KR970042997A - Encapsulated Bleach Activator - Google Patents

Encapsulated Bleach Activator Download PDF

Info

Publication number
KR970042997A
KR970042997A KR1019950061155A KR19950061155A KR970042997A KR 970042997 A KR970042997 A KR 970042997A KR 1019950061155 A KR1019950061155 A KR 1019950061155A KR 19950061155 A KR19950061155 A KR 19950061155A KR 970042997 A KR970042997 A KR 970042997A
Authority
KR
South Korea
Prior art keywords
bleach activator
bleach
cellulose
silicone
activator according
Prior art date
Application number
KR1019950061155A
Other languages
Korean (ko)
Other versions
KR100190819B1 (en
Inventor
장창현
오성근
안호정
Original Assignee
성재갑
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 성재갑, 주식회사 엘지화학 filed Critical 성재갑
Priority to KR1019950061155A priority Critical patent/KR100190819B1/en
Publication of KR970042997A publication Critical patent/KR970042997A/en
Application granted granted Critical
Publication of KR100190819B1 publication Critical patent/KR100190819B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3953—Inorganic bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 산소계 표백활성제인 금속(Ⅱ)-치환된 제올라이트를 과립화한 다음, 수용해성이 우수한 물질로 캡슐화하고 오일성분으로 코팅함으로써 표백제의 저장안정성을 향상시키고 세탁시 표백제에 대한 활성화능을 충분히 발휘할 수 있도록 고안된 새로운 형태의 산소계 표백활성화제, 및 표백제와 함께 본 발명의 표백활성화제를 유효성분으로 함유하는 세제조성물에 관한 것이다.The present invention is to granulate the metal (II) -substituted zeolite, which is an oxygen-based bleaching agent, and then encapsulate it with a water-soluble material and coat it with an oil component to improve the storage stability of the bleach and to sufficiently activate the activating capacity for the bleach during washing. It relates to a new type of oxygen-based bleach activator designed to exert, and a detergent composition containing the bleach activator of the present invention as an active ingredient together with the bleach.

Description

캡슐화된 표백활성화제Encapsulated Bleach Activator

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (15)

표백 활성화 성분을 수용해성 물질에 의해 캡슐화하고 오일성분으로 코팅하여 제조됨을 특징으로 하는 표백활성화제.A bleach activator, characterized in that it is prepared by encapsulating the bleach activating component with a water-soluble substance and coating with an oil component. 제1항에 있어서, 캡슐화되기 전에 결합제와 배합됨으로써 10 내지 200um 크기로 과립화된 표백활성화제.The bleach activator of claim 1, wherein the bleach activator is granulated to a size of 10 to 200 um by combining with a binder before encapsulation. 제2항에 있어서, 결합제가 알부민,젤라틴,아라비아검,아가로오스,알긴산염(alginate),셀룰로오스,셀룰로오스아세테이트탈레이트,메틸셀룰로오스,에틸셀룰로오스,하이드록시프로필셀룰로오스,폴리비닐알콜,폴리비닐피톨리돈,실리콘 중합체,가용성 전분(soluble starch),비누,노닐페닐에테르,폴리에틸렌글리콜,지방산,지방알콜 및 키토산(chitosan) 중에서 선택된 1종 이상인 표백활성화제.The method of claim 2, wherein the binder is albumin, gelatin, gum arabic, agarose, alginate, cellulose, cellulose acetate, cellulose, ethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol, polyvinyl pititol At least one bleach activator selected from reddon, silicone polymer, soluble starch, soap, nonylphenyl ether, polyethylene glycol, fatty acid, fatty alcohol and chitosan. 제2항 또는 3항에 있어서, 결합제를 표백 활성화 성분 1000 중량부에 대해 10 내지 1000 중량부의 비율로 사용한 표백활성화제.The bleach activator according to claim 2 or 3, wherein the binder is used in a ratio of 10 to 1000 parts by weight relative to 1000 parts by weight of the bleach activating component. 제2항에 있어서, 표백 활성화 성분이 2가 금속이온에 의해 치환된 제올라이트인 표백활성화제.The bleach activator according to claim 2, wherein the bleach activating component is a zeolite substituted by a divalent metal ion. 제5항에 있어서, 2가 금속이온이 Mn(Ⅱ), Cu(Ⅱ),Fe(Ⅱ) 및 Zn(Ⅱ) 중에서 선택된 1종 이상인 표백활성화제.The bleach activator according to claim 5, wherein the divalent metal ion is at least one selected from Mn (II), Cu (II), Fe (II) and Zn (II). 제5항에 있어서, 제올라이트가 제올라이트 A,X,Y,L,오메가(Omega),제올론 모데나이트(Zeolon mordenite),ZSM-5,F 및 W중에서 선택된 1종 이상인 표백활성화제.6. The bleach activator according to claim 5, wherein the zeolite is at least one selected from zeolite A, X, Y, L, Omega, Zelon mordenite, ZSM-5, F and W. 제5항에 있어서, 금속의 치환정도가 1,2 또는 3 유닛(unit)인 표백활성화제.6. The bleach activator according to claim 5, wherein the degree of substitution of the metal is 1,2 or 3 units. 제2항에 있어서, 과립화 및 캡슐화 공정을 유동층(fluidized bed)에서 수행함을 특징으로 하는 표백활성화제.The bleach activator according to claim 2, wherein the granulation and encapsulation processes are carried out in a fluidized bed. 제1항에 있어서, 캡슐화 물질이 알부민,젤라틴,아리미아검,아가로오스,알긴산염(alginate),셀룰로오스,셀룰로오스아세테이트탈레이트,메틸셀룰로오스,에틸셀룰로오스,하이드록시프로필셀룰로오스,폴리비닐알콜,폴리비닐피롤리돈,실리콘 중합체,가용성 전분(soluble starch),텍스트린,비누,노닐페닐에테르,폴리에틸렌글리콜,지방산,지방알콜 및 키토산 중에서 선택된 1종 이상인 표백활성화제.The method of claim 1, wherein the encapsulating material is albumin, gelatin, arimia gum, agarose, alginate, cellulose, cellulose acetate, methyl cellulose, ethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol, poly Bleach activator selected from vinylpyrrolidone, silicone polymer, soluble starch, textile, soap, nonylphenyl ether, polyethylene glycol, fatty acid, fatty alcohol and chitosan. 제10항에 있어서, 캡슐화 물질을 2 내지 50 중량% 농도의 용액상으로 분무하여 캡슐화한 표백활성화제.The bleach activator according to claim 10, wherein the encapsulating material is encapsulated by spraying the solution in a concentration of 2 to 50% by weight. 제10항 또는 제11항에 있어서, 캡슐화 물질을 표백활성화능을 갖는 성분 1000 중량부에 대해 20 내지 2000 중량부의 비율로 사용한 표백활성화제.The bleach activator according to claim 10 or 11, wherein the encapsulating material is used in a ratio of 20 to 2000 parts by weight based on 1000 parts by weight of the component having the bleaching activating ability. 제1항에 있어서, 오일성분이 실리콘 100∼5000, 실리콘 10000∼100000을 실리콘 100∼5000에 용해시킨 것, 실리콘 100∼5000중의 0.1∼5 중량% 왁스용액, 액체 파라핀(liquid paraffin), 대두유(soybean oil), 올리브유 및 참깨유 중에서 선택된 1종 이상인 표백활성화제.2. The oil component according to claim 1, wherein the oil component is silicone 100-5000, silicone 10000-100000 dissolved in silicone 100-5000, 0.1-5 wt% wax solution in silicone 100-5000, liquid paraffin, soybean oil ( soybean oil), at least one bleach activator selected from olive oil and sesame oil. 제13항에 있어서, 캡슐화된 입자를 오일성분 중에 침적시키고 약하게 교반하여 분산시킨 다음,분산된 용액을 필터를 통해 진공여과하고 건조시킨 표백활성화제.The bleach activator according to claim 13, wherein the encapsulated particles are deposited in an oil component and dispersed by slight stirring, and then the dispersed solution is vacuum filtered through a filter and dried. 표백제 및 제1항의 표백활성화제를 함유함을 특징으로 하는 세제조성물.A detergent composition comprising a bleach and a bleach activator of claim 1.
KR1019950061155A 1995-12-28 1995-12-28 Encapsulated bleaching actuator KR100190819B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019950061155A KR100190819B1 (en) 1995-12-28 1995-12-28 Encapsulated bleaching actuator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019950061155A KR100190819B1 (en) 1995-12-28 1995-12-28 Encapsulated bleaching actuator

