MX360657B - Método para seleccionar combinaciones de refrigerante y lubricante. - Google Patents

Método para seleccionar combinaciones de refrigerante y lubricante.

Info

Publication number
MX360657B
MX360657B MX2017001913A MX2017001913A MX360657B MX 360657 B MX360657 B MX 360657B MX 2017001913 A MX2017001913 A MX 2017001913A MX 2017001913 A MX2017001913 A MX 2017001913A MX 360657 B MX360657 B MX 360657B
Authority
MX
Mexico
Prior art keywords
heat transfer
refrigerant
lubricant
transfer cycle
combinations
Prior art date
Application number
MX2017001913A
Other languages
English (en)
Inventor
Bonnet Philippe
L Van Horn Brett
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of MX360657B publication Critical patent/MX360657B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008—Lubricant compositions compatible with refrigerants
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/126—Unsaturated fluorinated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C10M2203/1045—Aromatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/0406—Ethers; Acetals; Ortho-esters; Ortho-carbonates used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C10M2209/043—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/097—Refrigerants
    • C10N2020/099—Containing Chlorofluorocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/097—Refrigerants
    • C10N2020/101—Containing Hydrofluorocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/097—Refrigerants
    • C10N2020/103—Containing Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/097—Refrigerants
    • C10N2020/105—Containing Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/097—Refrigerants
    • C10N2020/106—Containing Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)

Abstract

La presente invención proporciona métodos para seleccionar combinaciones de refrigerante y lubricante para uso en sistemas de ciclo de transferencia de calor, y proporciona métodos para hacer funcionar dichos sistemas de transferencia de calor. Más particularmente, la invención proporciona métodos para seleccionar combinaciones de lubricante y refrigerante para un sistema de ciclo de transferencia de calor en el que, a las temperaturas más bajas del ciclo de transferencia de calor, el refrigerante y el lubricante son miscibles y, a las temperaturas más altas del ciclo de transferencia de calor, el refrigerante y el lubricante se separan en fases, y de forma que la temperatura de inversión de fase de densidad de la combinación esté por debajo de la temperatura más alta de funcionamiento del ciclo de transferencia de calor.
MX2017001913A 2009-12-29 2010-12-20 Método para seleccionar combinaciones de refrigerante y lubricante. MX360657B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US29069009P 2009-12-29 2009-12-29
PCT/US2010/061258 WO2011082003A1 (en) 2009-12-29 2010-12-20 Method of selecting refrigerant-lubricant combinations

Publications (1)

Publication Number Publication Date
MX360657B true MX360657B (es) 2018-11-12

Family

ID=44226767

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2017001913A MX360657B (es) 2009-12-29 2010-12-20 Método para seleccionar combinaciones de refrigerante y lubricante.
MX2012007563A MX345853B (es) 2009-12-29 2010-12-20 Metodo para seleccionar combinaciones del refrigerante y lubricante.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2012007563A MX345853B (es) 2009-12-29 2010-12-20 Metodo para seleccionar combinaciones del refrigerante y lubricante.

Country Status (8)

