KR970042759A - Flame Retardant Resin Composition for Polypropylene Fiber - Google Patents

Flame Retardant Resin Composition for Polypropylene Fiber Download PDF

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Publication number
KR970042759A
KR970042759A KR1019950056737A KR19950056737A KR970042759A KR 970042759 A KR970042759 A KR 970042759A KR 1019950056737 A KR1019950056737 A KR 1019950056737A KR 19950056737 A KR19950056737 A KR 19950056737A KR 970042759 A KR970042759 A KR 970042759A
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South Korea
Prior art keywords
flame retardant
resin composition
weight
retardant resin
parts
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KR1019950056737A
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Korean (ko)
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KR0169007B1 (en
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송병규
강상용
김영식
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성기웅
대림산업 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 폴리프로필렌 100중량부에 대하여, 폴리에틸렌 5~30중량부, 에틸렌-프로필렌 고무 1~20중량부, 브롬계 난연제 1~20중량부, 산화안티몬 0.5~10중량부, 계면활성제 0.05~10중량부 및 첨가제 0.05~6중량부를 포함하는 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물에 관한 것이다.The present invention is based on 100 parts by weight of polypropylene, 5 to 30 parts by weight of polyethylene, 1 to 20 parts by weight of ethylene-propylene rubber, 1 to 20 parts by weight of brominated flame retardant, 0.5 to 10 parts by weight of antimony oxide, and 0.05 to 10 surfactant. It is related with the flame-retardant resin composition for polypropylene fiber characterized by including a weight part and 0.05-6 weight part of additives.

Description

폴리프로필렌 섬유용 난연성 수지 조성물Flame Retardant Resin Composition for Polypropylene Fiber

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

포릴프로필렌 100 중량부에 대하여, 폴리에틸렌 5~30 중량부, 에틸렌-프로필렌 고무 1~20중량부, 브롬계 난연제 1~20중량부, 산화안티몬 0.5~10중량부, 계면활성제 0.05~10 중량부 및 첨가제 0.05~6중량부를 포함하는 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물5 to 30 parts by weight of polyethylene, 1 to 20 parts by weight of ethylene-propylene rubber, 1 to 20 parts by weight of brominated flame retardant, 0.5 to 10 parts by weight of antimony oxide, 0.05 to 10 parts by weight of surfactant, and 100 parts by weight of polypropylene Flame-retardant resin composition for polypropylene fibers comprising 0.05 to 6 parts by weight of an additive 제1항에 있어서, 상기 폴리프로필렌은 용융흐름지수가 3~60g/10분 및 수평균분자량이 30,000~100,000, 중량평균분자량 20,000~300,000, 분자량 분포도가 2~7인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The polypropylene of claim 1, wherein the polypropylene has a melt flow index of 3 to 60 g / 10 minutes, a number average molecular weight of 30,000 to 100,000, a weight average molecular weight of 20,000 to 300,000, and a molecular weight distribution of 2 to 7 Flame Retardant Resin Composition 제1항에 있어서, 상기 폴리에틸렌은 용융흐름지수가 1~30g/10분, 밀도가 0.890~0.970g/cm3인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame-retardant resin composition for polypropylene fibers according to claim 1, wherein the polyethylene has a melt flow index of 1 to 30 g / 10 minutes and a density of 0.890 to 0.970 g / cm3. 제1항에 있어서, 상기 에틸렌-프로필렌 고무는 무늬점도(ML1+4, 100℃에서 측정)가 10~100이고, 프로필렌 함량이 10~50중량%인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame retardant resin composition for polypropylene fibers according to claim 1, wherein the ethylene-propylene rubber has a pattern viscosity (measured at ML1 + 4, 100 ° C) of 10 to 100 and a propylene content of 10 to 50% by weight. 제1항에 있어서, 상기 브롬계 난연제는 테트라브로모프탈이미드, 테트라브로모비스페놀-A-비스(2,3-대브로모프로필에테르), 에틸렌비스테트라브로모프탈이미드, 폴리브로모페닐렌옥사이드, 헥사브로모시클로도데칸 등 브롬화 지환족 혹은 브롬화 지방족 화합물 또는 이들의 혼합물이며, 산화안티몬으로는 삼산화안티몬 또는 오산화안티몬인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The bromine-based flame retardant is tetrabromophthalimide, tetrabromobisphenol-A-bis (2,3- large bromopropyl ether), ethylene bistetrabromophthalimide, polybromo Brominated alicyclic or brominated aliphatic compounds such as phenylene oxide, hexabromocyclododecane, or mixtures thereof, and antimony oxide is antimony trioxide or antimony pentoxide, and is a flame retardant resin composition for polypropylene fibers. 제1항에 있어서, 상기 산화안티몬은 평균입경이 0.5~5미크론인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame retardant resin composition for polypropylene fibers according to claim 1, wherein the antimony oxide has an average particle diameter of 0.5 to 5 microns. 제1항에 있어서, 상기 계면활성제는 불소화합물, 실리콘 화합물 또는 이들의 혼합물인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame retardant resin composition for polypropylene fibers according to claim 1, wherein the surfactant is a fluorine compound, a silicone compound or a mixture thereof. 제1항에 있어서, 상기 첨가제는 내열 및 산화안정제, 자외선 안정제 및 활제군에서 선택된 1종 이상을 포함함을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame retardant resin composition for polypropylene fibers according to claim 1, wherein the additive comprises at least one member selected from heat and oxidation stabilizers, ultraviolet stabilizers, and lubricants. 제8항에 있어서, 상기 자외선 안정제는 비스-2,2,6,6,-테트라메틸-4-피페리딜-세바케이트, 키마소프 944 또는 이들의 혼합물인 것을 특징으로 하는 폴리프로필렌 섬유용 난연성 수지 조성물The flame retardant for polypropylene fibers as claimed in claim 8, wherein the UV stabilizer is bis-2,2,6,6, -tetramethyl-4-piperidyl-sebacate, chimasov 944 or mixtures thereof. Resin composition 제1항 내지 제9항의 난연성 수지 조성물로 부터 제조된 난연성을 지닌 폴리프로필렌 섬유Flame retardant polypropylene fiber prepared from the flame retardant resin composition of claim 1
KR1019950056737A 1995-12-26 1995-12-26 A non-burning resin composition for polypropylene fiber KR0169007B1 (en)

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Application Number Priority Date Filing Date Title
KR1019950056737A KR0169007B1 (en) 1995-12-26 1995-12-26 A non-burning resin composition for polypropylene fiber

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Application Number Priority Date Filing Date Title
KR1019950056737A KR0169007B1 (en) 1995-12-26 1995-12-26 A non-burning resin composition for polypropylene fiber

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KR0169007B1 KR0169007B1 (en) 1999-03-20

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100407724B1 (en) * 1999-12-30 2003-12-31 삼성아토피나주식회사 Flame retardant polypropylene resin composition
KR100405644B1 (en) * 2001-03-31 2003-11-14 이동환 Flame retardant yarn and manufacturing method of it
KR100745320B1 (en) * 2001-12-24 2007-08-01 삼성토탈 주식회사 Flame Retardant Polypropylene Resin Composition
KR100589510B1 (en) * 2004-12-08 2006-06-14 삼성토탈 주식회사 Flame retardant polypropylene resin composition
KR101887617B1 (en) * 2017-09-19 2018-09-10 주식회사 태현 flame resisting thread manufacturing method, and net safety using flame resisting thread
KR102501772B1 (en) * 2022-09-22 2023-02-21 주식회사 코솔러스 Flame-retardant master batch and method for manufacturing the same

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