KR950011503B1 - Process fir tge oreoaratuib of paint composition - Google Patents

Process fir tge oreoaratuib of paint composition Download PDF

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KR950011503B1
KR950011503B1 KR1019890020379A KR890020379A KR950011503B1 KR 950011503 B1 KR950011503 B1 KR 950011503B1 KR 1019890020379 A KR1019890020379 A KR 1019890020379A KR 890020379 A KR890020379 A KR 890020379A KR 950011503 B1 KR950011503 B1 KR 950011503B1
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weight
mixed
paint composition
pattern forming
pattern
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KR1019890020379A
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KR910012107A (en
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안성인
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고려화학주식회사
김충세
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/30Camouflage paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The pattern forming paint compsn. is prepd. by mixing : (a) 10-20 wt.% of vinyl butyral type resin comprising 70-80 wt.% of polyvinyl acetal and 1-10 wt.% of polyvinyl acetate and 10-25 wt.% of polyvinyl alcohol; (b) 1.5-12 wt.% of coloring asistant pigment; (c) 20-45 wt.% of isopropaol or ethanol; and (d) 30-53 wt.% of acetone, methanol or methylethyl ketone. In the process, 0.5 pts. of (a) component is mixed with (b) and (c); and other 0.5 pts of (a) is mixed with (d); then the obtd. two mixtures are mixed. The obtd. paint compsn. is coated by air-spray under 2.5-5.5 kg/cm2.

Description

무늬형성도료 조성물의 제조방법Manufacturing method of pattern forming paint composition

본 발명은 무늬형성도료 조성물의 제조방법에 관한 것으로서, 더욱 상세하게는 합도가 높은 비닐부티랄계 수지에 속건성용제를 용해시켜 놓은 것으로서, 일반적인 에어스프레이 방식으로 사용할 경우 균일한 필라멘트(Filament)무늬가 형성되어지는 1액형 무늬형성도료 조성물의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a pattern forming paint composition, and more particularly, a fast-drying solvent is dissolved in a high-density vinyl butyral resin, and has a uniform filament pattern when used in a general air spray method. It relates to a method for producing a one-part pattern forming paint composition to be formed.

최근들어서 생활의 발달과 여유공간의 중요성이 부각되면서, 가구나 악기 또는 실내의 공간에 고형색상을 적용시키거나 줄무늬와 같은 무늬를 형성시킬 수 있으면서도 사용이 간편한 새로운 미감의 도료가 요구되고 있다.Recently, with the development of life and the importance of free space, a new aesthetic paint that is easy to use while being able to apply solid colors or form stripes such as stripes in furniture, musical instruments or indoor spaces is required.

이런 이유로 인해, 일반적인 에어스프레이 도장방법에 의해 액체상태의 도료를 분무하므로서 다양한 무늬를 형성하는 액상의 도료가 필요하게 되었는 바, 종래에는 크랙(Crack) 무늬도료나 함마론 도료 등이 사용되었으나, 사용상 불편하고 원하는 무늬를 만들기 어려운 문제가 잇었다.For this reason, liquid paints that form various patterns by spraying liquid paints by general air spray coating methods have been required. In the past, crack pattern paints and hammer coatings were used. It was inconvenient and difficult to make the desired pattern.

따라서, 본 발명은 고분자량의 비닐부티랄계 수지에 안료나 염료, 속건성용제가 혼합된 도료조성물로서 일반적인 에어스프레이 도장방법에 의해 액체상태의 도료를 분무하므로서 필라멘트 무늬가 형성되게 되는 새로운 무늬형성도료 조성물의 제조방법과 그의 도포방법을 제공하는데 그 목적이 있다.Therefore, the present invention is a paint composition in which a pigment, a dye, or a fast-drying solvent is mixed with a high molecular weight vinyl butyral resin, and a new pattern forming paint composition is formed by spraying a liquid coating by a general air spray coating method. The purpose of the present invention is to provide a method for preparing and applying the same.

