KR970002050B1 - The composition of soaps - Google Patents
The composition of soaps Download PDFInfo
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- KR970002050B1 KR970002050B1 KR1019940032998A KR19940032998A KR970002050B1 KR 970002050 B1 KR970002050 B1 KR 970002050B1 KR 1019940032998 A KR1019940032998 A KR 1019940032998A KR 19940032998 A KR19940032998 A KR 19940032998A KR 970002050 B1 KR970002050 B1 KR 970002050B1
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- South Korea
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- weight
- soap
- polyquaternium
- carbomer
- cosmetic
- Prior art date
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- 239000000344 soap Substances 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 19
- 229960001631 carbomer Drugs 0.000 claims abstract description 18
- 239000002537 cosmetic Substances 0.000 claims description 16
- 229920000289 Polyquaternium Polymers 0.000 claims description 15
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000003860 storage Methods 0.000 abstract description 6
- 230000003796 beauty Effects 0.000 abstract 1
- 230000003020 moisturizing effect Effects 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 230000007774 longterm Effects 0.000 description 5
- 210000003491 skin Anatomy 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 235000019482 Palm oil Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 241001116389 Aloe Species 0.000 description 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 1
- 240000006891 Artemisia vulgaris Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 244000131316 Panax pseudoginseng Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C11D2111/10—
Abstract
Description
본 발명은 카보머(폴리아크릴릭에시드), 폴리쿼터니움(아크릴릭에시드와 디메칠 디아릴 암모니움 클로라이드의 중합체 : 이하 폴리쿼터니움-22라 명칭, 및 아크릴릭 아마이l드와 디메칠 디아릴 암모니움 클로라이드의 중합체 : 이하 폴리쿼터니움-7로 명칭)을 함유하는 화장비누 조성물에 관한 것이다. 더욱 상세하게는, 본 발명은 물 분산성이 개선된 카보머 및 폴리쿼터니움을 함유하여 비누의 사용감을 개선하고, 기포 안정성, 보습성 및 작업성이 우수하고, 장기 보관에 따른 안정성이 우수한 화장비누 조성물에 관한 것이다.The present invention relates to carbomer (polyacrylic acid), polyquaternium (polymer of acrylic acid and dimethyl diaryl ammonium chloride: hereinafter referred to as polyquaternium-22, and acrylic amyl and dimethyl diaryl ammonium chloride Polymers: hereinafter referred to as Polyquaternium-7). More specifically, the present invention contains carbomer and polyquaternium with improved water dispersibility to improve the feel of soap, excellent bubble stability, moisturizing and workability, and excellent makeup stability for long-term storage It relates to a soap composition.
화장비누는 일반적으로 지방산을 가성소다로 중화하여 제조하는데, 이러한 중화반응 중에 미량의 미반응 유리알칼리가 남아있게 되고, 또한 비누 사용중에 비누의 일부가 물에 해리되어 유리알칼리가 발생하게 된다. 따라서, 비누의 과도한 사용은 피지성분의 탈지 및 각질층의 탈각등으로 피부가 건조하게 되고 거칠어지는 원인이 될 수 있다.Cosmetic soaps are generally prepared by neutralizing fatty acids with caustic soda. During this neutralization reaction, a small amount of unreacted free alkali remains, and some of the soap is dissociated in water to generate free alkali during use of the soap. Therefore, excessive use of soap may cause the skin to become dry and rough due to degreasing of the sebum component and deshelling of the stratum corneum.
