MX2008007257A - Composition for separating mixtures - Google Patents

Abstract

Therefore, there is provided herein in one specific embodiment a composition comprising:a) at least one silicone, surfactant, and where silicone of silicone surfactant (a) has the general structure of:M1aM2bD1cD2dT1eT2fQgAnd:(I) and, b) a mixture comprising an aqueous phase, a solid filler phase and optionally an oil phase that is substantially insoluble in said aqueous phase.

Description

COMPOSITION FOR. SEPARATE MIXTURES BACKGROUND OF THE INVENTION Field of the Invention The present disclosure relates to compositions for separating mixtures containing different phases.

Description of the Prior Art Aqueous and / or oil-based mixtures are found in various commercial industries. The separation of these mixtures is often necessary to make possible the reuse of various components in the mixtures or for the appropriate treatment before the disposal of the separate components of the mixture. The mixtures can be separated by various means including mechanical, thermal and chemical. The mechanical separation of mixtures can generally result in the at least partial separation of the aqueous and / or oily phases that may occur in the mixture, but when these phrases are presented in the form of an emulsion, the mechanical separation often fails to provide a desirable degree of separation. Various chemical means have been provided for the separation of mixtures of emulsified phases, but various industries require still additional levels of separation which to date have not been have been adequately provided by conventional chemical means.

BRIEF DESCRIPTION OF THE INVENTION It has been unexpectedly discovered that greatly improved separation of blends can be provided by the direct use of compositions comprising silicone surfactants and the mixture to be separated. Therefore, there is provided herein, in a specific embodiment, a composition comprising: a) at least one silicone surfactant, and wherein the silicone of the silicone surfactant (a) has the general structure of: M1a M2b Dxc D2d ^ f Qg; where M1 = R1R2RSiO? / 2; M2 = R4R5R6SiO? / 2; D1 = R7R8Si02 / 2; D2 = R9R10SiO2 2; T1 = RuSi03 / 2; T2 = R12Si03 / 2; Q = Sio4 / 2 where R1, R2, R3, R5, R6, R7, R8, R10 and R11 are each independently selected from the group consists of monovalent hydrocarbon radicals containing one to twenty carbon atoms, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4, R9 and R12 independently are hydrophilic organic groups, and where the subscripts a, b, c, d, e, f and g are zero or positive integers for molecules subject to the following limitations: (a + b) corresponds to either (2 + e + f + 2g) or (e + f + 2g), b + d + f > 1, and, 2 < (a + b + c + d + e + f + g) < 100; and, b) a mixture comprising an aqueous phase, a solid filling phase and optionally an oil phase which is substantially insoluble in the aqueous phase.

BRIEF DESCRIPTION OF THE DRAWING Figure 1: Transmission and backscattering data of the Turbiscan Lab instrument at 29 degrees Celsius (° C) for a drilling mud from the Service Company treated with 2% by weight of Example 10B (Y-17014) with base in the weight of the drilling mud sample (corresponding to 1 g of silicone with 50 g of mud).

DETAILED DESCRIPTION OF THE INVENTION It has been discovered, in a specific embodiment, a composition comprising a silicone surfactant and a mixture of different phases, which can provide an intensified separation of the mixture of different phases. It will be understood herein that the terms polyorganosiloxane and organopolysiloxane are interchangeable with each other. It will be understood herein that all uses of the term centistokes were measured at 25 degrees Celsius. It will be understood that all the specific, more specific and highly specific ranges enumerated herein cover all sub-ranges between them. It will be understood that the terms wetting agent and demulsifier, as used herein, may be interchangeable and the silicone surfactant (a) may act as a wetting agent and / or a demulsifier, which may act separately or may act together. In a specific embodiment herein, the silicone surfactant may be any commercially available or known silicone surfactant. In another specific embodiment herein, the silicone surfactant (a) can be any silicone surfactant known or commercially and / or industrially used, which occurs naturally or is added in a conventional manner by known methods and / or conventional In another specific embodiment herein, the silicone of the silicone surfactant has the general structure described in the foregoing. In a specific embodiment herein, it will be understood that the components specifically described herein, silicone surfactant (a), aqueous phase, solid fill phase and optionally oil phase of the mixture (b), may all contain one or more of the other components. In another specific embodiment herein, any one or more of a component selected from the group consisting of silicone surfactant (a), mixture (b), aqueous phase of the mixture (b), solid filling phase of the mixture (b) ), oil phase of the mixture (b), the aqueous phase, solid filling phase and the oil phase, including the phases before and / or after the separation of the mixture (b), can comprise two or more thereof and / or different aforementioned components as described herein. It will also be understood herein that the phrases aqueous phase of the mixture (b) and / or solid filling phase of the mixture (b) and / or oil phase of the mixture (b) are the respective aqueous phase and / or phase of solid filler and / or oil phase as they occur in the mixture (b) before separation of the mixture (b). It will be understood herein that the phrases aqueous phase of the separated mixture (b) and / or solid filling phase of the separated mixture (b) and / or oil phase of the separated mixture (b) are, respectively, the aqueous phase and / or solid filling phase and / or oil phase as they occur after the mixture (b) has been separated. In a specific embodiment herein, it will be understood that R1, R2, R3, R5, R6, R7, R8, R10 and R11 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to twenty carbon atoms, hydrogen, OH and OR13, more specifically methyl, hydrogen, OH and OR13, even more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl and OH; where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms; and also such as R1, R2, R3, R5, R6, R7, R8, R10 and R11 are further described herein. In another specific embodiment herein, it will be understood that R4, R9 and R12 independently are hydrophilic organic groups selected from the group consisting of Z1, Z2, Z3, Z4, Z5, Z8 and Z9 as described herein; and also such as R4, R9 and R12 are further described herein. In yet another specific embodiment herein, it will be understood that 2 < (a + b + c + d + e + f + g) < 100, more specifically, 2 < (a + b + c + d + e + f + g) < 75, more specifically, 2 < (a + b + c + d + e + f + g) < 50, even more specifically, 2 < (a + b + c + d + e + f + g) < 30, and very specifically, 2 < (a + b + c + d + e + f + g) < twenty; and also such as (a + b + c + d + e + f + g) are further described herein. In yet another specific embodiment herein, it will be understood that 2 < (a + b + c + d) < 100, more specifically, 2 < (a + b + c + d) < 75, even more specifically, 2 < (a + b + c + d) < 50 and still more specifically, 2 < (a + b + c + d) < 30, and very specifically, 2 < (a + b + c + d) < twenty; and also such as (a + b + c + d) are further described herein. In yet another specific embodiment herein, it will be understood that a + b is approximately 2; and also such as a + b is further described herein. Still in another specific embodiment herein, it will be understood that c is specifically from 0 to 10, more specifically from 0 to 8 and very specifically from 0 to 5; and also such as c is further described herein. Still even in another specific embodiment herein, it will be understood that d is specifically from 1 to 10, more specifically from 1 to about 6 and very specifically from 1 to 3; and also such as d is further described herein.

In a more specific embodiment R4, R9 and R12 independently are hydrophilic organic groups selected from the group consisting of Z1, Z2, Z3 and Z8 where, Z1 is at least one polyoxyalkylene group having the general formula B ^ O (ChH2hO) nR14 where B1 is an alkylene radical containing from 2 to about 4 carbon atoms, specifically vinyl, allyl and methallyl, R14 specifically it is a hydrogen atom or a hydrocarbon radical containing from 1 to about 4 carbon atoms, more specifically where R14 is CH3 or H and, very specifically, where R14 is hydrogenated is 1 to 100; h is 2 to 4 which provides at least one polyoxyalkylene group selected from the group consisting of polyoxyethylene, polyoxypropylene, polyoxybutylene, and combinations thereof, with the proviso that at least about 10 mole percent of at least one group polyoxyalkylene is polyoxyethylene; Z2 has the general formula B2 (OH) m wherein B2 is a hydrocarbon containing from 2 to about 20 carbon atoms and optionally containing oxygen and / or nitrogen groups, such as the non-limiting examples having the general formulas C3H6 O CH 2 CHOH CH 2 OH, C 3 H 6 O CH 2 C (CH 2 OH) 2 C 2 H 5 C 3 H 6 O CO NH C 2 H 4 OH CH (CH 2 OH) C 2 H 4 OH , and m is sufficient to provide hydrophilicity, specifically m is from about 1 to about 20 Z3 is the reaction product of an epoxy adduct such as the non-limiting example of a functional silicone of AGE (allyl glycidyl ether) with a primary or secondary hydrophilic amine; Z8 is at least one polyoxyalkylene group having the general formula: 0 B7 0 (ChH2hO) nR14 where B7 is an alkyl bridge containing from 2 to about 12 carbon atoms or an aryl bridge containing from 2 to about 12 carbon atoms. carbon; R14 is specifically hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms, more specifically where R14 is CH3 or H and, very specifically, where R14 is hydrogen; n is 1 to 100; h is 2 to 4, which provides at least one polyoxyalkylene group selected from the group consisting of polyoxyethylene, polyoxypropylene, polyoxybutylene, and combinations thereof, with the proviso that at least about 10 percent by weight of at least a polyoxyalkylene group is polyoxyethylene; and where 2 < (a + b + c + d + e + f + g) < 100, specifically, 2 < (a + b + c + d + e + f + g) £ 5, more specifically, 2 < (a + b + c + d + e + f + g) < 50, even more specifically, 2 < (a + b + c + d + e + f + g) < 30, and very specifically, 2 < (a + b + c + d + e + f + g) < 20. Still even in another specific embodiment, the silicone of the silicone surfactant (a) has the general structure of: MXa M2b D ^ D2d where M1 = R1R2R3SiO? / 2; 2 = R R5R6SiO? / 2; D1 = R7R8SY02 / 2; D2 = R9R10SiO2 / 2; where R1 has the same definitions as described above and is further specifically selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, hydrogen, OH and OR13 , even more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl and OH, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and R2, R3, R5, R6, R7, R8 and R10 they have the same definitions as described in the foregoing and, in addition, they are specifically selected independently of the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl, wherein R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4 and R9 are independently selected from the group consisting of Z1, Z2, Z3 and Z8 as described above, where, a + b is approximately 2 and 2 < (a + b + c + d) < 75, more specifically, a + b is approximately 2 and 2 < (a + b + c + d) <; 50, and even more specifically, a + b is approximately 2 and 2 < (a + b + c + d) < 30, and very specifically, a + b is approximately 2 and 2 < (a + b + c + d) < 20. Still in another specific embodiment, the hydrophilic organic groups described in the above further comprise the cases in which R4, R9 and R12 are defined as described above and more specifically are independently selected from the group consisting of Z2, Z4 , Z6 and Z9, where Z4 has the general formula B10 (C2H40) p (C3H60) qR14 where B1 is an alkylene radical containing from 2 to about 4 carbon atoms, specifically vinyl, allyl and methallyl, R 14 is specifically hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms, more specifically where R 14 is CH 3 or H and, very specifically, where R 14 is hydrogen, p is 1 to 15, q < 10 and p > q; Z6 is selected from the general formula of: a. B5 (OR B6) s N (R15) 2 or where B5 and B6 independently are hydrocarbon radicals containing from 2 to about 6 carbon atoms, which optionally may contain OH groups, s is 0 or 1, and each R15 independently is hydrogen or an alkylenoxide group having the general formula - ( CuH2uO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least 50 mole percent of the alkylenoxide groups are oxyethylene; R16 is hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms; Z7 is either a nitrogen atom or an oxygen atom with the proviso that if Z7 is an oxygen atom, then w = 0, and if Z7 is a nitrogen atom, then w = 1, R17 is independently selected from an alkylene oxide group having the general formula - (CuHuO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least about 50 mole percent of the alkylene oxide groups are oxyethylene; the R18 groups are independently selected from the group consisting of hydrogen, OH, a hydrocarbon radical containing from 1 to about 4 carbon atoms and an alkylenoxide group having the general formula - (CuH2uO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least 25 mole percent of the alkylenoxide groups are oxyethylene; Z9 has the general formula O B7 O (C2H0) p (C3H60) qR14 where B7 is an alkyl bridge or an aryl bridge containing from 2 to about 12 carbon atoms, R14 is specifically hydrogen or a hydrocarbon radical containing 1 to about 4 carbon atoms, more specifically where R14 is CH3 or H and very specifically where R14 is hydrogen, p = 1 to 15, q < 10 and p > q. Still even in another specific embodiment, the silicone of the silicone surfactant (a) has the general structure of: 1 * M2b D ^ D2d where M1 = R1R2R3SiO? / 2; M2 = RR5R6SiO? / 2; D1 = R7R8Si02 / 2; D2 = R9R10SiO2 / 2; wherein R1 has the same definitions as described above and is further specifically selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, hydrogen, OH and OR13, even more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl and OH, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and R2, R3, R5, R6, R7, R8 and R10 have the same definitions as described above and more specifically are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy , and very specifically methyl, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4 and R9 are defined as described above r and in addition are selected specifically and independently of the group consisting of Z2, Z4, Z6 and Z9 as described above, and a + b corresponds to approximately 2 y, specifically, c + d < 10, more specifically c + d < 8 and, very specifically, c + d < 5, and where (a + b + c + d) can have any of the ranges described in the above. Still in another even more specific embodiment, the silicone of the silicone surfactant (a) has the general structure of: M2 Dxc M2 where M2 - R4R5R6SÍO? 2; D1 = R7R8Si02 / 2; where R5, R6, R7 and R8 have the same definitions as described above and more specifically are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4 has the same definition as described above and in addition it is specifically selected from the group consisting of Z2, Z4, Z6 and Z9 as described above and where c is specifically from 0 to 10, more specifically from 0 to 8 and very specifically from 0 to 5. In another embodiment specific here, the if licona of the surfactant (a) of if licona has the general structure of: M1 DXC D2d M1 where M1 = R1R R3SiO? 2; D1 = R7R8Si02 / 2; D2 = R9R10SiO2 / 2; wherein R1 has the same definitions as described above and is further specifically selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, hydrogen, OH and OR13, even more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl and OH, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and R2, R3, R7, R8 and R10 have the same definitions as described above, and more specifically, each is independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl, wherein R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and R9 is defined as described above and in addition it is specifically selected from the group consisting of Z2, Z4, Z6 and Z9, as described above, where c is specifically from 0 to 10, more specifically from 0 to 5 and very specifically from 0 to 2, and d specifically is from 1 to 10, more specifically from 1 to approximately 6 and very specifically from 1 to 3 and, in a more specific modality, where c is from 0 to 2 and d is from approximately 1 to 3. In another specific modality in the present, the silicone of the silicone surfactant (a) is a trisiloxane and has the general structure of: M1 D2 M1 which is obtained from the hydrosilylation of a silicone distilled polymer having the general formula M1 DH M1 and alkylene oxide initiated unsaturated in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1R2R3SiO? 2; DH = HR10SiO2 / 2; D2 = R9R10SiO / 2; where R1, R2, R3 and R10 are defined as described above and more specifically each is independently selected from the group consisting of monovalent hydrocarbon radicals containing from 1 to 6 carbon atoms, hydrogen, OH and OR13, where R13 is a group hydrocarbon containing from 1 to about 4 carbon atoms and R9 is defined as described above and is further specifically selected from the group consisting of Z2, Z4, Z6 and Z9. Still in another specific embodiment herein, the silicone surfactant (a) is a low molecular weight ABA siloxane block copolymer where the silicone of the silicone surfactant (a) has the general structure MRD1CMR which is obtained from the hydrosilylation of the silicone polymer having the general formula MHD1CMH and unsaturated initiating alkylene oxide and, specifically present in sufficient molar excess to terminate the hydrosilylation reaction, where c is specifically 0 to 10, more specifically 0 to 8 and very specifically 0 to 5 , D1 = R7R8Si02 2, MR = R4R5R6SiO? 2, MH = HR5R6SiO? 2 and where R5, R6, R7 and R8 have the same definitions as described above and, moreover, are specifically selected independently of the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy, and very specifically methylated lo, and where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms and where R4 is defined as described above and more specifically is CgH2g- O (CH40) p (C3H60) qR14 and where R14 specifically is hydrogen or a radical hydrocarbon containing from 1 to about 4 carbon atoms, more specifically where R14 is CH3 or H, and very specifically where R14 is hydrogen, g = 2 to 4, specifically g = 3; specifically p = 1 to 12; more specifically p = 2 to 10 and very specifically p = 3 to 8; q < 6 more specifically q < 3 very specifically q = 0 and p > q. Still in a further specific embodiment herein, the silicone surfactant (a) is a low molecular weight pending siloxane copolymer where the silicone of the silicone surfactant (a) has the general structure M1 D1c DRd M1 which is obtained from the hydrosilylation of the silicone polymer having the general formula M1 D1c DHd M1 and initiating alkylene oxide unsaturated in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1RR3Si01 2, D1 = R7R8Si02 2, DR = R9R10SiO2 2, DH = HR10SiO2 / 2, and where c is specifically from 0 to 10, more specifically from 0 to 5 and very specifically from 0 to 2, and d is specifically from 1 to 10, more specifically from 1 to approximately 6 and very specifically from 1 to 3, and in a more specific modality, when specifically c is 0 to 3 and d = 3, or more specifically either c is < 1 and d is about 1 to about 3, or c is about 1 to about 2 and d is about 1 to about 2, or even even more specifically c = 0 and d is about 1 to approximately 2 or very specifically, c is approximately 1 and d is approximately 1, and where c is from 0 to approximately 2 and d is from approximately 1 to approximately 3, where R1 has the same definitions as described above and in addition is specifically selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, hydrogen, OH and OR13, even more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl and OH , where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and R2, R3, R7, R8 and R10 have the same definitions as described above and more specifically each is selected independently of the group that consists of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, more specifically methyl, OH, methoxy and ethoxy, and very specifically methyl, wherein R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and where R9 is defined as described above and also specifically is independently CgH2g-0 (C2H40) p (C3H60) q R14 and wherein specifically R14 is hydrogen, or a hydrocarbon radical containing from 1 to about 4 carbon atoms. carbon, more specifically R14 is CH3 or hydrogen and very specifically R14 is hydrogen, g = 2 to 4, specifically, g = 3, specifically p = 1 to 12, more specifically p is 2 to 10, very specifically p is 3 to 8 , specifically q < 6 and more specifically q < 3 and very specifically q = 0, and p > q. Still further in another specific embodiment herein, the silicone surfactant (a) is a trisiloxane-siloxane copolymer where the silicone of the silicone surfactant (a) has the general structure M1 DR M1 which is obtained from the hydrosilylation of a silicone distilled polymer having the general formula M1 DH M1 and initiating unsaturated alkylene oxide in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1R2R3SiO? 2, DR = R9R10SiO2 / 2, DH = HR10SiO2 2, where R1, R2, R3 and R10 are defined as described above and more specifically each is independently selected from the group consisting of CH3, hydrogen, OH and OR13, more specifically CH3, and where R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and where R9 is CgH2g-0 (C2H40) p (C3H60) qR14, and where R14 is hydrogen, or a hydrocarbon radical containing from 1 to about 4 carbon atoms, more specific specifically, CH3 or H, and very specifically hydrogen, g = 2 to 4, specifically g = 3, specifically p = 1 to 12, more specifically p is 2 to 8, very specifically p is 3 to 8, specifically q < 6 and more specifically q < 3 and very specifically q = 0, and p > q. Still still in another additional specific embodiment, the silicone surfactant (a) can be used in a specific concentration of about 0.001 weight percent to about 5 weight percent, plus a specific of about 0.05 weight percent to about 4 weight percent. percent by weight and very specifically from about 0.1 weight percent to about 3 weight percent, based on the total weight of the composition, to intensify phase separation. In a specific embodiment herein, mixture (b) can be any mixture known or commercially available and / or used industrially provided that the mixture contains at least one aqueous phase and solid filling phase, and optionally one phase oily In another specific embodiment herein, the mixture (b) can be any known or commercially and / or industrially used mixture, which occurs naturally or is added in a conventional manner by known and / or conventional methods. In a specific embodiment herein, it will be understood that the mixture (b) comprising the aqueous phase, solid filling phase and oil phase when present, can all be intermixed so that each phase contains some amount of the other phases present and or any amount of silicone surfactant. In other Specific embodiment, it will be understood herein that the solid filling phase may comprise solid filler and any other phase as described herein and / or silicone surfactant (a) as described herein. In yet another specific embodiment herein, the solid fill phase may comprise only solid filler. Still in a further specific embodiment, the mixture (b) may comprise a drilling mud, an ash stripping sludge from shale oil, a refinery sludge, a floor of a refinery and / or industrial site, a soil from the site of the filtering fuel storage tank, a mixture of crude oil from tank waste, a pharmaceutical emulsion, such as the non-limiting example of a bioprocessing emulsion optionally containing a fermentation product, a sand impregnated with tar-oil and combinations of the same. In a specific embodiment, it will be understood herein that the sand impregnated with tar-oil may be any sand impregnated with pitch and does not necessarily have to contain oil. In a specific embodiment, a process for separating a mixture is provided, comprising: a) combining at least one silicone surfactant (a), as described herein, and b) a mixture comprising an aqueous phase, a solid filling phase and optionally an oil phase which is substantially insoluble in the aqueous phase, and allowing the separation of any one or more of the aqueous phase, the solid filling phase and, if present, the oil phase to provide a mixture ( b) separate. In a specific embodiment herein, mixture (b) can be separated before and / or after a mechanical separation process as is conventionally known to those skilled in the art. In another specific embodiment herein, mixture (b) is a mixture selected from the group consisting of a mixture resulting from an oil spill, a mixture resulting from a pipeline rupture, a mixture resulting from a tank of oil. filtering fuel, a mixture resulting from an industrial operation and combinations thereof. In another specific embodiment herein, a process is provided for allowing the separated mixture (b) to comprise stirring the combined silicone surfactant (a), as described herein and the mixture (b), and optionally adding additional fluid. , as described herein, and / or optionally heating the mixture (b). In a specific embodiment, the silicone surfactant (a) can be a combination of materials, such as a combination of silicone surfactants and a compound organic with non-limiting examples of the organic compound such as alkyl alcohol polyglycol ether, polyalkylene glycol, alkylaryl alcohol polyglycol ether and combinations thereof. In another specific embodiment herein, the combination of silicone surfactant and additive compound can be selected from Y-17188, Y-17189, Y-17190 and Y-17191 (where; Y-17188 is a combination of Y-17015 ( % by weight) and UCON 50H1500 (60% by weight) Y-17189 is a combination of Pluronic 17R2 (40% by weight), Rhodasurf DA-530 (30% by weight) and Y-17015 (30% by weight) Y-17190 is a combination of Genapol X50 (30% by weight), Pluronic L-62 (40% by weight) and Y-17015 (30% by weight); Y-17191 is a combination of Y-17015 (93.3) % by weight) and Pluronic 17R2 (6.7% by weight)). UCON 50H1500 is available from Dow Chemicals; Pluronic 17R2 and Pluroninc L-62 are available from BASF Chemcials; Rhodasurf DA-530 is available from Rhodia Chemicals; Genapol X50 is available from Clariant Chemicals. In another specific embodiment herein, a process is provided comprising the cases in which the combined surfactant (a), as described herein, and the mixture (b) are part of a recirculation stream from a previous separation of any or more of the aqueous phase, the solid filling phase and, if present, the oil phase. In a more specific modality, as described in present, a process is provided where the separated mixture (b) is a separate mixture of the non-limiting examples selected from the group consisting of a drilling mud, a shale extraction sludge from shale oil, a refinery sludge, a floor of a refinery and / or industrial site, a floor of the filtering fuel storage tank site, a mixture of crude oil from tank residues, a pharmaceutical emulsion, such as the non-limiting example of a bioprocessing emulsion optionally containing a fermentation product, a sand impregnated with tar-oil and combinations thereof. In a specific embodiment herein, a process is provided comprising the cases in which the separated mixture (b) is separated in a shorter period of time than required for a process to separate an identical mixture (b), which it comprises combining surfactant other than the silicone surfactant (a) as described herein and the mixture (b) identical. In another specific embodiment, a process is provided that further comprises the cases in which the separated mixture (b) separates more completely than an identical mixture (b) present in a process for separating a mixture, which comprises combining different surfactant to the silicone surfactant (a) as described herein and the mixture (b) identical.

