MX2008010386A - Apparatus and method for using tetrazine-based energetic material - Google Patents

Abstract

The present invention comprises apparatus and methods employing a gas produced from a tetrazine-based energetic material such as that known as"BTATz"containing 3;6-BtS(1 H- 1,2,3,4-Tetrazol-5-y1amino)1-,2,4,5-tetrazine 3;6-BtS(1 H- 1,2,3,4-Tetrazol-5-y1amino)1-,2,4,5-tetrazine or salts thereof. The tetrazinebased energetic material is ignited through the use of a percussion cap, a piezoelectric crystal or a battery-supplied electric spark or by encapsulating it in a container that is then exposed to a burning flame. The gas produced upon ignition is employed a propellant such as to inflate life rafts, life vests, emergency evacuation slides, tires, air bags and other inflatable devices. The gas produced upon ignition is alternatively employed to power an engine and many other applications such as a fire suppressant.

Description

APPARATUS AND METHOD FOR THE USE OF ENERGETIC MATERIAL BASED ON TETRACINE FIELD OF THE INVENTION The present invention relates to an apparatus and method for the use of energy materials based on tetrakine. More particularly, the invention relates to an apparatus or method using a gas produced from an energy material based on tetrakine. The present invention is also related to the ignition of the tetracin-based energy material. In some embodiments, the tetrakine-based energy material is ignited by the use of a fulminating capsule, a piezoelectric crystal or an electric spark supplied by a battery or by encapsulating it in a container which is then exposed to a burning flame. The present invention is further related to the use of the gas produced in the ignition as a propellant such as for inflating liferafts, life jackets, emergency evacuation sliders, tires, airbags, other inflatable devices. . Additionally, the present invention relates to the use of gas produced during ignition in many other applications such as fire suppressors or as an alternative vehicle fuel.

REF. : 195673 BACKGROUND OF THE INVENTION Currently, tetrakine-based energy materials are well known, such as what is known as "BTATz" containing 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino) -1, 2, 4, 5-tetrakine or salts thereof, as described in U.S. Patents 6,458,227 and 6,657,059, the descriptions of each of which are incorporated herein by reference.The BTATz was developed by Los. Alamos Laboratory mainly as an explosive for military applications The gas produced by the ignition of BTATz has many beneficial properties that the present invention has incorporated in many commercial applications such as the use of gas as a propellant to inflate liferafts, life jackets, water sliders emergency evacuation, tires, air bags and other inflatable devices or as an alternative fuel for vehicles to provide power to an engine and its use as a fire suppressor. As a prior art in the art for inflation, there are many types of inflators designed to inflate inflatable articles such as personal flotation devices (vests, rings and life-saving shoes), liferafts, buoys, signaling equipment and evacuation sliders. emergency. Inflators typically comprise a body to receive the neck of a gas cartridge containing compressed gas such as carbon dioxide. A reciprocating perforation is disposed in the inflator body to pierce the fragile seal of the gas cartridge whereby the compressed gas flows into an exhaust manifold of the inflator and then into the article to be inflated. Typically, a manually movable trigger lever is connected to the piercing needle in such a manner that the piercing needle pierces the fragile seal of the cartridge when pulling a ball lanyard. U.S. Pat. 3,809,288, the disclosure of which is incorporated herein by reference, illustrates a particular embodiment of a manual inflator. In the inflation technique, the gas cartridge is normally sized to contain the volume of carbon dioxide needed to inflate the article. Inflatable small items such as life jackets are inflated with a relatively small volume of carbon dioxide. Therefore, smaller gas cartridges can be used easily. Larger items such as liferafts and emergency evacuation sliders for aircraft require relatively larger volumes of carbon dioxide. Therefore, they must be used, whether larger gas cartridges, or multiple gas cartridges, or a combination of both, in order to have a sufficient volume of carbon dioxide to fully inflate the Article . It is desirable in many applications in the inflation art to minimize the weight of the inflatable article. For example, in the aviation industry, it is desirable to minimize the weight of each apparatus on the aircraft including the gas cartridges used to inflate lifejackets, liferafts and emergency escape sliders. Similarly, in other applications it is often desired to minimize not only the weight but the size of the gas cartridge used in the inflatable equipment. Therefore, there is currently a need for lighter and smaller sources for gas to inflate that produce the same or a larger volume of a propellant than conventional carbon dioxide gas cartridges. In related inflation applications such as airbags and the like, there is similarly a need to produce an environmentally safe gas to inflate the airbag. For example, with respect to airbags, it is appreciated that several prior art propellants have been used in automotive safety containment air bags. Most of these propellants from prior techniques are problematic due to the excessive heat generated, high sensitivity to inadvertent ignition. Some may even be toxic in their state without burning and burning. Airbag propellants of previous techniques often have a risk of environment and require special handling and disposal procedures. Additionally, many of the prior art pyrotechnic materials commonly used in automotive airbags pose a risk when collected and reused as improvised explosive devices. In relation to minimizing hazardous propellants used in airbags, in the technique of fire suppressors, there is currently a need to produce fire suppressant gas that is safe for humans. Similarly, there is currently a need for an environmentally friendly gas that can be used as an alternative fuel for vehicles to power an engine, thus minimizing the contamination of fossil fuels and greenhouse gases. Therefore, an object of the present invention is to provide an improvement that overcomes the aforementioned inadequacies of the prior art and provides an improvement that is a significant contribution to the advancement of the use of BTATz in a wide variety of applications. BRIEF DESCRIPTION OF THE INVENTION For purposes of summarizing the invention, the present invention comprises apparatus and methods using a gas produced from an energy material based on tetrakine such as the one known as "BTATz" containing 3.6- bis (1H-1,2,3,4-tetrazol-5-ylamino-1,2,4,5-tetrakine or salts thereof, as described in US Patents 6,458,227 and 6,657,059, the descriptions of which of each are incorporated herein by reference In some embodiments, the tetrakine-based energy material is ignited in accordance with the present invention by the use of a fulminating capsule, a piezoelectric crystal or an electric spark supplied by battery or by encapsulating it in A container that is then exposed to a burning flame The gas produced during ignition is used as a propellant such as to inflate life rafts, life jackets, emergency evacuation sliders, tires, air bags and other inflatable devices. produced during ignition is alternatively used to drive an engine, Alternatively, in accordance with the present invention, the gas produced during ignition is used in many other applications. such as a fire suppressor. More specifically, the BTATz is used as a propellant that generates deflagration gas to provide mainly nitrogen gas as the gas medium to inflate. The BTATz material is selected, in part, due to the non-toxic nature of the effluent gases produced from the deflagration of the material and its non-explosive nature as an energy material. The temperatures of the BTATz effluent gases they remain sufficiently low and have a very fast cooling rate to allow the use of the propellant in life jackets, life rafts and other traditional gas-containing bladder-type devices for inflatable devices without thermal damage to the device or damage by contact or exposure to the user . The grain load or shape of the BTATz material used in various inflator modes can be of a variety of shapes or configurations according to the special requirement with respect to desired time and pressure curves for the inflation event. The shape of the grain can alternatively be formed as a loose powder, a shape as pellets, a simple monolithic grain charge or any number of specific geometries required to provide the desired deflagration rate and gas generation, as well as any number of dispositions of packaged desired adapted to various inflators for various purposes, including, but not limited to; life jackets, liferafts, emergency escape gliders of aircraft. Additionally, a variety of other chemical substances can be added to the BTATz material to alter performance with respect to the rate of deflagration, the temperature of the effluent or other properties as required for specific environments or applications for the inflator device. The material of BTATz can use a binder material in order to form specific grain forms as mentioned above. The binder materials may include PVA (polyvinyl alcohol), PEA (polyethylene acrylate), or other suitable chemical materials to provide a binding property to the base material in order to maintain a specific structure or formation such as pellets, spherical balls or a form of monolithic grain. The addition of a binder material to the BTATz has shown a remarkable reduction in the sensitivity of the electrostatic discharge spark of the material. In order to reliably start the BTATz deflagration with binder material, the inclusion of "pure" material (without binder), can be used as a primary, spark-sensitive charge to facilitate ignition when an electric spark is used as a medium of ignition. In the various embodiments of the invention, the inflator can be initiated either by manual or automatic means or by a combination of manual and automatic methods. The initiation or ignition of the BTATz charge in the inflator mechanism may be by means of, but not limited to, a primary pyrotechnic charge such as a commercial primary or fulminating capsule, a mechanical pyrotechnic detonator, an electric wick, a spark generated by a source of stored electrical energy such as a battery or generated by means of a piezoelectric device. In an automatic initiation mode the inflator device can be activated either by electrical or electronic means. The mechanical initiation may comprise a pull-and-pull lever arrangement of the pull-out type that alternatively releases either a mechanical hammer or hammer to strike a primary flash capsule or activates a piezoelectric generator to produce an electrical spark through a conductive space for start the BTATz propellant. The optional automatic initiation can be by means of an electronic water immersion detector circuit that will activate the release of electrical energy stored in the battery to produce a spark, activate a pyrotechnic detonator, start an electric wick, or activate the release of a hammer. mechanical or hammer to impact a primary or fulminant pyrotechnic capsule. Alternatively, the automatic initiation may be by means of a water soluble coil which, upon dissolution, releases a hammer or striker arrangement to strike a fulminating or primary capsule. One embodiment of the inflator device includes a lever arrangement and drive cam that provides multiple striking impacts of the hammer or striker mechanism against the primary or fulminating capsule with a single pull of the lever. Another modality of the mechanism Inflator includes a similar lever and cam arrangement that provides multiple drives of a piezoelectric spark generator. Both multiple actuation mechanisms serve to provide a safety factor to ensure activation of the BTATz deflagration event. The containment of the cargo that generates BTATz gas can be in a metal, thermoplastic, thermosetting plastic or elastomeric container that can be easily attached and detached from a body of the inflator mechanism to facilitate the assembly and disassembly of the device. One embodiment of the cargo container uses both the BTATz material that generates gas and a fulminating or primary capsule. Another embodiment of the charging container includes electrical contact points and an internal conductive spark gap arrangement. Cargo containers can have an airtight seal to prevent moisture from entering the chemical charge and ignition components. The cargo containers can be of various sizes and geometric configurations to contain various quantities of BTATz material, various grain geometries or several specialized connections for different specific inflator devices. Another embodiment of the inflator includes a means which alternatively indicates a state triggered, not fired, (ready) by displaying an appropriate indicator or by means of a physical indicator. The inflator can be manufactured from a thermoplastic material, thermoset polymer, metal, elastomer or any combination thereof. The foregoing has highlighted, although broadly, the most relevant and important features of the present invention so that the detailed description of the invention can be understood below in such a way that the present contribution to the art can be more fully appreciated. The additional features of the invention will be described hereinafter which form the object of the claims of the invention. Those skilled in the art should appreciate that the conception and specific embodiment described can easily be used as a basis for modifying or designing other structures to accomplish the same purposes of the present invention. Also those skilled in the art should realize that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims. BRIEF DESCRIPTION OF THE FIGURES For a more complete understanding of the nature and objects of the invention, reference should be made to the following detailed description considered in connection with the appended figures in which: Figure 1 is an exploded view of a gas cartridge containing the BTATZ material fluidly connected to an inflatable article to inflate the article when activating the BTATZ material; Figure 2 is a sectional view of a device using BTATz as a propellant for automotive safety containment air bags; Figure 3 is a sectional view of a device containing BTATz that can be thrown, propelled, dropped