KR960703448A - MULTI-LAYERED TISSUE PAPER WEB COMPRISING BIODEGRADABLE CHEMICAL SOFTENING COMPOSITIONS AND BINDER MATERIALS AND PROCESS FOR MAKING THE SAME - Google Patents

MULTI-LAYERED TISSUE PAPER WEB COMPRISING BIODEGRADABLE CHEMICAL SOFTENING COMPOSITIONS AND BINDER MATERIALS AND PROCESS FOR MAKING THE SAME Download PDF

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KR960703448A
KR960703448A KR1019950706043A KR19950706043A KR960703448A KR 960703448 A KR960703448 A KR 960703448A KR 1019950706043 A KR1019950706043 A KR 1019950706043A KR 19950706043 A KR19950706043 A KR 19950706043A KR 960703448 A KR960703448 A KR 960703448A
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Prior art keywords
tissue paper
fibers
paper web
layer
multilayer
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KR1019950706043A
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Korean (ko)
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KR100333211B1 (en
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딘 밴 판
폴 데니스 트로칸
바트 스티븐 허스코
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제이코버스 코넬리스 레이서
더 프록터 앤드 갬블 캄파니
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets

Abstract

Multi-layered tissue paper webs comprising biodegradable chemical softener compositions and binder materials are disclosed. The multi-layered tissue webs are useful in the manufacture of soft, absorbent paper products such as facial tissues and/or toilet tissues. The multi-layered tissue paper products contain a biodegradable chemical softening composition, preferably comprising a mixture of an ester-functional quaternary ammonium compound and a polyhydroxy compound. Preferred ester-functional quaternary ammonium compounds include diester dialkyl dimethyl ammonium salts such as diester di(touch hardened)tallow dimethyl ammonium chloride, diester di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, sorbitols, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 4,000. The multi-layered tissue paper webs also contain an effective amount of binder materials to control linting and/or to offset the loss in tensile strength, if any, resulting from the use of the chemical softening compositions. The binder materials are selected from the various wet and dry strength additives, and retention aids used in the paper making art. Preferably, the majority of the biodegradable chemical softening compositions will be disposed on the outer layers of the multi-layered tissue paper products where they are most effective. The binder materials are typically dispersed throughout the multi-layered product to control linting. In other words, the chemical softening compositions and the binder materials can be selectively distributed within the multi-layered tissue paper web to enhance the softness, absorbency, and/or lint resistance of a particular layer or ply.

Description

생분해성 화학 연화제 조성물 및 결합제를 포함하는 다층의 티슈 종이 웹 및 이의 제조방법(MULTI LAYERED TISSUE PAPER WEB COMPRISING BIODEGRADABLE CHEMICAL SOFTENING COMPOSITIONS AND BINDER MATERIALS AND PROCESS FOR MAKING THE SAME)MULTI LAYERED TISSUE PAPER WEB COMPRISING BIODEGRADABLE CHEMICAL SOFTENING COMPOSITIONS AND BINDER MATERIALS AND PROCESS FOR MAKING THE SAME

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도는 본 발명에 따른 3개의 층으로 된 한겹의 화장실용 티슈의 개략적인 단면도이다. 제2도는 본 발명에 따른 2개의 층으로 된 2겹의 고급 티슈의 개략적인 단면도이다.1 is a schematic cross-sectional view of a three-layered toilet tissue in accordance with the present invention. 2 is a schematic cross-sectional view of a two-ply advanced tissue in two layers in accordance with the present invention.

Claims (10)

