KR950000460B1 - Method of coating ceramic ware - Google Patents

Method of coating ceramic ware Download PDF

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Publication number
KR950000460B1
KR950000460B1 KR1019920003584A KR920003584A KR950000460B1 KR 950000460 B1 KR950000460 B1 KR 950000460B1 KR 1019920003584 A KR1019920003584 A KR 1019920003584A KR 920003584 A KR920003584 A KR 920003584A KR 950000460 B1 KR950000460 B1 KR 950000460B1
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South Korea
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heat
magnetic
silver
coating layer
film
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KR1019920003584A
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Korean (ko)
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KR930019588A (en
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양승학
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양승학
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J27/00Cooking-vessels

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Cookers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

A silver solution is made by mixing 75-85% of Ag and 13-18 % of an adhesive and 2-7% of a synthetic resin. The silver solution is diluted by adding 11-13% of solvent relative to 100 % of silver solution to be gelled. The diluted silver solution is firstly printed by screen to 0.09-0.11 m/m of thickness and dried for 2 hr. at 38-42 deg.C by a hot air, and secondrily printed to 0.18-0.22 m/m of thickness and also dried. After aging at 800 deg.C, a final thickness of coating layer of magnetic body is 0.13-0.16 m/m. This cookware can be used at an induction heating cooker.

Description

내열조리용기 저면의 자성체 피막층 형성방법Method of forming magnetic coating layer on bottom of heat-resistant cooking container

제 1 도는 본 발명의 피막층을 형성하는 과정의 계통도.1 is a schematic diagram of a process of forming a coating layer of the present invention.

제 2 도는 본 발명에 의해 피막층이 형성된 내열조리용기의 단면도.2 is a cross-sectional view of the heat-resistant cooking container formed with a coating layer according to the present invention.

제 3 도는 인덕션 렌지와 자성체 주방기와의 자력선의 작용원리 설명예시도.3 is an exemplary view illustrating the principle of operation of the magnetic force line between the induction stove and the magnetic body kitchen.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 내열조리용기 2 : 자성체 주방기구1: heat-resistant cooking container 2: magnetic kitchen utensil

3 : 인덕션 렌지의 상판 4 : 자성체 피막층3: top plate of induction stove 4: magnetic coating layer

본 발명은 주로 세라믹과 규석으로 제조되는 내열조리용기의 저면에 자성체 피막층을 얇게 도막처리시켜주어 내열조리용기를 인덕션 렌지(Induction Heating Cooker)에서 사용할 수 있도록 저면에 자성체 피막층을 형성한 내열조리용기를 제공받을 수 있도록 한 내열조리용기 저면의 자성체 피막층 형성방법에 관한 것이다.The present invention is a heat-resistant cooking vessel having a magnetic coating layer formed on the bottom surface of the heat-resistant cooking container mainly made of ceramic and silica, so that the magnetic coating layer is thinly coated on the bottom of the heat-resistant cooking vessel so that the heat-resistant cooking container can be used in an induction heating cooker. It relates to a method for forming a magnetic coating layer on the bottom of the heat-resistant cooking container to be provided.

본 발명에서 자성체 피막층을 도막처리시키는 재질로서는 은(銀)용액을 채택하고 있으며, 은(銀)은 자성체 중에서 열전도율과 전기를 통과시키는 효율이 가장 우수하고 값이 비교적 저렴하기 때문에 채택사용한 것이다.In the present invention, a silver solution is used as a material for coating the magnetic coating layer, and silver is used because it has the best thermal conductivity and efficiency of passing electricity among magnetic materials and its value is relatively low.

본 발명은 내열조리용기와 같은 주방기구에 자성체 피막층을 형성시키므로서 인덕션 렌지에서 유용하게 사용할 수 있도록 한 것인데, 인덕션 렌지의 작동원리는 첨부도면 제 3 도에 도시되어 있다.The present invention is to be useful in an induction stove by forming a magnetic coating layer on a kitchen appliance such as a heat-resistant cooking vessel, the operation principle of the induction stove is shown in FIG.

