LU501553B1 - Gas-driven 3d printing material, preparation method and application thereof - Google Patents
Gas-driven 3d printing material, preparation method and application thereof Download PDFInfo
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- LU501553B1 LU501553B1 LU501553A LU501553A LU501553B1 LU 501553 B1 LU501553 B1 LU 501553B1 LU 501553 A LU501553 A LU 501553A LU 501553 A LU501553 A LU 501553A LU 501553 B1 LU501553 B1 LU 501553B1
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- printing
- gas
- driven
- carbonized
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/001—Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
- B29C64/307—Handling of material to be used in additive manufacturing
- B29C64/314—Preparation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
- B29C64/364—Conditioning of environment
- B29C64/371—Conditioning of environment using an environment other than air, e.g. inert gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00181—Mixtures specially adapted for three-dimensional printing (3DP), stereo-lithography or prototyping
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Producing Shaped Articles From Materials (AREA)
Abstract
The disclosure provides a gas-driven 3D printing material, a preparation method and an application thereof. The gas-driven 3D printing material comprises the following components in parts by weight: 100 parts of a carbonized gelling material, 10-15 parts of a carbonized reinforcement phase, 1-2 parts of a binding agent and 28-38 parts of water. In the disclosure, the carbonized gelling material is used as a main material, together with the carbonized reinforcement phase, the binding agent and the water, to prepare the 3D printing material, so that a printed product has excellent volume stability, mechanical property, durability and high printing quality. The 3D printing material is mainly prepared by the carbonized gelling material, so that carbonization and hardening operations can be performed simultaneously in a printing process to achieve synchronous printing process and hardening process, greatly reduce molding time and further significantly improve printing efficiency.
Description
BL-5432 GAS-DRIVEN 3D PRINTING MATERIAL, PREPARATION METHOD AND LU501553
[01] The disclosure relates to the technical field of 3D printing, and in particular, to a gas- driven 3D printing material, a preparation method and an application thereof.
[02] In recent years, 3D printing technology is rapidly developed as an innovative technology, and has been widely applied due to continually improved printing accuracy and printing efficiency. Theoretically, a layer-by-layer superposition method is used for the technology, the process is not influenced by entity prototype complexity and is applicable to the rapid manufacturing of various parts with complex structures, so that 3D printing technology is more and more widely concerned at home and abroad. At present, by molding technology principles, the 3D printing technology can be divided into SLA (Stereo Lithography Appearance), SLS (Selective Laser Sintering), DIW (Direct Ink Writing), FDM (Fused Deposition Modeling), LOM (Laminated Object Manufacturing), etc. Therein, the DIW technology has been widely applied due to wider material applicability and simple operability thereof, and especially plays an important role in the printing of such materials as ceramics, cements and plasters which mainly rely on slurry molding.
[03] At present, as mentioned above, 3D printing materials for the DIW technology mainly include ceramic-based, cement-based and plaster-based materials, etc. For the ceramic-based 3D printing technology, relatively complex after-treatment processes are needed after blank extrusion molding, and such after-treatment processes as sintering process may severely influence printing accuracy thereof. For the cement-based and plaster-based 3D printing materials, the coagulation time thereof needs to be controlled to meet printing requirements; shrinkage behaviors of the two materials in a hydration and hardening process may significantly influence quality of a printed product. Moreover, the three printing materials cannot achieve the printing process and the hardening process synchronously, thus failing to play the technical advantage of the rapid molding of the 3D printing technology.
[04] In view of this, the disclosure aims to propose a gas-driven 3D printing material to solve the problems of poor printing quality and low printing efficiency of existing 3D printing materials.
[05] To achieve this objective, the technical solutions of the disclosure are as follows:
[06] A gas-driven 3D printing material comprises the following components in parts by weight: 100 parts of a carbonized gelling material, 10-15 parts of a carbonized reinforcement phase, 1-2 parts of a binding agent and 28-38 parts of water.
[07] Optionally, the carbonized gelling material is one or more of y-dicalcium silicate, monocalcium silicate, tricalcium disilicate, steel slag powder and silicate cement mixture; the particle size of the carbonized gelling material is 2-10 pm. 1
BL-5432
[08] Optionally, when the carbonized gelling material is steel slag powder and silicate cement mixture, the gas-driven 3D printing material furthermore comprises 1-2 parts by weight LU501553 of water reducing agent.
[09] Optionally, the carbonized reinforcement phase is one or more of chitosan and amorphous silicone material.