제1층 및 상기 제1층에 연속적인 하나 이상의 제2층으로 이루어진 2개 이상의 겹쳐진 층을 포함함을 특징으로 하는, 하기 (a) 내지 (d) 를 포함하는 다층 티슈 종이 웹: (a) 제지 섬유; (b) 바람직하게는 하기 일반식을 갖는 약 0.01 내지 약 3.0%의 생분해성 4급 암모늄 화합물; (c) 바람직하게는 글리세롤, 솔리톨, 약 150 내지 약 800의 중량 평균 분자량을 갖는 폴리글리세롤, 및 약 200 내지 4000, 바람직하게는 200 내지 1000, 가장 바람직하게는 200 내지 600의 중량 평균 분자량을 갖는 폴리옥시에틸렌 글리콜 및 폴리옥시프로필렌 글리콜 및 그의 혼합물로 이루어진 그룹중에서 선택된 약 0.01 내지 약 3.0%의 수용성 폴리하이드록시 화합물; 및 (d) 영구 습윤 강도 수지, 바람직하게는 폴리아미드-에피클로로히드린 또는 플리아크릴아미드 영구 습윤 강도 수지 및 그의 혼합물, 일시적 습윤 강도 수지, 바람직하게는 전분계 일시적 습윤 강도 수지, 건조 강도 수지, 보유 보조 수지 및 그의 혼합물중에서 선택된 약 0.01% 내지 3.0%의 결합체:A multi-layer tissue paper web comprising the following layers (a) to (d), characterized in that it comprises a first layer and at least two overlapping layers consisting of at least one second layer continuous to the first layer: (a) Papermaking fibers; (b) about 0.01 to about 3.0% of a biodegradable quaternary ammonium compound, preferably having the general formula: (c) preferably glycerol, solitol, a polyglycerol having a weight average molecular weight of about 150 to about 800, and a weight average molecular weight of about 200 to 4000, preferably 200 to 1000, most preferably 200 to 600 From about 0.01 to about 3.0% of a water-soluble polyhydroxy compound selected from the group consisting of polyoxyethylene glycol and polyoxypropylene glycol and mixtures thereof; And (d) permanent wet strength resins, preferably polyamide-epichlorohydrin or polyacrylamide permanent wet strength resins and mixtures thereof, temporary wet strength resins, preferably starch-based temporary wet strength resins, dry strength resins, From about 0.01% to 3.0% of a binder selected from the retention aid resin and mixtures thereof: 상기 식에서, 각각의 R2치환제는 C1-C6알킬 또는 하이드록시알킬 그룹, 벤질 그룹 또는 이들의 혼합물이고, 바람직하게는 메틸이고; 각각의 R1치환체는 C12-C22하이드로카빌 그룹, 또는 치환된 하이드로카빌 그룹 또는 이들의 혼합물이고, 바람직하게는 C16-C18알킬 또는 알케닐이고; 각각의 R3치환체는 C11-C21하이드록카빌 그룹, 또는 치환된 하이드로카빌 또는 이들의 혼합물이고, 바람직하게는 C15-C17알킬 또는 알케닐이고; Y는 -O-C(O)-, -C(O)-O-, -NH-C(O)-, -C(O)-NH- , 또는 이들의 혼합물이고; n은 1내지 4이고; X-는 적합한 음이온이고, 바람직하게는 클로라이드 또는 메틸설페이트이다.Wherein each R 2 substituent is C 1 -C 6 alkyl or hydroxyalkyl group, benzyl group or mixture thereof, preferably methyl; Each R 1 substituent is a C 12 -C 22 hydrocarbyl group, or a substituted hydrocarbyl group or a mixture thereof, preferably C 16 -C 18 alkyl or alkenyl; Each R 3 substituent is a C 11 -C 21 hydrocarbyl group, or a substituted hydrocarbyl or mixture thereof, preferably C 15 -C 17 alkyl or alkenyl; Y is —OC (O) —, —C (O) —O—, —NH—C (O) —, —C (O) —NH—, or a mixture thereof; n is 1 to 4; X − is a suitable anion, preferably chloride or methylsulfate. 제1항에 있어서, 상기 다층 웹이 1개의 내층 및 2개의 외층으로 이루어진 3개의 겹쳐진 층을 포함하고, 상기 내층이 상기 2개의 외층 사이에 위치하고, 상기 다층 웹이 바람직하게는 단일 겹을 포함하고, 상기 생분해성 4급 암모늄 화합물, 상기 수용성 폴리하이드록시 화합물 및 상기 결합체가 상기 다층 웹의 각각 1개 이상의 상기 층중에 함유된 다층 티슈 종이 웹.2. The multilayer web of claim 1 wherein the multilayer web comprises three overlapping layers of one inner layer and two outer layers, the inner layer is located between the two outer layers, and the multilayer web preferably comprises a single ply, A multilayer tissue paper web, wherein said biodegradable quaternary ammonium compound, said water soluble polyhydroxy compound, and said binder are contained in each one or more of said layers of said multilayer web. 제2항에 있어서, 대부분의 생분해성 4급 암모늄 화합물 및 폴리하이드록시 화합물이 1개 이상의 상기 외층, 바람직하게는 상기 외층 둘다에 함유된 다층 티슈 종이 웹.3. The multilayer tissue paper web of claim 2 wherein most biodegradable quaternary ammonium compounds and polyhydroxy compounds are contained in at least one of said outer layers, preferably both. 제2항 또는 제3항에 있어서, 대부분의 결합제가 상기 내층에 함유된 다층 티슈 종이 웹.4. The multilayer tissue paper web of claim 2 or 3 wherein most of the binder is contained in the inner layer. 제2항 내지 제4항중 어느 한 항에 있어서, 상기 내층이 평균 길이 2.0㎜의 비교적 긴 제지 섬유, 바람직하게는 침엽수 섬유, 가장 바람직하게는 북부 침엽수 섬유를 포함하고, 상기 2개의 외층이 각각 평균 길이 0.2내지 1.5㎜의 비교적 짧은 제지 섬유, 바람직하게는 활엽수 섬유, 가장 바람직하게는 유칼립터스 섬유를 포함하는 다층 티슈 종이 웹.The method according to any one of claims 2 to 4, wherein the inner layer comprises a relatively long papermaking fiber, preferably coniferous fiber, most preferably northern coniferous fiber, with an average length of 2.0 mm, wherein the two outer layers are each averaged. A multilayer tissue paper web comprising relatively short papermaking fibers, preferably hardwood fibers, most preferably eucalyptus fibers, of 0.2 to 1.5 mm in length. 제5항에 있어서, 상기 내층이 침엽수 섬유 및 저가의 섬유을 포함하고, 1개 이상의 상기 외층이 저가의 섬유 또는 침엽수 섬유와 저가 섬유의 혼합물을 포함하고, 상기 저가 섬유가 설파이트 섬유, 열기계처리된 펄프 섬유, 화학-열기계처리된 펄프 섬유, 재생 섬유 및 그의 혼합물중에서 선택되는 다층 티슈 종이 웹.6. The method of claim 5 wherein the inner layer comprises coniferous fibers and inexpensive fibers, wherein at least one of the outer layers comprises inexpensive fibers or a mixture of coniferous fibers and inexpensive fibers, wherein the inexpensive fibers are sulfite fibers, thermomechanical treatment Multi-layer tissue paper web selected from pulp fibers, chemically-thermotreated pulp fibers, recycled fibers and mixtures thereof. 제1항 내지 제6항중 어느 한 항에 있어서, 상기 생분해성 4급 암모늄 화합물이 디에스테르 디(접촉 경화)탈로우 디메틸 암모늄 클로라이드 또는 디에스테르 디(접촉 경화)탈로우 디메틸 메틸 설페이트인 다층 티슈 종이 웹.The multi-layer tissue paper of claim 1, wherein the biodegradable quaternary ammonium compound is diester di (contact curing) tallow dimethyl ammonium chloride or diester di (contact curing) tallow dimethyl methyl sulfate Web. 제1항 내지 제7항중 어느 한 항에 있어서, 4급 암모늄과 폴리하이드록시 화합물의 중량비가 1.0 : 0.3 내지 0.3 : 1.0, 바람직하게는 1.0 : 0.7 내지 0.7 : 1.0인 다층 티슈 종이 웹.The multilayer tissue paper web according to any one of claims 1 to 7, wherein the weight ratio of the quaternary ammonium to the polyhydroxy compound is 1.0: 0.3 to 0.3: 1.0, preferably 1.0: 0.7 to 0.7: 1.0. 바람직하게는 2겹으로 이루어져 있고, 상기 2겹 각각이 바람직하게는 2개의 겹쳐진 층으로 이루어져 있고, 상기 겹합제가 영구 습윤 강도 수지 또는 일시적 습윤 수지이고, 상기 생분해성 4급 암모늄 화합물 및 폴리하이드록시 화합물 대부분이 1개 이상의 상기 외층에 함유되고, 대부분의 상기 결합제가 상기 내층에 함유된, 병렬배치된 2개 이상의 제1항의 다층 티슈 종이 웹을 포함하는 다층 티슈 종이 제품.It is preferably composed of two layers, each of which is preferably composed of two overlapping layers, wherein the mixture is a permanent wet strength resin or a temporary wet resin, and the biodegradable quaternary ammonium compound and polyhydroxy A multi-layer tissue paper product comprising at least two parallel tissue paper webs of claim 1, wherein most of the compound is contained in at least one of said outer layers, and most of said binder is contained in said inner layer. 제1항 내지 제9항중 어느 한 항에 있어서, 상기 티슈 종이 웹이 화장실용 티슈 또는 고급 티슈인 다층 티슈 종이 웹.10. The multi-layer tissue paper web of claim 1, wherein the tissue paper web is a toilet tissue or a high quality tissue. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950706043A 1993-06-30 1994-06-17 Multi-layer tissue paper web comprising biodegradable chemical softener composition and binder, and articles comprising the same KR100333211B1 (en)

