KR950704233A - Benzoylcyclohexenone, preparation method thereof, and their use as herbicide and plant growth regulator (BENZOYLCYCLOHEXENONES, METHODS OF PREPARING THEM AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS) - Google Patents
Benzoylcyclohexenone, preparation method thereof, and their use as herbicide and plant growth regulator (BENZOYLCYCLOHEXENONES, METHODS OF PREPARING THEM AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS)Info
- Publication number
- KR950704233A KR950704233A KR1019950702368A KR19950702368A KR950704233A KR 950704233 A KR950704233 A KR 950704233A KR 1019950702368 A KR1019950702368 A KR 1019950702368A KR 19950702368 A KR19950702368 A KR 19950702368A KR 950704233 A KR950704233 A KR 950704233A
- Authority
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- South Korea
- Prior art keywords
- alkyl
- compound
- halogen
- formula
- alkoxy
- Prior art date
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/48—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —S—C≡N groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/45—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by at least one doubly—bound oxygen atom, not being part of a —CHO group
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
- C07C205/56—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups bound to carbon atoms of six-membered aromatic rings and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
- C07C255/40—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by doubly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
- C07C255/41—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/45—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C255/46—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of non-condensed rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/56—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and doubly-bound oxygen atoms bound to the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C261/00—Derivatives of cyanic acid
- C07C261/02—Cyanates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/24—Sulfones; Sulfoxides having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
- C07C331/02—Thiocyanates
- C07C331/06—Thiocyanates having sulfur atoms of thiocyanate groups bound to carbon atoms of rings other than six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/80—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
- C07C49/813—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen polycyclic
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
하기 일반식(Ⅰ)의 화합물은 선택적인 제초제 또는 식물 생장조절제로서 본 발명에 따라 적합하다;The compounds of formula (I) are suitable according to the invention as selective herbicides or plant growth regulators;
상기 식에서, n은 0 내지 6의 정수이고, X는 할로겐, CN, OCN, SCN, C2-C4-알키닐 또는 CHR5R6이고, R5및 R6은 서로 독립적으로 CN, NO2, 포르밀, 임의적으로 할로-치환된 (C1-C4-알킬)카보닐, 임의적으로 할로-치환된(C1-C4-알콕시)-카보닐 또는 임의적으로 치환된 페닐카보닐이며, R1은 임의적으로 할로-치환된 C1-C4-알킬, 임의적으로 할로-치환된 C3-C6-사이클로알킬 또는 임의적으로 치환된 페닐이고, R2는 할로겐, CN, NO2, C1-C3-알킬, C1-C3-알콕시, C1-C3-할로알킬, C1-C3-할로알콕시 또는 R7S(O)m-이고, R7은 C1-C3-알킬이며, m은 0, 1 또는 2이고, R3은 H, 할로겐, OH, C1-C3-알킬, C1-C3-알콕시, C1-C3-할로알킬, C1-C3-할로알콕시 또는 (C1-C3-알콕시)카보닐이고, R4는 H, CN, NO2, 할로겐, C1-C3할로알킬, -C1-C3-할로알콕시 또는 R8S(O)p-이고, R8은 C1-C3-알킬이며, p는 0, 1 또는 2이다.Wherein n is an integer from 0 to 6, X is halogen, CN, OCN, SCN, C 2 -C 4 -alkynyl or CHR 5 R 6 , and R 5 and R 6 are independently of each other CN, NO 2 , Formyl, optionally halo-substituted (C 1 -C 4 -alkyl) carbonyl, optionally halo-substituted (C 1 -C 4 -alkoxy) -carbonyl or optionally substituted phenylcarbonyl, R 1 is optionally halo-substituted C 1 -C 4 -alkyl, optionally halo-substituted C 3 -C 6 -cycloalkyl or optionally substituted phenyl, R 2 is halogen, CN, NO 2 , C 1- C 3 -alkyl, C 1 -C 3 -alkoxy, C 1 -C 3 -haloalkyl, C 1 -C 3 -haloalkoxy or R 7 S (O) m- , R 7 is C 1 -C 3 -alkyl, m is 0, 1 or 2, R 3 is H, halogen, OH, C 1 -C 3 -alkyl, C 1 -C 3 -alkoxy, C 1 -C 3 -haloalkyl, C 1 -C 3 -haloalkoxy or (C 1 -C 3 -alkoxy) carbonyl, R 4 is H, CN, NO 2 , halogen, C 1 -C 3 haloalkyl, -C 1 -C 3 -haloalkoxy or R 8 S (O) p −, R 8 is C 1 -C 3 -alkyl and p is 0, 1 or 2.