즉, 인덕션 렌지의 내부에는 히팅코일(Heating Coil)이 내설되어 있는데, 전원이 입력되면 자속(磁束)이 발생하여 인덕션 렌지의 상판(3) 위에 안치되어 있는 자성체로된 주방기구에까지 자속이 유도(Induction)되어 주방기구의 바닥면에서 맴돌이 전류를 발생시킴으로써 그로 인한 열이 발생하게 되는 것이다.That is, a heating coil is installed inside the induction stove. When the power is input, magnetic flux is generated, and the magnetic flux is induced to the kitchen utensil made of magnetic material placed on the top plate 3 of the induction stove. Induction) generates eddy currents at the bottom of the kitchen utensils, resulting in heat generation.

그러나, 비자성체로 된 주방기구일 때에는 주방기구에 자속이 유도되지 못하여 맴돌이 전류가 발생하지 않으므로 인덕션 렌지에서의 사용이 불가능한 것이다.However, in the case of a non-magnetic kitchen utensils, the magnetic flux is not induced to the kitchen utensils, so no eddy current is generated, so it is impossible to use the induction stove.

즉, 도자기, 세라믹, 규석등으로 된 주방기구 특히 내열조리용기는 여타의 자성물질을 함유하고 있지 않기 때문에 인덕션 렌지에서 발생된 자속이 유도되지 못하고 차단되므로 사용할 수가 없는 단점이 있었던 것이다.In other words, kitchen utensils, especially heat-resistant cooking vessels made of ceramics, ceramics, silica, etc., do not contain any other magnetic materials, so the magnetic flux generated in the induction stove is not induced, and therefore, it cannot be used.

따라서 본 발명은 비자성체로 된 주방기구 특히, 본체가 도자기, 차이나, 세라믹등으로 된 내열조리용기(1)라 할지라도 이를 인덕션 렌지에서 효과적으로 사용할 수 있도록 하기 위하여 내열조리용기(1)의 저면에 자성의 성질을 갖는 물질 즉, 자성체 피막층(4)을 얇게 도막처리시켜 줌으로써 인덕션 렌지에서 발생하는 자속을 효율적으로 유도하여 자기유도(磁氣誘導)에 의해 맴돌이 전류가 발생할 수 있도록 한 것이다.Therefore, the present invention is a non-magnetic kitchen utensil, in particular, even if the heat-resistant cooking container (1) made of ceramics, China, ceramics, etc. in order to effectively use it in the induction stove to the bottom of the heat-resistant cooking container (1) By thinly coating a material having a magnetic property, that is, the magnetic coating layer 4, the magnetic flux generated in the induction stove is efficiently induced so that a eddy current can be generated by magnetic induction.

본 발명에서는 피막층(4)을 형성함에 있어서, 은(銀)을 주재료로 한 자성물질로 사용되는데, 은(銀)(75∼85%)에 접착제(Binder)(13∼18%)와 합성수지제(2∼7%)를 적절한 비율로 혼합시킨 은용액(銀溶液)을 희석시켜서 도막처리하여 피막층(4)을 형성하는 것으로, 상기 은(銀)용액에 휘발성 유체인 용제를 100 : 11∼13%의 비율로 첨가하여 젤(Gel) 또는 졸(Sul) 상태가 되도록 하여 잘 교반하고, 교반된 은(銀)희석 용액을 내열조리용기(1)의 저면에 약 0.09∼0.11m/m의 두께가 되도록 스크린 인쇄법에 의해 1차 인쇄하여 연도막 처리한 후, 38∼42℃의 상온에서 2시간 동안 열풍 건조하고, 다시 은(銀)희석 용액을 0.18∼0.22m/m의 두께로 재차 스크린 인쇄법에 의하여 2차 인쇄하여 경도막 처리한 후, 38∼42℃의 상온에서 2시간동안 재차 열풍건조하고 약 800℃의 고온에서 소성하여 연도막 처리된 자성체 피막층이 0.13∼0.16m/m의 두께로 형성되도록 한다.In the present invention, in forming the coating layer 4, it is used as a magnetic material mainly composed of silver, which is composed of silver (75 to 85%), adhesive (13 to 18%) and synthetic resin. Diluting the silver solution mixed with (2-7%) at an appropriate ratio to form a coating layer 4 by coating the silver solution, the solvent is a volatile fluid 100: 11 to 13 in the silver solution It is added in a ratio of% to make a gel or sol state and stirred well, and the stirred silver dilution solution has a thickness of about 0.09 to 0.11 m / m on the bottom of the heat-resistant cooking container (1). After primary printing by the screen printing method so that the coating film treatment, and hot-air dried at room temperature of 38 ~ 42 ℃ for 2 hours, the silver dilution solution is again screened to a thickness of 0.18 ~ 0.22m / m After the second printing by the printing method and the hardness film treatment, and hot-air dried again for 2 hours at a room temperature of 38 ~ 42 ℃ and calcined at a high temperature of about 800 ℃ The magnetic material coating layer of the coated film is treated so as to form a thickness of 0.13~0.16m / m.

