MX2019007622A - Procesos de oligomerizacion de etileno. - Google Patents
Procesos de oligomerizacion de etileno.Info
- Publication number
- MX2019007622A MX2019007622A MX2019007622A MX2019007622A MX2019007622A MX 2019007622 A MX2019007622 A MX 2019007622A MX 2019007622 A MX2019007622 A MX 2019007622A MX 2019007622 A MX2019007622 A MX 2019007622A MX 2019007622 A MX2019007622 A MX 2019007622A
- Authority
- MX
- Mexico
- Prior art keywords
- range
- ethylene
- iron
- reaction zone
- iron salt
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/107—Alkenes with six carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Pyridine Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Un proceso que comprende A) introducir de forma continua en una zona de reacción i) etileno, ii) una sal de hierro, iii) una bisimina piridina, iv) un compuesto de organoaluminio, y v) un medio de reacción orgánico; y B) formar un producto oligomérico en la zona de reacción, en donde la zona de reacción tiene i) una concentración de hierro de la sal de hierro en el rango de 5 x 10-4 mmol/kg a 5 x 10-3 mmol/kg ii) una relación molar de aluminio del compuesto de organoaluminio con respecto al hierro de la sal de hierro en el rango de 300:1 a 800:1, ii) una presión parcial de etileno en el rango de 750 psig a 1200 psig, iv) una relación de masa de etileno con respecto al medio de reacción orgánico en el rango de 0.8 a 4.5, v) una temperatura en el rango de 75°C a 95°C, y opcionalmente vi) una presión parcial de hidrógeno de la menos 5 psi.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/394,411 US20180186708A1 (en) | 2016-12-29 | 2016-12-29 | Ethylene Oligomerization Processes |
| PCT/US2017/068278 WO2018125824A1 (en) | 2016-12-29 | 2017-12-22 | Ethylene oligomerization processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019007622A true MX2019007622A (es) | 2019-09-06 |
Family
ID=61003407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019007622A MX2019007622A (es) | 2016-12-29 | 2017-12-22 | Procesos de oligomerizacion de etileno. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20180186708A1 (es) |
| EP (1) | EP3562798A1 (es) |
| JP (2) | JP7093780B2 (es) |
| KR (1) | KR102558714B1 (es) |
| CN (1) | CN110099885B (es) |
| BR (1) | BR112019013276A2 (es) |
| CA (1) | CA3048416A1 (es) |
| MX (1) | MX2019007622A (es) |
| RU (1) | RU2741600C1 (es) |
| WO (1) | WO2018125824A1 (es) |
| ZA (1) | ZA201904096B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10407360B2 (en) | 2017-12-22 | 2019-09-10 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
| AR124330A1 (es) * | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
| CN114377644B (zh) * | 2022-01-13 | 2024-06-25 | 万华化学集团股份有限公司 | 一种生产α-烯烃的装置及其利用该装置制备α-烯烃的方法 |
Family Cites Families (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2020509C (en) | 1989-08-10 | 1998-04-28 | William K. Reagen | Chromium compounds and uses thereof |
| US5451645A (en) | 1989-08-10 | 1995-09-19 | Phillips Petroleum Company | Process for olefin polymerization |
| US6423848B2 (en) | 1996-12-17 | 2002-07-23 | E. I. Du Pont De Nemours And Company | Tridentate ligand |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US6417305B2 (en) | 1996-12-17 | 2002-07-09 | E. I. Du Pont De Nemours And Company | Oligomerization of ethylene |
| US6214761B1 (en) | 1996-12-17 | 2001-04-10 | E. I. Du Pont De Nemours And Company | Iron catalyst for the polymerization of olefins |
| US6432862B1 (en) | 1996-12-17 | 2002-08-13 | E. I. Du Pont De Nemours And Company | Cobalt catalysts for the polymerization of olefins |
