KR960705540A - ULTRA MILD LATHERING PERSONAL CLEANSING COMPOSITION - Google Patents

ULTRA MILD LATHERING PERSONAL CLEANSING COMPOSITION

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KR960705540A
KR960705540A KR1019960702748A KR19960702748A KR960705540A KR 960705540 A KR960705540 A KR 960705540A KR 1019960702748 A KR1019960702748 A KR 1019960702748A KR 19960702748 A KR19960702748 A KR 19960702748A KR 960705540 A KR960705540 A KR 960705540A
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parts
surfactant
alkyl
coom
hydrogen
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KR1019960702748A
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Korean (ko)
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크리스토퍼 알렌 푸르만
챨스 케빈 쉘
티모시 제임스 웰치
존 죠셉 다미아노
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제이코버스 코넬리스 레이서
더 프록터 앤드 갬블 캄파니
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Publication of KR960705540A publication Critical patent/KR960705540A/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22—Gas releasing
    • A61K2800/222—Effervescent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/70—Biological properties of the composition as a whole
    • A61K2800/72—Hypo-allergenic

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 (a) 약 2.0 이상의 평균 에톡시화도를 갖는 알킬 에톡시화된 설페이트 음이온성 계면활성제 약 3내지 약 10중량부; (b) 베타인 계면활성제, 이미다졸린 계면활성제, 아미노알카노에이트 계면활성제, 이미노디알카노에이트 계면활성제 및 이들의 혼합물로 구성된 그룹중에서 선택된 양쪽성 계면활성제 약 3내지 약 10부; (c) N-아실 아미노산 계면활성제 또는 그의 염 약 0.1 내지 약 3중량부; (d) 양이온성 셀룰로스에테르 유도체 약 0.01 내지 약 0.5 중량부를 포함하고, 저자극성 및 거품 발생 특성이 개선된 액체 피부 세정 조성물에 관하여 개시한다.(A) about 3 to about 10 parts by weight of an alkyl ethoxylated sulfate anionic surfactant having an average degree of ethoxylation of at least about 2.0; (b) about 3 to about 10 parts of an amphoteric surfactant selected from the group consisting of betaine surfactant, imidazoline surfactant, aminoalkanoate surfactant, iminodialkanoate surfactant, and mixtures thereof; (c) about 0.1 to about 3 parts by weight of an N-acyl amino acid surfactant or salt thereof; (d) Disclosed is a liquid skin cleansing composition comprising from about 0.01 to about 0.5 parts by weight of a cationic cellulose ether derivative and having improved hypoallergenic and foaming properties.

Description

초 저자극성의 개인용 거품 발생 세정 조성물(ULTRA MILD LATHERING PERSONAL CLEANSING COMPOSITION)ULTRA MILD LATHERING PERSONAL CLEANSING COMPOSITION

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