이때, 가열과 냉각이 극히 서서히 이루어지도록 한다.At this time, the heating and cooling is to be made very slowly.

이와 같은 방법으로 되는 본 발명 실시예를 제조공정별로 상세히 설명하면 다음과 같다.When explaining the embodiment of the present invention by the method as described in detail by the manufacturing process as follows.

[제 1 공정][Step 1]

은과 접착제 및 합성수지제를 적절한 비율로 혼합시킨 은(銀)용액에 휘발성 유체를 100 : 11∼13%의 비율로 첨가하여 은(銀)희석 용액이 겔(Gel) 또는 졸(Sul) 상태가 되도록 잘 교반한다.A volatile fluid was added to the silver solution in which silver, an adhesive, and a synthetic resin were mixed in an appropriate ratio at a ratio of 100: 11 to 13%, so that the silver dilution solution was in a gel or sol state. Stir well if possible.

[제 2 공정]Second Process

상기 은(銀)희석 용액을 내열조리용기(1)의 저면에 스크린 인쇄법에 의해 0.09∼0.11m/m의 두께가 되도록 1차 인쇄하여 연도막 처리한다.The silver dilution solution is first printed on the bottom surface of the heat-resistant cooking container 1 so as to have a thickness of 0.09 to 0.11 m / m by a screen printing method and subjected to a soft coating treatment.

[제 3 공정][Third process]

상기 1차 연도막 처리된 내열조리용기(1)를 38∼42℃의 상온에서 2시간 동안 열풍건조시킨다.The heat-resistant cooking vessel (1) treated with the primary soft film is dried by hot air at room temperature of 38 to 42 ° C for 2 hours.

[제 4 공정][4th process]

상기 1차 연도막 처리층이 형성된 상부에 은(銀)희석 용액을 스크린 인쇄법에 의해 0.18∼0.22m/m의 두께로 2차 인쇄하여 경도막 처리한다.The silver dilution solution is second-printed by the screen printing method to the thickness of 0.18-0.22 m / m on the upper part in which the said 1st soft-film coating layer was formed, and it carries out a hardness film process.

[제 5 공정][5th process]

상기 경도막 처리된 내열조리용기(1)를 38∼42℃의 상온에서 2시간 동안 재차 열풍건조한다.The heat-resistant cooking vessel (1) subjected to the hardness film treatment is dried by hot air again for 2 hours at a room temperature of 38 to 42 ℃.

[제 6 공정][Sixth Step]

상기 경도막 처리된 은희석 용액이 완전히 건조되면 약 800℃의 고온에서 서서히 소성처리하되, 가열-숙성-냉각의 순으로서 아래 도표에 나타낸 바와 같이 서서히 소성처리한다.When the hard film-treated silver dilution solution is completely dried, it is gradually calcined at a high temperature of about 800 ° C., but gradually calcined as shown in the table below in the order of heating-aging-cooling.

상기와 같이 거의 4시간여에 걸쳐 온도가 매우 서서히 상승하도록 가열을 한 후, 최고온도 약 800℃의 내외에서 20여분간 숙성시킨 다음, 다시 4시간여에 걸쳐 매우 서서히 냉각시킨다.After heating the temperature so that the temperature rises very slowly over about 4 hours as described above, it is aged for about 20 minutes at about 800 ° C maximum temperature, and then cooled very slowly over 4 hours.

[표][table]

[제 7 공정][7th process]

상기 소성과정이 완료된 제품은 선별하고 포장하여 상품으로서 반출한다.After the firing process is completed, the product is sorted and packaged and taken out as a product.

