KR970027220A - Fiber reactive dyes. Method of manufacture and use thereof - Google Patents

Fiber reactive dyes. Method of manufacture and use thereof Download PDF

Info

Publication number
KR970027220A
KR970027220A KR1019960054429A KR19960054429A KR970027220A KR 970027220 A KR970027220 A KR 970027220A KR 1019960054429 A KR1019960054429 A KR 1019960054429A KR 19960054429 A KR19960054429 A KR 19960054429A KR 970027220 A KR970027220 A KR 970027220A
Authority
KR
South Korea
Prior art keywords
formula
compound
alkyl
same
hydrogen
Prior art date
Application number
KR1019960054429A
Other languages
Korean (ko)
Other versions
KR100460556B1 (en
Inventor
레이먼 페이틀
사벳 압두-사벳
위르겐 샤에처
한스 라이헤르트
Original Assignee
칼루자 마이클 이.
어드밴스트 엘라스토머 시스템즈, 엘.피.
발데크 베르너
시바-가이기 에이지
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/556,673 external-priority patent/US5621045A/en
Application filed by 칼루자 마이클 이., 어드밴스트 엘라스토머 시스템즈, 엘.피., 발데크 베르너, 시바-가이기 에이지 filed Critical 칼루자 마이클 이.
Publication of KR970027220A publication Critical patent/KR970027220A/en
Application granted granted Critical
Publication of KR100460556B1 publication Critical patent/KR100460556B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4411—Azo dyes
    • C09B62/4415—Disazo or polyazo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D06P3/248—Polyamides; Polyurethanes using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

본 발명은 매우 다양한 섬유재료를 염색 또는 날염하는 데 적합한 화학식(1)의 섬유 반응성 염료에 관한 것이다.The present invention relates to a fiber reactive dye of formula (1) suitable for dyeing or printing a wide variety of fiber materials.

Description

섬유 반응성 염료, 이의 제조방법 및 용도Fiber reactive dyes, preparation method and use thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