이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

본 발명은 비닐부티랄계 수지를 주성분으로 하는 무늬형성도료 조성물을 제조함에 있어서, (a) 폴리비닐아세탈 70∼80중량%와 폴리비닐아세테이트 1∼10중량% 및 폴리비닐알코올 10∼25중량%로 이루어진 비닐부티랄계 수지 10∼20중량%, (b) 조색용 피그먼트 1.5∼12중량%, (c) 이소프로판올 또는 에탄올 20∼45중량%, (d) 아세톤, 메탄올 및 메틸에틸케톤 중에서 선택된 것 30∼53중량%를 혼합시키되 상기 (a) 성분 중의 1/2을 (b) 및 (c)성분과 혼합시키고, 상기 (a)성분중 나머지 1/2은 (d)성분과 혼합시킨 다음, 이들 2가지 혼합물을 함께 혼합하여 제조하는 방법에 관한 것을 그 특징으로 한다.The present invention is to prepare a pattern forming paint composition comprising a vinyl butyral resin as (a) 70 to 80% by weight of polyvinyl acetal, 1 to 10% by weight of polyvinyl acetate and 10 to 25% by weight of polyvinyl alcohol. 10 to 20% by weight of vinyl butyral resin, (b) 1.5 to 12% by weight of pigment for pigmentation, (c) 20 to 45% by weight of isopropanol or ethanol, (d) acetone, methanol and methyl ethyl ketone 30 ˜53 wt.% Of the above (a) component is mixed with the (b) and (c) components, and the other half of the (a) component is mixed with the (d) component, and these It is characterized by a method for producing by mixing two mixtures together.

또한, 본 발명은 상기와 같은 방법으로 제조된 무늬형성도료 조성물 2.5∼5.5 ㎏/㎤의 압력으로 에어스프레이하여 도포표면에 코팅함을 특징으로 하는 무늬형성도료 조성물의 도포방법에 관한 것을 포함한다. 조성물의 도포방법에 관한 것을 포함한다.In addition, the present invention includes a method for applying a pattern forming paint composition, characterized in that the coating surface is coated by the air spray at a pressure of 2.5 to 5.5 kg / cm 3 produced by the pattern forming paint composition as described above. It relates to a method of applying the composition.

이와 같은 본 발명을 더욱 상세히 설명하면 다음과 같다.Referring to the present invention in more detail as follows.

본 발명은 비닐부티랄계 수지를 이용하여 이 수지들의 실킹(Silking)현상을 응용하여 스프레이 도장시 실과 같은 무늬를 만드는 필라멘트도료의 제조방법에 관한 것으로서, 이를 상세히 설명하면 중합도가 높은 비닐부티랄(Vinyl Butyral)계 수지를 속건성용제인 아세톤, 메킬에틸케톤, 메탄올, 에탄올, 이소프로판올 등의 용제에 용해시켜 에어스프레이로 도장할 때 균일한 필라멘트 무늬를 형성하게 된다.The present invention relates to a manufacturing method of a filament paint to make a pattern like a yarn when spray coating by applying the sealing phenomenon of these resins using vinyl butyral-based resin, which will be described in detail with a high degree of polymerization of vinyl butyral (Vinyl) Butyral) resin is dissolved in a solvent such as acetone, methyl ethyl ketone, methanol, ethanol, isopropanol, which is a fast-drying solvent, to form a uniform filament pattern when coated with an air spray.

본 발명에 의해 고중합도 비닐부티랄계 수지를 사용한 무늬형성도료 조성물의 제조공정을 살펴보면, 비닐부티랄계 수지(총 사용량의 1/2)와 이소프로판올 또는 에탄올과 같은 속건성용제를 교반기에 넣고 800∼1200rppm으로 2∼3시간 교반하여 비닐부티랄계 수지를 용해시킨 후 조색용 피그먼트(Pigment)를 첨가하여 30분 정도 혼합한 후 샌드밀(Sand Mill)로 입도 10μ 이하로 분산시켜 조성물(A)를 제조한다.Looking at the manufacturing process of the pattern forming paint composition using a high degree of polymerization of vinyl butyral resin according to the present invention, put the vinyl butyral resin (half of the total amount) and a fast-drying solvent such as isopropanol or ethanol in a stirrer at 800 ~ 1200rppm After stirring for 2-3 hours to dissolve the vinyl butyral resin, a pigment for pigmentation is added, mixed for about 30 minutes, and then dispersed in a sand mill with a particle size of 10 μ or less to prepare a composition (A). .

다시 비닐부티랄계 수지(총 사용량의 나머지1/2)와 아세톤, 메탄올 및 메틸에틸케톤 중에서 선택된 속건성용제를 교반기로 2∼3시간 교반하여 비닐부티랄계 수지를 용해시켜 조성물(B)를 만든 후, 상기 조성물(A)와 (B)를 혼합하여 약 30분간 교반하여 도료조성물을 제조한다.Then, a vinyl butyral resin (the remaining half of the total amount used) and a quick-drying solvent selected from acetone, methanol, and methyl ethyl ketone are stirred for 2 to 3 hours using a stirrer to dissolve the vinyl butyral resin to prepare a composition (B). The composition (A) and (B) are mixed and stirred for about 30 minutes to prepare a paint composition.