or otherwise introduced to a fire to suppress it; Figure 4 is a sectional view of a portable fire extinguisher containing BTATz; Figure 5 is a sectional view of a fire extinguisher made of solid material containing BTATz without other propellants; Figure 6 is a cross-sectional view of a BTATz inflator that includes an electronic water detection trigger that ignites the BTATz material when immersed in a body of water; Figure 7 illustrates a BTATz tire inflator including an adjustable release valve that limits the amount of gas pressure during inflation of the tire; Figures 8A-8F illustrate a BTATz inflator that can be thermally sealed to a lifejacket or other inflatable; Y Figure 9 illustrates a BTATz alternative fuel engine in which quantities of BTATz material are sequentially ignited to produce nitrogen gas supplies to power the engine. Similar reference numbers refer to parts similar to or along the various figures. DETAILED DESCRIPTION OF THE INVENTION The present invention comprises an apparatus and method for using a gas produced from an energy material based on tetrakine such as that known as "BTATz" as a propellant in one or more devices described in the patents and in the patent applications listed in Table I that are appended to this, whose descriptions of each of the patents and patent applications are incorporated herein by reference. More particularly, the BTATz propellant can be used in any device, system or application, as described in Table I, in which it is necessary to generate a harmless gas source from a supply of material. Without limiting the scope of the preceding paragraph, with reference to Figure 1, one embodiment of the invention comprises a gas cartridge 1-10 having an outlet 1-12 for fluid connection to an inflatable article, shown with the reference number 1-14. The gas cartridge 1-10 comprises a conical reaction chamber 1-16 containing the BTATz material 1-18. The conical reaction chamber 1-16 is desired to control the rate of evolution of the gal by linearly burning the BTATZ 1-18 material (which is believed to be achieved by the use of a binder). The conical chamber 1-16 is hermetically sealed and protected by a cover 1-20 to prevent the leakage of moisture and contain the BTATZ 1-18 material in place within chamber 1-16. The conical chamber 1-16 is mounted within a cylindrical shell 1-22 which provides mechanical stability and creates an air gap that allows thermal conductivity, and therefore a high resistance to transfer heat. A hemispherical dome 1-24 is placed on the cover 1-20 to provide a greater volume of space for the nitrogen gas to pressurize to drive a Joule-Thompson cooling through the outlet 1-12. Respective fold flanges 1-26 allow the aforementioned parts to be folded into a single unit that will withstand the pressure of the entire gas discharge from the deflagration of the BTATZ 1-18 material. Another embodiment of the invention comprises the use of BTATz as a propellant for automotive safety containment air bags. The BTATz is particularly suitable for use as a propellant for air bags due to its high nitrogen gas output and low gas temperatures. Also, the BTATz material is non-toxic and is environmentally safe and non-detonable, making it useless for malicious purposes, such as improvised explosive devices. The high output of nitrogen gas from BTATz allows less propellant to achieve the inflation of the airbag containment device with materials commonly used today. More particularly, with reference to Figure 2, the inflation device of the air bag of the invention comprises a vented envelope 2-10 in which an internal cavity 2-12 filled with the propellant of BTATz 2-14 is located. A fulminating capsule / detonator / lighter 2-16 is placed in the bottom of the cavity 2-12 with its firing terminals 2-16L extending through the casing 2-10 for connection to a firing mechanism. A space can be provided between the ventilation holes 2-18 of the casing 2-10 and the internal cavity 2-12 to receive a filter therein. The filter 2-20 has the function of filtering the gas produced by propellant 2-14 during firing. Upon detecting an impact, the trigger mechanism of the airbag is actuated to produce an electrical signal to send a signal to fire the capsule fulminating 2-16, whereby the propellant of BTATz 2-14 is turned on to produce the gas nitrogen that is then filtered to exit the 2-10 shell and inflate the air bag. Another embodiment of the invention comprises an apparatus and method for using a gas produced from a tetrakine-based energy material such as that known as "BTATz" as a fire suppressant in one or more devices described in the patents and patent applications listed in Table II attached hereto , whose descriptions of each of the patents and patent applications are incorporated herein by reference. More particularly, the BTATz propellant can be used in any device, system or application, such as those described in Table I, in which it is necessary to generate a harmless gas source from the material supply. More particularly, the nitrogen suppressant gas produced by igniting the BTATz material can be used in any device, system or application, such as those described above, in which it is necessary to generate a source of suppressing gas from the material supply. As shown in Figure 3, in accordance with the spirit and scope of the invention and without limitation, an example application includes filling a container 3-10 with the BTATz 3-12 material so that it is completely encapsulated therein. . The container 3-10 is constructed of a material 3-14 in such a way that when it is thrown, impelled, dropped or otherwise introduced into a fire, the material 3-14 constituting the container 3-10 is melted , burns, opens by fracture or is otherwise released to expose the BTATz 3-12 material on fire, whereby BTATz 3-12 material is ignited by fire flames. When the BTATz 3-12 material is ignited, a large volume of nitrogen suppressing fire is produced to displace the oxygen from the fire and thereby extinguish the fire. It is contemplated that the container 3-10 may comprise a variety of configurations and dimensions to facilitate its introduction to fire. More particularly, without limiting the spirit and scope of the invention, the container 3-10 may comprise a flammable container the size of a softball 3-10 filled with the BTATz 3-12 material which is easily held by hand for to be thrown into a fire that burns. Once the container the size of a softball 3-10 is in the fire, the flammable material 3-14 which constitutes the container 3-10 · catches fire, whereby the BTATz fire suppressant material 3-12 It ignites to produce a large volume of nitrogen gas suppressing fire to extinguish the fire. Depending on whether the fire burns in a confined space or burns in an open space, many of the containers the size of a 3-10 softball can be thrown as needed to put out the fire. In the case of a forest fire, many, even thousands, containers of the size of a softball (or larger) 3-10 can be thrown into the fire from the air.

As shown in Figure 4, the BTATz 4-12 material can be incorporated into portable fire extinguishers 4-16 with or without other propellants. For example, as shown in Figure 4, similar to a conventional fire extinguisher 4-16 using a propellant, a gas cylinder 4-18 can be filled through its opening 4-20 with the BTATz 4 material. -12. A conventional manually operated valve / nozzle 4-22 is then installed in the opening and cylinder 4-18 is pressurized with a 4-24 gas. When a fire needs to be extinguished, the nozzle 4-22 is directed towards the base of the fire and the valve 4-20 is actuated whereby the pressurized gas 4-24 displaces the BTATz material 4-12 from the bottom of the cylinder 4 -18 through a central tube 4-26 to then be driven to the base of the fire where it is ignited to produce a large volume of nitrogen gas is deprived of oxygen fire extinguishing the fire. It is appreciated that the "portable" extinguishers described above 4-16 may comprise a valve 4-22 which is actuated when a fire is detected in such a manner that the extinguisher 4-16 can be mounted at a fixed location, such as in the bilge of a boat, to automatically release the BTATz 4-12 material once a fire is detected. The BTATz material can be used in a 4-16 fire extinguisher without a propellant. More particularly, as shown in Figure 5, the valve 5-22 may include a lighter (e.g., a detonator, a fulminating capsule or other electronic or mechanical spark generator). When cylinder 5-18 is filled with BTATz material 5-12, it can be ignited directly by means of the valve igniter 5-22. When ignited in cylinder 5-18, the expanding nitrogen gas produced from BTATz 5-12 material that burns pressurizes the cylinder 5-18- The pressurized cylinder 5-18 is then "charged" and the nitrogen gas can then released immediately (or released at will) to extinguish the fire (similar to fire suppression gas systems that store Halon, F 2000 or other fire suppressing gases). In fact, the igniter of the valve 5-22 can be operated remotely by means of a sensor 5-30 in an area 5-32 to be protected (for example, a quarter of computers). The container 5-12 can be fixedly mounted in a central location and its output 5-34 connected to the protected area 5-32 in which the sensor 5-30 is located. In this way, when a fire is detected in the protected area 5-32, the igniter of the valve 5-22 is operated to ignite the BTATz 5-12 material to produce a large volume of nitrogen gas which then flows through the the pipe 34 to be injected into the protected area 5-32 to extinguish the fire. Therefore, it should be appreciated that the BTATz material Fire suppressor 5-12, coupled with the ignition system, can be used as a substitute for Halon or FM2000 in a wide variety of fire suppression systems, such as those described in the patents and patent applications listed above. With reference to Figure 6, in another embodiment of a BTATz inflator of the invention, a generally cylindrical BTATz charging vessel 6-10 is partially filled with a quantity of BTATz material 6-12 and then the loading vessel 6. -10 is filled with a primer charge 6-14. Preferably, a hollow central core 6-16 extends through the gas generating charge of BTATz 6-12 and the priming charge 6-14 of a specific grain shape that defines the rate of burning of the BTATz material 6-12 once it is turned on by the priming charge 6-14. The loading vessel 6-10 is then sealed with a seal membrane 6-16 (eg, a film). A particulate filter 6-18 is installed on the seal membrane 6-16 and then a ventilated cover 6-20 with a downwardly extending lighter 6-22 is installed around the open end of the charge container 6-10 with the lighter 6-22 extending into the hollow central core 6-16 of the priming charge 6-14. The exposed surface of the ventilated cover 6-20 includes electrical contacts of oscillating plates 6-24 connected electrically to the 6-22 lighter to fire it by applying an electrical voltage to the contacts 6-24. By firing the 6-22 ignitor, the priming charge 6-14 is turned on which in turn ignites the main BTATz gas generating charge 6-12 to produce a supply of nitrogen gas at a rate determined by the shape of the grain used. . The nitrogen gas produced is vented from the loading vessel 6-10 through the ventilation holes in the cover 6-20.

The BTATz charging container 6-10 is sized to be installed replaceably, preferably sealably, in a lower chamber of a generally cylindrical inflator casing 6-26 and held in position once installed by means of securing lugs 6-28 which are secured in corresponding securing grooves 6-30 formed in the lumen of the inflator casing 6-26. The exposed end of the loading container 6-10 includes an indicator fin 6-30 to facilitate the installation of a fresh charge container 6-10 and then the removal once it is spent) for example, the loading container is fired) 6-10. An exhaust port 6-32 is located in the lower chamber of the inflator casing 6-26 above the ventilation holes of the cover 6-20 of the loading vessel 6-10 so that when the generating charge is ignited of BTATz main gas 6-12 to produce the Nitrogen gas supply, the gas that is drained from there escapes through the exhaust port 6-32 towards the item to be inflated. The inflator casing 6-26 further includes a separate upper chamber sealed from the lower chamber by means of an intermediate divider wall 6-34. The upper chamber contains an electronic assembly activated by water, indicated generally by the number 6-36, whose function is to supply a tripping voltage to the electrical contacts 6-24 of the 6-22 lighter to fire the same when the inflator shell 6-26 is submerged in a body of water. More specifically, the electronic assembly 6-36 comprises a pair of immersion contact sensors 6-38 extending through a wall of the upper chamber of the casing 6-26. The sensors 6-38 are electrically connected to a controller 6-40 contained in the upper chamber. The controller 6-40 is optionally composed of discrete electrical components, integrated circuits or a microcontroller energized by means of a battery source 6-42 also contained in the upper chamber. The controller 6-40 detects the moment in which the sensors 6-38 have been submerged in a body of water. The controller 6-40 additionally comprises output contacts 6-42 which extend through the intermediate wall 6-34 to make electrical contact with the respective electrical contacts of oscillating plates 6-24 of the lighter 6-22 when the loading container 6-10 is installed in the lower chamber of the casing 6-26. When the controller 6-40 detects that the sensors 6-38 have been submerged in a body of water, it produces an output voltage to its output contacts 6-42 to fire the igniter 6-22. It is appreciated that optionally the controller 6-40 may additionally include a red / green status indicator LED 6-44 extending through the upper chamber wall of the casing 6-26 to indicate the trigger condition (e.g. , green for ready and red indicating a spent charging container 6-10, low battery or other inoperative condition) of the inflator. In addition, optionally, the operation of the controller 6-40 can be controlled by means of a on / off mode switch 6-46 which extends through the wall of the upper chamber case 6-26. It is further appreciated that the sensors 6-38, the indicator LED 6-44 and the mode switch 6-46 are preferably sealed as they extend through the wall of the upper chamber to prevent moisture from entering the upper chamber and damaging the upper chamber. otherwise the operation of the controller 6-40. Finally, it is appreciated that the end of the upper chamber can be removable to allow the replacement of the battery 6-42.

