KR970061977A - Fiber reinforced flame retardant polyester resin composition - Google Patents

Fiber reinforced flame retardant polyester resin composition Download PDF

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Publication number
KR970061977A
KR970061977A KR1019960004288A KR19960004288A KR970061977A KR 970061977 A KR970061977 A KR 970061977A KR 1019960004288 A KR1019960004288 A KR 1019960004288A KR 19960004288 A KR19960004288 A KR 19960004288A KR 970061977 A KR970061977 A KR 970061977A
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KR
South Korea
Prior art keywords
resin composition
polyester resin
retardant polyester
flame retardant
fiber
Prior art date
Application number
KR1019960004288A
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Korean (ko)
Other versions
KR0181677B1 (en
Inventor
임대우
백문수
조태흥
김종희
Original Assignee
박홍기
제일합섬 주식회사
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Priority to KR1019960004288A priority Critical patent/KR0181677B1/en
Publication of KR970061977A publication Critical patent/KR970061977A/en
Application granted granted Critical
Publication of KR0181677B1 publication Critical patent/KR0181677B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/84—Flame-proofing or flame-retarding additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

본 발명은 난연성이 뛰어나면서도 연소시 인체에 유해한 가스의발새이 거의 없고, 기계적 물성 저하가 거의 없고, 기계적 강도, 전기적 절연성 및 내약품성이 뛰어난 섬유강화 난연성 폴리에스테르 수지 조성물을 얻음을 목적으로 하는 것으로 그 구성은 폴리머의분자쇄 내에 아래 구조식의 인계 화합물의 함유량을 1,000∼50,000ppm되도록 공중합시킴을 특징으로 한 난연성 폴리에스테르 수지의 조성물.An object of the present invention is to provide a fiber-reinforced flame-retardant polyester resin composition which is excellent in flame retardancy and has almost no gaseous harmful gas to the human body during combustion, has little mechanical property deterioration, and is excellent in mechanical strength, electrical insulation and chemical resistance. Wherein the composition is copolymerized in the molecular chain of the polymer so that the content of the phosphorus compound of the following structural formula is 1,000 to 50,000 ppm.

(상기 식에서 R1, R2는 탄소수가 1∼18의 알킬기, 아릴기, 모노히드록시알킬기 또는 수소원자이며, R3는 알킬기 또는 아릴기이며, n은 1∼4의 정수이다)(Wherein R 1 and R 2 are an alkyl group, an aryl group, a monohydroxyalkyl group or a hydrogen atom having 1 to 18 carbon atoms, R 3 is an alkyl group or an aryl group, and n is an integer of 1 to 4)

Description

섬유강화 난연성 폴리에스테르 수지 조성물Fiber reinforced flame retardant polyester resin composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is a trivial issue, I did not include the contents of the text.

Claims (3)

성형용 폴리에틸렌테레프탈레이트 수지 조성물에 잇어서, 폴리머의 분자쇄 내에 아래의 구조식을 가지는 인계 난연제 화합물이 공중합되고, 유기 결정화 촉진제와 섬유상 강화제가 배합됨을 특징으로 하는 섬유강화 난연성 폴리에스테르 수지 조성물.A fiber-reinforced flame retardant polyester resin composition according to any one of claims 1 to 3, wherein in the polyethylene terephthalate resin composition for molding, a phosphorus flame retardant compound having the following structural formula is copolymerized in the molecular chain of the polymer, and an organic crystallization accelerator and a fiber- (상기 식에서 R1, R2는 탄소수가 1∼18의 알킬기, 아릴기, 모노히드록시알킬기 또는 수소원자이며, R3는 알킬기 또는 아릴기이며, n은 1∼4의 정수이다)(Wherein R 1 and R 2 are an alkyl group, an aryl group, a monohydroxyalkyl group or a hydrogen atom having 1 to 18 carbon atoms, R 3 is an alkyl group or an aryl group, and n is an integer of 1 to 4) 제1항에 있어서, 인화합물이 공중합되어 있는 폴리에틸렌테레프탈레이트 수지는 테레프탈산 또는 디메틸테레프탈산과 에틸렌글리콜을 주원료로 하여 폴리머 중의 인함유량이 1,000∼50,000ppm 범위내에 들도록 상기의분자 구조를 가지는 인화합물을 공중합하여 사용하는 것을 특징으로 하는 섬유강화 난연성 폴리에스테르 수지 조성물.The polyethylene terephthalate resin according to claim 1, wherein the polyethylene terephthalate resin in which the phosphorus compound is copolymerized contains terephthalic acid or dimethyl terephthalic acid and ethylene glycol as main raw materials, and the phosphorus compound having the above molecular structure is copolymerized so that the phosphorus flow rate in the polymer falls within the range of 1,000 to 50,000 ppm Reinforced flame retardant polyester resin composition. 제1항에 있어서, 섬유강화 난연성 폴리에스테르 수지 조성물은 유기산의 금속염이나 모노 또는 폴리카르복실산의 금속염에 폴리알킬렌 글리콜이나 유기 케톤 또는 유기 아마이드등의 유기 결정화촉진제, 섬유상강화제, 안정제등을 포함됨을 특징으로 하는 난연성 폴리에스테르 수지 조성물.The fiber-reinforced flame-retardant polyester resin composition according to claim 1, wherein the fiber-reinforced flame-retardant polyester resin composition comprises an organic crystallization accelerator, a fibrous reinforcing agent, a stabilizer, etc., such as a polyalkylene glycol, an organic ketone, or an organic amide in a metal salt of an organic acid or a mono or polycarboxylic acid metal salt Wherein the flame retardant polyester resin composition is a flame retardant polyester resin composition. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019960004288A 1996-02-23 1996-02-23 Fiber reinforced anti-flammable polyester resin compositions KR0181677B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960004288A KR0181677B1 (en) 1996-02-23 1996-02-23 Fiber reinforced anti-flammable polyester resin compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019960004288A KR0181677B1 (en) 1996-02-23 1996-02-23 Fiber reinforced anti-flammable polyester resin compositions

Publications (2)

Publication Number Publication Date
KR970061977A true KR970061977A (en) 1997-09-12
KR0181677B1 KR0181677B1 (en) 1999-05-15

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KR1019960004288A KR0181677B1 (en) 1996-02-23 1996-02-23 Fiber reinforced anti-flammable polyester resin compositions

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100457764B1 (en) * 1999-02-02 2004-11-17 에스케이씨 주식회사 Polyester film
KR100457767B1 (en) * 1999-11-09 2004-11-17 에스케이씨 주식회사 flame retardant and Heat-shrinkable polyester film

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100310273B1 (en) * 1999-10-20 2001-09-29 박호군 Nonflammable Cellulose Fiber Structures and a Process of Making Them

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100457764B1 (en) * 1999-02-02 2004-11-17 에스케이씨 주식회사 Polyester film
KR100457767B1 (en) * 1999-11-09 2004-11-17 에스케이씨 주식회사 flame retardant and Heat-shrinkable polyester film

Also Published As

Publication number Publication date
KR0181677B1 (en) 1999-05-15

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