(a) 약 2.0 이상의 평균 에톡시화도를 갖는 알킬 에톡시화된 설페이트 음이온성 계면활성제 약 3내지 약 10중량부; (b) 메타인 계면활성제, 이미다졸린 계면활성제, 아미노알카노에이트 계면활성제, 이미노디알카노에이트 계면활성제 및 이들의 혼합물로 구성된 그룹중에서 선택된 양쪽성 계면활성제 약 3내지 약 10부; (c) N-아실 아미노산 계면활성제 또는 그의 염 약 0.1 내지 약 3중량부; (d) 양이온성 셀룰로스에테르 유도체 약 0.01 내지 약 0.5 중량부; 및 (e) 물 50 내지 94부를 포함하는 저자극성 개인용 세정 조성물.(a) about 3 to about 10 parts by weight of an alkyl ethoxylated sulfate anionic surfactant having an average degree of ethoxylation of at least about 2.0; (b) about 3 to about 10 parts of an amphoteric surfactant selected from the group consisting of a metaine surfactant, an imidazoline surfactant, an aminoalkanoate surfactant, an iminodialkanoate surfactant, and mixtures thereof; (c) about 0.1 to about 3 parts by weight of an N-acyl amino acid surfactant or salt thereof; (d) about 0.01 to about 0.5 parts by weight of cationic cellulose ether derivative; And (e) 50 to 94 parts of water. 제1항에 있어서, (a) 약 2내지 약 12개의 평균 에톡시화도를 갖는 상기 알킬 에톡시화된 설페이트 음이온성 계면활성제 약 4 내지 약 8부; (b) 하기 (i) 내지 (iv)로 구성된 그룹중에서 선택된 양쪽성 계면활성제 약 4내지 약 8부; (i) 하기 일반식의 베타인 계면활성제;The composition of claim 1, comprising: (a) about 4 to about 8 parts of said alkyl ethoxylated sulfate anionic surfactant having an average degree of ethoxylation of about 2 to about 12; (b) about 4 to about 8 parts of an amphoteric surfactant selected from the group consisting of (i) to (iv); (i) betaine surfactants of the general formula: [상기 식에서, R1은 COOM 및로 구성된 그룹중에서 선택된 일원이고, R2는 저급 알킬 또는 하이드록시알킬이고, R3는 저급 알킬 또는 하이드록시알킬이고, R4는 수소 및 저급 알킬로 구성된 그룹중에서 선택된 일원이고, R5는 고급 알킬 또는 알케닐이고, Y는 저급 알킬(C1내지 C4)이고, m은 2내지 7의 정수이고, n은 1또는 0이고, M은 수소 또는 양이온임]; (ii) 하기 일반식 이미다졸린 계면활성제;[Wherein, R 1 is COOM and A member selected from the group consisting of R 2 is lower alkyl or hydroxyalkyl, R 3 is lower alkyl or hydroxyalkyl, R 4 is a member selected from the group consisting of hydrogen and lower alkyl, and R 5 is higher alkyl Or alkenyl, Y is lower alkyl (C 1 to C 4 ), m is an integer from 2 to 7, n is 1 or 0, and M is hydrogen or cation; (ii) the following general formula imidazoline surfactants; [상기 식에서, R1은 C8내지 C22알킬 또는 알케닐이고, R2는 수소 또는 CH2CO2M이고, R3는 CH2CH2OH 또는 CH2CH2OCH2CH2COOM이고, R4는 수소, CH2CH2OH 또는 CH2CH2OCH2CH2COOM이고, Z는 CO2M 또는 CH2CO2M이고, n은 2또는 3이고, M은 수소 또는 양이온임]; 및 (iii) 일반식 R-NH(CH2)nCOOM의 아미노알카노에이트, 및 일반식 R-N〔(CH2)mCOOM〕2아미노디알카노에이트 [상기 식에서 n및 m은 1 내지 4이고, R은 C8내지 C22알킬 또는 알케닐이고, M은 수소, 또는 알칼리 또는 알칼리금속임]; 및 (iv) 이들의 혼합물; (c) 하기 일반식의 N-아실아미노산 계면활성제 또는 이들의 염 약 0.25 내지 약 1중량부;[Wherein R 1 is C 8 to C 22 alkyl or alkenyl, R 2 is hydrogen or CH 2 CO 2 M, R 3 is CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CH 2 COOM, R 4 is hydrogen, CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CH 2 COOM, Z is CO 2 M or CH 2 CO 2 M, n is 2 or 3 and M is hydrogen or cation; And (iii) aminoalkanoates of the general formula R-NH (CH 2 ) n COOM, and