이러한 단점을 보완하기 위하여, 여러가지 피부 보습성분 및 미용성분이 함유된 비누가 연구되어 왔다. 또한, 일반적으로 비누를 찬물에서 사용하면 표면이 거칠고 점이 있는 등 사용감이 좋지 않고, 기포도 잘나지 않는 단점이 있다. 이러한 단점을 해결하기 위하여, 보습성분, 기포증진제 및 사용감 개선을 위한 여러 첨가제가 연구되어 왔다. 피부 보습성분 및 미용성분은 고급지방산, 고급지방알콜, 동식물유지, 리놀린 유도체등의 과지방제와 인삼, 오이, 알로에, 쑥 등의 식물추출액이 있는데, 이러한 것들은 비누사용시 수용액에 분산되어 피부에 흡착되기 때문에 세정후 비누의 감촉을 좋게하고 미용효과도 있으나, 미용효과를 충분히 제공하기 위해서는 첨가량이 많아야 하는 단점과 다량 첨가에 의해 장기간 보관시 안정성이 좋지 않게 되고 물성이 나빠지는 단점이 있다.In order to compensate for this disadvantage, soaps containing various skin moisturizing ingredients and cosmetic ingredients have been studied. In addition, in general, when the soap is used in cold water, there is a disadvantage that the feeling is not good, such as the surface is rough, there are spots, bubbles are not good. In order to solve these disadvantages, moisturizing ingredients, bubble enhancers and various additives for improving the feeling have been studied. Skin moisturizing ingredients and cosmetic ingredients include high fat acids, high fat alcohols, animal and vegetable fats and oils, linoleine derivatives and overfat agents and plant extracts such as ginseng, cucumber, aloe and mugwort. Because of this, after washing, the texture of soap is improved and there is a cosmetic effect. However, in order to provide a sufficient cosmetic effect, the amount of addition must be large and there is a disadvantage in that the stability becomes poor and the physical properties deteriorate for a long period of time by adding a large amount.
이러한 문제점들을 해결하기 위해 비누에 여러가지 수용성 폴리머를 첨가하는 방법이 연구되었는데, 예를 들면, 비누에 카보머를 첨가하여 사용감을 개선하고 유리알칼리를 제거하여 피부 자극을 줄이는 방법이 제시되었다. 그러나, 이러한 카보머는 고형비누에 첨가시 과량 첨가가 어렵고, 과량 첨가에 따라 일광 안정성이 나빠지며, 경수에서 사용시 사용감도 현저히 저하되는 문제가 있다.In order to solve these problems, a method of adding various water-soluble polymers to soap has been studied. For example, a method of adding carbomer to soap to improve the feeling of use and removing free alkali has been suggested to reduce skin irritation. However, such carbomer is difficult to add excessively when added to the solid soap, the daylight stability worsens according to the excessive addition, there is a problem that the use feeling in hard water is also significantly reduced.
본 발명자들은 이러한 문제를 해결하기 위하여 연구하던 중 카보머에 폴리쿼터니움을 혼합하여 비누에 첨가하면 사용감이 우수하고, 피부자극이 줄어들면서 피부보습, 작업성 및 장기보관에 따른 안정성도 우수하며, 경수에서의 사용감도 개선된다는 놀라운 사실을 밝혀냈다.The inventors of the present invention while studying to solve this problem is mixed with polyquaternium in carbomer and added to the soap, the feeling of use is excellent, the skin stimulation is reduced and the stability according to the skin moisturizing, workability and long-term storage, It also revealed a surprising improvement in the feel of hard water.
본 발명은 카보머 0.01 내지 5중량%와 폴리쿼터니움 0.01 내지 10중량%를 1 : 1 내지 1 : 5의 중량비로 혼합하여 전체 비누중에 0.02 내지 12중량% 함유시킨 것을 특징으로 하는 화장비누 조성물에 관한 것이다.The present invention provides a cosmetic soap composition comprising 0.01 to 5% by weight of carbomer and 0.01 to 10% by weight of polyquaternium in a weight ratio of 1: 1 to 1: 5 and containing 0.02 to 12% by weight of the total soap. It is about.
본 발명에 사용된 카보머와 폴리쿼터니움은 다음과 같은 식을 갖는다.The carbomer and polyquaternium used in the present invention have the following formula.
상기 식에서, 카보머의 분자량은 1.5 내지 4.0×106이고, 폴리쿼터니움 22의 분자량은 1.1 내지 1.9× 106이며, 폴리쿼터니움 7의 분자량은 4.3 내지 7.9×106이다.Wherein the molecular weight of the carbomer is 1.5 to 4.0 × 10 6 , the molecular weight of polyquaternium 22 is 1.1 to 1.9 × 10 6 , and the molecular weight of polyquaternium 7 is 4.3 to 7.9 × 10 6 .
