KR950018409A - Tablet type detergent composition with improved solubility and strength - Google Patents

Tablet type detergent composition with improved solubility and strength Download PDF

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Publication number
KR950018409A
KR950018409A KR1019930031012A KR930031012A KR950018409A KR 950018409 A KR950018409 A KR 950018409A KR 1019930031012 A KR1019930031012 A KR 1019930031012A KR 930031012 A KR930031012 A KR 930031012A KR 950018409 A KR950018409 A KR 950018409A
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South Korea
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weight
alkyl group
carbon atoms
surfactant
tablet
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KR1019930031012A
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KR960007876B1 (en
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곽상운
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최근선
주식회사 엘지화학
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 세정성분으로 음이온성 계면활성물질 10 내지 35중량%, 비이온성 계면활성물질 1 내지 10중량%, 규산소다 5 내지 15중량%, 제올라이트 5 내지 25중량% 및 첨가제 1 내지 10중량%를 포함하는 입상형 세제;코팅성분으로 전분 5 내지 25중량%, 코팅 및 발포성분으로 수용성 고체산 1 내지 20중량%, 발포성분으로 중탄산나트륨 5 내지 40중량%, 결합증진 및 발포성분으로 미중화 산성 계면활성물질 0.1 내지 10중량%를 포함함을 특징으로 하는 정체형 세제 조성물에 관한 것이다.The present invention comprises 10 to 35% by weight of anionic surfactant, 1 to 10% by weight of nonionic surfactant, 5 to 15% by weight of sodium silicate, 5 to 25% by weight of zeolite and 1 to 10% by weight of additive. Granular detergent comprising; 5 to 25% by weight of starch as coating component, 1 to 20% by weight of water soluble solid acid as coating and foaming component, 5 to 40% by weight of sodium bicarbonate as foaming component, unneutralized acidity It relates to a static detergent composition characterized in that it comprises 0.1 to 10% by weight of the surfactant.

Description

용해성 및 강도를 개선한 정제형 세제 조성물Tablet type detergent composition with improved solubility and strength

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (12)

