KR970006306A - Thiazolyl triazolothiazole derivatives - Google Patents

Thiazolyl triazolothiazole derivatives Download PDF

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KR970006306A
KR970006306A KR1019950020513A KR19950020513A KR970006306A KR 970006306 A KR970006306 A KR 970006306A KR 1019950020513 A KR1019950020513 A KR 1019950020513A KR 19950020513 A KR19950020513 A KR 19950020513A KR 970006306 A KR970006306 A KR 970006306A
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South Korea
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hydrogen
optionally substituted
compound
formula
different
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KR1019950020513A
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Korean (ko)
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KR0168979B1 (en
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서귀현
김영훈
강대필
김영희
백장훈
장만식
최완수
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김종인
영진약품공업 주식회사
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Priority to KR1019950020513A priority Critical patent/KR0168979B1/en
Priority to PCT/KR1996/000079 priority patent/WO1997003073A1/en
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D513/00Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04Ortho-condensed systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

본 발명은 항궤양효과가 탁월한 일반식(Ⅰ)로 표시되는 신규의 티아졸릴 트리아졸로티아졸 유도체 및 이의 약제학적으로 허용 가능한 산부가염, 그리고 이의 제조방법에 관한 것이다.The present invention relates to novel thiazolyl triazolothiazole derivatives represented by general formula (I) having excellent anti-ulcer effect, pharmaceutically acceptable acid addition salts thereof, and methods for preparing the same.

상기 식에서 R은 수소, 히드록시, C1-C6의 저급알킬, C1-C6의 저급알콕시, 치환될 수도 있는 페닐 또는 피리딘, 치환될 수도 있는 구아니디노기, 또는 NR4R5(R4및 R5는 서로 같거나 다른 것으로서 수소, C1-C6저급알킬, C3-C6시클로알킬, 치환될 수도 있는 페닐 또는 피리딘, C1-C6알콕시 C2-C6알킬, 페닐알킬이다)로 표시되는 아민기이고; R2및 R3는 서로 같거나 다른 것으로서 수소 또는 C1-C4저급알킬기이며; X와 Y는 서로 다른 것으로서 N과 CR6(R6는 수소, C1-C6저급알킬, 치환될 수도 있는 페닐이다)로 구성된다.Wherein R is hydrogen, hydroxy, C 1 -C 6 no holes that are of lower alkyl, C 1 -C 6 lower alkoxy, optionally substituted phenyl or pyridinyl, optionally substituted dino group, or NR 4 R 5 ( R 4 and R 5 are the same as or different from each other, hydrogen, C 1 -C 6 loweralkyl, C 3 -C 6 cycloalkyl, optionally substituted phenyl or pyridine, C 1 -C 6 alkoxy C 2 -C 6 alkyl, Phenyl group); R 2 and R 3 , which are the same as or different from each other, are hydrogen or a C 1 -C 4 loweralkyl group; X and Y are different and consist of N and CR 6 (R 6 is hydrogen, C 1 -C 6 loweralkyl, phenyl which may be substituted).

Description

티아졸릴 트리아졸로티아졸 유도체Thiazolyl triazolothiazole derivatives

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (3)