As shown in Figure 7, also another embodiment of the BTATZ inflator of the invention, similar to that of Figure 6, but configured to function as a tire inflator 7-10. More specifically, the tire pump 7-10 of the invention comprises a generally cylindrical housing 7-12 which sealingly receives at its proximal end a replaceable BTATz charging container 7-14 by circumferential coupling threads 7-16 in the external side of the loading vessel 7-14 and in the lumen of the shell 7-12. The loading container 7-14 includes a threaded ventilated cover 7-18 which allows filling. The loading vessel 7-14 is filled with a supply of BTATz material. A spark gap 7-16 is formed at the upper end of the load vessel 7-14 to create a spark when voltage is applied to its terminals 7-18. The trigger spark created is injected into the loading vessel 7-14 to ignite the BTATz material. As described above in relation to Figure 6, the BTATz material may include a hollow core with a desired grain shape to control the degree of burning and therefore the rate at which the nitrogen gas is produced. The nitrogen gas produced by burning the BTATz material is vented from the loading vessel 7-14 to the distal end of the shell 7-12. A piezoelectric mechanism 7-20 is mounted to the wall of the Distal end of shell 7-12. The piezoelectric mechanism 7-20 comprises a button 7-22 which, upon being pressed, creates a voltage spark by means of the piezoelectric which is supplied by the internal electrical terminals 7-24 to the terminals 7-18 of the spark gap 7-16. Therefore, it should be appreciated that by pressing the button 7-22, the piezoelectric is triggered to create a voltage spark that is supplied to the spark gap 7-16 to ignite the material material of BTATz in the charging vessel 7- 14, whereby the nitrogen gas produced there is dewatered towards the distal end of the shell 7-12. The distal end of the shell 7-12 is preferably tapered to receive a valve 7-26 which is designed to open a conventional inflation valve of a standard automobile tire, commonly referred to as the Schrader Valve. Consequently, during use to fill a tire, the 7-26 valve can be hooked to the Schrader Valve and the 7-22 button pressed to trigger the BTATz 7-14 loading container whereby the nitrogen gas produced flows into the tire. to inflate it. Preferably, in order to prevent excessive inflation of the tire, a pressure limiting presetting mechanism 7-28 is incorporated in the casing 7-12 to automatically let gas pressure escape to the atmosphere as long as the gas pressure exceeds the preset pressure. In one embodiment, the presetting pressure limiting mechanism comprises a releasable release valve 7-30 whose release pressure is preset by means of a selector 7-32 with pressure indicator lines 7-34 formed therein. The indicator lines 7-34 allow the informed selection of the presetting pressure (eg, 1436 Pa (30 psi)) whereby any excessive gas pressure is automatically dewatered from the casing 7-12, thus ensuring that the tire is inflated completely to the desired pressure (for example, 1436 Pa (30 psi)). As shown in Figures 8A-8F, a further embodiment of the BTATz inflator of the invention comprises an inflator 8-10 which uses a fulminating capsule 8-12 to ignite the loading vessel 8-14 filled with BTATz material 8- 14 In the specific embodiment illustrated, an inflator shell 8-16 comprises a generally rectangular configuration having a peripheral flange 8-18 whose purpose is to thermally seal an inflatable article such as a lifejacket, life raft, evacuation ramp or Similary. The underside of the inflator shell 8-16 includes an exhaust port 8-20 fluidly connected to the interior of the inflatable article to inflate it when firing the cargo vessel 8-14.

Similar to the previous embodiments described above, the loading container 8-14 comprises a generally cylindrical design that is removably installed to the inflator shell 8-16, which preferably seals by means of an O-ring 8-22. The ventilated end cover of the loading container 8-14 allows it to be filled with a desired amount of BTATz material which, upon ignition, produces a desired volume of nitrogen gas to inflate the inflatable article. The ventilated end cover of the cargo container 8-14 comprises a fulminating capsule seat configured to receive a fulminating capsule 8-26. The capsule fulminating 8-26 operates by striking to inject a spark in the charging vessel 8-14 to ignite the BTATz material contained therein. A trigger mechanism, indicated generally by the number 8-28, is provided to strike the capsule fulminating 8-26 one or more times by pulling a lanyard handle to pull 8-30. More specifically, the firing mechanism 8-28 comprises a cylindrical firing hammer 8-32 alternatingly positioned with an elongated hole 8-34 that moves in a forced manner towards the fulminating capsule 8-26 by means of a firing spring 8-34. An O-ring 8-36 is mounted around the trigger hammer 8-22 to seal with hole 8-34, thus preventing any gas leakage nitrogen during the shot. The lanyard handle for pulling 8-30 is coupled to a pivoting actuating lever 8-36. The activation lever 8-36 includes at least one lobe 8-38 aligned with an integral tongue 8-38 extending transversely from the firing hammer 8-32. Pulling the handle to pull 8-30, the lobe 8-38 pulls back the trigger hammer 8-32 against the force of the trigger spring 8-34 when pivoting the activation lever 8-36 until the lobe 8 -38 slides out of tab 8-38 to release spring-loaded trigger part 8-22. When the spring loaded trigger hammer 8-22 is released, the hammer 8-22 is forcedly moved by the spring 8-34 towards the capsule 8-26 to hit it and cause it to fire, thus producing the nitrogen gas which is then dewatered from the loading container 8-14 of the shell 8-16 through the discharge port 8-20 to inflate the inflatable article. As illustrated, preferably the activation lever 8-36 includes several lobes 8-34 (for example, three) such that with a single pull on the handle for pulling 8-30, each of the lobes 8-34 pulls sequentially back the firing hammer 8-32 and then slide out the tongue 8-38, thus firing the hammer 8-32.

A control unit 9-12 receives a signal from a pressure transducer 9-18 when the gas pressure in the storage tank falls below a predetermined level, at which point the control unit 9-12 provides an electrical current to the lighter 9-11 to fire a BTATz charge in the combustion chamber 9-10. The combustion chamber may contain several loads, which may be triggered independently as necessary to maintain the predetermined pressure level in the storage tank 9-6. In the case of an overpressure condition in the storage tank, an emergency pressure relief valve 9-4 opens and releases gas into the atmosphere through an exhaust pipe 9-5. Once the pressure falls to a certain safe level, safety valve 9-4 closes. The present description includes what is contained in the appended claims, as well as in the previous description. Although the present invention has been described in its preferred form with some degree of particularity, it is understood that the present description of the preferred form has been made only by way of example and that changes can be made in the details of construction and the combination and arrangement of parts.

TABLE I - PROPELLER APPLIANCES AND METHODS Publication Number Title RE36, 296 Propellant composition for 'automotive safety applications RE30, 327 Inflation seal RE36, 587 Inflatable safety belt with bag filter RE36, 661 Inflatable safety belt with leak detection device RE33, 938 Assembling air bag module for suction / venting 3, 934, 984 Gas generator 3, 938, 826 Aspiration system for containment of vehicle occupant 3, 942, 051 Powered electric pulse generator by collision 3, 942, 819 Safety belt tensioning device 3, 966,226 Fluid supply for occupant containment system 3, 971, 322 Pressure-operated tube primer 4, 008, 830 Liquid dispenser using non-contact pump ventilated and a foldable plastic bag 4, 023, 643 Passenger restraint device responding to deceleration 4,050,483 Delay of inflation impulse 4,061,088 Assembly of electric detonation fuse 4,179,327 Process for the coating of pyrotechnic materials 4,198,075 Safety installation in motorized vehicles with a knee impact element 4,200,615 Pyrotechnic inflator 4,203,786 Polyethylene binder for pyrotechnic composition 4.203.787 Solid gas-shaped, fast-burner nitrogen gas generator and cold 4,238,253 Starch as fuel in gas generating compositions 4,243,248 Airbag system for the protection of automobile passengers in case of accidents 4,244,758 Ignition-improving coating compositions for the azide propellant 4,246,051 Pyrotechnic coating composition 4,249,632 Safety device for the protection of pedestrians 4,369,079 Solid compositions generating nitrogen gas that do not contain azide 4,369,707 Short circuit fuse for lighters electric pyrotechnic gas generators that do not contain azide based on a tetrazole compound that does not contain hydrogen End cap for a propellant container Method for making the propellant container gas generator Propellant container gas generator Explosive bag air device Inflator for an inflatable cushion protector system Soft bark aerosol dispenser unit Apparatus for testing a smoke detector in the field Method of drug supplies and inhalation device of the same Propellant that conforms cone pills Air bag system Pressurized gas jet device increased propellant Method and compositions to generate nitrogen gas Autopressurized shock sensor Mechanical impact sensor for automotive shock bag systems 4,758,287 Porous propellant grain and method of making the same 4,761,254 Method of and apparatus for making a tool to form a hole of asymmetric constant cross section in the propellant in a solid rocket motor 4,766,799 Method of and apparatus for making a tool to form a hole of asymmetric constant cross section in the propellant in a solid rocket motor 4,798,142 Rapid burner propellant charge for automobile airbag inflators, rocket engines, and lighters for them 4,806,180 Gas generator material 4,834,817 Gas generating composition 4,845,377 Arrangement of circuits for the operation of a security system 4,864,086 Vehicle deceleration sensor 4,865,635 Filter assembly for the non-welded inflator 4,865,667 Gas-generating composition 4,877,264 Assembling the suction / ventilation air bag module 4,881.7 54 Safety device for the occupant of the central position of the rear seat in a car Generator of wafer grain gas Baffle ring for use with inflators with passive containment devices Generator of non-welded gas with roller spinning lip Air bag module and method of making it Vehicle airbag module and mounting method Shock sensor with improved activation for bore primer Gas generator for airbag Lightweight, non-welded inflation unit for automotive airbags Mechanical acceleration sensor Aspiration pump assembly Deceleration sensor Inflator housing structure Integral retainer, thermal shielding and assembly Deceleration sensor with safety catch means Occupant containment system and useful composition in it in the same , 982,664 Shock sensor with pressure disc release mechanism for perforator primer, 998,751 Two-stage automotive gas bag inflator using ignition material to retard the second ignition stage, 002,309 Automatic mobile, 005,486 Lighter for propellant grain air bag, 015,311 Primary compositions / detonators suitable for use in copper cups, 019,192 Primary compositions / detonators suitable for use in aluminum cups, 019,220 Process for making an azide gas generator of thermal stability and ignition, 022,674 Hybrid inflator dual pyrotechnic, 024,160 Rapid combustion propellant charge for automobile airbag inflators, rocket engines, and rocket lighters, 031,932 Simple pyrotechnic hybrid inflator, 033,772 Hybrid inflator, 035,757 Azida-free gas-generating composition with products easily filterable combustion Drilling initiator Assembly of ignition materials packages Linear bilateral inflator module Gas inflator device Rapid combustion propellant charge for automobile airbag inflators, rocket engines, and cigarette lighters Hybrid driver-side inflator and bag module air Air bag containment system with ventilation means Hybrid inflator Gas inflator Gas generator composition for air bags Air motorcyclist strips Compression and air storage device Electrothermal Inflatable Containment System Inflatable modules Laminated of air bags Liner method and apparatus of a vehicle frame Air bag lighter with double seal of glass 5,143,567 Approach of ballistic additives and control of slag melting point of azide-based gas generating compositions 5,149,129 Gas generator 5,160,386 Gas generating formulations containing poly (nitrite) metal complexes as oxidants and method 5,161,820 Safety device inflatable bag for cars 5,165, 830 Mass transit vehicle 5,179,982 Apparatus for