In another specific embodiment, a process is provided that further comprises the cases in which the separated mixture (b) has any or more of the aqueous phase, the solid filling phase and, if present, the oil phase, each containing a smaller amount of contaminants than a process for separating an identical mixture (b), which comprises combining surfactant other than the silicone surfactant (a) as described herein and the mixture (b) identical. In another specific embodiment, a process is provided which further comprises the cases in which any interface in the mixture (b) separated between any one or more of the aqueous phase, the solid filling phase and, if present, the oil phase, is sufficiently different to allow a smaller amount of interface to be isolated than a process for separating an identical mixture (b), which comprises combining surfactant other than the silicone surfactant (a) as described herein and the mixture (b) ) identical. In another specific embodiment herein, a process is provided which further comprises the cases in which the aqueous phase of the separated mixture (b) contains in particular from about 0 to about 1000 parts per million (ppm), more specifically about 0 to approximately 100 ppm, and very specific to about 0 to about 25 ppm of hydrocarbon contamination. In another specific embodiment herein, a process is provided which further comprises the cases in which the aqueous phase of the separated mixture (b) contains in particular about less than about 90 weight percent, more specifically less than about 50 percent by weight and very specifically less than about 10 percent by weight of the amount of heavy metal that was present in the mixture (b) before the mixture (b) separated, the weight percentage based on the total weight of the heavy metal in the mixture (b) before the mixture (b) separated. In another specific embodiment herein, a process is provided which further comprises the cases in which the aqueous phase of the separated mixture (b) contains in particular from about 0 to about 0.1 ppm of heavy metal. In another specific embodiment herein, the heavy metal is selected from the group consisting of lead, cadmium, arsenic, bismuth, mercury and combinations thereof. In another specific embodiment herein, a process is provided which further comprises the cases in which the aqueous phase of the separated mixture (b) contains in particular from about 0 to about 0.5 weight percent, more specifically about 0 to about 0.1 weight percent, and very specifically about 0 to about 0.02 weight percent solid filling phase, the weight percentages based on the total weight of the aqueous phase of the separated mixture (b). In another specific embodiment herein, a process is provided which further comprises the cases in which the solid filling phase of the separated mixture (b) contains in particular less than about 90 weight percent, more specifically less than about 80 percent by weight and very specifically less than about 70 weight percent of the amount of aqueous phase that occurred in the solid filling phase before the separation of the mixture (b), the percentages by weight based on the weight total of the aqueous phase in the mixture (b) before the mixture (b) separated. In a more specific modality, oil-based drilling muds are used in the sinking of boreholes, especially deep level boreholes sunk in search of hydrocarbons (including gas), to maintain the pressure against the producing field to prevent blowouts, to lubricate the drill pipe, to cool the rock drill and act as a carrier for the cuttings of the excavated drilling. The fluid or drilling mud is pumped along the drill pipe through nozzles in the auger at the bottom of the borehole and above the annular space between the drill pipe and the borehole wall. The perforated cuts, generated by the auger, are collected with the mud and transported to the surface of the borehole where they are separated from the drilling mud and discarded. The drilling mud is then cleaned and reused. The drill pipe is then able to operate freely inside the borehole. In another specific embodiment herein, oil-based drilling mud is generally used in the form of reverse emulsion sludge. In a specific embodiment, a reverse emulsion sludge consists of three phases: an aqueous phase, a solid filling phase and an oil phase. In another specific embodiment in addition to the hydrocarbon oil the drilling fluids typically include a solid, usually inorganic filler which is added to constitute the viscosity and density; an emulsifier (surfactants with low HLB such as fatty acids) to help suspend particulate materials and aid in wetting, as described herein; Wetting agents to help wet a variety of the substrates with which the fluid comes in contact (the wetting agents may be fatty acids as described herein), the emulsifier serves to diminish the interfacial tension of the liquids so that the aqueous phase can form a stable dispersion of fine droplets in the oil phase. In one embodiment in the present, after a certain period of drilling, the drilling mud becomes charged with more water, some crude oil and drilling cuts, changing the physical properties of the drilling mud (increase in viscosity); then the mud needs to be removed from the well and recycled. In a specific embodiment, the large cuts are first mechanically separated and the remainder of the sludge is placed in a tank for later phase separation. In a specific embodiment herein, a process is provided which further comprises the cases in which the drilling mud comprises drilling cuttings, from a well drilling operation using a fluid or oil-based drilling mud, which further comprises the cases in which allowing the separation of the mixture (b) comprises cleaning the drilling mud and oil from the perforation cuts sufficiently for an environmentally safe arrangement. In a specific embodiment, the environmentally safe arrangement may include cases in which clean cuts are essentially non-toxic and can be disposed on land without the need for the special procedures required for the disposal of toxic waste.

In another specific embodiment here, in many marine drilling operations when an oil-based drilling mud has been used, environmental protection has made it necessary to accumulate the drilling cuttings and transport them to shore for disposal at a waste site. toxic This can be a significant item of expenditure on the total cost of the well. In this way, in a more specific embodiment, a process is provided that also includes the cases in which the well drilling operation comprises a mixture of drilling cuts produced by a maritime well and that also includes the cases in which the mixture of Piercing cuts can be returned to the sea near the maritime well and / or transported to shore for disposal. In another specific embodiment, there may be cost savings to drive the process for separating a drilling mud in a marine well as described above using the combination of silicone surfactant (a) and mixture (b) as described at the moment. In another specific embodiment herein, any mixture (b) as described herein can be separated in a marine operation as described herein using the combination of surfactant (a) silicone and mixture (b) as described herein. In a specific embodiment here, it is provides a process for specifically removing from about 1 to about 99 weight percent of the aqueous phase of the mixture (b), more specifically from about 20 to about 98 weight percent of the aqueous phase of the mixture (b) ), and more specifically from about 50 to about 97 weight percent of the aqueous phase of the mixture (b) based on the total weight of the aqueous phase in the mixture (b) before the separation of the mixture (b) In a specific embodiment herein, a process is provided for specifically removing from about 1 to about 99 weight percent of the oil phase, more specifically from about 20 to about 98 weight percent of the oil phase, and more specifically from about 50 to about 97 weight percent of the oil phase based on the total weight of the oil phase before the separation of the mixture (b) as described herein, specifically prior to separation of a drilling mud containing drilling cuttings using the composition described herein. In another specific embodiment herein, the properties of the drilling mud recovered from the cuts, as described herein, are not significantly adversely affected; the drilling mud recovered can be returned to an active mud system without danger to its properties. In another specific embodiment herein, a process is provided for separating suspended solids from crude oil from tank residues, such as the non-limiting example of the remaining crude oil after the main refining of crude oil, using any of the processes described in the present. In a specific modality, the crude oil from tank waste is added to a desalter together with fresh crude oil to get it dissolved and washed and refined. In another specific modality, the goal is to increase the performance of the refinery. In a specific embodiment herein, any of the processes described herein can remove all suspended matter (aqueous phase, solid filling phase and oil phase) from the crude oil (or mixture (b)) to the lower part of the desalter so that they are stirred together with the brine. In another specific embodiment, the crude oil from tank waste may comprise a wide variety of hydrocarbon emulsions found in the production, refining and chemical processing of crude oil, such as the non-limiting examples of emulsions from the production of oil fields, emulsions. desalination of refineries, refined fuel emulsions and recovered oil emulsions. In a More specific modality, crude oil from tank waste may include used lubricating oils and recovered oils in the steel and aluminum industries. In another specific embodiment herein, a process for the treatment of a pharmaceutical emulsion is provided, using any of the processes described herein, wherein the emulsion can be produced in the preparation of pharmaceutical products and other bioprocessing applications involving fermentation, such an emulsion containing fermentation product and, very specifically, includes a pharmaceutical product that is desired to be separated from the emulsion. Still in a further specific embodiment herein, a process is provided for the treatment of the tar-impregnated sand or sands, since these systems are quite similar to drilling muds, with an emulsion of solid particles, petroleum and Water. In a more specific embodiment, the process for treating the tar-impregnated sands or sands may comprise extracting the crude oil adsorbed on the sand particles and / or dusting solids containing hydrocarbon oils. In another embodiment herein, the tar-impregnated sand or sands described herein may have additional water added to the tar-impregnated tar sands or sand to assist with the separation process. In a more specific embodiment herein, mixture (b) can comprise any aqueous phase. In another specific embodiment, the aqueous phase can be any known or commercially and / or industrially used aqueous phase, which occurs naturally or is added in a conventional manner by known and / or conventional methods. In one embodiment, the aqueous phase of the mixture (b), before separation of the mixture (b), contains water in a specific amount of from about 1 to about 99 weight percent, more specifically about 5. to about 90 weight percent and most specifically from about 10 to about 60 weight percent of the mixture (b) before the separation of the mixture (b), with the weight percentage based on the total weight of the mixture. mix (b) before separation of the mixture (b). In another specific embodiment herein, mixing (b) before separation may further comprise one or more fluids, specifically water that originates from the use of a filtration process before separation of the mixture (b); the additional fluids being included in the percentages by weight described in the above of the aqueous phase present in the mixture (b) before the separation of the mixture (b). Still in a further specific embodiment, any one or more of the mixture (b); phases of the mixture (b) such as phase aqueous, aqueous phase containing additional fluid, specifically water, which can comprise anything that that water of the aqueous phase can comprise as described herein, solid filling phase and oil phase and combinations thereof, can be heated before and / or after separation of the mixture (b) to facilitate separation, as can be any process described herein. In another specific embodiment herein, the water of the aqueous phase further comprises one or more inorganic salts such as the non-limiting examples selected from the group consisting of sodium chloride, calcium chloride, magnesium chloride, sodium sulfates, sulfate of magnesium, sodium carbonate, calcium carbonate, magnesium carbonate and combinations thereof in an amount up to about saturation of the aqueous phase. In a specific embodiment, the amount of inorganic salts up to about 0 to about 20 weight percent, more specifically about 0.1 to about 15 weight percent, and very specifically about 1 to about 10 weight percent of the mixture (b), based on the total weight of the mixture (b) before the separation of the mixture (b). In a specific embodiment, the inorganic salts or salts may be present in an amount up to about the saturation of the phase aqueous and / or mixture (b). In a more specific embodiment herein, mixture (b) also contains an additional silicone surfactant such as the non-limiting example of the silicone surfactant (a). The amount of additional silicone surfactant such as the non-limiting example of surfactant (a) the silicone that is contained in the mixture (b) is specifically from about 0.0001 to about 4 weight percent, more specifically from about 0.05 to about 3.5 weight percent, and very specifically from about 0.1 to about 2.5 percent by weight of the mixture (b) based on the total weight of the mixture (b) before separation of the mixture (b). In a specific embodiment herein, the aqueous phase of the mixture (b), before separation of the mixture (b), may contain silicone surfactant (a) as an impurity or the silicone surfactant (a) may be solvated in the aqueous phase (a) in known and conventional methods. In another specific embodiment herein, the mixture (b) may comprise a solid filling phase. In another more specific embodiment, the solid filling phase can be any solid filler known or commercially and / or industrially used, which occurs naturally or is added in a conventional manner by known and / or conventional methods.