이와 같은 본 발명에 사용되는 비닐부티랄계 수지로서는 예컨데, 독일 Hoechst사 제품인 상품명 Mowital B-60H과 Mowital B-70H가 사용될 수 있으며, 필라멘트 무늬를 가늘고 조밀하게 만들때는 특히 B-60H를 사용하고, 무늬를 굵게 할 때는 Mowitac B-70H를 사용하는 것이 좋다. 이때 사용된 피그먼트는 일반적인 조색안료를 사용할 수 있다.As the vinyl butyral resin used in the present invention, for example, the brand names Mowital B-60H and Mowital B-70H manufactured by Hoechst, Germany can be used, especially when making the filament pattern thin and dense, B-60H is used, It is recommended to use Mowitac B-70H to make it thicker. Pigment used at this time may use a general pigment pigment.

또한, 본 발명에서 필라멘트도료 제조공정중 비닐부티랄 수지를 속건성용제로 두 번으로 나누어 용해시킨 후 혼합시키는 이유는 사용되는 피그먼트의 분산을 용이하게 하기 위하여 조성물(A)의 제조시에는 이소프로판올이나 에탄올 등의 휘발성이 적은 용제를 사용하여 피그먼트를 충분히 분산시킨 뒤, 조성물(B)와 혼합시키는 것이다.In addition, in the present invention, the reason for dissolving the vinyl butyral resin in the filament paint manufacturing process by dissolving it twice with a fast-drying solvent and then mixing is isopropanol or the like during the preparation of the composition (A) to facilitate dispersion of the pigment used. The pigment is sufficiently dispersed by using a solvent having a low volatility such as ethanol and then mixed with the composition (B).

이때, 조성물(H)에서는 아세톤, 메탄올, 메틸에틸케톤 등과 같이 비교적 휘발성이 좋은 용제를 사용하여 비닐수지를 분산시켜 필라멘트 형성이 용이하게 한다.At this time, in the composition (H) to disperse the vinyl resin using a relatively volatile solvent such as acetone, methanol, methyl ethyl ketone and the like to facilitate filament formation.

이렇게 본 발명에 의한 필라멘트 무늬형성도료 조성물은 용제의 사용방법 및 혼합사용에 의해 무늬의 길이나 굵기 등을 조절할 수 있으며, 특히 휘발성이 좋은 용제를 사용할 경우 필라멘트 무늬가 길어진다.Thus, the filament pattern forming paint composition according to the present invention can control the length and thickness of the pattern by the use method and mixed use of the solvent, especially when using a volatile solvent is long filament pattern.

한편, 본 발명에 의한 필라멘트 무늬형성도료는 자연건조형 1액형 도료로서 범용적인 에어스프레이방식의 도장으로 도장이 가능한 바, 도장시의 스프레이 압력도 2.0∼5.5㎏/㎠의 압력으로 하는 것이 바람직하다.On the other hand, the filament pattern forming paint according to the present invention is a natural-drying one-component paint, which can be painted by a general air spray method, and the spraying pressure during coating is also preferably 2.0 to 5.5 kg / cm 2. .

만일, 이때 그 압력이 크거나 적으면 무늬형성이 제대로 이루어지지 않게 되고, 특히 너무 강한 압력에는 형성되는 무늬가 깔끔한 느낌을 주지 못하게 되고 너무 약하면 무늬형성 자체가 이루어지지 않게 된다.If the pressure is large or small at this time, the pattern formation is not made properly, especially when the pressure is too strong does not give a neat feeling of the formed pattern, if too weak, the pattern formation itself is not made.

이상과 같이 본 발명에 의해 제조되는 무늬형성도료 조성물은, 일반적인 에어스프레이 도장방법에 의해 액체상태의 도료를 분무하므로서 실모양의 무늬를 형성하는 액상의 도료로서, 고분자량의 비닐부티랄계 수지, 안료 또는 염료, 속건성용제에 의한 액상의 혼합물이므로 본 도료는 하도도막의 색상과 필라멘트 도료의 색상대비에 의해 무늬를 더욱 선명하게 하며 색상 선택과 무늬형성 정도에 따라 마블(Marble)의 감각을 부여하기도 한다.As described above, the pattern forming coating composition prepared by the present invention is a liquid coating which forms a pattern of a yarn by spraying a liquid coating by a general air spray coating method, and has a high molecular weight vinyl butyral resin and a pigment. Or, because it is a liquid mixture by dyes and fast-drying solvents, this paint makes the pattern more vivid by the color of the undercoat and the color contrast of the filament paint, and gives the sense of Marble according to the color selection and the degree of pattern formation. .

