KR960010716A - Aliphatic Copolyester and Blown Film Made Using the Same - Google Patents

Aliphatic Copolyester and Blown Film Made Using the Same Download PDF

Info

Publication number
KR960010716A
KR960010716A KR1019940024774A KR19940024774A KR960010716A KR 960010716 A KR960010716 A KR 960010716A KR 1019940024774 A KR1019940024774 A KR 1019940024774A KR 19940024774 A KR19940024774 A KR 19940024774A KR 960010716 A KR960010716 A KR 960010716A
Authority
KR
South Korea
Prior art keywords
residues
residue
mol
acid
compound
Prior art date
Application number
KR1019940024774A
Other languages
Korean (ko)
Inventor
임대우
김대진
이명섭
이창수
김현직
Original Assignee
박홍기
제일합섬 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박홍기, 제일합섬 주식회사 filed Critical 박홍기
Priority to KR1019940024774A priority Critical patent/KR960010716A/en
Publication of KR960010716A publication Critical patent/KR960010716A/en

Links

Abstract

본 발명은 신규한 지방족 공중합 폴리에스터 및 이를 이용하여 제조한 블로우 필름에 관한 것으로, 좀 더 구체적으로는 산성분의 잔기의 구성이 석신산 95~70몰%와 아디프산 5~30몰%을 사용하여 디올 잔기는 1,6-헥산디올 잔기 5~40몰%와 1,4-부탄디올 잔기 95~60몰% 구성된 화합물 또는 1,6-헥산디올 잔기를 단독 사용하며, 3관능 이상의 다관능성을 갖는 화합물 잔기가 산 잔기일 경우 산성분의 잔기에 대해 알콜 잔기인 경우 디올 잔기에 대해 0.01~1몰% 비율로 구성된 고유점도가 1.0 이상이며, 우수한 용융강도를 갖는 신규한 지방족 공중합 폴리에스터 및 이를 원용 중공다이를 통해 용융, 압출 및 연신하여 제조한 블로우 필름(blown-film)에 관한 것이다.The present invention relates to a novel aliphatic copolyester and a blown film prepared using the same. More specifically, the acid residues are composed of 95 to 70 mol% of succinic acid and 5 to 30 mol% of adipic acid. The diol residue may be a compound consisting of 5 to 40 mol% of 1,6-hexanediol residues and 95 to 60 mol% of 1,4-butanediol residues or 1,6-hexanediol residues alone, When the compound residue having an acid residue is an alcohol residue with respect to the residue of the acid component is a novel aliphatic copolymer polyester having an intrinsic viscosity of 1.0 to 1 mol% relative to the diol residue is 1.0 or more, and excellent melt strength and A blown film (blown-film) prepared by melting, extruding and stretching through a raw hollow die.

Description

지방족 공중합 폴리에스터 및 이를 이용하여 제조한 블로우 필름(blown-film)Aliphatic Copolyester and Blown Film Made Using the Same