general amino acids RN [(CH 2 ) m COOM] 2 aminodialkanoates wherein n and m are 1 to 4, R is C 8 to C 22 alkyl or alkenyl and M is hydrogen or an alkali or alkali metal; And (iv) mixtures thereof; (c) about 0.25 to about 1 part by weight of an N-acylamino acid surfactant or salt thereof of the formula: [상기 식에서, R1은 C8내지 C24알킬 또는 알케닐이고, R2는 -H, C1내지 C4알킬, 페닐, 또는 -CH2COOM 이고, R3는 -CR4 2이고, n은 1내지 4이고, R4는 H, C1내지 C6알킬 또는 C1내지 C6알킬에스테르이고, M은 H 또는 양이온, 또는 이들의 혼합물임]; (d) 양이온성 셀룰로스 에테르 유도체 약 0.02 내지 약 0.2 부 및 (e) 물 약 75 내지 약 90부를 포함하며, 이때 상기 (a) 및 (b)가 약 2:1 내지 약 1:1.5의 몰비를 갖는 저자극성의 개인용 액체 세정 조성물.[Wherein R 1 is C 8 to C 24 alkyl or alkenyl, R 2 is —H, C 1 to C 4 alkyl, phenyl, or —CH 2 COOM, R 3 is —CR 4 2 , n Is 1 to 4, R 4 is H, C 1 to C 6 alkyl or C 1 to C 6 alkylester, and M is H or a cation, or a mixture thereof; (d) from about 0.02 to about 0.2 parts of cationic cellulose ether derivative and (e) from about 75 to about 90 parts of water, wherein (a) and (b) have a molar ratio of about 2: 1 to about 1: 1.5. A hypoallergenic personal liquid cleaning composition having. (a) 약 2.0 이상의 평균 에톡시화도를 갖는 알킬 에톡시화된 설페이트 음이온성 계면활성제 약 3내지 약 10중량부; (b) 메타인 계면활성제, 이미다졸린 계면활성제, 아미노알카노에이트 계면활성제, 이미노디알카노에이트 계면활성제 및 이들의 혼합물로 구성된 그룹중에서 선택된 양쪽성 계면활성제 약 3내지 약 10부; (c) N-아실 아미노산 계면활성제 또는 그의 염 약 0.1 내지 약 3중량부; (d) 양이온성 셀룰로스에테르 유도체 약 0.01 내지 약 0.5 중량부; 및 (e) 물 50 내지 94부를 포함하고, 이때 상기 (a) 및 (b)가 약 2:1 내지 약 1:1.5의 몰비를 가지며, 실질적으로 알킬 설페이트 음이온성 계면활성제, 1급 아민을 함유하지 않는, 저자극성의 개인용 세정 조성물.(a) about 3 to about 10 parts by weight of an alkyl ethoxylated sulfate anionic surfactant having an average degree of ethoxylation of at least about 2.0; (b) about 3 to about 10 parts of an amphoteric surfactant selected from the group consisting of a metaine surfactant, an imidazoline surfactant, an aminoalkanoate surfactant, an iminodialkanoate surfactant, and mixtures thereof; (c) about 0.1 to about 3 parts by weight of an N-acyl amino acid surfactant or salt thereof; (d) about 0.01 to about 0.5 parts by weight of cationic cellulose ether derivative; And (e) 50 to 94 parts of water, wherein (a) and (b) have a molar ratio of about 2: 1 to about 1: 1.5, substantially containing alkyl sulfate anionic surfactant, primary amine Hypoallergenic personal cleansing composition. 제3항에 있어서, 약 4내지 약 8부의 상기 알킬 에톡시화된 설페이트, 약 4내지 약 8부의 상기 양쪽성 계면활성제, 약 0.25 내지 약 1부의 상기 N-아실 아미노산 계면활성제, 약 0.02 내지 약 1부의 양 이온성 셀룰로스 에테르 유도체를 포함하고, 상기 N-아실 아미노산 계면활성제가 N-아실 사코시네이트 계면활성제인 저자극성의 개인용 액체 세정 조성물.The method of claim 3, wherein from about 4 to about 8 parts of the alkyl ethoxylated sulfate, from about 4 to about 8 parts of the amphoteric surfactant, from about 0.25 to about 1 part of the N-acyl amino acid surfactant, from about 0.02 to about 1 A hypoallergenic personal liquid cleansing composition comprising a negative cationic cellulose ether derivative, wherein the N-acyl amino acid surfactant is an N-acyl sacosinate surfactant. 