MX2014015534A - Reactive dyes and their metal complexes, process for the production thereof and their use. - Google Patents

Abstract

The present invention refers to dyes of the formula (I) and mixtures thereof, in which n, A, B and K are defined as given in claim, a process for preparing them, and their use for dyeing and printing hydroxyl-, amino-, and/or carboxamido-containing materials.

Description

REACTIVE DYES AND THEIR COMPLEX PROCESSES FOR THEIR PRODUCTION AND USE The present invention relates to the technical field of reactive dyes and their metal complexes for the dyeing and printing of amino-containing material and the reactive dyes of metal complexes based on the rest bis and polyazo containing at least one anchor are known from the prior art and can be used as dyes in different documents DE3519551 and In the context of the dyeing and printing of amino-containing material the known dyes have a number of technical disadvantages such as low moderate moisture fastness and resistance level there is a need to develop new higher performance reactive dyes now it was found that the dyes of the formula as described below show very advantageous properties with respect to the dyes they include a superior Moisture resistance and resistance to the superior profile as well as the possibility of achieving a wide range of shades including dark blue brown violets and The present invention relates to dyes of the formula and their mixtures wherein h is an integer 0 or K is a radical of coupling heterocielic component as described further A is a radical of the average component as described below when n is 1 and has the meaning of B when n is B is a radical of diazo component as described further M is ammonium or an equivalent of an alkaline earth metal or an organic cation K is a coupling component of the following general formulas a wherein R1 and independently between are monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylureide and R5 and independently between are methylsulfonyl or R6 to R9 and each other are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are their alkyl is substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or alkyl or substituted aryl wherein X is vinyl or a radical where Y is a removable group under alkaline conditions that will leave the molecule in alkaline conditions to obtain the function of of such groups are OPO3M and and R10 is hydroxyl or group and in the general formula the point of attachment and R5 can be located ortho or para for the amino moiety bearing the R6 substituents and what it means when the point of attachment is located in ortho position with respect to the amino moiety carrying the substituents R6 and R5 is located in position for the me and K is a coupling component of the following general formulas a wherein T is a reactive anchor of the general formulas a wherein R24y independently between are halogen or independent between or each of R24 a independently between are substituted with one of the groups selected from the general formulas a wherein R339 and independently are phenyl or phenyl substituted with one of the group selected from halogen or heterocycloalkylamino or O are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or each of R34 and independently between are S03M or where M is lithium or X is vinyl or a radical where Y is a removable group under alkaline conditions such as OPO3M op is an integer of 1 at 5 R13 and independently between are monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylureide or R16 and independently between are methylsulfonyl or R independently between are heterocycloalkylamino or are alkyl interrupted by one or several heteroatoms such as oxygen or are alkyl substituted with one or several substitutes Hearers selected from the group that consists of monoarylsulphamoyl or R21 is hydroxyl or group and in the general formula the point of R16 can be located in ortho position for the amino moiety bearing the substituents R17 and what it means when the point of attachment is located in the ortho position of the amino moiety bearing the substituents R.sub.17 and is located in position with respect to those and A is the average phenylene or naptylene component and has the general formula or 346 341 342 RRRR R344 48 a independently between are alkyl chain interrupted by one or two or are alkyl substituted with one or more substituents selected from the group consisting of or are alkyl interrupted by one or more heteroatoms such as oxygen or alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfonyl or a group of formulas at 349 323 325 327 324 RR where and R350 independently of each other alkyl substituted with alkyl chain interru is defined by one or two heteroatoms or where T has the same meaning as U is or R327 and independently between are alkyl substituted with alkyl chain interrupted by one or two independently between are alkyl or alkyl chain interrupted by one or two r is an integer of 0 as is an integer of 1 a refers to point of union with Al or A2 refers to point of union with TT has the meaning of B is the component diazo and has one of the general formula wherein R 4035 to 351 and independently between are hydrogen or S02X or amino substituted with one of the general formulas at 330 NRN 33 NR 332 where V is or R47 and independently between are alkyl substituted with alkyl chain interrupted by one or two R46 and independently between are alkyl or alkyl chain interrupted by one or two R330 a independently between are a group of the formula 336 337 R336 and independently are heterocycloalkylamino or hydroxyalkylsulfonylalkyl or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or alkyl interrupted by one or more heteroatoms such as oxygen or containing a residue with free valency for linking it to the rest of reactive anchor R334 and independently of each other are alkyl or alkyl substituted with hydroxy c is an integer of 0 ad is an integer of 1 a refers to point of attachment with B1 and refers to point of attachment refers to the point of union with T and X are as defined with ammonium or an equivalent of an alkaline earth metal or an organic cation With ammonium or an equivalent of a metal with preference potassium or with the general condition that the tinctures of the formula General Contain At Least One Anchor The present invention relates to all types of tautomeric and geometric isomers of the dyes of the formula The alkyl groups appearing in this application can be straight-chain or can have 12 C atoms and preferably with hexyl and the same logic applies to alkoxy groups because they are methoxy and the cycloalkyl groups are cycloalkyl groups with cycloalkyl with particular cyclopentyl and The term cycloalkyl comprises for the purposes of the present application substituted cycloalkyl groups and also cycloalkyl groups A preferred group of this type is Preferred substituents are mono bis alkoxycarbonyl or Substituents of particular preference ureido or The groups alkenyl can be straight chain or branched and vinyl and The term alkenyl also comprises for the purposes of the present application groups for ethynyl and heterocycloalkyl groups with morpholine or aryl groups that appear in this application are phenyl or the terms phenyl and naphthyl It comprises phenyl and naphthyl not so preferred substituents are n mono alkoxycarbonyl bis or substituents particularly preferably ureido or halogen bromine or with chlorine or bromine with chlorine preference and preferred embodiments of the present invention are dyes of the formulas a and Sus wherein R78 and independently of each other are trifluoromethyl amino monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylsulfonylated alkylureide or R75 and independently from each other are methylsulfonyl or R60 and R68 independently from each other are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or several substituents selected