KR970701000A - Adjuvant Compositions - Google Patents

Adjuvant Compositions

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Publication number
KR970701000A
KR970701000A KR1019960704640A KR19960704640A KR970701000A KR 970701000 A KR970701000 A KR 970701000A KR 1019960704640 A KR1019960704640 A KR 1019960704640A KR 19960704640 A KR19960704640 A KR 19960704640A KR 970701000 A KR970701000 A KR 970701000A
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South Korea
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group
composition
carbon atoms
alkyl
formula
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KR1019960704640A
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Korean (ko)
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디르크 호어네
루데비엑 마리아 로기어스
Original Assignee
죠나단 윈스탄리 로버츠
임페리얼 케미칼 인더스트리즈 피엘씨
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Priority claimed from GB9403469A external-priority patent/GB9403469D0/en
Priority claimed from GB9403522A external-priority patent/GB9403522D0/en
Application filed by 죠나단 윈스탄리 로버츠, 임페리얼 케미칼 인더스트리즈 피엘씨 filed Critical 죠나단 윈스탄리 로버츠
Publication of KR970701000A publication Critical patent/KR970701000A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • C09K23/018Mixtures of two or more different organic oxygen-containing compounds

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

보조제 조성물을 함유하는 계면활성제 화학식(Ⅰ) Y.A1.O.C.(HR).C.C(HR1).C.O.A.(CmH2MO)n.R2또는 화학식(Ⅱ)Y.A1.O.C.(HR).C.C(HR1).C.O.A.(CmH2mO)n.RCpH2PA.C.O.(HR1)C.C(HR)CO.A1.Y(여기서, 치환체는 정의된다)의 계면활성제 빅-디카르복실산 폴리알킬렌옥시 반 에스테르 유도체, 및1종 이상의 (b) 1종 이상의 기타 계면 활성제, (c)1종 이상의 오일 성분, 및 (d) 1종 이상의 유기 용매를 포함한다.보조제 조성물은 농화학 제형에, 특히 성장 조절제, 제초제 및(또는) 농약을 포함하는 조성물에, 또는 전형적으로 금속 부식 억제제를 포함하는 금속 가공 조성물에 사용될 수 있다.Surfactant Containing Adjuvant Composition Formula (I) YA 1 .OC (HR) .CC (HR 1 ) .COA (CmH 2M O) nR 2 or Formula (II) YA 1 .OC (HR) .CC (HR 1 ) .COA (CmH 2m O) n.RCpH 2P ACO (HR 1 ) CC (HR) CO.A 1 .Y (where substituents are defined) Big-dicarboxylic acid polyalkyleneoxy half ester Derivatives, and one or more (b) one or more other surfactants, (c) one or more oil components, and (d) one or more organic solvents. The adjuvant compositions include agrochemical formulations, in particular growth regulators, herbicides. And / or a composition comprising agrochemicals, or a metalworking composition typically comprising a metal corrosion inhibitor.