| US6103946A (en) | 1997-07-15 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Manufacture of α-olefins |
| US6740715B2 (en) | 1997-07-15 | 2004-05-25 | E. I. Du Pont De Nemours And Company | Manufacture of alpha-olefins |
| ES2178247T3 (es) | 1997-09-05 | 2002-12-16 | Bp Chem Int Ltd | Catalizadores de polimerizacion. |
| ID27209A (id) | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| DZ2739A1 (fr) | 1998-03-12 | 2003-09-01 | Bp Chem Int Ltd | Composition de polyéthylène. |
| WO1999046303A1 (en) | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Polymerisation catalysts |
| EP1062249B1 (en) | 1998-03-12 | 2004-10-20 | BP Chemicals Limited | Polymerisation catalysts |
| GB9819847D0 (en) | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
| US6545108B1 (en) | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
| CA2363628A1 (en) | 1999-02-22 | 2000-08-31 | James Allen Ponasik Jr. | Catalysts containing n-pyrrolyl substituted nitrogen donors |
| US6291733B1 (en) | 1999-06-02 | 2001-09-18 | Chevron Chemical Company Llc | Process for dimerizing olefins |
| US6458905B1 (en) | 1999-08-16 | 2002-10-01 | Phillips Petroleum Company | Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts |
| WO2001036379A1 (fr) | 1999-11-11 | 2001-05-25 | Idemitsu Petrochemical Co., Ltd. | Compose de metal de transition, catalyseur pour la polymerisation d'olefines et procede de polymerisation d'olefines |
| US6710006B2 (en) | 2000-02-09 | 2004-03-23 | Shell Oil Company | Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins |
| US6621166B2 (en) | 2000-05-19 | 2003-09-16 | International Rectifier Corporation | Five layer adhesive/insulator/metal/insulator/adhesive tape for semiconductor die packaging |
| GC0000291A (en) | 2000-06-30 | 2006-11-01 | Shell Int Research | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
| US6555723B2 (en) | 2000-07-18 | 2003-04-29 | E. I. Du Pont De Nemours And Company | Continuous manufacturing process for alpha-olefins |
| US6534691B2 (en) | 2000-07-18 | 2003-03-18 | E. I. Du Pont De Nemours And Company | Manufacturing process for α-olefins |
| US7223893B2 (en) | 2000-09-12 | 2007-05-29 | Chevron Phillips Chemical Company Lp | Linear alpha-olefin dimers possessing substantial linearity |
| US7037988B2 (en) | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
| ATE344268T1 (de) | 2001-08-01 | 2006-11-15 | Shell Int Research | Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen |
| RU2194056C1 (ru) * | 2001-09-25 | 2002-12-10 | Институт катализа им. Г.К. Борескова СО РАН | Катализатор полимеризации этилена на основе бис(имино)пиридильных комплексов |
| US6911506B2 (en) | 2001-12-10 | 2005-06-28 | Chevron Phillips Chemical Company Lp | Catalyst composition and olefin polymerization using same |
| US7053259B2 (en) * | 2002-09-17 | 2006-05-30 | E. I. Du Pont De Nemours And Company | Process of producing α-olefins |
| RU2315658C2 (ru) | 2002-09-25 | 2008-01-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Каталитические системы для олигомеризации этилена в линейные альфа-олефины |
| US6911505B2 (en) | 2002-10-04 | 2005-06-28 | Chevron Phillips Chemical Company, Lp | Selective isomerization and linear dimerization of olefins using cobalt catalysts |
| US7001964B2 (en) | 2002-10-04 | 2006-02-21 | Chevron Phillips Chemical Company, Lp | Selective isomerization and linear dimerization of olefins using cobalt catalysts |