from the group consisting of monoarylsulphamoyl or R83 and independently from each other are hydrogen or R86 and R87 independently of one another are alkyl or alkyl substituted with hydroxy or 1 independently from alkyl alkyl chain interrupted by one or two alkoxy heteroat cycloalkyl alkylcarbonyl acylaryl or a group of the formulas a as defined by In the dyes of special preference of the present R78 and are hydrogen or alkyl or R75 and R79 are alkoxy or R60 and R68 are alkyl or aryl substituted with one or more substituents selected from Halogen or to R69 to R71 and R80 to independently between are alkyl-haloalkoxy-halogen or or contain a group of the formulas at R86 and R87 independently of each other are alkyl or alkyl substituted with R88 R89 independently among are alkyl substituted with X and M are as defined by other preferred embodiments of the present invention are tinctures of the formulas and and theirs wherein R 90 and independently of each are monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylureide and independently between are carbonyltrifor and independently between are heterocycloalkylamino or are alkyl interrupted by one or several such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or R99 and independently between are hydrogen or R102 independently of each other are alkyl or alkyl substituted with hydroxy or R96 a independently between are Alkyl alkyl chain interrupted by one or two alkoxy sulfa or a group of the formulas a as defined as long as and D2 contain a free valence moiety to bind it to the reactive anchor moiety T and M are as defined with In the dyes especially preferred of the formula and R 90 and so is hydrogen or alkyl or and so is alkoxy or D 1 and so is alkyl or alkyl or aryl substituted with one or more substituents selected from halogen or R96 a independently from each other are alkyl halogen alkoxy or oo contain a group of the formulas a and R102 independently whether they are alkyl or substituted alkyl with X and M are as defined Other preferred embodiments of the present invention are dyes of the formulas a and Su 106 O 107 RR M03S SO3M wherein R115 and independently are monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of heteroaryl alkylureide or R116 and independently between are methylsulfonyl or R117 and independently between are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or R129 and independently between are hydrogen or NHC OR and R independently between are alkyl or alkyl substituted with hydroxy or R120 and R126 a independently between are alkyl alkyl chain interrupted by one or two alkoxy or a group of the formulas at E4 to independently between are a the general formulas In the tincture s of special preference of this R115 and independently between is hydrogen or alkyl or R116 and independently between is alkoxy O and independently between is alkyl or aryl substituted with one or more substituents selected from halogen or R120 and independently from each other are haloalkyl halogen alkyl or they contain a group of the formulas at R129 and independently from each other are hydrogen or R131 and independently from each other are alkyl or alkyl substituted with E4 a independently between are a group of the general formulas to X and M are as were defined with another preferred embodiment of the present invention are dyes of the formulas a and their OT 136 i R 148 R R156 where and independently between are monocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of alkylureide or R144 and independently between are methylsulfonyl or D5 and D6 independently between are interrupted alkyl or p or one or more heteroatoms such as oxygen or alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or R155 and independently between are hydrogen or NHC O and independently between are alkyl or hydroxy substituted alkyl and so independent among are alkyl alkyl chain interrupted by one or two alkoxy cycloalkyl alkylcarbonyl or contain a group of the formulas a as defined in E8 a independently between are a the general formulas as defined in X and are as defined in the dyes of special preference of the formulas to R143 and independently between is hydrogen or alkyl or R144 and independently between is alkoxy or D5 and independently between is alkyl or alkyl or substituted aryl with one or more substituents selected from halogen or amino group substituted with R155 and independently from each other are hydrogen or R145 to R147 and R152 a independently from are alkyl halogenalkoxy or contain a group of the formulas at E8 a independently between are a group of the general formulas at X and M are as defined by other preferred embodiments of the present invention are tinctures of the formulas a and their 4 170 171 RR wherein each of R175 and independently are trifluoromethyltrifethylsulfonyl or R176 and is hydroxyl or R163 aa R172 R177 aya independently of each other are carbamoyl heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or alkyl or substituted aryl wherein X is vinyl or a radical wherein Y is a removable group under alkaline conditions such as or a rest with free valency to link it with the reactive anchor R193 and independently between are hydrogen or NH C or R195 and independently between are alkyl or alkyl substituted with hydroxy or R180 to R182 and R190 a independently between are alkyl alkyl chain interrupted by one or two alkoxy alkylcarbonyl or contain a group of the formulas to X is as In the dyes of special preference herein and R185 are alkyl alkoxycarbonyl or R176 and R186 are hydroxyl or R163 to R170 to R177 to R179 and R187 to each other are independently alkyl or free valence substituted with R193 and independently of each other are alkyl halogen alkoxy or R180 to R182 and R190 a independently between are haloalkyl alkyl halogen or contain the group of the formulas X and M have the same meaning as other preferred embodiments of the present invention are tinctures of the formulas a and 0 201 R 202 215 216 R213 and independently between are methylsulfonyl or and R224 independently between hydroxyl or R208 to R215 to R217 and R225 a independently between are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of carbamoyl monoaryl monoarylsulfamollo or alkyl or substituted aryl where X is vinyl or a radical where Y is a removable group in alkaline conditions such as or contains a free valence moiety to bind it to the reactive anchor residue R231 and independently from each other are hydrogen or NHC O R233 and independently from each other are alkyl or alkyl substituted with hydroxy or R218 to R220 and R228 a independently of each other are alkyl alkyl chain interrupted by one or two alkoxy or a group of the formulas a as defined with E12 a independently between are a group of the general formulas a as defined with X and have the same meanings In the dyes of special preference hereof independently between are alkyl alkoxycarbonyl and so independently of whether they are hydroxyl or R208 aa R217 and R225 independently of each other are alkyl alkyl or free valence substituted with and independently from each other are alkyl halogenalkoxy or R218 to R220 and R228 a independently from each other are haloalkyl or halogen alkyl they contain the group of the formulas at E12 a independently between are a group of the general formulas at T and X have the same meanings. Other preferred embodiments of the present invention are dyes of the formulas a and their 240 R 238VR 243 242 PRI wherein R253 and independently are monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylureide or R254 and independently between are methylsulfonyl or R239 to R247 a to R258 and R267 to independently are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with n one or more substituents selected from the group consisting of sulphamoyl monoarylsulphamoyl or alkyl COO which contains a free valence moiety for ligating it to the reactive anchor