Country Link
US (2) US9481820B2 (es)
EP (1) EP2519599B1 (es)
JP (1) JP6141019B2 (es)
CN (1) CN102686695B (es)
CA (1) CA2785854C (es)
ES (1) ES2957896T3 (es)
MX (2) MX360657B (es)
WO (1) WO2011082003A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110232306A1 (en) * 2008-04-30 2011-09-29 Honeywell International Inc. Absorption refrigeration cycles using a lgwp refrigerant
CA2788053A1 (en) * 2010-01-25 2011-07-28 Arkema Inc. Heat transfer composition of oxygenated lubricant with hydrofluoroolefin and hydrochlorofluoroolefin refrigerants
FR2957083B1 (fr) 2010-03-02 2015-12-11 Arkema France Fluide de transfert de chaleur pour compresseur centrifuge
FR2959997B1 (fr) 2010-05-11 2012-06-08 Arkema France Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant
FR2959999B1 (fr) 2010-05-11 2012-07-20 Arkema France Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant
FR2964976B1 (fr) 2010-09-20 2012-08-24 Arkema France Composition a base de 1,3,3,3-tetrafluoropropene
FR2964977B1 (fr) * 2010-09-20 2013-11-01 Arkema France Composition a base de 3,3,3-tetrafluoropropene
FR2974812B1 (fr) 2011-05-04 2014-08-08 Arkema France Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification
EP3239268B1 (en) * 2011-05-19 2020-02-12 AGC Inc. Working medium and heat-cycle system
FR2986236B1 (fr) * 2012-01-26 2014-01-10 Arkema France Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification
CN106133316B (zh) 2014-03-18 2020-04-07 开利公司 制冷剂滑油系统
KR20240132524A (ko) 2015-05-21 2024-09-03 더 케무어스 컴퍼니 에프씨, 엘엘씨 SbF5에 의한 1233xf의 244bb로의 히드로플루오린화
CN107787413B (zh) 2015-06-16 2020-06-30 开利公司 在轴承表面上具有摩擦膜的热传递系统
CN105041660A (zh) * 2015-07-15 2015-11-11 广东美芝制冷设备有限公司 旋转式压缩机及含有该旋转式压缩机的制冷设备
CN117249595A (zh) * 2016-02-16 2023-12-19 霍尼韦尔国际公司 多级低gwp空气调节系统
EP3243893B1 (en) * 2016-05-10 2023-07-19 Trane International Inc. Lubricant blends to reduce refrigerant solubility
FR3056222B1 (fr) * 2016-09-19 2020-01-10 Arkema France Composition a base de 1-chloro-3,3,3-trifluoropropene
FR3057272B1 (fr) 2016-10-10 2020-05-08 Arkema France Compositions azeotropiques a base de tetrafluoropropene
FR3057271B1 (fr) * 2016-10-10 2020-01-17 Arkema France Utilisation de compositions a base de tetrafluoropropene
EP4067454A1 (en) * 2018-01-23 2022-10-05 The Chemours Company FC, LLC Compositions, system and methods for introducing pag lubricant or refrigerant into an air conditioning or system using lower or low gwp refrigerant or refrigerant blends
US10883063B2 (en) * 2018-01-23 2021-01-05 The Chemours Company Fc, Llc Compositions, system and methods for introducing PAG lubricant or refrigerant into an air-conditioning or system using lower or low GWP refrigerant or refrigerant blends
FR3077822B1 (fr) 2018-02-15 2020-07-24 Arkema France Compositions de transfert de chaleur en remplacement du r-134a
KR20210002626A (ko) * 2018-04-30 2021-01-08 더 케무어스 컴퍼니 에프씨, 엘엘씨 안정화된 플루오로올레핀 조성물, 및 그의 제조, 저장 및 사용 방법
US10976079B2 (en) 2019-04-30 2021-04-13 Emerson Climate Technologies, Inc. Carbon dioxide refrigerant system

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Publication number Priority date Publication date Assignee Title
US4916914A (en) * 1988-05-27 1990-04-17 Cpi Engineering Services, Inc. Rotary displacement compression heat transfer systems incorporating highly fluorinated refrigerant-synthetic oil lubricant compositions
US5027606A (en) * 1988-05-27 1991-07-02 Cpi Engineering Services, Inc. Rotary displacement compression heat transfer systems incorporating highly fluorinated refrigerant-synthetic oil lubricant compositions
US6875370B2 (en) * 1996-03-05 2005-04-05 George H. Goble Drop-in Substitutes for dichlorodifluoromethane refrigerant
US6374629B1 (en) * 1999-01-25 2002-04-23 The Lubrizol Corporation Lubricant refrigerant composition for hydrofluorocarbon (HFC) refrigerants
US6880360B2 (en) * 2002-10-03 2005-04-19 York International Corporation Compressor systems for use with smokeless lubricant
US20040089839A1 (en) * 2002-10-25 2004-05-13 Honeywell International, Inc. Fluorinated alkene refrigerant compositions
PL2260231T3 (pl) * 2008-04-01 2022-01-03 Honeywell International Inc. Sposoby stosowania dwufazowych mieszanin chłodziwa-smaru w urządzeniach chłodniczych ze sprężaniem pary

Also Published As

Publication number Publication date
ES2957896T3 (es) 2024-01-29
CA2785854A1 (en) 2011-07-07
CA2785854C (en) 2017-11-28
CN102686695A (zh) 2012-09-19
US20170029680A1 (en) 2017-02-02
MX2012007563A (es) 2012-07-25
EP2519599A4 (en) 2017-05-03
US9890312B2 (en) 2018-02-13
US9481820B2 (en) 2016-11-01
WO2011082003A1 (en) 2011-07-07
CN102686695B (zh) 2016-10-26
US20120272668A1 (en) 2012-11-01
JP2013515838A (ja) 2013-05-09
JP6141019B2 (ja) 2017-06-07
EP2519599A1 (en) 2012-11-07
EP2519599B1 (en) 2023-08-23
MX345853B (es) 2017-02-17

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