제4항에 있어서, 상기 양이온성 셀룰로스 에테르 유도체가 폴리쿼터니움-10(트리메틸 암모늄 치환된 에폭시드와 반응된 하이드록시에틸 셀룰로스 중합체성 4급 암모늄염에 대해 코스메틱, 토일레트리 및 프래그런스 어소시에이션(Cosmetic, Toiletry and Fragrance Association(CTFA))에서 지정한 공업 용어임)인 저자극성의 개인용 액체 세정 조성물.The method according to claim 4, wherein the cationic cellulose ether derivative is used for the cosmetic, toetree and fragrance associations for hydroxyethyl cellulose polymeric quaternary ammonium salts reacted with polyquaternium-10 (trimethyl ammonium substituted epoxides. Hypoallergenic personal liquid cleansing composition, which is an industrial term specified by the Toiletry and Fragrance Association (CTFA). 제5항에 있어서, 38℃에서 30일 동안 보관한후에 2.5cm 경로 길이에서 420nm에서의 투과율값이 약 80미만인 저자극성의 개인용 액체 세정 조성물.6. The hypoallergenic personal liquid cleansing composition of claim 5 wherein the transmittance value at 420 nm at a 2.5 cm path length of less than about 80 after storage at 38 ° C. for 30 days. 제6항에 있어서, 상기 알킬 에톡시화된 설페이트가 3 내지 4의 평균 에톡시화도를 갖고, 상기 양쪽성 계면활서제가 코크아미도프로필 베타인이고, 상기 N-아실 아미노산 계면활성제가 나트륨 라우로일 사코시네이트인 저자극성의 개인용 액체 세정 조성물.7. The method of claim 6 wherein said alkyl ethoxylated sulfate has an average degree of ethoxylation of 3 to 4, said amphoteric surfactant is cochamidopropyl betaine, and said N-acyl amino acid surfactant is sodium lauroyl. A hypoallergenic personal liquid cleaning composition that is sacosinate. 제7항에 있어서, 상기 알킬 에톡시화된 설페이트 및 상기 코크아미도프로필 베타인의 비가 약 1.5:1 내지 약 1:1.15인 저자극성의 개인용 액체 세정 조성물.8. The hypoallergenic personal liquid cleansing composition of claim 7, wherein the ratio of alkyl ethoxylated sulfate and cochamidopropyl betaine is from about 1.5: 1 to about 1: 1.15. 제1항에 있어서, (a) 약 2내지 약 12의 평균 에톡시화도를 갖는 알킬 에톡시화된 설페이트 음이온성 계면활성제 약 4내지 약 8부; (b) 하기 (i) 내지 (iv)로 구성된 그룹중에서 선택된 양쪽성 계면활성제 약 4내지 약 8부; (i) 하기 일반식의 베타인 계면활성제;The method of claim 1, comprising: (a) about 4 to about 8 parts of an alkyl ethoxylated sulfate anionic surfactant having an average degree of ethoxylation of about 2 to about 12; (b) about 4 to about 8 parts of an amphoteric surfactant selected from the group consisting of (i) to (iv); (i) betaine surfactants of the general formula: [상기 식에서, R1은 COOM 및로 구성된 그룹중에서 선택된 일원이고, R2는 저급 알킬 또는 하이드록시알킬이고, R3는 저급 알킬 또는 하이드록시알킬이고, R4는 수소 및 저급 알킬로 구성된 그룹중에서 선택된 일원이고, R5는 고급 알킬 또는 알케닐이고, Y는 저급 알킬(C1내지 C4)이고, m은 2내지 7의 정수이고, n은 1 또는 0이고, M은 수소 또는 양이온임]; (ii) 하기 일반식 이미다졸린 계면활성제;[Wherein, R 1 is COOM and A member