moiety R274 and independently between are hydrogen or NHC O R276 and independently between are alkyl or alkyl substituted with hydroxy or R 259 a and R 271 a independently between are alkyl alkyl chain interrupted by one or two alkoxy alkylcarbonyl or contain a group of the formulas a as defined With the dyes of special preference of the formulas a R 253 and R 264 are hydrogen or alkyl alkyl R 254 and R 265 are alkoxycarbonyl alkyl or independently of are alkyl or aryl alkyl substituted with one or more groups selected from the free valence substituted with R274 and independently between are haloalkyl halogen alkyl or R259 to R261 and R271 a independently between are alkoxyl halogen alkyl or they contain the group of the formulas to X and M has the same meanings as defined with preferred embodiments of the present invention are dyes of the formulas a and their 282 283 RR IM 286 RRN 284 0 280 R MO3S SO3M 305 R 30 R M03S SO3M 316 R S03M wherein R296 and independently are between trifluoro monocycloalkyl or are alkyl substituted with one or more substituents selected from the group consisting of alkylureido or R297 and independently between are methylsulfonyl or R282 to R290 to R298 and R309 to independently are heterocycloalkylamino or are alkyl interrupted by one or more heteroatoms such as oxygen or are alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or alkyl containing a free valence moiety to bind it to the reactive anchor moiety R316 and independently between are hydrogen or R318 and independently between are alkyl or alkyl substituted with hydroxy or R302 to R304 and R313 a independently between are alkyl alkyl chain interrupted by one or two alkoxy COOM or contain a group of the formulas a as defined with E16 a independently between are a group of the general formulas a as defined with X and M have the same meanings as previously defined In the dyes of particular preference of the present R296 and R307 independently between hydrogen or alkyl alkyl and independently between alkyl alkoxy carbonyl or R282 to R290 to R298 to R301 and R309 to independently between are alkyl or aryl alkyl substituted with one or more selected groups of free or substituted valence with R286 R305 R306 R316 317 and independently between are haloalkyl halogen alkyl or R302 to R304 and R313 a independently between are haloalkyl halogen alkyl or contain the group of the formulas a E 16 a independently between are a group of the general formulas to X and M are as defined with The examples of pre-dyes The dyes of this invention are dyes from 1 to 168 to the general formula wherein K7 is a heterocyclic coupling component radical and has the same meaning as that described above for 5 A3 is a radical of average component and has the same meaning that the one described above for B3 is a radical of diazo component and has the same meaning as described previously for M is lithium or Table 1 29 ot g ot 5 02 SI 99 OI L9 z SI OI 89 sz QZ OI 02 VL oe Z ot V ZL 03 s 5 L zz SI OI s OZ OI 9 9 L oz YES OI s LL 9Z 9 8 L 6 L 82 02 s 08 28 oe OI 9 98 5i OI L 8 OI 5 68 06 QZ YES ot s 26 oe OI 9 OI 5 oe 92 02 9 oe YES Y 86 66 92 02 9 OI 5 OI eot ot 9 02 yes s SOI 02 ot V 02 YES YES 601 02 91 01 9 III Vt 9 zti 02 9 OI 9 I LXX oe 02 02 6 it en en 52 02 YES S 02 S Further examples of the preferred dyes of this invention are the dyes from 169 to 336 corresponding to the general formula wherein K8 is a radical of the heterocyclic coupling component. ielico and has the same meaning as before for A4 is one of the middle component and has the same meaning as before for B4 is a radical of the diazo component and has the same meaning as before for M is lithium or Table 2 oi SI OI s 6ZI 02 9 oet Vt OI eei otes oz OI V Vet 02 YES Oe s oe oz OI s on 02 ot 9 OI zt 02 OI eh 02 5 ot 5 oz V oi V 9 OI 9 oe 93 OI oe 92 02 ot 9 tVt 02 9 Vt ot oe 92 02 9 03 YES s 8SI oz OI 5 651 02 O? 9 YES s Z9? Vt oi V ot ot s oe V SI OI Vt ot 02 LLL Vt s 02 081 oz ot 9 OI S2 YES OI S oe 02 5 oe zs 081 s 02 Vt ots oe Vt ot V oe oi V oe 02 9 Vt OI s The present invention also provides a process for the preparation of the dyes of the formula comprising diazotization of the compounds of the formulas and reaction of the diazonium salts correspondingly obtained with a compound of the formula K to obtain the intermediate of the general formula In In another step, the diazo component is diazotized and is coupled to intermediate V to obtain the bisazo of the general formula. Thus, the diazo component can be diazotized and coupled with the compound to obtain the intermediate. The intermediate is diazotized and is coupled with the compound for obtain the trisazo tincture of the general formula tinctures and they are reacted with copper salt, especially copper sulfate, to obtain copper complex dyes and where B and K have the same meaning as that described with L to diazotization of the compounds of the formulas and can be carried out by means of diazotization methods which are known to one skilled in the art using sodium nitrite or nitrosylsulfuric acid in acid medium using inorganic acids such as sulfuric acid or acid phosphoric acid or mixtures thereof or organic acids such as acetic acid propionic acid or its mixtures Mixtures of inorganic acid with acids can also be advantageously used The coupling reaction of the diazotized compounds of the formulas and with it the formula can also be carried out by methods The complexing reaction of the dyes and likewise can be carried out by known methods. The compounds of the formula B and K are known and commercially available or can be synthesized by means of common chemical reactions known to an expert in the art. present invention also provides the use of dyes of the present invention to dye or print amino carboxamide-containing material or a process for dyeing or printing hydroxyl carboxamide-containing material wherein a dye is applied to the material and fixed to the material by means where the process uses a dye according to the present. The hydroxyl-containing materials may be of natural origin or the examples are 0-fiber materials with jute and fibers of regenerated cellulose fibers such with basic viscose and viscose in cellulose fibers chemically such by cellulose fibers aminated and 5 also alcohols Materials that contain carboxami by synthetic polyamides and polyurethanes and by wool and other hairs and the above-mentioned hydroxyl carboxamide-containing materials may be present in various forms in the form of type structures such as paper and in the form of such nylon or in the form of a mass a by composed of polyamide and in particular in the form of fibers The fibers with fibers by in the form of woven fabrics or yarns or in the form of skeins or packages The tinctures of the present invention and their salts or mixtures can be used as a dyed product only in dyeing or printing processes or can be part of a combined product of three or several components in dyeing compositions or dyes of this invention and its salts or mixtures are very compatible with other known dyes available in shops and can be used together with such dyes to obtain specific tones of similar technical performance. Technical performance includes strength properties and dyes according to the invention can be applied to materials especially fibrous materials by known application techniques for dyes soluble in dyes. This applies to both dyeing and dyeing processes. It is applied in particular to the production of dyes in fibrous materials composed of wool or other natural polyamides or synthetic polyamides and their mixtures with other material In the material to be dyed is introduced into the bath at a temperature of about 40 is stirred during some staining bath then adjusted to slightly acid with acetic acid pH and the Real staining is carried out at a temperature between 60 and 98. Without staining it can also be carried out in boiling or in