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

석신산 화합물 잔기와 아디프산 잔기로 구성되는 산성분 잔기, 1,6-헥산디올 잔기와 1,4-부탄디올 잔기 혼합 또는 1,6-헥산디올 잔기 단독으로 구성되는 디올 잔기 및 3관능기 이상의 다관능성 화합물 잔기로 구성됨을 특징으로 하는 고유점도 1.0 이상의 지방족 공중합 폴리에스터.Acid component residues consisting of succinic acid compound residues and adipic acid residues, mixed 1,6-hexanediol residues and 1,4-butanediol residues, or diol residues consisting of 1,6-hexanediol residues alone and polyfunctional or more than three functional groups An aliphatic copolymer having an intrinsic viscosity of at least 1.0, characterized in that it consists of a functional compound residue. 제1항에 있어서, 석신산 화합물 잔기는 석신산, 석신산 무수화합물, 또는 석신산 에스테르 화합물 잔기중에서 선택된 것임을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolymer polyester of claim 1 wherein the succinic acid compound residues are selected from succinic acid, succinic anhydride compounds, or succinic acid ester compound residues. 제2항에 있어서, 산성분 잔기는 석신산 화합물 잔기 95~70몰%와 아디프산 잔기 5~30몰%로 구성됨을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolymer polyester according to claim 2, wherein the acid component residues are composed of 95 to 70 mol% of succinic acid compound residues and 5 to 30 mol% of adipic acid residues. 제1항에 있어서, 1,6-헥산디올 잔기와 1,4-부탄디올 잔기의 혼합물은 1,6-헥산디올 잔기 5~40몰%와 1,4-부탄디올 잔기 95~60몰%로 구성됨을 특징으로 하는 지방족 공중합 폴리에스터.The method of claim 1, wherein the mixture of 1,6-hexanediol residues and 1,4-butanediol residues comprises 5-40 mol% of 1,6-hexanediol residues and 95-60 mol% of 1,4-butanediol residues. An aliphatic copolyester characterized by the above. 제1항에 있어서, 다관능성 화합물 잔기는 산 잔기인 경우 산성분에 대해, 알콜 잔기인 경우 디올 잔기에 대해 0.01~1몰%로 구성됨을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolymer polyester according to claim 1, wherein the polyfunctional compound residue is composed of 0.01 to 1 mol% relative to the acid component in the case of an acid residue and diol residue in the case of an alcohol residue. 제1항에 있어서, 3관능 이상의 다관능성 화합물 잔기가 트리메리트산 잔기임을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolyester according to claim 1, wherein the trifunctional or higher trifunctional compound residue is a trimellitic acid residue. 제1항에 있어서, 3관능 이상의 다관능성 화합물 잔기가 트리메틸올프로판 잔기임을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolymer polyester according to claim 1, wherein the trifunctional or higher trifunctional compound residue is a trimethylolpropane residue. 제1항에 있어서, 3관능 이상의 다관능성 화합물 잔기가 트리메틸올에탄 잔기임을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolyester according to claim 1, wherein the trifunctional or higher trifunctional compound residue is a trimethylolethane residue. 제1항에 있어서, 3관능 이상의 다관능성 화합물 잔기가 글리세린 잔기임을 특징으로 하는 지방족 공중합 폴리에스터.The aliphatic copolymer polyester according to claim 1, wherein the trifunctional or higher trifunctional compound residue is a glycerin residue. 제1항 기재의 지방족 공중합 폴리에스터를 원형중공 다이를 통해 위 또는 아래의 방향으로 용융, 압출 및 연신하여 제조함을 특징으로 하는 블로우 필름.A blow film, which is prepared by melting, extruding and stretching the aliphatic copolyester according to claim 1 in an upward or downward direction through a circular hollow die. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940024774A 1994-09-29 1994-09-29 Aliphatic Copolyester and Blown Film Made Using the Same KR960010716A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019940024774A KR960010716A (en) 1994-09-29 1994-09-29 Aliphatic Copolyester and Blown Film Made Using the Same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019940024774A KR960010716A (en) 1994-09-29 1994-09-29 Aliphatic Copolyester and Blown Film Made Using the Same

Publications (1)

Publication Number Publication Date
KR960010716A true KR960010716A (en) 1996-04-20

Family

ID=66766741

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940024774A KR960010716A (en) 1994-09-29 1994-09-29 Aliphatic Copolyester and Blown Film Made Using the Same

Country Status (1)

Country Link
KR (1) KR960010716A (en)

Similar Documents

Publication Publication Date Title
KR960705876A (en) PLASTICIZED POLYESTER FOR SHRINK FILM APPLICATIONS
KR880011274A (en) Manufacturing method of thermoplastic resin composition
KR900018266A (en) Preparation of Thermoplastic Elastomer Compositions
KR910014426A (en) Polymer film
KR950014173A (en) Method for producing film using aliphatic copolyester
KR920008138A (en) Thermoplastic Elastomer Composition
KR960010716A (en) Aliphatic Copolyester and Blown Film Made Using the Same
KR970062122A (en) METHOD FOR MANUFACTURING A FLAT YARN OF ALPHA COPOLYMER POLYESTER
JPS57189823A (en) Production of polyester film
US6630230B2 (en) Polyester resin composition and film using the same
KR960022656A (en) Aliphatic Copolyester and Blown Film Made Using the Same
KR960000948A (en) Aliphatic Copolyester and Blow Film Prepared Using the Same
DE69722997D1 (en) Process for the production of polyester resins
KR970701755A (en) Copolymers of recycled polyesters
KR960031537A (en) Method for producing flame retardant thermoplastic polyester resin composition
JP2001354842A (en) Polyester composition for calender forming
KR970010870A (en) Manufacturing method of biodegradable resin
KR920008139A (en) Manufacturing method of impact resistant polyester resin composition
KR910700310A (en) A mixture of polyester and polycarbonate made of 4,4-biphenyldicarboxylic acid and 1,6-hexanediol
KR960022658A (en) Thermoplastic Aliphatic Polyester Resin And Manufacturing Method Thereof
KR960022659A (en) Thermoplastic aliphatic polyester resin excellent in moldability and manufacturing method thereof
KR970042819A (en) Polyester resin composition for extrusion blow molding
KR940014637A (en) Manufacturing method of biodegradable resin
KR950018208A (en) Manufacturing method of biodegradable resin
JP2001192019A (en) Creased sheet and plastic case using the same

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application