본 발명의 화장비누 조성물에서 카보머와 폴리쿼터니움 혼합물의 함량은 조성물 전체중에 0.02 내지 12중량%가 적당하다. 이 혼합물을 0.02 미만 사용할 경우에는 작업성 및 안정성은 우수하지만, 사용감 및 보습효과가 낮으며, 12중량% 이상 사용할 경우에는 사용감 및 보습효과는 우수하지만 작업성이 좋지 않으며 경시 안정성이 저하되는 단점이 있다.The content of the carbomer and polyquaternium mixture in the cosmetic soap composition of the present invention is appropriately 0.02 to 12% by weight in the total composition. When the mixture is used less than 0.02, the workability and stability are excellent, but the feeling and moisturizing effect is low, and when using more than 12% by weight, the feeling and moisturizing effect is excellent, but the workability is poor and the stability over time decreases. have.
본 발명의 화장비누 조성물은 사용시 사용감 및 기포력이 우수하고 보습효과 및 장기간 보관시에도 안정성이 우수하다. 본 발명의 화장비누 조성물에 있어서 비누 베이스는 지방산의 알칼리 금속비누이다. 지방산의 알칼리 금속비누는 탄소 원자가 8 내지 20개인 지방산의 알칼리 금속염이며, 여기서 지방산은 야자유, 팜유, 대두유, 파마자유, 올리브유, 팜핵유 등의 식물 유지와 우지, 돈지, 양지, 어유 등의 동물 유지로부터 얻어지고, 알칼리 금속은 나트륨, 칼륨 등을 단독 또는 혼합 사용하여 지방산과 중화시켜 제조한다.The cosmetic soap composition of the present invention has excellent feeling of use and foaming power, excellent moisturizing effect and stability even during long-term storage. In the cosmetic soap composition of the present invention, the soap base is an alkali metal soap of a fatty acid. Alkali metal soaps of fatty acids are alkali metal salts of fatty acids having 8 to 20 carbon atoms, wherein the fatty acids are oils and fats of plants such as palm oil, palm oil, soybean oil, perm oil, olive oil, palm kernel oil, and animal fats and oils such as tallow, pig oil, sun palm oil and fish oil. And alkali metals are prepared by neutralizing with fatty acids using solely or mixed sodium, potassium and the like.
본 발명의 화장비누 조성물은 통상적으로 화장비누에 사용되는 성분을 함유할 수 있다. 비누 베이스에는 일반적으로 수분이 5 내지 20중량% 함유되어 있으며, 산화방지제 및 향료, 염료, 기타 첨가물을 첨가할 수 있다.The cosmetic soap composition of the present invention may contain components commonly used in cosmetic soap. Soap bases generally contain from 5 to 20% by weight of moisture, and antioxidants and flavorings, dyes, and other additives may be added.
카보머와 폴리쿼터니움은 화장비누 소자와 혼합기에서 혼합하여 첨가할 수 있고 비누 성형시 연속적으로 첨가할 수도 있다. 비누의 제조방법은 통상적인 비누의 제조방법으로 혼합 및 압출, 성형하여 수행한다.Carbomer and polyquaternium may be added by mixing in a cosmetic soap element and a mixer, or may be added continuously during soap molding. The soap manufacturing method is performed by mixing, extruding and molding in a conventional soap manufacturing method.
이하, 실시예와 비교예를 들어 본 발명을 설명하지만, 이들 실시예가 본 발명의 기술적 범위를 한정하는 것은 아니다.Hereinafter, although an Example and a comparative example are given and this invention is demonstrated, these Examples do not limit the technical scope of this invention.