discharging a fluid and, more particularly, for spraying a liquid 5,184,846 Mounting of inflators 5,197,758 Gas generating formulation that does not contain azides, method, and apparatus 5.197.759 Collision safety device air bag 5,199,740 Hybrid air bag inflator 5,203,427 Fire escape ladder with integral air cushion 5,207,450 Air cushion containment system aspirated 5,221,107 Pre-filter assembly , 223,184 Improved gas thermal stability and ignition generator, 224,734 Gas generator for air bags with vertical stack layout, 230,287 Low cost hermetically sealed detonator, 233,141 Passenger compartment mass shock sensors, 236,675 Gas generator with circumferential joints, 243,492 Procedure to manufacture a hermetic coaxial feed pin, 246,083 Inflatable air bag for automobiles, 249,826 Activation of the inertial mass security system for personal vehicles, 255,938 Tubular gas generator for an inflatable impact cushion , 256,904 Circuit that determines collisions with a start signal generating circuit .257.818 Apparatus for rapidly changing the temperature of a device in an inflatable containment system .257.819 Hybrid inflator, 259.644 Ignition unit, particularly for a gas generator of bag air, 260,038 Gas generator for bags of air with knives arranged circumferentially ,263,740 Hybrid Airbag Inflator 5,273,311 Gas Generator 5, 273,722 Gas Generator 5,277,440 Airbag Retention Device 5,286,054 Passenger Air Bag Module for Suction / Ventilation Automobile 5,294,414 Gas Generator, particularly a tubular generator gas for an airbag 5,295,709 Activation of the inertial mass security system of an airbag in personal vehicles 5,305,914 Pressurized gas bottle discharge device 5,308,108 collector or retainer for a gas generator ,309,138 Vehicle collision detection method using an acceleration sensor 5,314,203 Driver's side module attachment bracket 5,320,382 Pulsed pressure source adapted particularly for airbag containment systems of the vehicle occupant 5,322,018 Start-up deflagration material Area 5,322,322 System of protection against blows to the head lateral impact 5,324,075 Gas generator for the containment of the vehicle occupant 5,331,126 Pressure change apparatus for monitoring the pressure level in an enclosed chamber and methods for calibrating it and for making a movable contact arm for use therein 5,338,061 Air bag with double wall construction 5,340,147 Air bag inflator assembly 5,342,081 Air bag module with top mounted bag 5,345,873 Gas bag inflator containing inhibited generator 5,345,875 Gas generator 5,345,876 Hybrid air pump 5,351,619 Gas generator sheet or film ignition 5,351,988 Hybrid inflator with gradual inflation capacity 5,354,094 Airbag arrangement 5,360,956 Acceleration sensor for vehicles 5,362,100 Control circuit for a compressed gas inflator 5,364,127 Inflator assembly . 372,380 Filtter and method of formation 5,372,381 Air bag with inflatable ribs 5,374,407 gas generator with porous external wall 5,378,011 Air bag assembly 5,378,012 Air bag system cover structure ,378,018 Procedure for inflating a gas cushion and air bag type security system 5,383,388 Starting device 5,387,296 Approach for ballistic additives and control of the slag melting point of azide-based gas generating compositions 5,388,322 Method of making a unbreakable pressure vessel of the air bag inflator 5,397,543 Gas generator 5,398,967 Air bag inflator 5,401,340 Borohydride fuels in gas generating compositions 5,403,035 Preparation of the vehicle propellant air bag containment device containing cellulose 5,403,036 Lighter for an air bag inflator ,404,263 Assembly of totally glass head used in an inflator system Direct ignition by laser of ignition products Fabric containing the graft polymer in the same Generator of gas with novel nozzle structure Inorganic ceramic paper, its manufacturing method and articles produced from it Thermita Compositions for use as gas generators comprising base metal carbonates and / or base metal nitrates Low cost hermetically sealed detonator Mechanical acceleration sensor three points for automobiles Indicator device for a pressure vessel Intermediary generating gas for thermal stability and ignition azide Inflator for the air bag device Thermite compositions for use as gas generators Air bag module on the driver's side with extruded shell Mechanical acceleration sensor Solid pyrotechnic compositions with a thermoplastic binder and polybutadiene sililferrocene plasticizer Containment system for occupants of vehicles with laser ignition for an air bag gas generator Gas generator for containment of vehicle occupants System of occupant protection for vehicles. Inflatable tubular cushions for the protection of collisions of seated occupants of automobiles Inflatable safety belt with leakage detection device Inflatable safety belt with bag filter Double system of air bag for the containment of the occupant Air bag inflator with provision of fuel Gas-generating composition containing non-metallic salts of 5- Nitrobarbituric 5,474,328 Hybrid gas driven impeller ,480,181 Lateral impact head impact protection system 5,486,210 Air bag fabric containing graft polymer therein 5,486,248 Extruded gas generator for a hybrid air bag inflation system 5,487,561 Safety bag inflation apparatus using a liquid propellant gas generator 5,489,118 Air bag inflator 5,492,364 Breathable plastic wrap for an air bag inflator 5,494,312 Self-ignition of an inflator with fluid supply 5, 501, 152 Air bag gas generator with ignition agent spontaneous 5,503,079 Linear gas generator and filter structure for the gas generator 5, 504, 288 Sensor for use with the airbag inflator and method for processing 5,507,890 Gas-generator multi-layer disk for use in gas generators 5,507,891 Composition of propellant for applications of automotive safety 5,513,572 Hybrid inflator 5,516,146 Assembly of air bag without fastener 5,516,377 Gas-generating compositions based on 5-nitraminotetrazole salts 5,518,271 Activation of the inertial mass safety system of a safety belt restraint system in personal vehicles 5,525,306 Generator system gas 5,527,062 Air bag device for impact protection 5,527,067 Gas generator formed with electron beam welding 5,529,337 Air bag device 5,531,473 Initiator device containing fluid fuel for an air bag inflator 5,531,941 Method for preparing a gas generator composition azide-free gas 5,536,040 Inflator for side impact air bag 5,538,567 Gas generator propellant 5,538,568 Extruded gas generator for an airbag inflation system 5,542,688 Two-piece lighter for gas-generating compositions 5,542,695 System of the deployment of air bags , 542,701 Wire channel with integral closing mechanism and inflator, 542,997 Gas generating mixture, 544,687 Gas generating compositions using dicyanamide salts as fuel 5,544,913 Protective device to protect the vehicle occupant 5,544,916 Two-piece inflator wrap 5,547,214 Bag module side impact soft pack air 5,547,217 Air bag inflator and manufacturing method 5,549,769 Low entry, high temperature stable energy primer / detonator 5,551,343 Special geometry generating elements for automotive gas bag inflator 5,551,725 Bag inflator vehicle air and related method 5,552,472 Fabric containing the graft polymer therein 5,553,888 Detachable, snap-mounted handwheel with integral airbag cover 5,556,127 Seat-mounted side impact module 5,556,132 Vehicle occupant restraint with auto-ignition material 5,557,061 Low-energy input / detonator primer, stable at high temperature 5,560,642 Conductor air bag module assembly 5,562,303 Pyrotechnic mixture and gas generator for an air bag 5,564,734 Air bag mounted on the door ,566,543 PVC-based gas generator for hybrid gas generators 5,566,972 Air bag device 5,567,536 Inorganic ceramic paper, its manufacturing method and articles produced from it 5,570,904 Air bag inflator with mobile container ,571,988 Gas Producer Material 5,575,497 Method for Developing an Air Bag for Vehicle 5,575,499 Inflator for Air Bag Device 5,577,769 Hybrid Inflator for Inflating Air Bags ,580,086 Shock protection method and apparatus ,582,422 Inflator mounting frame 5,582,426 Ventilated ignition cup in the stored fluid inflator 5,584,505 Inflator assembly ,585,597 Air bag inflator 5, 586, 386 Sensor for use with air bag inflator and manufacturing method 5,586,782 Dual pressure side impact air bag 5,589,141 Use of mixed gases in hybrid air bag inflators 5,592,812 Metal complexes for use as gas generators 5,593,180 Double chamber inflator for side impact air bag 5,597,179 Air bag inflation devices and methods 5,601,308 Inflator, inflation fluid heater and mounting methods 5,607,180 Bag inflation devices and methods of air 5,607,181 Inflator with liquid supply with a porous containment device 5,615,914 Inflatable metal bladders for passenger car protection 5,622,380 Non-azide containing gas generator that has multiple propellant chambers 5,624,134 Gas generator formed with solder beam of electrons ,628,528 Gas generator that does not contain double chamber azide 5,630,616 Air bag inflator integrated to the seat structure 5,630,618 Hybrid inflator with one valve 5,635,665 Linear gas generator and filter structure for gas generator 5,639,116 Structure of the instrument panel in one vehicle 5,642,904 Two-piece inflator wrap 5,648,634 Electric starter 5,649,466 Rapid deployment method of volume displacement devices to restrict the movement of objects 5,652,389 Non-contact method and apparatus for the inspection of inertial welds 5,653,464 Air bag system with bag auto-forming air 5,658,011 Air bag apparatus of a tire air pressure sensing system for a vehicle 5,659,150 Gas-generating composition with cyanamide and transition metal nitrate 5,659,295 Sliding-piston pressure sensing device Hybrid inflator Inflator filter to produce helical gas flow Simple pyrotechnics Metal complexes for gas generators azido polymers with improved burning speed Gas generator body with compressed layer to inhibit burning Moderation of combustion in a bag inflator of air Integrated switch for deactivation of air bags Air bag module with flexible base for mounting cover Vehicle steering arrangement Protective device Procedure for manufacturing a glass-to-metal tight seal Hybrid inflator with coaxial camera Vehicle seat for children equipped with air bag and alarm system / armed for the same Inflator for vehicle air bags ,719,351 Anti-rupture method for liquid propellant gas inflator 5,720,519 Children's vehicle seat equipped with air bag and alarm system / armed for the same 5,721,392 Pyrotechnic ignition device 5,725,245 Diffuser plate for an air bag gas generator 5,725,699 Metal complexes for use as gas generators 5,726,382 Eutectic mixtures of ammonium nitrate and amino guanidine nitrate 5,727,813 Air bag inflator 5,734,123 Extrudable gas generating compositions 5,735,118 Use of complex metal compositions as gas generators 5,738,374 Pyrotechnic gas generator for pouch of inflatable air of an automobile 5,741,465 Installation and method of deactivation of reactive waste 5,746,445 Characteristic of completion of the injection . 746,446 Plastic film air bag 5,747,696 Non-invasive method of monitoring the pressure of a compressed gas in a closed container 5,747,730 Pyrotechnic method of generating a gas odorless and colorless, non-toxic, non-toxic 5,752,717 Inflatable metal bladders for passenger car protection 5,755,457 Air bag device 5,756,929 Gas-generating compositions that do not contain azide 5,756,930 Procedure for obtaining gas generating compositions 5,762,369 Bag inflator air that uses monopropellant liquid and adaptable to produce outputs with various parameters 5,763,027 Insensitive pressure vessels of ammunition compositions 5,763,817 Central gas filling inflator 5,763,821 Self-igniting propellant containing superfine iron oxide 5,765,867 Air bag with externally attached fastening ,769,452 Vehicle occupant protective airbag system 5,772,239 Airbag submodule having a cloth housing with horn switch 5,773,754 Gas generator agent with trihydrazine triazine fuel 5,779,261 Airbag retention arrangement of vehicles 5,779,263 Side impact airbag system integrated in a seating structure 5,779,269 Assembly of the propellant module 5,780,768 Gas generating compositions 5,782,486 Rapid gas filling apparatus and method , 782, 487 Gas generator. 