하기 일반식(Ⅰ)로 표시되는 신규의 티아졸릴 트리아졸로티아졸 유도체 및 이의 약제학적으로 허용 가능한 산부가염.Novel thiazolyl triazolothiazole derivatives represented by the following general formula (I) and pharmaceutically acceptable acid addition salts thereof. 상기 식에서, R는 수소, 히드록시, C1-C6의 저급알킬, C1-C6의 저급알콕시, 치환될 수도 있는 페닐 또는 피리딘, 치환될 수도 있는 구아니디노기, 또는 NR4R5(R4및 R5는 서로 같거나 다른 것으로서 수소, C1-C6저급알킬, C3-C6시클로알킬, 치환될 수도 있는 페닐 또는 피리딘, C1-C6알콕시 C2-C6알킬, 페닐알킬이다)로 표시되는 아민기이고; R2및 R3는 서로 같거나 다른 것으로서 수소 또는 C1-C|4저급알킬기이며; X와 Y는 서로 다른 것으로서 N과 CR6(R6는 수소, C1-C6저급알킬, 치환될 수도 있는 페닐이다)로 구성된다.Wherein R is hydrogen, hydroxy, C 1 -C 6 lower alkyl, C 1 -C 6 lower alkoxy, optionally substituted phenyl or pyridine, optionally substituted guanidino group, or NR 4 R 5 (R 4 and R 5 are the same as or different from each other, hydrogen, C 1 -C 6 loweralkyl, C 3 -C 6 cycloalkyl, optionally substituted phenyl or pyridine, C 1 -C 6 alkoxy C 2 -C 6 alkyl Phenylalkyl); R 2 and R 3 are the same as or different from each other and are hydrogen or C 1 -C | 4 lower alkyl group; X and Y are different and consist of N and CR 6 (R 6 is hydrogen, C 1 -C 6 loweralkyl, phenyl which may be substituted). 제1항에 있어서, R은 C1-C6의 저급알킬, 치환될 수도 있는 페닐 또는 피리딘, 치환될 수도 있는 구아니디노기, 또는 NR4R5로 표시되는 아민기이고; R4및 R5는 서로 같거나 다른 것으로서 수소, C1-C6저급알킬, C3-C6시클로알킬, 치환될 수도 있는 페닐 또는 피리딘, C1-C6알콕시 C2-C6알킬, 페닐알킬기이고; R2는 수소이고; R3는 메틸이고; X는 수소 또는 메틸이고; Y는 N임을 특징으로 하는 일반식(Ⅰ)의 화합물 및 이의 약제학적으로 허용가능한 산부가염.The compound of claim 1, wherein R is C 1 -C 6 lower alkyl, optionally substituted phenyl or pyridine, optionally substituted guanidino group, or amine group represented by NR 4 R 5 ; R 4 and R 5 are the same as or different from each other, hydrogen, C 1 -C 6 loweralkyl, C 3 -C 6 cycloalkyl, optionally substituted phenyl or pyridine, C 1 -C 6 alkoxy C 2 -C 6 alkyl, Phenylalkyl group; R 2 is hydrogen; R 3 is methyl; X is hydrogen or methyl; Y is N, and a pharmaceutically acceptable acid addition salt thereof. 하기 일반식(Ⅱ)의 화합물을 하기 일반식(Ⅲ)의 화합물과 반응시켜 하기 일반식(Ⅳ)의 화합물 또는 그의 염을 얻는 단계; 상기 단계에서 얻은 일반식(Ⅳ)의 화합물 또는 그의 염을 할로겐화시켜 하기 일반식(Ⅴ)의 화합물 또는 그의 염을 얻는 단계; 및 상기 단계에서 얻은 일반식(Ⅴ)의 화합물 또는 그의 염을 하기 일반식 (Ⅵ)의 티오화합물과 반응시켜 일반식(Ⅰ)의 화합물 또는 그의 염을 얻는 단계를 포함함을 특징으로 하는 일반식(Ⅰ)로 표시되는 신규한 티아졸릴 트리아졸로 티아졸 유도체 및 그의 약제학적으로 허용가능한 산부감의 제조방법.Reacting a compound of formula (II) with a compound of formula (III) to obtain a compound of formula (IV) or a salt thereof; Halogenating the compound of formula (IV) or a salt thereof obtained in the above step to obtain a compound of formula (V) or a salt thereof; And reacting a compound of formula (V) or a salt thereof obtained in the step with a thio compound of formula (VI) to obtain a compound of formula (I) or a salt thereof. A novel thiazolyl triazolo thiazole derivative represented by (I) and a method for producing a pharmaceutically acceptable acid value thereof. 상기 식에서 R는 수소, 히드록시, C1-C6의 저급알킬, C1-C6의 저급알콕시, 치환될 수도 있는 페닐 또는 피리딘, 치환될 수도 있는 구아니디노기, 또는 NR4R5(R4및 R5는 서로 같거나 다른 것으로서 수소, C1-C6저급알킬, C3-C|6시클로알킬, 치환될 수도 있는 페닐 또는 피리딘, C1-C6알콕시 C2-C6알킬, 페닐알킬이다)로 표시되는 아민기이고; R2및 R3는 서로 같거나 다른 것으로서 수소 또는 C1-C4저급알킬기이며; X와 Y는 서로 다른 것으로서 N과 CR6(R6는 수소, C1-C6저급알킬, 치환될 수도 있는 페닐이다)로 구성되고; 그리고 Z는 반응기로서 염소 또는 브롬과 같은 할로겐원자이다.Wherein R is hydrogen, hydroxy, C 1 -C 6 lower alkyl, C 1 -C 6 lower alkoxy, optionally substituted phenyl or pyridine, optionally substituted guanidino group, or NR 4 R 5 ( R 4 and R 5 are the same as or different from each other, hydrogen, C 1 -C 6 loweralkyl, C 3 -C | 6 cycloalkyl, optionally substituted phenyl or pyridine, C 1 -C 6 alkoxy C 2 -C 6 alkyl Phenylalkyl); R 2 and R 3 , which are the same as or different from each other, are hydrogen or a C 1 -C 4 loweralkyl group; X and Y are different and consist of N and CR 6 (R 6 is hydrogen, C 1 -C 6 loweralkyl, phenyl which may be substituted); And Z is a halogen atom such as chlorine or bromine as the reactor. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950020513A 1995-07-12 1995-07-12 Thiazolyl triazolothiazole derivatives KR0168979B1 (en)

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KR1019950020513A KR0168979B1 (en) 1995-07-12 1995-07-12 Thiazolyl triazolothiazole derivatives
PCT/KR1996/000079 WO1997003073A1 (en) 1995-07-12 1996-06-01 Thiazolyl triazolothiazole derivatives

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KR1019950020513A KR0168979B1 (en) 1995-07-12 1995-07-12 Thiazolyl triazolothiazole derivatives

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AU3740101A (en) 2000-03-01 2001-09-12 Janssen Pharmaceutica Nv 2,4-disubstituted thiazolyl derivatives
US7357989B2 (en) * 2000-08-07 2008-04-15 Osram Opto Semiconductors Gmbh Di(het)arylaminothiazole derivatives and their use in organic light-emitting diodes(OLEDs) and organic photovoltaic components
EP2905336A1 (en) 2007-03-29 2015-08-12 Alnylam Pharmaceuticals Inc. Compositions and methods for inhibiting expression of a gene from the ebola

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BE755028A (en) * 1969-08-19 1971-02-19 Bayer Ag NEW ESTERS OF TRIAZOLO-THIAZOLE- (THIONO) -PHOSPHORIC, -PHOSPHONIC AND -PHOSPHINIC ACIDS, THEIR PREPARATION PROCESS AND THEIR APPLICATION FOR THE CONTROL OF INSECTS AND MITES
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