[10] Optionally, the binding agent is one or more of polyethylene glycol, polyvinyl alcohol, waterborne polyurethane, ethylene-vinyl acetate ~~ copolymer and sodium carboxymethylcellulose.
[11] Optionally, the water reducing agent is a composite water reducing agent prepared by mixing polycarboxylate-type high-efficiency water reducing agent and sodium citrate retarder.
[12] The second objective of the disclosure is to provide a method for preparing the gas- driven 3D printing material, comprising the following steps:
[13] ball-milling the carbonized gelling material and the carbonized reinforcement phase to obtain a mixture A;
[14] dissolving the binding agent in the water to obtain a solution B;
[15] adding the mixture A into the solution B and stirring to obtain a gas-driven 3D printing material.
[16] The third objective of the disclosure is to provide an application of the gas-driven 3D printing material in 3D printing, comprising the following steps:
[17] constructing an objective printing model through 3D data modeling;
[18] slicing the objective printing model and planning a scanning line;
[19] referencing to size and printing accuracy requirements of the objective printing model slice, and matching suitable printing parameters;
[20] after removing bubbles in the gas-driven 3D printing material, filling the material into a charging barrel of a 3D printer;
[21] starting an infrared radiation heater to preheat a printing area, introducing CO» gas into the sealed printing area for air discharge, and then starting printing;
[22] after printing, carrying out carbonization and hardening treatment to obtain a printed product.
[23] Optionally, carbonization and hardening treatment temperature is 0-100°C, relative humidity is 5-100% and carbon dioxide concentration is 10-100%.
[24] Compared with the prior art, the gas-driven 3D printing material of the disclosure has the following advantages: 2
BL-5432
[25] 1. In the disclosure, the carbonized gelling material is used as a main material, together with the carbonized reinforcement phase, the binding agent and the water, to prepare the 3D LU501553 printing material. On the one hand, the carbonized gelling material can rapidly react with carbon dioxide in a proper carbonization environment to generate compact calcium carbonate hardened objects, so that a printed product has excellent volume stability, mechanical property and durability. On the other hand, the binding agent and the water reducing agent enable the 3D printing material of the disclosure to have certain stability, so that the material can keep the form thereof after being extruded from a nozzle and before being carbonized to prevent collapse and deformation and further improve printing quality. Moreover, the 3D printing material is mainly prepared by the carbonized gelling material, so that carbonization and hardening operations can be performed simultaneously in a printing process to achieve synchronous printing process and hardening process, greatly reduce molding time and further significantly improve printing efficiency.
[26] 2. The disclosure utilizes a slurry DIW 3D printing technology, with simple printing process operations. The gas-driven 3D printing material has good mobility and stability, thus the disclosure has a relatively high printing accuracy.
[27] It should be noted that in case of no conflicts, the embodiments and the characteristics in the embodiments can be mutually combined in the disclosure.
[28] The disclosure will be described in detail with reference to the embodiments.
Embodiment 1
[29] A gas-driven 3D printing material is specifically prepared by the following method:
[30] ball-milling 100 g of y-dicalcium silicate and 11 g of an amorphous silicone material for 0.5 h, and uniformly mixing them to obtain a mixture A;
[31] dissolving 0.2 g of polyvinyl alcohol and 2 g of sodium carboxymethylcellulose in 38 g of water, and stirring the mixture uniformly to obtain a solution B;
[32] adding the mixture A into the solution B and stirring for 2-3 min till the slurry is uniform, to obtain a gas-driven 3D printing material.
[33] An application of the gas-driven 3D printing material in 3D printing specifically comprises the following steps:
[34] 1) data model construction: constructing an objective printing model through 3D data modeling; slicing the objective printing model and planning a scanning line; referencing to size and printing accuracy requirements of the objective printing model slice, and matching suitable printing parameters;
[35] 2) placing the gas-driven 3D printing material in a container to remove bubbles by a vibrator, and filling the material into a charging barrel of a 3D printer;
[36] 3) starting an infrared radiation heater to preheat a printing area, introducing CO; gas 3
BL-5432 with a concentration of 100% into the sealed printing area for air discharge, continuously introducing CO, gas with a concentration of 100%, and then starting printing; after completely LUS01553 printing a sample, continuously introducing CO» gas with a concentration of 100%, keeping carbonization for 1-2 h under the conditions of temperature of 40°C and relative humidity of 60%, and fully carbonizing and hardening the sample to obtain a printed product, wherein the heater is in an on-state in the whole printing and carbonization process in step 3) to keep the temperature at 40°C till carbonization completion. Embodiment 2
[37] A gas-driven 3d printing material is specifically prepared by the following method:
[38] ball-milling 179.4 g of steel slag powder, 44.8 silicate cement and 28.5 g of an amorphous silicone material for 0.5 h, and uniformly mixing them to obtain a mixture A;
[39] dissolving 3.54 g of polyvinyl alcohol, 5.05 g of sodium carboxymethylcellulose and
10.11 g of water reducing agent in 70.7g of water, and stirring the mixture uniformly to obtain a solution B, wherein the water reducing agent is a composite water reducing agent prepared by mixing polycarboxylate-type high-efficiency water reducing agent and sodium citrate retarder.
