KR960014253A - Thermoplastic resin composition - Google Patents

Thermoplastic resin composition Download PDF

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Publication number
KR960014253A
KR960014253A KR1019940027562A KR19940027562A KR960014253A KR 960014253 A KR960014253 A KR 960014253A KR 1019940027562 A KR1019940027562 A KR 1019940027562A KR 19940027562 A KR19940027562 A KR 19940027562A KR 960014253 A KR960014253 A KR 960014253A
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South Korea
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weight
phosphate
resin composition
component
thermoplastic resin
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KR1019940027562A
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Korean (ko)
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KR100232656B1 (en
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박영선
김석준
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성재갑
주식회사 엘지화학
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Publication of KR960014253A publication Critical patent/KR960014253A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/18—Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 (A) 방향족 폴리카보네이트 수지 10∼90중량%, (B) 스티렌계 수지 10∼90중량% (C) 다음 일반식(Ⅰ)로 나타내는 인산 에스테르계 화합물 2∼20중량%The present invention is (A) 10 to 90% by weight aromatic polycarbonate resin, (B) 10 to 90% by weight styrene resin (C) 2 to 20% by weight phosphate ester compound represented by the following general formula (I)

상기식에서, n은 10 이하의 정수이고, Ar은 아릴그룹이며 알킬그룹으로도 치환될 수 있고, R1,R2는 방향족기이다. (D) 폴리아릴레이트 수지 1∼50중량% (E) 수산화실리케이트 또는 수산화알루미늄 실리케이트 0.01∼30중량% (F) 폴리테트라플루오로에틸렌 0.1∼10중량%로 구성됨을 특징으로 하는 난연성, 열적특성, 고화속도 및 물성이 우수한 열가소성 수지 조성물에 관한 것이다.Wherein n is an integer of 10 or less, Ar is an aryl group and may be substituted with an alkyl group, and R 1 and R 2 are aromatic groups. (D) 1 to 50% by weight of polyarylate resin (E) 0.01 to 30% by weight of silicate or aluminum hydroxide silicate (F) flame retardancy, thermal characteristics, characterized in that it consists of 0.1 to 10% It relates to a thermoplastic resin composition excellent in solidification rate and physical properties.

Description

열가소성 수지 조성물Thermoplastic resin composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (8)