이들 화합물은 X가 C1인 일반식(Ⅰ)의 화합물을 제외하고는 신규하다.These compounds are novel except for compounds of formula (I) wherein X is C1.
다양한 방법에 의해 2-벤조일-1,3-사이클로헥산디온으로부터 이들을 제조할 수 있다.These can be prepared from 2-benzoyl-1,3-cyclohexanedione by various methods.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4241999.9 | 1992-12-12 | ||
DE4241999A DE4241999A1 (en) | 1992-12-12 | 1992-12-12 | Benzoylcyclohexenones, process for their preparation and their use as herbicides and plant growth regulators |
PCT/EP1993/003385 WO1994013619A1 (en) | 1992-12-12 | 1993-12-02 | Benzoylcyclohexenones, methods of preparing them and their use as herbicides and plant-growth regulators |
Publications (1)
Publication Number | Publication Date |
---|---|
KR950704233A true KR950704233A (en) | 1995-11-17 |
Family
ID=6475127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950702368A KR950704233A (en) | 1992-12-12 | 1993-12-02 | Benzoylcyclohexenone, preparation method thereof, and their use as herbicide and plant growth regulator (BENZOYLCYCLOHEXENONES, METHODS OF PREPARING THEM AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS) |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0673359A1 (en) |
JP (1) | JPH08504414A (en) |
KR (1) | KR950704233A (en) |
AU (1) | AU5694994A (en) |
BR (1) | BR9307631A (en) |
CA (1) | CA2151498A1 (en) |
DE (1) | DE4241999A1 (en) |
HU (1) | HU9501685D0 (en) |
WO (1) | WO1994013619A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU672058B2 (en) * | 1993-12-30 | 1996-09-19 | Sds Biotech K.K. | Substituted benzoyl cyclic enone, process for preparation, and herbicide |
JP2001525798A (en) * | 1997-05-07 | 2001-12-11 | ビーエーエスエフ アクチェンゲゼルシャフト | Substituted 2- (3-alkenylbenzoyl) cyclohexane-1,3-dione |
DE19846792A1 (en) | 1998-10-10 | 2000-04-13 | Hoechst Schering Agrevo Gmbh | New benzoyl-cycloalkanone and benzoyl-cycloalkanedione derivatives useful as herbicides, especially for selective weed control in crops, and plant growth regulators |
JP4608054B2 (en) * | 2000-06-26 | 2011-01-05 | 株式会社エス・ディー・エス バイオテック | Process for producing substituted benzoylthioether compounds |
EP2229813A1 (en) * | 2009-03-21 | 2010-09-22 | Bayer CropScience AG | Pyrimidine-4-ylpropandinitrile derivatives, method for their manufacture and their use as herbicides and plant growth regulators |
WO2024146512A1 (en) * | 2023-01-03 | 2024-07-11 | 沈阳万菱生物技术有限公司 | Tri-substituted phenyl cyclohexene thioether compound and use thereof |
CN118344301A (en) * | 2023-01-16 | 2024-07-16 | 沈阳万菱生物技术有限公司 | Tetra-substituted cyclohexene thioether compound, preparation method and application thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762551A (en) * | 1986-06-09 | 1988-08-09 | Stauffer Chemical Company | Certain 3-(substituted thio)-2-benzoyl-cyclohex-2-enones |
-
1992
- 1992-12-12 DE DE4241999A patent/DE4241999A1/en not_active Withdrawn
-
1993
- 1993-12-02 WO PCT/EP1993/003385 patent/WO1994013619A1/en not_active Application Discontinuation
- 1993-12-02 BR BR9307631A patent/BR9307631A/en not_active Application Discontinuation
- 1993-12-02 JP JP6513740A patent/JPH08504414A/en active Pending
- 1993-12-02 AU AU56949/94A patent/AU5694994A/en not_active Abandoned
- 1993-12-02 KR KR1019950702368A patent/KR950704233A/en not_active Application Discontinuation
- 1993-12-02 EP EP94902660A patent/EP0673359A1/en not_active Withdrawn
- 1993-12-02 HU HU9501685A patent/HU9501685D0/en unknown
- 1993-12-02 CA CA002151498A patent/CA2151498A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
DE4241999A1 (en) | 1994-06-16 |
CA2151498A1 (en) | 1994-06-23 |
HU9501685D0 (en) | 1995-08-28 |
BR9307631A (en) | 1999-08-24 |
JPH08504414A (en) | 1996-05-14 |
AU5694994A (en) | 1994-07-04 |
EP0673359A1 (en) | 1995-09-27 |
WO1994013619A1 (en) | 1994-06-23 |
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