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US8585293A 1993-06-30 1993-06-30
US08/085,852 1993-06-30
US08/085852 1993-06-30
PCT/US1994/006916 WO1995001479A1 (en) 1993-06-30 1994-06-17 Multi-layered tissue paper web comprising biodegradable chemical softening compositions and binder materials and process for making the same

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KR960703448A true KR960703448A (en) 1996-08-17
KR100333211B1 KR100333211B1 (en) 2002-11-04

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KR (1) KR100333211B1 (en)
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SG64312A1 (en) 1999-04-27
WO1995001479A1 (en) 1995-01-12
AU7112894A (en) 1995-01-24
HUT74119A (en) 1996-11-28
EP0706591B1 (en) 2001-08-29
ES2159561T3 (en) 2001-10-16
CA2165536A1 (en) 1995-01-12
FI956336A (en) 1996-02-28
BR9406992A (en) 1996-09-10
HU9503967D0 (en) 1996-03-28
TW305001B (en) 1997-05-11
CZ351495A3 (en) 1996-07-17
EP0706591A1 (en) 1996-04-17
FI956336A0 (en) 1995-12-29
TR27850A (en) 1995-09-04
NO960002D0 (en) 1996-01-02
JPH08512104A (en) 1996-12-17
ATE204935T1 (en) 2001-09-15
PE28095A1 (en) 1995-10-11
DE69428118T2 (en) 2002-06-06
DE69428118D1 (en) 2001-10-04
KR100333211B1 (en) 2002-11-04
NO308320B1 (en) 2000-08-28
MY114367A (en) 2002-10-31
NO960002L (en) 1996-02-29

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