Description

보조제 조성물(Adjuvant Compositions)Adjuvant Compositions

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

(a) 하기 화학식(Ⅰ) 또는 (Ⅱ)의 계면활성제 빅-디카르복실산 폴리알킬렌욱시 반에스테르 유도체 1종 이상, 및 1종 이상의 (b) 기타 계면활성제 1종 이상, (c)오일 성분 1종 이상, 및 (d) 유기 용매 1종 이상을 함유함을 특징으로 하는 보조제 조성물:(a) at least one surfactant big-dicarboxylic acid polyalkylene oxy half ester derivative of formula (I) or (II), and at least one (b) at least one other surfactant, (c) oil An adjuvant composition comprising at least one component and (d) at least one organic solvent: Y.A1.OC.(HR).C.C(HR1).CO.A.(CmH2mO)n.R2(Ⅰ)YA 1 .OC. (HR) .CC (HR 1 ) .CO.A. (C m H 2m O) n .R 2 (I) Y.A1.OC.(HR).C.C(HR1).CO.A.(CmH2mO)n.CpH2PA.CO.(HR1)C.C(HR)CO.A1.Y (Ⅱ)YA 1 .OC. (HR) .CC (HR 1 ) .CO.A. (C m H 2m O) nC p H 2P A.CO. (HR 1 ) CC (HR) CO.A 1 .Y (II ) 상기 식에서, R 및 R1중 하나는 C6내지 C22알케닐 또는 알킬이고 나머지 하나는 수소이고: A는 -O- 또는 -NR4-이고,이때 R4는 수소 또는 C1내지C6알킬이고; n은 2 내지 100(또한 평균치이므로 정수가 아닐수 있음)이고; m은 2 또는 3(또한 폴리옥시알킬렌 쇄에 따라서 변할 수 있음)이고; R2는 수소 또는 C1내지C6알킬이고;A|1는 -O-, -O-또는 -NR4-이고,이때 R4는 수소 또는 C1내지C6알킬이고;A1이 -O-인경우Y는 양이온이고; A1이 -O- 또는 -NR4-인 경우 Y는 C1내지 C6알칼기(R|3) 또는 화학식(CmH2mO)n.R2의 기이고, 이때 m, n 및 R2는 독립적으로 상기에서 정의된 바와 같고; p는 2 또는 3이다.Wherein one of R and R 1 is C 6 to C 22 alkenyl or alkyl and the other is hydrogen: A is —O— or —NR 4 —, where R 4 is hydrogen or C 1 to C 6 alkyl ego; n is 2 to 100 (also an average and therefore may not be an integer); m is 2 or 3 (which may also vary depending on the polyoxyalkylene chain); R 2 is hydrogen or C 1 to C 6 alkyl; 1 is -O-, -O - or -NR 4 -, and wherein R 4 is hydrogen or C 1 to C 6 alkyl; The A 1 -O - Ann Wu Y is a cation; When A 1 is -O- or -NR 4- , Y is a C 1 to C 6 alkyl group (R | 3 ) or a group of the formula (C m H 2m O) nR 2 , wherein m, n and R 2 are Independently as defined above; p is 2 or 3. 제1항에 있어서, (a) 조성물 총 함량의 1내지 90중량%로 존재하는, 제1항에서 정의 된 바와 같은 빅-디카르복실산 폴리알킬렌옥시 반 에스테르 유도체 1종 이상; 및 1종 이상의 (b) 조성물 총 함량의 0 내지 99중량%로 존재하는, 기타 계면 활성제 1종 이상; (c) 조성물 총 함량의 0 내지 99중량%로 존재하는 오일 성분 1종 이상; 및(또는) (d) 조성물 총 함량의 0 내지 90중량%로 존재하는 유기 용매 1종 이상을 함유하는 보조제 조성물.2. A composition according to claim 1, comprising: (a) at least one big-dicarboxylic acid polyalkyleneoxy half ester derivative as defined in claim 1, present in 1 to 90% by weight of the total content of the composition; And at least one other surfactant present at 0-99% by weight of the total content of at least one (b) composition; (c) at least one oil component present at 0-99% by weight of the total content of the composition; And / or (d) at least one organic solvent present at 0-90% by weight of the total content of the composition. 제1항 또는 제2항에 있어서, 화학식(Ⅰ) 또는 (Ⅱ)의 화합물이 하기 화학식(Ⅰa) 또는 (Ⅱa)의 화합물 1종 이상인 조성물;The composition of claim 1 or 2, wherein the compound of formula (I) or (II) is at least one compound of formula (Ia) or (IIa); R1-CH(CO.AY)-CH2CO.AZ (Ⅰa)R 1 -CH (CO.AY) -CH 2 CO.AZ (IA) R1-CH(COA'Y)-CH2-CO.A-D-A.OC-CH2-CH(COA1Y)-R1(Ⅱa)R 1 -CH (COA'Y) -CH 2 -CO.ADA.OC-CH 2 -CH (COA 1 Y) -R 1 (IIa) 상기 식에서, Z는 화학식(CmH2mO)nR2의 기이고, 이때 n, m 및 R2는 상기 화학식(Ⅰ)에 대하여 정의된 바와 같고, n은 바람직하게는 3 내지 50이고; R2는 수소 또는 탄소수 1 내지 16의 알킬 기이고; A 및 A1은 각각 독립적으로 -O- -O1또는 -NH- 기이고; A 또는 A1이 -O-인 경우 Y는 각각 양이온(예:H+) 또는 알칼리 금속 이온이고; A 또는 A1이 -O- 또는 -NH-인 경우 Y는 각각 기 R2또는 화학식(CmH|2mO)nR2의 기이고, 이때 m 및 R2는 상기 정의된 바와 같고 기 Z와 동일 또는 상이할 수 있고; R1은 탄소수 6내지 22, 바람직하게는 13 내지 20의 알킬 또는 알케닐 기이고; D는 화학식(CmH2mO)nCpH2p-의 기이고, 