KR970065793A - Method for producing polyacrylonitrile precursor - Google Patents

Method for producing polyacrylonitrile precursor Download PDF

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Publication number
KR970065793A
KR970065793A KR1019960008318A KR19960008318A KR970065793A KR 970065793 A KR970065793 A KR 970065793A KR 1019960008318 A KR1019960008318 A KR 1019960008318A KR 19960008318 A KR19960008318 A KR 19960008318A KR 970065793 A KR970065793 A KR 970065793A
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KR
South Korea
Prior art keywords
emulsion
precursor
producing
polyacrylonitrile
polyacrylonitrile precursor
Prior art date
Application number
KR1019960008318A
Other languages
Korean (ko)
Other versions
KR0168738B1 (en
Inventor
윤성로
신동훈
김순식
임대우
Original Assignee
한형수
제일합섬 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 한형수, 제일합섬 주식회사 filed Critical 한형수
Priority to KR1019960008318A priority Critical patent/KR0168738B1/en
Publication of KR970065793A publication Critical patent/KR970065793A/en
Application granted granted Critical
Publication of KR0168738B1 publication Critical patent/KR0168738B1/en

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • D01F9/225—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles from stabilised polyacrylonitriles
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00—Treatment of filament-forming or like material
    • D01D1/06—Feeding liquid to the spinning head
    • D01D1/065—Addition and mixing of substances to the spinning solution or to the melt; Homogenising
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00—Inorganic fibres
    • D10B2101/10—Inorganic fibres based on non-oxides other than metals
    • D10B2101/12—Carbon; Pitch

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Fibers (AREA)

Abstract

본 발명은 탄소섬유용으로 사용되는 폴리아크릴로니트릴계 전구체의 제조에 있어 소성시 작업성의 향상과 물성의 개선을 위해 특수 화합물이 함유된 수분산액을 사용하여 유제를 부여하는 것을 특징으로 한 것으로서, 구체적으로는, 하기 일반식(I)로 표현되는 폴리옥시에틸렌계 화합물을 물에 분산시켜 제조된 수분산액을 사용하여 유제를 부여함으로써, 특히 소성시 정전기 발생으로 인한 내염화섬유의 모우, 단사절 융착 및 접착으로 인한 섬유의 물성저하를 현저히 개선한 탄소섬유용 폴리아크릴로니트릴계 전구체의 제조방법에 관한 것이다.The present invention is characterized in that an emulsion is provided by using an aqueous dispersion containing a special compound for improving workability and physical properties during firing in the production of a polyacrylonitrile precursor used for carbon fiber, Specifically, by applying an emulsion using an aqueous dispersion prepared by dispersing a polyoxyethylene-based compound represented by the following general formula (I) in water, it is possible to prevent the generation of static electricity, The present invention relates to a method for producing a polyacrylonitrile precursor for carbon fibers which significantly improves the physical properties of fibers due to fusion and adhesion.

H2N-R1-(OR2)n-O-R1-NH2(I)H 2 NR 1 - (OR 2 ) n -OR 1 -NH 2 (I)

(단, R1및 R2는 탄소수 1-8의 지방족 탄화수소를 포함하는 화합물이고, n은 정수임)(Provided that R 1 and R 2 are aliphatic hydrocarbons containing 1 to 8 carbon atoms and n is an integer)

Description

폴리아크릴로니트릴계 전구체의 제조방법Method for producing polyacrylonitrile precursor

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is a trivial issue, I did not include the contents of the text.

Claims (3)

폴리아크릴로니트릴계 방사용 원액을 제조한 후 방사 및 연신 공정에 유제부여 공정을 추가하여 탄소섬유용 전구체를 제조함에 있어서, 하기 일반식(I)로 표현되는 폴리옥시에틸렌계 화합물을 물에 분산시킨 수분산액을 사용하여 유제를 부여하는 것을 특징으로 하는 탄소섬유용 폴리아크릴로니트릴계 전구체의 제조방법.In producing a precursor for a carbon fiber by adding an emulsion applying step to a spinning and drawing process after preparing a polyacrylonitrile spinning solution, a polyoxyethylene compound represented by the following general formula (I) is dispersed in water Wherein the emulsion is dispersed in an aqueous solution of a polyacrylonitrile-based precursor. H2N-R1-(OR2)n-O-R1-NH2(I)H 2 NR 1 - (OR 2 ) n -OR 1 -NH 2 (I) (단, R1및 R2는 탄소수 1-8의 지방족 탄화수ㅅ를 포함하는 화합물이고, n은 정수임)(Provided that R 1 and R 2 are each a compound containing aliphatic hydrocarbon having 1 to 8 carbon atoms and n is an integer) 제1항에 있어서, 수분산액은 일반식(I)로 표현되는 폴리옥시에틸렌게 화합물이 15-35중량% 함유된 것임을 특징으로 하는 탄소섬유용 폴리아크릴로니트릴계 전구체의 제조방법.The method for producing a polyacrylonitrile precursor for carbon fiber according to claim 1, wherein the aqueous dispersion contains 15 to 35% by weight of a polyoxyethylene glycol compound represented by the general formula (I). 제1항에 있어서, 유제의 부여시 전구체에 대한 유제의 부착 농도는 0.3-5.0중량%임을 특징으로 하는 탄소섬유용 폴리아크릴로니트릴계 전구체의 제조방법.The method for producing a polyacrylonitrile precursor for carbon fiber according to claim 1, wherein the adhesion concentration of the emulsion to the precursor upon application of the emulsion is 0.3-5.0 wt%. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019960008318A 1996-03-26 1996-03-26 Method of manufacturing polyacrylnitryl fiber precursor KR0168738B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960008318A KR0168738B1 (en) 1996-03-26 1996-03-26 Method of manufacturing polyacrylnitryl fiber precursor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019960008318A KR0168738B1 (en) 1996-03-26 1996-03-26 Method of manufacturing polyacrylnitryl fiber precursor

Publications (2)

Publication Number Publication Date
KR970065793A true KR970065793A (en) 1997-10-13
KR0168738B1 KR0168738B1 (en) 1999-01-15

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Application Number Title Priority Date Filing Date
KR1019960008318A KR0168738B1 (en) 1996-03-26 1996-03-26 Method of manufacturing polyacrylnitryl fiber precursor

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102004731B1 (en) 2016-11-23 2019-07-29 주식회사 엘지화학 Method of preparing polyacrylonitrile based fiber and polyacrylonitrile based copolymer

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KR0168738B1 (en) 1999-01-15

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