sealed staining apparatus at temperatures of up to 106. Although the water solubility of the stains according to the invention is very also can be used advantageously in continuous dyeing processes The dyes of the present invention also n can be used in printing processes in particular in textile printing For the dyes of the present invention need to be formulated in aqueous inks for digital printing comprising a dye according to the present invention likewise form part of the subject of the present inks of the present invention comprise the dyeing of the present invention in amounts that with the weight of the in with greater than by weight by weight and with maximum by weight in in based on the total weight of the Las as well as the tincture of the present may be if other dyes used in printing For the inks of the present invention for use in the flow process a conductivity of a 25 can be set by adding a useful electrolytes by lithium nitrate and nitrate The inks of the present invention may include organic solvents at a total level of with in the appropriate organic solvents for alcohol alcohols for alkylene glycols having 1 to 8 groups by lower alkyl ethers of alcohols ethylene glycol monomethyl ethylene glycol monoethyl ethylene glycol monobutyl diethylene glycol monomethyl diethylene glycol monoethyl diethylene glycol monobutyl diethylene glycol monohexyl triethylene glycol monomethyl triethylene glycol monobutyl tripropylene glycol monomethyl tetraethylene glycol monomethyl tetraethylene glycol monobutyl tetraethylene glycol dimethyl propylene glycol monomethyl glycol monoethyl glycol monobutyl isopropyl tripropylene polyalkylene glycol such by monomethyl polyethylene glycol polypropylene glycol polyethylene glycol glycerol tridecyl polyethyleneglycol nonylphenyl such derivatives of such by ketones or such by alcohol ethers such by gamma alcohol plus ethylpentyl ether acetate of and The inks of the invention may also include additives by moderators of viscosity at fixed viscosities in the range of a mPas over a range of temperatures from 20 to 50 Preferred inks have a viscosity of 20 mPas and the inks of particular preference are They have a viscosity of 15 The viscosity moderators of utility include additives for polyvinyl pyrrolidone and their copolymers thickeners alginates of galactomannanos cellulose ethers no As other inks of the invention may include surfactants to fix surface tensions of 20 to 65 which are adapted from be necessary depending on the thermal process used or Useful surfactants include all those with non-hexanediol surfactants The inks of the present invention may also include additives for substances to inhibit the growth of fungi and bacteria in amounts of a by weight based on The total weight of the inks can be prepared in a conventional manner by mixing the components in the inks of the invention are particularly useful in inkjet printing processes to print a wide variety of materials such as polyamide fibers and polyurethanes and fibrous materials cellulosic cu alquier Woven fabrics by blends of wool with polyester fibers or polyamide fibers can be printed in the opposite way to the printing of textiles where the printing ink already contains all the chemicals in digital or jet printing of the auxiliaries should be applied to the textile substrate in a pretreatment stage The pretreatment of the substrate by cellulose and regenerated cellulose fibers and also silk and is carried out with an aqueous alkaline liquor before there is a need for thickeners to prevent the flow of the motives when the ink is applied by alginates of modified polyacrylates or highly etherified galactomannants These pretreatment reagents are uniformly applied to the textile substrate in a defined amount using applicators by using a pad with 2 or 3 spray technologies without using foam or using ink jet technologies. appropriately adapted and subsequently The following examples serve to illustrate the The parts and percentages are in unless otherwise noted The ratio between parts by weight and parts by volume is that of kilogram a Synthesis procedure for Example 1 parts of disulfonic acid were dissolved in 50 parts of The reaction vessel was cooled to 0 to 5 using a mixture of After 10 parts of hydrochloric acid were added to the reaction mixture. The reaction mixture was stirred for 1 to 2 After completing portions of sulfamic acid were added into the mixture. parts of the coupling component were suspended in 50 parts of The pH was adjusted to The diazo component was The reaction mixture was stirred for 2 parts after the product was obtained by addition of salt followed by parts of sulfatoethyl were suspended in 50 parts of water The reaction vessel was cooled to 0-5 using a mixture of hydrochloric acid. parts of sodium nitrite solution were added in the The reaction mixture was stirred for 1 to 2 After completing parts of sulfamic acid were added in the mixture of coupler parts were dissolved in 50 parts of A this diazo component was added dropwise during 1 The reaction mixture was stirred for 2 hrs After parts of Example 3 were obtained by addition of salt and followed by parts of the dye were dissolved in 50 parts of water and the pH was adjusted to slightly parts of copper sulphate and parts of sodium acetate were added in The mixture of the reaction mixture was heated to 100 for 1 After the example, it was obtained in portions by addition of salt followed by filtration to SO 3 H SO 3 H OSO 3 H 3 os O OSO 3 H 3 Dyeing example 1 2 parts of a dye obtained according to the formula and 50 parts of sodium chloride were dissolved in 999 parts of water and 5 parts of sodium carbonate and 1 part of an agent were added to this dye bath they added 100 parts of a cotton cloth. emperature of the dye bath was increased to 30 and kept for 30 the temperature of the dye bath was increased to 60 and maintained for 60 mins after the dyed fabric was rinsed initially with it dyed fabric was neutralized using 1000 parts of a aqueous solution containing 1 part of acetic acid to and heated to 50 for 30 to 40 The dyed fabric was rinsed with water to 70 and then soaped to boiling with the laundry detergent for 30 to 40 minutes and then rinsed again in water and dyeing Example 2 1 part of the tincture of the formula was dissolved in 2000 parts of water and heated to 80 for 20 minutes and 1 part of an agent was added The pH was then adjusted to using acetic acid and 100 parts of woolen fabric were placed in the bath The dye bath was heated up to 40 for 15 The temperature was raised to 98 and kept at 98 for 90 then the staining was reduced to 60 and the tissue was removed from the bath The dyed fabric was washed with water and dyeing Example 3 1 part of the tincture of the formula was dissolved in 2000 parts of water and 1 part of a base leveling agent of a condensation product of a Upper aliphatic amine and oxide of and 6 parts of sodium acetate were The pH was then adjusted to 5 using acetic acid The dye bath was heated to 50 for 10 minutes and then mixed with 100 parts of a woven cloth of the it rose to 110 over the course of 50 minutes and then the dyeing was reduced cooling to 60 and the material was removed The polyamide fabric was washed with hot water and soaped and stained. Example 4 A textile fabric consisting of mercerized cotton was covered with a liquor containing 35 calcium carbonate and 100 of urea and 150 of a low viscosity sodium alginate solution and then the extraction of the liquor was of The textile thus pretreated was printed with an aqueous ink containing the dye from Mergal K9N example and from water using a drip ink jet print head on demand. The print was dried by Se by means of saturated stream at 102 for 8 minutes. The print was then rinsed in was subjected to a washing of solidity with hot water to 95. Again it was rinsed with hot water and then insufficientOCRQuality

Claims (1)

