KR950001667B1 - Process for the preparation of cement - Google Patents
Process for the preparation of cement Download PDFInfo
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- KR950001667B1 KR950001667B1 KR1019900004013A KR900004013A KR950001667B1 KR 950001667 B1 KR950001667 B1 KR 950001667B1 KR 1019900004013 A KR1019900004013 A KR 1019900004013A KR 900004013 A KR900004013 A KR 900004013A KR 950001667 B1 KR950001667 B1 KR 950001667B1
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- Prior art keywords
- oxide
- masato
- cement
- powder
- mixed
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
Abstract
Description
본 발명은 천연의 마사토 또는 이와 비슷한 성질의 규조토를 그 속에 포함된 모래만 선별가공작업없이 그대로 통상의 포틀랜시멘트와 혼합하여 건축자재로 사용할 수 있도록 한 연질시멘트 및 그 제조방법에 관한 것이다.The present invention relates to a soft cement and a method of manufacturing the same by using natural masato or diatomaceous earth having similar properties and mixing only with the sand contained therein, as it is, as a building material.
마사토나 규조토는 화강암과 규조암이 각각 오랜 세월 풍화된 것으로서 통상의 포트랜드시멘트와 혼합하여 벽돌등의 건축자재를 제조하면 건축자재로서의 필요한 강도를 얻을 수 없기 때문에 종래에는 마사토나 규조토를 직접 포트랜드시멘트와 혼합제조하여 건축자재로 사용할 수가 없었고 샌드밀과 같은 기계로 물과 함께 분쇄한 다음 그 중에서 순수모래만 선별하여 사용하고 나머지(뻘)는 버리게 되는 것이었다.Masato and diatomaceous earth are weathered granite and diatomite for many years, and if they are mixed with ordinary portland cement and manufacture building materials such as bricks, they cannot obtain the required strength as building materials. It could not be mixed and used as a building material. It was crushed with water using a machine such as sand mill, and then only pure sand was selected and the rest was discarded.
따라서 마사토나 규조토에서 순수모래를 선별하는 작업에 많은 기계장비와 인력이 소모될 뿐아니라 선별과정에서 나오는 많은 량이 뻘은 처리하기도 어렵고 수질을 오염시킬 우려가 있으며 또한 많은 뻘을 버리게 되므로 그만큼 자연자원을 낭비하게 되는 등의 문제가 있는 것이었다.Therefore, not only the large amount of mechanical equipment and manpower is required for sorting pure sand from masato or diatomaceous earth, but also the large amount from the sorting process is difficult to process and contaminates the water quality, and also throws away a lot of natural resources. There was a problem such as wasted.
본 발명은 이러한 문제점을 해결하여 마사토나 규조토에서 모래만을 선별하여 사용하지않고 그대로 포트랜드시멘트와 혼합하여 벽돌이나 블록등의 건축자재를 제조 사용할 수 있도록 한 것이다.The present invention solves this problem is to be used to manufacture the building materials, such as brick or block by mixing with Portland cement as it is not used to select only sand from Masato or diatomaceous earth.
천연의 마사토나 규조토를 시멘트와 혼합하면 강도가 부족하여 쉽게 부숴지므로 건축자재로 사용할 수 없다.If natural masato or diatomaceous earth are mixed with cement, they cannot be used as building materials because they lack strength and easily break down.
따라서 본 발명에서는 통상의 포트랜드시멘트성분인 산화칼슘분말(CaO), 이산화실리콘(SiO2), 산화알미늄(Al2O3) 및 산화철(Fe2O3)을 산화나트륨(Na2O3) 및 산화마그네슘(NGO)과 혼합하여 혼합분말을 얻고 이 혼합분말을 천연의 마사토 또는 규조토와 혼합하고 적량의 물을 투입 반죽하므로서 반죽물 상태의 연질시멘트를 제조하며 이 연질시멘트는 물과 반응하여 발열하는 산화나트륨과 산화마그네슘의 작용으로 점차응결경화되어 벽돌, 블록 등의 건축자재로서 충분한 압축강도를 갖게 되는 것이다.Therefore, in the present invention, calcium oxide powder (CaO), silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), and iron oxide (Fe 2 O 3 ), which are conventional portland cement components, are sodium oxide (Na 2 O 3 ) and Magnesium oxide (NGO) is mixed to obtain a mixed powder, and the mixed powder is mixed with natural masato or diatomaceous earth and kneaded with an appropriate amount of water to prepare a soft cement in the form of a dough, and the soft cement reacts with water to generate heat. It is gradually hardened by the action of sodium oxide and magnesium oxide, so that it has sufficient compressive strength as a building material for bricks and blocks.