[40] adding the mixture A into the solution B and stirring for 2-3 min till the slurry is uniform, to obtain a gas-driven 3D printing material.
[41] An application of the gas-driven 3D printing material in 3D printing specifically comprises the following steps:
[42] 1) data model construction: constructing an objective printing model through 3D data modeling; slicing the objective printing model and planning a scanning line; referencing to size and printing accuracy requirements of the objective printing model slice, and matching suitable printing parameters;
[43] 2) placing the gas-driven 3D printing material in a container to remove bubbles by a vibrator, and filling the material into a charging barrel of a 3D printer;
[44] 3) starting an infrared radiation heater to preheat a printing area, introducing CO; gas with a concentration of 100% into the sealed printing area for air discharge, continuously introducing CO; gas with a concentration of 100%, and then starting printing; after completely printing a sample, continuously introducing CO; gas with a concentration of 100%, keeping carbonization for 1-2 h under the conditions of temperature of 40°C and relative humidity of 60%, and fully carbonizing and hardening the sample to obtain a printed product, wherein the heater is in an on-state in the whole printing and carbonization process in step 3) to keep the temperature at 40°C till carbonization completion.
[45] The above embodiments are only preferred embodiments of the disclosure, but the disclosure should not be limited thereby; any modification, equivalent replacement, improvement, etc., made by those skilled in the art within the spirit and principle of the disclosure shall be included in the protection scope of the disclosure.
4
Claims (6)
1. A gas-driven 3D printing material, comprising the following components in parts by weight: 100 parts of a carbonized gelling material, 10-15 parts of a carbonized reinforcement phase, 1-2 parts of a binding agent and 28-38 parts of water.
2. The gas-driven 3D printing material according to claim 1, wherein the carbonized gelling material is one or more of y-dicalcium silicate, monocalcium silicate, tricalcium disilicate, steel slag powder and silicate cement mixture; the particle size of the carbonized gelling material 1s 2-10 pm.
3. The gas-driven 3D printing material according to claim 2, wherein when the carbonized gelling material is steel slag powder and silicate cement mixture, the gas-driven 3D printing material furthermore comprises 1-2 parts by weight of water reducing agent.
4. A method for preparing the gas-driven 3D printing material according to any one of claims 1-3, comprising: ball-milling the carbonized gelling material and the carbonized reinforcement phase to obtain a mixture A; dissolving the binding agent in water to obtain a solution B; adding the mixture A into the solution B and stirring to obtain a gas-driven 3D printing material.
5. An application of the gas-driven 3D printing material in 3D printing according to any one of claims 1-3, comprising: constructing an objective printing model through 3D data modeling; slicing the objective printing model and planning a scanning line; referencing to size and printing accuracy requirements of the objective printing model slice, and matching suitable printing parameters; after removing bubbles in the gas-driven 3D printing material, filling the material into a charging barrel of a 3D printer; starting an infrared radiation heater to preheat a printing area, introducing CO; gas into the sealed printing area for air discharge, and then starting printing; after printing, carrying out carbonization and hardening treatment to obtain a printed product.
6. The application of the gas-driven 3D printing material in 3D printing according to claim 5, wherein carbonization and hardening treatment temperature is 0-100°C, relative humidity is 5-100% and carbon dioxide concentration is 10-100%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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LU501553A LU501553B1 (en) | 2022-02-25 | 2022-02-25 | Gas-driven 3d printing material, preparation method and application thereof |
Applications Claiming Priority (1)
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LU501553A LU501553B1 (en) | 2022-02-25 | 2022-02-25 | Gas-driven 3d printing material, preparation method and application thereof |
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LU501553B1 true LU501553B1 (en) | 2022-08-25 |
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LU501553A LU501553B1 (en) | 2022-02-25 | 2022-02-25 | Gas-driven 3d printing material, preparation method and application thereof |
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2022
- 2022-02-25 LU LU501553A patent/LU501553B1/en active IP Right Grant
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Effective date: 20220825 |