MD4364C1 - (+)-3-Carene heterogeneous epoxidation catalyst - Google Patents

(+)-3-Carene heterogeneous epoxidation catalyst

Info

Publication number
MD4364C1
MD4364C1 MDA20150016A MD20150016A MD4364C1 MD 4364 C1 MD4364 C1 MD 4364C1 MD A20150016 A MDA20150016 A MD A20150016A MD 20150016 A MD20150016 A MD 20150016A MD 4364 C1 MD4364 C1 MD 4364C1
Authority
MD
Moldova
Prior art keywords
carene
epoxidation catalyst
heterogeneous epoxidation
heterogeneous
catalyst
Prior art date
Application number
MDA20150016A
Other languages
Romanian (ro)
Russian (ru)
Other versions
MD4364B1 (en
Inventor
Флюр МАКАЕВ
Сергей КУРЛАТ
Людмила ЛОГИНА
Original Assignee
Институт Химии Академии Наук Молдовы
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Институт Химии Академии Наук Молдовы filed Critical Институт Химии Академии Наук Молдовы
Priority to MDA20150016A priority Critical patent/MD4364C1/en
Publication of MD4364B1 publication Critical patent/MD4364B1/en
Publication of MD4364C1 publication Critical patent/MD4364C1/en

Links

Abstract

The invention relates to the field of organic chemistry, in particular to a (+)-3-carene heterogeneous epoxidation catalyst.According to the invention, the use of aluminum oxide is claimed in the form of nanosized particles of 2…4 nm as a (+)-3-carene heterogeneous epoxidation catalyst.
MDA20150016A 2015-02-17 2015-02-17 (+)-3-Carene heterogeneous epoxidation catalyst MD4364C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MDA20150016A MD4364C1 (en) 2015-02-17 2015-02-17 (+)-3-Carene heterogeneous epoxidation catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MDA20150016A MD4364C1 (en) 2015-02-17 2015-02-17 (+)-3-Carene heterogeneous epoxidation catalyst

Publications (2)

Publication Number Publication Date
MD4364B1 MD4364B1 (en) 2015-08-31
MD4364C1 true MD4364C1 (en) 2016-03-31

Family

ID=54064855

Family Applications (1)

Application Number Title Priority Date Filing Date
MDA20150016A MD4364C1 (en) 2015-02-17 2015-02-17 (+)-3-Carene heterogeneous epoxidation catalyst

Country Status (1)

Country Link
MD (1) MD4364C1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2322442C2 (en) * 2002-05-02 2008-04-20 Дегусса Аг Olefin epoxidation process
RU2400465C1 (en) * 2009-04-29 2010-09-27 Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) (статус государственного учреждения) Method for synthesis of 3,4-epoxycarane from 3-carane with simultaneous production of 3-caren-5-one and 3-carene-2,5-dione

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2322442C2 (en) * 2002-05-02 2008-04-20 Дегусса Аг Olefin epoxidation process
RU2400465C1 (en) * 2009-04-29 2010-09-27 Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) (статус государственного учреждения) Method for synthesis of 3,4-epoxycarane from 3-carane with simultaneous production of 3-caren-5-one and 3-carene-2,5-dione

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
Buffon R., Schuchardt U. Heterogenization of alkene epoxidation catalysts. Journal of the Brazilian Chemical Society, 2003, vol. 14, nr. 3, p. 347-353 (regăsit în Internet la 2015.05.20 URL:<http://www.scielo.br/scielo.php?pid=S0103-50532003000300002&script=sci_arttext>) *
Burke S. D., Danheiser R.L. Handbook of reagents for organic synthesis, oxidizing and reducing agents. Wiley, 1999, p. 84-89 *
Juliana M. de S. e Silva, Vinhado F.S., Mandelli D., Schuchardt U., Rinaldi R. The chemical reactivity of some terpenes investigated by alumina catalyzed epoxidation with hydrogen peroxide and by DFT calculations. Journal of Molecular Catalysis A: Chemical, 2006, vol. 252, nr. 1-2, p. 186-193 (regăsit în Internet la 2015.05.20 URL:<http://www.sciencedirect.com/science/article/pii/S1381116906005747>) *
Mandelli D., Michiel C.A. van Vliet, Sheldon R.A., Schuchardt V. Alumina-catalyzed alkene epoxidation with hydrogen peroxide. Applied Catalysis A: General, 2001, vol. 219, p. 209-213 (regăsit în Internet la 2015.05.20 URL:< <http://www.researchgate.net/profile/Roger_Sheldon/publication/244107460_Alumina-catalyzed_alkene_epoxidation_with_hydrogen_peroxide/links/544cde950cf2d6347f4540c2.pdf>) *
Martins R.R.L., Neves M.G.P., Silvestre A.J.D., Simoes M.M.Q., Silva A.M.S., Tome A.C., Cavaleiro J.A.S., Tagliatesta P., Crestini C. Oxidation of unsaturated monoterpenes with hydrogen peroxide catalysed by manganese(III) porphyrin complexes. Journal of Molecular Catalysis A: Chemical, 2001, vol. 172, p. 33-42 *
Padwa A., Shaun Murphreeb S. Epoxides and aziridines - a mini review. Arkivoc (Archive for Organic Chemistry), 2006, p. 6-33 *
Rajan V. P., Bannore S.N., Subbarao H.N., Dev S. Ligand effect in epoxidations by hydroperoxides using molybdenum catalyst: epoxidation of 3-carene. Tetrahedron, 1984, vol. 40, nr. 6, p. 983-990 *
Van Vliet M.C., Mandelli D., Arends I.W., Schuchardt U., Sheldon R.A. Alumina: a cheap, active and selective catalyst for epoxidations with (aqueous) hydrogen peroxide. Green Chemistry, 2001, vol. 3, nr. 5, p. 243-246 (regăsit în Internet la 2015.05.20 URL:<http://pubs.rsc.org/en/content/articlelanding/2001/gc/b103952k#!divAbstract>) *

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Publication number Publication date
MD4364B1 (en) 2015-08-31

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Legal Events

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FG4A Patent for invention issued
KA4A Patent for invention lapsed due to non-payment of fees (with right of restoration)
MM4A Patent for invention definitely lapsed due to non-payment of fees