이때 p는 2 또는 3이다.Wherein Z is a group of formula (C m H 2m O) n R 2 , wherein n, m and R 2 are as defined for formula (I) above, n is preferably 3 to 50; R 2 is hydrogen or an alkyl group having 1 to 16 carbon atoms; A and A 1 are each independently an —O— —O 1 or —NH— group; A or A 1 is -O -, if Y is a cation, respectively (for example: H +) or alkali metal ions, and; When A or A 1 is —O— or —NH—, Y is a group R 2 or a group of the formula (C m H | 2m O) n R 2 , where m and R 2 are as defined above and the group Z May be the same as or different from; R 1 is an alkyl or alkenyl group having 6 to 22 carbon atoms, preferably 13 to 20 carbon atoms; D is a group of the formula (C m H 2m O) n C p H 2p −, where p is 2 or 3. 제1항 내지 제3항 중의 어느 한 항에 있어서, 알카렌 설포네이트 염의 기; 폴리(아릴아릴알콕실레이트) 포스페이트 또는 설페이트 염의 기; 알카릴 포스페이트 또는 설페이트 염의 기; 직쇄 또는 측쇄 알킬- 및 알콕실화 알킬 포스페이트 또는 설페이트 염의 기; 탄소수 8 내지 24의 지방산 염의 기; 및(또는) 염 양이온이 알칼리 금속, 알칼리 토금속 및(또는) 암모늄, 지방족 암모늄 또는 알칸을 암모늄 양이온이고, 이때 지방족 또는 알칸올 부분이 탄소수 1 내지 4의 알킬인 알콕실화 카르복실화 알카릴 및 지방 알콜의 염의 기; 또는 이들의 혼합물의 계면활성제로부터 선택된 음이온계 계면활성제; 탄소수 8 내지 24, 특히 12 내지18의 알콕실화 지방 아민 염으로부터 선택된 양이온계 계면활성제; 및(또는) 하기 화학실의 비이온계 계면활성제 중 1종 이상이거나 이들을 포함하는 1종 이상의 계면활성제를 포함하는 조성물:The method according to any one of claims 1 to 3, further comprising: a group of an alkali sulfonate salt; Groups of poly (arylarylalkoxylate) phosphate or sulfate salts; Groups of alkaline phosphate or sulfate salts; Groups of straight or branched chain alkyl- and alkoxylated alkyl phosphate or sulfate salts; Groups of fatty acid salts having 8 to 24 carbon atoms; And / or alkoxylated carboxylated alkaryl and fatty, wherein the salt cation is an alkali metal, alkaline earth metal and / or ammonium, aliphatic ammonium or alkane, wherein the aliphatic or alkanol moiety is alkyl having 1 to 4 carbon atoms. Groups of salts of alcohols; Or anionic surfactants selected from surfactants thereof; Cationic surfactants selected from alkoxylated fatty amine salts having 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms; And / or at least one of the nonionic surfactants of the following chemical chambers, or comprising at least one surfactant comprising: R21.O(X)R22및(또는) R24OR25및(또는) R26-N-(-XH)|2 R 21 .O (X) R 22 and / or R 24 OR 25 and / or R 26 -N-(-XH) | 2 상기 식에서, R은 탄소수 24 이하의 알킬기 또는 알케닐기, 그의 알킬기의 탄소수 6 내지 12인 알킬페놀기, 소르비탄기, 또는 R26이 탄소수 11 내지 22의 알킬기인 화학식 R26CO의 기이고; R22는 수소, 또는 알킬기, 탄소수 2 내지 4의 카르복시알킬기, 또는 탄소수 10 내지 22의 지방산 잔기이고; X는 평균 2 내지 40개의 알킬렌 옥사이드기 또는 혼합된 알킬렌 옥사이드기를 포함하는 폴리알킬렌옥사이드기이고;R23는 소르비탄기이고, R24는 탄소수 10 내지 22의 지방산 잔기이고, R26는 탄소수 10 내지 22의 알킬 또는 알케닐기이다.Wherein R is an alkyl or alkenyl group having 24 or less carbon atoms, an alkylphenol group having 6 to 12 carbon atoms, a sorbitan group, or a group of formula R 26 CO wherein R 26 is an alkyl group having 11 to 22 carbon atoms; R 22 is hydrogen or an alkyl group, a carboxyalkyl group having 2 to 4 carbon atoms, or a fatty acid residue having 10 to 22 carbon atoms; X is a polyalkylene oxide group comprising an average of 2 to 40 alkylene oxide groups or mixed alkylene oxide groups; R 23 is a sorbitan group, R 24 is a fatty acid residue having 10 to 22 carbon atoms, and R 26 is An alkyl or alkenyl group having 10 to 22 carbon atoms. 