(A) 방향족 폴리카보네이트 수지 10∼90중량%, (B) 스티렌계 수지 10∼90중량% (C) 다음 일반식(Ⅰ)로 나타내는 인산 에스테르계 화합물 2∼20중량%(A) 10 to 90% by weight of aromatic polycarbonate resin, (B) 10 to 90% by weight of styrene resin (C) 2 to 20% by weight of phosphate ester compound represented by the following general formula (I) 상기식에서, n은 10 이하의 정수이고, Ar은 아릴그룹이며 알킬그룹으로도 치환될 수 있고, R1,R2는 방향족기이다. (D) 폴리아릴레이트 수지 1∼50중량% (E) 수산화실리케이트 또는 수산화알루미늄 실리케이트 0.01∼30중량% (F) 폴리테트라플루오로에틸렌 0.1∼10중량%로 구성됨을 특징으로 하는 난연성, 열적특성, 고화속도 및 물성이 우수한 열가소성 수지 조성물.Wherein n is an integer of 10 or less, Ar is an aryl group and may be substituted with an alkyl group, and R 1 and R 2 are aromatic groups. (D) 1 to 50% by weight of polyarylate resin (E) 0.01 to 30% by weight of silicate or aluminum hydroxide silicate (F) flame retardancy, thermal characteristics, characterized in that it consists of 0.1 to 10% Thermoplastic resin composition excellent in solidification rate and physical properties. 제1항에 있어서, (A) 성분의 방향족 폴리카보네이트 수지는 수평균 분자량이 1,000∼200,000임을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein the aromatic polycarbonate resin of component (A) has a number average molecular weight of 1,000 to 200,000. 제1항에 있어서, (B) 성분의 스티렌계 수지는 스티렌계 단량체의 단독중합체이거나 공단량체로서 알파－메틸스티렌, 아크릴로니트릴, 메틸메타크릴레이트를 함유하는 공중합체, HIPS, ABS, AES, AAS, MBS 수지중에서 1종 이상을 사용함을 특징으로 하는 열가소성 수지 조성물.The styrene resin of claim 1, wherein the styrene resin of component (B) is a homopolymer of styrene monomer or a copolymer containing alpha-methylstyrene, acrylonitrile, methyl methacrylate as a comonomer, HIPS, ABS, AES, A thermoplastic resin composition characterized by using at least one of AAS and MBS resin. 제1항 또는 제3항에 있어서, (B) 성분의 스티렌계 수지는 (B) 성분의 사용범위 내에서 ABS 수지 10∼90중량%와 SAN 수지 40중량%로 이하로 사용됨을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin according to claim 1 or 3, wherein the styrene resin of component (B) is used in an amount of 10 to 90% by weight of ABS resin and 40% by weight of SAN resin within the range of use of component (B). Resin composition. 제1항에 있어서, (C) 성분의 인산에스테르계 화합물은 트리페닐포스페이트, 폴리(아릴－아릴렌 포스페이트), 폴리 (아릴－아릴렌 포스포네이트), 디페닐옥틸 포스페이트, 알킬아릴포스페이트, 크레질디페닐포스페이트, 트리부틸포스페이트, 트리부톡시에틸포스페이트, 트리에틸포스페이트, 트리옥틸포스페이트, 트리크레질포스페이트, 트리클로로에틸포스페이트임을 특징으로 하는 열가소성 수지 조성물.The phosphate ester compound of component (C) is triphenylphosphate, poly (aryl-arylene phosphate), poly (aryl-arylene phosphonate), diphenyloctyl phosphate, alkylarylphosphate, crease. A thermoplastic resin composition characterized in that the diphenyl phosphate, tributyl phosphate, tributoxy ethyl phosphate, triethyl phosphate, trioctyl phosphate, tricresyl phosphate, trichloroethyl phosphate. 제1항에 있어서, (D) 성분의 폴리아릴레이트 수지는 방향족 디카르복실산(aromatic dicarboxylicacid)과 디히드릭 페놀(dihydric phenol)의 반응 및 테레프탈산 또는 이소프탈산과 비스페놀 A의 공중합체로 제조되는 방향족 폴리에스테르 임을 특징으로 하는 열가소성 수지 조성물.The polyarylate resin according to claim 1, wherein the polyarylate resin of component (D) is made of a reaction of aromatic dicarboxylic acid with dihydric phenol and a copolymer of terephthalic acid or isophthalic acid and bisphenol A. Thermoplastic resin composition characterized in that the aromatic polyester. 제1항에 있어서, (E) 성분의 수산화 실리케이트는 아스베스토스(asbestos), 다이아토마이트(diatomite), 파이로필라이트(pyrophillite), 퍼라이트(perlite) 및 탈크로서 평균입자 직경이 0.1∼20μm임을 특징으로 하는 열가소성 수지 조성물.The hydroxide silicate of component (E) is asbestos, diatomite, pyrophillite, perlite and talc, and has an average particle diameter of 0.1 to 20 µm. A thermoplastic resin composition. 제1항에 있어서, (E) 성분의 수산화알루미늄 실리케이트는 카올린, 카올리나이트(kaolinite), 내크라이트(nacrite), 디카이트(dickite) 및 할로이사이트(halloysite)로서 소성(calcination) 또는 반소성의 후가공된 것으로 평균입자직경이 2μm 이하가 60% 이상 함유됨을 특징으로 하는 열가소성 수지 조성물.The aluminum hydroxide silicate of component (E) is post-calcined or semi-baked as kaolin, kaolinite, nacrite, dickite and halloysite. A thermoplastic resin composition, characterized in that the average particle diameter is 2% or less, 60% or more. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940027562A 1994-10-27 1994-10-27 Thermoplastic resin composition KR100232656B1 (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030003362A (en) * 2001-06-30 2003-01-10 심대근 Door panel composed of burning resist plastics
KR100425981B1 (en) * 1998-12-24 2004-08-02 제일모직주식회사 Flame-retardant polycarbonate-based plastic resin composition
WO2006041237A1 (en) * 2004-10-13 2006-04-20 Cheil Industries Inc. Flame retardant thermoplastic resin composition
US9790362B2 (en) 2014-06-27 2017-10-17 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and molded article made using the same
US9850333B2 (en) 2014-06-27 2017-12-26 Lotte Advanced Materials Co., Ltd. Copolymers and thermoplastic resin composition including the same
US9856371B2 (en) 2014-06-27 2018-01-02 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and low-gloss molded article made therefrom
US9862822B2 (en) 2014-11-18 2018-01-09 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and molded article made using the same
US9902850B2 (en) 2014-06-26 2018-02-27 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100374258B1 (en) * 2000-10-04 2003-03-04 주식회사 나노코 Fire retardant composition containing nanoclay and method for producing the fire retardant composition
KR100877296B1 (en) 2007-12-31 2009-01-07 제일모직주식회사 Scratch-resistant flame retardant thermoplastic resin composition
KR101234601B1 (en) * 2009-12-31 2013-02-19 제일모직주식회사 Novel phosphoanate based compound and flame retardant thermoplastic resin composition　including the same
WO2014104847A1 (en) * 2012-12-27 2014-07-03 제일모직주식회사 Polycarbonate resin composition having excellent light transmission and flame retardancy

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100425981B1 (en) * 1998-12-24 2004-08-02 제일모직주식회사 Flame-retardant polycarbonate-based plastic resin composition
KR20030003362A (en) * 2001-06-30 2003-01-10 심대근 Door panel composed of burning resist plastics
WO2006041237A1 (en) * 2004-10-13 2006-04-20 Cheil Industries Inc. Flame retardant thermoplastic resin composition
US8119726B2 (en) 2004-10-13 2012-02-21 Cheil Industries Inc. Flame retardant thermoplastic resin composition
US9902850B2 (en) 2014-06-26 2018-02-27 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition
US9790362B2 (en) 2014-06-27 2017-10-17 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and molded article made using the same
US9850333B2 (en) 2014-06-27 2017-12-26 Lotte Advanced Materials Co., Ltd. Copolymers and thermoplastic resin composition including the same
US9856371B2 (en) 2014-06-27 2018-01-02 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and low-gloss molded article made therefrom
US9862822B2 (en) 2014-11-18 2018-01-09 Lotte Advanced Materials Co., Ltd. Thermoplastic resin composition and molded article made using the same

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