KR960022704A - Biaxially oriented polyamide film and its manufacturing method - Google Patents

Biaxially oriented polyamide film and its manufacturing method Download PDF

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Publication number
KR960022704A
KR960022704A KR1019940035348A KR19940035348A KR960022704A KR 960022704 A KR960022704 A KR 960022704A KR 1019940035348 A KR1019940035348 A KR 1019940035348A KR 19940035348 A KR19940035348 A KR 19940035348A KR 960022704 A KR960022704 A KR 960022704A
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South Korea
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crystal content
peak
content index
film
area
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KR1019940035348A
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Korean (ko)
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KR100237216B1 (en
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조서현
김격현
박순종
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이웅열
주식회사 코오롱
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

본 발명은 축차 이축 연신 폴리아미드 필름 및 그 제조 방법에 관한 것으로서, 상세하게는 지방족 폴리아미드를 주성분으로 하여 축차 이축 연신에 의해 제조되어 α결정함량 지수가 0.7 내지 1.5,결정함량 지수가 0.3 내지 0.8인 기계적 물성과 가스 차단성이 우수하여 식품 포장재로 사용되기에 적합한 용도를 갖는 폴리아미드 필름 및 그 제조 방법에 관한 것이다.The present invention relates to a sequential biaxially stretched polyamide film and a method for producing the same, and in particular, prepared by sequential biaxial stretching with an aliphatic polyamide as a main component, the α-crystal content index is 0.7 to 1.5, The present invention relates to a polyamide film having a suitable use as a food packaging material having excellent mechanical properties and gas barrier properties having a crystal content index of 0.3 to 0.8, and a method of manufacturing the same.

상기한 목적을 달성하기 위하여, 본 발명은 지방족 폴리아미드를 주성분으로 하여 축차 이축 연신에 의해 제조함에 있어서, 종방향 연신하여 연신 필름의 α 결정함량 지수가 0.1 내지 0.2,결정함량 지수가 0.29 내지 0.5 되도록 한 후, 횡방향 연신하여 연신 필름의 α 결정함량 지수가 0.7 내지 1.5,결정함량 지수가 0.3 내지 0.8 되도록 함을 특징으로 하는 폴리아미드 이축 연신 필름의 제조 방법을 제공한다.In order to achieve the above object, the present invention in the manufacturing by sequential biaxial stretching with an aliphatic polyamide as a main component, the α crystal content index of the stretched film in the longitudinal direction is 0.1 to 0.2, After the crystal content index was 0.29 to 0.5, the film was stretched in the transverse direction so that the α crystal content index of the stretched film was 0.7 to 1.5, It provides a process for producing a polyamide biaxially oriented film, characterized in that the crystal content index is 0.3 to 0.8.

Description

이축 연신 폴리아미드 필름 및 그 제조 방법Biaxially oriented polyamide film and its manufacturing method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (7)

