & Company | Durable coating compositions containing novel aspartic amine compounds |
| US7732018B2 (en) * | 2004-12-15 | 2010-06-08 | E. I. Du Pont De Nemours And Company | Durable coating compositions containing novel aspartic amine compounds |
| US7214828B2 (en) * | 2004-12-15 | 2007-05-08 | E. I. Dupont De Nemours And Company | Durable coating compositions containing novel aspartic amine compounds |
| US7166748B2 (en) * | 2004-12-15 | 2007-01-23 | E.I. Dupont De Nemours & Co. | Durable coating compositions containing novel aspartic amine compounds |
| US7427647B2 (en) * | 2005-01-13 | 2008-09-23 | E.I. Du Pont De Nemours & Company | Durable coating compositions containing aspartic amine compounds with improved potlife |
| DE102005047562A1 (de) * | 2005-10-04 | 2007-04-05 | Bayer Materialscience Ag | Zweitkomponenten-Systeme für die Herstellung flexibler Beschichtungen |
| EP1834971A1 (de) * | 2006-03-13 | 2007-09-19 | Sika Technology AG | Feuchtigkeitshärtende Polyurethanzusammensetzung mit gutem Tieftemperaturverhalten |
| US20080173728A1 (en) * | 2007-01-22 | 2008-07-24 | Patrick Ilfrey | High-solids, reactive components spray application systems |
| US8313809B2 (en) * | 2007-12-11 | 2012-11-20 | Patrick Ilfrey | Same-day coatings and processes |
| US8710170B2 (en) * | 2008-05-15 | 2014-04-29 | The United States of Americas, as represented by the Secretary of the Navy | Polyureas made from aminocrotonates and enaminones |
| CN102149741A (zh) * | 2008-09-12 | 2011-08-10 | 陶氏环球技术有限责任公司 | 基于多元胺、多元醇和多异氰酸酯的涂料配方和组合物及制备和使用它们的方法 |
| EA201290136A1 (ru) * | 2009-10-01 | 2012-10-30 | Юниверсити Оф Хьюстон Систем | Нанокомпозиты органоглины с полимочевиной |
| US20110132782A1 (en) | 2009-12-07 | 2011-06-09 | Patrick Ilfrey | Article and method for reactive mixtures |
| US11484627B2 (en) | 2010-10-20 | 2022-11-01 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications |
| WO2015095745A1 (en) | 2010-10-20 | 2015-06-25 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications |
| US10525169B2 (en) | 2010-10-20 | 2020-01-07 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications |
| US11207109B2 (en) | 2010-10-20 | 2021-12-28 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications |
| US11058796B2 (en) | 2010-10-20 | 2021-07-13 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications |
| US11291483B2 (en) | 2010-10-20 | 2022-04-05 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants |
| EP2629780A4 (en) | 2010-10-20 | 2014-10-01 | 206 Ortho Inc | IMPLANTABLE POLYMER FOR BONE AND VASCULAR LESIONS |
| WO2013130877A1 (en) | 2012-02-29 | 2013-09-06 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, including the use of composite implants |
| US9284400B2 (en) | 2013-03-15 | 2016-03-15 | The United States Of America, As Represented By The Secretary Of The Navy | Aspartic resins |
| EP3795635A1 (en) | 2013-05-23 | 2021-03-24 | 206 ORTHO, Inc. | Apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants |
| EP4042950A1 (en) | 2014-05-08 | 2022-08-17 | 206 Ortho, Inc. | Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone |
| US10280333B2 (en) | 2015-02-03 | 2019-05-07 | Seagrave Coatings Corp. | Coating compositions |
| KR101997051B1 (ko) | 2019-03-21 | 2019-10-01 | 미경산업주식회사 | 도로표지용 폴리우레아 차선 조성물 및 이를 이용한 시공방법 |
| US11827788B2 (en) | 2019-10-07 | 2023-11-28 | Covestro Llc | Faster cure polyaspartic resins for faster physical property development in coatings |
| CN111763299A (zh) * | 2020-07-20 | 2020-10-13 | 佛山市万化科技有限公司 | 一种高强度单组份聚脲及其制备方法 |
| AU2021365371A1 (en) * | 2020-10-19 | 2023-02-23 | Sika Technology Ag | Cycloaliphatic aldimine mixture |
| CN118909525B (zh) * | 2024-07-17 | 2025-11-04 | 深圳飞扬骏研新材料股份有限公司 | 一种喷涂液态车衣膜组合物、喷涂车衣膜及其制备方法 |
| CN118895082A (zh) * | 2024-07-23 | 2024-11-05 | 南京维新高分子科技有限公司 | 一种低粘度、缓凝胶无溶剂双组份脂肪族聚脲涂料及其应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3567692A (en) * | 1963-02-04 | 1971-03-02 | Ici Ltd | Polymeric materials produced by interacting polyisocyanate and water in the presence of polyaldimine or polyketimine |
| GB1064841A (en) * | 1963-02-04 | 1967-04-12 | Ici Ltd | Manufacture of polymers containing biuret and urea groups |
| DE59007601D1 (de) * | 1989-06-23 | 1994-12-08 | Bayer Ag | Verfahren zur Herstellung von Überzügen. |
| US5124427A (en) * | 1991-01-22 | 1992-06-23 | Miles Inc. | Polyisocyanates containing allophanate and isocyanurate groups, a process for their production and their use in two-component coating compositions |
| US5214086A (en) * | 1991-09-04 | 1993-05-25 | Basf Corporation | Coating compositions which may be ambient cured |
-
1994
- 1994-07-11 US US08/273,551 patent/US5516873A/en not_active Expired - Lifetime
-
1995
- 1995-06-28 MX MX9502839A patent/MX9502839A/es unknown
- 1995-07-07 CA CA002153451A patent/CA2153451A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2153451A1 (en) | 1996-01-12 |
| US5516873A (en) | 1996-05-14 |
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