본 발명의 실시예를 상세히 설명하면 다음과 같다.An embodiment of the present invention will be described in detail as follows.
[실시예]EXAMPLE
[제1공정][Step 1]
석회석을 가열분쇄하여서 된 산화칼슘분말(CaO) 약 6,670Kg, 이산화실리콘(SiO2), 2,220Kg, 산화알미늄(Al2O3)300Kg, 산화철(Fe2O3) 400Kg, 산화나트륨(Na2O3)200Kg, 산화마그네슘(MGO) 210Kg을 혼합하여 약 10ton의 혼합분말을 형성한다.Calcium oxide powder (CaO) obtained by heating and grinding limestone, about 6670 Kg, silicon dioxide (SiO 2 ), 2,220 Kg, aluminum oxide (Al 2 O 3 ) 300 Kg, iron oxide (Fe 2 O 3 ) 400 Kg, sodium oxide (Na 2 O 3 ) 200 Kg, 210 Kg of magnesium oxide (MGO) is mixed to form a mixed powder of about 10 tons.
[제2공정][Step 2]
제1공정에서 얻은 혼합분말을 마사토 또는 규조토와 약 1 : 4의 용적비로 고르게 혼합하고 적량의 물을 투입하여 반죽하므로 반죽물 상태의 연질시멘트가 완성된다.The mixed powder obtained in the first step is evenly mixed with masato or diatomaceous earth at a volume ratio of about 1: 4, and kneaded by adding an appropriate amount of water, thereby completing a soft cement in a kneaded state.
이와 같이 하여서된 본 발명은 필요에 따라 건축용 벽돌, 도로경계석, 기와, 타일, 하수관 등의, 각종 건설자재 형상으로 성형하고 통상의 방법과 같이 건조하면 물과 반응하여 발열하는 산화나트륨과 산화마그네슘의 작용으로 서로 응결경화되어(자연건조 15-20일, 스팀건조 2-3시간 소요됨) 압축강도가 표(1)(2)(3)에서와 같이 KS획득기준 압축강도인 벽돌 80Kg/㎠, 블록 40Kg/㎠ 이상이 된다.Thus, the present invention is formed of various building materials, such as brick, road boundary stone, tile, tiles, sewer pipes, etc., if necessary, and the sodium oxide and magnesium oxide that react with water to generate heat when dried in the usual manner. By condensation hardening with each other (15-20 days of natural drying, 2-3 hours of steam drying), the compressive strength is 80Kg / ㎠, the block of KS standard compressive strength as shown in Table (1) (2) (3). It becomes 40Kg / cm <2> or more.
[표 1]TABLE 1
* 시험방법 : KSF-4004-85* Test method: KSF-4004-85
* 시험기관 : 한국화학시험검사소* Test organization: Korea Testing Laboratory
* 품명 : 벽돌* Name: Brick
[표 2]TABLE 2
* 시험번호 : 민 961-1-8* Test Number: Min 961-1-8
* 시험기관 : 부산직할시 건설시험소* Test organization: Busan Direct Construction Construction Laboratory
* 품명 : 벽돌* Name: Brick
[표 3]TABLE 3
* 시료번호 : 157-1-42* Sample Number: 157-1-42
* 시험기관 : 경상남도 주택자재검사소* Test organization: Gyeongsangnam-do Housing Materials Inspection Office
* 품명 : 벽돌, 블록* Product Name: Brick, Block
본 발명에 있어 보통의 포트랜드시멘트 주성분인 CaO, SiO2, Al2O3, Fe2O3의 혼합비율은 통상의 시멘트 제조시의 비율에 따른 것이며 산화나트륨(Na2O3)와 산화마그네슘(MGO)의 혼합비율은 가장 이상적인 비율을 제시한 것이며, 이 비율은 다소 다르게 혼합하여도 경화시간 등에서 차이가 날뿐 작용효과상의 큰 차이는 없다.In the present invention, the mixing ratio of CaO, SiO 2 , Al 2 O 3 , and Fe 2 O 3 , which are the main components of portland cement, is based on the ratio of ordinary cement, and sodium oxide (Na 2 O 3 ) and magnesium oxide ( The mixing ratio of MGO) suggests the most ideal ratio, and even if mixed slightly differently, the difference in curing time and the like does not have a big difference in effect.