화학식(1)의 화합물.Compound of formula (1). 상기 화학식(1)에서 B는 화학식 (2a), (2b) 또는 (2c)의 브릿지이고 (R)n은 C1-C4알킬, C1-C4알콕시, 할로겐 및 설포로 이루어진 그룹으로부터 선택된 동일하거나 상이한 n개의 라디칼이며, (R')m은 C1-C4알킬, C1-C4알콕시, 할로겐 및 설포로 이루어진 그룹으로부터 선택된 동일하거나 상이한 m개의 라디칼이고, n 및 m은 서로 독립적으로 각각 0, 1 또는 2이며, R1및 R1'는 독립적으로 각각 수소 또는 치환되거나 치환되지 않은 C1-C4알킬이고, X1및 X2는 서로 독립적으로 각각 할로겐, 3-카복시피리딘-1-일 또는 3-카바모일피리딘-1-일이며, Y 및 Y′는 서로 독립적으로 각각 비닐 또는 라디칼 -CH2-CH2-U(여기서, U는 이탈그룹이다)이고, p 및 q는 서로 독립적으로 각각 0 또는 1이다.In formula (1), B is a bridge of formula (2a), (2b) or (2c) and (R) n is selected from the group consisting of C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen and sulfo Same or different n radicals, (R ′) m is the same or different m radicals selected from the group consisting of C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen and sulfo, n and m are independent of each other Are each 0, 1 or 2, R 1 and R 1 ′ are independently hydrogen or substituted or unsubstituted C 1 -C 4 alkyl, respectively, X 1 and X 2 are each independently halogen, 3-carboxypyridine -1-yl or 3-carbamoylpyridin-1-yl, Y and Y 'are each independently a vinyl or a radical -CH 2 -CH 2 -U, wherein U is a leaving group, p and q Are each independently 0 or 1. 상기 화학식 (2a), (2b) 및 (2c)에서, R2및 R2'는 독립적으로 각각 수소 또는 치환되거나 치환되지 않은 C1-C4알킬이고, R3은 하이드록실에 의해 치환된 C1-C6알킬이며, R4는 수소 또는 C1-C4알킬이고, (alk)는 직쇄 또는 측쇄 C2-C12알킬렌이며, (alk')는 직쇄 또는 측쇄 C2-C4알킬렌이고, r은 1, 2 또는 3이다.In the above formulas (2a), (2b) and (2c), R 2 and R 2 ′ are each independently hydrogen or substituted or unsubstituted C 1 -C 4 alkyl, and R 3 is C substituted by hydroxyl 1 -C 6 alkyl, R 4 is hydrogen or C 1 -C 4 alkyl, (alk) is straight or branched C 2 -C 12 alkylene, (alk ') is straight or branched C 2 -C 4 alkyl Ren and r is 1, 2 or 3. 제1항에 있어서, (R)n및 (R')m이 서로 독립적으로 각각 메틸, 메톡시 및 설포로 이루어진 그룹으로부터 선택된 0, 1 또는 2개의 동일하거나 상이한 라디칼인 화합물.The compound of claim 1, wherein (R) n and (R ′) m are each independently 0, 1 or 2 identical or different radicals selected from the group consisting of methyl, methoxy and sulfo. 제1항 또는 제2항에 있어서, X1및 X2가 동일하고 각각 염소 또는 불소, 바람직하게는 염소인 화합물.A compound according to claim 1 or 2, wherein X 1 and X 2 are the same and are each chlorine or fluorine, preferably chlorine. 제1항 내지 제3항 중의 어느 한 항에 있어서, R1및 R1'가 동일하고 각각 수소 또는 C1-C4알킬인 화합물.The compound of any one of claims 1-3, wherein R 1 and R 1 ′ are the same and are each hydrogen or C 1 -C 4 alkyl. 제1항 내지 제4항 중의 어느 한 항에 있어서, p 및 q가 각각 1인 화합물.The compound of any one of claims 1-4, wherein p and q are each 1. 제1항 내지 제5항 중의 어느 한 항에 있어서, X1및 X2가 동일하고 각각 염소이며 R1및 R1'가 동일하고 각각 수소 또는 에틸이며 (R)n및 (R')m이 동일하고 각각 메틸, 메톡시 및 설포로 이루어진 그룹으로부터 선택된 0, 1 또는 2개의 동일하거나 상이한 라디칼이며 Y 및 Y'가 동일하고 각각 비닐 또는 β-설페이토에틸이며 p 및 q가 각각 1인 화합물.6. The compound of claim 1, wherein X 1 and X 2 are the same and are each chlorine and R 1 and R 1 ′ are the same and are each hydrogen or ethyl and (R) n and (R ′) m are 6. The same, 0, 1 or 2 identical or different radicals each selected from the group consisting of methyl, methoxy and sulfo, Y and Y 'are the same, vinyl or β-sulfatoethyl and p and q are each 1 . 제1항 내지 제6항 중의 어느 한 항에 있어서, B가 화학식 (2a), (2b) 또는 (2c)의 라디칼[여기서, (alk)는 직쇄 또는 측쇄 C2-C8알킬렌이며, (alk')는 1, 2-에틸렌이며, r은 2 또는 3이고, R2및 R2′는 각각 수소이며, R3는 모노하이드록시 치환된 C1-C4알킬이고, R4는 수소이다]인 화합물.7. The radical of claim 1, wherein B is a radical of formula (2a), (2b) or (2c), wherein (alk) is a straight or branched C 2 -C 8 alkylene, ( alk ') is 1, 2-ethylene, r is 2 or 3, R 2 and R 2 ′ are each hydrogen, R 3 is a monohydroxy substituted C 1 -C 4 alkyl and R 4 is hydrogen ]. 제1항 내지 제7항 중의 어느 한 항에 있어서, B가 화학식(2a)의 라디칼인 화합물.8. A compound according to any one of claims 1 to 7, wherein B is a radical of formula (2a). 제1항 내지 제8항 중의 어느 한 항에 있어서, B가 화학식(2a)의 라디칼[여기서, R2는 수소이고, (alk)는 직쇄 또는 측쇄 C2-C4알킬렌이며, R3은 모노하이드록시 치환된 C1-C4알킬이다]인 화합물.9. The compound of claim 1, wherein B is a radical of formula (2a) wherein R 2 is hydrogen, (alk) is a straight or branched C 2 -C 4 alkylene, and R 3 is Monohydroxy substituted C 1 -C 4 alkyl. 제1항에 있어서, 화학식(1a)의 화합물.The compound of formula 1a according to claim 1. 상기 화학식(1a)에서, X1및 X2는 동일하고 각 염소이며 R1및 R1'는 각각 수소이고, (R)n및 (R')m은 동일하며 각각 메틸, 메톡시 및 설포로 이루어진 그룹으로부터 선택된 0, 1 또는 2개의 동일하거나 상이한 라디칼이고, Y 및 Y'는 동일하며 각각 비닐 또는 β-설페이토에틸이고, B는 화학식(2a)의 라디칼이다.In formula (1a), X 1 and X 2 are the same and each chlorine and R 1 and R 1 ′ are each hydrogen, (R) n and (R ′) m are the same and are methyl, methoxy and sulfo, respectively. 0, 1 or 2 identical or different radicals selected from the group consisting of, Y and Y 'are the same and are each vinyl or β-sulfatoethyl and B is a radical of formula (2a). -NR2-(alk)-NR3- (2a)-NR 2- (alk) -NR 3- (2a) 상기 화학식(2a)에서, R2는 수소이고, (alk)는 직쇄 또는 측쇄 C2-C4알킬렌이며, R3은 모노하이드록시 치환된 C1-C4알킬이다.In formula (2a), R 2 is hydrogen, (alk) is straight or branched C 2 -C 4 alkylene, and R 3 is monohydroxy substituted C 1 -C 4 alkyl. 제10항에 있어서, B가 라디칼 -NH-CH2CH2-N(CH2CH2OH)-인 화합물.The compound of claim 10, wherein B is a radical —NH—CH 2 CH 2 —N (CH 2 CH 2 OH) —. 화학식(3a), (3b), (4a), (4b), (5a), (5b) 및 6의 화합물 약 1몰 당량을 서로 순서에 관계없이 각각 반응시킴을 포함하는, 제1항에 따르는 화학식(1)의 화합물의 제조방법.According to claim 1, comprising reacting about one molar equivalent of the compounds of formulas (3a), (3b), (4a), (4b), (5a), (5b), and 6 with each other in any order Process for the preparation of the compound of formula (1). 상기 화학식(3a), (3b), (4a), (4b), (5a), (5b) 및 (6)에서 B, (R)n, (R')m, n, m, R1, R1', X1,X2, Y, Y', p 및 q는 제1항에서 정의한 바와 같다.In Formulas (3a), (3b), (4a), (4b), (5a), (5b), and (6), B, (R) n , (R ') m , n, m, R 1 , R 1 ′, X 1 , X 2 , Y, Y ′, p and q are as defined in claim 1. 하이드록실 그룹 또는 질소를 함유하는 섬유재료를 염색 또는 날염하기 위한, 제1항 내지 제11항 중의 어느 한 항에 따르는 화학식(1)의 화합물의 용도.Use of a compound of formula (1) according to any one of claims 1 to 11 for dyeing or printing fibrous materials containing hydroxyl groups or nitrogen. 제13항에 있어서, 셀룰로오즈 섬유재료, 특히 면을 함유하는 섬유재료가 염색 또는 날염되는 용도.Use according to claim 13, wherein the cellulose fiber material, in particular cotton containing fiber material, is dyed or printed. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960054429A 1995-11-13 1996-11-15 Fiber-reactive dyes, a method for producing the same, and a dyeing or printing method using the same KR100460556B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US08/556,673 US5621045A (en) 1995-11-13 1995-11-13 Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber
US95-08/556,673 1995-11-13
CH03254/95 1995-11-16
CH325495 1995-11-16
CH03305/95 1995-11-22
CH330595 1995-11-22