5,783,773 Low-residue azide-free gas generating composition 5,787,563 Method for assembling a compressed air bag inflator 5,788,275 Hybrid inflator 5,791,340 Resuscitator 5,791,685 Three-side impact airbag 5,792,976 Rapid deployment volume displacement system Quickly to restrict the movement of objects 5,794,973 Double-stage air bag inflator 5,799,469 Method for the manufacture and / or filling of a two-chamber pressure package 5,799,974 Vehicle air bag system 5,801,453 Procedure for preparing spherical energy compounds 5,803,488 Inflator retainer and bag module air 5,806,885 Ignition hole in inflator provisioned with fluid 5,806,886 Device to decrease carbon monoxide in air bags 5,806,888 Air bag inflator 5,817,972 Iron oxide as a coolant and waste former in an organic propellant 5,821,448 Hybrid inflator Compact 5, 823,566 Air bag module with deployment flap 5,833,264 Inflator assembly for a vehicle air bag system 5,833,311 Child seat 5,836,610 Air bag inflator provided with multi-level fluid 5, 839, 754 multi-stage airbag gas 5,847,315 Clean gas generator exhaust from vehicle bag of solid solutions 5,850,053 Eutectic mixtures of ammonium nitrate, guanidine nitrate and potassium perchlorate 5,851,027 Variable output driver-side hybrid inflator 5,851,028 Inflator with flow diverter and heat sink heat Containment, gas pressure detection and release systems Variable ventilation envelope Gas-generating compositions Energy and communication device Inductively coupled gas-generating composition consisting essentially of ammonium perchlorate plus a chlorine scavenger and a fuel organic Plastic film air bag Inflatable metal bladders for passenger passenger protection Inflator substantially smoke-free and particle-free for the inflatable containment security system of gas-generating compositions that do not contain azide Side-mounted impact module Airbag system for automotive passenger seat Airbag inflation system suction type Airbag system mounted on seats Side impact air bag system Air bag module with simplified manifold Air bag arrangement and trigger procedure Ventilation system for air bag systems Air bag device Air bag catalytically plated inflator for vehicle air bags Explosive semiconductor bridge device Hybrid inflator with hole and bursting disc Mounting and igniter method Inflator mounting for a vehicle air bag system Ignition system for a fluid inflator Vehicle stabilizer device of two-chamber inflator External body structure impact absorber of an automobile Air bag device Hybrid air pump Security system sensor operator seats for a car 5,944,343 Miniature Inflator 5,947,510 Airbag module 5,947,514 Automotive controlled pyrotechnic system 5,951,040 Air bag inflator with pressure regulation 5,951,042 Vehicle occupant protection device 5, 951., 043 Airbag inflator that uses a monopropellant liquid and adaptable to produce outputs with various parameters 5,962,803 Apparatus for preparing spherical energy compounds 5,962,808 Complex gas-generating oxidants 5,967,550 Pyrotechnic air bag inflator ,970,703 Metal hydrazine complexes used as gas generators 5,976,293 Method for making a case for combustible materials 5,979,328 Vehicle impact indicator device . 984.351 Double stage drive system 5.984.352 Air bag inflator with pressure regulation 5,988,069 Electric starter having a material sealant forming a ceramic-to-metal seal, 988,438 Apparatus for rapid inflation of an inflatable object and related method, 997,666 Gas-generating composition GN, AGN and KP, 000,718 Mounting of end caps for the airbag inflator, 004,410 Apparatus comprising an inflatable vehicle occupant protection device and a gas generating composition therefor, 009,809 Cursor yarn initiator, 012,737 Vehicle occupant protection apparatus, 017,404 Gas-generating compositions containing no azide based on nitrate Ammonium burned at ambient pressure .019.389 Air bag inflator .019.390 Multiple panel air bag, 020.655 Control circuit for one air bag release unit, 029,558 Reactive personal protection system, 029.932 Knock valve to release openings of airbag landing systems, 036,226 Inflator capable of modulating the inflation speed of an air bag in a device containment of vehicle occupants .039.347 Liquid propellant air bag inflator with double telescopic pistons .039.348 Variable output inflator with adaptive heat sink, 039,820 Metal complexes for use as gas generators, 042,147 air bag device, 045,638 compositions monopropellant and propellant including mono and polyaminoguanidine dinitrate, 047,541 Propellant tank pressurizer HAN TEAN mixed gas generator (xm-46) for launch vehicles and spacecraft, 050,598 Apparatus for and method of monitoring the amount of mass and the density of a fluid in a closed container, and a vehicular air bag system incorporating such an apparatus, 053,110 Design of air bag generating wafers with beam construction in I, 053,270 Steering angle correction system that in the vehicle, 059,906 Methods for preparing propellant compositions stabilized with time, 062,142 Sis auto-ignition theme for devices inflators with separator that melts, 062,143 Distributed charge inflator system, 065,773 Gas pressure retention, detection and release systems, 068,287 Electronic device and method to operate a passenger protection system, 073,438 Preparation of eutectic mixtures of ammonium nitrate and amino guanidine nitrate, 073,961 Inflatable side air bag curtain module, 073,963 initiator with molded insert member by injection, 074,502 Smokeless gas generating compositions, 076,468 Solid gas / water propellant hybrid gas generator, 079,739 Gas pyrotechnic generator with an adaptable flow rate for air bags, 086,095 Air bag cushion showing low seam use and fabrics and simultaneously high volume of inflation available. , 093,269 Gas-generating pyrotechnic composition including fuel with high oxygen balance, 095,558 Gas generator made of metal sheets for protective devices passenger cars 6,095,561 Multi-chamber inflator 6,099,033 Compressed air bag inflator 6,106,038 Collision damage reduction system 6,109,647 Seating occupant restraint system 6,116,641 Double level gas generator 6,117,255 Gas generating composition comprising guanylurea dinitramide 6,120,058 Air bag inflator 6,120,626 Fibrous cellulose blowing material 6,123,359 Inflator for use with gas generating compositions containing guanidines 6,123,790 Gas generating compositions based on ammonium nitrate do not contain azide that burns at ambient pressure 6,126,197 Air bag inflator without light disk filter 6,131,949 vent systems for inflatables 6, 139, 054 Reduced smoke gas generator with improved temperature stability 6,142,056 Variable thrust cartridge 6,142,508 side impact air bag 6,142,511 Inflatable restraint of the passenger and inflator thereof 6,142,515 Air bag inflator with heat sink and retainer 6,142,518 Dual inflator that includes a pyrotechnic inflator 6,143,103 gas generator material for vehicle occupant protection device 6,145,876 Vehicle inflator with gas storage to provide inflation 6,149,184 simplified bag assembly Driver's side air bag 6,149,194 Plastic film air bag 6,155,600 Safety air bag inflation device 6,156,137 Gas generative compositions 6,156,230 Metal oxide containing the gas generating composition 6,165,295 Gas-generating liquid compositions (PERSOL 1) 6,170,594 Method and apparatus to reduce the turnover of the vehicle 6,170,868 Hybrid inflator 6,176,517 Gas generating apparatus 6,176,950 Gas-generating propellants based on ammonium nitrate and paraffinic material 6,179,326 Efficient air bag system 6,182,782 Device to reduce the impact of pedestrians 6,186,540 Filling method of an empty flexible container, and a container device 6,186,541 Air bag arrangement with gas filtration 6, 186, 543 airbag for the passenger car seat 6,189,919 Steering column arrangement for occupant protection 6,189,922 Inflator with multiple initiators 6,196,577 Air bag apparatus 6, 196,581 Air bag inflator and air bag apparatus 6,196,582 Variable outlet inflator for an air bag 6,196,583 Gas generator with cooling device 6,199,900 Headrest safety system for vehicle collisions 6,199,905 High thermal efficiency inflator and passive retainers incorporating the same 6,203,061 Output air bag module variable with PAV heat sink 6,210,505 Gas generators that do not contain azide and high gas performance 6,213,496 Air bag device with internal and external bags 6,213,502 Air bag module with variable inflation 6,214,138 Ignition improver composition for an airbag inflator 6,217,067 Flame protection for a gas bag 6,218,577 Hydrazinium salts Energy 6,220,309 Inflatable fabrics comprising basket fastening points between cloth panels 6,220,626 Air tape apparatus 6,224,097 Inflator for inflatable retainer 6,224,099 Gas generating device of supplemental containment system with water-soluble polymeric binder 6,224,100 Air bag apparatus, airbag folding method, and air bag folding device 6,227,565 Air bag inflator with pressure regulation 6,227,566 Air bag device with inflator 6,228,191 Gas generating preparation with iron and / or copper carbonate 6,230,491 Liquid gas generating compositions (persol 1) 6,230,501 Ergonomic systems and methods that provide intelligent adaptive surfaces and temperature control 6,234,523 Dual-type inflator device where the phenomenon of light emission is suppressed 6,235,132 Gas generating compositions 6,237,941 Inflatable curtain module of the side air bag 6.237.950 Pneumatic air bag inflator 6.237.951 Device to allow a pressurized gas stream in a safety device 6,241,281 Metal complexes for use as gas generators 6,247,726 Air bag module with variable inflation 6,250,668 Tubular air bag, method of preparation of the same and occupant protection system that includes the same 6,254,164 Vehicle occupant protection system 6,257,527 Hypersonic and orbital vehicle system 6,257,617 Air bag inflator with pressure regulation 6,266,926 Apparatus and method gas generator deployed occupant protection 6,270,113 Side air bag system 6,274,064 Metal oxide containing a gas generating composition 6,274,252 Useful glass-to-metal seal on airbag heads 6,277,221 Propellant compositions with salts and complexes of lanthanide and Rare earth elements 6,283,543 Car roof 6,287,400 Gas generating composition 6,290,256 Air bag inflator with pressure regulation 6,293,581 Occupant containment device 6,293,582 Airbag control system in different vehicle locations 6,294,487 Very low coverage factor for processing of air bag fabrics 6,296,274 Apparatus for inflating a side curtain 6,298,787 Weapons system and method of non-lethal kinetic energy 6,299,203 Air bag device in a vehicle and method for activating an air bag device 6,299,204 Vehicle restraint system what it comprises an air bag having an integrated mouth. Vehicle containment system comprising an air bag having a loop-shaped cavity for the provision of an inflation cartridge. Vehicle containment system comprising an air bag having an integrated mouth Gas-generating liquid compositions (OXSOL 3) Inflatable fabrics comprising detachment seams that become cut seams during inflation Automotive automotive airbag propellants that do not contain thermally stable azide High capacity inertial change device of type of Microelectromechanical Systems (MEMS) Air Bag Inflator Water-free preparation of lighter granules for waterless extrusion processes Method for making a propellant that has a relatively low burning speed exponent and high gas performance for use in a vehicle inflator 6,325,408 Fixation of air bags 6,328,830 Gas-generating composition based on 5-aminotetrazole-free metal oxides 6,328,831 Liquid gas-generating compositions (Perhan) 6,328,906 Chemical supply systems for fire suppression 6,331,220 Gas-generating liquid compositions (PERSOL 2) 6,334,917 Propellant compositions for apparatus gas generators 6,334,961 Composition of ash-containing and ignition-grade gas for passive vehicle occupant restraint systems 6,336,657 Restraint system for occupant seats 6,340,175 Air bag assemblies with foamed energetic lighters 6,341,562 Starter assembly with activation circuits 6,343,812 Method to fix an adjustable steering column of the automobile and device to perform the method 6,352,030 Gas generator ejection engine 6,361,064 Inflator seal retainer for a air bag module 6,361,631 Liquid monopropellant for passive vehicle occupant containment systems 6,363,307 Control system for occupant protection 6,364,350 Car occupant safety device 6,364,353 Double stage air bag inflator 6,364,356 Air bag cushion including seam reinforcement seams 6,364,975 Ammonium nitrate propellant 6,368,431 Air bag inflation 6,371,517 Inflation adaptive mechanism 6,373,384 Inflatable safety device 6,375,219 Air bag cushion showing little use of fabric and simultaneously high inflation volume available 6,379,627 Generator of gas 6,382,660 Air bag assembly 6,400,145 Seat belt tension sensor, integration and fastening methods 6,402,191 Inflatable air bag system that serves as a protective wall in front of a side wall of a vehicle 6,409,213 Adapted mechanism inflation 6, 409,214 Air bag inflator and air bag apparatus 6,412,391 Personal protection reactive method and system 6,416,600 Procedure for the production of an exothermically reactive composition 6,417,579 Electrical system with safety battery disconnection 6,418,870 Release mechanism and method torpedoes 6,419,262 Occupant protective device