제1항 내지 제4항 중의 어느 한 항에 있어서, 대기압에서의 비점이 2000℃를 초과하고 융점은 60℃ 미만이고; 광유, 임의로는 수소화 식물성유, C8내지 C22지방산의 C1-6에스테르 및 이들의 혼합물로부터 선택된 오일 성분 1종 이상을 포함하는 조성물.The method of claim 1, wherein the boiling point at atmospheric pressure exceeds 2000 ° C. and the melting point is less than 60 ° C. 6. A composition comprising at least one oil component selected from mineral oil, optionally hydrogenated vegetable oil, C 1-6 esters of C 8 to C 22 fatty acids and mixtures thereof. 제1항 내지 제5항 중의 어느 한 항에 있어서, 알콜 및 글리콜로부터 선택된 수용성 또는 수혼화성 유기용매 1종 이상을 포함하는 조성물.The composition according to any one of claims 1 to 5, comprising at least one water soluble or water miscible organic solvent selected from alcohols and glycols. 제1항 내지 제6항 중의 어느 한 항에서,(a) 조성물 총 함량의 5 내지 90중량%로 존재하는, 제1항에서 정의된 바와 같은 화학식(Ⅰ) 또는 (Ⅱ)의 빅-디카르복실산 폴리알킬렌옥시 반 에스테르 유도체 1종 이상; 및 (b) (ⅰ) 조성물 총 함량의 0 내지 90중량%로 존재하는 비이온계 계면활성제 1종 이상; 및(또는) (ⅱ) 조성물 함량의 0 내지 60중량%로 존재하는 음이온계 계면활성제 1종 이상; 및(또는) (C) 조성물 총 함량의 0 내지 97중량%로 존재하는 오일 성분 1종 이상을 함유하는 보조제 조성물.The big-dicar of any of claims 1 to 6, wherein (a) is present at 5 to 90% by weight of the total content of the composition, as defined in claim 1 At least one acid polyalkyleneoxy half ester derivative; And (b) at least one nonionic surfactant present in 0-90% by weight of the total content of the composition; And / or (ii) at least one anionic surfactant present at 0-60% by weight of the composition content; And / or (C) at least one oil component present at 0 to 97% by weight of the total content of the composition. (a) 화학식(Ⅰ) 또는 (Ⅱ)의 계면활성제 빅-디카르복실산 폴리알킬렌옥시 반 에스테르 유도체 1종 이상; 및 (b) 농축물 또는 이에 대응하는 회석 제형의 의도한 용도에 대하여 특이 활성을 갖는 화학 약제 1종 이상을 함유함을 특징으로 하는 분산성 및(또는) 가용성 농축물.(a) at least one surfactant big-dicarboxylic acid polyalkyleneoxy half ester derivative of formula (I) or (II); And (b) at least one chemical agent having specific activity for the intended use of the concentrate or its corresponding dilution formulation. 제8항에 있어서, 의도된 용도에 대하여 특이 활성을 갖는 화학 약제가 성장 조절제, 제조제 및 농약으로부터 선택된 화합물 1종 이상인 농축물.The concentrate of claim 8, wherein the chemical agent having specific activity for the intended use is at least one compound selected from growth regulators, preparations, and pesticides. 제8항에 있어서, 화학 약제가 PMCM 화합물 1종 이상이거나 또는 이들을 포함하는 농축물.The concentrate of claim 8, wherein the chemical agent is one or more of PMCM compounds. 제8항에 있어서, 의도된 용도에 대하여 특이 활성을 갖는 화학 약제가 금속 부식 억제제인 농축물.The concentrate of claim 8 wherein the chemical agent having specific activity for the intended use is a metal corrosion inhibitor. 그의 물 성분의 총 중량의 10 내지 10,000배로 분산된, 제1항 내지 제7항 중의 어느 한 항에서 청구된 바와 같은 조성물 또는 제8항 내지 제11항 중의 어느 한 항에서 청구된 바와 같은 농축물을 함유함을 특징으로 하는 희석제형.A composition as claimed in any one of claims 1 to 7 or a concentrate as claimed in any one of claims 8 to 11, dispersed at 10 to 10,000 times the total weight of its water component. Diluent type, characterized in that it contains. 그의 물 성분의 총 중량의 10내지 10,000배로 분산된, 제9항 또는 제10항에서 청구된 바와 같은 농축물을 식물에 적용하는 단계를 포함하는 식물의 처리 방법.A method of treating a plant, comprising applying to the plant a concentrate as claimed in claim 9 or 10, dispersed 10 to 10,000 times the total weight of the water component thereof. 그의 물 성분의 총 중량의 10 내지 10,000배로 분산된, 제11항에서 청구된 바와 같은 농축물을 식물에 적용하는 단계를 포함하는 금속의 가공 방법.A method of processing a metal comprising applying to a plant a concentrate as claimed in claim 11, dispersed at 10 to 10,000 times the total weight of its water component. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
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