Still further still in a specific embodiment herein, the solid filling phase of the mixture (b) comprises solid filler selected from the group consisting of perforation cuts; siliceous solid, wherein the siliceous solid may further comprise the non-limiting examples of sand and quartz; rock; gravel; floor; ash; mineral; metal and metal minerals, such as non-limiting examples of iron, iron ore, and precious metals such as non-limiting examples of gold and silver; a part of metal; a glass plate; cellulosic material, such as non-limiting examples of bark, straw and sawdust; densifying agent such as non-limiting examples of barite, galena, ilmenite, iron oxides, (specular or micaceous hematite, magnetite, calcined iron minerals), siderite, and calcite; suspending agent such as non-limiting examples of organophilic clay (organarcilla), which may be selected from the non-limiting group consisting of attapulgite, bentonite, hectorite, saponite and sepiolite; agent for fluid loss control such as non-limiting examples of asphalt materials and organophilic humates, and combinations thereof of any of the solid fillers described above. In another specific embodiment, the solid filler of the solid filler phase can comprise any of the organic or inorganic materials described in the patent.

North American No. 4,508,628, the contents of which are incorporated herein by reference in their entirety. In another specific embodiment herein, the solid filler phase specifically comprises from about 1 to about 99 weight percent, more specifically from about 10 to about 80 weight percent, and very specifically from about 20 to about 60 weight percent of the mixture (b), based on the total weight of the mixture (b) before the separation of the mixture (b). In a more specific embodiment herein, the puncture cuts specifically comprise from about 0 to about 25 weight percent, more specifically from about 2 to about 20 weight percent, and very specifically from about 5 to about 15 percent by weight of the mixture (b), based on the total weight of the mixture (b) before the separation of the mixture (b). In another specific embodiment herein, it is well known that organic compounds containing a cation will react with clays having an anionic surface and interchangeable cations to form organarcillas. Depending on the structure and amount of the organic cation and the characteristics of the clay, the resulting organarcilla can be organophilic and thus have the property of dilation and dispersing or gelling in certain organic liquids depending on the concentration of organarcilla, the degree of shear applied and the presence of a dispersant. See for example the following US Pat. Nos., All incorporated herein by reference in their totals for all purposes: 2,531,427 (Hauser); 2,966,506 (Jordan); 4,105,578 (Finlayson and Jordan); 4,208,218 (Finlayson); and the book "Clay Mineralogy", 2nd Edition, 1968 by Ralph E. Grim, McGraw-Hill Book Co. , Inc., particularly Chapter 10 - Clay Mineral-Organic Reactions, pp. 356-368 - Ionic Reactions, Smectite, and pp. 392-401 - Organophilic Clay-Mineral Complexes. In another specific embodiment herein, the organophilic clays with base in attapulgite and sepiolite generally allow the suspension of the solid filling phase without drastically increasing the viscosity of the oil-mud, while the organophilic clays with base in bentonite, hectorite and saponite they are gelling agents and appreciably increase the viscosity of the oil-based mud. In one embodiment, some clays (such as bentonite) can be used as builders or viscosity in drilling muds, and are modified to make them organophilic in such a way that the layers in the clay are separated from each other and adsorb the oil that exists . Still in another specific modality in the present, the organophilic clays based on attapulgite or sepiolite can have a milliequivalent ratio (ME ratio) of about 30 to about 50. The ME ratio (milliequivalent ratio) is defined as the number of milliequivalents of the cationic compound in the organarcilla, per 100%. grams of clay, 100% active clay base. In one embodiment herein, organophilic clays based on bentonite, hectorite or saponite can have an ME ratio of about 75 to about 120. The optimum ME ratio will depend on the particular clay and the cationic compound used to prepare the organarcilla. In general, it has been found that the gelling efficiency of organophilic clays in non-polar oleaginous liquids increases as the ME ratio increases. In a specific embodiment, the more specific organophilic clays based on bentonite, hectorite or saponite can have an ME ratio in the range of 85 to about 110. In another specific embodiment herein, organic quaternary compounds useful herein are selected of the non-limiting group consisting of quaternary ammonium salts, quaternary phosphonium salts and mixtures thereof. In a specific embodiment herein, some representative non-limiting salts of quaternary phosphonium are described in the following patents North American Nos. , all incorporated in the present for reference in their totals: 3,929,849 (Oswald) and 4,053,493 (Oswald). In another specific embodiment, some representative non-limiting salts of quaternary ammonium are described in U.S. Patent No. 4,081,496 (Finlayson), incorporated herein by reference herein in its entirety, in addition to the patents previously cited herein. In a specific embodiment, the preferred quaternary compounds comprise a quaternary ammonium salt such as those described in U.S. Patent No. 4,508,628 the contents of which are incorporated herein by reference in their entirety. In another specific embodiment herein, some non-limiting quaternary ammonium cations are selected from the group consisting of trimethyloctadecylammonium, hydrogenated tallow trimethylammonium, trimethyldinoleylammonium, dimethyldidodecylammonium, dimethyldiotadecylammonium, dicoco dimethylammonium, dihydrogenated tallow dimethylammonium, dimethyldiricinolethylammonium, dimethylbenzyloctadecylammonium, dimethylbenzylammonium. hydrogenated tallow, dimecylbenzyltrichloleylammonium, methylbenzyldioctadecylammonium, methylbenzylammonium tallow dihydrogenase, methylbenzyldiricinolethylammonium, methylbenzylammonium dicoxide, metildibenciloctadecilamonio, metildibencilamonio hydrogenated tallow metildibencilricinoleilamonio, metildibencilamonio coconut metiltrioctadecilamonio, methylammonium of tri-, tallow, metiltriricinoleilamonio, methylammonium of tricoco, dibenzylammonium dicoconut, dibenzylammonium dihydrogenated tallow, dibencildioctadecilamonio, dibencildiricinoleilamonio, tribencilamonio hydrogenated tallow tribencildioctadecilamonio, tribencilamonio coconut tribencilricinoleilamonio and mixtures thereof. In another specific embodiment herein, the mixture (b) further comprises an additional component selected from the non-limiting group consisting of support agent, which may be selected from the non-limiting group consisting of resin-coated sand and high-grade ceramic materials. resistance as sintered bauxite; wetting agent which may be selected from the non-limiting group consisting of lecithin and various surfactants such as the non-limiting group consisting of modified polyamide (solubilized in naphthenic oil) and alkylamidomine, and one or more silicone surfactants such as the non-limiting example of silicone surfactant (a) described herein; temperature stabilizing additive which can be selected from the non-limiting group consisting of ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, glycerin, hexylenetriol, ethanolamine, diethanolamine, triethanolamine, aminoethylethanolamine, 2,3-diamino-1-propanol, 1,3-diamine-2-propanol, 3-amino-1, 2-propanediol, 2-amino-1, 3-propandiol; acrylic polymers; sulfonated polymers and copolymers; lignite; lignosulfonate; additives based on tannins; emulsifier which can be selected from the non-limiting group consisting of various fatty acid detergents, specifically calcium detergents, and polyamides; alkalinity and pH control additives, which may be selected from the non-limiting group consisting of lime, caustic soda, sodium carbonate and sodium bicarbonate, as well as other common acids and bases as are known to those skilled in the art; bactericides which may be selected from the non-limiting group consisting of imidazolines, aldehyde-based formulations, such as paraformaldehyde, isothiazoline and brominated compounds as are known to those skilled in the art; flocculants such as those used to increase viscosity for improved orifice cleaning, to increase bentonite yield and to rinse or dewater low solids fluids, which may be selected from the non-limiting group consisting of salt ( or brine), hydrated lime, gypsum, sodium carbonate, sodium bicarbonate, sodium tetraphosphate and polymers based on acrylamide; rheology modifier which can be selected from the non-limiting group consisting of starch, xanthan gum, dimeric and trimeric fatty acids, imidazolines, amides and synthetic polymers; filtrate reducers and / or fluid loss reducers which may be selected from the non-limiting group consisting of bentonite clays, lignite, sodium carboxymethylcellulose (CMC) and polyacrylate; shale control inhibitors which may be selected from the non-limiting group consisting of soluble calcium and potassium, as well as inorganic salts and organic compounds; lubricant which can be selected from the non-limiting group consisting of oil, synthetic liquid, graphite, surfactant, glycol and glycerin; and combinations thereof of any of the additional components described in the foregoing. In a specific embodiment herein, the additional component can be present in at least one of the aqueous phase, solid filling phase and oil phase and / or in the silicone surfactant (a) before and / or after the separation of the mixture (b). In a specific embodiment, the wetting agent may be any wetting agent such as those described in the following US Pat. Nos., Incorporated herein by reference in their entireties: 2,612,471; 2,661,334; 2,943,051, and US Patent Publication No. 2002/0055438 and the agent The humectant may further comprise the silicone surfactant (a) as described herein. In another specific embodiment herein, the temperature stabilizing additive may contain from 2 to about 6 carbon atoms and from 2 to about 4 polar groups selected from the group consisting of hydroxyl (OH), primary amino (NH2) and mixtures of the same per molecule. In yet another specific embodiment, the temperature stabilizing additive can be any temperature stabilizing additive such as those described in U.S. Patent No. 4,508,628 the contents of which are incorporated herein by reference in their entirety. In another specific embodiment, the emulsifier used in any mixture described herein, and specifically for preparing inverse oil emulsion drilling fluids, can be any of the commonly used water-in-oil emulsifiers used in the oil and gas drilling industry. gas. The emulsifying detergents described above can be formed in-situ in the oil-based mud by the addition of a fatty acid and a desired base, specifically the non-limiting example of lime. In a specific embodiment, some non-limiting representative emulsifiers are listed in the following US Pat. Nos., Incorporated herein by reference. reference in their totalities: 2,861,042; 2,876,197; 2,994,660; 2,999,063; 2,962,881; 2,816,073, 2,793,996; 2,588,808; 3,244,638. In a further specific embodiment, the fatty acid containing materials contain a fatty acid having eighteen carbon atoms, such as stearic acid, oleic acid, linoleic acid, preferably resin oil, air-blown resin oil, oxidized resin oil , triglycerides and the like. In yet another specific embodiment, the polyamide emulsifiers result from the reaction of a polyalkylene polyamine, preferably a polyethylene polyamine, with about 0.4 to about 0.7 equivalents of a fatty acid mixture containing at least 50% by weight of a fatty acid which it has 18 carbon atoms, and with about 0.3 to 0.6 equivalents of a dicarboxylic acid having from 4 to 8 carbon atoms. In another specific embodiment herein, the polyamide emulsifiers that result from the reaction of a polyalkylene polyamine, with a mixture of fatty acids as described above may be those represented by the reaction equation described in US Patent No. 4,508,628. , the contents of which are incorporated for reference in the present in its entirety.

In another specific embodiment herein, the mixture (b) may comprise an oil phase. In another more specific embodiment, the oil phase can be any oil phase known or commercially and / or industrially used, which occurs naturally or is added in a conventional manner by known and / or conventional methods. In a specific embodiment herein, the oil phase may comprise a hydrocarbon. In another more specific embodiment, the oil phase may comprise a fraction of petroleum oil, natural or synthetic oil, tallow, fat, wax, silicone containing synthetic oil, silicone containing fat and combinations thereof. In yet another more specific embodiment herein, the petroleum oil fraction is a petroleum or natural or synthetic petroleum product, selected from the group consisting of crude oil, heating oil, fuel oil for ships, kerosene, diesel fuel, fuel for aviation, gasoline, naphtha, shale oil, kerosene, tar oil, lubricating oil, motor oil, mineral oil, ester oil, fatty acid glyceride, aliphatic ester, aliphatic acetal, solvent, lubricating grease and combinations of same. In another specific embodiment herein, the oil phase of the mixture (b) also contains the additional silicone surfactant (a).

In a specific embodiment herein, the oil phase may also comprise other dissolved or suspended constituents, including suspended solid constituents which remain part of the oil phase after the separation of another solid phase. In a specific embodiment, for example, oil-based drilling fluid typically comprises a base oil, additives such as surfactants and viscosity modifiers, and suspended clay particles, as described herein. In a specific embodiment, the clay imparts body to the fluid so that the circulating fluid can entrain the perforation cuts and haul them from the borehole. In another specific embodiment, the drilling fluids also frequently contain a finely divided densifying material such as barite, a dense mineral that increases the density of the fluid for use in deep wells. In another specific embodiment, both the clay and the densifying material are typically so finely divided that they can remain suspended in the base oil over a substantial amount of time. In yet another specific embodiment, in the separation of the drilling fluid from the perforation cuts according to this invention, the drilling fluid, including its suspended solid constituents, may constitute the "oil phase" and the Piercing cuts can constitute the "solid filling phase." In yet another specific embodiment herein, if a given particulate solid filler can be separated from an oil phase as described herein, it is believed that it depends in part on the affinity of the oil phase for the solid filler (s), ie , of the tendency of the oily phase to wet the solid filler (s), and also in part of the particle sizes of the solid filler, the larger particles being easier to separate. In a specific embodiment, the base oil in the drilling fluid has a relatively strong affinity for the clay particle (s), while the shale oil has a lower affinity for the siliceous particle (s) found in the extractive mud. shale oil ashes. In another specific embodiment herein, the clay, for example, bentonite, the particle or particles in the drilling fluid are extremely fine, approximately 0.05 to 5 microns, averaging approximately 0.5 microns, while the ash particles in the extractor mud of ashes are in the order of 100 times larger, approximately 0.5 to 200 microns, averaging approximately 50 microns. In a more specific embodiment herein, the clay particles are charged electrically and therefore have a high affinity for the oil phase, while the siliceous particles are electrically neutral and therefore have a lower affinity for the oil phase. Thus, in a specific embodiment of this invention, the clay particles in the drilling fluid remain with the base oil when the fluid is separated from the drilling cuts, while in another embodiment, the ash particles are separated from the drilling fluid. shale oil. Still in another specific embodiment herein, it is not possible to affirm in advance, for all possible combinations of oils and particulate solids, precisely which mixtures can be successfully separated according to the modalities described herein, but as a general rule, however , particles that vary in average size (the largest dimension in cross section) of about 50 microns and larger can be separated from hydrocarbonaceous oils, such as crude and refined petroleum oils and similar oils produced from bituminous shale, sands impregnated with petroleum pitch, coal and the like, without difficulty using the modalities of the composition described herein. In yet another specific embodiment herein, the oil phase comprises in particular from about 1 to about 90 weight percent, more specifically from about 2 to about 70 weight percent, and very specifically from about 5 to about 50 weight percent of the mixture (b;, based on the total weight of the mixture (b) before the separation of the mixture (b) Still in another specific embodiment herein, the oil phase which is substantially insoluble in the aqueous phase comprises an oil phase which specifically is less than about 10 volume percent soluble in the aqueous phase, more specifically less than about 5 volume percent soluble in the aqueous phase and very specifically less than about 1 volume percent soluble in the aqueous phase, the percentages by volume based on the total volume of the oil phase. The following are given for the purpose of illustrating the invention of the present case, and are not intended for any purpose to set limitations to the embodiments described herein.