혼합분말과 마사토 또는 규조토와의 혼합비율은 보통정도의 마사토와 규조토와의 이상적인 혼합비율이며 이 혼합비율은 생산지역에 따라 여러가지인 마사토와 규조토의 종류와 성분에 따라 각각 다르게 작용된다.The mixing ratio of mixed powder and masato or diatomaceous earth is the ideal mixing ratio of normal masato and diatomaceous earth. The mixing ratio is different depending on the type and composition of masato and diatomaceous earth depending on the production area.
이상과 같이 본 발명은 고갈되어가는 모래와 자갈대신에 거의 무한정으로 존재하는 마사토나 규조토를 사용하여 각종 건설자재를 생산사용토록 하므로서 자원의 고갈을 방지하고 새로운 자원을 활용하는 효과가 있는 것이다.As described above, the present invention has the effect of preventing the exhaustion of resources and utilizing new resources by producing and using various construction materials using masato or diatomaceous earth, which exist almost indefinitely instead of depleted sand and gravel.
또한 본 발명은 종래의 시멘트와 모래를 혼합하여서된 시멘트벽돌에 비하여 내충격성이 높아 충격에 강하고 쉽게 균열되거나 깨어지지 않는다.In addition, the present invention has a high impact resistance compared to the cement brick is a mixture of conventional cement and sand, resistant to impact and not easily cracked or broken.
이는 마사토나 규조토의 부드러운 성질 때문이다.This is due to the soft nature of masato or diatomaceous earth.
또 마사토나 규조토의 입자가 미세하여 제품의 밀도가 높기때문에 투과성이 낮아 방수, 방음, 보온효과가 높다.In addition, because the particles of masato or diatomaceous earth are fine and the density of the product is high, the permeability is low and the waterproofing, soundproofing, and thermal insulation effect is high.
또 내산성이 높아 거의 산화되지 않으므로 반영구적이며 염수에 강하고 염수에도 콘크리트화가 되므로 해중공사나 해변공사가 용이하고 내화력이 강하고 특히 견운모와 같은 연결성소재를 약 6% 정도 본 발명과 혼합하여 제조하면 소정공정을 거치지 않고도 약 1,600℃까지의 내화력을 갖는다.In addition, it is semi-permanent, resistant to salt water and concrete to salt water because it is hardly oxidized due to high acid resistance, so it is easy to undersea construction or beach construction. Has fire resistance up to about 1,600 ℃ without going through.
종래의 시멘트는 모래가 견운모와 합체가 잘되지 않아 혼합사용이 곤란하였으나 마사토는 쉽게 견운모와 합체가 되므로 혼합사용이 가능하다.Conventional cement is difficult to mix and use because the sand is not well coalesced with the mica, but Masato is easily mixed with the mica and thus can be mixed.
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KR1019900004013A KR950001667B1 (en) | 1990-03-22 | 1990-03-22 | Process for the preparation of cement |
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KR1019900004013A KR950001667B1 (en) | 1990-03-22 | 1990-03-22 | Process for the preparation of cement |
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KR910016642A KR910016642A (en) | 1991-11-05 |
KR950001667B1 true KR950001667B1 (en) | 1995-02-28 |
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KR1019900004013A KR950001667B1 (en) | 1990-03-22 | 1990-03-22 | Process for the preparation of cement |
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