지방족 폴리아미드를 주성분으로 하여 축차 이축 연신에 의해 제조 함에 있어서, 종방향 연신하여 연신필름의 α 결정함량 지수가 0.1 내지 0.2,결정함량 지수가0.29 내지 0.5 되도록 한 후, 횡방향 연신하여 연신 필름의 α 결정함량 지수가 0.7 내지 1.5,결정함량 지수가 0.3 내지 0.8되도록 함을 특징으로 하는 폴리아미드 이축 연신필름의 제조 방법을 제공한다.In the production by sequential biaxial stretching with an aliphatic polyamide as a main component, the α crystal content index of the stretched film in the longitudinal direction is 0.1 to 0.2, After the crystal content index was set to 0.29 to 0.5, the film was stretched in the transverse direction and the α crystal content index of the stretched film was 0.7 to 1.5, It provides a method for producing a polyamide biaxially oriented film, characterized in that the crystal content index is 0.3 to 0.8. 제1항에 있어서, α 결정함량 지수와결정함량 지수는 은폴리아미드 필름을 FT-IR으로 분석하였을 때 나타나는 1120㎝-1, 975㎝-1, 929㎝-1의 피크를 각각 폴리아미드 필름의 두께와 관련된 피크,결정함량과 관련된 피크, 및 α 결정함량과 관련된 피크로 선택하여 각 피프의 면적으로부터 다음의 관계식에 의해 정의되어짐을 특징으로 하는 방법.The method according to claim 1, wherein the α content index and Crystal content index is related to the thickness of the 1120㎝ -1, 975㎝ -1, -1 the peak 929㎝ each polyamide film that appears when analyzing the polyamide film by FT-IR peak, A peak related to a crystal content, and a peak related to a crystal content, and is defined by the following relationship from the area of each pipe. α결정함량 지수=929㎝-1피크의 면적/1120㎝-1피크의 면적,결정함량 지수=929㎝-1피크의 면적/1120㎝-1피크의 면적.α crystal content index = 929 cm −1 area of peak / 1120 cm −1 area of peak, Crystal content index = 929 cm −1 area of peak / 1120 cm −1 area of peak. 제1항에 있어서, 종방향 연신은 용융 폴리아미드 수지를 압축시킨 필름을 50 내지 70℃의 온도에서 3.0 내지 3.5배 연신하는 것으로 행하여짐을 특징으로 하는 방법.The method according to claim 1, wherein the longitudinal stretching is performed by stretching the film compressed with the molten polyamide resin by 3.0 to 3.5 times at a temperature of 50 to 70 캜. 제1항에 있어서, 횡방향 연신은 65 내지 80℃에서 3.5 내지 3.9배 연신하는 것으로 행하여 짐을 특징으로 하는 방법.The method according to claim 1, wherein the transverse stretching is performed by stretching 3.5 to 3.9 times at 65 to 80 占 폚. 제1항에 있어서, 횡방향 연신 후 200 내지 240℃의 온도에서 2내지 5%의 이완율으로 열처리함을 특징으로 하는 방법.The method of claim 1, characterized in that the heat treatment at a relaxation rate of 2 to 5% at a temperature of 200 to 240 ℃ after transverse stretching. 제1항 내지 제6항 중 어느 하나의 항에 의하여 제조되어 짐을 특징으로 하는 필름중에 α 결정함량 지수가 0.7 내지 1.5이고,결정함량 지수는 0.3 내지 0.8이 되는 이축 연신 폴리아미드 필름.The α crystal content index of the film produced by any one of claims 1 to 6 is 0.7 to 1.5, A biaxially stretched polyamide film having a crystal content index of 0.3 to 0.8. 제6항에 있어서, α결정함량 지수와결정함량 지수는 폴리아미드 필름을 FT-IR으로 분석하였을 때 나타나는 1120㎝-1, 975㎝-1, 929㎝-1의 피크를 각각 폴리아미드 필름의 두께와 관련된 피크,결정함량과 관련된 피크 및 α 결정함량과 관련된 피크로 선택하여 각 피프의 면적으로부터 다음의 관계식에 의해 정의 되어짐을 특징으로 하는 이축 연신 폴리아미드 필름방법.The method according to claim 6, wherein the α crystal content index and Crystal content index associated 1120㎝ -1, a peak of 975㎝ -1, -1 929㎝ appear when analyzed by FT-IR of a polyamide film and the thickness of each polyamide film peak, 2. A biaxially oriented polyamide film process according to claim 1, wherein the peak is related to the crystal content and the peak related to the α content is defined by the following relationship from the area of each pipe. α결정함량 지수=929cm-1피크의 면적/1120cm-1피크의 면적, γ결정함량 지수=929cm-1피크의 면적/1120cm-1피크의 면적.α crystal content index area = 929cm -1 / 1120cm -1 peak area of the peak, γ crystal content index = 929cm -1 peak area / area of 1120cm -1 peak of. ※ 참고사항 :최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940035348A 1994-12-20 1994-12-20 Polyamide film of biaxially and its manufacturing method KR100237216B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100371606B1 (en) * 1999-12-04 2003-02-11 주식회사 코오롱 A bi-axial oriented film having an excellent oxygen-barrier, and a process of preparing for the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100371606B1 (en) * 1999-12-04 2003-02-11 주식회사 코오롱 A bi-axial oriented film having an excellent oxygen-barrier, and a process of preparing for the same

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