Publications (2)

Publication Number Publication Date
KR970042997A true KR970042997A (en) 1997-07-26
KR100190819B1 KR100190819B1 (en) 1999-06-01

Family

ID=19445808

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950061155A KR100190819B1 (en) 1995-12-28 1995-12-28 Encapsulated bleaching actuator

Country Status (1)

Country Link
KR (1) KR100190819B1 (en)

Also Published As

Publication number Publication date
KR100190819B1 (en) 1999-06-01

Similar Documents

Publication Publication Date Title
KR100928133B1 (en) Solid Phase Redispersible Emulsion
US5254283A (en) Isophthalic polymer coated particles
JPS63252543A (en) Water-soluble microcapsule
US5876755A (en) Humidity resistant composition
US20060172909A1 (en) Peroxycarboxylic acid-based polyelectrolyte capsule system having a long shelf life
Quellet et al. Flavors & fragrance delivery systems
JPH021528B2 (en)
JPH0333196A (en) Pereume particle used for cleaning and conditioning compounds
WO2002060573A2 (en) Capsule-in-capsule system and method for the production thereof
US4828746A (en) Detergent compatible, dryer released fabric softening/antistatic agents in a sealed pouch
US4898680A (en) Detergent compatible, dryer released fabric softening/antistatic agents
KR20100067655A (en) Encapsulated active ingredients for cleaning applications
KR970042997A (en) Encapsulated Bleach Activator
WO2021214009A1 (en) Scent booster
KR930703427A (en) Granules containing coated bleach activator
CN1188143A (en) Cleaning perfume particle
KR970074914A (en) Encapsulated bleach activator
KR970070177A (en) Encapsulated bleach activator
EP0684984B1 (en) Humidity resistant composition
KR100203740B1 (en) Encapsulated bleaching activator
JPH04310233A (en) Micro-capsule capable of releasing core material when it is wet
EP0269179A1 (en) Detergent compatible, dryer released fabric softening/antistat agents
KR100416934B1 (en) Ecapsulated Bleaching Activator
JPS6317936A (en) Production of desiccant

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20061226

Year of fee payment: 9

LAPS Lapse due to unpaid annual fee