또한, 투명색상에 색상 페이스트로 조색할 수도 있으며 색상으로 배합된 도료로도 제조하여 조색이 가능하다. 상도도료의 선택에 의해 유광에서 무광까지 광택조절이 용이하고 비황변 타입으로 변색이 거의 없다.In addition, the color may be tinted with a color paste on a transparent color and may also be tinted by preparing a paint blended with the color. It is easy to control the gloss from gloss to matt by the selection of top coat, and there is almost no discoloration as non-yellowing type.

또 도장단계를 준수할 경우 L/O계 우레탄계, A/A계, U/P계 도장시스테에 적용 가능하다. 즉, 본 발명의 도료조성물은 일반적인 에어스프레이 방식으로 필라멘트 무늬를 균일하게 분포시킬 수 있고, 도료의 점도와 에어스프레이의 압력조절만으로도 무늬의 크기를 자유롭게 조절할 수가 있는 특징이 있다.In addition, if the coating step is followed, it can be applied to L / O urethane, A / A, U / P-based coating cyste. In other words, the paint composition of the present invention can uniformly distribute the filament pattern by a general air spray method, and has a feature that the size of the pattern can be freely adjusted only by adjusting the viscosity of the paint and the pressure of the air spray.

이하, 본 발명을 실시예에 의거 설명하기로 한다.Hereinafter, the present invention will be described based on Examples.

[실시예 1]Example 1

중ㆍ소 무늬형성용 도료조성물의 제조Preparation of Paint Composition for Forming Small and Medium Patterns

비닐부티랄계 수지 D-60H(독일 Hoechst사 제품)5g과 이소프로판올 25g을 800~1200rpm의 교반기로 2시간 정도 교반하여 상기 비닐수지를 용해시킨다. 여기에다 피그먼트 12g을 투입하여 교반기로 약 30분 교환한 뒤 롤밀로서 입도 10μ 이하로 분산시킨다.5 g of vinyl butyral resin D-60H (manufactured by Hoechst, Germany) and 25 g of isopropanol are stirred for about 2 hours with a stirrer at 800 to 1200 rpm to dissolve the vinyl resin. 12 g of pigment was added thereto, exchanged with a stirrer for about 30 minutes, and dispersed in a roll mill having a particle size of 10 μm or less.

다른 한편으로는, 비닐부티랄계 수지 B-60H 5g과 메틸에틸케톤 53g을 교반기로 2시간 정도 교반하여 용해시킨 다음, 이들 상기 분산용액에 혼합하여 동일 교반기로 약 30분 교반하여 마감한다.On the other hand, 5 g of vinyl butyral resin B-60H and 53 g of methyl ethyl ketone are dissolved by stirring for about 2 hours, and then mixed with the above dispersion solution and finished by stirring for about 30 minutes with the same stirrer.

[실시예 2]Example 2

대무늬형성용도료 조성물의 제조Preparation of large pattern forming paint composition

비닐부티랄계 수지 B-70H(독일 Hoechst사 제품)5g과 에탄올 45g을 800~1200rpm의 교반기로 2시간 교반하여 상기 비닐부티랄계 수지를 용해시킨 다음, 여기에 피그먼트 12g을 투입하여 교반기로 약 30분 교반한 뒤 샌드밀로서 입도 10μ 이하로 분산시킨다.5 g of vinyl butyral resin B-70H (manufactured by Hoechst, Germany) and 45 g of ethanol were stirred for 2 hours using a stirrer of 800 to 1200 rpm to dissolve the vinyl butyral resin, and then 12 g of pigment was added thereto to add about 30 After stirring for a minute, the particle size is dispersed to a particle size of 10 mu or less as a sand mill.

그리고 다른 한편으로는, 비닐부티랄계 수지 B-70H 5g과 메탄올 23g, 그리고 아세톤 10g을 교반기로 2시간 교반하여 용해시킨 다음, 여기에 상기 분산된 용액을 혼합하여 동일 교반기로 약 30분간 교반하여 마감한다.On the other hand, 5 g of vinyl butyral resin B-70H, 23 g of methanol, and 10 g of acetone were dissolved by stirring for 2 hours, and then the dispersed solution was mixed and mixed with the same stirrer for about 30 minutes to finish. do.