[실시예 1]Example 1
화장비누 소지 98.21중량%(수분 12중량% 포함)에 에틸렌디아민 테트라아세트산 0.05중량%, 부틸레이티드 하이드록시톨루엔 0.01중량%, 향료 1.50중량%, 산화티탄 0.20중량%, 염료 0.01중량%, 카보머 0.01중량% 및 폴리쿼터니움 0.01중량%를 혼합기에서 혼합한 후, 압출, 성형, 형타하여 비누를 제조하였다.To 98.21% by weight of cosmetic soap (including 12% by weight of water), 0.05% by weight of ethylenediamine tetraacetic acid, 0.01% by weight of butylated hydroxytoluene, 1.50% by weight of fragrance, 0.20% by weight of titanium oxide, 0.01% by weight of dye, carbomer Soap was prepared by mixing 0.01% by weight and 0.01% by weight of polyquaternium in a mixer, followed by extrusion, molding and mold.
[비교예 1]Comparative Example 1
화장비누 소지 98.23중량%(수분 12중량% 포함)에 에틸렌디아민 테트라아세트산 0.05중량%, 부틸레이티드 하이드록시톨루엔 0.01중량%, 향료 1.50중량%, 산화티탄 0.20중량%, 염료 0.01중량%를 혼합기에서 혼합한 후, 압출 성형, 형타하여 비누를 제조하였다.To 98.23% by weight of cosmetic soap (including 12% by weight of water), 0.05% by weight of ethylenediamine tetraacetic acid, 0.01% by weight of butylated hydroxytoluene, 1.50% by weight of fragrance, 0.20% by weight of titanium oxide, and 0.01% by weight of dye in a mixer After mixing, extrusion and molding were performed to prepare a soap.
실시예 2 내지 6 및 비교예 2 내지 6의 하기 표 1에 나타낸 물질들은 첨가하여, 실시예 1의 제조방법과 동일한 방법으로 비누를 제조하였다.The materials shown in Table 1 of Examples 2 to 6 and Comparative Examples 2 to 6 were added to prepare soaps in the same manner as in Example 1.
상기 실시예 1 내지 6 및 비교예 1 내지 6에서 제조한 비누의 사용감, 기포도, 작업성, 40℃에서의 안정성 및 보습력을 다음과 같이 시험하였다.The usability, foamability, workability, stability and moisturizing power of the soaps prepared in Examples 1 to 6 and Comparative Examples 1 to 6 were tested as follows.
(1) 사용감 시험(1) feeling test
20명의 사용자에게 동일한 조건으로 사용하게 하여, 사용중의 매끄러움성 및 사용감을 비교평가하여 20명의 평균값을 구하였다.Twenty users were used under the same conditions, and the average value of 20 people was obtained by comparing and evaluating the smoothness and the feeling of use.
◎ : 아주 우수◎: very good
○ : 우수○: excellent
△ : 보통△: normal
× : 나쁨×: bad
×× : 아주 나쁨××: very bad
(2) 작업성 시험(2) workability test
상기 실시예 및 비교예에서 제조된 비누에 대해 작업성을 시험하고 다음과 같이 판정하였다.The soap prepared in the above Examples and Comparative Examples was tested for workability and determined as follows.
◎ : 아주 우수◎: very good
○ : 우수○: excellent
△ : 보통△: normal
× : 나쁨×: bad
×× : 아주 나쁨××: very bad
(3) 기포도 시험(3) Bubble Test
20명의 사용자에게 동일한 조건으로 사용하게 하여, 비누의 기포도를 비교평가하여 20명의 평균값을 구하였다.Twenty users were used under the same conditions, and the average bubble value of 20 people was obtained by comparing and evaluating the bubble level of the soap.
◎ : 기포가 아주 풍부함◎: Very rich bubble
○ : 기포가 풍부함○: rich bubbles
△ : 보통△: normal
× : 기포가 적음×: less bubbles
×× : 기포가 아주 적음××: very few bubbles
(4) 40℃에서의 안정성 시험(4) Stability test at 40 ° C
상기 실시예 및 비교예에서 제조된 비누를 40℃ 항온조에서 1개월간 보관한 후, 변색 및 변취 정도를 시험하고 다음과 같이 판정하였다.After the soaps prepared in Examples and Comparative Examples were stored in a 40 ° C. thermostat for one month, the degree of discoloration and odor was tested and determined as follows.