EXAMPLES In a specific embodiment in this description, it will be understood that silicone surfactant and demulsifier are equivalent terms. In another specific embodiment in this description it will be understood that one or more silicone surfactants (a) and mixtures of different silicone surfactants (a) can be used as described in this description.

It will be understood herein that the phrases "% by weight" and "percent by weight" are interchangeable as described herein. It will be understood that time, as expressed in the examples, is always total time from the start of the reaction mixture of polysiloxane hydride, allyl ether (or allyl alcohol), 2-propanol (solvent, if present), buffer and catalyst. It will be understood herein that the terms "catalyst", "platinum" and "platinum catalyst" are used interchangeably herein. In a specific embodiment herein, it will be understood that an initial catalyst charge is added at a time. If the reaction does not proceed to completion (ie, the consumption of all silicone hydrogen functionality), additional gradual charges of catalyst are made to direct the reaction to termination. In another specific embodiment herein, it will be understood that Examples A, B and C are organic demulsifiers which are benchmarks for comparing the benefits of the subject description, and the materials of Examples A, B and C by themselves are formulations whose compositions are closely guarded trade secrets. The sludge, which was studied in the examples in the following, (from a service company in oil and gas applications) in an oil-based mud used for marine drilling, removed from the well after use, mechanically separated from its cuts. It contains organarcillas covered with polymers, barium sulfate, biocides, emulsifiers, corrosion inhibitors, mineral oil, traces of crude oil from the well, water, inorganic salts, remaining cuts. It will be understood herein, in this full description, that the use of the h and hours for the time must be estimated equivalent. The method of manufacturing the starting materials, such as the non-limiting group of the polysiloxane hydrides, is well known in the art, as described in U.S. Patent Nos. 5,542,960; 6,221,815; 6,093,222; and 5,613,988, the contents of all of them are incorporated herein by reference in their totals. 1. Phasing Separation Test A first qualitative selection test of organic versus silicone based demulsifiers, generally comprised of the composition described herein, was performed. For this, 50 grams (g) or (gms) of a used drilling mud (mud) was used in a glass flask, then the required amount of silicones (silicone surfactant) as described in the following ( which varies from 0.1 weight percent to 5 weight percent for the largest concentration range (or 0.05 g to 2.5 g silicone plus 50 g mud with the weight percent silicone based on the total weight of the mud), was added to the mud). The glass flask was then vigorously stirred by hand for a period of 10 seconds measured with a stopwatch, and the sample was allowed to settle for a non-specific period of time, but for a minimum of one day before selection. Generally the qualitative observation of phase separation with time was made in the first 150 minutes where most of the phase separation occurred, this was an approximate test that was determined qualitatively. If a large phase separation of 40 to 50 volume percent of the aqueous phase occurred compared to the full volume of mud and silicone sample, it was denoted by the term "SI" in Table 1, if a small separation of phases of approximately 10 percent by volume, was denoted by "MODERATE" in Table 1, and when a phase separation did not occur it was denoted by "NO" in Table 1. 2. Phase Separation Rate - Turbiscan Lab instrument The most important part of the Turbiscan instrument Formulaction Lab is a detection head which moves up and down along a cylindrical cell of flat bottom borosilicate glass. The detection head consists of a pulse light close to the infrared (? = 850 nm) and two synchronous detectors. He Transmission detector receives the light, which goes through the sample (0o from the incident beam) while the backscatter detector receives scattered light through the sample at 135 ° from the incident beam. (The 135 ° angle was chosen to be outside the coherent backscatter cone). The detection head scans the total length of the sample (approximately 45 mm), acquiring transmission and backscatter data every 40 μm (1625 transmission and backscatter acquisitions per scan). These measured flows are calibrated with a non-absorbent reflectance standard (calibrated polystyrene latex beads) and a transmittance standard (silicone oil). The signal is first treated by a Turbiscan Lab voltage-to-current converter. The integrated microprocessor software handles data acquisition, in analogy to digital conversion, data storage, motor control and computer dialogue.

Description of the Turbiscan graphs: The silicone surfactant (a) was added at the top of a drilling mud (weight% silicone surfactant (a) / mud weight, the weight of the mud being 50 g in a flask glass, which was vigorously shaken by hand for 10 seconds (measured using a wristwatch) and then poured into the glass borosilicate used for the Turbiscan Lab instrument. Explorations were started as soon as possible after preparation to see sediment settlement. The scans were taken every minute for 10 minutes and then every 5 minutes for the next 50 minutes, and then every 30 minutes for the next 3 hours and 30 minutes and finally every 2 hours for the next 18 hours). Figure 1 shows a graph obtained by the Turbiscan Lab instrument from the beginning of the demulsification using the silicone surfactant (a) and for a period of 22 hours after the start of the demulsification. The vertical axis describes the diffuse reflectance or normalized backscattering with respect to a standard non-absorbing reflector and the horizontal axis represents the height of the sample in millimeters (mm) (0 mm corresponds to the bottom of the measurement cell). Due to the action of the silicone surfactant (a) on the mud, there is a sedimentation of the heavy solid particles (barite and clays) that appear quickly, shown in the backscatter plot by the change of sharp decrease on the right side of each curve to the left (corresponding to the decrease in the interface between the upper aqueous phase and the solid filling phase). It is interesting to note that the Turbiscan instrument Lab allows the detection of the destabilization of drilling mud at an early stage even when the medium is not transmitting light. Figure 1: Transmission and backscattering data of the Turbiscan Lab instrument at 29 degrees Celsius (° C) for a drilling mud from the Service Company treated with 2% by weight of Example 10B (Y-17014) based on the weight of drilling mud sample (corresponding to 1 g of silicone with 50 g of mud). Analysis of the data: the position of the air / drilling mud interface at the beginning of the demulsification using the silicone surfactant (a) gives the total height of the drilling mud in the Turbiscan tube and is on the right side of the first transmission curve when the curve finds the transmission axis zero. The lower part (minimum height of the drilling mud in the tube) of the Turbiscan glass is given by the left side of the first curve when the curve leaves the transmission axis zero. The evolution of the demulsification of the drilling mud using the silicone surfactant (a) is indicated by the decrease in the position of the aqueous phase / solid filler interface over time. This position is given by the point of inflection of the sharpest decrease in the backscatter and the shift to the left (the height of the solid fill phase is then decreasing with time). The Aqueous phase is then deduced from the complement to this position, compared to the whole sample. (See Tables 2a, 2b and 2c for different concentrations of demulsifiers ranging from 2 to 0.5% percent by weight of demulsifier based on the total weight of the sludge) The same experiments were performed for the different silicone surfactants (a) and then the results were compared with three other organic demulsifiers provided by a Service Company which is a customer. Example A belongs to the family of the ethoxylated alcohol and Example B belongs to the family of glycosides, Example C is a commercially secret compound that is unknown and was provided as a reference under a secret agreement, thus avoiding Applicants investigate or disclose their description. The results were compared in terms of percentages of the position of the solid phase / aqueous phase interface. In conclusion, from Tables 2a, 2b and 2c, the largest and fastest separation of aqueous phases was obtained for Example 41 (Y-17015) in the first 400 minutes (min). As described in the foregoing, Examples A, B and C are benchmarks for comparing the benefits of the subject description, and the materials of Examples A, B and C by themselves are formulations whose compositions are closely guarded business secrets. 3. Water clarity - Haze 2100 ratio turbidity measurement The best estimate of the clarity of the aqueous phase after separation was using Hach 2100 NTU turbidimeter (NTU = turbidity nephelometric units) since the demulsification of the mud perforation by the silicone or organic surfactant leads to the adhesiveness of the drilling mud sediments in the wall of the glass flask. In this way, the aqueous phase had to be removed without contaminating it to measure its turbidity. 250 g of drilling mud were treated with demulsifier in the required amount. The mixture was vigorously shaken by hand for 10 seconds and allowed to settle for two specified times such as 6 hours and 12 hours. About 30 g of the upper aqueous layer were removed with a plastic pipette in the middle part of the aqueous phase (to avoid taking the surface of the water and the sediments in the lower part of the aqueous phase) at different times. The turbidity of the extracted water was measured (see Table 4). Turbidity measures the dispersion of light through water caused by the materials in suspension or solution. Suspended and dissolved material may include clay, silt, finely divided organic and inorganic matter, soluble organic compounds of color and plankton and other organisms microscopic Other methods used for drilling mud analysis: (a) Measurement of the nonvolatile content of drilling mud or different phases after phase separation: The test was performed on samples of 2 grams (either drilling mud alone or the separated aqueous phase or the separated phase of solid filler) by using a thermogravimetric balance and heating the sample to approximately 160 ° C. The evolution of the disappearance of the volatile compounds was observed by measuring the weight loss from 100 weight percent to 0 weight percent based on the total weight of the volatile compound (s). The remaining non-volatile compound (s) corresponded to the remaining weight in the aluminum plate. The percentages obtained corresponded to the ratio of the remaining weight after heating to the initial mass of 2 grams. (See Table 3a for the results). (b) The analysis of the water content in the solid filling phase (sediments, barite), after the phase separation (and also for the drilling mud only) and after the aqueous phase was discarded, was carried out using the Karl Fischer method. For this test, each sample was homogenized by shaking. About lOg of sample were taken in 50 ml of Isopropyl Alcohol (IPA) in a polypropylene container. The sample solution in IPA is It stirred well to extract water from the mud. (See Table 3b for the results.) The titration of Silicon content by aluminum molybdate was performed according to the method of ASTM D859-00 (Standard test method for silica in water) in the separated water phases after treat the mud with 2% w / w of demulsifiers (separated water taken after 6 or 12 hours). The silicon content in the aqueous phase had to be measured to see where the remaining silicon is; for environmental reasons, in case of discharging the separated water to the sea or on land, (see Table 3c). The presence of heavy metals was also measured in the separated aqueous phase (both after 6 hours and 12 hours (total time after agitation of the treated sludge with 2% w / w of demulsifier (or Ig plus 50 g of sludge ))) using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP). (description of the method: 5g of the water layer was weighed in a beaker, evaporated slowly to dryness at 50 deg C. The residue obtained was boiled with concentrated nitric acid to leach the possible heavy metals in the residue. it was compensated to 25 ml using Milli-Q water, and analyzed by ICP) (see Table 3d). Table 1. Summary of tested materials (with results for phase separation test 1). The products listed in Table 1 in the second column, starting and including from Silwet L-720 and including all products under the second column up to and including Y-17015, are commercially available from GE Silicone with the exception of Magnasoft Expend, TP360 and TP 3890 which are no longer commercial grades. The remaining products in Table 1 and the continuation of Table 1 in the following are descd herein. Demulsification Tested level (test 1 of (percentage by weight Example Product Silicone separation of as weight of phases) demulsifier / pe of the sludge) Silwet L-720 Yes Light 1% Silwet L-7200 Yes No 1% Silwet L-7230 Yes No 1 % Ex 66 Silwet L-7280 Yes Yes 1 to 3% Silwet L-7550 Yes No 1% Silwet L-7600 Yes No 1% Silwet L-7602 Yes No 1% Silwet L-7604 Yes No 1% Ex 67 Silwet L- 7607 Yes No 1 to 5% Silwet L-7650 Yes No 1% Ex 28 Silwet L-77 Yes Yes 1.5 to 3% Silwet L-8600 Yes No 1% Silwet L-8610 Yes No 1% Magnasoft Expend Yes No 1% Magnasoft HSSD Yes No 1% Magnasoft SRS Yes No 1% Magnasoft HWS Yes Light 1% Magnasoft Ultra Yes No 1% Silbreak 1324 Yes No 1% Silbreak 1840 Yes No 1% Silbreak 327 Yes No 1% Silbreak 605 Yes Light 1% Silbreak 625 Yes Light 1% Silbreak 322 Yes No 1% Silbreak 323 Yes Light 1% Silbreak 638 Yes No 1% Silquest PA-l Yes No 1% TP 360 Yes No 2% TP-367 Yes No 1% TP 3890 Yes No 1% Ej 68 Y- 14759 Yes No 1% Y-14547 Yes Light 1% Ej 10B Y-17014 Yes Yes 0.2% to 2% Ej 41 Y-1 7015 Yes Yes 0.5 to 2% Y-17191 Yes Yes 0.5 to 2% Ex 69 Y- 17188 Yes Yes 1% Ex 70 Y-17189 Yes Yes 1% Ex 71 Y-17190 Yes Yes 1% Ex A Demulsifier B No Yes 0.5 to 2% Ex B Demulsifier C No Yes 0.75 to 2% Ej C Demulsifier. A No Nc 2% Summary of tested materials (with results for phase separation test 1). CONTINUE TABLE 1 Demulsification Tested level (test 1 of (percentage by weight of Product, as a weight of separation of demulsive / weight phases) of the sludge) Ex 01 MFV Yes No 1% Ex 02 MFVI Yes No 1% Ex 03 MFVII Yes No 1% Ex 04 MF VIII Yes No 1% Ex 05 MFIX Yes No 1% Ex 06 MFX Yes No 1% Ex 07 MFXI Yes No 1% Ex 08 MFXII Yes No 1% Ex 09 MFXIII Yes No 1% Ex 10A MFXIV Yes Yes 1% Ex 11 MFXV Yes Yes 1% Ex 12 MFXVI Yes Yes 1% Ex 13 MF XVII Yes Yes 0.3 to 2% Ex 14 RHI Yes No 1% Ex 15 RHII Yes No 1% Ex 16 RHIII Yes No 1% Ex 17 RHV Yes No 1% Ex 18 RHVI Yes No 1% Ex 19 RHVII Yes No 1% Ex 20 RHVIII Yes No 1% Ex 21 RHD Yes No 1-2% Ex 22 RHX Yes No 1-2% Ex 23 RH I Yes No 1% Ex 24 RHXH Yes No 1% Ex 25 RHXIII Yes No 1% Ex 26 RHXIV Yes Yes 1% Ex 27 RHXV Yes No 1% Ex 29 RHXVII No 1% Ex 30 RH XVIII Yes No 1% Ex 31 RHXIX Yes No 1% Ex 32 RHXX Yes No 1% Ex 33 RHXXI Yes No 1% Ex 34 RHXXII Yes No 1% Ex 35 RH XXIII Yes Light 1% Ex 36 RHXXIV Yes Light 1% Ex 37 RHXXV Yes No 1% Ex 38 RHXXVI Yes No 1% Ex 39 RHXXV1I Yes No 1% Ex 40 RH XXVIII Yes No 1% Ex 42 WARO 2590 Yes No 1% Ex 43 WARO 2591 Yes Yes 0.5 to 2% Ex 44 WARO 2592 Yes No 1% Ex 45 WARO 2593 Yes No 1% Ex 46 WARO 2594 Yes No 1% Ex 47 WARO 2595 Yes No 1% Ex 48 WARO 2596 Yes No 1% Ex 49 WARO 2597 Yes No 1% Ex 50 WARO 3609 Yes No 1% Ex 51 WARO 3743 Yes No 1% Ex 52 WARO 3744 Yes No 1% Ex 53 WARO 3745 Yes No 1% Ex 54 WARO 2598 Yes No 1% Ex 55 WARO 2599 Yes Yes 0.5 to 2% Ex 56 WARO 3601-2 Yes Yes 0.5 to 2% Ex 57 WARO 3602 Yes No 1% Ex 58 WARO 3603 Yes No 1% Ex 59 WARO 3604 Yes No 1% Ex 60 WARO 3605 Yes No 1% Ex 61 WARO 3606 Yes No 1% Ex 62 WARO 3610 Yes No 1% Ex 63 WARO 3748 Yes No 1% Ex 64 WARO 3749 Yes No 1% Ex 65 WARO 3751 Yes No 1% In a specific embodiment, the following definitions are defined for the following examples: M = Si (CH3) 3-01 / 2 MH = YES (CH3) 2-O? / 2 DH = YES (CH3) (O? / 2) 2 D = YES (CH3) 2 (O? / 2) 2 MM = hexamethyldisiloxane MHMH = 1, 1,3,3-Tetramethyldisiloxane D4 = octamethylcyclotetrasiloxane L31 = MDH50M MDHXM or MHDXMH are also called SiH or polysiloxane hydride The catalyst is either a 3.3 percent by weight (% by weight) solution (based on the weight of ethanol) of chloroplatinic acid in ethanol or a Karstedt PTS type catalyst solution of ("Platinum chelated to tetravinylcyclotetrasiloxane") in toluene containing 1% by weight of platinum metal (based on the weight of toluene). The Karstedt PTS type catalyst is one commercially available in ABCR as a Platinum-cyclovinylmethylsiloxane complex in cyclic methyl vinyl with CAS number 68585-32-0. The allyl content (or vinyl content or unsaturation rate) of a molecule is the percentage ratio by weight between the molecular weight of the allyl (or vinyl) group and the molecular weight of the total molecule. It will be understood herein that the demulsifier and the silicone surfactant (a), as described herein, are interchangeable. A molar excess of 30% of the allyl ether corresponds to an excess of 30% of the allyl ether in moles, compared to the polysiloxane hydride as described in each example in the following.

