KR960029381A - Adhesive polyester film - Google Patents

Adhesive polyester film Download PDF

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Publication number
KR960029381A
KR960029381A KR1019960000119A KR19960000119A KR960029381A KR 960029381 A KR960029381 A KR 960029381A KR 1019960000119 A KR1019960000119 A KR 1019960000119A KR 19960000119 A KR19960000119 A KR 19960000119A KR 960029381 A KR960029381 A KR 960029381A
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KR
South Korea
Prior art keywords
polyester film
adhesive
group
film
acrylic acid
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KR1019960000119A
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Korean (ko)
Inventor
신이찌로 오까다
마사유끼 후꾸다
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이따가끼 히로시
데이진 가부시끼가이샤
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Publication of KR960029381A publication Critical patent/KR960029381A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/042Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J139/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
    • C09J139/04Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62Record carriers characterised by the selection of the material
    • G11B5/73Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2439/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
    • C08J2439/04Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer

Abstract

접착성 폴리에스테르 필름은 방향족 폴리에스테르 필름 및 그 방향족 폴리에스테르 필림의 한면 이상에 존재하는 접착성 도포 필름을 포함한다. 그 도포 필름은 카르복실산 기 함유 아크릴산 공중합체 및 주요 사슬에 복수의 암모늄 양이온을 갖는 중합체 또는 그 주요 사슬에 복수의 피롤리디늄 고리를 갖는 중합체를 포함하는 조성물로부터 이루어진다.The adhesive polyester film includes an aromatic polyester film and an adhesive coating film present on one side or more of the aromatic polyester film. The coating film is composed of a composition containing a carboxylic acid group-containing acrylic acid copolymer and a polymer having a plurality of ammonium cations in the main chain or a polymer having a plurality of pyrrolidinium rings in its main chain.

Description

접착성 폴리에스테르 필름Adhesive polyester film

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is a trivial issue, I did not include the contents of the text.

Claims (12)