located on the steering wheel of a car 6,422,601 Dual chamber inflation 6,425,601 Air bag module 6,427,599 Pyrotechnic compositions and uses thereof 6,428,041 Car air bag system 6,431, 582 Simplified air bag assembly driver's side 6,431,594 Air bag inflator with mechanism for second stage deactivation and autoignition 6,431, 597 Reduced smoke gas generator with improved mechanical stability 6,435,552 Method for gas inflation articles 6,439,603 Air bag module with in variable flation 6,447,007 Compact nozzle air bag inflator 6,450,529 Inflatable side air bag curtain module with chamber spacers 6,450,573 Anti-submarine vehicle seating device 6,454,299 Air bag device 6,454,306 Gas generator for safety belt pretensioner 6,454,887 Gas generator for air bag 6,457,741 Air bag lateral mounted on the seat 6,464,253 Vehicle containment system 6,472,033 Air bag cushion showing little use of seams and simultaneously high volume of inflation available 6,472,352 Aqueous lubricant and process for cold forming metal, with improved formed surface quality 6,474,684 Double stage inflator 6,475,312 formulation of a gas generating composition 6,477,957 Ignition device for a safety system 6, 478, 329 Airbag 6,481,746 Metal hydrazine complexes for use as gas generators 6,481,747 Cold pyrotechnic inflator with low effluent 6, 485, 403 One air bag folding air bag system 6,485,588 Self-ignition material additive 6,487,974 6,488,310 Inflator Hybrid air pump 6,489,006 Inflatable fabrics comprising detachment seams that become cut seams during inflation 6,497,429 Bagging Apparatus of air 6,497,774 Gas generator for airbag 6,508,894 Formulations of the insensitive propellant containing energy-efficient thermoplastic elastomers 6,511,094 Airbag system for motor vehicles 6,513,602 Gas-generating device 6,513,834 Monopropellant-free smoke-generating gas materials 6,513,835 automotive airbag 6,513,880 Power driver suitable for vehicle occupant containment systems 6,523,855 Airbag, manufacturing method and system of the same 6,530,543 Hypersonic and orbital vehicle system 6,533,316 Automotive electronic safety net 6, 533,318 Air bag system for the passenger seat of motor vehicles 6,536,798 Activation of control of containment devices in a vehicle 6,539,869 Initiator of heat transfers 6,543,805 Double air bag inflator 6,547,275 Gas generator of air bags and airbag device 6,547,277 Two-chamber gas generator 6,556,119 High-current fuse device 6,557,474 Starter sub-assembly for inflation devices 6,560,832 Structurally efficient airbag cushion with high inflation volume available 6,566,869 Seat belt tension sensor, integration and fixing methods 6,568,703 Interference mounting fixation for a rounded member 6,572,136 Automotive air bag system 6,572,144 Air bag 6. 574,962 KOH combustion gas recirculation electric power plant with waste heat recovery and byproduct 6,581,963 Catalytic filter for an inflator 6,581,964 Gas bag module 6,584,911 Initiators for airbag inflators 6,585,290 Diffuser for an airbag 6,595,102 Reactive personal protection system and method 6,595,244 Inflatable fabrics having knitted fastening points between cloth panels 6,595,548 Airbag system, airbag folding method and bag folding apparatus air 6,598,899 Inflatable safety belt using MEMS devices 6,598,901 Gas generator for air bag and air bag apparatus 6,598,902 Welded air bag cushion comprising reinforcement seams 6,601,872 Compact multi-level inflator 6,604,599 System of containment of occupants of antisubmarine vehicles 6,605,233 Gas generation composition with refrigerant 6,607,213 Gas generator device for gas bag air and method to inflate the air bag 6,612,243 Fire extinguisher 6,612,610 Air bag device 6, 619, 692 Air bag inflators 6,623,033 Airbag inflation control and method 6,626,455 Deformable envelope of bags of air bags air 6,626,457 Curtain airbag 6,629,575 Vehicle occupant emergency system 6,640,721 Non-lethal airbag ammunition 6,641,074 Seat belt tensioner pretensioner using MEMS devices 6,644,206 Electric drive starter with output load 6,648,366 driver's side air with particle diverter 6.648.367 Integrated occupant protection system 6,650,528 Ignition device for a security system 6,659,500 multi-chamber inflator 6,666,934 Extruded material polybutadiene gas generator with hydroxy termination 6,669,226 Air bag module with inflators Opposite aligned 6,669,229 Automotive airbag system 6,669,231 Adaptive ventilation for an airbag module 6,672,220 Apparatus and method to disperse a projectile ammunition 6,672,618 Multiple panel airbag and method 6,673,172 Gas generating compositions that exhibit low autoignition temperatures and gas generation methods thereof 6,673,728 High resistance, low permeability timing fabric, for use in airbag inflation modules 6,679,522 Airbag 6,688,231 Gas generator type Rope 6,688,555 Anti-sequestration system 6,695,259 Communication system, communication receiving device and communication terminal in the system 6,701,849 Double-stage air bag inflator with secondary propellant capsule 6,702,323 Air bag module with pressure regulator 6,705,637 Inflator 6,709,006 Air bag device 6,713,412 High resistance and low permeability timing fabric, for use in air bag inflation modules 6,715,371 Test method of an air bag module 6,715,790 Side curtain air bag 6,718,884 Assembly of initiators 6,719,323 Air bag and flywheel 6,726,788 Preparation of reinforced ammonium nitrate propellants 6,733,036 Automotive electronic safety net 6,739,362 Hybrid gas generator, particularly for filling a gas bag 6,746,044 Fastener Operable for the venting of an air bag module 6,749,218 External deployment air bag system 6,755,273 Combined airbag inflation and method and apparatus that allows occupant displacement 6,758,199 Tuned energy ignition system 6,764,096 Double chamber inflator 6,767,030 Airbag system for automobile passenger seat 6,779,464 Gas generator composition 6,789,702 System for stock component products manifolds 6,789,820 Variable outlet inflator 6,793,244 Hybrid multipurpose expansion tire inflator 6,796,579 Gauze generator with air bag device 6,799,776 Hybrid inflator 6,805,376 Inflator with shock wave generator 6. 805.377 Inflator 6,805,380 Passive vehicle safety device 6,808,204 Hybrid Inflator 6,823,244 Vehicle parts control system including electronic sensors 6,823,645 Radial tube airbag folding apparatus and method radial 6,834,885 Inflator 6,835,102 Connector provided with front fastener 6,837,517 Multiple panel airbag and method 6,843,503 Controlled venting device and method for the same 6,851,709 Hybrid inflator type of multistage inflation 6,854,762 Air bag system 6,860,510 Hybrid inflator type of multistage inflation 6,860,511 Double-chamber multi-stage inflator 6,860,951 Gas generating compositions 6,863,303 Hybrid inflator 6,865,825 Ergonomic systems and methods that provide intelligent adaptive surfaces and temperature control 6,871,871 Air bag inflator 6,874,544 System for supplying multiple component products 6, 877, 435 Two stage gas generator using a Ecologically Friendly Gas Generator Formulation 6,877,698 Inflatable Evacuation + Inflator System that uses a stored liquefied gas capable of thermal decomposition 6,883,827 Modular system of airbag cushions 6,886,469 Distributed load inflator system 6,887,326 Gas generating compositions that do not contain azide 6,889,613 Variable outlet inflator 6,889,614 Air bag inflator 6,892,983 Anti-sequestration system 6,905,135 Inflator system 6,908,149 Anti-submarine vehicle seating device 6,910,713 Airbag cushion that presents little use of fabric and simultaneously high volume of inflation available 6,913,319 Energy actuator 6,913,661 Ammonium nitrate propellants and methods to prepare the same 6,918,340 Double stage gas generator that uses the ecologically friendly gas generation formulation Friendly for military applications 6,918,459 Method and apparatus for deploying airbags 6,918,611 system and method for the control of an inflatable cushion 6,918,976 Gas-generating composition 6,923,342 Systems for supplying multi-component products 6,926,303 Inflatable vehicle occupant protection device with inflation fluid diverter 6,926,792 Method of manufacturing an airbag and a air bag manufactured by the method 6,936,303 Electric type starter and gas generator 6,945,559 Method and apparatus for venting air bags 6,951,317 Vehicle, light pneumatic pilot valve and related systems thereof 6,953,823 Composition of elastomeric insulation for a solid propellant rocket engine, 962,113 segmented rods combat warhead, 962,363 Multiple chamber air bags and methods, 966,373 Inflatable closure assembly and method for sealing an inner part of a flux carrier 6,969,435 Metal complexes for use as power generators gas 6,979,022 Flexible inflator with propellant and moisture barrier joint 6,979,024 Gas generator for safety belt pretensioner 6,983,955 Air bag inflators 6,988,026 Wireless sensor and interrogator without power 6,991,254 Air bag system 6,997,477 Inflator 7,004,074 Dsuminist burst cartridge controlled fluid energy 7,007,972 Method and Inflating device for air bags using magnetic fluid 7,017,944 Multiple chamber inflator 7,025,378 Air bag and method for making an air bag 7,042,696 Systems and methods using a electrified projectile 7,048,304 Multiple panel airbag and method 7,052,041 Gas generator and gas generator package used in the same 7,057,872 Systems and methods for immobilization using selected electrodes 7,059,633 Hybrid gas inflator 7,059,635 Hybrid inflator 7,069,961 Inflatable fabrics comprising fastening points of basket fabric between cloth panels 7, 070,204 Programmable gas generator using microcells 7,073,820 Inflator 7,080,854 Linear pyrotechnic inflator 7,080,855 Safety direction column, motorized vehicle with safety system and method 7,082,359 Vehicle information and monitoring system and methods 7,089,099 Sensor assemblies 7,097,203 Inflator 7,103,460 System and method for vehicle diagnostics 7,104,569 Air bag module with pressure regulator Ergonomic systems and methods that provide intelligent adaptive surfaces and temperature control Automotive vehicle air bag system Air bag apparatus and related method Safety barrier Air bag system for automobile passenger seat TABLE II - SUPPRESSORS OF FIRE AND METHODS Publication Number Title 20020023967 Apparatus and method of fine mist of effervescent liquid 20020070035 method and system for extinguishing fire in an enclosed space 20020139542 Process and facilities for combating fire in an aircraft and airplane compartment equipped with such facilities 20020144824 Microemulsion fogs as fire suppression agents 20030006046 Extinguishing ball 20030019641 Fire suppression system and method for a fire interior fire protection area of a waste container of the airplane basin 20030051886 Fire suppression using water mist with ultrafine droplets 20030062173 Fire extinguishing method with gas and fire extinguishing equipment 20030062175 Fire suppression system and solid propellant aerosol generator for use therein 20030141082 Supply system of liquefied gas portable breathable fire extinguisher 20030150623 Fire extinguishing spray boom 20030155134 Fire blanket 20030205390 Method and apparatus for distributing granular material 20040016551 Methods and apparatus for extinguishing fire 2004002066 Total fire suppression system with helium gas 20040020666 Explosion suppression 20040045725 Modernized halon-free fire suppression system and systems based modernization method of existing halon-based systems 20040069505 Method and apparatus for extinguishing fire in areas beyond the reach of equipment for standard fire 20040089460 Fire suppression system and method 20040129435 Flame suppression agent, system and uses 20040140105 Combustion suppression system 20040163826 Fire protection systems and methods 20040188103 Thermally activated fire suppression system 20040194974 Pressurization system for fire extinguishers 20040194977 System self-modulating inert gas fire suppressor 20040226726 Fire extinguisher for vehicles 20040262018 Fire extinguisher cover 20050016741 Extinguishing system for large structures 20050023007 Methods using fluorocetones to: extinguish fire; avoid fire; and reducing or eliminating the flammability of a flammable working fluid 20050051345 Fire blanket 20050077054 Methods and apparatus for extinguishing fire 20050115722 Method and apparatus for fire suppression 20050139363 Fire suppression supply system 20050139365 System and method for suppressing fire 20050139366 Method and apparatus for extinguishing a fire in a fire closed area 20050139367 Extinguishing device and method 20050150663 Extinguishing device 20050178566 Fire extinguisher with means to prevent freezing at exit 20050183869 Fire suppression system for an aircraft 20050189123 System and method for suppressing fire 20050217871 Fire suppression system and