1. CLAIMS 1. Chemical compound according to the formula (I) (l) where n is an integer 0 or 1; K is a heterocyclic coupling component radical as described below; A is a radical of the middle component as described below when n is 1 and has the meaning of · B when n is 0; B is a radical of diazo component as described below; M is hydrogen, sodium, potassium, lithium or ammonium; K is a coupling component of the following general formulas (Kl) to (K3); (K1) (K2) (K3) where, R1 and R4, independently of each other, are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, monocycloalkylamino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoaryl-amino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido and phenylureido; R2, R5 and R11, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -S03M; R3 'R6 to R9 and R12, independently of one another are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl- Carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, -aryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N- monoalkylsulfamoyl, N, N- dicycloalkylsulphamoyl, N, N-dialkyl sulfamollo, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoaryl-sulphamoyl, amino, N-acylamino, N- thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogeno, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocyloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N- monoalkylcarbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N- monocarilcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkyl-sulfamoyl N-monoalkyl sulfamollo, N, N-dicycloalkyl-sulfamoyl, N, N-dialkyl-sulfame, L, N-monoaryl-sulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl- N-monoarylsulphamoyl or -SO3M; or rent or or alkyl or aryl substituted with -S02X; wherein X is vinyl or a radical -CH2CH2-Y, where Y is a group that is removable under alkaline conditions such as OSO3M; Y R10 is hydroxyl or amino group; wherein, in the general formula K2, the point of attachment and R5 can be located in position ortho or for the amino moiety bearing the substituents R6 and R7, which means that, when the point of attachment is located in the ortho position with respect to the amino moiety carrying the substituents R6 and R7, R5 is located in position for them, and vice versa, or K is a coupling component of the following general formulas (K4) to (K6); where T is a reactive anchor of the general formulas (TI) to (T3); (T1) (T2) (T3) where R24 and R25, independently of each other, are halogen or R26 to R30 independently of each other, are halogen; or each of R24 to R30, independently of each other, are substituted with one of the selected groups of the general formulas (la) to (le); (1a) (1b) (1c) where R31, R32, R339 and R340, independently of one another, are hydrogen, alkyl, phenyl or phenyl substituted with one of the group selected from alkyl, alkoxy, halogen or -SO3M; alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkylcarba oyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N , N-diaryl-carbamoyl, .N- monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamollo, N, N-dicycloalkylsulfamoyl, N, N-dialkyl -sulfamollo, N- monoaryl-sulfamollo, N, N-diaryl-sulphamoyl, N-monocycloalkyl-N-monoarylsulfamene, N-monoalkyl-N- monoaryl-sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido , phenylureido, N-5 monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N- Heterocycloalkylamino or 0-hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino ,. ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl carbamoyl, sulfamoyl, N-monocycloalkyl sulfamollo, N-monoalkylsulfamollo, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoarylsulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoaryl sulfamoyl , N-monoalkyl-N-monoarylsulphamoyl or SO3M; R33, R34 and R338, independently of each other, are hydrogen, alkyl, alkoxy, halogen, trifluoromethyl, cyano, nitro, ester, carbamoyl, S03M or -S02X; where · M is hydrogen, sodium, potassium, lithium or ammonium; X is vinyl or a radical -CH2CH2-Y, where Y is a removable group under alkaline conditions such as 0S03, · SSO3M, OCOCH3, OPO3M or halogen; p is an integer from 1 to 5 R13 and. R15, independently of each other, are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, monocycloalkylamino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoaryl-amino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R12, R16 and R22, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or - S03M; R14, R17 to R20 and R23, independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkylcarbamoyl, N-monoalkyl carbamoyl, N, N- dicycloalkyl carbamoyl, N, -dialkylcarbamoyl, N-monoarylcarbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfamollo, N -monoalkyl sulphonyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-onoaryl-sulphamoyl, N, N-diaryl-sulfamyl, N-monocycloalkyl-N-monoalkylsulfamoyl, N-monoalkyl-N-monoaryl-sulphamoyl , amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N -monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulphamoyl, N-monocycloalkyl-sulphamoyl, N-phenyalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamollo, N- monoarylsulphamoyl, N, N-diarylsulfamollo, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulphamoyl or S03M; R21 is hydroxyl or amino group; and wherein, in the general formula K5, the junction point and R16 can be located ortho or for the amino moiety bearing the substituents R17 and -R18, which means that, when the junction point is located in position ortho to the amino moiety bearing the substituents it is placed in position for them, and vice versa, A is the middle component of phenylene or naptylene and has the general formula (Al) or (A2); (A1) (A2) R341 to R3, independently of each other, are hydrogen, alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, ureido, alkylureido, S03M, COOM; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkyl-a, N, N-dialkylamino, N-monoaryl-amino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-mono-alkyl-carbamoyl, N- monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl- carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamollo, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfame Ilo, N-monoarylsulphamoyl, N, N-diaryl-sulfamoyl, N- monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulphamoyl or S03M; or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N- monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoarylcarbamoyl, N, li diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl- carbamoyl, sulfamoyl, N-monocycloalkyl sulfamollo, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-monoarylsulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl-N-monoarylsulfamollo or SO3M; or alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or a group of the formulas (2a) to (2c) 323 325 328 R 2 C wherein R49 and R350 independently of each other, hydrogen, alkyl, alkyl substituted with S03M, alkyl chain interrupted by one or two heteroatoms or T; where T has the same meaning as before; U is -O-, -S- or -N (R329) R323, R327 and R329, independently of each other, are hydrogen, alkyl, alkyl substituted with S03M, alkyl chain interrupted by one or two heteroatoms; R324, R325, R326 and R328, independently of one another, are hydrogen, alkyl or alkyl chain interrupted by one or two heteroatoms; r is an integer from 0 to 6; s is an integer from 1 to 6; ** refers to point of union with Al or A2 *** refers to point of union with T T has the meaning of before; B is the diazo component and has one of the general formula (Bl) or (B2); where R35 to R40 and R351 independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -SO3M, trifluoromethyl, nitro, ester, NHC (O) R41, CONH2, S (O) 2R42, -S02X or substituted amino with T or one of the general formulas (El) to (E3); . 