MX169580B - Metodo mejorado para la produccion de acrilato de etilo - Google Patents

Metodo mejorado para la produccion de acrilato de etilo

Info

Publication number
MX169580B
MX169580B MX012239A MX1223988A MX169580B MX 169580 B MX169580 B MX 169580B MX 012239 A MX012239 A MX 012239A MX 1223988 A MX1223988 A MX 1223988A MX 169580 B MX169580 B MX 169580B
Authority
MX
Mexico
Prior art keywords
ethyl acrylate
production
improved method
acid
acrylic acid
Prior art date
Application number
MX012239A
Other languages
English (en)
Inventor
Edward F Dougherty
James L Paul
Original Assignee
Hoechst Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Celanese Corp filed Critical Hoechst Celanese Corp
Publication of MX169580B publication Critical patent/MX169580B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/22—Accessories

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

La presente invención se refiere a un metodo mejorado para producir acrilato de etilo mediante la reacción de etileno y ácido acrílico en presencia de ácido sulfúrico para obtener acrilato de etilo y un residuo de ácido sulfúrico, que contiene ácido sulfúrico, sulfato ácido de etilo, sulfato de dietilo, ácido acrílico, acrilato de etilo, poliesteres de ácido acrílico y polímeros de lactona, en donde la mejora comprende poner en contacto dicho residuo con un solvente seleccionado del grupo que consiste de agua, un alcohol inferior que tiene de 1 a 4 átomos de carbono o una mezcla acuosa de dicho alcanol, calentar y destilar la mezcla a temperaturas dentro del rango de aproximadamente 50 a 250 grados C, a presiones de aproximadamente 30 mm Hg absoluto hasta 3 atmósferas, para evaporar el ácido acrílico y el acrilato de etilo, y posteriormente, recuperar el ácido acrílico y el acrilato de etilo.
MX012239A 1987-07-14 1988-07-13 Metodo mejorado para la produccion de acrilato de etilo MX169580B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/073,782 US5145989A (en) 1987-07-14 1987-07-14 Recovery of acrylic acid and/or ethyl acrylate from black acid

Publications (1)

Publication Number Publication Date
MX169580B true MX169580B (es) 1993-07-13

Family

ID=22115768

Family Applications (1)

Application Number Title Priority Date Filing Date
MX012239A MX169580B (es) 1987-07-14 1988-07-13 Metodo mejorado para la produccion de acrilato de etilo

Country Status (13)

Country Link
US (1) US5145989A (es)
EP (1) EP0299743B1 (es)
JP (1) JP2602696B2 (es)
CN (1) CN1019970C (es)
AT (1) ATE64367T1 (es)
AU (1) AU602779B2 (es)
BR (1) BR8803496A (es)
CA (1) CA1307795C (es)
DD (1) DD274209A5 (es)
DE (1) DE3863244D1 (es)
ES (1) ES2022623B3 (es)
GR (1) GR3002122T3 (es)
MX (1) MX169580B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4968834A (en) * 1990-05-07 1990-11-06 Hoechst Celanese Corporation Recovery of acrylic acid and/or ethyl acrylate from black acid
DE4019781A1 (de) * 1990-06-21 1992-01-02 Basf Ag Verfahren zur herstellung von monoethylenisch ungesaettigten carbonsaeureestern
US20040019235A1 (en) * 2000-12-18 2004-01-29 Friedrich-Georg Martin Method for producing higher (meth)acrylic acid esters
US6897338B2 (en) * 2001-12-18 2005-05-24 Metabolix, Inc. Methods of making intermediates from polyhydroxyalkanoates
CA2788596A1 (en) 2010-02-11 2011-08-18 Metabolix, Inc. Process for producing a monomer component from a genetically modified polyhydroxyalkanoate biomass
CN110684470B (zh) * 2019-10-21 2022-03-01 江苏利田科技股份有限公司 一种利用uv单体废水制备丙烯酸酯粘合剂的方法以及一种丙烯酸酯粘合剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1668391A1 (de) * 1966-09-09 1972-03-30 Montedison Spa Verfahren zur kontinuierlichen Herstellung von AEthylestern ungesaettigter Monocarbonsaeuren mit bis zu 4 Kohlenstoffatomen
US3894076A (en) * 1974-01-24 1975-07-08 Celanese Corp Production of alkyl esters of unsaturated monocarboxylic acids
US3951756A (en) * 1974-11-08 1976-04-20 Celanese Corporation Purification of alkyl esters
US4490553A (en) * 1980-08-29 1984-12-25 Celanese Corporation Process for production of ethyl acrylate
FR2492369A1 (fr) * 1980-10-21 1982-04-23 Celanese Corp Procede de production d'acrylate d'ethyle