selected from the group consisting of R 2 is lower alkyl or hydroxyalkyl, R 3 is lower alkyl or hydroxyalkyl, R 4 is a member selected from the group consisting of hydrogen and lower alkyl, and R 5 is higher alkyl Or alkenyl, Y is lower alkyl (C 1 to C 4 ), m is an integer from 2 to 7, n is 1 or 0, and M is hydrogen or cation; (ii) the following general formula imidazoline surfactants; 상기 식에서 R1은 C8내지 C22알킬 또는 알케닐이고, R2는 수소 또는 CH2CO2M이고, R3는 CH2CCH2OH 또는 CH2CH2OCH2CH2COOM이고, R4는 수소, CH2CH2OH, 또는 CH2CH2OCH2CH2COOM이고, Z는 CO2M 또는 CH2CO2M이고, n은 2또는 3이고, M은 수소 또는 양이온임]; 및 (iii) 일반식 R-NH(CH2)nCOOM의 아미노알카노에이트, 및 일반식 R-N〔(CH2)mCOOM〕2아미노디알카노에이트 [상기식에서 n 및 m은 1내지 4이고, R은 C8내지 C22알킬 또는 알케닐이고, M은 수소, 또는 알칼리 또는 알칼리금속임]; 및 (iv) 이들의 혼합물; (c) 하기 일반식 N-아실 아미노산 계면활성제 또는 그의 염 0.25 내지 약 1부;Wherein R 1 is C 8 to C 22 alkyl or alkenyl, R 2 is hydrogen or CH 2 CO 2 M, R 3 is CH 2 CCH 2 OH or CH 2 CH 2 OCH 2 CH 2 COOM, R 4 Is hydrogen, CH 2 CH 2 OH, or CH 2 CH 2 O CH 2 CH 2 COOM, Z is CO 2 M or CH 2 CO 2 M, n is 2 or 3 and M is hydrogen or cation; And (iii) aminoalkanoates of the general formula R-NH (CH 2 ) n COOM, and general amino acids RN [(CH 2 ) m COOM] 2 aminodialkanoates wherein n and m are 1-4; R is C 8 to C 22 alkyl or alkenyl and M is hydrogen or an alkali or alkali metal; And (iv) mixtures thereof; (c) 0.25 to about 1 part of the following general formula N-acyl amino acid surfactant or salt thereof; [상기 식에서, R1은 C8내지 C24알킬 또는 알케닐이고, R2는 -H, C1내지 C4알킬, 페닐, 또는 -CH2COOM 이고, R3는 -C-R4 2이고, n은 1내지 4이고, R4는 H, C1내지 C6알킬 또는 C1내지 C6알킬에스테르이고, M은 H 또는 양이온, 또는 이들의 혼합물임]; (d) 양이온성 셀룰로스 에테르 유도체 약 0.02 내지 약 0.2 부 (e) 항균제 약 0.1 내지 약 0.3 부; (f) 유성 조절제 약 0.1 내지 약 15부; 및 (g) 물 약 75 내지 약 90부를 포함하며, 이때 상기 (a) 및 (b)가 약 2:1 내지 약 1:1.5의 몰비를 갖는 저자극성의 개인용 액체 세정 조성물.[Wherein R 1 is C 8 to C 24 alkyl or alkenyl, R 2 is —H, C 1 to C 4 alkyl, phenyl, or —CH 2 COOM, R 3 is —CR 4 2 , n Is 1 to 4, R 4 is H, C 1 to C 6 alkyl or C 1 to C 6 alkylester, and M is H or a cation, or a mixture thereof; (d) about 0.02 to about 0.2 parts of a cationic cellulose ether derivative (e) about 0.1 to about 0.3 parts of an antimicrobial agent; (f) about 0.1 to about 15 parts of an oily modulator; And (g) about 75 to about 90 parts of water, wherein (a) and (b) have a molar ratio of about 2: 1 to about 1: 1.5. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960702748A 1993-11-24 1994-11-16 ULTRA MILD LATHERING PERSONAL CLEANSING COMPOSITION KR960705540A (en)

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US5804538A (en) * 1996-06-20 1998-09-08 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
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