| US7045632B2 (en) | 2003-03-04 | 2006-05-16 | Chevron Phillips Chemical Company, Lp | Composition and method for a hexadentate ligand and bimetallic complex for polymerization of olefins |
| US20050014983A1 (en) | 2003-07-07 | 2005-01-20 | De Boer Eric Johannes Maria | Process for producing linear alpha olefins |
| US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| WO2006010065A2 (en) | 2004-07-09 | 2006-01-26 | E.I. Dupont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| US7456284B2 (en) | 2004-12-10 | 2008-11-25 | Chevron Phillips Chemical Company Lp | Methods for producing a hexadentate bimetallic complex |
| US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7129304B1 (en) | 2005-07-21 | 2006-10-31 | Chevron Phillips Chemical Company Lp | Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US20070221608A1 (en) | 2006-03-27 | 2007-09-27 | Graham Packaging Company, Lp. | Handle and finish attachment for a container |
| US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| CA2736590A1 (en) | 2008-10-31 | 2010-05-06 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system and process for oligomerizing olefins |
| US8471085B2 (en) | 2008-10-31 | 2013-06-25 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system and process for oligomerizing olefins |
| US8916664B2 (en) | 2010-03-29 | 2014-12-23 | E I Du Pont De Nemours And Company | Olefin polymerization process |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| FR2986717B1 (fr) * | 2012-02-10 | 2014-08-08 | IFP Energies Nouvelles | Composition catalytique et procede d'oligomerisation des olefines utilisant ladite composition catalytique |
| CN104418690B (zh) | 2013-08-23 | 2016-05-25 | 中国石油化工股份有限公司 | 一种乙烯齐聚的方法 |
| US9505675B2 (en) * | 2015-02-09 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Deactivation of a process by-product |
| CN104961618B (zh) * | 2015-06-12 | 2017-07-11 | 浙江大学 | 一种抑制乙烯齐聚反应中聚乙烯蜡生成的方法 |
| CN105884565A (zh) * | 2016-05-23 | 2016-08-24 | 浙江大学 | 一种提高线性α-烯烃产率的方法 |
-
2016
- 2016-12-29 US US15/394,411 patent/US20180186708A1/en not_active Abandoned
-
2017
- 2017-12-22 RU RU2019120149A patent/RU2741600C1/ru active
- 2017-12-22 WO PCT/US2017/068278 patent/WO2018125824A1/en unknown
- 2017-12-22 BR BR112019013276A patent/BR112019013276A2/pt not_active Application Discontinuation
- 2017-12-22 CA CA3048416A patent/CA3048416A1/en active Pending
- 2017-12-22 EP EP17832163.4A patent/EP3562798A1/en active Pending
- 2017-12-22 JP JP2019534964A patent/JP7093780B2/ja active Active
- 2017-12-22 CN CN201780080623.6A patent/CN110099885B/zh active Active
- 2017-12-22 KR KR1020197018775A patent/KR102558714B1/ko active IP Right Grant
- 2017-12-22 MX MX2019007622A patent/MX2019007622A/es unknown
-
2019
- 2019-06-24 ZA ZA2019/04096A patent/ZA201904096B/en unknown
-
2021
- 2021-03-26 US US17/213,638 patent/US11358914B2/en active Active
-
2022
- 2022-04-08 JP JP2022064422A patent/JP2022105017A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP3562798A1 (en) | 2019-11-06 |
| US20180186708A1 (en) | 2018-07-05 |
| CN110099885A (zh) | 2019-08-06 |
| JP7093780B2 (ja) | 2022-06-30 |
| ZA201904096B (en) | 2020-12-23 |
| JP2022105017A (ja) | 2022-07-12 |
| KR20190100214A (ko) | 2019-08-28 |
| US11358914B2 (en) | 2022-06-14 |
| KR102558714B1 (ko) | 2023-07-21 |
| CA3048416A1 (en) | 2018-07-05 |
| CN110099885B (zh) | 2022-07-22 |
| BR112019013276A2 (pt) | 2019-12-17 |
| JP2020504750A (ja) | 2020-02-13 |
| RU2741600C1 (ru) | 2021-01-27 |
| US20210214289A1 (en) | 2021-07-15 |
| WO2018125824A1 (en) | 2018-07-05 |
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