MHMH is commercially available from Flu a (CAS No. = 3277-26-7) as 1, 1, 3, 3-Tetramethyldisiloxane. For paragraphs 136 to 158 it is noted, in various examples in the following, that the NMR spectra indicated that the reaction product can sometimes be bound either Si-C (between the polysiloxane hydride and the allyther). linked Si-OC. The type of reaction product was then indicated. Example 01 (MF V) is a material prepared in the laboratory, obtained from the hydrosilylation reaction between MHD8MH and a molar excess of 30% of monoallyl ether of trimethylolpropane, which has the formula CH2 = CH-CH2-0-CH-C (CH2OH) 2-CH5. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 30 grams of polysiloxane hydride of the balanced formula MHD8MH containing 61.7 centimeters cubic per gram (cc / g) of active hydrogen (ccH2 / g), 18 grams of the allyl ether with an allyl content of 23.3 percent by weight and 48.9 grams of 2-propanol (solvent); then 114 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 74 ° C and platinum catalyst was introduced as 98 microliters of a 3.3% solution of chloroplatinic acid in ethanol (based on the weight of ethanol), which corresponds to 10 parts per million (ppm) of platinum (platinum metal). The The reaction was exothermic and the reactor temperature rose to 85 ° C within 9 minutes. The reaction ended (ie, the balanced SiH (MHD8MH) was consumed) after 1 hour (total time). The copolymer was allowed to cool with stirring in the reactor for 30 minutes and then removed. The solvent was removed under vacuum. The balanced MHD8MH was obtained by adding 36.9 g of MHMH, where MH has the definition described above, 163.1 g of D4 with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day dibutylethanolamine (272 microliters) was added for neutralization. The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a folded filter paper (10 μm pore size). Example 02 (MF VI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD8MH and a 30% molar excess of an allyl initiated polyether of the formula CH2 = CH-CH2-0- (CH2CH20 )? 2H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 30 grams of polysiloxane hydride of the formula MHD8MH balanced containing 61.7 cc / g of active hydrogen, 60.4 grams of the allyl ether with an allyl content of 7.3 weight percent (ratio between the molecular weight of the allyl group and the molecular weight of the total molecule) and 90.4 grams of 2 -propanol; then 181 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 212 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 79 ° C within 15 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The solvent was removed under vacuum. The balanced MHD8MH was obtained as explained in example 01. Example 03 (MF VII) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD6MH and a 30% molar excess of a polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2CH20)? 2H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 30 grams of polysiloxane hydride of the balanced formula MHD6MH containing 77.5 cc / g of active hydrogen, 75. 8 grams of the allyl ether with an allyl content of 7.3 weight percent and 105.8 grams of 2-propanol; then 246 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 212 microliters of a 3.3% solution of chloroplatinic acid in ethanol (based on the weight of ethanol), which corresponds to 10 parts per million (ppm) of platinum. The reaction was exothermic and the reactor temperature rose slightly to 79 ° C within 40 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The solvent was removed under vacuum. The balanced MHD6MH was obtained by adding 46.4 g of MHMH, 153.6 g of D4 with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a folded filter paper. Example 04 (MF VIII) is a material prepared in the laboratory, obtained from the hydrosilylation reaction between the balanced MHDMH and a molar excess of 30% of an allyl initiated polyether of the formula CH2 = CH-CH2-0- (CH2CH20)? .H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 25 grams of polysiloxane hydride of the balanced MHDMH formula containing 104.1 cc. / g of active hydrogen, 85 grams of the allyl ether with an allyl content of 7.3 weight percent and 110 grams of 2-propanol; then 256 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 220 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 parts per million (ppm) of platinum. The reaction was exothermic and the reactor temperature rose to 79 ° C within 40 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The solvent was removed under vacuum. The balanced MHDMH was obtained by adding 62.3 g of MHMH, 137.7 g of D4 with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary er for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The mixture was stirred on the rollers for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a folded filter paper. Example 05 (MF IX) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD2MH and 30 mol% of an allyl initiated polyether of the formula CH2 = CH-CH2-0- (CH2CH20) 12H . A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 16 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen, 82.9 grams of the allyl ether with an allyl content of 7.3 weight percent and 98.9 grams of 2-propanol; then 230 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 198 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was slightly exothermic and the reactor temperature rose to 75 ° C; then a second platinum addition (10 ppm) was made in 40 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then it was removed. The solvent was removed under vacuum. The balanced MHD2MH was obtained by adding 95 g of MHMH, 105 g of D4 with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary er for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The mixture was stirred on the rollers for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a filter paper. Example 06 (MF X) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD6MH and a molar excess of 30% of an allyl initiated polyether of the formula CH = CH-CH2-0- (CH2CH20 ) 7.5H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 42 grams of polysiloxane hydride of the balanced formula MHD6MH containing 77.5 cc / g of active hydrogen, 75.9 grams of the allyl ether with an allyl content of 10.23 weight percent; then 137 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 118 microliters of a 3.3% acid solution chloroplatinic in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature amounted to 96 ° C within 25 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD6MH was obtained as cited in example 03. Example 07 (MF XI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHDMH and a molar excess of 30% of a polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2CH20) 7. H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 34 grams of polysiloxane hydride of the balanced MHDMH formula containing 104.1 cc / g of active hydrogen, 82.6 grams of the allyl ether with an allyl content of 10.2 weight percent; then 136 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 117 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 88 ° C within 49 minutes. The reaction ended (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD4MH was obtained as cited in Example 04. Example 08 (MF XII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD2MH and a molar excess of 30% of a polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2CH20) 7.5 H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 25 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc / g of active hydrogen, 92.6 grams of the allyl ether with an allyl content of 10.2 weight percent; then 137 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 116 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. After the temperature was no longer increased, a second catalyst addition (10 ppm) was made in 17 min (total time) and 74 ° C, and a third catalyst addition of 10 ppm was made in 60 min (total time ) at 74 ° C. Then the temperature rose to 85 ° C after 107 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 4 hours (time total). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH was obtained as cited in Example 05. Example 09 (MF XIII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD6MH and a 30% molar excess of a polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2CH0) 3.5H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 33 grams of polysiloxane hydride of the balanced formula MHD6MH containing 77.5 cc / g of active hydrogen, 32.1 grams of the allyl ether with an allyl content of 19.0 weight percent; then 76 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 65 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 116 ° C within 5 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD6MH was obtained as cited in Example 03. Example 10A (MF XIV) is a material prepared in laboratory, obtained from the hydrosilylation reaction between the balanced MHDMH and a 30% molar excess of an allyl initiated polyether of the formula CH2 = CH-CH2-0- (CH2CH20) 3.5H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 33 grams of polysiloxane hydride of the balanced formula MHDMH containing 104.1 cc / g of active hydrogen, 43.1 grams of the allyl ether with an allyl content of 19.0 weight percent; then 89 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 76 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature amounted to 124 ° C within 9 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The balanced MHDMH was obtained as cited in example 04. Example 10B (Y-17014) is a commercial product of GE Silicones. Example 11 (MF XV) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD2MH and a 30% molar excess of an allyl initiated polyether of the formula CH2 = CH-CH2-0- (CH2CH20 ) 3.5H. A Glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 33 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc / g of active hydrogen, 65.75 grams of the allyl ether with an allyl content of 19.0 weight percent; then 115 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 99 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. After the temperature was no longer increased, a second catalyst addition (10 ppm) was made (after 27 min, total time) and then the temperature rose to 118 ° C after 51 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH was obtained as cited in Example 05. Example 12 (MF XVI) is the reaction product of the hydrosilylation between the balanced MDDHM and a molar excess of 30% of a polyether initiated by allyl with the formula of CH2 = CH-CH2-0- (CH2CH20) 3.5H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet was charged with 80.5 grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc / g of active hydrogen, 73.6 grams of polyether with an allyl content of 18.96 weight percent and 179 microliters of dibutylethanolamine as buffer. The (heterogeneous) reaction mixture was heated to 74 ° C and platinum catalyst was introduced as 154 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 parts per million (ppm) of platinum. The reaction was exothermic and the reactor temperature rose to 122 ° C within 12 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDHM was obtained by adding 106.4 g of MM, 49.9 g of D4 and 43.6 g of MDH50M or L31 (for the DH units) with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a paper bent filter. Example 13 (MF XVII) is the reaction product of the hydrosilylation between the balanced M (DH) 2M and a molar excess of 30% of a polyether initiated by allyl with the formula of CH 2 = CHCH 2-0- (CH 2 CH 20) 3.5 -H A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 30.0 grams of polysiloxane hydride of the balanced formula M (DH) 2M containing 153 cc / g of active hydrogen, 57.60 g of the polyether with an allyl content of 18.96 weight percent and 102 microliters of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 88 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 99 ° C within 40 minutes. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced M (DH) 2M was obtained by adding 108.4g of MM and 91.6g of MDH50M (or L31) with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a folded filter paper. Example 14 (RH I) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD? 0MH and a 30% molar excess of a polyether initiated by allyl CH2 = CH-CH2-0- (CH2CH20) 7.5 H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 45 grams of polysiloxane hydride of the formula MHD? OMH balanced containing 51.2 cc / g of active hydrogen, 53.8 grams of the allyl ether with an allyl content of 10.2 weight percent and 98.8 grams of 2-propanol; then 230 microliters of dibutylethanolamine was added as a buffer. The (homogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 98 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the temperature rose to 83 ° C after 11 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed The solvent was removed under vacuum. The balanced MHD? 0MH was obtained by adding 30.7 g of MHMH, 169.3 g of D with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day dibutylethanolamine (272 microliters) was added for neutralization. The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a folded filter paper. Example 15 (RH II) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD8MH and a molar excess of 30% of a polyether initiated by allyl with the formula of CH2 = CH-CH2-0- ( CH2CH20) 7.5-H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 48 grams of polysiloxane hydride of the balanced formula MHD8MH containing 61.7 cc. / g of active hydrogen, 69.1 g of polyether with an allyl content of 10.2 weight percent and 136 microlitres of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 117 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature amounted to 101 ° C within 14 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD8MH was obtained as cited in Example 01. Example 16 (RH III) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDS DH2 M and a 30% molar excess of an initiated polyether by allyl with the formula CH2 = CH-CH2-0- (CH2-CH2-0) 3.5-H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 38 grams of polysiloxane hydride of the balanced MD6DH2M formula containing 59.5 cc / g of active hydrogen, 28.4 g of polyether with an allyl content of 19.0 weight percent and 77 microliters of dibutylethanolamine as a buffer. The reaction mixture (heterogeneous) was heated to 72 ° C and platinum catalyst was introduced as 66 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 85 ° C within 30 minutes. The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor during minutes and then it was removed. The balanced MD6DH2M was obtained by adding 42.2 g of MM and 122.2 g of D and 35.6 g of MDH50M (or L31) with 163 microliters of trimethylsilyl trifluoromethanesulfonate. The glass flask was placed on a rotary shaker for 24 hours to equilibrate and the next day 272 microliters of dibutylethanolamine were added for neutralization. The mixture was stirred on the rollers of the rotary stirrer for 1 hour. There were some droplets on the glass walls, so 3 spatulas of NaHCO3 were added to further neutralize the mixture and then the mixture was filtered on a filter paper. Example 17 (RH V) is a laboratory-prepared material obtained from the hydrosilylation reaction between the balanced MHD2MH and a 30% molar excess of a polyether initiated by allyl CH2 = CH-CH2-0- (CH2CH20) 7.5CH3 . A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 20 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen, 77.7 grams of the allyl ether with an allyl content of 9.2 weight percent; then 115 microliters of dibutylethanolamine was added as a buffer. The reaction mixture (heterogeneous) was heated to 73 ° C and platinum catalyst was introduced as 99 microliters of a 3.3% acid solution chloroplatinic in ethanol, which corresponds to 10 ppm of platinum. After the temperature was no longer increased, a second catalyst addition (10 ppm) was made (after a total time of 15 min) and a third addition (10 ppm) was made after 36 min (total time) still at 74 ° C and then the bath regulated by thermostat was set at 90 ° C and the temperature rose to 92 ° C after 120 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH was obtained as cited in example 05. Example 18 (RH VI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD4MH and a 30% molar excess of a polyether initiated by allyl CH2 = CH-CH2-0- (CH2CH20) 7.5CH3. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 28 grams of polysiloxane hydride of the balanced MHDMH formula containing 104.1 cc. / g of active hydrogen, 71.4 grams of the allyl ether with an allyl content of 9.7 weight percent; then 116 microliters of dibutylethanolamine was added as buffer. The reaction mixture (heterogeneous) was heated to 85 ° C and catalyst was introduced platinum as 99 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. As no increase in temperature was observed, a second platinum addition was made after 10 minutes (total time) and the temperature of the reactor rose to 101 ° C within 23 minutes (total time). The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD4MH was obtained as cited in example 04. Example 19 (RH VII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD2MH and a molar excess of 30% of monoallyl ether of trimethylolpropane, the which has the formula of CH2 = CH-CH-0-CH2-C (CH20H) 2-C2H5. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 24 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen, 38.9 grams of the allyl ether with an allyl content of 23.3 weight percent allyl; then 73 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 85 ° C and platinum catalyst was introduced as 73 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH was obtained as cited in example 01. Example 20 (RH VIII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHDMH and a 30% molar excess of the 2-allyloxyethanol, the which has the formula CH2 = CH-CH2-0-CH2-CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 24 grams of polysiloxane hydride of the balanced MHDMH formula containing 158.8 cc. / g of active hydrogen, 22.7 grams of the allyl ether with an allyl content of 40 weight percent; then 54 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 47 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 154 ° C after 1.5 min but, after a total time of 30 min, the reaction did not end and an addition of 2 g of 2-allyloxyethanol was made at 6.8 ° C to finish the hydrosilation reaction. It will be understood in the present that the terms hydrosilation and hydrosilylation are interchangeable. The reaction ended (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH was obtained as cited in example 05. Example 21 (RH IX) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD2MH and a molar excess of 30% of 2-Allyloxy, 2 -propanediol (or Glycerin-1-allyl ether), which has the formula CH = CH-CH2-OCH2-CH (OH) -CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 24 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen, 29.3 grams of the allyl ether with an allyl content of 31 weight percent; then 62 microliters of dibutylethanolamine were added as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 53 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature amounted to 147 ° C after 1.5 min, but another addition of 10 ppm of platinum was made after 150 minutes (total time) at 71 ° C (an increase of five degrees after this addition). The reaction ended (ie, the balanced SiH was almost completely consumed with less than 0.05 ce H2 / g SiH remaining) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHDMH was obtained as cited in Example 05. Example 22 (RH X) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD2MH and a molar excess of 30% of the 2-allyl alcohol, which has the formula of CH2 = CH-CH2-OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 20 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen, 10.8 grams of the allyl alcohol with an allyl content of 70 weight percent, then 56 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 61 ° C and platinum catalyst was introduced as 48 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 81 ° C after 4 min but, as the reaction was not yet complete, an addition of 10 ppm was made. platinum catalyst after 25 min (total time) and at 62 ° C, and another addition of 10 ppm of platinum catalyst plus 2 grams of allylic alcohol, after 150 minutes (total time) at 62 ° C, allowed the reaction will finish. The reaction finally ended (ie, the balanced SiH was consumed) after 4 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The excess allyl alcohol was allowed to evaporate. The balanced MHD2MH was obtained as cited in Example 05. Example 23 (RH XI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHDMH and a molar excess of 30% of the trimethylolpropane monoallyl ether, the which has the formula of CH2 = CH-CH2-0-CH2-C (CH2OH) 2-C2H5. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 23.2 grams of polysiloxane hydride of the balanced formula MHD4MH containing 104.1 cc. / g of active hydrogen, 24.8 grams of the allyl ether with an allyl content of 23.3 weight percent, then 56 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 68 ° C and platinum catalyst was introduced as 48 microliters of a 3.3% solution of chloroplatinic acid in ethanol, corresponding to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 126 ° C after 2.5 min (total time). The reaction ended (ie, the balanced SiH was consumed) after 2 hours (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The excess allyl alcohol was allowed to evaporate. The balanced MHDMH was obtained as cited in example 04. Example 24 (RH XII) is a laboratory-prepared material, obtained from the hydrosilylation reaction between MDHM of heptamethyltrisiloxane, purified by distillation, and a molar excess of 30% of the allyl glycidyl ether initiated by allyl with the formula CH2 = CH-CH2-OCH2CHOCH2. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 55 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen, 35.5 grams of the allyl ether with an allyl content of 35.9 weight percent; then 105 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 61 ° C and platinum catalyst was introduced as 90 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. As no increase in temperature occurred, a second addition of platinum (10 ppm) was made after 12 min (total time). The reaction was then exothermic and the reactor temperature rose to 146 ° C after 27.5 min (total time). After 2 hours (total time) 2 g of the allyl ether and 10 ppm of platinum were added at 61 ° C. The reaction ended (ie, the balanced SiH was consumed) after 4 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The MDHM is 1,1,1,2,3,3,3 heptamethyltrisiloxane wherever it appears in the description, and the MDHM is distilled to a purity of 99 weight percent (% by weight) where it appears in the description. Example 25 (RH XIII) is a material prepared in the laboratory, obtained from the hydrosilylation reaction between the MDHM of heptamethyltrisiloxane, purified by distillation, and a molar excess of 30% of monoallyl ether of trimethylolpropane, which has the formula CH2 = CH-CH2-0-CH2-C (CH2OH) 2-C2H5. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 47.7 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen, 47.4 grams of the allyl ether with an allyl content of 23.3 weight percent; then 111 microliters of dibutylethanolamine was added as a buffer. The reaction mixture (heterogeneous) was heated to 76 ° C and introduced platinum catalyst as 95 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then exothermic and the reactor temperature rose to 135 ° C after 2.5 min (total time). A second addition of platinum (10 ppm) plus 2 grams of the allyl ether was made after 60 min at 77 ° C. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The MDHM was obtained as cited in Example 24. Example 26 (RH XIV) is a laboratory prepared material, obtained from the hydrosilylation reaction between MDHM of heptamethyltrisiloxane, purified by distillation, and a molar excess of 30% of a polyether initiated by allyl CH2 = CH-CH2-0- (CH2-CH20) 3.5-H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 45 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen, 55 grams of the allyl ether with an allyl content of 19.0 weight percent; then 116 microliters of dibutylethanolamine was added as buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 100 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then a little exothermic and the reactor temperature rose to 79 ° C after 5 min (total time). A second platinum addition (10 ppm) was needed and was made after 60 min (total time). The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The MDHM was obtained as cited in Example 24. Example 27 (RH XV) is a laboratory prepared material, obtained from the hydrosilylation reaction between MDHM of heptamethyltrisiloxane, purified by distillation, and a molar excess of 30% of a polyether initiated by allyl CH2 = CH-CH2-0- (CH2-CH20)? 2-H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 30 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen, 95.3 grams of the allyl ether with an allyl content of 7.3 weight percent; then 146 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 125 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then exothermic and the reactor temperature amounted to 103 ° C after 23 min (total time). A second addition of platinum (10 ppm) was needed and was made after 60 min at 73 ° C. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The MDHM was obtained as cited in Example 24. Example 28 is a commercial Silwet L77 product available from GE Silicones. Example 29 (RH XVII) is a material prepared in the laboratory, obtained from the hydrosilylation reaction between MDHM of heptamethyltrisiloxane and a molar excess of 30% of 2-allyloxyethanol, which has the formula of CH2 = CH-CH2-0- CH2-CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 50 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen and 29 grams of the allyl ether with an allyl content of 40 weight percent; then 92 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 74 ° C and platinum catalyst was introduced as 79 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then exothermic and the reactor temperature amounted to 147 ° C after 8 min (total time).

