KR960022701A - Polymer film and preparation method thereof - Google Patents

Polymer film and preparation method thereof Download PDF

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Publication number
KR960022701A
KR960022701A KR1019940033120A KR19940033120A KR960022701A KR 960022701 A KR960022701 A KR 960022701A KR 1019940033120 A KR1019940033120 A KR 1019940033120A KR 19940033120 A KR19940033120 A KR 19940033120A KR 960022701 A KR960022701 A KR 960022701A
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South Korea
Prior art keywords
resin
weight
parts
polymer film
polyester resin
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KR1019940033120A
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Korean (ko)
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김범상
김문선
김상일
이영진
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안시환
주식회사 에스케이씨
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Priority to KR1019940033120A priority Critical patent/KR960022701A/en
Publication of KR960022701A publication Critical patent/KR960022701A/en

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Abstract

본 발명은 고분자 필름 및 이의 제조 방법에 관한 것이다. 폴리에스테르 수지에 대하여 산가 1.0㎎KOH/g 이하의 설폰산 금속염 유도체 0.01 내지 1.0중량부 및 힌더드 페놀계 화합물 0.005 내지 0.5중량부를 함유한 폴리에스테르 수지를 제조하는 단계, 전체 고분자에 대하여 상기 폴리에스테르 수지 65 내지 95중량부와 용융 지수 1.0 내지 25(g/10분) 사이의 폴리올레핀계 수지 5 내지 35중량부를 용융혼합하여 컴파운딩 방식에 의해 1차 혼합수지를 제조하는 단계, 및 상기 혼합수지를 건조, 용융, 압축하여 쉬이트를 성형 후 연신하는 단계를 포함하여 제조된 고분자 필름은 물성 균일도가 우수하며 제전특성과 필름 표면에의 인쇄성이 뛰어나고, 외관이 미려하며, 겉보기 밀도 및 열안정성 등의 필름 특성이 향상되었다.The present invention relates to a polymer film and a method for producing the same. Preparing a polyester resin containing 0.01 to 1.0 parts by weight of a sulfonic acid metal salt derivative having an acid value of 1.0 mgKOH / g or less and 0.005 to 0.5 parts by weight of a hindered phenolic compound with respect to the polyester resin; Preparing a primary mixed resin by a compounding method by melting and mixing 5 to 35 parts by weight of a polyolefin-based resin having a resin content of 65 to 95 parts by weight and a melt index of 1.0 to 25 (g / 10 minutes), and the mixed resin. The polymer film produced by drying, melting, and compressing a sheet after forming it is stretched to have excellent uniformity of physical properties, excellent antistatic properties and printability on the surface of the film, beautiful appearance, apparent density, thermal stability, and the like. The film properties of were improved.

Description

고분자 필름 및 이의 제조 방법Polymer film and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (7)