[실시예 3]Example 3

무늬형성도료 조성물의 도포Application of the pattern forming paint composition

우레탄에나멜(흑색)을 도포하고 그 위에 상기 실시예 1에서 무늬형성도료 조성물(백색)을 도포한 다음, 다시 우레탄 투명도료를 도포하였다.Urethane enamel (black) was applied, and the pattern forming paint composition (white) was applied on it, and then urethane transparent paint was applied thereon.

상기 도포는 모두 통상의 압력에 의해 에어스프레이 방식으로 하였으며, 특히 무늬형성도료 조성물은 5.0kg/㎠ 압력으로 스프레이 하였다.All of the coating was in the air spraying by the usual pressure, in particular, the patterning coating composition was sprayed at a pressure of 5.0kg / ㎠.

락카에나멜(백색)을 도포하고 그 위에 상기 실시예 2에서 제조된 무늬형성도료 조성물(백색)을 도포한 다음, 다시 락카투명도료를 상기 실시예 3과 동일한 방법으로 도포하였다.Lacquer enamel (white) was applied and the pattern forming paint composition (white) prepared in Example 2 was applied thereon, and then lacquer transparent paint was applied in the same manner as in Example 3.

상기 실시예에 따르면, 본 발명에 따른 무늬형성도료 조성물의 도장시 점도는 실온에서 Ford Cup #4로서 20~30Sec정도가 적당하고, 무늬의 크기나 모양은 희석제의 사용으로 점도를 조절하면 변화가 가능하였다.According to the above embodiment, the viscosity of the pattern forming coating composition according to the present invention is suitable for about 20 ~ 30Sec as Ford Cup # 4 at room temperature, and the size or shape of the pattern is changed by adjusting the viscosity by using a diluent. It was possible.

이때 점도가 낮으면 무늬가 짧고 조밀한 무늬가 형성되었다.At this time, when the viscosity was low, the pattern was short and a dense pattern was formed.

또한, 상기 무늬형성도료의 도포시 스프레이 공기압력은 2.5~5.5kg/㎠ 가 적당하며 이 압력에 따라 무늬의 크기조절이 가능하였다. 이때 압력이 낮으면 무늬가 길어진다.In addition, the spray air pressure is 2.5 ~ 5.5kg / ㎠ when the coating of the pattern forming paint is appropriate and the size of the pattern was able to be adjusted. At this time, the lower the pressure, the longer the pattern.

Claims (2)

비닐부티랄계 수지를 주성분으로 하는 무늬형성도료 조성물을 제조함에 있어서, (a) 폴리비닐아세탈 70∼80중량%와 폴리비닐아세테이트 1∼10중량% 및 폴리비닐알코올 10∼25중량%로 이루어진 비닐부티랄계 수지 10∼20중량%, (b) 조색용 피그먼트 1.5∼12중량%, (c) 이소프로판올 또는 에탄올 20∼45중량% 및 (d) 아세톤, 메탄올 및 메틸에틸케톤 중에서 선택된 것 30∼53중량%를 혼합시키되 상기 (a) 성분 중의 1/2을 (b) 및 (c)성분과 혼합시키고, 상기 (a)성분중 나머지 1/2은 (d)성분과 혼합시킨 다음, 이들 2가지 혼합물을 함께 혼합하여 제조함을 특징으로 하는 무늬형성도료 조성물의 제조방법.In preparing a pattern forming paint composition containing vinylbutyral resin as a main component, (a) a vinylbuty consisting of 70 to 80% by weight of polyvinyl acetal, 1 to 10% by weight of polyvinyl acetate and 10 to 25% by weight of polyvinyl alcohol. 10 to 20% by weight of LAL resin, (b) 1.5 to 12% by weight of pigment for pigmentation, (c) 20 to 45% by weight of isopropanol or ethanol, and (d) 30 to 53% by weight selected from acetone, methanol and methyl ethyl ketone % Is mixed, one half of the component (a) is mixed with the components (b) and (c), and the other half of the component (a) is mixed with the component (d), and then the two mixtures Method for producing a pattern forming paint composition, characterized in that by mixing together to prepare. 제1항에 의해 제조된 무늬형성도료 조성물 2.5∼5.5 ㎏/㎠의 압력으로 에어스프레이하여 도포표면에 코팅함을 특징으로 하는 무늬형성도료 조성물의 도포방법.A method of applying a pattern forming paint composition, characterized by coating the coating surface by air spraying at a pressure of 2.5 ~ 5.5 kg / ㎠.
KR1019890020379A 1989-12-30 1989-12-30 Process fir tge oreoaratuib of paint composition KR950011503B1 (en)

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