MD4364C1 - (+)-3-Carene heterogeneous epoxidation catalyst - Google Patents
(+)-3-Carene heterogeneous epoxidation catalystInfo
- Publication number
- MD4364C1 MD4364C1 MDA20150016A MD20150016A MD4364C1 MD 4364 C1 MD4364 C1 MD 4364C1 MD A20150016 A MDA20150016 A MD A20150016A MD 20150016 A MD20150016 A MD 20150016A MD 4364 C1 MD4364 C1 MD 4364C1
- Authority
- MD
- Moldova
- Prior art keywords
- carene
- epoxidation catalyst
- heterogeneous epoxidation
- heterogeneous
- catalyst
- Prior art date
Links
Landscapes
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
The invention relates to the field of organic chemistry, in particular to a (+)-3-carene heterogeneous epoxidation catalyst.According to the invention, the use of aluminum oxide is claimed in the form of nanosized particles of 2…4 nm as a (+)-3-carene heterogeneous epoxidation catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MDA20150016A MD4364C1 (en) | 2015-02-17 | 2015-02-17 | (+)-3-Carene heterogeneous epoxidation catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MDA20150016A MD4364C1 (en) | 2015-02-17 | 2015-02-17 | (+)-3-Carene heterogeneous epoxidation catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
MD4364B1 MD4364B1 (en) | 2015-08-31 |
MD4364C1 true MD4364C1 (en) | 2016-03-31 |
Family
ID=54064855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MDA20150016A MD4364C1 (en) | 2015-02-17 | 2015-02-17 | (+)-3-Carene heterogeneous epoxidation catalyst |
Country Status (1)
Country | Link |
---|---|
MD (1) | MD4364C1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2322442C2 (en) * | 2002-05-02 | 2008-04-20 | Дегусса Аг | Olefin epoxidation process |
RU2400465C1 (en) * | 2009-04-29 | 2010-09-27 | Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) (статус государственного учреждения) | Method for synthesis of 3,4-epoxycarane from 3-carane with simultaneous production of 3-caren-5-one and 3-carene-2,5-dione |
-
2015
- 2015-02-17 MD MDA20150016A patent/MD4364C1/en not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2322442C2 (en) * | 2002-05-02 | 2008-04-20 | Дегусса Аг | Olefin epoxidation process |
RU2400465C1 (en) * | 2009-04-29 | 2010-09-27 | Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) (статус государственного учреждения) | Method for synthesis of 3,4-epoxycarane from 3-carane with simultaneous production of 3-caren-5-one and 3-carene-2,5-dione |
Non-Patent Citations (8)
Title |
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Buffon R., Schuchardt U. Heterogenization of alkene epoxidation catalysts. Journal of the Brazilian Chemical Society, 2003, vol. 14, nr. 3, p. 347-353 (regăsit în Internet la 2015.05.20 URL:<http://www.scielo.br/scielo.php?pid=S0103-50532003000300002&script=sci_arttext>) * |
Burke S. D., Danheiser R.L. Handbook of reagents for organic synthesis, oxidizing and reducing agents. Wiley, 1999, p. 84-89 * |
Juliana M. de S. e Silva, Vinhado F.S., Mandelli D., Schuchardt U., Rinaldi R. The chemical reactivity of some terpenes investigated by alumina catalyzed epoxidation with hydrogen peroxide and by DFT calculations. Journal of Molecular Catalysis A: Chemical, 2006, vol. 252, nr. 1-2, p. 186-193 (regăsit în Internet la 2015.05.20 URL:<http://www.sciencedirect.com/science/article/pii/S1381116906005747>) * |
Mandelli D., Michiel C.A. van Vliet, Sheldon R.A., Schuchardt V. Alumina-catalyzed alkene epoxidation with hydrogen peroxide. Applied Catalysis A: General, 2001, vol. 219, p. 209-213 (regăsit în Internet la 2015.05.20 URL:< <http://www.researchgate.net/profile/Roger_Sheldon/publication/244107460_Alumina-catalyzed_alkene_epoxidation_with_hydrogen_peroxide/links/544cde950cf2d6347f4540c2.pdf>) * |
Martins R.R.L., Neves M.G.P., Silvestre A.J.D., Simoes M.M.Q., Silva A.M.S., Tome A.C., Cavaleiro J.A.S., Tagliatesta P., Crestini C. Oxidation of unsaturated monoterpenes with hydrogen peroxide catalysed by manganese(III) porphyrin complexes. Journal of Molecular Catalysis A: Chemical, 2001, vol. 172, p. 33-42 * |
Padwa A., Shaun Murphreeb S. Epoxides and aziridines - a mini review. Arkivoc (Archive for Organic Chemistry), 2006, p. 6-33 * |
Rajan V. P., Bannore S.N., Subbarao H.N., Dev S. Ligand effect in epoxidations by hydroperoxides using molybdenum catalyst: epoxidation of 3-carene. Tetrahedron, 1984, vol. 40, nr. 6, p. 983-990 * |
Van Vliet M.C., Mandelli D., Arends I.W., Schuchardt U., Sheldon R.A. Alumina: a cheap, active and selective catalyst for epoxidations with (aqueous) hydrogen peroxide. Green Chemistry, 2001, vol. 3, nr. 5, p. 243-246 (regăsit în Internet la 2015.05.20 URL:<http://pubs.rsc.org/en/content/articlelanding/2001/gc/b103952k#!divAbstract>) * |
Also Published As
Publication number | Publication date |
---|---|
MD4364B1 (en) | 2015-08-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG4A | Patent for invention issued | ||
KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
MM4A | Patent for invention definitely lapsed due to non-payment of fees |