0 (E2) (E3) where V is -O-, -S- or -N (R352) -R43, R47 and R352, independently of each other, are hydrogen, alkyl, alkyl substituted with S03M, alkyl chain interrupted by one or two heteroatoms; R44, R45, R46 and R48, independently of each other, are hydrogen, alkyl or alkyl chain interrupted by one or two heteroatoms; R330 to R333, independently of one another, are hydrogen or alkyl, alkoxy, halogen, cyano, -S03M, trifluoromethyl, nitro, ester, NHC (O) R334, C0NH2, group of the formula (3a); _ (3a) R336 and R337, independently of one another, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkylcarbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N , N-dialkyl-carbamoyl, N-monoarylcarbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkyl- sulfamollo, N, N-dicycloalkylsulfamollo, N, N-dialkylsulfamoyl, N- monoaryl sulfamollo, N, N-diarylsulphamoyl, N- monocycloalkyl-N-monoarylsulfamoyl, N-monoalkyl-N- monoaryl sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-aryl- amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogeno, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heteroalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N -monoalkylcarbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoarylcarbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl - carbamoyl, sulfamoyl, N-monocycloalkyl-sulfamollo, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, -dialkyl- sulfamoyl, N-monoaryl- Sulfonyl, N, N-diarylsulfamollo, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulphamoyl or S03M; containing a free valence moiety to be ligated with the T reactive anchor; R41, R42, R334 and R335, independently of one another are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; c is an integer from 0 to 6; d is an integer from 1 to 6; **** refers to the point of attachment with B1 and B2; ***** refers to point of union with T; ****** refers to junction point with E3; T and X are as previously defined; M is hydrogen, lithium, sodium, potassium, ammonium or mono-, di-, tri- or tetra-C 1 -C 4 alkylammonium, an equivalent of an alkaline earth metal or a monovalent organic cation; with the general condition that the dyes of the general formula (I) contain at least one reactive anchor. 2 . Chemical compound according to claim 1 having the formulas (la) a (If): formulas (la) a (If) and its mixtures; (° l) 822 (®l) 622 (If) where R49, R85, R58, R66, R74 and R78, independently of one another, are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, monocycloalkylamino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoaryl amino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, ary, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R50, R54, R59, R67, R75 and R79, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -S03M; R51, R55, R60 and R68 independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl- carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfamollo, N- monoalkylsulfamollo, N, N-dicycloalkylsulphamoyl, N, N-dialkylsulfamoyl, N-monoarylsulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoaryl sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N- monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or they are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl,. cycloalkyl, alkoxy, thioalkoxy, amino, N- monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N, N-dicycloalkylamino, N- monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyanq, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N- dialkyl sulphonyl, N-monoaryl sulphamoyl, N, N-diarylsulfamoyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl-N-monoarylsulphamoyl or SO3M; independently of one another are hydrogen or alkyl, alkoxy, halogen, cyano, -S03M, trifluoromethyl, nitro, ester, NHC (O) R86, CONH2, S (O) 2R87 or -S02X; R86 and R87 independently of one another are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R6I to m0 0 independent of each other, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio alkylsulfonyl, alkoxycarbonyl carbamoyl, sulfamoyl, ureido, alkylureido, SO 3 M, COOM; or a group of the formulas (2a) to (2c), X and M are as in claim 1. 3. Chemical compound according to claim 1 having the formulas (Ig) or (Ih): (ig) X 0 R (Ih) where R90 and R9i, independently of one another, are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, monocycloalkylamino; monoalkylamine; di (cyclo) alkyl-amino; dialkyl amino; monoaryl-amino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, aminq, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R91 and R95, independently of each other, are cyano, 0 carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -S03M; D1 and D2 independently of each other are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfmoyl, N-monoalkylsulfamollo, N, N-dicycloalkylsulphamoyl, N, N-dialkyl sulfamollo, N-monoaryl sulfamollo, N, N-diaryl-sulphamoyl, N-monocycloalkyl-N-monoarylsulfamethyl, N-monoalkyl-N-monoaryl-sulphamoyl, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkyl-amino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N- monocycloalkyl-amino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkylcarbamoyl, N, -dicycloalkyl-carbamoyl, N, N - dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulphamoyl, N-monocycloalkylsulfamollo, N-monoalkylsulfamoyl , N, N-dicycloalkyl sulphamoyl, N, N-dialkyl sulfamoyl, N-monoaryl sulphamoyl, N, N-diarylsulphyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl-N-monoarylsulphamoyl or S03M; R92, R93, R "and R100, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, - S03M, trifluoromethyl, nitro, ester, NHC (O) R101, CONH2, S (O) 2R102 O - S02X; R101 and R102 independently of one another are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R96 to R98, independently of each other, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, 0 alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carba oyl, sulfamoyl, ureido, alkylureido, SO3M, COOM; or a group of formulas (2a) to (2c); provided that D1 and D2 contain a free valence residue to link it with the reactive anchor T; T, X and M are as defined in claim 1. · Four . Chemical compound according to claim 1 having one of the formulas (Ii) to (II): 106 O 107 R R (OR) MO3S SO3M (II) where R105, R 110 RH5 and R123 independently of one another are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, mono-alkyl-amino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoarylamino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or they are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyclo, COOM, alkoxycarbonyl, acyloxy, carbaraoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R106, R111, R116 and R124, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -S03M; R107, R112, R117 and R125, independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl -carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N -monoalkyl-sulphonyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl-sulphamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoalkylsulfamoyl, N-monoalkyl-N-monoaryl-sulfamoyl , amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N -monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonium lalquil, or alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, TSI-monoalkylamino, N, N-dialkylamino, N-monoaryl-amino, N, N-diaryl-amino , N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl -amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl -carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoarylcarbayl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl- carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamollo , N-monoarylsulfamoyl, N, N-diarylsulfamoyl, N-monocycloalkyl-N-monoarylsulfamoyl, N-monoalkyl-N-monoarylsulphamoyl or S03M; R108, R109, R113, R114, R121, R122, R129 and R130, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -SO3, trifluoromethyl, nitro, ester, NHC (O) R131, C0NH2, S (O) 2R132 or -S02X; R131 and R132, independently of one another, are hydrogen, alkyl or alkyl substituted with hydroxy or halogen, R118 to R120 and R126 to R128, independently of each other, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfa oyl, ureido, alkylureido, S03M, COOM; or a group of formulas (2a) to (2c); E4 to E7, independently of each other, are a group of the general formulas (El) to (E3) M is as defined in claim 1. 