A second addition of platinum was needed and was made after 90 min (total time) at 71 ° C. The reaction ended (ie, the balanced SiH was consumed) after 2 hours (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. MDHM was obtained as cited in Example 24. Example 30 (RH XVIII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MDHM of heptamethyltrisiloxane and a molar excess of 30% 2-Allyloxy, 2 -propanediol (Glycerin-1-allyl ether), which has the formula of CH2 = CH-CH2-OCH2-CH (OH) -CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen and 29.9 grams of the allyl ether with an allyl content of 31 weight percent; then 81 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 70 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then exothermic and the reactor temperature rose to 129 ° C after 4 min (total time). A second addition of platinum (10 ppm) plus 2 grams of 2- Aliloxil, 2-propandiol and was made after 90 min (total time) at 71 ° C. To finish the reaction, a final addition of 10 ppm of platinum plus 1 gram of 2-Allyloxyl, 2-propanediol was made after 120 min (total time). The reaction ended (ie, the balanced SiH was consumed) after 4 hours (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. MDHM was obtained as cited in example 24. Example 31 (RH XIX) is a laboratory prepared material, obtained from the hydrosilylation reaction between MDHM of heptamethyltrisiloxane and a molar excess of 30% allyl alcohol, which has the formula of CH2 = CH-CH2-OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the general formula MDHM containing 97.3 cc. / g of active hydrogen, 13.2 grams of the allyl alcohol with an allyl content of 70 weight percent; then 62 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 61 ° C and platinum catalyst was introduced as 53 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was then a little exothermic without termination of the reaction. A second addition was needed of platinum (10 ppm) plus 1 gram of allyl alcohol and was made after 60 min (total time) at 62 ° C. The reaction ended (ie, the balanced SiH was consumed) after 2 hours (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The MDHM was obtained as cited in Example 24. Example 32 (RH XX) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD2MH and a 30% molar excess of allyl glycidyl ether with the formula CH2 = CH-CH2-OCH2CHOCH2. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the balanced formula MHD2MH containing 158.8 cc. / g of active hydrogen and 42.1 grams of the allyl ether with an allyl content of 35.9 weight percent; then 95 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 70 ° C and platinum catalyst was introduced as 82 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 183 ° C after 3 min (total time). A second addition of platinum (10 ppm) was required and was made after 60 minutes at 72 ° C. The reaction is over (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD2MH is obtained as cited in Example 05. Example 33 (RH XXI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MHD4MH and a 30% molar excess of allyl glycidyl ether with the formula CH2 = CH-CH2-OCH2CHOCH2. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the balanced formula MHD4MH containing 104.1 cc. / g of active hydrogen, 27.6 grams of the allyl ether with an allyl content of 35.9 weight percent; then 79 microliters of dibutylethanolamine was added as a buffer. The (heterogeneous) reaction mixture was heated to 71 ° C and platinum catalyst was introduced as 68 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction was exothermic and the reactor temperature rose to 180 ° C within 1 minute. A second addition of 10 ppm of platinum plus 1 g of the allyl ether was needed (it will be understood herein that the reference to the phrases "the allyl ether", "allyl alcohol", "allyl ether" or "allyl alcohol" or "polyether" started by alilo "refers allyl ether or allyl alcohol or "specific allyl initiated polyether", described in the example in which the phrase appears unless otherwise stipulated) and made after 2 hours (total time) at 71 ° C. The reaction ended (ie, the balanced SiH was consumed) after 3 hours (total time). The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MHD4MH is obtained as cited in example 04. Example 34 (RH XXII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and 30 mol% of 2-allyloxyethanol with the formula CH2 = CH-CH2-0-CH2-CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the balanced MD DHM formula containing 72.9 cc / g of active hydrogen, 17.3 g of polyether initiated by allyl with an allyl content of 40.0 weight percent and 67 microliters of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 57 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then it was removed. The balanced MDDH M was obtained as cited in Example 12. Example 35 (RH XXIII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDH M and a molar excess of 30% polyether initiated by allyl CH2 = CH-CH2-0- (CH2-CH20) 7.5-H. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 31 grams of polysiloxane hydride with the formula MDDHM containing 72.9 cc / g of active hydrogen, 52.7 g of the polyether initiated by allyl above with an allyl content of 10.2 weight percent and 97 microlitre of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 84 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The reaction ended (ie, the balanced SiH was consumed) after 2 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDHM was obtained as cited in Example 12. Example 36 (RH XXIV) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and a molar excess of 30% polyether initiated by ally CH2 = CH-CH2-0- (CH2-CH20) 7.5-CH3. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 35 grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc. / g of active hydrogen, 62.4 g of the polyether initiated by allyl with an allyl content of 9.7 weight percent and 113 microlitres of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 72 ° C and platinum catalyst was introduced as 97 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. As an increase in temperature did not occur after 10 min (total time), 10 ppm of platinum was added and the bath temperature regulated by thermostat was increased to 90 ° C. The temperature in the reactor amounted to 110 ° C after 20 min (total time). The reaction ended (ie, the balanced SiH was consumed) after 1 hour. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDHM was obtained as cited in Example 12. Example 37 (RH XXV) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and a 30% molar excess of Allyl glycidyl ether with the formula CH2 = CH-CH2-OCH2CHOCH2. A Glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 35 grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc / g of active hydrogen, 16.9 g of the allyl ether with an allyl content of 35.9 weight percent and 60 microliters of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 85 ° C and platinum catalyst was introduced as 52 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. Since no increase in temperature occurred after 10 min (total time), 10 ppm of platinum was added. The temperature in the reactor rose to 92 ° C after 20 min (total time). The reaction ended (ie, the balanced SiH was consumed) after 3 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDH M is obtained as cited in Example 12. Example 38 (RH XXVI) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and a molar excess of 30% of monoallyl ether of trimethylolpropane ( TMPMAE), which has the formula of CH2 = CH-CH2-0-CH2-C (CH2OH) 2-C2H5. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 35 grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc / g of active hydrogen, 26 g of the trimethylolpropane monoallyl ether with an allyl content of 23.3 weight percent and 71 microliters of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 74 ° C and platinum catalyst was introduced as 61 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The temperature rose to 134 ° C after 2 minutes (total time). Since the reaction was not yet finished after 3 hours (total time), 10 ppm of platinum was added in addition to 1 gram of trimethylolpropane monoallyl ether at 73 ° C. The reaction ended (ie, the balanced SiH was consumed) after 4 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDHM was obtained as cited in Example 12. Example 39 (RH XXVII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and a molar excess of 30% 2-allyloxy, 2 -propanediol (Glycerin-1-allyl ether), which has the formula of CH2 = CH-CH2-OCH2-CH (OH) -CH2OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with nitrogen. grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc / g of active hydrogen, 22.4 g of the allyl ether with an allyl content of 31 weight percent and 73 microliters of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 73 ° C and platinum catalyst was introduced as 62 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The temperature rose to 124 ° C after 5 minutes. As the reaction did not finish after 60 min (total time), 10 ppm of platinum and 2 grams of allyl ether were added. The reaction ended (ie, the balanced SiH was consumed) after 2 hours (total time) The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDHM was obtained as cited in Example 34. Example 40 (RH XXVIII) is a laboratory prepared material, obtained from the hydrosilylation reaction between the balanced MDDHM and a molar excess of 30% 2-allyl alcohol, which has the formula of CH2 = CH-CH2-OH. A glass reactor covered with nitrogen at atmospheric pressure, which was equipped with a temperature probe, a stirrer, a condenser and a nitrogen inlet, was charged with 40 grams of polysiloxane hydride of the balanced MDDHM formula containing 72.9 cc. / g of active hydrogen, 9.9 g of the allyl alcohol in the above, with a content of allyl of 70 weight percent of the allyl group, and 58 microlitre of dibutylethanolamine as a buffer. The (heterogeneous) reaction mixture was heated to 61 ° C and platinum catalyst was introduced as 50 microliters of a 3.3% solution of chloroplatinic acid in ethanol, which corresponds to 10 ppm of platinum. The temperature in the reactor did not rise. After 15 minutes (total time), the bath temperature regulated by thermostat was increased to 80 ° C. After 60 min (total time), 10 ppm of platinum were added at 74 ° C. After 2 hours (total time), the bath temperature regulated by thermostat was increased to 90 ° C. Another addition of 10 ppm platinum was performed at 74 ° C after 200 min (total time). The temperature rose to 86 ° C and, to finish the reaction, 2 grams of the allyl ether was added at 74 ° C after 300 min (total time). The reaction finally ended (ie, the balanced SiH was consumed) after 6 hours. The copolymer was allowed to cool in the reactor for 30 minutes and then removed. The balanced MDDH M was obtained as cited in Example 12. Example 41 (Y-17015) is a commercial product of GE. Example 42 (WARO 2590) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and an allyloxyethanol, which has the formula of CH2 = CH-CH2-0-C2H4OH, with the allyloxyethanol added in excess molar (30%) in the presence of the Karstedt PTS type catalyst ("platinum tetravinylsiloxane") (1% platinum in toluene). In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 26.26 grams of the allyloxyethanol of allyl ether were mixed with 0.1 gram of PTS (containing 1% of platinum metal) and the mixture is heated to a 70 ° C. Then, 13.4 g of MHMH are added dropwise for 10 minutes to complete the reaction. The system heated itself to 140 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-C predominantly, as observed by NMR. The weight of the obtained product was 37.4 g. The MHMH is commercially available from Fluka, as indicated above. Example 43 (WARO 2591) is a laboratory-prepared material obtained from the reaction product of the hydrosilylation of MHMH equilibrated with 30% molar excess of a polyether initiated by allyl with the formula CH2 = CH-CH2-0- (CH2CH20 ) 4.1-H, in the presence of the Karstedt PTS type catalyst (1% platinum in toluene). In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 33.93 g of the allyl initiated polyether were mixed with 0.1 gram of PTS (containing 1% of Platinum metal) and the mixture was heated at 70 ° C. Then, 6.7 grams of MHMH are added dropwise for 20 minutes to complete the reaction. The system was heated by itself to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-O-C predominantly, as observed by NMR. The weight of the product obtained was 38.4 g. The MHMH is commercially available from Fluka, as indicated above. Example 44 (WARO 2592) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and an allyl initiated polyether with the formula CH2 = CHCH2-0- added in molar excess (30%) and in the presence of the type Karstedt PTS catalyst. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 47.5g of the allyl initiated polyether was mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to a 70 ° C. Then, 6.7 g of MHMH are added dropwise during 20 minutes to complete the reaction. The system heated itself up to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-O-C predominantly, as observed by NMR. The weight of the product obtained was 52.7 g. The MHMH is commercially available from Fluka, as indicated above.

Example 45 (WARO 2593) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and an allyl initiated polyether with the formula of CH2 = CHCH2-0- (CH2CH20) 6.5H added in molar excess (30% ) in the presence of Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 49.53 grams of the allyl initiated polyether were mixed with 0.1 gram of PTS (containing 1% Platinum metal) and the mixture was heated at 70 ° C. Then, 6.7 grams of MHMH were added by dripping for 20 minutes to complete the reaction. The system heated itself to 130 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-C predominantly, as observed by NMR. The weight of the obtained product was 40.6 g. The MHMH is commercially available from Fluka, as indicated above. Example 46 (WARO 2594) is a laboratory-prepared material obtained from the hydrosilylation reaction between MHMH and a polyether initiated by allyl with the formula CH2 = CH-CH2-0- (C (H) (CH3) -CH20)? 6H added in molar excess (30%) in the presence of the catalyst type Karstedt PTS. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 39.0 grams of the allyl initiated polyether were mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. Then, 13.4 grams of MMH were added dropwise for 10 minutes. The system heated itself to 140 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-C predominantly, as observed by NMR. The weight of the product obtained was 52 g. The MHMH is commercially available from Fluka, as indicated above. Example 47 (WARO 2595) is a laboratory-prepared material obtained from the hydrosilylation reaction between MHMH and a vinyl-initiated polyether with the formula of CH2 = CH-0- (CH2-CH20) 2H with the vinyl-initiated polyether added in molar excess (30%) in the presence of Karstedt PTS type catalyst. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 34.06 grams of the vinyl initiated polyether were mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to a 70 ° C. Then, 13.4 grams of MHMH were added dropwise for 15 minutes. The system was heated by itself to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-O-C predominantly, as observed by NMR. The weight of the product obtained was 44.6 g. The MHMH is commercially available available from Fluka, as indicated in the above. Example 48 (WARO 2596) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and a vinyl initiated polyether with the formula of CH2 = CH-0- (CH2-CH20) 2 -CH3 with the polyether initiated per vinyl aggregate in molar excess (30 in the presence of Karstedt PTS type catalyst.) In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 49.14 grams of the polyether initiated by vinyl were mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. Then, 13.4 grams of MHMH were added by dripping for 15 minutes.The system heated itself up to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool The reaction product was predominantly bound with Si-OC as observed by NMR The weight of the product obtained was 57.5 gm MHMH is commercially available of Fluka, as indicates in the above. Example 49 (WARO 2597) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and a vinyl initiated polyether with the formula CH2 = CH-0- (CH2-CH20) 4-CH = CH2 with the Polyether initiated by vinyl added in molar excess (30%) in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a drip funnel and a reflux condenser, evacuated with nitrogen, 31.85 grams of the polyether initiated by vinyl was mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. Then, 6.7 grams of MHMH were added by dripping for 20 minutes to complete the reaction. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The reaction product was Si-C bonded predominantly, as observed by NMR. Example 50 (WARO 3609) is a laboratory-prepared material obtained from the hydrosilylation reaction between MHMH and the monoallyl ether of trimethylolpropane with the allyl ether added in molar excess (30%) and in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, were mixed 45.24g of the allyl ether with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. Then, 13.4 g of MHMH were added dropwise for 10 minutes. The system was heated by itself to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product binds Si-C predominantly, as observed by NMR. The weight of the product obtained was 57.1 g. The MHMH is commercially available from Fluka, as indicated above.

