KR970015639A - Olefin thermoplastic elastomer sheet, laminate comprising the sheet and uses thereof - Google Patents

Olefin thermoplastic elastomer sheet, laminate comprising the sheet and uses thereof Download PDF

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Publication number
KR970015639A
KR970015639A KR1019960041821A KR19960041821A KR970015639A KR 970015639 A KR970015639 A KR 970015639A KR 1019960041821 A KR1019960041821 A KR 1019960041821A KR 19960041821 A KR19960041821 A KR 19960041821A KR 970015639 A KR970015639 A KR 970015639A
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KR
South Korea
Prior art keywords
sheet
weight
thermoplastic elastomer
parts
laminate
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Application number
KR1019960041821A
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Korean (ko)
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KR100458977B1 (en
Inventor
마코토 마키노
다쓰오 하마나카
Original Assignee
고사이 아키오
스미토모가가쿠고교 가부시키가이샤
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Application filed by 고사이 아키오, 스미토모가가쿠고교 가부시키가이샤 filed Critical 고사이 아키오
Publication of KR970015639A publication Critical patent/KR970015639A/en
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Publication of KR100458977B1 publication Critical patent/KR100458977B1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/025Polyolefin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0278Polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/003Interior finishings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16Ethene-propene or ethene-propene-diene copolymers

Abstract

본 발명은 100℃에서의 무니 점도(Mooney viscosity, ML1+4100℃)가 5 내지 100이고 실질적으로 비공액 디엔을 함유하지 않는 올레핀계 중합체 고무(A) 40 내지 90중량%와 올레핀계 중합체(B) 60 내지 10중량%를 함유하는 혼합물 100중량부를 유기 과산화물 0.005 내지 0.5중량부 및 N,N′-m-페닐렌비스말레이미드 또는 디비닐벤젠 0.05 내지 4중량부의 존재하에 동적으로 열처리하여 수득할 수 있는 올레핀계 열가소성 탄성체를 포함하는 시이트에 관한 것이다. 당해 시이트는 내광성과 내열노화성이 우수하다. 당해 시이트를 포함하는 적중체 및 이의 용도도 또한 제공된다.The present invention relates to 40 to 90% by weight of olefinic polymer rubber (A) and an olefinic polymer having a Mooney viscosity (ML 1 + 4 100 ° C) at 100 ° C of 5 to 100 and substantially free of nonconjugated diene. (B) 100 parts by weight of the mixture containing 60 to 10% by weight dynamically heat-treated in the presence of 0.005 to 0.5 parts by weight of organic peroxide and 0.05 to 4 parts by weight of N, N'-m-phenylenebismaleimide or divinylbenzene A sheet comprising an olefinic thermoplastic elastomer obtainable. The sheet is excellent in light resistance and heat aging resistance. Also provided are hitters comprising the sheet and uses thereof.

Description

올레핀계 열가소성 탄성체 시이트, 당해 시이트를 포함하는 적층체 및 이의 용도Olefin thermoplastic elastomer sheet, laminate comprising the sheet and uses thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (4)