◎ : 아주 우수◎: very good
○ : 우수○: excellent
△ : 보통△: normal
× : 약간 변색×: slightly discolored
×× : 변색 및 변취가 심함××: discoloration and bad smell
(5) 보습력 시험(5) moisture retention test
상기 실시예 및 비교예에서 제조한 비누를 증류수로 희석하여 5% 수용액을 만들고 이 수용액 0.1ml를 취해 팔 안쪽에 가로 5cm × 세로 5cm의 크기로 도포한 후, 스키콘 200(Skicon 200)을 이용하여 시간 경과에 따른 수분 손실을 측정하였다. 용액을 도포한 직후를 100으로 하고 도포전을 40으로 하여 시간경과에 따른 수분 손실을 구하였다. 실시예와 비교예의 비누 조성물에 대한 사용감, 작업성, 기포도, 보습효과 및 40℃ 안정성을 측정한 결과는 다음 표 2 및 3에 나타내었다.The soaps prepared in Examples and Comparative Examples were diluted with distilled water to make a 5% aqueous solution, and 0.1 ml of the aqueous solution was applied to the inside of the arm in a size of 5 cm x 5 cm, and then used skicon 200. Moisture loss was measured over time. Immediately after the solution was applied, the amount was set to 100 and before the coating was made to 40 to determine moisture loss over time. The results of measuring the usability, workability, foaming degree, moisturizing effect and 40 ° C. stability for the soap compositions of Examples and Comparative Examples are shown in Tables 2 and 3 below.
상기 표 2 및 표 3에서 보는 바와 같이, 폴리쿼터니움과 카보머를 혼합해 12중량% 초과 사용할 경우, 사용감 및 보습효과는 아주 우수하지만 작업성과 40℃ 안정성이 좋지 않고, 0.02중량% 미만 사용할 경우에는 작업성 및 40℃ 안정성은 우수하지만 사용감 및 보습효과를 느낄 수 없었다. 또한, 카보머를 5중량% 이상 초과 사용할 경우, 작업성 및 40℃ 안정성이 현저히 저하되는 것을 확인할 수 있었다. 따라서 사용감, 보습효과 및 장기 보관시 안정성이 우수하면서 작업성이 양호한 비누를 제조하기 위해서는, 카보머와 폴리쿼터니움을 1:1 내지 1:5의 비율로 혼합하여 바람직하게는 0.02 내지 12중량%, 더욱 바람직하게는 0.1 내지 5중량%를 사용하는 것이 작업성 및 장기 보관시의 안정성을 위해서 좋다.As shown in Table 2 and Table 3, when mixed with more than 12% by weight of polyquaternium and carbomer, the use and moisturizing effect is very good, but the workability and 40 ℃ stability is not good, if less than 0.02% by weight There is excellent workability and stability at 40 ℃ but could not feel the feeling of use and moisturizing effect. In addition, when the carbomer is used in excess of 5% by weight, it was confirmed that workability and stability at 40 ° C are significantly lowered. Therefore, in order to prepare a soap having excellent usability, moisturizing effect and long-term storage stability and good workability, carbomer and polyquaternium are mixed at a ratio of 1: 1 to 1: 5, preferably 0.02 to 12% by weight. More preferably, 0.1 to 5% by weight is used for workability and stability in long term storage.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940032998A KR970002050B1 (en) | 1994-12-06 | 1994-12-06 | The composition of soaps |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940032998A KR970002050B1 (en) | 1994-12-06 | 1994-12-06 | The composition of soaps |
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| Publication Number | Publication Date |
|---|---|
| KR960022993A KR960022993A (en) | 1996-07-18 |
| KR970002050B1 true KR970002050B1 (en) | 1997-02-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1019940032998A KR970002050B1 (en) | 1994-12-06 | 1994-12-06 | The composition of soaps |
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| Country | Link |
|---|---|
| KR (1) | KR970002050B1 (en) |
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