Example 51 (WARO 3743) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHMH and a polyether initiated by allyl with the formula of CH2 = CH-CH2- (CH2-CH20) 5.8-CH3 with the polyether initiated by allyl added in molar excess (30%) in the presence of the catalyst HPtCl6 (containing 1% Platinum). Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 43.2 g of the allyl initiated polyether were mixed with 0.1 gram of H2PtCl6 (containing 1% of Platinum metal) and the mixture was heated at 75 ° C. Then, 13.4 g of MHMH were added dropwise for 15 minutes. The system heated itself up to 90 ° C during hydrosilylation. The mixture was further stirred for 80 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 49.1 g. The MHMH is commercially available from Fluka, as indicated above. Example 52 (WARO 3744) is a laboratory-prepared material obtained from the hydrosilylation reaction between MHMH and an allyl initiated polyether with the formula CH2 = CH-CH2-0- (CH2-CH20) 6.8-CH3 with the Polyether initiated by added allyl in molar excess (30%) in the presence of the H2PtCle catalyst (containing 1% Platinum). In a bottle with a magnetic stirrer, a drip funnel and a reflux condenser, evacuated with nitrogen, 4.0 g of the allyl initiated polyether were mixed with 0.56 g of MHMH. The mixture was heated to 70 ° C and 0.02 gram of the H2PtCl6 catalyst (containing 1 percent platinum metal) was added. The system did not heat on its own during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the obtained product was 4.5 g. The MHMH is commercially available from Fluka, as indicated above. Example 53 (WARO 3745) is a laboratory prepared material obtained from the hydrosilylation reaction between MHMH and an allyl initiated polyether with the formula CH2 = CH-CH2-0- (CH2-CH20) 4.? - CH3 with the polyether initiated by added allyl in molar excess (30%) in the presence of the H2PtCl6 catalyst (containing 1% Platinum). Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 33.2 g of the allyl initiated polyether were mixed with 0.1 gram of H2PtCl6 (containing 1% Platinum) and the mixture was heated to a 72 ° C. Then, 6.7 g of MHMH were added dropwise for 5 minutes. The system heated itself to 92 ° C during hydrosilylation. The mixture was further stirred for 70 min at 130 ° C and allowed to cool. The reaction product is He linked Si-C predominantly, as observed by NMR. The weight of the obtained product was 4.5 g. The MHMH is commercially available from Fluka, as indicated above. Example 54 (WARO 2598) is a laboratory prepared material, obtained from the hydrosilylation reaction between MHDMH and an allyl initiated polyether with the formula of CH2 = CH-CH2-0- (CH2-CH20) H with the polyether initiated by allyl added in molar excess (30%) in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 26.26 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. . Then, 13.4 g of MHDMH were added dropwise for 20 minutes. The system heated itself to 150 ° C during hydrosilylation. The mixture was further stirred for 60 min at 140 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 45.5 g. The balanced MHDMH was obtained as follows: 600 g of MHDMH were obtained from the equilibrium of 1025 g of MHMH and 3800 g of MHD2MH (see preparation in Example 05) in the presence of 120 g of Levatit K2641 (a polystyrene ion exchanger) modified with sulfonic acid available from Lanxess) under reflux for 3 hours (the temperature was up to 97 ° C) and after cooling, the Levatit ion exchanger was filtered through a bent paper filter with a pore size of 10 μm. The final product was distilled to obtain a product with 96% purity. Example 55 (WARO 2599) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with molar excess of 30% of the initiated allyl of the formula CH2 = CH-CH2-0- (CH2CH20) 4.1-H , in the presence of the catalyst type Karstedt PTS. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 33.93 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1 percent of platinum) and the mixture was heated to 70 °. C. Then, 10.4 g of MHDMH were added dropwise for 10 minutes. The system heated itself to 130 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 42.8 g. The balanced MHDMH was obtained as cited in example 54. Example 56 (WARO 3601) is the reaction product of the hydrosilylation of the MHDMH equilibrated with molar excess of 30% of the initiated allyl of the formula CH2 = CHCH2-0- ( CH2CH20) 5.7-H, in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dripping funnel and a reflux condenser, evacuated with nitrogen, 47.5 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. Then, 10.4 g of MHDMH were added dropwise for 10 minutes. The system was heated by itself to 120 ° C during hydrosilylation. The mixture was further stirred for 60 min at 150 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 52.7 g. The balanced MHDMH was obtained as cited in example 54. Example 57 (WARO 3602) is a laboratory-prepared material obtained from the hydrosilylation reaction between the MHDMH equilibrated with 30% molar excess of the polyether initiated by allyl of the formula CH2 = CHCH-0- (CH2CH20) 6.5-H, in the presence of the catalyst type Karstedt PTS. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 49.53 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1 percent Platinum) and the mixture was heated to 70 °. C. Then, 10.4 g of MHDMH were added dropwise for 10 minutes. The system heated itself to 140 ° C during hydrosilylation. The mixture was further stirred for 60 min at 150 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the obtained product was 58.7 g. The balanced MHDMH was obtained as cited in Example 54. Example 58 (WARO 3603) is a laboratory prepared material obtained from the hydrosilylation reaction between the MHDMH equilibrated with molar excess of 30% of the initiated allyl of the formula CH2 = CHCH2- 0- (C (H) (CH3) -CH20)? 6-H, in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 39.0 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1 weight percent of platinum metal) and the mixture was heated at 70 ° C. Then, 20.8 g of MHDMH were added dropwise for 10 minutes. The system heated itself up to 160 ° C during hydrosilylation. The mixture was further stirred for 60 min at 140 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the obtained product was 58.2 g. The balanced MHDMH was obtained as cited in Example 54. Example 59 (WARO 3604) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with 30% molar excess of the vinyl initiated polyether of the formula CH2 = CH-0- (CH2-CH20) 2-H, in the presence of the Karstedt PTS type catalyst. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 34.06 g of the vinyl ether were mixed with 0.1 gram of PTS (which contains 1% Platinum) and the mixture was heated to 70 ° C. Then, 20.8 g of MHDMH were added dropwise for 15 minutes. The system heated itself to 150 ° C during hydrosilylation. The mixture was further stirred for 60 min at 140 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 53.1 g. The balanced MHDMH was obtained as cited in Example 54. Example 60 (WARO 3605) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with 30% molar excess of the vinyl initiated polyether of the formula CH2 = CH-0- (CH2-CH20) 3-CH3, in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 33.0 g of the vinyl ether was mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to 70 ° C. . Then, 13.96 g of MHDMH were added dropwise for 10 minutes. The system heated itself to 110 ° C during hydrosilylation. The mixture was further stirred for 60 min at 140 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 43.9 g. The balanced MHDMH was obtained as cited in example 54. Example 61 (WARO 3606) is a prepared material in the laboratory, obtained from the hydrosilylation reaction between the balanced MHDMH with a molar excess of 30% of the vinyl-initiated polyether of the formula CH2 = CH-0- (CH2-CH20) 4-CH = CH2, in the presence of the Karstedt-type catalyst PTS. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 31.85 g of the vinyl ether was mixed with 0.1 gram of PTS (containing 1 percent of platinum metal) and the mixture was heated to 70 ° C. Then, 10.4 g of MHDMH were added dropwise for 10 minutes. The system was heated by itself to 100 ° C during hydrosilylation. The mixture was further stirred for 60 min at 150 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 39.2 g. Balanced MHDMH was obtained as cited in example 54. Example 62 (WARO 3610) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with 30% molar excess of the trimethylolpropane monoallyl ether initiated by allyl , in the presence of the catalyst type Karstedt PTS. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 22.62 g of the allyl ether was mixed with 0.1 gram of PTS (containing 1 percent Platinum) and the mixture heated to 70 °. C. Then, 10.4 g of MHDMH were added dropwise for 10 minutes. He system was heated by itself to 130 ° C during hydrosilylation. The mixture was further stirred for 60 min at 150 ° C and allowed to cool. The reaction product binds Si-C predominantly, as observed by NMR. The weight of the product obtained was 31.4 g. The balanced MHDMH was obtained as cited in example 54. Example 63 (WARO 3748) is a laboratory-prepared material obtained from the hydrosilylation reaction between the MHDMH equilibrated with 30% molar excess of the polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2-CH20) 6.g-CH3, in the presence of the Karstedt PTS type catalyst. Into a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 10.4 g of the allyl initiated polyether were mixed with 0.1 gram of PTS (containing 1% Platinum) and the mixture was heated to a 70 ° C. Then, 10.4 g of MHDMH were added dropwise for 5 minutes. The system heated itself to 148 ° C during hydrosilylation. The mixture was further stirred for 90 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 57 g. The balanced MHDMH was obtained as cited in Example 54. Example 64 (WARO 3749) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with molar excess of 30% of the polyol initiated by allyl of the formula CH2 = CH-CH2-0- (CH2-CH20) 5.8-CH3, in the presence of the catalyst type Karstedt PTS. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 43.2 g of the allyl polyether were mixed with 0.1 gram of PTS (containing 1% of Platinum metal) and the mixture was heated to 76 °. C. Then, 10.4 g of MHDMH were added by dripping for 7 minutes. The system heated itself to 150 ° C during hydrosilylation. The mixture was further stirred for 60 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 54.2 g. The balanced MHDMH was obtained as cited in Example 54. Example 65 (WARO 3751) is a laboratory prepared material, obtained from the hydrosilylation reaction between the MHDMH equilibrated with molar excess of 30% of the polyether initiated by allyl of the formula CH2 = CH-CH2-0- (CH2-CH20) 4.1-CH3, in the presence of the Karstedt PTS type catalyst. In a bottle with a magnetic stirrer, a dropping funnel and a reflux condenser, evacuated with nitrogen, 33.2 g of the allyl polyether were mixed with 0.1 gram of PTS (containing 1% of Platinum metal) and the mixture was heated to 82 °. C. Then, 10.4 g of MHDMH were added by dripping for 7 minutes. The system heated itself to 130 ° C during hydrosilylation. The mixture was further stirred during 60 min at 130 ° C and allowed to cool. The reaction product was Si-C bonded predominantly, as observed by NMR. The weight of the product obtained was 43.6 g. The balanced MHDMH was obtained as cited in example 54. Example 66 (Silwet L-7280) is a commercial product of GE Silicones. Example 67 (Silwet L-7607) is a commercial product of GE Silicones. Example 68 (Y-14759) is a commercial product of GE Silicones. Example 69 (Y-17188) is an experimental product made by combining Y-17015 (40% by weight) and UCON 50H1500 (60% by weight). UCON 50H1500 is a commercial material available from Dow Chemicals. Example 70 (Y-17189) is an experimental product made by combining Pluronic 17R2 (40% by weight), Rhodasurf DA-530 (30% by weight) and Y-17015 (30% by weight). Pluroninc 17R2 is available from BASF Chemcials and Rhodasurf DA-530 is available from Rhodia Chemicals. Example 71 (Y-17190) is an experimental product made by combining Genapol X50 (30% by weight); Pluronic L-62 (40% by weight) and Y-17015 (30% by weight). Genapol X50 is available from Clariant Chemicals and Pluroninc L-62 is available from BASF Chemicals. Example A is an organic demulsifier provided by industry as Reference B, which belongs to the ethoxylated alcohol family. Example B is an organic demulsifier provided by the industry as Reference C, which belongs to the glycoside family. Example C is a business secret as described in the foregoing. No separation was observed in Example C at 2% 1% and 0.5% and thus is not included in Tables 2a, 2b and 2c.

Table 2a: Amount of aqueous phase (in% by volume based on the total volume of the initial sludge sample) versus time during phase separation of sludge samples of 50 g treated by different demulsifiers at a treatment rate of 2 % p / p (demulsifier weight / mud weight) of Turbiscan measurements at 29 ° C. (2% w / w of demulsifier corresponds to 1 g of demulsifier in 50 g of sludge). For examples 43, 55 and 56, smaller amounts of samples were available, so that 0.4 g was used in addition to 20 g of mud. t tsJ L? or L? L? Table 2b: Amount of aqueous phase (in% by volume based on the total volume of the initial sample) versus time during phase separation of sludge samples of 50 g treated by different demulsifiers at a treatment rate of 1 p / p (demulsifier weight / mud weight) of Turbiscan measurements at 29 ° C. (1% w / w of demulsifier corresponds to 0.5 g of demulsifier in 50 g of sludge).

H1 t co L? or L? or L? Table 2c: Amount of aqueous phase (in% by volume based on the total volume of the initial sample) versus time during phase separation of sludge samples of 50 g treated by different demulsifiers at a treatment rate of 0.5 p / p (demulsifier weight / mud weight) of Turbiscan measurements at 29 ° C. (0.5% w / w of demulsifier corresponds to 0.25 g of demulsifier in 50 g of mud).

[SJ OO tSJ ISJ L? or L? L? Table 3a: Non-volatile content and calculated total solids of the pure mud sample, the separated water phase and the separated solid phase (remaining mud) after 30 min and 60 minutes (total time after the agitation of treated sludge with 2% w / w of demulsifier (based on the weight of the initial sample of sludge or 1 g of demulsifier plus 50 g of sludge)) at 25 ° C. TABLE 3a H1 to LO a) Calculation made taking into account the percentage (by volume) of separated water phase after 30 min (total time), ie 32% and 68% of remaining sludge after separation (based on the total volume of the initial sample of mud). b) Calculation made taking into account the percentage (by volume) of separated water phase after 60 min (total time), ie 37% and 63% of remaining sludge after separation (based on the total volume of the initial sample of mud). c) Calculation made taking into account the percentage (in volume) of separated water phase after 30 min (total time), that is, 57% and 43% of remaining sludge after separation (based on the total volume of the initial sample of mud). d) Calculation made taking into account the percentage (by volume) of separated water phase after 60 min (total time), ie 57% and 43% of remaining sludge after separation (based on the total volume of the initial sample of mud). Table 3b: Percentage by weight of the moisture content (using the Karl Fischer method at 25 ° C) of the pure mud sample (before separation) and the separated solid phase after 6h and 12h (total time after the agitation of sludge treated with 2% (percent) by weight of demulsifier (based on the weight of the initial mud sample or lg plus 50 g of mud)). The moisture content in percentage is based on the weight of the sample that is being analyzed.

TABLE 3b t L? or L? L? Table 3c: Titration of the Silicon content by aluminum molybdate according to the method of ASTM D859-00 (Standard test method for silica in water) in the separated water phases after treating the slurry with 2% by weight (with base on the weight of the initial sample of sludge or 1 g of demulsifier for 50 g of sludge) of demulsifiers (separated water taken out after 6 or 12 h).

Table 3c LO to Table 3d: Concentration of heavy metals in the separated water phase (both after 6 h and 12 h (total time after agitation of the treated sludge with 2% w / w of demulsifier (based on the weight of the sample initial mud or lg plus 50 g of mud))) measured with an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP) co to L? Or O L? Table 4: Turbidity of the separated aqueous phase, measured after a period of time of 60 min or 15 hours of phase separation for mud samples treated by different demulsifiers at 25 ° C using the Hach 2100 Turbidimeter test as described in the foregoing) (The treatment rate of the demulsifier is given in% by weight of demulsifier / sludge weight). (1.5% w / w of demulsifier corresponds to 0.75 g of demulsifier in 50 g of sludge) (1% w / w of demulsifier corresponds to 0.5 g of demulsifier in 50 g of sludge) TABLE 4 LO In conclusion, after 60 minutes of separation, Examples 10B, 12 and 13 give the best clarity of water. After 15 hours of separation, Examples 10B, 41, 12 and 13 give the best clarity of water. These results indicate that the aqueous phases do not require any flocculants to further separate them. While the previous description comprises many specific details, these specific details should not be interpreted as limitations, but merely as exemplifications of specific modalities of the same. Those skilled in the art will envision many other modalities within the scope and spirit of the description as defined by the claims appended thereto.