Publications (2)

Publication Number Publication Date
KR970027220A true KR970027220A (en) 1997-06-24
KR100460556B1 KR100460556B1 (en) 2005-08-17

Family

ID=66321668

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960054429A KR100460556B1 (en) 1995-11-13 1996-11-15 Fiber-reactive dyes, a method for producing the same, and a dyeing or printing method using the same

Country Status (1)

Country Link
KR (1) KR100460556B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001063968A1 (en) * 2000-02-22 2001-08-30 Il Sung International Co., Ltd. Speaker system for personal computers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001063968A1 (en) * 2000-02-22 2001-08-30 Il Sung International Co., Ltd. Speaker system for personal computers

Also Published As

Publication number Publication date
KR100460556B1 (en) 2005-08-17

Similar Documents

Publication Publication Date Title
KR970059234A (en) Reactive dyes, preparation method and use thereof
KR950032498A (en) Black fiber reactive azo dye mixtures and their use for dyeing hydroxy- and / or carboxamido-containing fiber materials
KR940007285A (en) Process for preparing dyes on modified fiber materials using anionic textile dyes by ink spray printing technique
KR970070133A (en) Fiber reactive dyes, preparation method thereof and use thereof
TR199800059T1 (en) Dyestuff mixtures.
KR900013025A (en) Fiber reactive asymmetric dioxazine compounds, preparation method thereof and use thereof as fiber reactive dyes
KR940011587A (en) Phthalocyanine reactive dye mixture
KR970027220A (en) Fiber reactive dyes. Method of manufacture and use thereof
KR930013007A (en) Water-soluble fiber-reactive dyes, preparation method thereof and use thereof
ATE26315T1 (en) PROCESS FOR DYING DIFFERENTIAL-DYEING FIBERS.
KR880004045A (en) Reactive dyes, preparation method and use thereof
DE60209035D1 (en) FIBER-REACTIVE AZO-PURPOSES, THEIR PREPARATION AND THEIR USE
KR880007673A (en) Monoazo yellow compound, preparation method thereof, and dyeing or printing method of fibers using same
KR970027222A (en) Reactive dyes, preparation methods thereof and uses thereof
KR960034323A (en) Reactive dye mixture for navy shade
KR930021736A (en) Symmetric Azo Dye
JPS6012474B2 (en) Dye preparations for cellulose and cellulose-containing textile materials
TW375642B (en) Mixtures of monoazopyridone dyes and process for making the same
KR920000879A (en) Azo dyes prepared using 2-alkylamino-3-cyano-4,6-diaminopyridine as coupling component
KR960037774A (en) REACTIVE DYES FROM DIOX PHOTOGRAPHY, METHODS AND USES THEREOF
KR970021214A (en) Blue type disperse dye mixture
RU2003122195A (en) ANTHRAKHINE DYES, THEIR PRODUCTION AND APPLICATION
KR970006409A (en) Azo dyes, their preparation methods and uses
ATE209233T1 (en) WATER SOLUBLE REACTIVE DYE MIXTURES AND THEIR USE FOR DYEING
ATE347577T1 (en) POLYCYCLIC DYES

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20131030

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20141030

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee