KR960001099A - Granular high density nonionic detergent composition and preparation method thereof - Google Patents

Granular high density nonionic detergent composition and preparation method thereof Download PDF

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KR960001099A
KR960001099A KR1019940014860A KR19940014860A KR960001099A KR 960001099 A KR960001099 A KR 960001099A KR 1019940014860 A KR1019940014860 A KR 1019940014860A KR 19940014860 A KR19940014860 A KR 19940014860A KR 960001099 A KR960001099 A KR 960001099A
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weight
detergent composition
nonionic
nonionic surfactant
fatty acid
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KR1019940014860A
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KR960015153B1 (en
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백인섭
김혁
김원종
최형오
김용철
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최무섭
애경산업 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/02—Preparation in the form of powder by spray drying
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 비이온 계면활성제를 주 세정기제로 하며 오염제거에 복합상승작용을 나타내기 위해 음이온 계면 활성제를 동시에 함유한 비이온성 분말세제조성물에 관한 것으로서, 본 발명에 의하여 1단계로 음이온 계면활성제를 함유하는 기본분말을 제조하여 2단계로 고속 혼합기/과립화기내에서 기본분말, 결정성알루미노규산염, 탄산나트륨, 다공질의 흡유성 운반체 등에 고농도로 비이온 계면활성제를 분무혼합한 평균입경 200-1000㎛, 겉보기 밀도 750g/l 이상인 과립형 고밀도 비이온성 분말세제 조성물이 제공한다. 이러한 본 발명의 세제조성물은 상온에서 액체인 비이온 계면활성제의 누액이 없고 분말의 유동성 및 내케이킹성에 있어서 우수한 신규유용의 세제조성물이다.The present invention relates to a nonionic powder detergent composition containing a nonionic surfactant as a main cleaning agent and simultaneously containing an anionic surfactant in order to exhibit a complex synergism in decontamination. The anionic surfactant is contained in one step according to the present invention. The average particle size 200-1000㎛, which was prepared by spraying and mixing a high concentration of nonionic surfactant in a high-speed mixer / granulator in a high-speed mixer / granulator in two steps. A granular high density nonionic powder detergent composition having an apparent density of at least 750 g / l is provided. The detergent composition of the present invention is a novel useful detergent composition having no leakage of nonionic surfactant which is liquid at room temperature and excellent in fluidity and caking resistance of the powder.

Description

과립형 고밀도 비이온성 세제조성물 및 그 제조방법Granular high density nonionic detergent composition and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (11)

다음의 조성으로 되는 평균입경 200-1000㎛, 겉보기 밀도(Bulk Density) 750g/l 이상의 과립형 고밀도 비이온성 세제조성물 : (a) 음이온 계면활성제 20-45중랴우, 비이온 계면활성제 0-5중량부, 및 통상의 세정보조첨가제 50-75중량부를 함유하는 기본분말, 10-30중량%: (b)과립화를 위하여 상기 기본분말과 배합되는 성분으로서, 비이온 계면활성제 10-25중량%, 결정성 알루미노규산염 20-50중량%, 탄산나트륨 10-35중량% 및 다공질의 흡유성 운반체 0.5-7중량%.Granular high-density nonionic detergent composition with an average particle diameter of 200-1000 µm and a bulk density of 750 g / l or more having the following composition: (a) 20-45 anion surfactant, 0-5 weight of nonionic surfactant Part, and a base powder containing 50 to 75 parts by weight of a conventional fine additive, 10-30% by weight: (b) 10-25% by weight of a nonionic surfactant as a component blended with the base powder for granulation, 20-50% by weight crystalline aluminosilicate, 10-35% by weight sodium carbonate and 0.5-7% by weight porous oil-absorbing carrier. 제1항에 있어서 음이온 계면활성제는 직쇄알킬벤젠술폰산염, 알킬 또는 알켄일황산염, α-올레핀술폰산염, α-술포지방산에스테르염, 지방산염, 알킬 또는 알케일에테르카르복시산염, 알칸술폰산염, 술포호박산알킬에스테르염, 아실아미노알칸술폰산염, 알킬 또는 알켄일에스테르 또는 그의 염 등으로부터 선택되는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.The anionic surfactant according to claim 1 is a linear alkylbenzene sulfonate, alkyl or alkenyl sulfate, α-olefin sulfonate, α-sulfo fatty acid ester salt, fatty acid salt, alkyl or alkale ether carboxylate, alkanesulfonate, sulfo A granular high density nonionic detergent composition, which is selected from succinic acid alkyl ester salts, acylamino alkanesulfonates, alkyl or alkenyl esters or salts thereof. 제1항에 있어서, 비이온 계면활성제는 40℃이하에서 액체 또는 페이스트(paste)를 형성하며 HLB 가 5-15를 갖는 것으로서, 폴리옥시에틸렌알킬에테르, 폴리옥시에틸렌솔비탄지방산에스테르, 슈가지방산에스테르, 솔비탄지방산에스테르, 폴리옥시에틸렌솔비탄지방산에스테르, 폴리옥시에틸렌지방산에스테르, 지방산알카놀아미드 등으로부터 선택되는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.The nonionic surfactant according to claim 1, wherein the non-ionic surfactant forms a liquid or paste at 40 ° C. or lower and has a HLB of 5-15. Polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, and sugar fatty acid ester And sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid ester, fatty acid alkanolamide and the like. 제3항에 있어서, 비이온 계면활성제는 알킬기의 평균 탄소수가 6-22인 직쇄 또는 분지쇄 1급 또는 2급의 알코올의 에틸렌옥사이드 평균 부가몰수가 3-20인 폴리옥시에틸렌알킬에테르인 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.4. The nonionic surfactant according to claim 3, wherein the nonionic surfactant is a polyoxyethylene alkyl ether having an average added mole number of 3-20 of ethylene oxide of a linear or branched chain primary or secondary alcohol having an average carbon number of 6-22 alkyl group. Granular high density nonionic detergent composition. 제4항에 있어서, 폴리옥시에틸렌알킬에테르는 알킬기의 평균 탄소수가 10-20인 직쇄 또는 분지쇄 1급 또는 2급 알코올의 에틸렌옥사이드 평균 부가몰수가 5-5인 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.The polyoxyethylene alkyl ether according to claim 4, wherein the polyoxyethylene alkyl ether has an average added mole number of 5-5 ethylene oxide of a linear or branched primary or secondary alcohol having an average carbon number of 10-20 alkyl groups. Mild detergent composition. 제1항에 있어서, 다공질의 흡유성 운반체는 수은다공도 측정법으로 100-600㎠/100g의 다공규격, BET법으로 측정하였을 때 20-700㎡/g의 비표면적, 그리고 KSM6558에 따른 측정법으로 100㎖/100g 또는 그 이상의 흡유성을 갖는, 비정질 실리카, 비정질 알루미노규산염 또는 이들의 혼합물로부터 선택되는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.The porous oil-repellent carrier according to claim 1, wherein the porous oil absorbent carrier has a porosity of 100-600 cm 2/100 g by mercury porosimetry, a specific surface area of 20-700 m 2 / g when measured by BET method, and 100 ml by KSM6558 A granular high density nonionic detergent composition, characterized in that it is selected from amorphous silica, amorphous aluminosilicate, or mixtures thereof having oil absorption of / 100 g or more. 제1항에 있어서, 과립화후의 첨가성분으로 프로테아제, 리파아제, 세룰라아제, 아미라아제등의 효소, 과탄산나트륨, 과붕산나트륨 1 또는 4수화물등의 표백제, 표백활성제, 향료 등의 열민감성 성분을 더 함유하는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물.2. The thermosensitive component according to claim 1, wherein the additive components after granulation are enzymes such as proteases, lipases, cerulases, amirases, bleaches such as sodium percarbonate, sodium perborate 1 or tetrahydrate, bleach activators, and perfumes. A granular high density nonionic detergent composition, further comprising. 