KR970701757A - Flame-retardant Regenerated Polyester Composition (FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS) - Google Patents

Flame-retardant Regenerated Polyester Composition (FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS)

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Publication number
KR970701757A
KR970701757A KR1019960705013A KR19960705013A KR970701757A KR 970701757 A KR970701757 A KR 970701757A KR 1019960705013 A KR1019960705013 A KR 1019960705013A KR 19960705013 A KR19960705013 A KR 19960705013A KR 970701757 A KR970701757 A KR 970701757A
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KR
South Korea
Prior art keywords
phosphinic acid
carboxyethyl
carboxy
polyester
phenyl
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KR1019960705013A
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Korean (ko)
Inventor
자웨드 애스라
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원본미기재
몬산토 캄파니
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Publication of KR970701757A publication Critical patent/KR970701757A/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C08G63/6924Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6926Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313Phosphinic compounds, e.g. R2=P(:O)OR'
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

본 발명은 폴리에틸렌 테레프탈레이트와 같은 재생 폴리에스테르 및 방염 유효량의 카르복시-포스핀산의 생성물을 포함하는 방염성 선형 폴리에스테르, 이 폴리에스테르의 제조방법 및 이 폴리에스테르로 제조된 제품에 관한 것이다.(FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS)The present invention relates to a flame retardant linear polyester comprising a regenerated polyester such as polyethylene terephthalate and a product of a flame retardant effective amount of carboxy-phosphinic acid, a process for preparing the polyester, and a product made of the polyester. RETARDANT RECYCLED POLYESTER COMPOSITIONS)

Description

방염성 재생 폴리에스테르 조성물(FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS)Flame-retardant Regenerated Polyester Composition (FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS)

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (22)