method for a fire interior area of a fire protection container for aircraft washbasin waste 20050257937 Device for extinguishing fire by the injection of a gas generated by the combustion of a pyrotechnic block 20050263299 Method of extinguishing fire by gas and extinguishing device 20060011356 Store resistant to fire for building structures 20060076430 Methods and systems for simulating multi-phase fluids flows, including fire suppressor flows 20060175429 Fire fighting system 20060196681 Fire suppression using water mist with Ultra-fine droplets 20060201687 Automated residential fire extinguisher independent 20060213673 Method to prevent fire in a computer room and other enclosed facilities 20060231270 Automotive fire suppression system with dynamic tank seal 3, 930, 541 Flame prevention system for fuel tank fires 3, 952, 809 serial to parallel transfer circuit for initiator chain 3, 964, 390 Assembly of bursting disc 3, 965, 988 Method and apparatus extinguishers 3, 967, 255 Flame detection system 3, 980, 139 Fire extinguishing pump 3, 986, 560 Fire protection means 3, 990, 516 delay pneumatic valve 4, 006, 780 Breaker head for fire extinguishers 4, 013, 128 Modular fire protection system 4, 020, 904 Dispersion nozzle with removable dispersion element 4,020,905 Construction fire extinguishers 4, 046, 156 Explosion discharge valve 4, 055, 844 detection system 4, 064, 944 Apparatus for the extinguishing system for floating roof tanks 4, 069, 873 Apparatus for the extinguishing system for tanks floating roof 4,073,464 Cylindrical valve for gas extinguishing system 4,082,148 Fire protection system 4,090,567 Fire fighting helicopter 4,109,726 Gas extinguishing system 4,110,812 Non-recurring pulse generator 4,121,666 Fuel tank fire extinguisher (flammable liquid) 4,126,184 Dual valve Instant release, for fire suppression apparatus 4,129,185 fire suppression system 4,132,271 Fragment prevention screen for fire suppression panels that can explode 4,159,744 Fire extinguisher mechanism 4,183,409 Automatic fire extinguishing system 4,188,856 compressed gas operated switching device 4,194,571 Mechanism of fire suppression for military vehicles 4,199,029 Multiple fire suppression devices of independent operation each with an individual power source of action 4,201,178 Fire protection of engines 4,213,567 Discharge nozzle for a fire suppression system of fluorinated hydrocarbons 4,217,959 Electrically controlled fluid disperser for a fire extinguishing system 4,232,742 Flame guard for electrical installations 4,262,749 Fire Suppression bladder system for fuel tanks 4,263,971 Fire Suppression and Explosion Apparatus 4,267,890 Extinguishing system including a comparable sensor to determine the load 4,270,613 Fire and explosion detection and suppression system 4,275,860 Provisioning system full-board full-board fuel for aircraft 4,281,717 Explosion suppression system for fire or explosion-susceptible enclosures 4,285,403 Explosive fire extinguisher 4,289,207 Extinguishing system 4,296,817 Fire suppression system for military tanks 4,305,469 Extinguishing system that has a safety valve discharge and a distribution valve driven by a pneumatic actuator 4,319,640 Fire suppressor mechanism powered by gas generator 4. 328,867 Fire extinguishers 4,328,868 Fire suppressor impact diffuser 4,332,368 Valve 4,347,901 Fire extinguishing system for aircraft 4,351,394 Method and system for fire protection in aircraft 4,390,069 Fire fighting system with trifluorobromomethane foam 4,394,868 Horizontal discharge assembly for fire extinguisher vertically oriented fire 4.411.318 Fire extinguishing waste receptacle 4,420,047 Storable fire suppression system for aircraft cabins and the like 4,436,159 manually / electrically activated detonator discharge valve for fire extinguishers 4,462,319 Method and apparatus for controlling safely explosions in black liquor recovery boilers 4,487,266 Explosion suppression device 4,488,603 Compact and quite mobile fire fighting vehicle 4,499,952 Fire and explosion detection and suppression system and drive circuit thereof 4,520,871 Extinguishing system 4,531,588 Fire suppression system 4,532,996 Automatic fire extinguisher with acoustic alarm 4,567,948 Fire extinguisher valve 4,569,399 Safety lock 4,577,544 Ultrafast thermal actuator 4,580,638 Suppression and fire control system 4,583,597 Fire and explosion detection and suppression system 4,589,496 Fire suppression valve using a floating stem valve 4,592,301 Fire extinguisher support mechanism incorporating an audible alarm 4,597,451 Fire detection and suppression and explosion 4,606,832 Fire extinguishing composition 4,616,694 System fireproof cabinet for electronic equipment 4,617,174 automatic self-contained apparatus for rapid production of polyurethane foam 4,622,209 Procedure and apparatus to reduce the chances of ignition and explosion due to the decomposition of high-pressure industrial process gases 4,625,808 Device for coupling fire extinguishers a closing-off compartments 4,630,684 Method of detection and suppression of fire and system sensitive to optical radiation and mechanical wave energy 4,633,967 Indirect safety system for a vehicle 4,637,472 Rapid discharge fire extinguisher 4,637,473 Fire suppression system 4,643,260 suppression of fire with controlled secondary extinguishing discharge 4,645,009 Method and means to produce and supply extinguishing fluids 4,646,848 Fire suppression system for an aircraft 4,650,003 Light trajectory heat detector 4,662,454 Foam extinguishing system 4,664,199 Method and apparatus for extinguishing fires in storage containers filled with flammable liquids 4,668,407 Composition for fire extinguishing and method for preparing fire 4,676,319 Fire fighting tool and method fires 4,691,783 Automatic modular fire extinguishing system for computer rooms 4,693,320 Fire suppression test apparatus 4,697,643 Pressure controller compensated by the temperature, operationally reliable extinguisher provided with said pressure and process controller to fill said pressure controller 4,702,322 Explosion suppression system 4,709,763 Automatic fire extinguisher 4,711,307 Compact autonomous fire extinguisher 4,718,497 Fire and explosion detection and suppression 4,719,973 Fire detection and suppression and explosion 4,726,426 Fire extinguishing system for an aircraft passenger cabin 4,729,434 Portable fire fighting device 4,760,886 Rapid discharge fire extinguisher and a method of manufacturing it 4,763,731 Fire suppression system for aircraft 4,779,683 Control head discharge for fire extinguisher containers for aircraft 4,805,701 Fire extinguisher and alarm apparatus 4,815,541 Fire extinguisher 4,826,610 Fire extinguisher 4,830,114 Self-extinguishing fire extinguisher 4,830,116 Fire extinguishing system 4,830,762 Method for extinguishing fire l Chlorosilane liquid compound fire 4,834,187 Explosion Suppression System 4,854,388 Fire Extinguisher 4,854,389 Linear Fire Extinguisher 4,856,762 Fire Retardant Gas Spring Assembly for Passenger Seat Control 4,889, 189 Fire Suppressor Mechanism and Method to Classify Fire 4,893,680 Fire Suppression Activator 4,895. 208 Elevator cab fire extinguishing system 4,899,826 Combination fire extinguisher and tire sealant 4,938,293 Linear fire extinguisher 4,951,755 Manual actuator 4,953,623 Protected L-shaped environment using a single chemical nozzle 4,953,624 Cylinder pressure switch for systems automatic fire protection 4,954,271 Non-toxic fire extinguisher 4,964,469 Device for dry broadcasting material by explosive force 4,970,936 Gas storage operation device 4. 986.366 Method and apparatus for suppressing explosions and fires 4,989,675 Spray nozzle for fire control 4,991,657 Fire suppression system 5,014,790 Method and apparatus for fire control 5,016,715 Fire extinguishing system in elevator cabins 5,018,586 Fire suppression system for a decorative tree 5,031,701 Suppressor discharge nozzle for Explosion protection system 5,036,924 Container fire nozzle hole adapter 5,038,866 Powder discharge device 5,040,609 Fire extinguishing composition and process 5,050,683 Solid propellant rocket / missile extinguisher 5,052,493 Fire suppression systems for vehicles ,053,147 Methods and compositions to extinguish fires ,062,486 Fire Barrier Penetrator and Agent Injector 5,069,291 Method and apparatus to suppress explosions and fires and prevent re-ignition thereof 5,088,560 Zero force fire extinguisher 5,090,482 Method and apparatus to extinguish fires 5,093,013 Ozone friendly fire extinguishing agents ,099,976 Fire extinguishing apparatus for compressors ,102,557 Fire extinguishing agents for fluid applications 5,113,947 Fire extinguishing methods and compositions using 2-chloro-1,1,1,2-tetrafluoroethane . 115.867 Dual linear fire extinguisher 5.115.868 Fire extinguishing composition and process . 119,877 Explosion suppression system 5,119,878 Impact-activated fire extinguisher 5,121,797 Methods and apparatus for sealing a burned-out oil well 5,124,053 Fire-extinguishing methods and mixtures using hydrofluorocarbons 5,135,054 Fire extinguishing agents for flood applications 5,146,996 Apparatus and method for pushing a cover over a target area 5,152,345 Fire extinguishing tool 5,154,237 Suppression of detonations 5,154,238 Fire protection apparatus in vehicles 5,158,138 Apparatus for sealing a burned-out oil well 5,163,517 Fire extinguishing systems ,174,384 Transport unit for fluids or solid materials or devices, and method 5,183,117 Fire extinguisher 5,211,245 Vehicle mounted aerial lift 5,211,246 Method and cleaning system to suppress fire in an enclosed area 5,224,550 Explosion suppression system 5,232,053 Explosion suppression system 5,244,021 Fuel transfer vessel 5,249,631 Hydraulic drive mobile robot 5,275,243 Dry powder and liquids method and fire extinguishing apparatus 5,275,244 Apparatus and process for extinguishing fires with a non-combustible fluid in the liquid and gaseous states 5,276,433 Methods and apparatus to detect temperature ,277,256 Nozzle for firefighters 5,301,756 Vehicle-mounted aerial lift 5,305,957 Process and apparatus for fine dispersion of liquids or powders in a gaseous medium 5,340,490 Azeotrope-like compositions of trifluoromethane and carbon dioxide or hexafluoroethane and carbon dioxide 5,361,847 Fire extinguishing system type flaw-proof bottle ,368,106 Tool to fight fires particularly for fires on board and similar 5,370,189 Fire extinguisher bottle with collector tube 5,393,438 Fire extinguishing composition and process ,402,967 Apparatus for water supply to aircraft cabin spray systems 5,409,067 Portable firefighting tool 5,423,384 Fire suppression apparatus 5,423,385 Fire extinguishing methods and systems 5,425,426 Fire extinguishing methods and systems 5,425,886 Fire extinguishing systems a application, without halon 5,441,114 Portable fire extinguishing system 5,449,041 Fire suppression apparatus and method 5,458,202 Pressurized fire extinguisher release device with roll-up diaphragm 5,465,795 Fire suppression device for generating steam from an ice-water mixture 5,492,179 System for extinguishing a fire in a volume for supply from a distance . 492.180 Painted wall surfaces with a solid-fuel composition capable of igniting which generates a particulate aerosol fire extinguishers 5,495,893 Apparatus and method for controlling gas deflagration 5,501,284 Fire extinguishing system for inflatable bags 5,505,383 Fire protection nozzle 5,511,621 Fire suppression system for fine sprinkling of local flood water using recirculation principles 5,518,075 Fire extinguisher fire 5,534,164 non-toxic, environmentally benign fire extinguishers 5,573,067 Apparatus for extinguishing an oil well fire 5,575,341 Mechanical fire fighting equipment with foam ,588,493 Methods and systems extinguishing 5,588,987 Discharge stream conditioner and method 5,597,044 Method to disperse an atomized liquid stream 5,609,210 Apparatus and method to suppress a fire 5,609,787 Method to extinguish fire 5,610,359 Method of generating non-toxic smoke 5,613,562 Apparatus for suppressing a fire 5,615,742 Atmospheres that They contain hydrogen gas fuel and its production 5,617,923 Modular extinguishing apparatus for a closed environment 5,626,786 Labile bromine fire suppressors 5,647,438 Explosion-suppressor dispersion nozzle 5,651,417 Base for a fire-fighting tool 5,664,631 Apparatus for boosting fire suppression 5,678,638 Suppression system sparks and flames 5,685,376 System and method that uses low pressure nozzles for fire extinguishing 5,718,293 Process and composition of fire extinguishing . 