5. Chemical compound according to claim 1 having one of the formulas (Im) a (Ip): (Im) (Ip) where each of R135, R139, R143 and R150, are, independently of each other, hydrogen, alkyl, cycloalkyl, trifluoromethyl, alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino, hydroxyl, monocycloalkylamino, monoalkylamino, di (cyclo) alkyl-amino, dialkyl-amino, monoaryl-amino, diaryl-a, monocycloalkyl-monoarylamino, monoalkyl-monoaryl-amino, alkylthio, arylthio, or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R136, R140, R144 and R151, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -S03M; D3, D4, D5 and D6, independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkylcarbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl -carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulphamoyl, N-monocycloalkyl-sulphamoyl, N -monoalkyl-sulfamollo, N, N-dicycloalkylsulfamoyl, N, N-dialkyl-sulfamoyl, N- monoaryl sulfamollo, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoaryl-sulphamoyl, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkyl-amino, N-arylamino, N, -aryl amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl -N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoaryl-amino, N, N-diaryl-amino , N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl - amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl - carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl- carbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-monoaryl-sulphamoyl, N, N-diaryl-sulphamoyl, N-monocycloalkyl- N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulfamollo or S03M; R137, R138, R141, R142, R148, R149, R155 and R156, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -S03M, trifluoromethyl, nitro, ester, NHC (O) R195, CONH2, S (O) 2R157 or -S02X; R157 and R158, independently of one another, are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R145, R146, R147, R152, R153 and R154, independently of each other, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulphamoyl, ureido, alkyl-acid, SO3M, COOM; or they contain a group of the formulas (2a) to (2c) as defined above; E8 to E11, independently of each other, are a group of the general formulas (El) to (E3) as previously defined; T, X and M are as defined in claim 1. Chemical compound according to claim 1 has one of the formulas (Iq) a (It): (S |) · 9 fr2 and R185, independently of one another, are alkyl, cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or - S03;. R162, R169, R176 and R186 are, independently of each other, hydroxyl or amino; R163 to R165, R170 to R172, R177 to R179 and R187 to R189, independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-onoalkyl -carbamoyl, N, -dicycloalkylcarbamoyl, N, N-dialkylcarbamoyl, N-monoarylcarbamoyl, N, N-diarylcarbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulphamoyl, N- monocycloalkyl sulfamollo, N-monoalkylsulfamolló, 0 N, N-dicycloalkylsulfamollo, N, N-dialkyl sulfamollo, N-monoaryl sulfamollo, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoaryl sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N- monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or they are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N -monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy , aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N- monocycliclichl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl- carbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamollo, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl- N-monoalkylsulfamoyl, N-monoalkyl-N-monoarylsulfamollo or SO3M; or alkyl or aryl substituted with -S02X; where X is vinyl or a radical -CH2CH2-Y, where Y is a removable group under alkaline conditions such as OSO3M; or a remainder with free valence to link it with the reactive anchor T; R166, R167, R173, R174, R183, R184, R193 and R194, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -SO3M, trifluoromethyl, nitro, ester, NHC (O) R195, CONH2, S (O) 2R196 or -S02X; R195 and R196, independently of one another, are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R180 to R182 and R190 to R192, independently of each other, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, ureido, alkylureido, SO3M, COO; or they contain a group of the formulas (2a) to (2c); X is as defined previously, and M and T are as defined in claim 1. 7. Chemical compound according to claim 1 having one of the formulas (Iu) to (Ix): on-i 202 (Iv) 215 216 221 R R .14 217 R 222! > ^ N R I III D, 2-18 y-N s ^ ° R 1V R ™ 219 RON (lw) 231 225 226 227 R .228 N O -.223 b h ^ \ R ^ R 1 J Cu i 229 // R (Ix) R199, R206, R213 and R223, independently of one another, are alkyl, cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrif luoromethyl, halogen, methylsulfonyl or -SO3M; R200, R207, R214 and R224 are, independently of each other, hydroxyl or amino; R201 to R203, R208 to R210, R215 to R217 and R225 to R227, independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diarylcarbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkyl sulfamollo, N-monoalkylsulfamollo, N, N-dicycloalkylsulfamollo, N, N-dialkylsulfamollo , N-monoaryl-sulfamollo, N, -diaryl-sulfonyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl-N-monoaryl-sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido ,. N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N- heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diaryl- amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, -dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl -amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialguyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N- monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-monoaryl sulphamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl-N-monoarylsulphamoyl or S03M; or alkyl or aryl substituted with -SO2X; wherein X is vinyl or a radical -CH2CH2-Y, where Y is a removable group under alkaline conditions such as OSO3M; or a remainder with free valence to link it with the reactive anchor T; R204, R205, R211, R212, R221, R222, R231 and R232, independently of one another are hydrogen or alkyl, alkoxy, halogen, cyano, -SO3M, trifluoromethyl, nitro, ester, NHC (O) R233, C0NH2, S (O) 2R234 or -S02X; R233 and R234, independently of one another are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R218 to R220 and R228 to R230, independently of each other are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl, cieloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; rent it; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, ureido, alkylureido, S03M, COOM; or a group of formulas (2a) to (2c); E12 to E15, independently of each other, are a group of the general formulas (El) to (E3); T, X and M have the same meanings as in claim 1. 