재생 폴리에스테르와 방염 유효량의 카르복시-포스핀산의 생성물을 포함하는 것을 특징으로 하는 방염성 선형 폴리에스테르.A flame retardant linear polyester comprising a product of a regenerated polyester and a flame retardant effective amount of carboxy-phosphinic acid. 제1항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트 또는 재생 폴리부틸렌 테레프탈레이트인 것을 특징으로 하는 방염성 선형 폴리에스테르.The flame retardant linear polyester of claim 1 wherein the regenerated polyester is regenerated polyethylene terephthalate or regenerated polybutylene terephthalate. 제2항에 있어서, 카르복시-포스핀산 모노머는 폴리에스테르 전체 중량에 대하여 약 0.1∼10중량%로 존재하는 것을 특징으로 하는 방염성 선형 폴리에스테르.The flame retardant linear polyester of claim 2 wherein the carboxy-phosphinic acid monomer is present at about 0.1-10% by weight based on the total weight of the polyester. 제3항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산, 2-카르복시에틸(메틸)포스핀산, 2-카르복시에틸(페닐)포스핀산의 시클릭 무수물 및 2-카르복시에틸(메틸)포스핀산의 시클로 무수물로 이루어진 군으로부터 선택되는 것을 특징으로 하는 방염성 선형 폴리에스테르.4. The carboxy-phosphinic acid monomer of claim 3 wherein the carboxy-phosphinic acid monomers are 2-carboxyethyl (phenyl) phosphinic acid, 2-carboxyethyl (methyl) phosphinic acid, cyclic anhydrides and 2-carboxyethyl of 2-carboxyethyl (phenyl) phosphinic acid. Flame-retardant linear polyester selected from the group consisting of cyclo anhydride of (methyl) phosphinic acid. 제4항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산인 것을 특징으로 하는 방염성 선형 폴리에스테르.The flame retardant linear polyester of claim 4 wherein the carboxy-phosphinic acid monomer is 2-carboxyethyl (phenyl) phosphinic acid. 제4항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(메틸)포스핀산인 것을 특징으로 하는 방염성 선형 폴리에스테르.The flame retardant linear polyester of claim 4 wherein the carboxy-phosphinic acid monomer is 2-carboxyethyl (methyl) phosphinic acid. 약 250∼293℃의 온도에서 촉매의 존재하에 재생 폴리에스테르 및 상기 폴리에스테르 전체 중량에 대하여 약 0.1∼10중량%로 존재하는 방염성 카르복시-포스핀산 모노머로 이루어진 혼합물을 축합시키는 단계를 포함하는 것을 특징으로 하는 방염성 선형 폴리에스테르의 제조방법.Condensing a mixture of the regenerated polyester in the presence of a catalyst at a temperature of about 250 to 293 ° C. and a flame retardant carboxy-phosphinic acid monomer present at about 0.1 to 10% by weight relative to the total weight of the polyester. The manufacturing method of flame-proof linear polyester to be. 제7항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트 또는 재생 폴리부틸렌 테레프탈레이트인 것을 특징으로 하는 제조방법.8. A process according to claim 7, wherein the recycled polyester is recycled polyethylene terephthalate or recycled polybutylene terephthalate. 제7항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산, 2-카르복시에틸(메틸)포스핀산, 2-카르복시에틸(페닐) 포스핀산의 시클릭 무수물 및 2-카르복시에틸(메틸) 포스핀산의 시클릭 무수물로 이루어진 군으로부터 선택되는 것을 특징으로 하는 제조방법.8. The carboxy-phosphinic acid monomer of claim 7, wherein the carboxy-phosphinic acid monomers are 2-carboxyethyl (phenyl) phosphinic acid, 2-carboxyethyl (methyl) phosphinic acid, cyclic anhydride and 2-carboxyethyl of 2-carboxyethyl (phenyl) phosphinic acid. A manufacturing method, characterized in that it is selected from the group consisting of cyclic anhydrides of (methyl) phosphinic acid. 제9항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산인 것을 특징으로 하는 제조방법.10. The process according to claim 9, wherein the carboxy-phosphinic acid monomer is 2-carboxyethyl (phenyl) phosphinic acid. 재생 폴리에스테르와 방염 유효량의 카르복시-포스핀산의 생성물을 포함하는 방염성 선형 폴리에스테르로부터 제조된 것임을 특징으로 하는 성형품.A molded article characterized in that it is made from a flame retardant linear polyester comprising a regenerated polyester and a product of a flame retardant effective amount of carboxy-phosphinic acid. 제11항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트 또는 재생 폴리부틸렌 테레프탈레이트인 것을 특징으로 하는 성형품.12. The molded article according to claim 11, wherein the recycled polyester is recycled polyethylene terephthalate or recycled polybutylene terephthalate. 제12항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트인 것을 특징으로 하는 성형품.13. The molded article of claim 12, wherein the recycled polyester is recycled polyethylene terephthalate. 제11항에 있어서, 카르복시-포스핀산은 폴리에스테르 전체중량에 대하여 약 0.1∼10중량%로 존재하는 것을 특징으로 하는 성형품.12. The molded article of claim 11, wherein the carboxy-phosphinic acid is present at about 0.1-10% by weight based on the total weight of the polyester. 제14항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산, 2-카르복시에틸(메틸)포스핀산, 2-카르복시에틸(페닐)포스핀산의 시클릭 무수물 및 2-카르복시에틸(메틸)포스핀산의 시클릭 무수물로 이루어진 군으로부터 선택되는 것을 특징으로 하는 성형품.15. The carboxy-phosphinic acid monomer of claim 14, wherein the carboxy-phosphinic acid monomers are 2-carboxyethyl (phenyl) phosphinic acid, 2-carboxyethyl (methyl) phosphinic acid, cyclic anhydride and 2-carboxyethyl of 2-carboxyethyl (phenyl) phosphinic acid. A molded article, characterized in that it is selected from the group consisting of cyclic anhydrides of (methyl) phosphinic acid. 제15항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산인 것을 특징으로 하는 성형품.16. The molded article of claim 15, wherein the carboxy-phosphinic acid monomer is 2-carboxyethyl (phenyl) phosphinic acid. 재생 폴리에스테르와 방염 유효량의 카르복시-포스핀산의 생성물을 포함하는 방염성 선형 폴리에스테르로부터 제조된 것을 특징으로 하는 화이버.A fiber characterized in that it is made from a flame retardant linear polyester comprising a product of a regenerated polyester and a flame retardant effective amount of a carboxy-phosphinic acid. 제17항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트 또는 재생 폴리부틸렌 테레프탈레이트인 것을 특징으로 하는 화이버.18. The fiber of claim 17 wherein the regenerated polyester is regenerated polyethylene terephthalate or regenerated polybutylene terephthalate. 제18항에 있어서, 재생 폴리에스테르는 재생 폴리에틸렌 테레프탈레이트인 것을 특징으로 하는 화이버.19. The fiber of claim 18 wherein the recycled polyester is recycled polyethylene terephthalate. 제17항에 있어서, 카르복시-포스핀산은 폴리에스테르 전체중량에 대하여 약 0.1∼10중량%로 존재하는 것을 특징으로 하는 화이버.18. The fiber of claim 17 wherein the carboxy-phosphinic acid is present at about 0.1 to 10 weight percent based on the total weight of the polyester. 제20항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산, 2-카르복시에틸(메틸)포스핀산, 2-카르복시에틸(페닐)포스핀산의 시클릭 무수물 및 2-카르복시에틸(메틸)포스핀산의 시클릭 무수물로 이루어진 군으로부터 선택되는 것을 특징으로 하는 화이버.21. The carboxy-phosphinic acid monomer of claim 20 wherein the carboxy-phosphinic acid monomers are 2-carboxyethyl (phenyl) phosphinic acid, 2-carboxyethyl (methyl) phosphinic acid, cyclic anhydride and 2-carboxyethyl of 2-carboxyethyl (phenyl) phosphinic acid. Fibers selected from the group consisting of cyclic anhydrides of (methyl) phosphinic acid. 제21항에 있어서, 카르복시-포스핀산 모노머는 2-카르복시에틸(페닐)포스핀산인 것을 특징으로 하는 화이버.23. The fiber of claim 21 wherein the carboxy-phosphinic acid monomer is 2-carboxyethyl (phenyl) phosphinic acid. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960705013A 1994-03-11 1995-03-03 Flame-retardant Regenerated Polyester Composition (FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS) KR970701757A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US20993194A 1994-03-11 1994-03-11
US209,931 1994-03-11
PCT/US1995/002651 WO1995024445A2 (en) 1994-03-11 1995-03-03 Flame-retardant recycled polyester compositions