718.294 Fire suppression or explosion protection system having a manual actuator for an electrically responsive initiator or gas generator cartridge activator 5,727,635 vehicle and marine fire suppression system 5,759,430 Clean tropodegradable agents with low ozone depletion and potentials global warming to protect against fire and explosions 5,775,434 Fire-fighting method and installation to extinguish an elongated object .785.126 Method of extinguishing fire in open or closed spaces and means for carrying out the method .785.127 Fire suppressor mounted on the back of a user, 808,541 Hazard detection, warning and response system, 826,664 Active system for suppression of fire fire and explosions using a reclosable valve 5,833,874 Fire extinguishing gels and methods of preparation and use thereof 5,845,714 Method and installation for fire extinguishing using a combination of liquid fog and non-combustible gas 5,845,716 Method and apparatus for supplying liquid with gas ,848,650 Combustion suppression method of vehicle engines 5,848,652 Engine fire extinguishing system 5,850,876 Apparatus and system for the storage and supply of low pressure liquid CO.sub.2 to extinguish fires 5,856,587 Flame extinction compositions 5,857,627 Formation nozzle of foam 5,862,867 Gas-liquid mixture as well as unit and method for the use thereof, 881,817 Fire control device of cold compressed air foam, 884,710 Liquid pyrotechnic fire extinguishing composition that produces a large amount of water vapor, 894,891 Method and device to extinguish fire, 909,776 Fire extinguishers , 913,367 Aircraft Penetrator, 918,680 Water spray cooling system for fire extinguishing and suppression of fire compartments, 919,393 Fire extinguishing process and composition, 921,322 Device to regulate the speed of deployment of sprinkler heads in systems of pre-active sprinklers .934.379 Method and apparatus for the detection and prevention of fire risk .934.380 Apparatus for preparing and disseminating novel fire extinguishing agents, 947.207 Dual sprinkler system, 954.138 Fire extinguishing valve and fire extinguishing equipment, 971.080 Rapid response dry tube sprinkler system ,975,213 Fire suppression device 5,984,016 Fire extinguisher for enclosed spaces 5,992,528 Fire suppression system based on inflators 5,993,682 Mixtures of hydrobromocarbons to protect against fire and explosions 6,003,608 Fire suppression system for a confined space 6,012,531 Fire extinguishing pump 6,016,874 Extinguishing system affordable compact inert gas fire 6,019,177 Flame suppression methods 6,024,889 Chemically active composition for fire suppression 6,029,751 Automatic fire suppression apparatus and method 6,032,745 Valve for fire suppression device 6,047,777 Explosion-like fire suppression method and device, particularly hydrocarbons 6,053,256 Fire extinguishing system 6,053,256 Fire extinguishing system 6,056,063 Thermally controlled self-explosive fire extinguisher 6,065,546 Fire extinguishing device and smoke eliminator and method that uses water mist 6.065, 547 Apparatus and method for suppression of fire 6,068,058 Apparatus and method for suppression of fire 6,076,610 Fire extinguishing device in vehicles 6,082,464 Dual stage fire extinguisher 6,089,324 Fire control device for cold compressed air foam 6,095,251 Stage fire extinguisher dual 6,104,301 Hazard, warning, and response detection system 6,112,822 Method for supplying a fire suppression composition to a hazard 6,131,667 Manual and automatic fire extinguishing systems 6,138,766 Apparatus for preparing and disseminating novel fire extinguishing agents 6,146,544 Flooding agents environmentally benign non-toxic fire 6,164,382 Pyrotechnic device and process to extinguish fire 6,173,790 Process and device to atomize liquid extinguishing agents in fixed extinguishing installations 6,182,768 Gas-liquid mixture as well as a fire extinguishing unit and method for the use of the Same 6,189,625 Fire extinguisher liquid mist 6,202,755 Fire extinguishing agent and method of preparation and use of it 6,216,963 Device to regulate the speed of deployment of spray heads in sprinkler systems proactivos 6,241,164 Fine fog apparatus effervescent liquid 6,257,340 Fire extinguishing system using shock tube 6,267,788 Gas-liquid mixture as well as a fire extinguishing unit and method for its use 6,314,754 Hypoxic fire prevention and fire suppression systems for computer rooms and other installations occupied by fire human 6,317,053 Switching cabinet with a fire extinguishing system 6,318,473 Expanding fire extinguishing system 6,346,203 Fire suppression method 6,352,648 Environmentally benign non-toxic fire flooding agents 6,367,560 Wet spraying system for cold environments 6,390,203 Apparatus and fire suppression method 6,394,188 Fire extinguishing device in vehicles 6,401,487 Hypoxic fire prevention and fire suppression systems with respirable fire extinguishing compositions for human-occupied environments 6,401,830 Fire extinguishing agent and method 6,402,975 Environmentally benign non-toxic fire flooding agents 418,752 Hypoxic fire prevention and suppression systems and breathable fire extinguishing compositions for human-occupied environments 6,419,027 Fluoroalkylphosphorous compounds as fire and explosion protection agents 6,422,320 Design of improved fire extinguishing agent extinguisher 6,431,465 Opening and closing valve for work 6,478,979 Use of fluorinated ketones in fire extinguishing compositions 6,598,802 Apparatus and method of fine mist of effervescent liquid 6,601,653 Method and system to extinguish fire in a closed space 6,637,518 fire extinguishing apparatus 6,676,081 System to extinguish and suppress fire in an enclosed space in an aircraft 6,695,068 Fire extinguishing system net in textiles and rope 6,702,033 Fire hybrid fire extinguisher 6,732,809 Apparatus for distribution of granular material 6,739,400 Process and installation to combat fire in an aircraft and airplane compartment equipped with said installation 6,745,847 Spray nozzle for fire extinguishing 6,763,894 Clean agent fire suppression system and rapid atomization nozzle in it 6,796,382 Fire extinguishing ball 6,810,964 Pressurization system for extinguishers 6,840,331 Portable breathable fire extinguishing system for liquefied gas supply 6,849,194 Methods for preparing ethers, compositions of ethers, fluoroether fire extinguishing systems, mixtures and methods 6,851,483 Fire suppression system and solid propellant aerosol generator for use in the same 6,860,333 Thermally activated fire suppression system 6,868,915 Method for suppressing explosions in development 6,871,802 Self-modulating inert gas fire suppression system 6,889,775 Modernized fire suppression system without Halon and modernization method of existing systems based on Halon. 6,899,184 Fire suppression system and method for an interior fire protection area of an aircraft washbasin waste container 6,902,009 Fire extinguisher with means to prevent freezing at the outlet 6,907,940 Fluid flow control valve / nozzle rapid response 6,935,433 Total gas flood suppression system 6,981,659 Liquid mist fire extinguisher 6,983,805 Fire blanket 6,988,558 Method of extinguishing fire by means of a gas device and extinguisher 7,004,261 Microemulsion fogs as fire suppression agents 7,011,164 Engine disassembly spray system 7, 028,782 System and method to suppress fires 7,048,068 Fire extinguishing system for large structures 7,066,274 Fire suppression system for an aircraft 7,082,999 Pressurization system for fire extinguishers 7,083,742 Fluoroiodocarbon mixtures as CFC and halon replacements 7,089,862 Water receptacle 7,090,028 Suppression of fire fire using water mist with ultra-fine droplets 7,121,353 Air transport vehicle for fire fighting 7,121,354 Fire extinguishing device and method 7,128,163 Self-service fire extinguisher with externally operated internal mixing with wide mouth and external CO chamber. sub .2 H141 Rapid assortment fire extinguisher RE29,614 Breaking head for fire extinguishers It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention.

Claims (9)

1. CLAIMS Having described the invention as above, the content of the following claims is claimed as property: 1. An inflator using a propellant produced from a material of 3,6-bis (1H-1, 2, 3, 4- tetrazol-5-ylamino-1,2,4,5-tetrakine, characterized in that it comprises in combination: a gas cartridge having an outlet for fluid connection to an inflatable article, the gas cartridge includes a reaction chamber containing the material of 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-1,2,4,5-tetrakine and controls the evolution of gas upon ignition of the 3,6-bis material (1H-1, 2, 3, 4-tetrazol-5-ylamino-1, 2, 4, 5-tetrakine, a cover mounted to the reaction chamber, and a shell in which the reaction chamber is located including a dome that provides a higher volume of space for nitrogen gas produced during the ignition of 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ilam) material no-1,2,4,5-tetrakine.
2. 2. A device for inflating an air pocket of 3,6-bis (1H-1, 2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine, characterized in that it comprises in combination: a ventilated envelope in which a cavity is located internal filled with 3, 6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-1,2,4,5-tetrakine) and a lighter located at the bottom of the cavity with its trigger terminals extending through the shell for connection to a firing mechanism 3. A fire suppressant of 3,6-bis (1H-1, 2, 3, -tetrazol-5-ylamino-l, 2, 4, 5- tetrazine, characterized in that it comprises a vessel filled with 3,6-bis (1H-1,2,3,4-tetrazol-5-ylamino-1,2,4,5-tetrakine which, on ignition, produces nitrogen gas suppressant of fire 4. A fire extinguisher of 3, 6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-l, 2,4, -tetracina, characterized in that it comprises in combination: a gas cylinder containing 3,6-bis (1H-1,2,3,4-tetrazol-5-ylamino-1,4,4-tetrakine and a pressurized gas) and a manually operated supply valve / nozzle that releases the Pressurized gas to supply 3,6-bis (1H-1,2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine. 3, 6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-l, 2,4,5-tetrakine fire entrainer, characterized in that it comprises in combination: a container that includes a supply of 3 , 6-bis (1 H-1,2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine; and a valve that includes a lighter to ignite 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-1,2,4,5-tetrakine with which the expanding nitrogen gas produced from the 3,6-bis (lH-1, 2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine that is burned pressurizes the container that it is then used to suppress a fire 6. An inflator of 3,6-bis (lH-1,2,3,4-tetrazol-5-ylamino- 1, 2, 4, 5-tetracin, characterized in that it comprises in combination : a casing: a 3,6-bis (lH-1,2,3,4-tetrazol-5-ylamino-1,2,4,5-tetrakine loading vessel that includes an amount of 3,6-bis (lH-1, 2, 3, 4-tetrazol-5-ylamino-l, 2,4, 5-tetrakine and a primer charge, the loading container is placed inside the shell; a lighter will spread on the load primer to ignite the primer charge which in turn ignites 3,6-bis (1H-1, 2,3,4-tetrazol-5-ylamino-1, 2,4,5-tetrakine; escape in such a way that during the ignition of 3,6-bis (lH-1,2,3,4-tetrazol-5-ylamino-1,2,4,5-tetrakine a Nitrogen gas supply escaping from the shell towards an article to be inflated. 7. A tire inflator of 3, 6-bis (lH-1, 2, 3, 4-tetrazol-5-ylamino-l, 2,4,5-tetrakine, characterized in that it comprises in combination: a shell; a container containing 3,6-bis (1H-1,2,3,4-tetrazol-5-ylamino-1,2,4,5-tetrakine), the container includes a spark gap to create a spark when voltage is applied to its terminals, the cargo container is placed inside the envelope; a piezoelectric mechanism that includes a button that, when pressed, creates a voltage spark through the piezoelectric that is supplied to the spark gap terminals to ignite the 3,6-bis (1H-1, 2, 3, 4-tetrazol- 5-i lamino- 1, 2, 4, 5-tetracina whereby the nitrogen gas produced there is deflated towards the shell, and a valve located in the shell designed to open a conventional inflation valve of a standard automobile tire, whereby the nitrogen gas in the shell is used to inflate the tire 8. An inflator of 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-1, 2, 4, 5 -tetrazine, characterized in that it comprises, in combination: a shell, a container containing 3,6-bis (1 H-1, 2, 3, 4-tetrazol-5-ylamino-l, 2,4, 5-tetracin located in the shell, the loading vessel includes a capsule to ignite 3,6-bis (1H-1, 2, 3, 4-tetrazol-5-ylamino-1,2,2,5-tetrakine) when hit; and a firing mechanism to hit the capsule fulminating when pulling a lanyard handle to pull. 9. An alternative combustion engine of 3,6-bis (lH-1,2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine, characterized in that it comprises a combustion chamber including a lighter to fire a charge of 3,6-bis (1H-1,2,3,4-tetrazol-5-ylamino-l, 2,4,5-tetrakine that is in it and produces pressurized nitrogen gas to boost a motor .