Also Published As

Publication number Publication date
ES2022623B3 (es) 1991-12-01
CA1307795C (en) 1992-09-22
JP2602696B2 (ja) 1997-04-23
EP0299743A1 (en) 1989-01-18
JPS6438046A (en) 1989-02-08
AU602779B2 (en) 1990-10-25
AU1903388A (en) 1989-01-19
GR3002122T3 (en) 1992-12-30
DD274209A5 (de) 1989-12-13
BR8803496A (pt) 1989-01-31
EP0299743B1 (en) 1991-06-12
US5145989A (en) 1992-09-08
DE3863244D1 (de) 1991-07-18
ATE64367T1 (de) 1991-06-15
CN1019970C (zh) 1993-03-03
CN1030909A (zh) 1989-02-08

Similar Documents

Publication Publication Date Title
ATE65491T1 (de) Verfahren zur herstellung von hochreinem 4,6diamino-1,3-benzoldiol.
PT88554A (pt) High yield method for preparation of dialkil esters of polyhaloaromatic acids
PT69760A (en) Process for recovery of acrylic acid with recycle quench
MX169580B (es) Metodo mejorado para la produccion de acrilato de etilo
ATE212973T1 (de) Verfahren zum herstellen von zimtsäureestern
DE3883973D1 (de) 1-2-dehydrierung von steroid-21-estern mit a. simplex.
ES2019851T3 (es) Procedimiento mejorado para la produccion de esteres carbonicos.
MX166774B (es) Metodo mejorado para producir acrilato de etilo
ATE35131T1 (de) Verfahren zur herstellung von (meth)acrylsaeureestern und deren verwendung.
ATE60092T1 (de) Verfahren zur herstellung von kaliumnitrat.
DE3473438D1 (en) Process for the production of alpha, beta-ethylenically unsaturated esters
ATE21117T1 (de) Gaerungsverfahren zur herstellung von alphaisopropylapfels|ure.
DE69321767D1 (de) Verfahren zur Herstellung von N-Alkyl oder N-Cycloalkyl-2-Benzolthiazolesulfenimiden
PT94127A (pt) Processo para a producao de 2-oxindol-1-carboxamidas
ATE63536T1 (de) Verfahren zur herstellung von carbonsaeurechloriden.
DE3578566D1 (de) Verfahren zur herstellung von 3-cyclohexen-1-carboxaldehyd.
ATE128126T1 (de) Verfahren zur herstellung von 2- thiocyanatomethylthiobenzthiazol.
ES2019062B3 (es) Procedimiento de purificacion de un ester del acido p-metoxicinamico.
JPS5559156A (en) Recovery of organic acid as by-product
ATE41766T1 (de) Verfahren zur herstellung von monochlorhydrochinonen.
BR7800529A (pt) Processo para a recuperacao de epsilon-caprolactama de uma mistura de reacao de epsilon-caprolactama e acido sulfurico
ATE56955T1 (de) Verfahren fuer (1h>-isoindolin-1-on-3-carbonsaeure.
JPS6419052A (en) Production of l-methylosin
BR8008331A (pt) Processo de recuperacao de acido acrilico usando polianidridos
ATE1780T1 (de) Verfahren zur herstellung von beta-(5-nitro-2furyl)-acrolein.