8. Chemical compound according to one of the formulas (Iy) to (lab): 240 R VR 243 242 R 0¾ A 241 R (iy) (lz) c or 255 D 256 R (lab) where R237, R245, R253 and R264, independently of each other, are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, mono-alkyl-amino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoaryl-amino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulfonylamino, ureido, alkylureido or phenylureido; R238, R246, R254 and R265, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -SO3M; R 239 to R 242 R 247 to R 250 R 255 to R 258 267 270 and R to R independently of each other, are hydrogen, alkyl, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkylarymoyl, N, N-dicycloalkyl-carbamoyl, N , N-dialkyl carbamoyl, N-monoarylcarbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl, N- monocyclic alkyl sulfonyl, N-monoalkyl sulfamollo, N, N-dicycloalkylsulphamoyl, N, N-dialkyl sulphamoyl, N-monoaryl sulphamoyl, N, N-diaryl sulfamyl, N-monocycloalkyl-N-monoarylsulphamoyl, N-monoalkyl -N-monoaryl-sulfamoyl, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl-N -aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkylamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, -diarylamino , N-alkyl-N-aryl-araino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl - amino, ureido, alkylureido, phenylureido, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl - carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N- diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulphamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfonyl, N-monoaryl-sulfamoyl, N, N-diaryl-sulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulphamoyl or S03M; which contains a free valency residue to bind it to the rest of reactive anchor T; R243, R244, R251, R252, R262, R263, R274 and R275, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -S03M, trifluoromethyl, nitro, ester, NHC (O) R276, CONH2, S (O) 2R277 or -S02X; R276 and R277, independently of each other, are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R259 to R261 and R271 to R273, independently of one another, are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, ureido, alkylureido, SO3, COOM; or they contain a group of the formulas (2a) to (2c) X, M and T are as defined in claim 1. 9. Chemical compound according to one of the formulas (Iac) to (Iaf): 282 283 E 281 284 R; N SO3M (the D) 305 R 298 299 R R 0 (the e) 316 teeth are hydrogen, alkyl, cycloalkyl, trifluoromethyl; alkoxy, cyano, carbamoyl, alkoxycarbonyl, COOM, amino; hydroxyl, monocycloalkylamino; monoalkylamino; di (cyclo) alkyl-amino; dialkyl amino; monoarylamino; diaryl-amino; monocycloalkyl monoarylamino; monoalkylmonoarylamino; alkylthio; arylthio; or are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, cycloalkyl, heteroaryl, heterocycloalkyl, aryl, aryloxy, alkoxy, alkylthio, arylthio, halogen, cyano, COOM, alkoxycarbonyl, acyloxy, carbamoyl, nitro, amino, acylamino, arylcarbonylamino, alkylsulfonylamino, arylsulphonylamino, ureido, alkyureido or phenylureido; R281, R289, R297 and R308, independently of each other, are cyano, carbamoyl, alkoxycarbonyl, trifluoromethyl, carbonyltrifluoromethyl, halogen, methylsulfonyl or -SO3M; R282 to R285, R290 to R293, R298 to R301 and R309 to R312, independently of each other, are hydrogen, alkylo, alkenyl, cycloalkyl, trifluoromethyl, aryl, heteroaryl, heterocycloalkyl, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl -carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoarylcarbamoyl, sulfamoyl , N-monocycloalkyl sulfamollo, N-monoalkyl sulfamollo, N, N-dicycloalkylsulphamoyl, N, N-dialkylsulfamoyl, N-monoaryl sulfamollo, N, N-diaryl sulfamollo, N-monocycloalkyl-N-monoalkylsulfamoyl, N -monoalkyl-N-monoaryl-sulfamollo, amino, N-acylamino, N-thioacylamino, ureido, alkylureido, phenylureido, N-monoalkylamino, N, N-dialkylamino, N-arylamino, N, N-diarylamino, N-alkyl -N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-alkyl-N-cycloalkylamino, N-aryl-N-cycloalkylamino, N-heteroarylamino, N-heterocycloalkyl lamino or hydroxyalkylsulfonylalkyl, or they are alkyl interrupted by one or more heteroatoms such as oxygen or sulfur; or they are alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl ,. cycloalkyl, alkoxy, thioalkoxy, amino, N- monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N, N-dicycloalkylamino, N- monoalkyl-monocycloalkylamino, N, N-monoaryl-monocycloalkylamino, N-acylamino, N-alkylsulfonyl-amino, ureido, alkylureide, phenylureide, halogen, cyano, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl carbaraoyl, N , N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-Ralocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkyl sulfamollo, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl-N-monoarylsulfamollo, N-monoalkyl-N-monoarylsulfamollo or SO3M; or a remainder with free valence to link it with the reactive anchor T; R286, R287, R294, R295, R305, R306, R316 and R317, independently of each other, are hydrogen or alkyl, alkoxy, halogen, cyano, -SO3M, trifluoromethyl, nitro, ester, NHC (O) R318, CONH2, S (O) 2R319 or -S02X; R318 and R319, independently of one another, are hydrogen, alkyl or alkyl substituted with hydroxy or halogen; R302 to R304 and R313 to R315, independently of each other they are hydrogen, alkyl, substituted alkyl, alkyl chain interrupted by one or two heteroatoms, alkoxy, substituted alkoxy, halogen, trifluoromethyl; cycloalkyl; heterocycloalkyl; cyano; nitro; acyloxy; alkylcarbonyl, acylamino; arylailamino, cinnamoylamino, alkylsulfonylamino; alkylthio; alkylsulfonyl, alkoxycarbonyl, carbamoyl, sulfaryloyl, ureido, alkylureido, S03, COOM or contain a group of the formulas (2a) to (2c); E16 to E19, independently of each other, are a group of the general formulas (El) to (E3); T, X and M have the same meanings as defined in claim 1. 10. Chemical composition consisting of two or more chemical compounds according to any of claims 1 to 9. 11. Chemical composition comprising one or more chemical compounds according to any of claims 1 to 9. 12. Aqueous solution for staining comprising one or more chemical compounds according to any of claims 1 to 9. 13. Process for the production of chemical compounds according to formula (I) comprising the steps of a) diazotization of compounds of formula (IV), b) reaction of the diazonium salts obtained in step a) with a compound of the formula K to obtain an intermediate of the formula (V) c) diazotation of the component (B-NH2), cxl) optionally coupling the diazotized product of step c) with the compound (A-NH2) and cx2) diazotization of the coupling product of stage cxl) d) coupling the diazotized product of step c) with intermediate V to obtain the bisazo product of general formula (VI) in the case of step c) I or coupling of the diazotized coupling product of cx2) with intermediate V to obtain the trisazo product of the general formula (VIII), NH 2 + A.NH2 B reaction of the product of step d) having the formula (VI) or (VIII) with copper salt to give the copper complex dyes (IX) in the case of (VI) or (X) in the case of ( VIII): 14. Use of a chemical compound according to any of claims 1 to 9, a chemical composition according to claim 10 or 11 or an aqueous solution according to claim 12 for dyeing fibers selected from the group consisting of: vegetable fibers, seed fibers, cotton, kapok, coconut fiber from coconut shell; bast fibers, flax, hemp, jute, kenaf, ramie, rattan; leaf fibers, sisal, henequen, banana; stalk fibers, bamboo; fibers from animals, wool, silk, cashmere wool, alpaca fiber, ohair, Angora fiber, as well as manufactured leather and leather materials and fibers, cellulosic fibers; paper and regenerated cellulose fibers, viscose rayon fibers, acetate and triacetate fibers and Lyocell fibers; and synthetic fibrous materials, nylon, nylon-6, nylon-6,6.and 5 materials aramid fibers. 15. Fiber selected from the group consisting of: vegetable fibers, seed fibers, cotton, kapok, coconut fiber from coconut shell; fibers of 0 bast, flax, hemp, jute, kenaf, ramie, rattan; leaf fibers, sisal, henequen, banana; stalk fibers, bamboo; fibers from animals, wool, silk, cashmere, alpaca fiber, mohair, Angora fiber, as well as leather and leather materials; fibers manufactured, regenerated and recied (see No. 17), cellulose fibers; paper and regenerated cellulose fibers, viscose rayon fibers, acetate and triacetate fibers and Lyocell fibers; · and synthetic fibrous materials, nylon, b-nylon, nylon-6,6 materials and aramid fibers, comprising one or more chemical compounds according to any of claims 1 to 9 either in a chemical and / or physically bound form.