Claims (36)

1. CLAIMS 1. A composition comprising: a) at least one silicone surfactant, and wherein the silicone of the silicone surfactant (a) has the general structure of: where M1 = R1R2R3SiO? 2; M2 = R4R5R6SiO?; D1 = R7R8Si02 2; D2 = R9R10SiO2 / 2; T1 = R ^ SiOa / z; T2 = R12Si03 / 2; Q = Si04 / 2 where R1, R2, R3, R5, R6, R7, R8, R10 and R11 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to twenty carbon atoms, hydrogen, OH and OR13 , where R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, R4, R9 and R12 independently are hydrophilic organic groups, and where the subscripts a, b, c, d, e, f and g are zero or positive integers for molecules subject to the following limitations: (a + b) corresponds to either (2 + e + f + 2g) or (e + f + 2g), b + d + f > 1, and, 2 < (a + b + c + d + e + f + g) < 100; and, b) a mixture comprising an aqueous phase, a solid filling phase and optionally an oil phase which is substantially insoluble in the aqueous phase.
2. 2. The composition of Claim 1, further comprising the cases wherein: R4, R9 and R12 independently are hydrophilic organic groups selected from the group consisting of Z1, Z2, Z3 and Z8 where, Z1 is at least one group polyoxyalkylene having the general formula B10 (ChHhO) nR14 where BIO is an alkylene radical containing from 2 to about 4 carbon atoms R14 is a hydrogen atom or a hydrocarbon radical containing from 1 to about 4 carbon atoms; n is 1 to 100; h is 2 to 4 which provides at least one polyoxyalkylene group with the proviso that at least about 10 mole percent of at least one polyoxyalkylene group is polyoxyethylene; Z2 has the general formula B2 (OH) m where B2 is a hydrocarbon containing from 2 to about 20 carbon atoms and containing optionally groups with oxygen and / or nitrogen, and m is sufficient to provide hydrophilicity, Z3 is the reaction product of an epoxy adduct, with a primary or secondary hydrophilic amine; Z8 is at least one polyoxyalkylene group having the general formula: O B7 0 (ChH2hO) nR14 where B7 is an alkyl bridge containing from 2 to about 12 carbon atoms or an aryl bridge containing from 2 to about 12 carbon atoms. carbon; R14 is hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms; n is 1 to 100; h is 2 to 4 which provides at least one polyoxyalkylene group with the proviso that at least about 10 weight percent of at least one polyoxyalkylene group is polyoxyethylene; and where, 2 < (a + b + c + d + e + f + g) < 100.
3. 3. The composition of Claim 2, further comprising the cases in which the silicone of the silicone surfactant (a) has the general structure of: M ^ Mb D ^ D2d where M1 = R1R2R3SiO? / 2; M2 = RR5R6SiO? / 2; D1 = R7R8SY02 / 2; D2 = R9R10SiO2 / 2; wherein R1 is selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, wherein R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and R2, R3, R5, R6, R7, R8 and R10 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4 and R9 are independently selected from the group consisting of Z1, Z2, Z3 and Z8 where a + b is approximately 2 and 2 < (a + b + c + d) < 75.
4. 4. The composition of claim 3, further comprising the cases in which the hydrophilic organic groups further comprise the cases in which R4, R9 and R12 are independently selected from the group consisting of Z2, Z4, Z6 and Z9, where Z4 has the general formula B10 (CH40) p (C3H60) qR14 where B1 is an alkylene radical containing from 2 to about 4 carbon atoms R14 is hydrogen or a hydrocarbon radical contains from 1 to about 4 carbon atoms, p is 1 to 15, q < 10 and p > q; Z6 is selected from the general formula of: c. B5 (OR B6) s N (R15) 2 or where B5 and B6 independently are hydrocarbon radicals containing from 2 to about 6 carbon atoms, which optionally may contain OH groups, s is 0 or 1, and each R0.15 independently is hydrogen or an alkylene oxide group having the general formula - (CuHuO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least 50 mole percent of the alkylenoxide groups are oxyethylene; R16 is hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms; Z7 is either a nitrogen atom or an oxygen atom with the proviso that if Z7 is an oxygen atom, then w = 0, and if Z7 is a nitrogen atom, then w = 1, R17 is independently selected from an alkylene oxide group having the general formula - (CuH2uO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least about 50 mole percent of the alkylenoxide groups are oxyethylene; the R18 groups are independently selected from the group consisting of hydrogen, OH, a hydrocarbon radical containing from 1 to about 4 carbon atoms and an alkylenoxide group having the general formula - (CuH2uO) v-R16 where u is 2 to 4 and v is 1 to 10, with the proviso that at least 25 mole percent of the alkylenoxide groups are oxyethylene; Z9 has the general formula O B7 O (C2H40) p (C3H60) qR14 where B7 is an alkyl bridge or an aryl bridge containing from 2 to about 12 carbon atoms, R14 is hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms; p = 1 to 15, q < 10 and p > q.
5. 5. The composition of Claim 4, wherein the silicone of the silicone surfactant (a) has the general structure of: Mxa M2b D ^ D2d where M1 = R1R2R3Si0? 2; M2 = R4R5R6Si0? / 2; D1 = R7R8Si02 / 2; D2 = R9R10SiO2 / 2; wherein R1 is selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, wherein R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and R2, R3, R5, R6, R7, R8 and R10 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, R4 and R9 are independently selected from the group consisting of Z2, Z4, Z6 and Z9 as described above, and + b corresponds to approximately 2 and, in particular, c + d < 10, more specifically c + d < 8, and very specifically c + d < 5.
6. The composition of Claim 5, further comprising the cases in which the silicone of the silicone surfactant (a) has the general structure of: M2 Dxc M2 where M2 = R4R5R6SiO? 2; D1 = R7R8Si02 / 2; where R5, R6, R7 and R8 are each independently selected from the group consisting of radicals monovalent hydrocarbons containing one to six carbon atoms, hydrogen, OH and OR13, wherein R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and R4 is selected from the group consisting of Z2, Z4, Z6 and Z9 and where c is specifically from 0 to 10, more specifically from 0 to 8 and very specifically from 0 to 5.
7. The composition of Claim 5, further comprising the cases in which the silicone of the surfactant (a) Silicone has the general structure of: M1 D1, - D2d M1 where M1 = RxR2R3SiO? 2; D1 = R7R8Si02 / 2; D2 = R9R10SiO2 / 2; wherein R1 is selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, wherein R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and R2, R3, R7, R8 and R10 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, where R13 is a group hydrocarbon containing from 1 to about 4 carbon atoms, and R9 is specifically selected from the group consisting of Z2, Z4, Z6 and Z9, as described above, where c specifically is from 0 to 10, more specifically from 0 to 5 and very specifically from 0 to 2, and d specifically is from 1 to 10, more specifically from 1 to approximately 6 and very specifically from 1 to 3 and, in a more specific modality, where c is from 0 to 2 and d is from about 1 to 3.
8. The composition of Claim 7, further comprising the cases in which the silicone of the silicone surfactant (a) is a trisiloxane and has the general structure of: M1 D2 M1 which is obtained from the hydrosilylation of a silicone distilled polymer having the general formula M1 DH M1 and initiating unsaturated alkylene oxide in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1R2R3SiO? 2; DH = HR10SÍO2 / 2, D2 = R9R10SiO2 / 2; wherein R1, R2, R3 and R10 are each independently selected from the group consisting of radicals monovalent hydrocarbons containing from 1 to 6 carbon atoms, hydrogen, OH and OR13; where R13 is a hydrocarbon group containing 1 to about 4 carbon atoms and R9 is specifically selected from the group consisting of Z2, Z4, Z6 and Z
9. 9. The composition of Claim 6, further comprising the cases where the silicone surfactant (a) is a low molecular weight ABA siloxane block copolymer where the silicone of the silicone surfactant (a) has the general structure MRD1CMR which is obtained from the hydrosilylation of the silicone polymer having the general formula MHD1CMH and unsaturated initiated alkylene oxide and present in sufficient molar excess to terminate the hydrosilylation reaction, where c is 0 to 10, D1 = R7R8Si02 / 2, MR = R4RR6SÍ01 / 2, MH = HR5R6Si01 / 2 and where R5, R6, R7 and R8 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and wherein R 4 is CgH 2g-0 (C 2 H 40) p (C 3 H 60) g R 14 and wherein R 14 is hydrogen, or a hydrocarbon radical containing from 1 to about 4 carbon atoms; g = 2 to 4; p = 1 to 12; q < 6; and p > q.
10. 10. The composition of Claim 7, which further comprises the cases in which the silicone surfactant (a) is a low molecular weight pending siloxane copolymer where the silicone of the silicone surfactant (a) has the general structure M1 D1c DRd M1 which is obtained from the hydrosilylation of a silicone polymer having the general formula M1 D1c DHd M1 and initiating alkylene oxide unsaturated in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1RR3SiO? / 2, D1 = R7R8Si02 / 2, DR = R9R10SiO2 / 2, DH = HR10SiO2 2, and where c is from 0 to 10, and d specifically is from 1 to 10, where R1 is selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing 1 to about 4 carbon atoms, and R 2, R 3, R 7, R 8 and R 10 are each independently selected from the group consisting of monovalent hydrocarbon radicals containing one to six carbon atoms. carbon, hydrogen, OH and OR13, where R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and where R9 independently is CgH2g-0 (C2H4?) p (C3H60) qR14 and where R14 is hydrogen, or a hydrocarbon radical containing from 1 to about 4 carbon atoms; g = 2 to 4; p = 1 to 12; q < 6; and p > q.
11. 11. The composition of Claim 10, further comprising the cases in which the silicone surfactant (a) is a trisiloxane-siloxane copolymer where the silicone of the silicone surfactant (a) has the general structure M1 DR M1 which is obtained from the hydrosilylation of a silicone distilled polymer having the general formula M1 DH M1 and initiating unsaturated alkylene oxide in molar excess sufficient to terminate the hydrosilylation reaction, where M1 = R1R2R3SiO? 2, DR = R9R10SiO2 / 2, DH = HR10SiO2 2, wherein R1, R2, R3 and R10 are each independently selected from the group consisting of CH3, hydrogen, OH and OR13, and wherein R13 is a hydrocarbon group containing from 1 to about 4 carbon atoms, and wherein R9 is CgH2g- 0 (C2H40) p (C3H60) qR14, and where R14 is hydrogen or a hydrocarbon radical containing from 1 to about 4 carbon atoms; g = 2 to 4; p = 1 to 12; q < 6; and p > q.
12. The composition of Claim 1, further comprising the cases where the silicone surfactant (a) is used in a concentration of about 0.001 weight percent to about 5 weight percent, based on the total weight of the the composition, to intensify the separation of phases.
13. The composition of Claim 2, further comprising the cases in which the surfactant (a) of silicone is used in a concentration of about 0.001 weight percent to about 5 weight percent, based on the total weight of the composition, to intensify phase separation.
14. The composition of Claim 3, further comprising the cases in which the silicone surfactant (a) is used in a concentration of about 0.001 weight percent to about 5 weight percent, based on the total weight of the the composition, to intensify the separation of phases.
15. The composition of Claim 4, further comprising the cases in which the silicone surfactant (a) is used in a concentration of about 0.001 weight percent to about 5 weight percent, based on the total weight of the the composition, to intensify the separation of phases.
16. The composition of Claim 5, further comprising the cases where the silicone surfactant (a) is used in a concentration of about 0.001 weight percent to about 5 weight percent, based on the total weight of the the composition, to intensify the separation of phases.
17. The composition of Claim 6, further comprising the cases where the silicone surfactant (a) is used in a concentration of about 0.001 percent by weight to about 5 percent by weight, based on the total weight of the composition, to intensify phase separation.
18. The composition of Claim 1, further comprising the cases in which the mixture (b) can be any known or commercial and / or industrially used mixture, which occurs naturally or is added in a conventional manner by methods known and / or conventional.
19. 19. The composition of Claim 1, further comprising the cases in which the mixture (b) may comprise a drilling mud, a shale-extracting sludge from shale oil, a refinery sludge, a floor of a refinery and / or industrial site, a site floor of the filtering fuel storage tank, a mixture of crude oil from tank waste, a pharmaceutical emulsion, a sand impregnated with tar-oil and combinations thereof.
20. The composition of Claim 1, further comprising the cases in which the mixture (b) is a mixture selected from the group consisting of a mixture resulting from an oil spill, a mixture resulting from a rupture of oil pipelines, a mixture resulting from a filter fuel tank, a mixture resulting from an industrial operation and combinations thereof.
21. 21. The composition of Claim 1, further comprising the cases in which the aqueous phase can be any known commercial or commercial and / or industrially used aqueous phase, which occurs naturally or is added in a conventional manner by known methods and / or conventional.
22. The composition of Claim 1, further comprising the cases in which the aqueous phase of the mixture (b) contains water in an amount of about 1 to about 99 weight percent, with the weight percentage based on the weight total of the mixture (b).
23. 23. The composition of Claim 22, which further comprises the cases in which the water further comprises an inorganic salt selected from the group consisting of sodium chloride, calcium chloride, magnesium chloride, sodium sulfates, magnesium sulfate, sodium carbonate, calcium carbonate, carbonate of magnesium and combinations thereof in an amount up to about saturation of the aqueous phase.
24. The composition of Claim 1, further comprising the cases in which the aqueous phase of the mixture (b) also contains additional silicone surfactant.
25. 25. The composition of Claim 1, further comprising the cases in which the solid filling phase of the mixture (b) occurs naturally or is added to conventional way through known and / or conventional methods.
26. 26. The composition of Claim 25, further comprising the cases wherein the solid filling phase of the mixture (b) comprises a solid filler selected from the group consisting of perforation cuts; siliceous solid; rock; gravel; floor; ash; mineral; metal and metal minerals; a part of metal; a glass plate; cellulosic material; densifying agent; suspension agent; agent for fluid loss control; and combinations thereof.
27. The composition of Claim 25, further comprising the cases in which the solid filling phase comprises from about 1 to about 99 weight percent of the mixture (b), based on the total weight of the mixture (b) ).
28. The composition of Claim 26, further comprising the cases where the perforation cuts comprise from about 0 to about 25 weight percent of the mixture (b), based on the total weight of the mixture (b) .
29. 29. The composition of Claim 1, further comprising the cases in which the solid filling phase of the mixture (b) also contains additional silicone surfactant.
30. 30. The composition of Claim 1, further comprising the cases in which the mixture (b) further comprises an additional component selected from the group consisting of support agent; wetting agent; temperature stabilizing additive; sulfonated polymers and copolymers; lignite; lignosulfonate; additives based on tannins; emulsifier; alkalinity additives and pH control; bactericides; flocculants; rheology modifier; inhibitors of shale control of filtrate reducers and / or fluid loss reducers; lubricant; and combinations thereof.
31. The composition of Claim 1, further comprising the cases in which the oil phase can be any known or commercial and / or industrially used oil phase, which occurs naturally or is added in a conventional manner by known methods and / or conventional.
32. 32. The composition of Claim 1, further comprising the cases in which the oil phase comprises a hydrocarbon.
33. 33. The composition of Claim 1, further comprising the cases in which the oil phase comprises a fraction of petroleum oil, natural or synthetic oil, tallow, grease, wax, silicone containing synthetic oil, silicone containing fat and combinations of the same.
34. 34. The composition of Claim 33, further comprising the cases in which the petroleum oil fraction is a petroleum or natural or synthetic petroleum product, selected from the group consisting of crude oil, heating oil, fuel oil for ships , kerosene, diesel fuel, aviation fuel, gasoline, naphtha, shale oil, kerosene, tar oil, lubricating oil, motor oil, mineral oil, ester oil, fatty acid glyceride, aliphatic ester, aliphatic acetal, solvent, lubricating grease and combinations thereof.
35. 35. The composition of Claim 1, further comprising the cases in which the oil phase of the mixture (b) also contains additional silicone surfactant.
36. 36. The composition of Claim 1, further comprising the cases in which the oil phase comprises from about 1 to about 90 percent by weight of the mixture (b), based on the total weight of the mixture (b).