세정성분으로 음이온성 계면활성물질 10 내지 35중량%, 비이온성 계면활성물질 1 내지 10중량%, 규산소다 5 내지 15중량%, 제올라이트 5 내지 25중량% 및 첨가제 1 내지 10중량%를 포함하는 입상형 세제 ; 코팅성분으로 전분 5 내지 25중량%, 코팅 및 발포성분으로 수용성 고체산 1 내지 20중량%, 발포성분으로 중탄산나트륨 5 내지 40중량%, 결합증진 및 발포성분으로 미중화 산성 계면활성물질 0.1 내지 10중량%를 포함함을 특징으로 하는 정제형 세제 조성물.Granules containing 10 to 35% by weight of anionic surfactant, 1 to 10% by weight of nonionic surfactant, 5 to 15% by weight of sodium silicate, 5 to 25% by weight of zeolite and 1 to 10% by weight of additives Type detergent; 5 to 25% by weight of starch as coating component, 1 to 20% by weight of water soluble solid acid as coating and foaming component, 5 to 40% by weight of sodium bicarbonate as foaming component, 0.1 to 10 unneutralized acidic surfactant A tablet detergent composition comprising a weight percent. 제1항에 있어서, 음이온성 계면활성물질이 알킬기의 탄소수 11 내지 17의 알킬벤젠술폰산나트륨, 알킬기의 탄소수 10 내지 18의 알파올레핀술포네이트 및 알킬기의 탄소수 12 내지 18의 알킬술페이트로부터 선택되는 정제형 세제조성물.The tablet according to claim 1, wherein the anionic surfactant is selected from sodium alkylbenzenesulfonate having 11 to 17 carbon atoms in the alkyl group, alphaolefinsulfonate having 10 to 18 carbon atoms in the alkyl group and alkyl sulfate having 12 to 18 carbon atoms in the alkyl group. Type detergent composition. 제1항에 있어서, 비이온성 계면활성물질이 탄소수 11 내지 13의 직쇄알킬기에 7 내지 9몰의 에틸렌옥사이드가 부가된 알킬폴리옥시에틸렌인 정제형 세제조성물.The tablet detergent composition according to claim 1, wherein the nonionic surfactant is alkylpolyoxyethylene to which 7 to 9 mol of ethylene oxide is added to a C11-C13 linear alkyl group. 제1항에 있어서, 첨가제가 소포제, 형광제, 효소, 오염부착방지제 및 향인 정제형 조성물.The tablet composition of claim 1, wherein the additives are antifoams, fluorescent agents, enzymes, antifouling agents, and flavors. 제1항에 있어서, 미중화 산성 계면활성물질이 알킬기의 탄소수 11 내지 17의 알킬벤젠술폰산, 알킬기의 탄소수 10 내지 18의 알파올레핀술폰산 및 알킬기의 탄소수 12 내지 18의 알킬술폰산으로부터 선택되는 정제형 세제조성물.The tablet detergent according to claim 1, wherein the unneutralized acidic surfactant is selected from an alkylbenzenesulfonic acid having 11 to 17 carbon atoms of an alkyl group, an alphaolefinsulfonic acid having 10 to 18 carbon atoms of an alkyl group and an alkylsulfonic acid having 12 to 18 carbon atoms of an alkyl group. Composition. 제5항에 있어서, 미중화 산성 계면활성물질을 메탄올, 에탄올, 프로판올, 부탄올 및 이소프로필알콜 등에 용해시켜 입상형 세제의 과립화 및 코팅에 사용함을 특징으로 하는 정제형 세제조성물.The tablet detergent composition according to claim 5, wherein the unneutralized acidic surfactant is dissolved in methanol, ethanol, propanol, butanol and isopropyl alcohol and used for granulation and coating of the granular detergent. 음이온성 계면활성물질 10 내지 35중량%, 비이온성 계면활성물질 1 내지 10중량%, 규산소다 5 내지 15중량%, 제올라이트 5 내지 35중량% 및 첨가제 1 내지 10중량%를 혼합하여 입상형 세제를 제조하고, 이 입상형 세제의 외부에 미중화산성 계면활성물질 0.1 내지 10중량%를 알콜에 용해시켜 중탄산나트륨 5 내지 40중량%, 전분 5 내지 25중량%와 수용성 고체산 1 내지 20중량%를 코팅시켜 입자크기 600 내지 1400μm의 과립상으로 제조하여 건조시킨후, 코팅된 과립형 세제에 알칼리 금속 탄산염을 첨가, 혼합하여 타정함을 특징으로 하는 정제형 세제조성물의 제조방법.Granular detergent is prepared by mixing 10 to 35% by weight of anionic surfactant, 1 to 10% by weight of nonionic surfactant, 5 to 15% by weight of sodium silicate, 5 to 35% by weight of zeolite and 1 to 10% by weight of additives. 0.1 to 10% by weight of the unneutralized acidic surface active substance was dissolved in alcohol, and 5 to 40% by weight of sodium bicarbonate, 5 to 25% by weight of starch and 1 to 20% by weight of a water-soluble solid acid were prepared. A method of manufacturing a tablet detergent composition characterized in that the coating is prepared by granules having a particle size of 600 to 1400 μm, dried, and then added by mixing and mixing the alkali metal carbonate to the coated granular detergent. 제7항에 있어서, 음이온성 계면활성물질이 알킬기의 탄소수 11 내지 17의 알킬벤젠술폰산나트륨, 알킬기의 타소수 10 내지 18의 알파올레핀술포네이트 및 알킬기의 탄소수 12 내지 18의 알킬술페이트로부터 선택되는 정제형 세제조성물의 제조방법.8. The anionic surfactant according to claim 7, wherein the anionic surfactant is selected from sodium alkylbenzenesulfonate having 11 to 17 carbon atoms of the alkyl group, alphaolefin sulfonate having 10 to 18 carbon atoms of the alkyl group and alkyl sulfate having 12 to 18 carbon atoms of the alkyl group. Method for producing a tablet detergent composition. 제7항에 있어서, 비이온성 계면활성물질이 탄소수 11 내지 13의 직쇄알킬기에 7 내지 9몰의 에틸렌옥사이드가 부가된 알킬폴리옥시에틸렌인 정제형 세제조성물의 제조방법.8. The method for producing a tablet detergent composition according to claim 7, wherein the nonionic surfactant is an alkylpolyoxyethylene having 7 to 9 moles of ethylene oxide added to a C11-C13 linear alkyl group. 제7항에 있어서, 첨가제가 소포제, 형광제, 효소, 오염부착 방지제 및 향인 정제형 세제조성물의 제조방법.8. The method of claim 7, wherein the additive is an antifoaming agent, a fluorescent agent, an enzyme, an antifouling agent, and a fragrance. 제7항에 있어서, 미중화 산성 계면활성물질이 알킬기의 탄소수 11 내지 17의 알킬벤젠술폰산, 알킬기의 탄소수 10 내지 18의 알파올레핀술폰산 및 알킬기의 탄소수 12 내지 18의 알킬술폰산으로부터 선택되는 정제형 세제조성물의 제조방법.The tablet detergent according to claim 7, wherein the unneutralized acidic surfactant is selected from an alkylbenzenesulfonic acid having 11 to 17 carbon atoms of an alkyl group, an alphaolefinsulfonic acid having 10 to 18 carbon atoms of an alkyl group and an alkylsulfonic acid having 12 to 18 carbon atoms of an alkyl group. Method of Preparation of the Composition. 제7항에 있어서, 미중화 산성 계면활성물질을 메탄올, 에탄올, 프로판올, 부탄올 및 이소프로필알콜에 용해시켜 입상형 세제의 과립화 및 코팅공정에 사용함을 특징으로 하는 정제형 세조성물의 제조방법.The method of claim 7, wherein the unneutralized acidic surfactant is dissolved in methanol, ethanol, propanol, butanol, and isopropyl alcohol, and used for granulation and coating process of granular detergent. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930031012A 1993-12-29 1993-12-29 Tablet detergent composition KR960007876B1 (en)

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