폴리에스테르 수지를 기준으로 하여 산가 1.0㎎KOH/g 이하의 설폰산 금속염 유도체 0.01 내지 1.0중량부 및 힌더드 페놀계 화합물 0.005 내지 0.5중량부를 함유한 주반복 단위 폴리에스테르 수지를 전체 고분자에 대하여 65 내지 95중량부 및 용융수지가 1.0 내지 25(g/10분)인 폴리올레핀계 수지를 전체 고분자에 대하여 5 내지 35중량부 혼합하고 이축연신하여 되는 것을 특징으로 하는 고분자 필름.The main repeating unit polyester resin containing 0.01 to 1.0 parts by weight of the sulfonic acid metal salt derivative having an acid value of 1.0 mgKOH / g or less and 0.005 to 0.5 parts by weight of the hindered phenol compound, based on the polyester resin, was 65 to A polymer film comprising 95 parts by weight and a polyolefin resin having a melt resin of 1.0 to 25 (g / 10 minutes) by mixing 5 to 35 parts by weight with respect to all the polymers and biaxially stretching. 제1항에 있어서, 상기 설폰산 금속염 유도체는 하기 식으로 표시되는 것을 특징으로 하는 고분자 필름.The polymer film according to claim 1, wherein the sulfonic acid metal salt derivative is represented by the following formula. R1- S03MeR 1 -S0 3 Me (상기 식에서 R1은 탄소수 5 내지 20개의 알킬기, Me는 Li, Na, K 및 Mg을 포함하는 알칼리 토금속류 또는 알칼리 금속류 원소중의 어느 하나이다. )(Wherein R 1 is an alkyl group having 5 to 20 carbon atoms, Me is any one of alkaline earth metals or alkali metal elements including Li, Na, K and Mg.) 제1항에 있어서, 상기 폴리올레핀계 수지는 폴리에틸렌, 폴리프로필렌 및 폴리메틸렌으로 이루어진 군에서 선택된 적어도 하나인 것을 특징으로 하는 고분자 필름.The polymer film of claim 1, wherein the polyolefin-based resin is at least one selected from the group consisting of polyethylene, polypropylene, and polymethylene. 폴리에스테르 수지에 대하여 산가 1.0㎎KOH/g 이하의 설폰산 금속염 유도체 0.01 내지 1.0중량부 및 힌더드 페놀계 화합물 0.005 내지 0.5중량부를 함유한 폴리에스테르 수지를 제조하는 단계; 전체 고분자에 대하여 상기 폴리에스테르 수지 65내지 95중량부와 용융지수 1.0 내지 25(g/10분) 사이의 폴리올렌핀계 수지 5 내지 35중량부를 용융혼합하여 컴파운딩 방식에 의해 1차 혼합수지를 제조하는 단계; 및 상기 혼합수지를 건조, 용융, 압축하여 쉬이트를 성형 후 연신하는 단계를 포함하는 것을 특징으로 하는 고분자 필름의 제조 방법.Preparing a polyester resin containing 0.01 to 1.0 parts by weight of a sulfonic acid metal salt derivative having an acid value of 1.0 mgKOH / g or less and 0.005 to 0.5 parts by weight of the hindered phenol compound based on the polyester resin; A primary mixed resin was prepared by compounding by melt-mixing 65 to 95 parts by weight of the polyester resin and 5 to 35 parts by weight of the polyolefin resin based on a melt index of 1.0 to 25 (g / 10 minutes) based on the total polymer. Doing; And drying and melting and compressing the mixed resin to form a sheet and to stretch the mixed resin. 제4항에 있어서, 상기 설폰산 금속염 유도체는 하기 식으로 표시되는 것을 특징으로 하는 고분자 필름dml제조 방법.The method of claim 4, wherein the sulfonic acid metal salt derivative is represented by the following formula. R1- S03MeR 1 -S0 3 Me (상기 식에서 R1은 탄소수 5 내지 20개의 알킬기, Me는 Li, Na, K 및 Mg을 포함하는 알칼리 토금속류 또는 알칼리 금속류 원소중의 어느 하나이다. )(Wherein R 1 is an alkyl group having 5 to 20 carbon atoms, Me is any one of alkaline earth metals or alkali metal elements including Li, Na, K and Mg.) 제4항에 있어서, 상기 폴리올레핀계 수지는 폴리에틸렌, 폴리프로필렌 및 폴리메틸렌으로 이루어진 군에서 선택된 적어도 하나인 것을 특징으로 하는 고분자 필름의 제조 방법.The method of claim 4, wherein the polyolefin-based resin is at least one selected from the group consisting of polyethylene, polypropylene, and polymethylene. 제4항에 있어서, 상기 컴파운딩 용융혼합은 컴파운딩 온도 조건 및 최종 토출 수지 온도 조건이 하기식을 만족하는 것을 특징으로 하는 고분자 필름의 제조 방법. 가) 컴파운딩 온도 조건 200℃〈T1</SB〈250℃, T f=Ti+15℃, 나) 최종 토출 수지 온도 Tf+10℃〈Tp+20℃, 단, Ti는 초기 입구 온도, Tf는 최종 토출 온도, Tp는 최종 토출수지 온도임.The method of manufacturing a polymer film according to claim 4, wherein in the compounding melt mixing, the compounding temperature condition and the final discharge resin temperature condition satisfy the following formula. A) Compounding temperature condition 200 ℃ <T 1 </ SB <250 ℃, T f = T i + 15 ℃, b) Final discharge resin temperature T f + 10 ℃ <T p + 20 ℃, provided T i is Initial inlet temperature, T f is final discharge temperature, T p is final discharge resin temperature. ※ 참고사항 :최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940033120A 1994-12-07 1994-12-07 Polymer film and preparation method thereof KR960022701A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100326564B1 (en) * 1995-03-16 2002-07-27 주식회사 코오롱 Colored polyester film and process for producing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100326564B1 (en) * 1995-03-16 2002-07-27 주식회사 코오롱 Colored polyester film and process for producing the same

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