상술한 바와 같은 제조공정에 따라 형성되는 본 발명의 내열조리용기는 그 소성과정에서 소성(가열-숙성-냉각)이 서서히 이루어지도록 하는 것은 도막처리된 자성체 피막층(4)이 용기본체와의 접착력을 양호하게 하기 위한 것이며, 또한 내열조리용기 본연의 성질등이 변화되지 않도록 하기 위한 것이다.The heat-resistant cooking container of the present invention formed in accordance with the manufacturing process as described above so that the firing (heat-maturation-cooling) is gradually carried out during the firing process, the coating of the magnetic film layer (4) of the coated film to the adhesion of the container body It is for making it favorable, and for preventing the nature, etc. of a heat resistant cooking container from changing.

이렇게 소성이 완료된 상태에서 도막처리된 자성체 피막층(4)의 두께는 0.15m/m 내외가 되도록 하는 것이 가장 큰 효율을 얻을 수 있는 것이며, 또한 본 발명에서는 자성체 피막층(4)을 내열조리용기(1)에 스크린 인쇄법에 의하여 직접 도막처리하지 않고, 별도의 자성체 피막층을 제조하여 이를 내열조리용기(1)에 증착시키는 간접도막처리방법도 용이하게 실시할 수 있으며, 이러한 간접 증착방법에 의해 제조된 내열조리용기도 동일한 효과를 얻을 수 있는 것이다.In this state, the thickness of the magnetic coating layer 4 that has been coated in the state where the firing is completed is about 0.15 m / m, so that the greatest efficiency can be obtained. In addition, in the present invention, the magnetic coating layer 4 is formed of a heat-resistant cooking container (1). Indirect coating treatment method to prepare a separate magnetic coating layer and deposit it on the heat-resistant cooking container (1) without directly coating the coating film by the screen printing method, can be easily carried out. Heat-resistant cooking containers can also achieve the same effect.

상술한 바와 같은 자성체 피막층의 형성방법에 의하여 도막처리된 자성체 피막층을 갖는 내열도자기는 인덕션 렌지에서 효율적이고 유용하게 사용할 수 있는 것이다.Heat-resistant ceramics having a magnetic coating layer coated by the method of forming the magnetic coating layer as described above can be used efficiently and efficiently in an induction stove.

즉, 인덕션 렌지의 히팅코일에서 발생되는 자속이 내열도자기의 자성체 피막층에 유도되어 유도전류에 의해 맴돌이 전류가 생성되고 이 맴돌이 전류에 의하여 열이 발생함으로써 내열조리용기에 의해 음식을 조리할 수 있는 것이다.That is, the magnetic flux generated from the heating coil of the induction stove is induced in the magnetic coating layer of the heat-resistant ceramic, so that a eddy current is generated by the induced current, and heat is generated by the eddy current, so that the food can be cooked by the heat-resistant cooking container. .

Claims (1)

은(銀)에 접착제와 합성수지제를 적절히 혼합시킨 은(銀)용액에 휘발성 유체인 용제를 100 : 11∼13%의 비율로 첨가하여 교반한 후, 희석된 은희석 용액을 내열조리용기(1)의 저면에 1차 연도막 처리하고 38∼42℃의 상온에서 2시간동안 열풍건조한 다음, 재차 경도막 처리하고 상온에서 열풍건조시킨 후, 약 800℃의 고온에서 소성하여 연도막 처리된 자성체 피막층(4)이 0.13∼0.16m/m의 두께로 형성되도록 한 것을 특징으로 하는 내열조리용기 저면의 자성체 피막층 형성방법.To a silver solution in which an adhesive and a synthetic resin were properly mixed with silver, a volatile fluid was added and stirred at a ratio of 100: 11 to 13%, and the diluted silver dilution solution was added to a heat-resistant cooking container (1). The primary soft film was treated on the bottom of the film, and hot air dried at room temperature of 38 to 42 ° C. for 2 hours, and then treated with a hard film, and hot air dried at room temperature, and then fired at a high temperature of about 800 ° C. to obtain a soft film treated magnetic film layer ( 4) is formed in a thickness of 0.13 ~ 0.16m / m method of forming a magnetic coating layer on the bottom of the heat-resistant cooking container.
KR1019920003584A 1992-03-04 1992-03-04 Method of coating ceramic ware KR950000460B1 (en)

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KR950000460B1 true KR950000460B1 (en) 1995-01-20

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