100℃에서의 무니 점도(Mooney viscosity, ML1+4100℃)가 5 내지 100이고 실질적으로 비공액 디엔을 함유하지 않는 올레핀계 중합체 고무(A) 40 내지 90중량%와 올레핀계 중합체(B) 60 내지 10중량%를 함유하는 혼합물 100중량부를 유기 과산화물 0.005 내지 0.5중량부 및 N,N′-m-페닐렌비스말레이미드 또는 디비닐벤젠 0.05 내지 4중량부의 존재하에 동적으로 열처리하여 수득할 수 있는 올레핀계 열가소성 탄성체를 포함하는 시이트.40 to 90% by weight of an olefinic polymer rubber (A) and an olefinic polymer (B) having a Mooney viscosity (ML 1 + 4 100 ° C) at 100 ° C of 5 to 100 and substantially free of nonconjugated diene. 100 parts by weight of a mixture containing 60 to 10% by weight can be obtained by dynamically heat treatment in the presence of 0.005 to 0.5 parts by weight of organic peroxide and 0.05 to 4 parts by weight of N, N'-m-phenylenebismaleimide or divinylbenzene. A sheet comprising an olefinic thermoplastic elastomer. 제1항에 있어서, 유기 과산화물이 2,5-디메틸-2,5-디(t-부틸퍼옥시)헥산 또는 2,5-디메틸-2,5-디(t-부틸퍼옥시)헥신-3인 시이트.The method of claim 1 wherein the organic peroxide is 2,5-dimethyl-2,5-di (t-butylperoxy) hexane or 2,5-dimethyl-2,5-di (t-butylperoxy) hexine-3 In sheet. 제1항에 따르는 올레핀계 열가소성 탄성체 시이트와 당해 탄성체 시이트 위에 적층되고 폴리에텔렌, 폴리프로필렌 및 폴리우레탄으로 이루어진 그룹으로부터 선택되는 물질의 발포제 또는 발포 시이트를 포함하는 적층제.A laminate comprising an olefinic thermoplastic elastomer sheet according to claim 1 and a foaming agent or foam sheet of a material laminated on the elastomeric sheet and selected from the group consisting of polyethylene, polypropylene and polyurethane. 제1항에 따르는 올레핀계 열가소성 탄성체 시이트 또는 제3항에 따르는 적층체를 포함하는 자동차용 내장재.An automotive interior comprising the olefinic thermoplastic elastomer sheet according to claim 1 or the laminate according to claim 3. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960041821A 1995-09-27 1996-09-24 Olefin series plastic elastomer sheets, laminates containing the sheets and interior materials for automobiles containing the sheets or laminates KR100458977B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP95-249442 1995-09-27
JP7249442A JPH0987394A (en) 1995-09-27 1995-09-27 Olefinic thermoplastic elastomer sheet, and laminate comprising the same and its use

Publications (2)

Publication Number Publication Date
KR970015639A true KR970015639A (en) 1997-04-28
KR100458977B1 KR100458977B1 (en) 2005-01-27

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KR1019960041821A KR100458977B1 (en) 1995-09-27 1996-09-24 Olefin series plastic elastomer sheets, laminates containing the sheets and interior materials for automobiles containing the sheets or laminates

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JP (1) JPH0987394A (en)
KR (1) KR100458977B1 (en)
DE (1) DE19639865A1 (en)
GB (1) GB2305666B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19801651A1 (en) * 1998-01-15 1999-07-22 Bayerische Motoren Werke Ag Process for laminating a plastic film on the back of a decorative material to be back-foamed afterwards
JP2000044743A (en) * 1998-07-28 2000-02-15 Sumitomo Chem Co Ltd Thermoplastic elastomer composition and laminate
DE60127477T2 (en) * 2000-02-09 2007-07-12 Mitsui Chemicals, Inc. Thermoplastic elastomer composition with fogging poor properties, their use and manufacturing process
EA016860B1 (en) * 2007-12-20 2012-08-30 ДСМ АйПи АССЕТС Б.В. Air bag container
EP2851394B1 (en) * 2013-09-19 2016-09-14 Arlanxeo Netherlands B.V. Vulcanizable rubber composition for low fogging articles

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2822815C2 (en) * 1977-05-26 1994-02-17 Mitsui Petrochemical Ind Process for the preparation of a partially vulcanized thermoplastic composition
FI98524C (en) * 1987-11-09 1997-07-10 Shell Oil Co Poly-1-butene resin composition and water-resistant wafer prepared therefrom
JP2658222B2 (en) * 1988-04-22 1997-09-30 住友化学工業株式会社 Thermoplastic elastomer composition and method for producing the same
KR920003034B1 (en) * 1988-06-21 1992-04-13 동양나이론 주식회사 Resin making material
JP2876031B2 (en) * 1990-04-13 1999-03-31 工業技術院長 Surface treatment method of thermoplastic elastomer molded article and coating method thereof
JPH05279524A (en) * 1992-03-31 1993-10-26 Sumitomo Chem Co Ltd Elastomer composition for light-resistant facing material and light-resistant facing material for industrial part comprising said composition
JP5742389B2 (en) * 2011-03-31 2015-07-01 凸版印刷株式会社 Method for correcting mask for EUV exposure and mask for EUV exposure

Also Published As

Publication number Publication date
KR100458977B1 (en) 2005-01-27
DE19639865A1 (en) 1997-04-03
GB2305666A (en) 1997-04-16
GB2305666B (en) 1997-12-24
GB9620214D0 (en) 1996-11-13
JPH0987394A (en) 1997-03-31

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