다음의 단계로 되는 과립형 고밀도 비이온성 세제조성물의 제조방법 : (1) 건조분말기준으로 음이온 계면활성제 20-45중량부, 건조분말기준으로 비이온 계면활성제 0-5중량부 및 건조분말기준으로 통상의 세정보조첨가제 50-75중량부를 함유하는 수분함량 30-60%의 세제슬러리를 분무건조하여 기본 분말을 준비하는 단계, (2) 고속혼합기/과립화기에서 단계(1)에서 수득된 기본분말 10-30중량%와 탄산나트륨 10-35중량%, 결정성 알루미노규산염 20-50중량%와 다공질흡유성운반체 0.5-7중량% 및 비이온 계면활성제 10-25중량%를 혼합하여 평균입경 200-1000㎛, 겉보기 밀도 750g/l 이상의 과립을 수득하는 단계.Manufacturing method of granular high density nonionic detergent composition having the following steps: (1) 20-45 parts by weight of anionic surfactant on the basis of dry powder, 0-5 parts by weight of nonionic surfactant on the basis of dry powder and dry powder Preparing a basic powder by spray-drying a detergent slurry having a water content of 30-60% containing 50-75 parts by weight of a conventional detergent additive, (2) the basic powder obtained in step (1) in a high speed mixer / granulator 10-30% by weight, 10-35% by weight sodium carbonate, 20-50% by weight crystalline aluminosilicate, 0.5-7% by weight porous oil-absorbing carrier and 10-25% by weight of nonionic surfactant Obtaining granules of at least 1000 μm, apparent density of 750 g / l. 제8항에 있어서, 상기 단계(1)에서 준비되는 기본분말중의 일부 비이온계면활성제와 세정보조첨가제는 세제슬러리의 분무건조후 투여되는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물의 제조방법.The method of claim 8, wherein the nonionic surfactant and the tax aid additive in the basic powder prepared in step (1) are administered after spray drying of the detergent slurry. . 제8항에 있어서, 과립화단계(2)중에 비이온 계면활성제는 분무투여되고, 일부의 결정성 알루미노규산염과 일부의 다공질 흡유성 운반체는 비이온 계면활성제를 분무한 후, 과립화단계의 말기에 표면코팅제로 첨가되는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물의 제조방법.10. The method of claim 8, wherein during the granulation step (2), the nonionic surfactant is sprayed, and some of the crystalline aluminosilicate and some of the porous oil absorbent carriers are sprayed with the nonionic surfactant, A method for producing a granular high density nonionic detergent composition, characterized in that it is added as a surface coating agent at the end. 제8항에 있어서, 과립화단계(2) 후에 프로테아제, 리파아제, 셀룰라아제, 아미라아제등의 효소, 과탄산나트륨, 과붕산나트륨 1 또는 4수화물등의 표백제, 표백활성제, 향료 등의 열민감성 성분을 첨가하는 단계(3)를 더 포함하는 것을 특징으로 하는 과립형 고밀도 비이온성 세제조성물의 제조방법.The method according to claim 8, wherein after the granulation step (2), enzymes such as proteases, lipases, cellulases, amirases, bleaching agents such as sodium percarbonate, sodium perborate 1 or tetrahydrate, bleaching agents, fragrances, and the like are added. Method for producing a granular high-density nonionic detergent composition, characterized in that it further comprises the step (3). ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940014860A 1994-06-27 1994-06-27 Detergent composition and its method KR960015153B1 (en)

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KR960015153B1 KR960015153B1 (en) 1996-11-01

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Cited By (2)

* Cited by examiner, † Cited by third party
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KR100361131B1 (en) * 1998-12-31 2003-02-14 주식회사 엘지씨아이 Laundry powder detergent with high deusity and method of prepairing the same
KR100448993B1 (en) * 1997-09-09 2004-11-26 씨제이 주식회사 Particulate high-density non-ionic detergent composition having excellent flowability, solubility and cleaning power, and preparation thereof

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Publication number Priority date Publication date Assignee Title
KR100448993B1 (en) * 1997-09-09 2004-11-26 씨제이 주식회사 Particulate high-density non-ionic detergent composition having excellent flowability, solubility and cleaning power, and preparation thereof
KR100361131B1 (en) * 1998-12-31 2003-02-14 주식회사 엘지씨아이 Laundry powder detergent with high deusity and method of prepairing the same

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