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KR970701757A true KR970701757A (en) 1997-04-12

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Application Number Title Priority Date Filing Date
KR1019960705013A KR970701757A (en) 1994-03-11 1995-03-03 Flame-retardant Regenerated Polyester Composition (FLAME-RETARDANT RECYCLED POLYESTER COMPOSITIONS)

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Country Link
EP (1) EP0754202A1 (en)
JP (1) JPH09510245A (en)
KR (1) KR970701757A (en)
CA (1) CA2183662A1 (en)
MX (1) MX9604038A (en)
TW (1) TW333542B (en)
WO (1) WO1995024445A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185792A (en) * 1996-03-26 1998-06-24 埃姆斯-英维塔公司 Process for direct chemical modification of (co) polyesters
DE102006012881A1 (en) * 2006-03-21 2007-09-27 Clariant International Limited Phosphorus-containing mixtures, a process for their preparation and their use
DE102006012879A1 (en) * 2006-03-21 2007-09-27 Clariant International Limited Phosphorus-containing mixtures, a process for their preparation and their use
DE102006012878A1 (en) 2006-03-21 2007-09-27 Clariant International Limited Phosphorus-containing mixtures, a process for their preparation and their use

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2454189C3 (en) * 1974-11-15 1980-08-14 Hoechst Ag, 6000 Frankfurt Process for the production of flame-retardant linear polyesters
JPS60248646A (en) * 1984-05-25 1985-12-09 Toray Ind Inc Depolymerization of waste polyester
IT1252236B (en) * 1991-12-18 1995-06-05 Enichem Sintesi LINEAR COPOLYESTER CONTAINING PHOSPHORUS, PREPARATION PROCEDURE AND USE AS AN ANTI-FLAME ADDITIVE

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Publication number Publication date
WO1995024445A3 (en) 1995-11-16
WO1995024445A2 (en) 1995-09-14
EP0754202A1 (en) 1997-01-22
MX9604038A (en) 1997-09-30
JPH09510245A (en) 1997-10-14
CA2183662A1 (en) 1995-09-14
TW333542B (en) 1998-06-11

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