MX2009000939A - Process for removal of oxygenates from a paraffin stream. - Google Patents

Process for removal of oxygenates from a paraffin stream.

Info

Publication number
MX2009000939A
MX2009000939A MX2009000939A MX2009000939A MX2009000939A MX 2009000939 A MX2009000939 A MX 2009000939A MX 2009000939 A MX2009000939 A MX 2009000939A MX 2009000939 A MX2009000939 A MX 2009000939A MX 2009000939 A MX2009000939 A MX 2009000939A
Authority
MX
Mexico
Prior art keywords
oxygenates
removal
paraffin
rich
stream
Prior art date
Application number
MX2009000939A
Other languages
Spanish (es)
Inventor
Bryan K Glover
Stephen W Sohn
Santi Kulprathipanja
James W Priegnitz
Bipin V Vora
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Publication of MX2009000939A publication Critical patent/MX2009000939A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14Base exchange silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C10G25/05Removal of non-hydrocarbon compounds, e.g. sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20Organic compounds not containing metal atoms
    • C10G29/205Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1081Alkanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1088Olefins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1096Aromatics or polyaromatics
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The present invention comprises a process for removal of oxygenates from a paraffin-rich or olefin-rich paraffin stream which comprises passing a feed stream, comprising one or more C10 to C15 feed paraffins or C10 to C15 olefin-rich paraffin stream and one or more oxygenates through an adsorbent bed comprising one or more adsorbents selected from silica gel, activated alumina and sodium x zeolites to remove essentially all of said oxygenates; and recovering said paraffins. A second adsorbent bed may be employed to more thoroughly remove these oxygenates.
MX2009000939A 2006-07-24 2006-07-24 Process for removal of oxygenates from a paraffin stream. MX2009000939A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2006/028490 WO2008013519A2 (en) 2006-07-24 2006-07-24 Process for removal of oxygenates from a paraffin stream

Publications (1)

Publication Number Publication Date
MX2009000939A true MX2009000939A (en) 2009-04-14

Family

ID=38981914

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009000939A MX2009000939A (en) 2006-07-24 2006-07-24 Process for removal of oxygenates from a paraffin stream.

Country Status (8)

Country Link
EP (1) EP2054359A4 (en)
KR (1) KR101089886B1 (en)
CN (1) CN101535219B (en)
AU (1) AU2006346510A1 (en)
BR (1) BRPI0621924A2 (en)
CA (1) CA2658601C (en)
MX (1) MX2009000939A (en)
WO (1) WO2008013519A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9382344B2 (en) 2013-06-25 2016-07-05 Exxonmobil Chemical Patents Inc. Mitigation of catalyst inhibition in olefin polymerization
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
US10047178B2 (en) 2017-02-07 2018-08-14 Exxonmobil Chemical Patents Inc. Mitigation of catalyst inhibition in olefin polymerization
WO2019045878A1 (en) 2017-08-29 2019-03-07 Exxonmobil Chemical Patents Inc. Carbon dioxide as a catalyst quench agent in solution polymerization, and products made therefrom
CN109482143B (en) * 2017-09-13 2022-05-24 正大能源材料(大连)有限公司 Adsorbent for purifying low-carbon olefin and preparation and application thereof
CN110314674B (en) * 2018-03-29 2021-10-08 中国石油化工股份有限公司 Regeneration method of adsorbent
EP3792337B1 (en) * 2019-05-14 2024-02-07 Evonik Oxeno GmbH & Co. KG Method for purifying a hydrocarbon flow with residual butene
GB2613166A (en) * 2021-11-25 2023-05-31 Plastic Energy Ltd A method for the removal of impurities from a pyrolysis oil
CN114409509A (en) * 2022-01-24 2022-04-29 福州华为医药技术开发有限公司 Lauryl alcohol purification method, polidocanol synthesis method and polidocanol injection
CN115505418A (en) * 2022-10-21 2022-12-23 中国石油化工股份有限公司 Method for removing oxygen-containing compounds in isoparaffin

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531324A (en) * 1947-10-18 1950-11-21 California Research Corp Preparation of alkylated aromatic hydrocarbons and sulfonation thereof
US2448489A (en) * 1948-04-14 1948-08-31 Sun Oil Co Separation of aromatic hydrocarbons by selective adsorption in silica gel
US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US4404118A (en) * 1981-12-28 1983-09-13 Uop Inc. Regeneration of adsorbents by low temperature hydrogen stripping
US4814517A (en) * 1988-06-09 1989-03-21 Uop Oxygenate removal in MTBE production
US5677260A (en) * 1995-06-23 1997-10-14 Indian Petrochemicals Corporation Limited Catalyst composite for dehydrogenation of paraffins to mono-olefins and method for the preparation thereof
MXPA04009353A (en) * 2002-03-25 2005-01-25 Uop Llc Process for producing selected phenyl-alkanes with adsorptive separation step.
US7311815B2 (en) * 2003-02-20 2007-12-25 Syntroleum Corporation Hydrocarbon products and methods of preparing hydrocarbon products
US7326821B2 (en) * 2003-06-16 2008-02-05 Exxonmobil Chemical Patents Inc. Removal of oxygenate from an olefin stream
US20040267071A1 (en) * 2003-06-30 2004-12-30 Chevron U.S.A. Inc. Process for the oligomerization of olefins in Fischer-Tropsch derived feeds

Also Published As

Publication number Publication date
EP2054359A2 (en) 2009-05-06
CA2658601C (en) 2012-09-18
WO2008013519A3 (en) 2009-05-14
KR101089886B1 (en) 2011-12-05
EP2054359A4 (en) 2009-12-02
WO2008013519A2 (en) 2008-01-31
CN101535219B (en) 2013-02-13
AU2006346510A1 (en) 2008-01-31
CN101535219A (en) 2009-09-16
KR20090051048A (en) 2009-05-20
CA2658601A1 (en) 2008-01-31
BRPI0621924A2 (en) 2011-12-20

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