(A) 방향족 폴리에스테르 필름 및 (B) 방향족 폴리에스테르 필림(A)의 한면 이상에 존재하는 접착성 도포 필름을 포함하며, 그 도포 필름은 (a) 카르복실산 기 함유 아크릴산 공중합체 및 (b) 주요 사슬에 복수의 암모늄 양이온을 갖는 중합체 및 그 주요 사슬에 복수의 피롤리디늄 고리를 갖는 중합체로 이루어지는 군으로부터 선택된 하나 이상의 다가 양이온성 중합체를 포함하는 조성물로부터 이루어짐을 특징으로 하는 접착성 폴리에스테르 필름.(A) an aromatic polyester film, and (B) an aromatic polyester film (A), wherein the coating film comprises (a) an acrylic acid copolymer containing a carboxylic acid group and (b) ) Comprising at least one polyvalent cationic polymer selected from the group consisting of a polymer having a plurality of ammonium cations in its main chain and a polymer having a plurality of pyrrolidinium rings in its main chain film. 제1항에 있어서, 방향족 폴리에스테르 필름(A)는 백색 안료를 포함함을 특징으로 하는 접착성 폴리에스테르 필름.The adhesive polyester film according to claim 1, wherein the aromatic polyester film (A) comprises a white pigment. 제1항에 있어서, 방향족 폴리에스테르 필름(A)는 20㎛ 이상의 두께를 가짐을 특징으로 하는 접착성 폴리에스테르 필름.The adhesive polyester film according to claim 1, wherein the aromatic polyester film (A) has a thickness of 20 탆 or more. 제1항에 있어서, 접착성 도포 필름(B)가 방향족 폴리에스테르 필름(A)의 양면에 존재함을 특징으로 하는 접착성 폴리에스테르 필름.The adhesive polyester film according to claim 1, wherein the adhesive coating film (B) is present on both sides of the aromatic polyester film (A). 제1항에 있어서, 카르복실산 기 함유 아크릴산 공중합체(a)는 아크릴산, 메트아크릴산, 말레산 및 푸마르 산으로 이루어진 군으로부터 선택된 하나 이상의 불포화 카르복실산으로부터 유래하는 중합성 단위를 함유함을 특징으로 하는 접착성 폴리에스테르 필름.The acrylic acid-containing copolymer (a) according to claim 1, characterized in that the carboxylic acid group-containing acrylic acid copolymer (a) contains a polymerizable unit derived from at least one unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, maleic acid and fumaric acid By weight. 제1항에 있어서, 카르복실산기 함유 아크릴산 공중합체(a)는 중합성 단위 총량을 기준으로 0.5 내지 10몰%의 양으로 불포화 카르복실산으로부터 유래하는 중합성 단위를 함유함을 특징으로 하는 접착성 폴리에스테르 필름.The acrylic acid copolymer (a) according to claim 1, wherein the carboxylic acid group-containing acrylic acid copolymer (a) contains a polymerizable unit derived from an unsaturated carboxylic acid in an amount of 0.5 to 10 mol% Cast polyester film. 제1항에 있어서, 주요 사슬에 복수의 암모늄 양이온을 갖는 중합체는 하기 식(1)로 표시되는 반복 단위를 갖는 다가 양이온성 중합체임을 특징으로 하는 접착성 폴리에스테르 필름:The adhesive polyester film according to claim 1, wherein the polymer having a plurality of ammonium cations in the main chain is a polyvalent cationic polymer having a repeating unit represented by the following formula (1): [상기 식 중, R1, R2, R3및 R4은 동일하거나 상이하며, 알킬기, 시클로알킬기, 아릴기, 아르알킬기 및 부분적으로 헤테로원자로 치환된 이러한 기들로 이루어지는 군으로부터 선택되며, Z1및 Z2은 동일하거나 상이하며, 알킬렌기, 시클로알킬렌기, 아릴렌기, 아르알킬렌기 및 부분적으로 헤테로원자로 치환된 이러한 기로 이루어지는 군으로부터 선택되고, X-는 1당량의 음이온이다.]Wherein R 1 , R 2 , R 3 and R 4 are the same or different and are selected from the group consisting of alkyl groups, cycloalkyl groups, aryl groups, aralkyl groups and those groups partially substituted with heteroatoms, and Z 1 And Z 2 are the same or different and are selected from the group consisting of an alkylene group, a cycloalkylene group, an arylene group, an aralkylene group, and those groups partially substituted by a hetero atom, and X - is one equivalent of an anion. 제1항에 있어서, 주요 사슬에 복수의 피롤리디늄 고리를 갖는 중합체는 하기 식(2)로 표시되는 반복단위를 갖는 다가 양이온성 중합체임을 특징으로 하는 접착성 폴리에스테르 필름:The adhesive polyester film according to claim 1, wherein the polymer having a plurality of pyrrolidinium rings in the main chain is a polyvalent cationic polymer having a repeating unit represented by the following formula (2) [상기 식 중, R5및 R6은 동일하거나 상이하며, 수소원자, 알킬기, 시클로알킬기, 아릴기, 아르알킬기 및 부분적으로 헤테로원자로 치환된 이러한 기들로 이루어지는 군으로부터 선택되며, Z3은 단일 결합 또는 -SO2- 기익, X-는 1당량의 음이온이며, R5및 R6모두는 수소원자일 수 없다.]Wherein R 5 and R 6 are the same or different and are selected from the group consisting of a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group and those groups partially substituted by a hetero atom, and Z 3 represents a single bond Or-SO 2 -heterocycle, X - is one equivalent of anion, and R 5 and R 6 are both not a hydrogen atom. 제1항에 있어서, 다가 양이온성 중합체(b)에 대한 카르복실산기 함유 아크릴산 공중합체(a)의 중량비는 97:3 내지 70 : 30의 범위임을 특징으로 하는 접착성 폴리에스테르 필름.The adhesive polyester film according to claim 1, wherein the weight ratio of the carboxylic acid group-containing acrylic acid copolymer (a) to the polyvalent cationic polymer (b) is in the range of 97: 3 to 70:30. 제1항에 기재된 접착성 폴리에스테르 필름의 방향족 폴리에스테르 필름(A)의 한면에 접착성 도포 필름이 존재하고, 하나 이상의 마그네틱 기록충 및 인쇄 잉크층이 접착성 도포 필름 표면의 일부분 이상에 존재함을 특징으로 하는 정보 기능을 갖는 폴리에스테르 필름.An adhesive film is present on one side of the aromatic polyester film (A) of the adhesive polyester film according to claim 1, and at least one magnetic recording layer and a printing ink layer are present on at least a part of the adhesive film surface Wherein the polyester film has an information function. 제1항에 기재된 접착성 폴리에스테르 필름의 방향족 폴리에스테르 필름(A)의 양면에 접착성 도포 필름이 존재하고, 하나 이상의 마그네틱 기록충 및 인쇄 잉크층이 접착성 도포 필름의 어느 한쪽 표면의 일부분 이상에 존재함을 특징으로 하는 정보 기능을 갖는 폴리에스테르 필름.The adhesive polyester film (A) of the adhesive polyester film according to claim 1, wherein an adhesive coating film is present on both sides and at least one magnetic recording layer and a printing ink layer are provided on at least a part of one surface of the adhesive coating film Wherein the polyester film has an information function. 제1항에 기재된 접착성 폴리에스테르 필름의 방향족 폴리에스테르 필름(A)의 양면에 접착성 도포 필름이 존재하고, 마그네틱 기록층이 주로 접착성 도포 필름의 한면의 표면에 존재하고, 인쇄 잉크층이 주로 접착성 도포 필름의 다른 한면의 표면상에 존재함을 특징으로 하는 정보 기능을 갖는 폴리에스테르 필름.A process for producing an adhesive film, wherein an adhesive coating film is present on both sides of the aromatic polyester film (A) of the adhesive polyester film according to claim 1, the magnetic recording layer is mainly present on one surface of the adhesive coating film, Characterized in that the adhesive film is present mainly on the surface of the other side of the adhesive application film. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019960000119A 1995-01-05 1996-01-05 Adhesive polyester film KR960029381A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP7000218A JPH08188662A (en) 1995-01-05 1995-01-05 Easily adherable white polyester film
JP95-000218 1995-01-05

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KR960029381A true KR960029381A (en) 1996-08-17

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KR (1) KR960029381A (en)
AU (1) AU4080896A (en)
TW (1) TW343231B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1283701C (en) * 2001-06-21 2006-11-08 优泊公司 Method of surface treatment of thermoplastic resin film

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JPH08188662A (en) 1996-07-23
AU4080896A (en) 1996-07-11
TW343231B (en) 1998-10-21

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