KR960022669A - Method for preparing biodegradable copolyester - Google Patents
Method for preparing biodegradable copolyester Download PDFInfo
- Publication number
- KR960022669A KR960022669A KR1019940036638A KR19940036638A KR960022669A KR 960022669 A KR960022669 A KR 960022669A KR 1019940036638 A KR1019940036638 A KR 1019940036638A KR 19940036638 A KR19940036638 A KR 19940036638A KR 960022669 A KR960022669 A KR 960022669A
- Authority
- KR
- South Korea
- Prior art keywords
- biodegradable
- producing
- aliphatic polyester
- polyester
- aliphatic
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/62—Carboxylic acid esters
- C12P7/625—Polyesters of hydroxy carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2230/00—Compositions for preparing biodegradable polymers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
본 발명은 생분해성 공중합 폴리에스터의 제조방법에 관한 것이다. 좀 더 구체적으로, 본 발명은 미생물 발효에 의해 합성된 지방족 폴리에스터를 화학적으로 합성된 지방족 폴리에스터와 에스테르 교환반응시켜 다양한 구조와 물성을 지닌 생분해성 공중합 폴리에스터의 제조방법에 관한 것이다. 본 발명의 생분해성 공중합 폴리에스터는 미생물합성 지방족 폴리에스터를 질소분위기와 용매 및 촉매의 존재하에서 화학합성 지방족 폴리에스터와 에스테르 교환반응시켜 제조되며, 본 발명에 의해 우수한 생분해성을 유지하면서도 다양한 분자구조와 물성을 지닌 생분해성 공중합 폴리에스터를 간단히 제조할 수 있다는 것이 확인되었다.The present invention relates to a process for the preparation of biodegradable copolymerized polyester. More specifically, the present invention relates to a method for producing a biodegradable copolymer polyester having various structures and properties by transesterification of the aliphatic polyester synthesized by microbial fermentation with the chemically synthesized aliphatic polyester. The biodegradable copolyester of the present invention is prepared by transesterification of a biosynthetic aliphatic polyester with a chemical synthetic aliphatic polyester in the presence of a nitrogen atmosphere, a solvent and a catalyst, and various molecular structures while maintaining excellent biodegradability according to the present invention. It was confirmed that biodegradable copolyester having physical and physical properties can be easily produced.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.
제1도는 본 발명의 일 실시예에 의해 제조된 공중합 폴리에스터의 NMR 스펙트럼이다.1 is an NMR spectrum of a copolyester prepared by one embodiment of the present invention.
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019940036638A KR0158428B1 (en) | 1994-12-24 | 1994-12-24 | Process for preparing biodegradable polyester copolymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019940036638A KR0158428B1 (en) | 1994-12-24 | 1994-12-24 | Process for preparing biodegradable polyester copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960022669A true KR960022669A (en) | 1996-07-18 |
KR0158428B1 KR0158428B1 (en) | 1999-01-15 |
Family
ID=19403403
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940036638A KR0158428B1 (en) | 1994-12-24 | 1994-12-24 | Process for preparing biodegradable polyester copolymer |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR0158428B1 (en) |
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1994
- 1994-12-24 KR KR1019940036638A patent/KR0158428B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR0158428B1 (en) | 1999-01-15 |
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